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list and off-list prices for Pamolyn 100 FGK, 100, 125, 300, 327B, 347 have increased by US$0.04/lb ($0.088/kg) for products supplied in 410 lb drums and by $0.03/lb ($0.066/kg) for bulk shipments. Pamolyn 125, 100 and its kosher equivalent 100 FGK are oleic acid products used as emulsifiers or surfactants in cosmetic or personal care products; Pamolyn 347 is a blend of oleic and conjugated linoleic acids. Pamak 1, 2, 4A, 4, 25A tall oil fatty acids are also subject to global list and off-list price increases of $0.03/lb for 410 lb drums and $0.02/lb for bulk shipments. These products find applications as emulsifiers, soaps and flotation reagents. Press release from: Eastman Chemical Company, Kingsport, TN, USA. Tel: +1 423 229 6636. Website: http://www.eastman.com (9 May 2005) New silicone products from GE for foam and personal care applications GE Advanced Materials is launching new NIAX silicone L-650 surfactant, which offers a further 10-30% reduction by weight of flame-retardant use in slabstock polyurethane foam applications, compared to earlier products in the industry. In addition, new NIAX silicone L-650 can be applied in conventional foam manufacturing processes, as well as those that use carbon dioxide as an auxiliary blowing agent. NIAX silicone L-650 may be an excellent candidate for use in flame retardant grades of foam for furniture, bedding and automotive products, to reduce the amount of flame retardant required to pass small-scale tests like California Technical Bulletin 117 and MVSS-302. In addition to its outstanding flame retardant improvement, this quality may also translate into reduced material costs for manufacturers who use GE’s NIAX silicone L-650. The new surfactant is said to provide excellent froth formation and stability as required in CO 2 processes to help make soft and low-density foam grades. It also delivers wide processing latitude, very fine cell structure in CO 2 processes, and a very broad grade range latitude. GE Advanced Materials has also launched four new silicone-based products that help offer enhanced performance and greater versatility to personal care formulations. Silsoft Tone (AB)n terpolymer is a multifunctional hair conditioning agent that can be added to shampoos and leave-on hair conditioners. It enhances shine by promoting alignment of hair fibres, and helps deliver excellent colour retention, plus an added degree of protection to hair treated with high-temperature styling devices such as flat ceramic irons. Silsoft A-553 material is a 100% active (AB)n terpolymer designed to deliver premium conditioning benefits to hair. In addition to providing outstanding wet- and dry-combing performance, this proprietary material minimizes fly-away, and gives hair a unique soft, silky after-feel. It is soluble in surfactant matrices commonly used in shampoos, and can be used for both clear and opaque products. SilShine 151 silicone resin is a multi-functional, film-forming material that can be used in sun care, colour cosmetics and hair care products. Its helps deliver visually perceptible, durable high gloss to lips and hair, boosts SPF performance, provides emolliency and may increase the compatibility of organic sunscreens (particularly oxybenzone and avobenzone) in a formulation. It also offers anti- whitening performance for antiperspirant formulations, and its phenyl functionality helps deliver excellent compatibility with both organic emollients and silicone materials. Finally, GE’s SF 1540 emulsifier is a water-in-oil product with high actives content (40%), which helps to provide formulators with more room in the oil phase for pigments, sunscreens, actives, emollients and other ingredients critical for cosmetics and ultra-high SPF lotions. A member of the polyether-modified silicone copolymer family, this emulsifier also offers the opportunity for stabilization of sensitive, hydrolytically unstable ingredients in a skin cream. It also provides high internal phase emulsion stability, cold processability and an excellent feel on the skin. Press release from: GE Advanced Materials, Pittsfield, MS, USA. Website: http://www.geadvancedmaterials.com (15 Apr 2005 & 9 May 2005) Huntsman surfactant prices rise The rising cost of energy and raw materials combined with the tight market has forced Huntsman’s Performance Products division to increase the price of certain surfactants from 1 May 2005. The price of Surfonic N series surfactants has been increased by 3 cts/lb. The off-list price of the Surfonic L series and the DA series of alcohol ethoxylates has also been increased by 3 cts/lb. Dinonyl phenol prices have risen by 10 cts/lb and the off-list price of the Surfonic TDA series of alcohol ethoxylates has been increased by 5 cts/lb. Chemical Week, 11 May 2005, 167 (16) (Website: http://www.chemweek.com) Tri-Tex introduces alkanolamide replacement Tri-Tex Co launches Tritexaine OC, an effective amphoteric surfactant that can substitute typical formulation uses of alkanolamides specifically with diethanolamine. The liquid, which is clear yellow, is claimed to be water- soluble and is easy to incorporate, offering superior viscosity building properties and enhancing conditioning, foaming and mildness in personal care products. The product is compatible with anionic, nonionic and cationic surfactants. Low temperature blending is allowed because of its low cloud point. HAPPI, Household & Personal Products Industry, May 2005, 42 (5), 142-143 Further US concerns about possible PFOA exposure A nationwide campaign has been launched by the United Steelworkers of America to determine whether its members are being exposed to perfluorooctanoic acid (PFOA) and whether this is causing any health problems. The particular focus of the survey is Zonyl, the PFOA from DuPont [see also Focus on Surfactants, Jun 2003]. The EPA lists PFOA as a possible carcinogen and there are links between exposure to PFOA and developmental impairment. The surfactant is used in paper coating to give stain resistance. Food packaging is one of the uses of such PFOA-treated paper. Because coatings are often premixed away from the facilities where they are applied, workers may not be aware that the products they are handling JULY 2005 3 FOCUS ON SURFACTANTS

Tri-Tex introduces alkanolamide replacement

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Page 1: Tri-Tex introduces alkanolamide replacement

list and off-list prices for Pamolyn 100FGK, 100, 125, 300, 327B, 347 haveincreased by US$0.04/lb ($0.088/kg)for products supplied in 410 lb drumsand by $0.03/lb ($0.066/kg) for bulkshipments. Pamolyn 125, 100 and itskosher equivalent 100 FGK are oleicacid products used as emulsifiers orsurfactants in cosmetic or personalcare products; Pamolyn 347 is ablend of oleic and conjugated linoleicacids. Pamak 1, 2, 4A, 4, 25A tall oilfatty acids are also subject to global listand off-list price increases of $0.03/lbfor 410 lb drums and $0.02/lb for bulkshipments. These products findapplications as emulsifiers, soaps andflotation reagents.

Press release from: Eastman Chemical Company,Kingsport, TN, USA. Tel: +1 423 229 6636. Website:http://www.eastman.com (9 May 2005)

New silicone products from GE forfoam and personal care applications

GE Advanced Materials is launchingnew NIAX silicone L-650 surfactant,which offers a further 10-30%reduction by weight of flame-retardantuse in slabstock polyurethane foamapplications, compared to earlierproducts in the industry. In addition,new NIAX silicone L-650 can beapplied in conventional foammanufacturing processes, as well asthose that use carbon dioxide as anauxiliary blowing agent. NIAX siliconeL-650 may be an excellent candidatefor use in flame retardant grades offoam for furniture, bedding andautomotive products, to reduce theamount of flame retardant required topass small-scale tests like CaliforniaTechnical Bulletin 117 and MVSS-302.In addition to its outstanding flameretardant improvement, this qualitymay also translate into reducedmaterial costs for manufacturers whouse GE’s NIAX silicone L-650. Thenew surfactant is said to provideexcellent froth formation and stabilityas required in CO2 processes to helpmake soft and low-density foamgrades. It also delivers wide processinglatitude, very fine cell structure in CO2processes, and a very broad graderange latitude.

GE Advanced Materials has alsolaunched four new silicone-basedproducts that help offer enhancedperformance and greater versatility topersonal care formulations. Silsoft

Tone (AB)n terpolymer is amultifunctional hair conditioning agentthat can be added to shampoos andleave-on hair conditioners. Itenhances shine by promotingalignment of hair fibres, and helpsdeliver excellent colour retention, plusan added degree of protection to hairtreated with high-temperature stylingdevices such as flat ceramic irons.Silsoft A-553 material is a 100%active (AB)n terpolymer designed todeliver premium conditioning benefitsto hair. In addition to providingoutstanding wet- and dry-combingperformance, this proprietary materialminimizes fly-away, and gives hair aunique soft, silky after-feel. It issoluble in surfactant matricescommonly used in shampoos, andcan be used for both clear andopaque products. SilShine 151silicone resin is a multi-functional,film-forming material that can be usedin sun care, colour cosmetics and haircare products. Its helps delivervisually perceptible, durable highgloss to lips and hair, boosts SPFperformance, provides emolliencyand may increase the compatibility oforganic sunscreens (particularlyoxybenzone and avobenzone) in aformulation. It also offers anti-whitening performance forantiperspirant formulations, and itsphenyl functionality helps deliverexcellent compatibility with bothorganic emollients and siliconematerials. Finally, GE’s SF 1540emulsifier is a water-in-oil product withhigh actives content (40%), whichhelps to provide formulators with moreroom in the oil phase for pigments,sunscreens, actives, emollients andother ingredients critical for cosmeticsand ultra-high SPF lotions. A memberof the polyether-modified siliconecopolymer family, this emulsifier alsooffers the opportunity for stabilization ofsensitive, hydrolytically unstableingredients in a skin cream. It alsoprovides high internal phase emulsionstability, cold processability and anexcellent feel on the skin.

Press release from: GE Advanced Materials, Pittsfield,MS, USA. Website:http://www.geadvancedmaterials.com (15 Apr 2005 &9 May 2005)

Huntsman surfactant prices rise

The rising cost of energy and rawmaterials combined with the tight

market has forced Huntsman’sPerformance Products division toincrease the price of certainsurfactants from 1 May 2005. Theprice of Surfonic N series surfactantshas been increased by 3 cts/lb. Theoff-list price of the Surfonic L seriesand the DA series of alcoholethoxylates has also been increasedby 3 cts/lb. Dinonyl phenol priceshave risen by 10 cts/lb and the off-listprice of the Surfonic TDA series ofalcohol ethoxylates has beenincreased by 5 cts/lb.

Chemical Week, 11 May 2005, 167 (16) (Website:http://www.chemweek.com)

Tri-Tex introduces alkanolamidereplacement

Tri-Tex Co launches Tritexaine OC,an effective amphoteric surfactantthat can substitute typical formulationuses of alkanolamides specificallywith diethanolamine. The liquid, whichis clear yellow, is claimed to be water-soluble and is easy to incorporate,offering superior viscosity buildingproperties and enhancingconditioning, foaming and mildness inpersonal care products. The productis compatible with anionic, nonionicand cationic surfactants. Lowtemperature blending is allowedbecause of its low cloud point.

HAPPI, Household & Personal Products Industry,May 2005, 42 (5), 142-143

Further US concerns about possiblePFOA exposure

A nationwide campaign has beenlaunched by the United Steelworkersof America to determine whether itsmembers are being exposed toperfluorooctanoic acid (PFOA) andwhether this is causing any healthproblems. The particular focus of thesurvey is Zonyl, the PFOA fromDuPont [see also Focus onSurfactants, Jun 2003]. The EPA listsPFOA as a possible carcinogen andthere are links between exposure toPFOA and developmentalimpairment. The surfactant is used inpaper coating to give stain resistance.Food packaging is one of the uses ofsuch PFOA-treated paper. Becausecoatings are often premixed awayfrom the facilities where they areapplied, workers may not be awarethat the products they are handling

JULY 2005 3

F O C U S O N S U R F A C T A N T S