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Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

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Page 1: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive
Page 2: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Transporting Hazardous Materials by Rail

Railroads transport over 1.7 million hazardous material shipments in the US each year. Over 99.96% arrive without incident.

Page 3: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

YOU ARE NOT IN IT ALONE!

When emergencies occur, the railroads are there to help you handle the incident . . .

Transporting Hazardous Materials by Rail

Page 4: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Objectives

Provide knowledge and skills to help you respond to transportation emergencies involving anhydrous ammonia. Contacting the railroad Railroad resources Assessing the incident, using:

Rail shipping papers Markings

Identifying pressure tank cars for transporting anhydrous ammonia

Page 5: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Contacting the Railroad

When notified of a rail emergency: Contact the railroad using the railroad’s emergency phone number.Make sure the railroad knows about the emergency.Stop trains if necessary.

BNSF - 800-832-5452 Canadian National - 800-465-9239 Canadian Pacific - 800-716-9132 CSX Transportation - 800-232-0144 Kansas City Southern - 877-527-9464 Norfolk Southern - 800-453-2530 Union Pacific - 888-UPRR-COP (877-7267) CHEMTREC - 800-424-9300 CANUTEC - 613-996-6666 (collect)

Page 6: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Contacting the Railroad

Crossing Sign Information Ownership Emergency telephone number Crossing ID number Milepost location

Page 7: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Contacting the Railroad

Upon arrival, if at railroad crossing: Contact railroad emergency center

immediately. Give the location of emergency using

information printed on signal bungalows or signs at the crossing.

Page 8: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Contacting the Railroad

Upon arrival, if between rail crossings: Look for railroad mileposts in all

directions. Give the railroad emergency center

your location using the closest rail milepost number in addition to any other location information.

If you have GPS, provide your coordinates to the railroad emergency center.

Page 9: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Railroad Resources

Railroad Emergency Center Stay in contact with the

emergency center - you are their eyes and ears.

They are staffed 24 hrs/day. They make reports/calls to

CHEMTREC®, National Response Center and shippers.

They make mandatory notifications to state and federal agencies.

Page 10: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

HARDIN, MONTANA

Railroad Resources

Geographic Information System - GIS Railroad emergency centers may

have detailed GIS Maps include data on pipelines,

infrastructure, soil types, streams, waterways, environmentally sensitive areas, schools, hospitals, etc.

Railroads share this information about handling the incident.

Page 11: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Railroad Resources

Plume Modeling Railroad contractors can provide

air dispersion modeling capabilities which are made available to you by fax or email.

Page 12: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Railroad Resources

On-scene railroad personnel Transportation, mechanical and

engineering personnel. Railroad hazardous materials

response personnel, police and environmental personnel.

Re-railing contractors. Environmental contractors. These railroad personnel will

coordinate with the Incident Commander and responders.

Page 13: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Assessing the Emergency

Size-up carefully - know what you are dealing with.Seek out railroad personnel; ask them about the situation.Get shipping papers from the railroad personnel.Using binoculars from a safe location, look for visible leaks - vapors or liquids.Pay attention to the weather conditions and find out how they may change during the emergency.

Page 14: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Shipping Papers

Get the shipping papers Find the train crew - the conductor

is responsible for the shipping papers and has the most complete copy on-scene.

Ask the crew to share the shipping papers with you and help interpret the information provided.

If the train crew is not available, contact the railroad and ask them to fax or email a copy of the shipping papers or read the information over the phone or radio.

Page 15: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Shipping Papers

Shipping papers are the primary safety instrument at a rail emergency.

Shipping papers provide: Location of each HM shipment in a trainDescription of contents of each HM shipmentEmergency response information for each HM

11 UTLX 95248 LT19 NFGAS HO754 ICG PUEB AMOS IN ZAP COOL

60-MPH 126-TONS 51-FT 1-P 1.00-BRK 1585-ATONS 1068-AFT

RAIL SECURITY SENSITIVE MATERIAL FLAT YARD - DO NOT KICK 1/TC, 150000 LB************************* UN1005* DANGEROUS * AMMONIA, ANHYDROUS ************************* 2.2EMERGENCY CONTACT: RQ (AMMONIA) 1-800-424-9300 INHALATION HAZARD TN=(ANHYDROUS AMMONIA) SHIPPER CONTACT CHEMTREC

HAZMAT STCC = 4904210  12 PROX 33205 LT32 APOISN OW409 38-751-55 WULA HEDGES WA AGRIUM GAM      

60-MPH 128-TONS 68-FT 1-P 1.00-BRK 648-ATONS 305-AFT

RAIL SECURITY SENSITIVE MATERIAL                              

FLAT YARD - DO NOT KICK                                        

1/TC, 72590/KG                          

*************************               UN1005                                  

* DANGEROUS             *               ANHYDROUS AMMONIA                      

*************************               2.3  (8  )                              

EMERGENCY CONTACT:                      RQ (AMMONIA)                            

  8007928311                            POISON-INHALATION HAZARD                

                                        ZONE D                                  

                                        ERP 2-1451                              

                                          8007928311                            

                                        AGRIUM PARTNERSHIP                      

                                        16KM E OF GIBBONS AB ON H              

                                        REDWATER OPERATIONS                    

                                        BEAMER           AB T0A2W              

                                        SHIPPER CONTACT                        

                                          AGRIUM                                

                                        HAZMAT STCC = 4920359                  

Page 16: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Shipping Papers

Key information for each hazardous material on the train: Line number Emergency contact number Reporting marks (initials) and number Shipping description entries

19 UTLX 95248 LT19 NFGAS HO754 ICG PUEB AMOS IN ZAP COOL 60-MPH 126-TONS 51-FT 1-P 1.00-BRK 1585-ATONS 1068-AFT RAIL SECURITY SENSITIVE MATERIAL FLAT YARD - DO NOT KICK 1/TC, 150000 LB************************* UN1005* DANGEROUS * AMMONIA, ANHYDROUS ************************* 2.2EMERGENCY CONTACT: RQ (AMMONIA) 1-800-424-9300 INHALATION HAZARD TN=(ANHYDROUS AMMONIA) SHIPPER CONTACT CHEMTREC HAZMAT STCC = 4904210

Page 17: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Shipping Papers

Train List - “Cars Listed from Rear of Train”

Page 18: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Shipping Papers

Shipping description entries - United States

1/TC, 150000/LB************************* UN1005* DANGEROUS * AMMONIA, ANHYDROUS ************************* 2.2EMERGENCY CONTACT: RQ (AMMONIA) 1-800-424-9300 INHALATION HAZARD TN=(ANHYDROUS AMMONIA) SHIPPER CONTACT CHEMTREC HAZMAT STCC = 4904210

Page 19: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Shipping Papers

Shipping description entries - Canada

1/TC, 72590/KG          *************************               UN1005      * DANGEROUS             *               ANHYDROUS AMMONIA    *************************               2.3  (8  )EMERGENCY CONTACT:                      RQ (AMMONIA)  8007928311                            POISON-INHALATION HAZARD                                        ZONE D                                         ERP 2-1451                                                 8007928311                                          AGRIUM PARTNERSHIP                                        16KM E OF GIBBONS AB ON H                                        REDWATER OPERATIONS                                         BEAMER           AB T0A2W                                         SHIPPER CONTACT                                            AGRIUM                                                      HAZMAT STCC = 4920359    

Page 20: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Shipping Papers

Shipping description entries - residue/empty shipments of anhydrous ammonia

1/TC************************* UN1005* DANGEROUS * RESIDUE: LAST CONTAINED************************* AMMONIA, ANHYDROUSEMERGENCY CONTACT: 2.2 1-800-424-9300 RQ (AMMONIA) INHALATION HAZARD TN=(ANHYDROUS AMMONIA) SHIPPER CONTACT CHEMTREC HAZMAT STCC = 4904210

Page 21: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Shipping Papers

Emergency Response Information

COMMODITY NUMBER IS 4904210                 AMMONIA, ANHYDROUS <OR> AMMONIA             SOLUTIONS                                   DIVISION 2.2 (NONFLAMMABLE GAS)             UN1005                                      ENVIRONMENTALLY HAZARDOUS SUBSTANCE  (RQ-100/45.4)                          ANHYDROUS AMMONIA IS A CLEAR COLORLESS GAS WITH A CHARACTERISTIC ODOR.  IT  WILL BURN UNDER EXTREME FIRE CONDITIONS IN CONFINED AREAS.  IT IS SHIPPED AS  A LIQUID UNDER PRESSURE.  IT IS SOLUBLE IN WATER FORMING A CORROSIVE LIQUID.  ALTHOUGH AMMONIA VAPORS ARE LIGHTER THAN AIR, THE VAPORS FROM A LEAK          INITIALLY HUG THE GROUND.  IT WEIGHS 6 LBS./GAL.  LONG TERM EXPOSURE TO LOW   CONCENTRATIONS OR SHORT TERM EXPOSURE TO HIGH CONCENTRATIONS CAN RESULT IN    ADVERSE HEALTH EFFECTS FROM INHALATION.  UNDER PROLONGED EXPOSURE TO FIRE OR  INTENSE HEAT THE CONTAINERS MAY RUPTURE VIOLENTLY AND ROCKET.  IT IS USED AS  A FERTILIZER, AS A REFRIGERANT, AND IN THE MANUFACTURE OF OTHER CHEMICALS.                                                                                  IF MATERIAL ON FIRE OR INVOLVED IN FIRE                                         SOLID STREAMS OF WATER MAY BE INEFFECTIVE                                     EXTINGUISH FIRE USING AGENT SUITABLE FOR TYPE OF SURROUNDING FIRE               (MATERIAL ITSELF DOES NOT BURN OR BURNS WITH DIFFICULTY.)                   COOL ALL AFFECTED CONTAINERS WITH FLOODING QUANTITIES OF WATER                APPLY WATER FROM AS FAR A DISTANCE AS POSSIBLE           

Page 22: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Placards

Shipments within the United States

U.S. Nonflammable Gas placard

1/TC, 150000/LB ************************* UN1005 * DANGEROUS * AMMONIA, ANHYDROUS ************************* 2.2 EMERGENCY CONTACT: RQ (AMMONIA) 1-800-424-9300 INHALATION HAZARD TN=(ANHYDROUS AMMONIA) SHIPPER CONTACT CHEMTREC HAZMAT STCC = 4904210

Page 23: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Placards

Canadian shipments - in Canada or to/from the United States

1/TC, 72590/KG            *************************           UN1005      * DANGEROUS             *           ANHYDROUS AMMONIA    *************************           2.3  (8  )EMERGENCY CONTACT:                  RQ (AMMONIA)  8007928311                        POISON-INHALATION HAZARD                                    ZONE D                                     ERP 2-1451                                             8007928311                                      AGRIUM PARTNERSHIP                                    16KM E OF GIBBONS AB ON H                                    REDWATER OPERATIONS                                     BEAMER           AB T0A2W                                     SHIPPER CONTACT                                        AGRIUM                                                  HAZMAT STCC = 4920359    

Canadian placard for Anhydrous Ammonia

Page 24: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Tank Cars for Anhydrous Ammonia

Pressure tank car – typically DOT/TC Class 105s and 112s (specifications 105S340W, 105J300 W, and 112J340W)

Steel tank (minimum 11/16” thick)

Top mounted fittings within a protective housing

Page 25: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Tank Cars for Anhydrous Ammonia

Tank Car Safety Systems

“Top and Bottom Shelf” couplers

- aka “Double-shelf couplers

(coupler vertical restraint systems).

Page 26: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Tank Cars for Anhydrous Ammonia

Tank Car Safety Systems

“Top and Bottom Shelf” couplers

- aka “Double-shelf couplers

(coupler vertical restraint systems).

Head shields (tank head puncture-resistance systems).

Page 27: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Tank Cars for Anhydrous Ammonia

Tank Car Safety Systems

“Top and Bottom Shelf” couplers

- aka “Double-shelf couplers

(coupler vertical restraint systems).

Head shields (tank head puncture-resistance systems).

Thermal protection (thermal protection systems - fire).

Page 28: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Tank Cars for Anhydrous Ammonia

Thermal Protection Performance

Will not lose any lading due to effects of heat (except through the pressure relief device) for:

- 100 minutes in pool fire

- 30 minutes in torch fire

Page 29: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Tank Cars for Anhydrous Ammonia

Tank Car Service Equipment(valves and fittings)

Liquid eduction lines (2) Vapor eduction line (1) Pressure relief valve (spring

loaded)(1) Gauging device (closed

type)(1) Sample line (1) Thermometer well (1)

Ball typePlug type angle valve

Page 30: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Tank Cars for Anhydrous Ammonia

Tank Car Markings

Placards and markings Specification mark Test date qualification Commodity name Inhalation hazard mark

Page 31: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Damage Assessment

Utilize railroad responders to determine damage; they are trained to assess damage to tank cars and other rail equipment.

Page 32: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Jacket damage - not leaking.

Damage Assessment

Page 33: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive

Remember, you are NOT out there alone.Railroad response personnel are on their way to help.

Questions

Contacting the railroad Railroad resources Assessing the incident, using:

Rail shipping papers Markings

Tank cars for transporting anhydrous ammonia

Page 34: Transporting Hazardous Materials by Rail u Railroads transport over 1.7 million hazardous material shipments in the US each year. u Over 99.96% arrive