35
290 Elwood Davis Road, Suite 230 Liverpool, New York 13088 Phone 315.453.9009 Fax 315.453.9010 www.anchorqea.com Three Rivers System – Summary of 2009 Data Overview Map and Sample Summary Table Three full water quality surveys were conducted on July 9 th , August 12 st and September 24 th , 2009. Three additional surveys were conducted only at Buoy 316 on July 30 th , August 27 th and September 16 th . In addition, YSI data sondes were deployed between June and October 2009 to measure in-situ water quality parameters (e.g., dissolved oxygen, pH, salinity, and temperature) at 15-minute intervals. Seneca River Hydrograph and Flow Summary Table Flow conditions in the Seneca River in 2009 exhibited a pattern of relatively higher and more variable flows in spring and relatively lower flows in summer. Compared to the past two years the summer flow conditions were more variable, with flows ranging between 2,000 and 6,000 cfs and relatively short low flow periods at the beginning of August and throughout the month of September. The average summer flow rate in 2009 was approximately 1,600 cfs, which is comparable with the long- term summer average of 1,700 cfs, but higher than what might be considered a summer low flow condition (7Q10 flow is estimated at 350 cfs). In 2009 there were just two days below the 7Q10 flow rate. Spatial Plots of Water Quality Parameters The Seneca River water column appeared to be vertically well-mixed during the July 9 th (3,350 cfs) and the August 12 th (5,090 cfs) surveys, but exhibited stratification in water quality parameters during the September 24 th (783 cfs) survey, especially between the Onondaga Lake outlet and the Three River Junction. Generally in 2009 the spatial trends of the water quality parameters were consistent with those measured under similar flow conditions in previous years (e.g., 2008 and 2006). However, the patterns in 2009 were generally less pronounced than those observed in lower flow years (e.g., 2007). A summary of the spatial trends in 2009 water quality is as follows: o Between Cross Lake and the Onondaga Lake outlet: Library Reference 9.1

Three Rivers System – Summary of 2009 Datastatic.ongov.net/WEP/wepdf/2009_AMP-FINAL/Library/09_SenecaRiver... · Three Rivers System – Summary of 2009 Data ... - Chlorophyll-a

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290 Elwood Davis Road, Suite 230 Liverpool, New York 13088

Phone 315.453.9009 Fax 315.453.9010

www.anchorqea.com

Three Rivers System – Summary of 2009 Data Overview Map and Sample Summary Table

• Three full water quality surveys were conducted on July 9th, August 12st and September 24th, 2009. Three additional surveys were conducted only at Buoy 316 on July 30th, August 27th and September 16th. In addition, YSI data sondes were deployed between June and October 2009 to measure in-situ water quality parameters (e.g., dissolved oxygen, pH, salinity, and temperature) at 15-minute intervals.

Seneca River Hydrograph and Flow Summary Table

• Flow conditions in the Seneca River in 2009 exhibited a pattern of relatively higher and more variable flows in spring and relatively lower flows in summer. Compared to the past two years the summer flow conditions were more variable, with flows ranging between 2,000 and 6,000 cfs and relatively short low flow periods at the beginning of August and throughout the month of September. The average summer flow rate in 2009 was approximately 1,600 cfs, which is comparable with the long-term summer average of 1,700 cfs, but higher than what might be considered a summer low flow condition (7Q10 flow is estimated at 350 cfs). In 2009 there were just two days below the 7Q10 flow rate.

Spatial Plots of Water Quality Parameters • The Seneca River water column appeared to be vertically well-mixed during the July

9th (3,350 cfs) and the August 12th (5,090 cfs) surveys, but exhibited stratification in water quality parameters during the September 24th (783 cfs) survey, especially between the Onondaga Lake outlet and the Three River Junction.

• Generally in 2009 the spatial trends of the water quality parameters were consistent with those measured under similar flow conditions in previous years (e.g., 2008 and 2006). However, the patterns in 2009 were generally less pronounced than those observed in lower flow years (e.g., 2007). A summary of the spatial trends in 2009 water quality is as follows:

o Between Cross Lake and the Onondaga Lake outlet:

Library Reference 9.1

2009 AMP Report June 15, 2010

Page 2

- Soluble reactive phosphorus (SRP) concentrations increased gradually while Chlorophyll-a concentrations exhibited a notable decrease due to zebra mussel activities.

- Chlorophyll-a data at Buoy-409 in the September river survey exhibited relatively high Chlorophyll-a concentrations (up to about 55 μg/L) in the vicinity of the Cross Lake, which decreased to below 30 μg/L at the Onondaga Lake outlet.

- Dissolved oxygen (DO) concentrations during the July and August surveys were similar in the top and the bottom layers; DO decreased steadily across the area by a total of 2 - 3 mg/L as a result of zebra mussel respiration and sediment oxygen demand. During the September survey, the DO data indicated stratified conditions in the river with concentrations being higher within the surface waters than the bottom waters throughout the reach between Cross Lake (surface higher by 2 mg/L) and the Onondaga Lake Outlet (surface higher by 3 mg/L).

- Ammonia-N (NH3-N), nitrate (NO3-N) and nitrite (NO2-N) concentrations exhibited little change, with only a slight increase of NH3-N, likely due to zebra mussel activities.

o Between the Onondaga Lake outlet and the Three Rivers Junction: - SRP concentrations remained relatively constant in the surface waters

as a result of the balancing of algal production with filtration of the remaining algae by zebra mussels, as well as mixing with deeper waters and Onondaga Lake inflows. During the September survey, a slight increase in SRP was observed, suggesting a greater influence by zebra mussel activities during that time. The top and bottom SRP concentrations were similar during the July and August surveys but the bottom SRP concentrations were higher than the top SRP during the September survey. A similar situation occurred during the low flow survey in September of 2007 – in both instances the SRP depletion in the top water was also accompanied by an increase in DO and Chlorophyll-a concentrations, suggesting that this trend is a result of phytoplankton activity.

2009 AMP Report June 15, 2010

Page 3

- Consistent with past years, stratification downstream of the lake outlet was observed for salinity, DO, and to a much lesser extent for temperature, but most noticeably during the September survey. These observations can be explained by the influx of Onondaga Lake water, oxygen demand associated with sediments and zebra mussel activity, limited vertical mixing, and potential inflow of groundwater in the area of the “Deep Hole”.

- NH3-N concentrations exhibited little change during the July and August surveys and a slight stratification during the September survey, with higher concentrations in the bottom waters, which was likely due to the lower river flow conditions and possibly flux from sediments and/or zebra mussel activity.

- NO2-N concentrations exhibited little change in this reach of the river, with the exception of a slight increase in the bottom waters during the September survey (similar to NH3-N, but less pronounced).

- Increased concentrations in NO3-N resulting from lake water inflow were observed in all three surveys, although during the September survey, NO3-N exhibited the most prominent increase, including a strong vertical stratification with high bottom layer concentrations (up to 1.7 mgN/L) just downstream of the outlet. The stratification was due to the relatively high bottom concentration waters that entered the river from the lake and the limited vertical mixing in the area of the “Deep Hole”. In all surveys the NO3-N concentrations increased toward the Three Rivers Junction as a result of increased vertical mixing.

YSI Sonde Figure

Temporal trends in the high frequency DO data recorded by the YSI sondes exhibited some stratification at Buoy 409, with several periods of low concentrations (in the upper waters and more so in the bottom waters), with relatively large diurnal variations as compared to the other sampling locations. Compared to 2008, the daily DO concentrations at Buoy 409 were similar in the top waters and slightly higher in the bottom waters, with a greater swing in the daily minimum and maximum DO values. Similar to 2008, DO data at Buoys 316 and 236 showed less stratification and

2009 AMP Report June 15, 2010

Page 4

less day-to-day variability. Note that the DO concentrations at Buoy 236 were higher at the bottom water than at the top water during the first half of July. The reason for this oxygenated bottom water is uncertain; however, the large DO increase (from 1.4 to 15.3 mg/L) in the bottom water on July 3rd 2009 may suggest an equipment failure.

Seneca River Compliance and Sonde Compliance Tables

• From the routine water quality surveys, the data showed two violations of the NYSDEC instantaneous minimum DO standard (4 mg/L) for both the top and bottom waters at Buoy 316 during the August 27th survey. There were no observed violations of the NH3-N or NO2 standards.

• In 2009, DO standard violations were observed in the 15-minute in-situ data collected by the YSI sondes. For days in which the sondes were in operation, one or more of the measured DO levels at either the top or the bottom layer were below the daily instantaneous standard of 4 mg/L on 26%, 19% and 19% of those days at Buoys 409, 316, and 236, respectively. Likewise, daily averages calculated from the DO measurements made by the sondes at either the top or the bottom layer were below the daily average standard of 5 mg/L on 14%, 24% and 21% of the days in which the sondes were operated at Buoys 409, 316, and 236, respectively. Similar to previous years, these violations were more prevalent in the bottom waters than in the upper waters. However, compared to previous lower flow years, these data represent an improvement in water quality conditions (e.g., the frequency of violations was much higher during the low flow conditions observed in 2007).

2009 AMP Report June 15, 2010

Page 5

Three Rivers System – 2009 Major Findings

• The water quality data collected in 2009 during the three full river surveys were generally similar to data collected in previous years. The data measured during the individual surveys were reflective of the predominant processes occurring in the river at that time of the year, including flow conditions, zebra mussel activities and inflow from Onondaga Lake and subsequent mixing.

• The average summer flow rate in 2009 was comparable to the long-term summer average, but it was much higher than what might be considered summer low flow conditions. As a result, the spatial trends of water quality parameters during the July and August surveys were similar in top and bottom waters and were overall less pronounced than those typically observed under lower flow conditions. Spatial trends observed during the September survey indicated stratified flow conditions and were consistent with trends observed during low flow surveys conducted in previous years.

• When compared with previous lower flow years (e.g., 2007) the water quality conditions in 2009 exhibited an improvement in terms of regulatory compliance.

Jacks Reef

Syracuse

Baldwinsville

Phoenix

Brewerton

State Ditch Cut

Three Rivers

OSWEGO

SENECA

ONEIDA

OSWEG

O R

OX

CR

SE

NE

CA

R

SE

NE

CA

R

ONEIDA R

ON

ON

DA

GA L

CROSS L

NIN

EM

ILE C

R

ONEIDA L

CAUGHDENOY DAM

OSWEGO CANAL LOCK O-1

PHEONIX DAM

LOCK 24 ERIE CANAL

BALDWINSVILLE DAM

SAWMILL CR

BLOODY BROOK

LEY CR

ONONDAGA CR

HARBOR BROOK

TRIBUTARY 5A

EAST FLUME

JORDAN WPCP METROPOLITAN SYRACUSE WWTP

WETZEL ROAD WWTP

PHOENIX WWTP

OAK ORCHARD STP

ERIE CANAL

LOCK 23

LO2 LO1

Buoy 10

Buoy 409

Buoy 397

Buoy 362 Buoy 334

Buoy 316

Buoy 294

Buoy 269

Buoy 260

Buoy 255

Buoy 222

Buoy 212 Buoy 182

LO3

Buoy 412

Buoy 178

Buoy 240

BREWERTON

WPCP

BALDWINSVILLE

SENECA KNOLLS

WWTP

ANHEUSER

BUSCH INC

Buoy 236

June 2010090582-01

Overview of AMP River

Sampling Locations within

the Three Rivers System

LEGEND

SCALE

LOCATORTo Lock O-7 in Oswego

1 0 1 2 30.5 Miles

AMP Sampling Locations

YSI Sonde Locations

Wastewater Treatment Plants

Locks and Dams

Cities / Towns

USGS Gages

Shoreline

Watershed Boundaries

H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\Fig1__study_area_withFigNum1.mxd ; IF, CP

Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec0

2000

4000

6000

8000

10000

US

GS

Flo

w R

ate

at B

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(cfs

)

Seneca River

Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov DecMonth

0

2000

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6000

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GS

Flo

w R

ate

at E

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fs)

Oneida River

Temporal plot of USGS flows at Seneca River and Oneida River as well as days that AMP river surveys were conducted during 2009.

Note: Points represent OCDWEP water quality sampling dates.

IF - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\Figures\River_Appendix\Fig2_QEA7__p_hydrograph.proThu May 20 12:57:10 2010

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0

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6

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12

14D

O-f

ield

(m

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CrossLake

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OnondagaLake Outlet

Three RiversJunction

DO-field

3350 cfs 7/ 9/09

Seneca River

Oneida River

Oswego River

Onondaga Lake Outlet

Minimum Daily Average Standard

Instantaneous Minimum Standard

Spatial profiles of dissolved oxygen collected from the Three Rivers System during 2009.Notes: (1)River km measured from Three Rivers Junction, upstream (-) for Seneca and Oneida /downstream (+) for Oswego; (2)Open symbols represent surface samples, filled symbols represent bottom samples, gray circles represent mid-depth samples, and open symbols with dots represent composite samples; (3)Baldwinsville flow on sampling dates shown in each panel.

IF - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_2_11__spatial_by_parameter.proTue Jun 08 17:37:56 2010

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5090 cfs 8/12/09

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0

2

4

6

8

10

12

14

DO

-fie

ld (

mg/

L)

783 cfs 9/24/09

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0.0

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0.8

1.0N

H3-

N (

mgN

/L)

CrossLake

BaldwinsvilleDam

OnondagaLake Outlet

Three RiversJunction

NH3-N

3350 cfs 7/ 9/09

Seneca River

Oneida River

Oswego River

Onondaga Lake Outlet

Spatial profiles of ammonia collected from the Three Rivers System during 2009.Notes: (1)River km measured from Three Rivers Junction, upstream (-) for Seneca and Oneida /downstream (+) for Oswego; (2)Open symbols represent surface samples, filled symbols represent bottom samples, gray circles represent mid-depth samples, and open symbols with dots represent composite samples; (3)Baldwinsville flow on sampling dates shown in each panel.

IF - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_2_11__spatial_by_parameter.proTue Jun 08 17:37:56 2010

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)

5090 cfs 8/12/09

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0.0

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0.4

0.6

0.8

1.0

NH

3-N

(m

gN/L

)

783 cfs 9/24/09

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0.00

0.05

0.10

0.15

0.20N

O2

(m

gN/L

)

CrossLake

BaldwinsvilleDam

OnondagaLake Outlet

Three RiversJunction

NO2

3350 cfs 7/ 9/09

Seneca River

Oneida River

Oswego River

Onondaga Lake Outlet

Spatial profiles of nitrite collected from the Three Rivers System during 2009.Notes: (1)River km measured from Three Rivers Junction, upstream (-) for Seneca and Oneida /downstream (+) for Oswego; (2)Open symbols represent surface samples, filled symbols represent bottom samples, gray circles represent mid-depth samples, and open symbols with dots represent composite samples; (3)Baldwinsville flow on sampling dates shown in each panel.

IF - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_2_11__spatial_by_parameter.proTue Jun 08 17:37:56 2010

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0.10

0.15

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2 (

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5090 cfs 8/12/09

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0.00

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0.10

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0.20

NO

2 (

mgN

/L)

783 cfs 9/24/09

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0.0

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1.0

1.5

2.0N

O3

(m

gN/L

)

CrossLake

BaldwinsvilleDam

OnondagaLake Outlet

Three RiversJunction

NO3

^2.04^

2.04

3350 cfs 7/ 9/09

Seneca River

Oneida River

Oswego River

Onondaga Lake Outlet

Spatial profiles of nitrate collected from the Three Rivers System during 2009.Notes: (1)River km measured from Three Rivers Junction, upstream (-) for Seneca and Oneida /downstream (+) for Oswego; (2)Open symbols represent surface samples, filled symbols represent bottom samples, gray circles represent mid-depth samples, and open symbols with dots represent composite samples; (3)Baldwinsville flow on sampling dates shown in each panel.

IF - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_2_11__spatial_by_parameter.proTue Jun 08 17:37:56 2010

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0.0

0.5

1.0

1.5

2.0

NO

3 (

mgN

/L)

^2.19^

2.19

5090 cfs 8/12/09

-40 -30 -20 -10 0 10Distance from Three Rivers Junction (km)

0.0

0.5

1.0

1.5

2.0

NO

3 (

mgN

/L)

783 cfs 9/24/09

-40 -30 -20 -10 0 10

0.0

0.2

0.4

0.6

0.8

1.0

1.2

1.4T

KN

(m

gN/L

)

CrossLake

BaldwinsvilleDam

OnondagaLake Outlet

Three RiversJunction

TKN

3350 cfs 7/ 9/09

Seneca River

Oneida River

Oswego River

Onondaga Lake Outlet

Spatial profiles of TKN collected from the Three Rivers System during 2009.Notes: (1)River km measured from Three Rivers Junction, upstream (-) for Seneca and Oneida /downstream (+) for Oswego; (2)Open symbols represent surface samples, filled symbols represent bottom samples, gray circles represent mid-depth samples, and open symbols with dots represent composite samples; (3)Baldwinsville flow on sampling dates shown in each panel.

IF - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_2_11__spatial_by_parameter.proTue Jun 08 17:37:56 2010

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0.0

0.2

0.4

0.6

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1.2

1.4

TK

N (

mgN

/L)

5090 cfs 8/12/09

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0.0

0.2

0.4

0.6

0.8

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1.2

1.4

TK

N (

mgN

/L)

783 cfs 9/24/09

-40 -30 -20 -10 0 10

0.0

0.2

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0.6

0.8

1.0

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KN

-F (

mgN

/L)

CrossLake

BaldwinsvilleDam

OnondagaLake Outlet

Three RiversJunction

TKN-F

3350 cfs 7/ 9/09

Seneca River

Oneida River

Oswego River

Onondaga Lake Outlet

Spatial profiles of TKN (filtered) collected from the Three Rivers System during 2009.Notes: (1)River km measured from Three Rivers Junction, upstream (-) for Seneca and Oneida /downstream (+) for Oswego; (2)Open symbols represent surface samples, filled symbols represent bottom samples, gray circles represent mid-depth samples, and open symbols with dots represent composite samples; (3)Baldwinsville flow on sampling dates shown in each panel.

IF - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_2_11__spatial_by_parameter.proTue Jun 08 17:37:56 2010

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5090 cfs 8/12/09

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0.2

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0.6

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TK

N-F

(m

gN/L

)

783 cfs 9/24/09

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0.0

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0.4

0.6

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1.0

1.2O

RG

-N (

mgN

/L)

CrossLake

BaldwinsvilleDam

OnondagaLake Outlet

Three RiversJunction

ORG-N

3350 cfs 7/ 9/09

Seneca River

Oneida River

Oswego River

Onondaga Lake Outlet

Spatial profiles of organic N collected from the Three Rivers System during 2009.Notes: (1)River km measured from Three Rivers Junction, upstream (-) for Seneca and Oneida /downstream (+) for Oswego; (2)Open symbols represent surface samples, filled symbols represent bottom samples, gray circles represent mid-depth samples, and open symbols with dots represent composite samples; (3)Baldwinsville flow on sampling dates shown in each panel.

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)

5090 cfs 8/12/09

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0.2

0.4

0.6

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OR

G-N

(m

gN/L

)

783 cfs 9/24/09

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0.00

0.02

0.04

0.06

0.08

0.10S

RP

(m

gP/L

)

CrossLake

BaldwinsvilleDam

OnondagaLake Outlet

Three RiversJunction

SRP

3350 cfs 7/ 9/09

Seneca River

Oneida River

Oswego River

Onondaga Lake Outlet

Spatial profiles of SRP collected from the Three Rivers System during 2009.Notes: (1)River km measured from Three Rivers Junction, upstream (-) for Seneca and Oneida /downstream (+) for Oswego; (2)Open symbols represent surface samples, filled symbols represent bottom samples, gray circles represent mid-depth samples, and open symbols with dots represent composite samples; (3)Baldwinsville flow on sampling dates shown in each panel.

IF - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_2_11__spatial_by_parameter.proTue Jun 08 17:37:57 2010

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SR

P (

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5090 cfs 8/12/09

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0.02

0.04

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0.08

0.10

SR

P (

mgP

/L)

783 cfs 9/24/09

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0.04

0.06

0.08

0.10

0.12

0.14T

P (

mgP

/L)

CrossLake

BaldwinsvilleDam

OnondagaLake Outlet

Three RiversJunction

TP

3350 cfs 7/ 9/09

Seneca River

Oneida River

Oswego River

Onondaga Lake Outlet

Spatial profiles of total P collected from the Three Rivers System during 2009.Notes: (1)River km measured from Three Rivers Junction, upstream (-) for Seneca and Oneida /downstream (+) for Oswego; (2)Open symbols represent surface samples, filled symbols represent bottom samples, gray circles represent mid-depth samples, and open symbols with dots represent composite samples; (3)Baldwinsville flow on sampling dates shown in each panel.

IF - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_2_11__spatial_by_parameter.proTue Jun 08 17:37:57 2010

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0.14

TP

(m

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)

5090 cfs 8/12/09

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0.00

0.02

0.04

0.06

0.08

0.10

0.12

0.14

TP

(m

gP/L

)

783 cfs 9/24/09

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0.00

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0.06

0.08

0.10

0.12T

DP

(m

gP/L

)

CrossLake

BaldwinsvilleDam

OnondagaLake Outlet

Three RiversJunction

TDP

3350 cfs 7/ 9/09

Seneca River

Oneida River

Oswego River

Onondaga Lake Outlet

Spatial profiles of total dissolved P collected from the Three Rivers System during 2009.Notes: (1)River km measured from Three Rivers Junction, upstream (-) for Seneca and Oneida /downstream (+) for Oswego; (2)Open symbols represent surface samples, filled symbols represent bottom samples, gray circles represent mid-depth samples, and open symbols with dots represent composite samples; (3)Baldwinsville flow on sampling dates shown in each panel.

IF - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_2_11__spatial_by_parameter.proTue Jun 08 17:37:57 2010

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TD

P (

mgP

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5090 cfs 8/12/09

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0.00

0.02

0.04

0.06

0.08

0.10

0.12

TD

P (

mgP

/L)

783 cfs 9/24/09

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3

4

5

6

7T

OC

(m

g/L)

CrossLake

BaldwinsvilleDam

OnondagaLake Outlet

Three RiversJunction

TOC

3350 cfs 7/ 9/09

Seneca River

Oneida River

Oswego River

Onondaga Lake Outlet

Spatial profiles of TOC collected from the Three Rivers System during 2009.Notes: (1)River km measured from Three Rivers Junction, upstream (-) for Seneca and Oneida /downstream (+) for Oswego; (2)Open symbols represent surface samples, filled symbols represent bottom samples, gray circles represent mid-depth samples, and open symbols with dots represent composite samples; (3)Baldwinsville flow on sampling dates shown in each panel.

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3

4

5

6

7

TO

C (

mg/

L)

5090 cfs 8/12/09

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3

4

5

6

7

TO

C (

mg/

L)

783 cfs 9/24/09

-40 -30 -20 -10 0 10

3

4

5

6

7T

OC

-F (

mg/

L)

CrossLake

BaldwinsvilleDam

OnondagaLake Outlet

Three RiversJunction

TOC-F

3350 cfs 7/ 9/09

Seneca River

Oneida River

Oswego River

Onondaga Lake Outlet

Spatial profiles of TOC (filtered) collected from the Three Rivers System during 2009.Notes: (1)River km measured from Three Rivers Junction, upstream (-) for Seneca and Oneida /downstream (+) for Oswego; (2)Open symbols represent surface samples, filled symbols represent bottom samples, gray circles represent mid-depth samples, and open symbols with dots represent composite samples; (3)Baldwinsville flow on sampling dates shown in each panel.

IF - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_2_11__spatial_by_parameter.proTue Jun 08 17:37:57 2010

-40 -30 -20 -10 0 10

3

4

5

6

7

TO

C-F

(m

g/L)

5090 cfs 8/12/09

-40 -30 -20 -10 0 10Distance from Three Rivers Junction (km)

3

4

5

6

7

TO

C-F

(m

g/L)

783 cfs 9/24/09

-40 -30 -20 -10 0 10

0

5

10

15

20

25

30T

SS

(m

g/L)

CrossLake

BaldwinsvilleDam

OnondagaLake Outlet

Three RiversJunction

TSS

3350 cfs 7/ 9/09

Seneca River

Oneida River

Oswego River

Onondaga Lake Outlet

Spatial profiles of TSS collected from the Three Rivers System during 2009.Notes: (1)River km measured from Three Rivers Junction, upstream (-) for Seneca and Oneida /downstream (+) for Oswego; (2)Open symbols represent surface samples, filled symbols represent bottom samples, gray circles represent mid-depth samples, and open symbols with dots represent composite samples; (3)Baldwinsville flow on sampling dates shown in each panel.

IF - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_2_11__spatial_by_parameter.proTue Jun 08 17:37:57 2010

-40 -30 -20 -10 0 10

0

5

10

15

20

25

30

TS

S (

mg/

L)

^31

5090 cfs 8/12/09

-40 -30 -20 -10 0 10Distance from Three Rivers Junction (km)

0

5

10

15

20

25

30

TS

S (

mg/

L)

783 cfs 9/24/09

-40 -30 -20 -10 0 10

0

5

10

15

20

25

30T

urbi

dity

(N

TU

)

CrossLake

BaldwinsvilleDam

OnondagaLake Outlet

Three RiversJunction

Turbidity

3350 cfs 7/ 9/09

Seneca River

Oneida River

Oswego River

Onondaga Lake Outlet

Spatial profiles of turbidity collected from the Three Rivers System during 2009.Notes: (1)River km measured from Three Rivers Junction, upstream (-) for Seneca and Oneida /downstream (+) for Oswego; (2)Open symbols represent surface samples, filled symbols represent bottom samples, gray circles represent mid-depth samples, and open symbols with dots represent composite samples; (3)Baldwinsville flow on sampling dates shown in each panel.

IF - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_2_11__spatial_by_parameter.proTue Jun 08 17:37:58 2010

-40 -30 -20 -10 0 10

0

5

10

15

20

25

30

Tur

bidi

ty (

NT

U)

5090 cfs 8/12/09

-40 -30 -20 -10 0 10Distance from Three Rivers Junction (km)

0

5

10

15

20

25

30

Tur

bidi

ty (

NT

U)

783 cfs 9/24/09

-40 -30 -20 -10 0 10

0.0

0.5

1.0

1.5

2.0S

alin

ity-f

ield

(pp

t)

CrossLake

BaldwinsvilleDam

OnondagaLake Outlet

Three RiversJunction

Salinity-field

3350 cfs 7/ 9/09

Seneca River

Oneida River

Oswego River

Onondaga Lake Outlet

Spatial profiles of salinity collected from the Three Rivers System during 2009.Notes: (1)River km measured from Three Rivers Junction, upstream (-) for Seneca and Oneida /downstream (+) for Oswego; (2)Open symbols represent surface samples, filled symbols represent bottom samples, gray circles represent mid-depth samples, and open symbols with dots represent composite samples; (3)Baldwinsville flow on sampling dates shown in each panel.

IF - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_2_11__spatial_by_parameter.proTue Jun 08 17:37:58 2010

-40 -30 -20 -10 0 10

0.0

0.5

1.0

1.5

2.0

Sal

inity

-fie

ld (

ppt)

5090 cfs 8/12/09

-40 -30 -20 -10 0 10Distance from Three Rivers Junction (km)

0.0

0.5

1.0

1.5

2.0

Sal

inity

-fie

ld (

ppt)

783 cfs 9/24/09

-40 -30 -20 -10 0 10

0

100

200

300

400

500

600C

hlor

ide

(m

g/L)

CrossLake

BaldwinsvilleDam

OnondagaLake Outlet

Three RiversJunction

Chloride

3350 cfs 7/ 9/09

Seneca River

Oneida River

Oswego River

Onondaga Lake Outlet

Spatial profiles of chloride collected from the Three Rivers System during 2009.Notes: (1)River km measured from Three Rivers Junction, upstream (-) for Seneca and Oneida /downstream (+) for Oswego; (2)Open symbols represent surface samples, filled symbols represent bottom samples, gray circles represent mid-depth samples, and open symbols with dots represent composite samples; (3)Baldwinsville flow on sampling dates shown in each panel.

IF - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_2_11__spatial_by_parameter.proTue Jun 08 17:37:58 2010

-40 -30 -20 -10 0 10

0

100

200

300

400

500

600

Chl

orid

e (

mg/

L)

5090 cfs 8/12/09

-40 -30 -20 -10 0 10Distance from Three Rivers Junction (km)

0

100

200

300

400

500

600

Chl

orid

e (

mg/

L)

783 cfs 9/24/09

-40 -30 -20 -10 0 10

0

10

20

30

40

50C

hlor

ophy

ll-a

(ug

/L)

CrossLake

BaldwinsvilleDam

OnondagaLake Outlet

Three RiversJunction

Chlorophyll-a

3350 cfs 7/ 9/09

Seneca River

Oneida River

Oswego River

Onondaga Lake Outlet

Spatial profiles of chlorophyll-a collected from the Three Rivers System during 2009.Notes: (1)River km measured from Three Rivers Junction, upstream (-) for Seneca and Oneida /downstream (+) for Oswego; (2)Open symbols represent surface samples, filled symbols represent bottom samples, gray circles represent mid-depth samples, and open symbols with dots represent composite samples; (3)Baldwinsville flow on sampling dates shown in each panel.

IF - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_2_11__spatial_by_parameter.proTue Jun 08 17:37:58 2010

-40 -30 -20 -10 0 10

0

10

20

30

40

50

Chl

orop

hyll-

a (

ug/L

)

5090 cfs 8/12/09

-40 -30 -20 -10 0 10Distance from Three Rivers Junction (km)

0

10

20

30

40

50

Chl

orop

hyll-

a (

ug/L

)

^53.4

^50.2

^56.6

783 cfs 9/24/09

-40 -30 -20 -10 0 10

0

5

10

15

20P

heop

hytin

-a (

ug/L

)

CrossLake

BaldwinsvilleDam

OnondagaLake Outlet

Three RiversJunction

Pheophytin-a

3350 cfs 7/ 9/09

Seneca River

Oneida River

Oswego River

Onondaga Lake Outlet

Spatial profiles of pheophytin-a collected from the Three Rivers System during 2009.Notes: (1)River km measured from Three Rivers Junction, upstream (-) for Seneca and Oneida /downstream (+) for Oswego; (2)Open symbols represent surface samples, filled symbols represent bottom samples, gray circles represent mid-depth samples, and open symbols with dots represent composite samples; (3)Baldwinsville flow on sampling dates shown in each panel.

IF - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_2_11__spatial_by_parameter.proTue Jun 08 17:37:58 2010

-40 -30 -20 -10 0 10

0

5

10

15

20

Phe

ophy

tin-a

(ug

/L)

5090 cfs 8/12/09

-40 -30 -20 -10 0 10Distance from Three Rivers Junction (km)

0

5

10

15

20

Phe

ophy

tin-a

(ug

/L)

783 cfs 9/24/09

-40 -30 -20 -10 0 10

16

18

20

22

24

26

28

30T

emp-

field

(D

eg.C

)

CrossLake

BaldwinsvilleDam

OnondagaLake Outlet

Three RiversJunction

Temp-field

3350 cfs 7/ 9/09

Seneca River

Oneida River

Oswego River

Onondaga Lake Outlet

Spatial profiles of temperature collected from the Three Rivers System during 2009.Notes: (1)River km measured from Three Rivers Junction, upstream (-) for Seneca and Oneida /downstream (+) for Oswego; (2)Open symbols represent surface samples, filled symbols represent bottom samples, gray circles represent mid-depth samples, and open symbols with dots represent composite samples; (3)Baldwinsville flow on sampling dates shown in each panel.

IF - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_2_11__spatial_by_parameter.proTue Jun 08 17:37:58 2010

-40 -30 -20 -10 0 10

16

18

20

22

24

26

28

30

Tem

p-fie

ld (

Deg

.C)

5090 cfs 8/12/09

-40 -30 -20 -10 0 10Distance from Three Rivers Junction (km)

16

18

20

22

24

26

28

30

Tem

p-fie

ld (

Deg

.C)

783 cfs 9/24/09

06/01 07/01 08/01 09/01 10/01 11/015

10

15

20

25

30te

mpe

ratu

re(D

egre

e C

)Buoy 409 Top

Daily Average Conc

Max/Min Conc

06/01 07/01 08/01 09/01 10/01 11/015

10

15

20

25

30

tem

pera

ture

(Deg

ree

C)

Buoy 316 Top

06/01 07/01 08/01 09/01 10/01 11/015

10

15

20

25

30

tem

pera

ture

(Deg

ree

C)

Buoy 236 Top

06/01 07/01 08/01 09/01 10/01 11/015

10

15

20

25

30

tem

pera

ture

(Deg

ree

C)

Buoy 409 Bottom

06/01 07/01 08/01 09/01 10/01 11/015

10

15

20

25

30te

mpe

ratu

re(D

egre

e C

)

Buoy 316 Bottom

06/01 07/01 08/01 09/01 10/01 11/015

10

15

20

25

30

tem

pera

ture

(Deg

ree

C)

Buoy 236 Bottom

Temporal profiles of daily average and variations of temperature recorded by YSI sondes at Buoys 409, 316 and 236 during 2009.

Notes: Results are only shown for days that at least half of the 15-minute instantaneous data were available.

if - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_12_16__p_3sonde.proWed Jun 09 13:12:39 2010

06/01 07/01 08/01 09/01 10/01 11/010.2

0.4

0.6

0.8

1.0sa

linity

(ppt

)Buoy 409 Top

Daily Average Conc

Max/Min Conc

06/01 07/01 08/01 09/01 10/01 11/010.2

0.4

0.6

0.8

1.0

salin

ity(p

pt)

Buoy 316 Top

06/01 07/01 08/01 09/01 10/01 11/010.2

0.4

0.6

0.8

1.0

salin

ity(p

pt)

Buoy 236 Top

^

06/01 07/01 08/01 09/01 10/01 11/010.2

0.4

0.6

0.8

1.0

salin

ity(p

pt)

Buoy 409 Bottom

^ 06/01 07/01 08/01 09/01 10/01 11/010.2

0.4

0.6

0.8

1.0sa

linity

(ppt

)

Buoy 316 Bottom

06/01 07/01 08/01 09/01 10/01 11/010.2

0.4

0.6

0.8

1.0

salin

ity(p

pt)

Buoy 236 Bottom

^

Temporal profiles of daily average and variations of salinity recorded by YSI sondes at Buoys 409, 316 and 236 during 2009.

Notes: Results are only shown for days that at least half of the 15-minute instantaneous data were available.

if - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_12_16__p_3sonde.proWed Jun 09 13:12:42 2010

06/01 07/01 08/01 09/01 10/01 11/010

5

10

15

20di

ssol

ved

oxyg

en(m

g/L)

Buoy 409 Top

Daily Average Conc

Max/Min Conc

Min Daily Average Std

Instantaneous Min Std

06/01 07/01 08/01 09/01 10/01 11/010

5

10

15

20

diss

olve

d ox

ygen

(mg/

L)

Buoy 316 Top

06/01 07/01 08/01 09/01 10/01 11/010

5

10

15

20

diss

olve

d ox

ygen

(mg/

L)

Buoy 236 Top

06/01 07/01 08/01 09/01 10/01 11/010

5

10

15

20

diss

olve

d ox

ygen

(mg/

L)

Buoy 409 Bottom

06/01 07/01 08/01 09/01 10/01 11/010

5

10

15

20di

ssol

ved

oxyg

en(m

g/L)

Buoy 316 Bottom

06/01 07/01 08/01 09/01 10/01 11/010

5

10

15

20

diss

olve

d ox

ygen

(mg/

L)

Buoy 236 Bottom

Temporal profiles of daily average and variations of dissolved oxygen recorded by YSI sondes at Buoys 409, 316 and 236 during 2009.

Notes: Results are only shown for days that at least half of the 15-minute instantaneous data were available.

if - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_12_16__p_3sonde.proWed Jun 09 13:12:44 2010

06/01 07/01 08/01 09/01 10/01 11/016.0

6.5

7.0

7.5

8.0

8.5

9.0

9.5pH

Buoy 409 Top

Daily Average Conc

Max/Min Conc

06/01 07/01 08/01 09/01 10/01 11/016.0

6.5

7.0

7.5

8.0

8.5

9.0

9.5

pH

Buoy 316 Top

06/01 07/01 08/01 09/01 10/01 11/016.0

6.5

7.0

7.5

8.0

8.5

9.0

9.5

pH

Buoy 236 Top

06/01 07/01 08/01 09/01 10/01 11/016.0

6.5

7.0

7.5

8.0

8.5

9.0

9.5

pH

Buoy 409 Bottom

06/01 07/01 08/01 09/01 10/01 11/016.0

6.5

7.0

7.5

8.0

8.5

9.0

9.5pH

Buoy 316 Bottom

06/01 07/01 08/01 09/01 10/01 11/016.0

6.5

7.0

7.5

8.0

8.5

9.0

9.5

pH

Buoy 236 Bottom

Temporal profiles of daily average and variations of pH recorded by YSI sondes at Buoys 409, 316 and 236 during 2009.

Notes: Results are only shown for days that at least half of the 15-minute instantaneous data were available.

if - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_12_16__p_3sonde.proWed Jun 09 13:12:47 2010

06/01 07/01 08/01 09/01 10/01 11/010

100

200

300

400ch

loro

phyl

l(u

g/L)

Buoy 409 Top̂̂

Daily Average Conc

Max/Min Conc

06/01 07/01 08/01 09/01 10/01 11/010

100

200

300

400

chlo

roph

yll

(ug/

L)

Buoy 409 Bottom^̂ ^ ^̂

06/01 07/01 08/01 09/01 10/01 11/010

100

200

300

400

chlo

roph

yll

(ug/

L)

Buoy 236 Top^

Temporal profiles of daily average and variations of chlorophyll recorded by YSI sondes at Buoys 409 and 236 during 2009 .

Notes: Results are only shown for days that at least half of the 15-minute instantaneous data were available.

if - H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\River_Appendix\FigA1_12_16__p_3sonde.proWed Jun 09 13:12:48 2010

Summary of Seneca River flow conditions between 2001 and 2009.

YearAverage summer flow rate

(cfs) Days below 7Q10 criteria

2001 800 0

2002842

7

20032028 0

20044518 0

20051052 8

20064607 3

2007774 4

20081497 0

20091606 2Notes:Summer"season"starts"on"

July"1 st "and"ends"on"September"31 st .

This indicates that the summer flow conditions in 2009 were moderate compared to past years.

IF,H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\Tables\Table0_yearlyFlows.xlsx

Summary of AMP r iver sampling locations and total numbers of samples collected in 2009.

Buoy Buoy 412 Buoy 409 Buoy 397 Buoy 362 Buoy 334 Buoy 316 Buoy 294 Buoy 269 Buoy 260 Buoy 255 Buoy 240 Buoy 222 Buoy 178 Buoy 182 Buoy 212 Buoy 10 LO1 LO2 LO3River Seneca Seneca Seneca Seneca Seneca Seneca Seneca Seneca Seneca Seneca Seneca Seneca Oneida Oneida Oneida Oswego Lake Outlet Lake Outlet Lake OutletKilometer1 -36.5 -35.4 -33.3 -26.9 -21.6 -18.4 -14.1 -10.1 -8.3 -6.4 -3.5 -0.4 -7.3 -6.7 -0.9 2.4 -11.7 -12.4 -11.4

DO-field 6 6 6 0 6 12 6 9 6 6 6 6 6 6 6 6 6 6 6Chlorophyll-a 6 6 6 0 6 24 6 6 6 6 6 6 6 6 6 6 6 6 6Pheophytin-a 6 6 6 0 6 24 6 6 6 6 6 6 6 6 6 6 6 6 6TOC 6 6 6 0 6 24 6 9 6 6 6 6 6 6 6 6 6 6 6TOC-F 6 6 6 0 6 24 6 9 6 6 6 6 6 6 6 6 6 6 6NH3-N 6 6 6 0 6 24 6 9 6 6 6 6 6 6 6 6 6 6 6NO2 6 6 6 0 6 24 6 9 6 6 6 6 6 6 6 6 6 6 6NO3 6 6 6 0 6 24 6 9 6 6 6 6 6 6 6 6 6 6 6ORG-N 6 6 6 0 6 24 6 9 6 6 6 6 6 6 6 6 6 6 6TKN 6 6 6 0 6 24 6 9 6 6 6 6 6 6 6 6 6 6 6TKN-F 6 6 6 0 6 24 6 9 6 6 6 6 6 6 6 6 6 6 6TP 6 6 6 0 6 24 6 9 6 6 6 6 6 6 6 6 6 6 6SRP 6 6 6 0 6 24 6 9 6 6 6 6 6 6 6 6 6 6 6TDP 6 6 6 0 6 24 6 9 6 6 6 6 6 6 6 6 6 6 6Chloride 6 6 6 0 6 24 6 9 6 6 6 6 6 6 6 6 6 6 6COND-field 6 6 6 0 6 12 6 9 6 6 6 6 6 6 6 6 6 6 6Salinity-field 6 6 6 0 6 12 4 6 4 4 4 4 6 6 6 6 4 4 4Temp-field 6 6 6 0 6 12 6 9 6 6 6 6 6 6 6 6 6 6 6pH-field 6 6 6 0 6 12 6 9 6 6 6 6 6 6 6 6 6 6 6Turbidity 6 6 6 0 6 24 6 9 6 6 6 6 6 6 6 6 6 6 6TSS 6 6 6 0 6 24 6 9 6 6 6 6 6 6 6 6 6 6 6

Note: 1 River kilometers measured from Three Rivers Junction, upstream (-) for Seneca and Oneida / downstream (+) for Oswego.

IF:/H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\Tables\Table1_Sample_summary.xlsx

Summary of non-compliances Dissolved Oxygen, Nitr ite and Total Ammonia in the Seneca River dur ing 2009.

Parameter Sampling Date Location Depth Value (mg/L)

8/27/2009 BUOY-316 BOTTOM 3.62

8/27/2009 BUOY-316 TOP 3.86

Parameter Sampling Date Location Depth Value (mgN/L)

NO2-N (Compliance Criteria = 0.1

mgN/L)None None None --

Total NH3 (NYSDEC Criteria

Calculated from pH and Temperature)

None None None --

Dissolved Oxygen (Instantaneous Compliance

Criteria = 4 mg/L)

IF:/H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\Tables\Table2_SenecaCompliance.xls

Summary of 15-minute dissolved oxygen (DO) data(1) collected by the YSI sondes in 2009.

DO < 5 mg/L DO < 4 mg/L

Star t End (days) (4) (days) (5)

Buoy 409 (Top) 141 3 9Buoy 409 (Bottom) 138 17 30Buoy 409 (Top or Bottom) 141 20 36Buoy 316 (Top) 157 17 14Buoy 316 (Bottom) 151 31 22Buoy 316 (Top or Bottom) 157 37 30Buoy 236 (Top) 136 16 8Buoy 236 (Bottom) 136 23 21Buoy 236 (Top or Bottom) 136 29 25Notes: `(1) Blank and negative DO values were excluded from analysis.

(2) Not all parameters may have been measured during the deployment dates.

(3) DO measured at least half of the time within one day.

(4) NYSDEC minimum daily average DO standard. Reported value represents number of days in which the daily average calculated from the 15-minute data

was below the standard.

(5) NYSDEC instantaneous minimum DO standard. Reported value represents the number of days in which one or more of the 15-minute readings was

below the standard.

Sonde LocationDeployment Dates (2)

Operation (days) (3)

6/19/2009 11/2/2009

5/28/2009 11/2/2009

6/17/2009 11/4/2009

IF:/H:\ONOamp\DOCUMENTS\Reports\2009_AMP_chapter\Tables\Table3_SondeCompliance .x lsx