28
Thermodynamic Property Relations CH2303 Chemical Engineering Thermodynamics I Unit – IV www.msubbu.in Dr. M. Subramanian Associate Professor Department of Chemical Engineering Sri Sivasubramaniya Nadar College of Engineering Kalavakkam – 603 110, Kanchipuram (Dist) Tamil Nadu, India msubbu.in[AT]gmail.com 12-Sep-2011 www.msubbu.in

Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

Embed Size (px)

Citation preview

Page 1: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

Thermodynamic Property Relations

CH2303 Chemical Engineering Thermodynamics I

Unit – IV

www.msubbu.in

Relations

Dr. M. Subramanian

Associate Professor

Department of Chemical Engineering

Sri Sivasubramaniya Nadar College of Engineering

Kalavakkam – 603 110, Kanchipuram (Dist)

Tamil Nadu, India

msubbu.in[AT]gmail.com

12-Sep-2011

www.msubbu.in

Page 2: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

Contents

• Measurable quantities, basic energy relations, Maxwell relations,

• Thermodynamic formulations to calculate enthalpy, internal energy and entropy as function of pressure and temperature,

• Other formulations involving Cp and Cv, complex thermodynamic • Other formulations involving Cp and Cv, complex thermodynamic formulations,

12-Sep-2011 M Subramanian

www.msubbu.in

Page 3: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

Mathematical Relations

12-Sep-2011 M Subramanian

www.msubbu.in

Page 4: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

12-Sep-2011 M Subramanian

www.msubbu.in

Page 5: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

12-Sep-2011 M Subramanian

www.msubbu.in

Page 6: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

12-Sep-2011 M Subramanian

www.msubbu.in

Page 7: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

12-Sep-2011 M Subramanian

www.msubbu.in

Page 8: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

12-Sep-2011 M Subramanian

www.msubbu.in

Page 9: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

12-Sep-2011 M Subramanian

www.msubbu.in

Page 10: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

12-Sep-2011 M Subramanian

www.msubbu.in

Page 11: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

12-Sep-2011 M Subramanian

www.msubbu.in

Page 12: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

12-Sep-2011 M Subramanian

www.msubbu.in

Page 13: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

Steam tables

13

12-Sep-2011 M Subramanian

www.msubbu.in

Page 14: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

14

12-Sep-2011 M Subramanian

www.msubbu.in

Page 15: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

12-Sep-2011 M Subramanian

www.msubbu.in

Page 16: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

12-Sep-2011 M Subramanian

www.msubbu.in

Page 17: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

12-Sep-2011 M Subramanian

www.msubbu.in

Page 18: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

www.msubbu.in

Page 19: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

12-Sep-2011 M Subramanian

www.msubbu.in

Page 20: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

12-Sep-2011 M Subramanian

www.msubbu.in

Page 21: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

www.msubbu.in

Page 22: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

www.msubbu.in

Page 23: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

12-Sep-2011 M Subramanian

www.msubbu.in

Page 24: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

Developing Thermodynamic Diagrams

TS Diagram

12-Sep-2011 M Subramanian

www.msubbu.in

Page 25: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

12-Sep-2011 M Subramanian

www.msubbu.in

Page 26: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

12-Sep-2011 M Subramanian

www.msubbu.in

Page 27: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

12-Sep-2011 M Subramanian

www.msubbu.in

Page 28: Thermodynamic Property Relations - msubbu.in · Thermodynamic Property Relations ... • Thermodynamic formulations to calculate enthalpy, internal ... Steam tables 13

12-Sep-2011 M Subramanian

www.msubbu.in