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The Role of Contact Mechanics on the Fretting Corrosion Performance of PEEK-Metal Taper Junctions STEPHANIE M. SMITH, JEREMY L. GILBERT CLEMSON-MUSC BIOENGINEERING PROGRAM CHARLESTON, SC 4 TH INTERNATIONAL PEEK MEETING APRIL 25, 2019

The Role of Contact Mechanics on the Fretting Corrosion ... · The Role of Contact Mechanics on the Fretting Corrosion Performance of PEEK-Metal Taper Junctions ... →Surface damage

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Page 1: The Role of Contact Mechanics on the Fretting Corrosion ... · The Role of Contact Mechanics on the Fretting Corrosion Performance of PEEK-Metal Taper Junctions ... →Surface damage

The Role of Contact Mechanics on the Fretting Corrosion Performance of PEEK-Metal Taper JunctionsSTEPHANIE M. SMITH, JEREMY L. GILBERTCLEMSON-MUSC BIOENGINEERING PROGRAMCHARLESTON, SC

4 TH I N T E R N AT I O N A L P E E K M E E T I N GA P R I L 2 5 , 2 0 1 9

Page 2: The Role of Contact Mechanics on the Fretting Corrosion ... · The Role of Contact Mechanics on the Fretting Corrosion Performance of PEEK-Metal Taper Junctions ... →Surface damage

Research support: Amedica, Bausch and Lomb, DePuy Synthes

Consulting: Zimmer Biomet, Smith and Nephew, Stryker, DePuy Synthes, Medtronic, Woven Medical, TAV Medical, Pfizer, Mirus, Omnilife Sciences, Bayer

Editor-in-Chief: Journal of Biomedical Materials Research – Part B: Applied Biomaterials

Council: Society for Biomaterials

Disclosures (Gilbert)

Page 3: The Role of Contact Mechanics on the Fretting Corrosion ... · The Role of Contact Mechanics on the Fretting Corrosion Performance of PEEK-Metal Taper Junctions ... →Surface damage

Introduction

http://friction.engr.wisc.edu/home/projects/wear-analysis-of-modular-hip-implants

Total joint replacement & modularityo in situ degradation of metal alloys

→ Mechanical factors + crevice geometries + biology = ???

FDA medical device databases (as of 2013):o >100 implant components ‘substantially equivalent’1

o 5 components recalled for material/design reasons2

→ How does implant design affect performance?

31. https://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfPMN/pmn.cfm2. https://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfres/res.cfm

Page 4: The Role of Contact Mechanics on the Fretting Corrosion ... · The Role of Contact Mechanics on the Fretting Corrosion Performance of PEEK-Metal Taper Junctions ... →Surface damage

→ Surface damage is mainly dictated by contact mechanics, friction & surrounding electrochemical environment

Fretting Corrosion

http://danieli.wikidot.com/2-failure-mechanisms-in-total-joint-and-dental-implants

4

Gilbert et al. (2015)

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Fretting & Contact Conditions3 fretting regimes: o Stick: minimal surface damageo Stick-slip: some wear, fatigueo Slip: severe surface damage

Contact conditions depend on:o Normal/tangential forceso Displacemento Frequencyo Environmento Geometry3

oMaterial/Lubrication3

stick stick-slip slip

Vingsbo, O., & Söderberg, S. (1988).

3. Jauch, S. Y., Huber, G., Haschke, H., Sellenschloh, K., & Morlock, M. M. (2014). Design parameters and the material coupling are decisive for the micromotion magnitude at the stem–neck interface of bi-modular hip implants. Medical engineering & physics, 36(3), 300-307. 5

Stick-slip

Slip

Sliding distance (μm)

Shea

r for

ce (N

)

Stick

Page 6: The Role of Contact Mechanics on the Fretting Corrosion ... · The Role of Contact Mechanics on the Fretting Corrosion Performance of PEEK-Metal Taper Junctions ... →Surface damage

Gilbert et al. (2015).

Stiffness is directly involved in seating mechanics4

Motivation: Taper Compliance/Stiffness

6

Unmodified Surface

Fretting Motion

= surface oxide= bulk metal

Compliant Pillars

Fretting MotionCompliant Interface

Stick-slip

Slip

Sliding distance (μm)

Shea

r for

ce (N

)

Stick

Stick-slip

Slip

Sliding distance (μm)

Stiff Interface

Shea

r for

ce (N

)

Stick

4. Ouellette, E. S., Shenoy, A. A., & Gilbert, J. L. (2018). The seating mechanics of head-neck modular tapers in vitro: Load-displacement measurements, moisture, and rate effects. Journal of Orthopaedic Research®, 36(4), 1164-1172.

Compliant Material (PEEK)

Goal: Evaluate PEEK’s ability to alter contact mechanics and minimize surface damage under simulated fretting corrosion conditions

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5. Swaminathan, V., & Gilbert, J. L. (2012). Fretting corrosion of CoCrMo and Ti6Al4V interfaces. Biomaterials, 33(22), 5487-5503.6. Ouellette, E. S., & Gilbert, J. L. (2016). Properties and corrosion performance of self-reinforced composite PEEK for proposed use as a

modular taper gasket. Clinical Orthopaedics and Related Research®, 474(11), 2414-2427.

Counterface Hardness & Oxide Film DisruptionCurrent research on hardness & wear performance under fretting corrosion conditions is conflictingLow-hardness materials may play role in preventing fretting corrosion damage5,6

7

δ

Fi

Ai

FN

Fs = µ FN

= !"#$

FN

FN = ΣFi

σ$ ≈F'A'

Assuming elastic-perfectly plastic material, pressure in each asperity is ≈ σ0

Page 8: The Role of Contact Mechanics on the Fretting Corrosion ... · The Role of Contact Mechanics on the Fretting Corrosion Performance of PEEK-Metal Taper Junctions ... →Surface damage

SRC-PEEK GasketsOuellette & Gilbert (2016): Properties and corrosion performance of self-reinforced composite PEEK for proposed use as a modular taper gasket 6

8

Ouellette (2016).

6. Ouellette, E. S., & Gilbert, J. L. (2016). Properties and corrosion performance of self-reinforced composite PEEK for proposed use as a modular taper gasket. Clinical Orthopaedics and Related Research®, 474(11), 2414-2427.

Page 9: The Role of Contact Mechanics on the Fretting Corrosion ... · The Role of Contact Mechanics on the Fretting Corrosion Performance of PEEK-Metal Taper Junctions ... →Surface damage

Approach: Pin on disk

9

Swaminathan, V., & Gilbert, J. L. (2012).

-50

50

150

250

350

0.E+00

4.E-04

8.E-04

1.E-03

0 10 20 30 40 50

Wor

k do

ne d

urin

g fr

ettin

g (N

.µm

)

Aver

age

fret

ting

curr

ent

dens

ity (A

/cm

2 )

Nominal normal stress (MPa)

-20

20

560 600 640Ft (

N)

Disp (µm)

3.4 N -20

20

580 600 620Ft (N

)

Disp (µm)

7.4 N

-20

0

20

580 600 620

Ft (N

)

Disp (µm)

9.5 N

-20

0

20

580 600 620Ft (N

)

Disp (µm)

15.6 N

- Current density- Work done during fretting

StickStick–slipSlip

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Approach: Pin on DiskSample set:4 alloy pin/disk combinations (n = 3)

a. PEEK (Victrex 381G)/ Ti6Al4Vb. PEEK (Victrex 381G) / CoCrMoc. Ti6Al4V / Ti6Al4V (control)d. CoCrMo / CoCrMo (control)

Procedure:1. Load-variable, potentiostatic pin-on-disk test• 0-50 N, 100 sec fretting per load, 100 sec recovery• 100 µm displacement, 1 Hz

2. Data collection:• mechanical (force, displacement, COF)• electrochemical (current)

3. Results (averages):• fretted contact area• current/current density• sticking force• fretting loops • pin, system k • contact stresses • work done per fretting cycle

10

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Results: Sticking Conditions

11

Stick-slip

Slip

Sliding distance (μm)

Shea

r for

ce (N

)

Stick

Experimental load-displacement path

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Results: Surface Damage

12

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Results: Coefficient of Friction

13

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Results: Work of Fretting

14

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Results: System Compliance

15

Stick-slip

Sliding distance (μm)

Shea

r for

ce (N

)

Stick

Slip

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Conclusions1. PEEK couples cause significantly lower sticking forces under typical fretting corrosion conditions

→ PEEK dominates behavior regardless of alloy

2. Decreased sticking forces do cause less surface damage via lower fretting currents3. PEEK caused minimal alloy surface damage even under full slip conditions

→ Likely due to its compliance, hardness, COF, high-performance properties

16

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Acknowledgements

17

Gilbert Lab

Hansjörg Wyss

Steve Kurtz

Hannah Spece

Page 18: The Role of Contact Mechanics on the Fretting Corrosion ... · The Role of Contact Mechanics on the Fretting Corrosion Performance of PEEK-Metal Taper Junctions ... →Surface damage

The Role of Contact Mechanics on the Fretting Corrosion Performance of PEEK-Metal Taper JunctionsSTEPHANIE M. SMITH, JEREMY L. GILBERTCLEMSON-MUSC BIOENGINEERING PROGRAMCHARLESTON, SC

4 TH I N T E R N AT I O N A L P E E K M E E T I N GA P R I L 2 5 , 2 0 1 9