TEST REPORTen3img.allhaving.com/upload/3256/download/1/pdf/7_3_certificates... · SUMMARY OF TEST RESULTS TEST REQUESTED CONCLUSION REMARK Overall Migration Test for Plastic Materials

TEST REPORT

LAB NO. : (9314)161-1245 DATE : Jun 24, 2014

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RW

Bureau Veritas Consumer Products Services (Guangzhou)

Co.,Ltd

No. 183, Shinan Road, Meilin Plaza Block B, Dongchong, Panyu,

Guangzhou, Guangdong Province, China 511453

Tel: (86) 20 2290 2088 Fax:(86) 20 3490 9303

Email: [email protected] Website:cps.bureauveritas.com

This report is governed by, and incorporates by reference, the Conditions of Testing as posted at the date of issuance of this report at http://www.mtl-acts.com and is intended for your exclusive use. Any copying or replication of this report to or for any other person or entity, or use of our name or trademark, is permitted only with our prior written permission. This report sets forth our findings solely with respect to the test samples identified herein. The results set forth in this report are not indicative or representative of the quality or characteristics of the lot from which a test sample was taken or any similar or identical product unless specifically and expressly noted. Our report includes all of the tests requested by you and the results thereof based upon the information that you provided to us. You have 60 days from date of issuance of this report to notify us of any material error or omission caused by our negligence, provided, however, that such notice shall be in writing and shall specifically address the issue you wish to raise. A failure to raise such issue within the prescribed time shall constitute your unqualified acceptance of the completeness of this report, the tests conducted and the correctness of the report contents.

APPLICANT : ZHONGSHAN DONLIM WEILI ELECTRICAL APPLIANCES CO., LTD FUSHA INDUSTRIAL PARK, FUSHA TOWN, ZHONGSHAN CITY, GUANGDONG

CONTACT PERSON : Jianli Yang DATE OF SUBMISSION : Jun 10, 2014 TEST PERIOD : Jun 10, 2014 to Jun 24, 2014 NO. OF WORKING DAYS : 10 SAMPLE DESCRIPTION : ICE MAKER Color: / Style No.: ICM-1201, ICM-1202, ICM-1203 P.O. No.: / Country of Origin: / Country of Destination: / MANUFACTURER : /

LAB NO. : (9314)161-1245 DATE : Jun 24, 2014

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SUMMARY OF TEST RESULTS TEST REQUESTED CONCLUSION REMARK

Overall Migration Test for Plastic Materials in Contact with Foodstuffs – Commission Regulation (EU) No. 10/2011 and Its Amendments

PASS

Phthalate Content for Plastic Materials in Contact with Foodstuffs – Commission Regulation (EU) No. 10/2011 and Its Amendments

PASS

Specific Migration of Phthalate for Plastic Materials in Contact with Foodstuffs – Commission Regulation (EU) No. 10/2011 and Its Amendments

PASS

Specific Migration of Heavy Metals for Plastic Materials in Contact with Foodstuffs – Commission Regulation (EU) No. 10/2011 and Its Amendments

PASS

Peroxides Value for Plastic Materials in Contact with Foodstuffs – § 30 and 31 LFGB and BfR Recommendation

PASS

Volatile Organic Matter Content for Plastic Materials in Contact with Foodstuffs – § 30 and 31 LFGB and BfR Recommendation

PASS

Isocyanates Residue Content for Materials in Contact with Foodstuffs – Commission Regulation (EU) No. 10/2011 and Its Amendments

PASS

Total Zinc and Boron Content for Plastic Materials in Contact with Foodstuffs - § 30 and 31 LFGB and BfR Recommendation

PASS

Extractable Matter Content for Silicon in Contact with Foodstuffs – § 30 and 31 LFGB and BfR Recommendation

PASS

Sensory Test (Odour and Taste) for Materials in Contact with Foodstuffs – EC No. 1935/2004 and § 30 and 31 LFGB and BfR Recommendation

PASS

Specific Migration of 1,3-Butadiene for Plastic Materials in Contact with Foodstuffs – Commission Regulation (EU) No. 10/2011 and Its Amendments

PASS

Specific Migration of Primary Aromatic Amines for Materials in Contact with Foodstuffs – § 30 and 31 LFGB, BfR Recommendation, Commission Regulation (EU) No. 10/2011 and Its Amendments

PASS

Extractable Heavy Metals Contents for Metal in Contact with Foodstuffs

DATA

LAB NO. : (9314)161-1245 DATE : Jun 24, 2014

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BUREAU VERITAS CONSUMER PRODUCTS SERVICES (GUANGZHOU) CO., LTD

CHARLES WONG

ANALYTICAL LAB MANAG ER

REMARK If there are questions or concerns on this report, please contact the following persons:

a) GENERAL TEL: (86)755 83437287 FAX: (86)755 83439100 b) BUSINESS SZ TEL: (86)755 21534695 FAX: (86)755 83439100 BUSINESS GZ TEL: (86) 20 83809765 FAX: (86) 20 83278793 EMAIL: [email protected] WEBSITE cps.bureauveritas.cn

LAB NO. : (9314)161-1245 DATE : Jun 24, 2014

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Photo of the Submitted Sample

LAB NO. : (9314)161-1245 DATE : Jun 24, 2014

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TEST RESULT Materials in Contact with Foodstuffs – § 30 and 31 LFGB

Test Item Description Client Claimed Material 1 White plastic ABS 2 Silvery metal Stainless metal 3 Transparent plastic (Tube) PU 4 Translucent plastic (Pump) POM 5 Translucent soft plastic (Tube) silicone 6 Silvery metal (Tube) - 7 Completed article-ice maker -

*Overall Migration Test for Plastic Materials in Contact with Foodstuffs – Commission Regulation (EU) No. 10/2011 and Its Amendments Test Condition: Distilled water: 5 oC, 10days

Result Simulant Used Unit

1 3 4 Maximum

Allowable Limit Analytical Tolerance

Distilled water mg/dm2 <5 <5 <5 10 +2 Conclusion - PASS PASS PASS - -

Note: “<” = less than

mg/dm2 = milligram per square decimetre mg/kg = milligram per kilogram

Method: EN 1186-1: 2002

Remark: 1) The migration test is carried out according to EC Regulation No. 10/2011 and the corresponding

regulatory statutes. 2）Selected test(s) was/were specified by client.

LAB NO. : (9314)161-1245 DATE : Jun 24, 2014

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TEST RESULT *Phthalate Content for Plastic Materials in Contact with Foodstuffs – Commission Regulation (EU) No. 10/2011 and Its Amendments

Result Parameter Unit 1 3 4

Maximum Allowable Limit

Butyl benzyl phthalate (BBP) % <0.005 <0.005 <0.005 0.1 Dibutyl phthalate (DBP) % <0.005 <0.005 <0.005 0.05

Di-2-ethylhexyl phthalate (DEHP) % <0.005 <0.005 <0.005 0.1 Di-iso-decyl phthalate (DIDP) % <0.005 <0.005 <0.005 0.1 Di-iso-nonyl phthalate (DINP) % <0.005 <0.005 <0.005 0.1

Conclusion - PASS PASS PASS - Note: “<” = less than Method: Solvent extraction and analysis by Gas Chromatograph Mass Spectrometer (GC-MS) or Liquid

Chromatograph Mass Spectrometer (LC-MS). Remark: Selected test(s) was/were specified by client. *Specific Migration of Phthalate for Plastic Materials in Contact with Foodstuffs – Commission Regulation (EU) No. 10/2011 and Its Amendments Test Condition: Distilled water: 5 oC, 10 days

Result

Parameter Simulant Used Unit 1 3 4 Maximum Allowable

Limit Butyl benzyl phthalate (BBP) Distilled water mg/kg <0.3 <0.3 <0.3 30 Dibutyl phthalate (DBP) Distilled water mg/kg <0.3 <0.3 <0.3 0.3 Di-2-ethylhexyl phthalate (DEHP) Distilled water mg/kg <0.3 <0.3 <0.3 1.5 Di-iso-decyl phthalate (DIDP) and Di-iso-nonyl phthalate (DINP)

Distilled water mg/kg <0.6 <0.6 <0.6

9

Conclusion - - PASS PASS PASS - Note: “<” = less than mg/kg = milligram per kilogram Method: EN 13130-1: 2004 and analysis by Liquid Chromatograph Mass Spectrometer (LC-MS). Remark: 1) The migration test is carried out according to EC Regulation No. 10/2011 and the corresponding


LAB NO. : (9314)161-1245 DATE : Jun 24, 2014

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TEST RESULT *Specific Migration of Heavy Metals for Plastic Materials in Contact with Foodstuffs – Commission Regulation (EU) No. 10/2011 and Its Amendments Test Condition: Distilled water: 5 oC, 10 days

Result Parameter Simulant

Used Unit 1 3 4

Maximum Allowable

Limit Barium (Ba) Distilled water mg/kg <0.1 <0.1 <0.1 1 Cobalt (Co) Distilled water mg/kg <0.005 <0.005 <0.005 0.05 Copper (Cu) Distilled water mg/kg <0.5 <0.5 <0.5 5 Iron (Fe) Distilled water mg/kg <5 <5 <5 48

Lithium (Li) Distilled water mg/kg <0.1 <0.1 <0.1 0.6 Manganese (Mn) Distilled water mg/kg <0.1 <0.1 <0.1 0.6

Zinc (Zn) Distilled water mg/kg <3 <3 <3 25 Conclusion - - PASS PASS PASS -

Note: “<” = less than mg/kg = milligram per kilogram Method: EN 13130-1: 2004 and analysis by Inductively Coupled Argon Plasma Spectrometer (ICP). Remark: 1) The migration test is carried out according to EC Regulation No. 10/2011 and the corresponding


*Peroxides Value for Plastic Materials in Contact with Foodstuffs – § 30 and 31 LFGB and BfR Recommendation

Result Parameter 1 3 5


Peroxides Absent Absent Absent Absent Conclusion PASS PASS PASS -

Method: European Pharmacopeia 5.0, Ph. Eur. Method 2.5.5. Remark: The limit refers to BfR Recommendation VI.

Selected test(s) was/were specified by client.

LAB NO. : (9314)161-1245 DATE : Jun 24, 2014

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TEST RESULT *Volatile Organic Matter Content for Plastic Materi als in Contact with Foodstuffs – § 30 and 31 LFGB and BfR Recommendation

Result Parameter Unit 1


Volatile Organic Matter mg/dm2 0.75 15 Conclusion - PASS -

Note: “<” = less than mg/dm2 = milligram per square decimetre Method: Gravimetric method. Remark: The limit refers to BfR Recommendation VI.




Volatile Organic Matter % w/w 0.00295 0.5 Conclusion - PASS -

Note: “<” = less than % w/w = percent weight by weight Method: Gravimetric method. Remark: The limit refers to BfR Recommendation XV.


LAB NO. : (9314)161-1245 DATE : Jun 24, 2014

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TEST RESULT *Isocyanates Residue Content for Materials in Contact with Foodstuffs – Commission Regulation (EU) No. 10/2011 and Its Amendments



Isocyanates mg/kg as

NCO <0.1 1 (Total)

Conclusion - PASS - Note: “<” = less than mg/kg = milligram per kilogram NCO = isocyanate moiety Method: EN 13130-8:2004 modified. Remark: The list of isocyanates is summarized in table.


List of Isocyanates:

No. Name of Analytes CAS-No. No. Name of Analytes CAS-No.

1 2,4 Toluene diisocyanate 584-84-9 5 Hexamethylene diisocyanate 822-06-0

2 2,6 Toluene diisocyanate 91-08-7 6 Cyclohexyl isocyanate 3173-53-3

3 Diphenylmethane-2,4’-diisocyanate 5873-54-1 7 1,5-naphthalene diisocyanate 3173-72-6

4 Diphenylmethane-4,4’-diisocyanate 101-68-8 8 Phenyl isocyanate 103-71-9

*Total Zinc and Boron Content for Plastic Materials in Contact with Foodstuffs - § 30 and 31 LFGB and BfR Recommendation



Total Boron (B) % w/w 0.001 0.008 Total Zinc (Zn) % w/w 0.279 1 Conclusion - PASS -

Note: “<” = less than Method: Acid digestion and analysis by Inductively Coupled Argon Plasma Spectrometer (ICP). Remark: The limit refers to BfR Recommendation XXXIII.


LAB NO. : (9314)161-1245 DATE : Jun 24, 2014

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TEST RESULT

*Extractable Matter Content for Silicon in Contact with Foodstuffs – § 30 and 31 LFGB and BfR Recommendation



Extractable Matter % w/w 0.05 0.5 Conclusion - PASS -

Note: “<” = less than % w/w = percent weight by weight Method: Gravimetric method after reflux for 5 hours with water. Remark: The limit refers to BfR Recommendation XV.

Selected test(s) was/were specified by client. *Sensory Test (Odour and Taste) for Materials in Contact with Foodstuffs – EC No. 1935/2004 and § 30 and 31 LFGB and BfR Recommendation

Result Parameter

7 Maximum Allowable Limit

Odour 1 2.5 Scale Taste transfer into foodstuff through

simulant, Mineral water 1 2.5 Scale

Conclusion PASS - Note: Scale: 0 = no perceptible off-odour (or taste transfer);

1 = off-odour (or taste transfer) just perceptible (but still difficult to define); 2 = slight off-odour (or taste transfer); 3 = distinct off-odour (or taste transfer); 4 = strong off-odour (or taste transfer)

Method: DIN 10955: 2004-06

LAB NO. : (9314)161-1245 DATE : Jun 24, 2014

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TEST RESULT *Specific Migration of 1,3-Butadiene for Plastic Materials in Contact with Foodstuffs – Commission Regulation (EU) No. 10/2011 and Its Amendments Test Condition: Distilled waterl: 5 oC, 10 days

Result Parameter Simulant Used Unit

1 Maximum Allowable

Limit 1,3-Butadiene Distilled water mg/kg <0.01 Not Detected(<0.01) Conclusion - - PASS -

Note: “<” = less than mg/kg = milligram per kilogram Method: EN 13130-1: 2004 and EN 13130-15:2005. Remark: The migration test is carried out according to EC Regulation No. 10/2011 and the corresponding regulatory

statutes. *Specific Migration of Primary Aromatic Amines for Materials in Contact with Foodstuffs – § 30 and 31 LFGB, BfR Recommendation, Commission Regulation (EU) No. 10/2011 and Its Amendments Test Condition: Distilled waterl: 5 oC, 10 days

Result Parameter

Simulant Used

Unit 3


Primary Aromatic Amine Distilled water mg/kg <0.01 0.01 Conclusion - - PASS -

Note: “<” = less than mg/kg = milligram per kilogram Method: EN 13130-1:2004, LC-MS/ LC-MS/MS analysis. Remark: The limit refers to BfR Recommendation XXXIX

LAB NO. : (9314)161-1245 DATE : Jun 24, 2014

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TEST RESULT Extractable Heavy Metals Contents for Metal in Contact with Foodstuffs Test Condition: Artificial tap water: 5 oC, 10 days Migration Ratio: 600 ml/0.5 dm2

Result 6 Parameter Unit

1st Migrate Aluminum (Al) mg/kg <0.1 Antimony (Sb) mg/kg <0.004 Chromium (Cr) mg/kg <0.1 Cobalt (Co) mg/kg <0.005 Copper (Cu) mg/kg <0.5 Iron (Fe) mg/kg <5 Magnesium (Mg) mg/kg 1.5 Manganese (Mn) mg/kg <0.1 Molybdenum (Mo) mg/kg <0.01 Nickel (Ni) mg/kg <0.02 Silver (Ag) mg/kg <0.01 Tin (Sn) mg/kg <5 Titanium (Ti) mg/kg <0.5 Vanadium (V) mg/kg <0.002 Zinc (Zn) mg/kg <1 Arsenic (As) mg/kg 0.001 Barium (Ba) mg/kg <0.1 Beryllium (Be) mg/kg <0.001 Cadmium (Cd) mg/kg <0.001 Lead (Pb) mg/kg <0.002 Lithium (Li) mg/kg <0.01 Mercury (Hg) mg/kg <0.0004 Thallium (Tl) mg/kg <0.00005

Conclusion - -

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Test Condition: Artificial tap water: 5 oC, 10 days Migration Ratio: 125 ml/0.125 dm2

Result *2 Parameter Unit

1st Migrate Aluminum (Al) mg/kg <0.1 Antimony (Sb) mg/kg <0.004 Chromium (Cr) mg/kg <0.1 Cobalt (Co) mg/kg <0.005 Copper (Cu) mg/kg <0.5 Iron (Fe) mg/kg <5 Magnesium (Mg) mg/kg 0.7 Manganese (Mn) mg/kg <0.1 Molybdenum (Mo) mg/kg <0.01 Nickel (Ni) mg/kg <0.02 Silver (Ag) mg/kg <0.01 Tin (Sn) mg/kg <5 Titanium (Ti) mg/kg <0.5 Vanadium (V) mg/kg <0.002 Zinc (Zn) mg/kg <1 Arsenic (As) mg/kg <0.001 Barium (Ba) mg/kg <0.1 Beryllium (Be) mg/kg <0.001 Cadmium (Cd) mg/kg <0.001 Lead (Pb) mg/kg <0.002 Lithium (Li) mg/kg <0.01 Mercury (Hg) mg/kg <0.0004 Thallium (Tl) mg/kg <0.00005

Conclusion - - Note: “<” = less than

mg/kg = milligram per kilogram

Method: With reference to Metals and Alloys used in Food Contact Materials and articles - A Practical Guide to Manufacturers and Regulators (2013 1st Edition) published by European Directorate for the Quality of Medicines and HealthCare (EDQM), Chapter 3.

Remark: 1) Appropriate test condition(s) was (were) selected according to Guidelines on Testing Conditions for Articles in Contact with Foodstuffs (With a Focus on Kitchenware) (2009 1st Edition) published by European Commission Joint Research Center (JRC).

2) Artificial tap water was prepared according to German Standard DIN 10531: 2011-06. 3) By client request, the migration test of article intended for repeated use is conducted as a single

determination only which is deviate from the underlying regulations. 4）Selected test(s) was/were specified by client.

Comment: “*”The above results were transferred from (9314)136-1292 dated on Jun 20, 2014.

END

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TEST REPORTen3img.allhaving.com/upload/3256/download/1/pdf/7_3_certificates... · SUMMARY OF TEST RESULTS TEST REQUESTED CONCLUSION REMARK Overall Migration Test for Plastic Materials