TEST REPORT: 17.42278R2static.benettongroup.com/wp-content/uploads/2018/03/TiFAS.pdf · TEST REPORT: 17.42278R2 This report cancels and replaces the previous one (17.42278) issued

TEST REPORT: 17.42278R2

This report cancels and replaces the previous one (17.42278) issued on 13/10/2017

Page 1 of 2

*17.42278R1*17.42278R2

This report is composed by 3 pages, of which: 2 pages for the summary 1 page for the Report 17.42278R2a APPLICANT Ti.F.A.S. spa

LAB NO: (IT) 17.42278R2

Corso Italia 43 DATE IN: 15/09/2017 20025 Legnano (MI) DATE OUT: 29/09/2017 DATE REVISION: 2/11/2017 PAGES: 2

Facility: Ti.F.A.S. spa Corso Italia 43 20025 Legnano (MI)

Sample Description:

INCOMING WATER Date and hour of sampling: 15/09/2017 – h 12:00 Sampling location: Sampling point colour room Sampling method: Single grab as requested by the final client Burberry Sampling by: UL In-charge Technician Sampling Record N°: GITA15092017-1

TEST PERFORMED CONCLUSIONS

Metals Not Detected

NOTE ON REVISED 1: We revised this report in order to update the grid, as requested by the Client. NOTE ON REVISED 2: We revised this report to change the applicant as requested by the client.

Chemical Laboratory Supervisor Claudio Sironi

REMARKS 1. It is prohibited the partial reproduction, any changes or modifications of this test

report. The results are exclusively referred to the samples tested.

Issue date:Test beginning:

DATES APPLICANT

Ti.F.A.S. spa

TEST REPORT: 17.42278R2a Rev. No.: 2 dated 2 November 2017

18 Sep 201729 Sep 2017

This section is an integral part of the TEST REPORT 17.42278R2

T F A RD

17.42278R2a

This report cancels and replaces the previous one (17.42278R1) issued on 26/10/17.

INCOMING WATER - TI.F.A.S. SPA CORSO ITALIA 43 20025 LEGNANO (MI)SAMPLE DESCRIPTION (no. 371950)

52024

Identification Parts Compound

Metals

Instrument: Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) and Inductively Coupled Plasma with Mass Detector (ICP-MS)

Method: According to ISO17294-2 (2016) and ISO 11885 (2007)

PbCdHgSbAsCoCuNiZnCrAg

< 0,01< 0,01

< 0,001< 0,01

< 0,005< 0,01< 0,25< 0,05

< 0,5< 0,05

< 0,005

Incoming water

The results are expressed in mg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit of quantification(LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to ISO17294-2 (2016) and ISO 11885 (2007) Metals

Note:

page 1 of 1MD Standard Report CH_v5/14 ••• END OF REPORT •••

TEST REPORT: 17.42279R2

This report cancels and replaces the previous one (17.42279R1) issued on 13/10/2017

Page 1 of 2

*17.42279R1* 17.42279R2

This report is composed by 18 pages, of which: 2 pages for the summary 16 pages for the Report 17.42279R1a APPLICANT Ti.F.A.S. spa

LAB NO: (IT) 17.42279R1

Corso Italia 43 DATE IN: 15/09/2017 20025 Legnano (MI) DATE OUT: 29/09/2017 DATE REVISION: 2/11/2017 PAGES: 2

Facility: Ti.F.A.S. spa Corso Italia 43 20025 Legnano (MI)

Sample Description:

RAW WASTEWATER Date and hour of sampling: 15/09/2017 – h 11:00 Sampling location: Sampling point technical lamination room Sampling method: Single grab as requested by the final client Burberry Sampling by: UL In-charge Technician Sampling Record N°: GITA15092017-1

TEST REPORT: 17.42279R2 dated 2/11/2017 This report cancels and replaces the previous one (17.42279R1) issued on 13/10/2017

Page 2 of 2

TEST PERFORMED CONCLUSIONS Alkylphenol and Alkylphenol ethoxylates (AP / APEOs) Not Detected

Chlorinated Benzenes and Toluenes Not Detected

Chlorophenols Not Detected

Azo-dyes Not Detected

Colourants - Carcinogenic Not Detected

Colourants – Disperse Not Detected

Flame Retardants Not Detected

Glycols Not Detected

Halogenated solvents Not Detected

Organotin compounds Not Detected

Perfluorinated compounds (PFCs) Not Detected

Phthalates Not Detected

Polycyclic aromatic hydrocarbons Not Detected

Organic Volatile compounds Not Detected

Metals Detected

Cr (VI) - Hexavalent Chromium Not Detected

Cyanide Not Detected NOTE ON REVISED 1: We revised this report in order to update the grid, as requested by the Client. NOTE ON REVISED 2: We revised this report to change the applicant as requested by the Client. Chemical Laboratory Supervisor Claudio Sironi

REMARKS 1. It is prohibited the partial reproduction, any changes or modifications of this test

report. The results are exclusively referred to the samples tested.

Issue date:18 Sep 2017

201729 Sep 2017

Test beginning:

DATES APPLICANT

Ti.F.A.S. spa


T F A RD

This section is an integral part of the TEST REPORT 17.42279R2

17.42279R2a


Cr VIIdentification Parts

RAW WASTEWATER - TI.F.A.S. SPA CORSO ITALIA 43 20025 LEGNANO (MI)

SAMPLE DESCRIPTION (no. 370654)

Cr (VI) - Hexavalent Chromium

Method: According to USEPA 218.6

Instrument: Ion Cromatograph coupled with MS/UV detector

Raw wastewater < 0,001

The results expressed are in mg/L.The symbol < followed by a number indicates that the concentration of the substance is lower than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to USEPA 218.6 Chromium (VI) - Hexavalent Chromium

Note:

page 1 of 16MD Standard Report CH_v5/14

CyanideIdentification Parts

TEST REPORT: 17.42279R2a Rev. No.: 2 dated 2 Nov 2017

Cyanide

Method: ISO 6703-1:1984

Instrument: UV-Visible Spectrophotometer

T F A RD

52040


Raw wastewater < 0,05

The results expressed are in mg/L.The symbol < followed by a number indicates that the concentration of the substance is less than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference:

According to APAT CNR IRSA 4070 MAN 29 2003 Cyanide

Note:


Identification Parts Result

52000


Chlorobenzenes and Chlorotoluenes

Method: According to USEPA 8260B, 8270D

Instrument: Gaschromatograph with Mass detector

T F A RD


Monochlorobenzene1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene1,2,3-trichlorobenzene1,2,4-trichlorobenzene1,3,5-trichlorobenzene1,2,3,4-tetrachlorobenzene1,2,3,5-tetrachlorobenzene1,2,4,5-tetrachlorobenzenePentachlorobenzeneHexachlorobenzene2-chlorotoluene3-chlorotoluene4-chlorotoluene2,3-dichlorotoluene2,4-dichlorotoluene2,5-dichlorotoluene2,6-dichlorotoluene3,4-dichlorotoluene3,5-dichlorotoluene2,3,4-trichlorotoluene2,3,6-trichlorotoluene2,4,5-trichlorotoluene2,4,6-trichlorotoluene3,4,5-trichlorotoluene2,3,4,5-tetrachlorotoluene2,3,5,6-tetrachlorotoluene2,3,4,6-tetrachlorotoluenePentachlorotoluene

108-90-795-50-1541-73-1106-46-787-61-6120-82-1108-70-3634-66-2634-90-295-94-3608-93-5118-74-195-49-8108-41-8106-43-432768-54-095-73-819398-61-9118-69-495-75-025186-47-47359-72-02077-46-56639-30-123749-65-721472-86-676057-12-029733-70-8875-40-1877-11-2

< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2

Raw wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the substance is lower than the limit ofquantification (LOQ)

Legend:

Determination of organic substancesRequirements:


Note:


Identification Parts Results

52001


Chlorophenols

Method: According to USEPA 8270D

Instrument: Gas Chromatograph with Mass Detector (MS)

T F A RD


2-Chlorophenol3-Chlorophenol4-Chlorophenol2,3-Dichlorophenol2,4-Dichlorophenol2,5-Dichlorophenol2,6-Dichlorophenol3,4-Dichlorophenol3,5-Dichlorophenol2,3,4-Trichlorophenol2,3,5-Trichlorophenol2,3,6-Trichlorophenol2,4,5-Trichlorophenol2,4,6-Trichlorophenol3,4,5-Trichlorophenol2,3,4,5-Tetrachlorophenol2,3,4,6-Tetrachlorophenol2,3,5,6-TetrachlorophenolPentachlorophenol

95-57-8108-43-0106-48-9576-24-9120-83-2583-78-887-65-095-77-2591-35-515950-66-0933-78-8933-75-595-95-488-06-2609-19-84901-51-358-90-2935-95-587-86-5

< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5

Raw wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to USEPA 8270D ChlorophenolsRequirements:


Note:


Identification Parts

52002


Dyes - Azo

Method: According to EN ISO 14362-1:2017 , EN ISO 14362-3:2017

Instrument: Liquid chromatograph with Mass selective detector (HPLC -MS); Gas chromatograph with Mas selective detector (GC -MS).

T F A RD


4,4’-methylene-bis-(2-chloro-aniline)4,4’-methylenedianiline4,4’-oxydianiline4-chloroaniline3,3’-dimethoxylbenzidine3,3’-dimethylbenzidine6-methoxy-m-toluidine2,4,5-trimethylaniline4,4’-thiodianiline4-aminoazobenzene4-methoxy-m-phenylenediamine4,4’-methylene-di-o-toluidine2,6-xylidineo-anisidine2-naphthylamine3,3’-dichlorobenzidine4-aminodiphenylBenzidineo-toluidine2,4-xylidine4-chloro-o-toluidine4-methyl-m-phenylenediamineo-aminoazotoluene5-nitro-o-toluidine

101-14-4101-77-9101-80-4106-47-8119-90-4119-93-7120-71-8137-17-7139-65-160-09-3615-05-4838-88-087-62-790-04-091-59-891-94-192-67-192-87-595-53-495-68-195-69-295-80-797-56-399-55-8

< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1

Raw wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration for every Aromatic Amines detected (See listbelow) is lower than the limit of quantification (LOQ).

Legend:

According to EN ISO 14362-1:2017 , EN ISO 14362-3:2017 Dyes - AzoRequirements:


Note:



52003


Alkylphenol and Alkylphenol Ethoxylates

Method: According to ISO 18857-2 and ISO 18254-1

Instrument: H.P.L.C.with DAD/MSD detectors and Gaschromatograph with mass detector (GC-MS)

T F A RD


Nonylphenol (NP)

Octylphenol (OP)

Octylphenol ethoxylates, (OPEO)

Nonylphenol ethoxylates(NPEO)

104-40-511066-49-225154-52-384852-15-3140-66-91806-26-427193-28-89002-93-19036-19-568987-90-69016-45-926027-38-337205-87-168412-54-4127087-87-0

< 5

< 5

< 5

< 5

Raw wastewater


Legend:

According to ISO 18857-2 and ISO 18254-1 Alkylohenol and Alkylphenol EthoxylatesRequirements:


Note:


Identification Parts Result

52004


Dyes Carcinogenic and Disperse

Method: According to DIN 54231

Instrument: Liquid cromatograph with DAD and MS detector

T F A RD

Compound


Disperse DyesCarcinogenic Dyes

< 50< 500

Raw wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the substance is lower than the limit ofquantification (LOQ)

Legend:

According to DIN 54231 Dyes - Carcinogenic and DisperseRequirements:


List of Disperse Dyes detected (Which are classified to be allergenic) - CAS Number––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––1 Disperse Yellow 1 119-15-3 11 Disperse Red 17 3179-89-32 Disperse Blue 102 12222-97-8 12 Disperse Blue 7 3179-90-63 Dipserse Blue 106 12223-01-7 13 Disperse Blue 26 3860-63-74 Disperse Yellow 39 12236-29-2 14 Disperse Yellow 49 54824-37-25 Disperse Orange 37/76/59 13301-61-6 15 Disperse Blue 35 12222-75-26 Disperse Brown 1 23355-64-8 16 Disperse Blue 124 61951-51-77 Disperse Orange 1 2581-69-3 17 Disperse Yellow 9 6373-73-58 Disperse Yellow 3 2832-40-8 18 Disperse Orange 3 730-40-59 Disperse Red 11 2872-48-2 19 Disperse Blue 35 56524-77-710 Disperse Red 1 2872-52-8

List of Dyes detected (Which are classified to be carcinogenic) - CAS Number–––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––1 Acid Red 26 3761-53-3 9 Disperse Blue 3 2475-46-92 Basic Red 9 569-61-9 10 Basic Blue 26 2580-56-53 Basic Violet 14 632-99-5 11 Basic Green 4 569-64-2/2437-29-8/10309-95-24 Direct Black 38 1937-37-75 Direct Blue 6 2602-46-26 Direct Red 28 573-58-07 Disperse Blue 1 2475-45-88 Disperse Orange 11 82-28-0

Note:



52005


Flame Retardants

Method: According to ISO 22032:2006

Instrument: Gaschromatograph with mass detector (GC-MS)

T F A RD

Compound


TCEPdecaBDETRISpentaBDEoctaBDEBISTEPAPBBTBBPAHBCDDBBMPTDCPSCCP

115-96-81163-19-5126-72-732534-81-932536-52-05412-25-9545-55-159536-65-179-94-73194-55-63296-90-013674-87-885535-84-8

< 5< 5< 5< 5< 5< 5< 5< 5< 5< 5< 5< 5< 5

Raw wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)The substances determined are:TCEP : Tris(2-chloroethyl)phosphate; - DecaBDE : Decabromodiphenyl ether; - TRIS : Tris(2,3-dibromopropyl)-phosphate; - PentaBDE : Pentabromodiphenyl ether; - OctaBDE : Octabromodiphenyl ether; - BIS : Bis(2,3-dibromopropyl)phosphate; - TEPA : Tris(1-aziridinyl)phosphine oxide; - PBB : Polybromobiphenyls; - TBBPA :Tetrabromobisphenol A; - HBCDD : Hexabromocyclododecane; - BBMP : 2,2-bis(bromomethyl)-1,3-propanediol ; -TDCP : Tris(1,3-dichloro-isopropyl)phosphate ; - SCCP : Short-chain chlorinated paraffins

Legend:

According to USEPA 8270 Flame RetardantsRequirements:


Note:



52006


Glycols

Method: According to USEPA 8270

Instrument: Gaschromatograph with Mass Detector

T F A RD


Bis(2-methoxyethyl)-ether2-ethoxyethanol2-ethoxyethyl acetateEthylene glycol dimethyl ether2-methoxyethanol2-methoxyethylacetate2-methoxypropylacetateTriethylene glycol dimethyl ether

111-96-6110-80-5111-15-9110-71-4109-86-4110-49-670657-70-4112-49-2

< 50< 50< 50< 50< 50< 50< 50< 50

Raw wastewater


Legend:

According to USEPA 8270 GlycolsRequirements:


Note:



52007


Halogenated Solvents

Method: According to USEPA 8260B

Instrument: Gaschromatograph with FID and Mass Detector

T F A RD


1,2-DichloroethaneMethylene chlorideTrichloroethyleneTetrachloroethylene

107-06-275-09-279-01-6127-18-4

< 1< 1< 1< 1

Raw wastewater


Legend:

According to USEPA 8260B Halogenated SolventsRequirements:


Note:



52008


Organotin Compounds

Method: According to ISO 17353

Instrument: Gas - Chromatograph with Mass Detector (GC-MSD)

T F A RD


METDMTTMTMBTDBTTBTMPTDPTTPTMOTDOTTOT

MultipleMultipleMultipleMultipleMultipleMultipleMultipleMultipleMultipleMultipleMultipleMultiple

< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01

Raw wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)MET : Monomethyltin; - DMT: Dimethyltin; - TMT : Trimethyltin; MBT : Monobutyltin; - DBT : Dibutyltin; - TBT :Tributyltin; - MPT : Monophenyltin; - DPT : Diphenyltin; - TPT : Triphenyltin; - MOT : Monooctyltin; - DOT : Dioctyltin; -TOT : Trioctyltin.

Legend:

According to ISO 17353 Organotin CompoundsRequirements:


Note:



52009


Perfluorinated and Polyfluorinated Chemicals (PFCs)

Method: According to DIN 38407-42

Instrument: Liquid Chromatograph with Mass detector and Gas Chromatography with mass detector

T F A RD


PFOS

PFOAPFBS

PFHxA8:2 FTOH6:2 FTOH

355-46-4432-50-7335-67-129420-49-329420-43-3307-24-4678-39-7647-42-7

< 0,01

< 0,01< 0,01

< 0,01< 1< 1

Raw wastewater


Legend:

According to DIN 38407-42 Perfluorinated and Polyfluorinated Chemicals (PFCs)Requirements:


Note:



52010


Phthalates

Method: According to USEPA 8270D

Instrument: Gascromatograph with Mass Detector - Liquid Cromatograph with DAD and Mass detector

T F A RD


DEHPBBPDBPDEPDNOPDINPDIDPDIBPDnHPDMEPDPRPDIOPDCHPDNPDHNUPDIHP

117-81-785-68-784-74-284-66-2117-84-028553-12-026761-40-084-69-584-75-3117-82-8131-16-827554-26-384-61-784-76-468515-42-471888-89-6

< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10

Raw wastewater

The results are expressed in µg/L.The symbol < followed by a number indicates that the concentration of the analyte is lower than the limit ofquantification (LOQ)

The phthalates determined are:DEHP : Bis (2-ethylhexyl) phthalate ; - BBP : Butyl benzyl phthalate ; - DBP : Di-n-butyl phthalate ; - DEP : Diethylphthalate; - DNOP : Di-n-octyl phthalate; - DINP : Di-isononyl phthalate; - DIDP : Di-iso-decyl phthalate ; - DIBP : Di-isobutyl phthalate ; - DnHP : Di-n-hexyl phthalate; - DMEP : Dimethoxyethyl phthalate; - DPRP : Di-n-propyl phthalate;- DIOP : Di-iso-octyl phthalate; - DCHP : Di-cyclohexyl phthalate; - DNP : Dinonyl phthalate; - DIHP : Di-isoheptylphthalate; - DHNUP : 1,2-Benzene-di-carboxylic acid, di-C7-11-branched and linear alkyl esters.

Legend:

According to USEPA 8270D PhthalatesRequirements:


Note:



52011


Polycyclic Aromatic Hydrocarbons (PAH)

Method: According to USEPA 8270

Instrument: Gascromatograph with Mass Detector

T F A RD

Compound


Benzo(a)pyreneBenzo(e)pyreneBenzo(a)anthraceneBenzo(b)fluorantheneBenzo(j)fluorantheneBenzo(k)fluorantheneChryseneDibenzo(a,h)anthracene

AcenaphteneAcenaphthyleneAnthraceneBenzo(g,h,i)peryleneFluorantheneFluoreneIndeno(1,2,3-cd)pyreneNaphthalenePhenanthrenePyrene

50-32-8192-97-256-55-3205-99-2205-82-3207-08-9218-01-953-70-3

83-32-9208-96-8120-12-7191-24-2206-44-086-73-7193-39-591-20-385-01-8129-00-0

< 1< 1< 1< 1< 1< 1< 1< 1

< 1< 1< 1< 1< 1< 1< 1< 1< 1< 1

Raw wastewater

The results are expressed in µg/L.The symbol < followed by a number inicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to USEPA 8270 Polycyclic Aromatic Hydrocarbons (PAH)Requirements:


Note:



52012


Volatile Organic Compounds

Method: According to ISO 11423-1

Instrument: GC-MS headspace

T F A RD


BenzeneXyleneo-cresolp-cresolm-cresol

71-43-21330-20-795-48-7106-44-5108-39-4

< 1< 1< 1< 1< 1

Raw wastewater

The results are expressed in µg/L.The symbol < followed by a number indicates that the concentration of the substances is lower than the limit ofquantification (LOQ)

Legend:

According to ISO 11423-1 Volatile Organic Compounds (VOC)Requirements:


Note:



52024


Metals

Method: According to ISO17294-2 (2016) and ISO 11885 (2007)

Instrument: Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) and Inductively Coupled Plasma with Mass Detector (ICP-MS)

T F A RD

Compound


PbCdHgSbAsCoCuNiZnCrAg

< 0,01< 0,01

< 0,0010,022

< 0,005< 0,01< 0,25< 0,05

< 0,5< 0,05

< 0,005

Raw wastewater

The results are expressed in mg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to ISO17294-2 (2016) and ISO 11885 (2007) MetalsRequirements:


Note:

page 16 of 16MD Standard Report CH_v5/14 ••• END OF REPORT •••

Documents

TEST REPORT: 17.42278R2static.benettongroup.com/wp-content/uploads/2018/03/TiFAS.pdf · TEST REPORT: 17.42278R2 This report cancels and replaces the previous one (17.42278) issued