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Department of Electronic Engineering Technology
PGT 330/3
Teknologi Fabrikasi Mikroelectronik/
Microelectronic Fabrication Technology
Basic of Semiconductors and Silicon Wafer
ManufacturingDepartment of Electronic Engineering Technology,
Faculty of Engineering Technology (FTK),
Universiti Malaysia Perlis (UniMAP),
Kampus Kampus UniCITI Alam,
Sungai Chuchuh,
02100 Padang Besar, Perlis,
MALAYSIA.
Department of Electronic Engineering Technology
Basic of Semiconductor Devices
OBJECTIVES
Department of Electronic Engineering Technology
• Identify at least two semiconductor materials from the periodic
table of elements
• List n-type and p-type dopants
• Describe a diode and a MOS transistor
• List three kinds of chips made in the semiconductor industry
• List at least four basic processes required for a chip
manufacturing
TOPICS
Department of Electronic Engineering Technology
• What is semiconductor
• Basic semiconductor devices
• Basics of IC processing
WHAT IS A SEMICONDUCTOR
Department of Electronic Engineering Technology
• Semiconductors are materials with electrical conductivitybetween conductors and insulators.
• The most commonly used semiconductor materials are siliconand germanium.
• Some compounds, such as GaAs, SiC and SiGe.
• Most important property is its conductivity can be controlled byadding certain impurities in the process called doping.
WHAT IS A SEMICONDUCTOR
Department of Electronic Engineering Technology
WHAT IS A SEMICONDUCTOR
Department of Electronic Engineering Technology
• The study of semiconductor materials – 19th century
• Early 1950s – Ge was the major semiconductor material, andlater in early 1960, Si has become a practical substitute withseveral advantages:
- Better properties at room temperature
- Can be grown thermally – high quality silicon oxide
- Lower cost, and
- Easy to get, silica and silicates comprises25% of theEarth’s crust
WHAT IS A SEMICONDUCTOR
Department of Electronic Engineering Technology
WHAT IS A SEMICONDUCTOR
Department of Electronic Engineering Technology
WHAT IS A SEMICONDUCTOR
Department of Electronic Engineering Technology
Semiconductor Substrate and Dopants
WHAT IS A SEMICONDUCTOR
Department of Electronic Engineering Technology
WHAT IS A SEMICONDUCTOR
Department of Electronic Engineering Technology
• Atom is basic building block of all materials
• Classical mechanics – every atom has it
own orbit structure
• Electron orbits are called shells
• The outermost shell is called valence shell
• When e leaves the valence shell, it
becomes a free electron and can conduct
electric current
Band gap
WHAT IS A SEMICONDUCTOR
Department of Electronic Engineering Technology
• When 2 or more identical atoms bond together
to form solid materials, their orbit overlap and
form so called energy bands. Can be
represented by the energy band diagram
• The bottom of conduction band is called Ec,
and the top of the valence band is called Ev.
• Eg = Ec – Ev
• Eg is defined as the energy required to break a
bond in semiconductor to free an e to cond
band and leave the hole in the valence band.
• Electrons in conduction band are free to move
and can conduct electric current
• Electrons in the valence band are bonded with
nuclei and connot move freely, therefore
cannot conduct electric current
Band gap
WHAT IS A SEMICONDUCTOR
Department of Electronic Engineering Technology
• Resistivity is the capability of a material resisting electric current.
• A good conductor has a very low resistivity and a good insulator has a very high resistivity.
• Unit: Ohm.cm
Resistivity
WHAT IS A SEMICONDUCTOR
Department of Electronic Engineering Technology
• For most metals, conduction and valence bands almost overlap or very small band gap. Electron can easily jump from valence to conduction band. Therefore the conduction band has a lot of e.
• For insulators, the band gap is so large that electrons cannot jump across it.
Resistivity and band gap
WHAT IS A SEMICONDUCTOR
Department of Electronic Engineering Technology
• Si is used in standard CMOS fabrication.
• GaAs and SiGe are commonly used in high speed devices.
• GaAs and GaP commonly used in LED.
• ZnS(II-VI) television screen.
• InSb, CdSe, PbTe, HgCdTe as light detectors.
• InP for microwave devices.
• GaAs, AlGaAs as semiconductor laser.
Semiconductor materials and its applications
CRYSTAL PROPERTIES OF SEMICONDUCTORS
Department of Electronic Engineering Technology
• Amorphous
• Single Crystal
• Poly Crystal
Classification of Solids (Based on Atomic
Arrangement)
CRYSTAL PROPERTIES OF SEMICONDUCTORS
Department of Electronic Engineering Technology
Crystal structures
• Amorphous - no repeated structure at all
• Polycrystalline - Some repeated structures
• Single crystal - One repeated structure
CRYSTAL PROPERTIES OF SEMICONDUCTORS
Department of Electronic Engineering Technology
Crystal structures
• Amorphous - no repeated structure at all
• Polycrystalline - Some repeated structures
• Single crystal - One repeated structureAmorphous structure
Polycrystalline structure Single crystal structure
CRYSTAL PROPERTIES OF SEMICONDUCTORS
Department of Electronic Engineering Technology
Silicon crystal structures
• Silicon has four electrons in the outermost shell.
• In a single crystal structure, every atom is bonded with four atoms shares a pair of electrons with each of them.
CRYSTAL PROPERTIES OF SEMICONDUCTORS
Department of Electronic Engineering Technology
Crystal lattice
• LATTICE is the periodic arrangement of atom in a crystal.
• UNIT CELL is the basic building block of crystal lattice repeatingitself for entire lattice.
• The simplest 3D lattice is in cubic form(basic lattice forsemiconductor material is diamond lattice)
• Properties of periodic crystal lattice determine the allowedenergies of electron that participate in the conduction process.
CRYSTAL PROPERTIES OF SEMICONDUCTORS
Department of Electronic Engineering Technology
Unit cell
CRYSTAL PROPERTIES OF SEMICONDUCTORS
Department of Electronic Engineering Technology
Unit cell of single crystal structure
CRYSTAL PROPERTIES OF SEMICONDUCTORS
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Crystal Plane and Miller Indices
CRYSTAL PROPERTIES OF SEMICONDUCTORS
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Why Silicon Dominating
• Abundant, inexpensive
• Thermal stability
• Silicon dioxide is a strong dielectric and relatively easy to form
• Silicon dioxide can be used as diffusion doping mask
DOPING SEMICONDUCTOR
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Semiconductor material types
• Intrinsic Semiconductor
• Extrinsic Semiconductor
DOPING SEMICONDUCTOR
Department of Electronic Engineering Technology
Intrinsic semiconductor
• Pure semiconductor materials with no impurity atoms and no
lattice defect.
• At T=0 K, all energy states in valence band are filled with
electrons, states in conduction band are empty.
DOPING SEMICONDUCTOR
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Electrical Conduction in Intrinsic Semiconductor
DOPING SEMICONDUCTOR
Department of Electronic Engineering Technology
Electrical Conduction in Intrinsic Semiconductor
Si Si Si Si
Si Si Si Si
Si Si Si Si
Si Si Si Sie-
e
•As the temperature increase above 0K, a few valence bond
electrons may
gain enough thermal energy to break the bond and jump into the
conduction band.•As temperature
increase further, more
bonds broken, more
electrons jump
to the conduction band
and more “empty
states or holes”
created in the valence
band.
DOPING SEMICONDUCTOR
Department of Electronic Engineering Technology
• In intrinsic material, electrons and holes are created in pairs by
thermal energy. So the number of electrons in conduction band
is equal to the number of holes in the valence band
• Electron concentration = hole concentration
• ni = pi and
• nipi = ni2 (MASS ACTION LAW) – the product of n p is always a
constant for a given semiconductor material at given
temperature
Electrical Conduction in Intrinsic Semiconductor
DOPING SEMICONDUCTOR
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• Extrinsic s/c is defined as a semiconductor in which controlled
amounts of specific dopant or impurity atoms have been added
so that the thermal equilibrium electron and hole concentration
are different from the intrinsic carrier concentration.
Extrinsic Semiconductor
DOPING SEMICONDUCTOR
Department of Electronic Engineering Technology
• The purpose of doping is to alter the conductivity ofsemiconductor materials.
• Two types of dopant; p-type (B), n-type (P, As)
• N-type dopants provide an electron in s/c materials, hence calleddonors.
• P-type dopants provide a holein s/c materials, hence called acceptor
DOPING SEMICONDUCTOR
Department of Electronic Engineering Technology
N-type Dopant
• P and As have 5 electron valens
• When doped into Si, 4 electrons used to form the covalence bond
with Si
• 1 extra electron is left in the outermost shell and will occupy a
new
• energy level called Donor Energy.
DOPING SEMICONDUCTOR
Department of Electronic Engineering Technology
N-type Dopant
valence band
conduction bandEc
Ev
Ed
Ec
Ev
Ed+ ++
---
• Energy required to elevate donor electron is less than that for
electron involved in covalence bonding.
• With small thermal energy, donor electron is elevated to the
conduction band
• This process add electron to the conduction band without
creating holes in the valence band.
• The resulting material is referred as n-type semiconductor.
DOPING SEMICONDUCTOR
Department of Electronic Engineering Technology
P-type Dopant
• B have 3 electron valens
• When doped into Si, one empty state is created in the
covalence bond
• This empty state will occupy a new energy level called
Acceptor Energy.
DOPING SEMICONDUCTOR
Department of Electronic Engineering Technology
P-type Dopant
• Some valence electron gain a small amount of energy to move
around the crystal lattice.
• This electron would occupy the “empty” position associated with
B atom.
• The vacated electron position is considered as holes.
DOPING SEMICONDUCTOR
Department of Electronic Engineering Technology
P-type Dopant
• This process generate holes in the valence band without
creating electrons in the conduction band.
• The resulting material is referred as p-type semiconductor
DOPING SEMICONDUCTOR
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Illustration of hole movement
DOPING SEMICONDUCTOR
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Illustration of hole movement
DOPING SEMICONDUCTOR
Department of Electronic Engineering Technology
Dopant Concentration and Resistivity
DOPING SEMICONDUCTOR
Department of Electronic Engineering Technology
Dopant Concentration and Resistivity
DOPING SEMICONDUCTOR
Department of Electronic Engineering Technology
Dopant Concentration and Resistivity
• Higher dopant concentration, more carriers(electrons or
holes)
• Higher conductivity, lower resistivity
• Electrons move faster than holes
• N-type silicon has lower resistivity than p-type silicon at the
same dopant concentration
BASIC SEMICONDUCTOR DEVICES
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• Resistor
• Capacitor
• Diode
• MOS transistor
BASIC SEMICONDUCTOR DEVICES
Department of Electronic Engineering Technology
• The simplest electronic device.
• In the IC fabrication pattern doped silicon normally used to make resistors determined by the length, line width, junction depth and dopant concentration.
• Polysilicon also used a resistor.
Resistor
BASIC SEMICONDUCTOR DEVICES
Department of Electronic Engineering Technology
ResistorExample 1
Question: Many people use polysilicon to form gates and local
interconnections. Resistivity of polysilicon is determined by
dopant concentration, which is very high, about 1022 cm-3, and
200 μΩ.cm. Assuming that the polysilicon gate and local
interconnection line width, height, and length are 1 μm, 1 μm,
and 100 μm, respectively.
What is the resistance?
BASIC SEMICONDUCTOR DEVICES
Department of Electronic Engineering Technology
Capacitor
• One of the most important IC component
• When two conducting materials are separated by a dielectric,
a capacitor is formed.
C = Κε0h l
d
ε0- Absolute permittivity of vacuum
(8.85 x 10-12 F/m)
K - Dielectric constant
BASIC SEMICONDUCTOR DEVICES
Department of Electronic Engineering Technology
Capacitor
• Charge storage device
• Memory devices, esp. DRAM
• Challenge : reduce capacitor size while keeping the
capacitance.
• High- K dielectric material.
BASIC SEMICONDUCTOR DEVICES
Department of Electronic Engineering Technology
Capacitor
BASIC SEMICONDUCTOR DEVICES
Department of Electronic Engineering Technology
Parasitic Capacitor
• Unwanted (parasitic) capacitor, as result of dielectric
sandwiched between 2 metal layers. This will result in the RC
delay of the IC circuit.
• Major limitation for current IC device speed
• This application required low k dielectric and better conduction
metal
= RC
BASIC SEMICONDUCTOR DEVICES
Department of Electronic Engineering Technology
Capacitor
Example 2
Question: What is the capacitance for a capacitor with the
same structure as Figure below with h = l = 10 μm? (The
dielectric between two conducting plates is silicon dioxide, with
= 3.9, and d = 1000 Å.)
BASIC SEMICONDUCTOR DEVICES
Department of Electronic Engineering Technology
Diode
• P-N Junction
• Allows electric current go through only in one way (positively
biased)
BASIC SEMICONDUCTOR DEVICES
Department of Electronic Engineering Technology
Diode• When p-type and n-type semiconductors join together, they form a p-n
junction diode.
• Holes in p-type region will diffuse to the n-type region, and electrons in
n-type region will diffuse to the p-type region (at thermal equilibrium,
without applied bias).
• The area dominated by minority carriers is called the transition region.
• The voltage across the transition region given by;
BASIC SEMICONDUCTOR DEVICES
Department of Electronic Engineering Technology
MOSFET
• Metal-oxide-semiconductor also called MOSFET (MOS Field
Effect Transistor)
• Simple, symmetric structure
• Switch, good for digital, logic circuit
• Most commonly used devices in the semiconductor industry
BASIC SEMICONDUCTOR DEVICES
Department of Electronic Engineering Technology
MOSFET
NMOS
• Conducting gate(metal or polysilicon)
• Heavily doped source and drain
• P-type substrate
• Ultra thin gate oxide
BASIC SEMICONDUCTOR DEVICES
Department of Electronic Engineering Technology
MOSFET
NMOS• When no bias voltage is applied to the gate, no current flow.
• When gate is positively biased, positive charge will appear at the gate.
• Positive charge at the silicon surface will be expelled from the region.
• At certain voltage (Threshold Voltage), electron will be accumulated at
silicon surface to form channel, and allow the electron flow from source
to drain.
BASIC SEMICONDUCTOR DEVICES
Department of Electronic Engineering Technology
MOSFET
PMOS• When no bias voltage is applied to the gate, no current flow.
• When gate is negatively biased, negative charge will appear at the
gate.
• Negative charge at the Si surface will be expelled from the region.
• At certain voltage(threshold), holes will be accumulated at the Si
surface to form channel, allow the holes flow from drain to source.
BASIC SEMICONDUCTOR DEVICES
Department of Electronic Engineering Technology
THANK YOU