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The Global Market for Graphene 2018-2027
© Future Markets, Inc. 2017 All rights reserved.
TABLE OF CONTENTS
1 RESEARCH METHODOLOGY......................................................... 58
• 1.1 Market opportunity analysis.......................................................................................................... 59
• 1.1 Market challenges rating system................................................................................................. 61
2 EXECUTIVE SUMMARY................................................................... 63
• 2.1 Two-dimensional (2D) materials.................................................................................................. 63
• 2.2 Graphene......................................................................................................................................... 64
o 2.2.1 The market in 2016............................................................................................................... 65
o 2.2.2 The market in 2017............................................................................................................... 65
o 2.2.3 Production.............................................................................................................................. 66
o 2.2.4 Products.................................................................................................................................. 67
o 2.2.5 Graphene investments 2016-2017..................................................................................... 69
• 2.3 Market outlook for 2018................................................................................................................. 70
o 2.3.1 Global funding and initiatives.............................................................................................. 77
o 2.3.2 Products and applications.................................................................................................... 77
o 2.3.3 Production.............................................................................................................................. 79
o 2.3.4 Market drivers and trends.................................................................................................... 81
o 2.3.5 Market and technical challenges........................................................................................ 85
• 2.4 Key players...................................................................................................................................... 87
o 2.4.1 Asia-Pacific............................................................................................................................. 87
o 2.4.1.1 Australia......................................................................................................................... 89
o 2.4.2 North America........................................................................................................................ 90
o 2.4.3 Europe..................................................................................................................................... 90
3 PROPERTIES OF NANOMATERIALS.............................................. 91
The Global Market for Graphene 2018-2027
© Future Markets, Inc. 2017 All rights reserved.
• 3.1 Categorization................................................................................................................................. 92
4 OVERVIEW OF GRAPHENE............................................................ 94
• 4.1 History.............................................................................................................................................. 94
• 4.2 Forms of graphene......................................................................................................................... 95
• 4.3 Properties......................................................................................................................................... 96
• 4.4 3D Graphene................................................................................................................................... 98
• 4.5 Graphene Quantum Dots.............................................................................................................. 98
o 4.5.1 Synthesis.............................................................................................................................. 100
o 4.5.2 Applications.......................................................................................................................... 100
▪ 4.5.2.1 Optoelectronics, electronics and photonics........................................................... 100
▪ 4.5.2.2 Energy......................................................................................................................... 100
▪ 4.5.2.3 Biomedicine and healthcare.................................................................................... 101
▪ 4.5.2.4 Other............................................................................................................................ 101
▪ 4.5.2.5 Pricing.......................................................................................................................... 102
o 4.5.3 Producers............................................................................................................................. 102
5 CARBON NANOTUBES VERSUS GRAPHENE............................. 104
• 5.1 Comparative properties............................................................................................................... 105
• 5.2 Cost and production..................................................................................................................... 106
• 5.3 Carbon nanotube-graphene hybrids......................................................................................... 107
• 5.4 Competitive analysis of carbon nanotubes and graphene.................................................... 108
6 OTHER 2-D MATERIALS................................................................ 110
• 6.1 Beyond moore’s law..................................................................................................................... 112
• 6.2 Batteries......................................................................................................................................... 112
• 6.3 PHOSPHORENE.......................................................................................................................... 113
o 6.3.1 Properties............................................................................................................................. 114
The Global Market for Graphene 2018-2027
© Future Markets, Inc. 2017 All rights reserved.
▪ 6.3.1.1 Fabrication methods.................................................................................................. 115
▪ 6.3.1.2 Challenges for the use of phosphorene in devices.............................................. 116
o 6.3.2 Applications.......................................................................................................................... 116
▪ 6.3.2.1 Electronics.................................................................................................................. 116
▪ 6.3.2.2 Thermoelectrics......................................................................................................... 117
▪ 6.3.2.3 Batteries...................................................................................................................... 117
▪ 6.3.2.4 Supercapacitors......................................................................................................... 119
▪ 6.3.2.5 Photodetectors........................................................................................................... 119
▪ 6.3.2.6 Sensors....................................................................................................................... 119
o 6.3.3 Market opportunity assessment........................................................................................ 120
• 6.4 GRAPHITIC CARBON NITRIDE (g-C3N4).............................................................................. 121
o 6.4.1 Properties............................................................................................................................. 121
o 6.4.2 Synthesis.............................................................................................................................. 121
o 6.4.3 C2N........................................................................................................................................ 122
o 6.4.4 Applications.......................................................................................................................... 122
▪ 6.4.4.1 Electronics.................................................................................................................. 122
▪ 6.4.4.2 Filtration membranes................................................................................................ 122
▪ 6.4.4.3 Photocatalysts............................................................................................................ 123
▪ 6.4.4.4 Batteries (LIBs).......................................................................................................... 123
▪ 6.4.4.5 Sensors....................................................................................................................... 123
o 6.4.5 Market opportunity assessment........................................................................................ 123
• 6.5 GERMANENE............................................................................................................................... 124
o 6.5.1 Properties............................................................................................................................. 125
o 6.5.2 Applications.......................................................................................................................... 125
▪ 6.5.2.1 Electronics.................................................................................................................. 125
▪ 6.5.2.2 Batteries...................................................................................................................... 125
o 6.5.3 Market opportunity assessment........................................................................................ 126
• 6.6 GRAPHDIYNE.............................................................................................................................. 126
The Global Market for Graphene 2018-2027
© Future Markets, Inc. 2017 All rights reserved.
o 6.6.1 Properties............................................................................................................................. 127
o 6.6.2 Applications.......................................................................................................................... 127
▪ 6.6.2.1 Electronics.................................................................................................................. 127
▪ 6.6.2.2 Batteries...................................................................................................................... 127
▪ 6.6.2.3 Separation membranes............................................................................................ 128
▪ 6.6.2.4 Water filtration............................................................................................................ 128
▪ 6.6.2.5 Photocatalysts............................................................................................................ 128
▪ 6.6.2.6 Photovoltaics.............................................................................................................. 128
o 6.6.3 Market opportunity assessment........................................................................................ 129
• 6.7 GRAPHANE.................................................................................................................................. 129
o 6.7.1 Properties............................................................................................................................. 130
o 6.7.2 Applications.......................................................................................................................... 130
▪ 6.7.2.1 Electronics.................................................................................................................. 130
▪ 6.7.2.2 Hydrogen storage...................................................................................................... 131
o 6.7.3 Market opportunity assessment........................................................................................ 131
• 6.8 HEXAGONAL BORON-NITRIDE............................................................................................... 132
o 6.8.1 Properties............................................................................................................................. 132
o 6.8.2 Applications.......................................................................................................................... 133
▪ 6.8.2.1 Electronics.................................................................................................................. 133
▪ 6.8.2.2 Fuel cells..................................................................................................................... 133
▪ 6.8.2.3 Adsorbents.................................................................................................................. 133
▪ 6.8.2.4 Photodetectors........................................................................................................... 134
▪ 6.8.2.5 Textiles........................................................................................................................ 134
▪ 6.8.2.6 Biomedical.................................................................................................................. 134
o 6.8.3 Market opportunity assessment........................................................................................ 135
• 6.9 MOLYBDENUM DISULFIDE (MoS2)........................................................................................ 135
o 6.9.1 Properties............................................................................................................................. 136
The Global Market for Graphene 2018-2027
© Future Markets, Inc. 2017 All rights reserved.
o 6.9.2 Applications.......................................................................................................................... 137
▪ 6.9.2.1 Electronics.................................................................................................................. 137
▪ 6.9.2.2 Photovoltaics.............................................................................................................. 138
▪ 6.9.2.3 Piezoelectrics............................................................................................................. 138
▪ 6.9.2.4 Sensors....................................................................................................................... 138
▪ 6.9.2.5 Filtration....................................................................................................................... 139
▪ 6.9.2.6 Batteries...................................................................................................................... 139
▪ 6.9.2.7 Fiber lasers................................................................................................................. 139
o 6.9.3 Market opportunity assessment........................................................................................ 140
• 6.10 RHENIUM DISULFIDE (ReS2) AND DISELENIDE (ReSe2)........................................... 140
o 6.10.1 Properties........................................................................................................................ 141
o 6.10.2 Applications..................................................................................................................... 141
▪ 6.10.2.1 Electronics.................................................................................................................. 141
o 6.10.3 Market opportunity assessment................................................................................... 142
• 6.11 SILICENE.................................................................................................................................. 142
o 6.11.1 Properties........................................................................................................................ 143
o 6.11.2 Applications..................................................................................................................... 144
▪ 6.11.2.1 Electronics.................................................................................................................. 144
▪ 6.11.2.2 Photovoltaics.............................................................................................................. 144
▪ 6.11.2.3 Thermoelectrics......................................................................................................... 144
▪ 6.11.2.4 Batteries...................................................................................................................... 145
▪ 6.11.2.5 Sensors....................................................................................................................... 145
o 6.11.3 Market opportunity assessment................................................................................... 146
• 6.12 STANENE/TINENE................................................................................................................. 146
o 6.12.1 Properties........................................................................................................................ 147
o 6.12.2 Applications..................................................................................................................... 148
▪ 6.12.2.1 Electronics.................................................................................................................. 148
o 6.12.3 Market opportunity assessment................................................................................... 148
The Global Market for Graphene 2018-2027
© Future Markets, Inc. 2017 All rights reserved.
• 6.13 TUNGSTEN DISELENIDE..................................................................................................... 149
o 6.13.1 Properties........................................................................................................................ 149
o 6.13.2 Applications..................................................................................................................... 150
▪ 6.13.2.1 Electronics.................................................................................................................. 150
o 6.13.3 Market opportunity assessment................................................................................... 150
• 6.14 ANTIMONENE......................................................................................................................... 150
o 6.14.1 Properties........................................................................................................................ 150
o 6.14.2 Applications..................................................................................................................... 151
• 6.15 DIAMENE.................................................................................................................................. 151
o 6.15.1 Properties........................................................................................................................ 151
o 6.15.2 Applications..................................................................................................................... 151
• 6.16 INDIUM SELENIDE................................................................................................................. 152
o 6.16.1 Properties........................................................................................................................ 152
o 6.16.2 Applications..................................................................................................................... 152
▪ 6.16.2.1 Electronics.................................................................................................................. 152
• 6.17 COMPARATIVE ANALYSIS OF GRAPHENE AND OTHER 2D MATERIALS............. 154
7 GRAPHENE SYNTHESIS............................................................... 156
• 7.1 Large area graphene films.......................................................................................................... 156
• 7.2 Graphene oxide flakes and graphene nanoplatelets.............................................................. 157
• 7.3 Production methods..................................................................................................................... 158
o 7.3.1 Production directly from natural graphite ore................................................................. 160
o 7.3.2 Alternative starting materials............................................................................................. 160
o 7.3.3 Quality................................................................................................................................... 161
• 7.4 Synthesis and production by types of graphene..................................................................... 162
o 7.4.1 Graphene nanoplatelets (GNPs)...................................................................................... 162
o 7.4.2 Graphene nanoribbons...................................................................................................... 163
o 7.4.3 Large-area graphene films................................................................................................ 164
The Global Market for Graphene 2018-2027
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o 7.4.4 Graphene oxide (GO)......................................................................................................... 165
• 7.5 Pros and cons of graphene production methods.................................................................... 166
o 7.5.1 Chemical Vapor Deposition (CVD)................................................................................... 167
o 7.5.2 Exfoliation method.............................................................................................................. 168
o 7.5.3 Epitaxial growth method..................................................................................................... 168
o 7.5.4 Wet chemistry method (liquid phase exfoliation)........................................................... 169
o 7.5.5 Micromechanical cleavage method.................................................................................. 170
o 7.5.6 Green reduction of graphene oxide................................................................................. 170
o 7.5.7 Plasma.................................................................................................................................. 170
• 7.6 Recent synthesis methods.......................................................................................................... 171
• 7.7 Synthesis methods by company................................................................................................ 176
8 GRAPHENE MARKET STRUCTURE AND ROUTES TO COMMERCIALIZATION....................................................................... 178
9 REGULATIONS AND STANDARDS............................................... 182
• 9.1 Standards...................................................................................................................................... 182
• 9.2 Environmental, health and safety regulation........................................................................... 182
o 9.2.1 Europe.................................................................................................................................. 183
o 9.2.2 United States....................................................................................................................... 183
o 9.2.3 Asia........................................................................................................................................ 183
• 9.3 Workplace exposure.................................................................................................................... 184
10 PATENTS AND PUBLICATIONS.................................................... 185
• 10.1 Fabrication processes............................................................................................................. 185
• 10.2 Academia.................................................................................................................................. 185
• 10.3 Regional leaders...................................................................................................................... 186
11 TECHNOLOGY READINESS LEVEL............................................. 189
12 GRAPHENE INDUSTRY DEVELOPMENTS 2013-2018-INVESTMENTS, PRODUCTS AND PRODUCTION............................ 191
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13 END USER MARKET SEGMENT ANALYSIS................................ 242
• 13.1 Graphene production volumes 2010-2027.......................................................................... 242
• 13.2 Graphene pricing..................................................................................................................... 244
o 13.2.1 Pristine Graphene Flakes pricing................................................................................ 246
o 13.2.2 Few-Layer Graphene pricing........................................................................................ 247
o 13.2.3 Graphene Nanoplatelets pricing.................................................................................. 248
o 13.2.4 Reduced Graphene Oxide pricing............................................................................... 248
o 13.2.5 Graphene Quantum Dots pricing................................................................................. 249
o 13.2.6 Graphene Oxide Nanosheets pricing.......................................................................... 250
o 13.2.7 Multilayer Graphene (MLG) pricing............................................................................. 251
o 13.2.8 Mass production of lower grade graphene materials............................................... 251
o 13.2.9 High grade graphene difficult to mass produce......................................................... 251
o 13.2.10 Bulk supply...................................................................................................................... 252
o 13.2.11 Commoditisation............................................................................................................. 252
• 13.3 Graphene producers and production capacities................................................................ 253
14 3D PRINTING.................................................................................. 254
• 14.1 MARKET DRIVERS AND TRENDS..................................................................................... 255
• 14.2 PROPERTIES AND APPLICATIONS.................................................................................. 255
• 14.3 GLOBAL MARKET SIZE AND OPPORTUNITY................................................................ 257
• 14.4 MARKET CHALLENGES....................................................................................................... 258
• 14.5 PRODUCT DEVELOPERS.................................................................................................... 259
15 ADHESIVES.................................................................................... 260
• 15.1 MARKET DRIVERS AND TRENDS..................................................................................... 260
• 15.2 PROPERTIES AND APPLICATIONS.................................................................................. 261
• 15.3 GLOBAL MARKET SIZE AND OPPORTUNITY................................................................ 262
• 15.4 MARKET CHALLENGES....................................................................................................... 266
The Global Market for Graphene 2018-2027
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• 15.5 PRODUCT DEVELOPERS.................................................................................................... 267
16 AEROSPACE.................................................................................. 268
• 16.1 MARKET DRIVERS AND TRENDS..................................................................................... 268
• 16.2 PROPERTIES AND APPLICATIONS.................................................................................. 269
o 16.2.1 Composites..................................................................................................................... 269
o 16.2.2 Coatings........................................................................................................................... 270
• 16.3 GLOBAL MARKET SIZE AND OPPORUNTIY................................................................... 271
• 16.4 MARKET CHALLENGES....................................................................................................... 276
• 16.5 PRODUCT DEVELOPERS.................................................................................................... 277
17 AUTOMOTIVE................................................................................. 279
• 17.1 MARKET DRIVER AND TRENDS........................................................................................ 279
• 17.2 PROPERTIES AND APPLICATIONS.................................................................................. 280
o 17.2.1 Composites..................................................................................................................... 282
o 17.2.2 Thermally conductive additives.................................................................................... 282
o 17.2.3 Tires.................................................................................................................................. 282
• 17.3 GLOBAL MARKET SIZE AND OPPORTUNITY................................................................ 284
• 17.4 MARKET CHALLENGES....................................................................................................... 287
• 17.5 PRODUCT DEVELOPERS.................................................................................................... 289
18 COATINGS...................................................................................... 291
• 18.1 MARKET DRIVERS AND TRENDS..................................................................................... 291
• 18.2 PROPERTIES AND APPLICATIONS.................................................................................. 296
o 18.2.1 Anti-corrosion coatings.................................................................................................. 298
o 18.2.1.1 Marine.......................................................................................................................... 299
o 18.2.2 Anti-microbial.................................................................................................................. 299
o 18.2.3 Anti-icing.......................................................................................................................... 300
o 18.2.4 Barrier coatings............................................................................................................... 301
The Global Market for Graphene 2018-2027
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o 18.2.5 Heat protection............................................................................................................... 302
o 18.2.6 Anti-fouling....................................................................................................................... 303
o 18.2.7 Wear and abrasion resistance..................................................................................... 304
o 18.2.8 Smart windows............................................................................................................... 305
• 18.3 GLOBAL MARKET SIZE AND OPPORTUNITY................................................................ 306
• 18.4 MARKET CHALLENGES....................................................................................................... 314
• 18.5 PRODUCT DEVELOPERS.................................................................................................... 314
19 COMPOSITES................................................................................. 317
• 19.1 MARKET DRIVERS AND TRENDS..................................................................................... 318
• 19.2 PROPERTIES AND APPLICATIONS.................................................................................. 320
o 19.2.1 Polymer composites....................................................................................................... 320
o 19.2.2 Barrier packaging........................................................................................................... 323
o 19.2.3 Electrostatic discharge (ESD) and electromagnetic interference (EMI) shielding 323
o 19.2.4 Wind turbines.................................................................................................................. 323
o 19.2.5 Ballistic protection.......................................................................................................... 324
• 19.3 GLOBAL MARKET SIZE AND OPPORTUNITY................................................................ 324
• 19.4 MARKET CHALLENGES....................................................................................................... 328
• 19.5 PRODUCT DEVELOPERS.................................................................................................... 329
20 ELECTRONICS AND PHOTONICS................................................ 332
• 20.1 FLEXIBLE ELECTRONICS, WEARABLES, CONDUCTIVE FILMS AND DISPLAYS. 332
o 20.1.1 MARKET DRIVERS AND TRENDS............................................................................ 333
o 20.1.2 PROPERTIES AND APPLICATIONS......................................................................... 335
▪ 20.1.2.1 Transparent electrodes in flexible electronics....................................................... 338
▪ 20.1.2.2 Electronic paper......................................................................................................... 340
▪ 20.1.2.3 Wearable electronics................................................................................................ 341
▪ 20.1.2.4 Wearable sensors...................................................................................................... 345
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▪ 20.1.2.5 Industrial monitoring.................................................................................................. 351
▪ 20.1.2.6 Military......................................................................................................................... 351
o 20.1.3 GLOBAL MARKET SIZE AND OPPORTUNITY....................................................... 352
o 20.1.4 MARKET CHALLENGES.............................................................................................. 357
o 20.1.5 PRODUCT DEVELOPERS........................................................................................... 361
• 20.2 CONDUCTIVE INKS............................................................................................................... 363
o 20.2.1 MARKET DRIVERS AND TRENDS............................................................................ 363
o 20.2.2 PROPERTIES AND APPLICATIONS......................................................................... 364
▪ 20.2.2.1 RFID............................................................................................................................. 366
▪ 20.2.2.2 Smart labels................................................................................................................ 368
▪ 20.2.2.3 Smart clothing............................................................................................................ 369
▪ 20.2.2.4 Printable sensors....................................................................................................... 369
▪ 20.2.2.5 Printed batteries......................................................................................................... 370
▪ 20.2.2.6 Printable antennas.................................................................................................... 371
o 20.2.3 GLOBAL MARKET SIZE AND OPPORTUNITY....................................................... 373
o 20.2.4 MARKET CHALLENGES.............................................................................................. 378
o 20.2.5 PRODUCT DEVELOPERS........................................................................................... 379
• 20.3 TRANSISTORS AND INTEGRATED CIRCUITS............................................................... 380
o 20.3.1 MARKET DRIVERS AND TRENDS............................................................................ 380
o 20.3.2 PROPERTIES AND APPLICATIONS......................................................................... 382
▪ 20.3.2.1 Integrated circuits...................................................................................................... 382
▪ 20.3.2.2 Transistors.................................................................................................................. 383
▪ 20.3.2.3 Graphene Radio Frequency (RF) circuits.............................................................. 384
▪ 20.3.2.4 Graphene spintronics................................................................................................ 385
o 20.3.3 GLOBAL MARKET SIZE AND OPPORTUNITY....................................................... 386
o 20.3.4 MARKET CHALLENGES.............................................................................................. 389
o 20.3.5 PRODUCT DEVELOPERS........................................................................................... 391
The Global Market for Graphene 2018-2027
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• 20.4 MEMORY DEVICES............................................................................................................... 393
o 20.4.1 MARKET DRIVERS AND TRENDS............................................................................ 393
o 20.4.2 PROPERTIES AND APPLICATIONS......................................................................... 394
o 20.4.3 GLOBAL MARKET SIZE AND OPPORTUNITY....................................................... 398
o 20.4.4 MARKET CHALLENGES.............................................................................................. 399
o 20.4.5 PRODUCT DEVELOPERS........................................................................................... 399
• 20.5 PHOTONICS............................................................................................................................ 400
o 20.5.1 MARKET DRIVERS AND TRENDS............................................................................ 400
o 20.5.2 PROPERTIES AND APPLICATIONS......................................................................... 401
▪ 20.5.2.1 Si photonics versus graphene................................................................................. 401
▪ 20.5.2.2 Optical modulators.................................................................................................... 402
▪ 20.5.2.3 Photodetectors........................................................................................................... 402
▪ 20.5.2.4 Saturable absorbers.................................................................................................. 404
▪ 20.5.2.5 Plasmonics................................................................................................................. 404
▪ 20.5.2.6 Fiber lasers................................................................................................................. 405
o 20.5.3 MARKET SIZE AND OPPORTUNITY........................................................................ 406
o 20.5.4 MARKET CHALLENGES.............................................................................................. 406
o 20.5.5 PRODUCT DEVELOPERS........................................................................................... 407
21 ENERGY STORAGE, CONVERSION AND EXPLORATION.......... 408
• 21.1 BATTERIES.............................................................................................................................. 410
o 21.1.1 MARKET DRIVERS AND TRENDS............................................................................ 410
o 21.1.2 PROPERTIES AND APPLICATIONS......................................................................... 413
▪ 21.1.2.1 Lithium-ion batteries (LIB)........................................................................................ 413
▪ 21.1.2.2 Lithium-air batteries................................................................................................... 414
▪ 21.1.2.3 Lithium–sulfur batteries (Li–S)................................................................................. 415
▪ 21.1.2.4 Sodium-ion batteries................................................................................................. 415
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▪ 21.1.2.5 Flexible and stretchable batteries........................................................................... 415
o 21.1.3 GLOBAL MARKET SIZE AND OPPORTUNITY....................................................... 419
o 21.1.4 MARKET CHALLENGES.............................................................................................. 424
o 21.1.5 PRODUCT DEVELOPERS........................................................................................... 425
• 21.2 SUPERCAPACITORS............................................................................................................ 430
o 21.2.1 MARKET DRIVERS AND TRENDS............................................................................ 430
o 21.2.2 PROPERTIES AND APPLICATIONS......................................................................... 431
▪ 21.2.2.1 Flexible and stretchable supercapacitors.............................................................. 434
o 21.2.3 GLOBAL MARKET SIZE AND OPPORTUNITY....................................................... 435
o 21.2.4 MARKET CHALLENGES.............................................................................................. 438
o 21.2.5 PRODUCT DEVELOPERS........................................................................................... 439
• 21.3 PHOTOVOLTAICS.................................................................................................................. 441
o 21.3.1 MARKET DRIVERS AND TRENDS............................................................................ 441
o 21.3.2 PROPERTIES AND APPLICATIONS......................................................................... 442
▪ 21.3.2.1 ITO replacement........................................................................................................ 443
▪ 21.3.2.2 Graphene–silicon (Gr–Si) Schottky junction solar cells...................................... 443
▪ 21.3.2.3 Halide perovskites/graphene hybrids..................................................................... 444
▪ 21.3.2.4 Solar energy harvesting textiles.............................................................................. 444
o 21.3.3 GLOBAL MARKET SIZE............................................................................................... 446
o 21.3.4 MARKET CHALLENGES.............................................................................................. 448
o 21.3.5 PRODUCT DEVELOPERS........................................................................................... 449
• 21.4 FUEL CELLS............................................................................................................................ 449
o 21.4.1 MARKET DRIVERS AND TRENDS............................................................................ 449
o 21.4.2 PROPERTIES AND APPLICATIONS......................................................................... 451
▪ 21.4.2.1 Electrocatalyst supports........................................................................................... 452
o 21.4.3 GLOBAL MARKET SIZE AND GRAPHENE OPPORTUNITY................................ 452
o 21.4.4 MARKET CHALLENGES.............................................................................................. 454
o 21.4.5 PRODUCT DEVELOPERS........................................................................................... 455
The Global Market for Graphene 2018-2027
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• 21.5 LED LIGHTING AND UVC..................................................................................................... 455
o 21.5.1 MARKET DRIVERS AND TRENDS............................................................................ 456
o 21.5.2 PROPERTIES AND APPLICATIONS......................................................................... 456
▪ 21.5.2.1 Flexible OLED lighting.............................................................................................. 457
o 21.5.3 GLOBAL MARKET SIZE AND OPPORTUNITY....................................................... 458
o 21.5.4 MARKET CHALLENGES.............................................................................................. 459
o 21.5.5 PRODUCT DEVELOPERS........................................................................................... 460
• 21.6 OIL AND GAS.......................................................................................................................... 461
• 21.6.1 MARKET DRIVERS AND TRENDS............................................................................ 461
• 21.6.2 PROPERTIES AND APPLICATIONS......................................................................... 462
o 21.6.2.1 Sensing and reservoir management...................................................................... 463
o 21.6.2.2 Coatings...................................................................................................................... 464
o 21.6.2.3 Drilling fluids............................................................................................................... 466
o 21.6.2.4 Sorbent materials...................................................................................................... 466
o 21.6.2.5 Catalysts..................................................................................................................... 467
o 21.6.2.6 Separation.................................................................................................................. 467
• 21.6.3 GLOBAL MARKET SIZE AND OPPORTUNITY....................................................... 468
• 21.6.4 MARKET CHALLENGES.............................................................................................. 470
• 21.6.5 PRODUCT DEVELOPERS........................................................................................... 471
22 FILTRATION................................................................................... 472
• 22.1 MARKET DRIVERS AND TRENDS..................................................................................... 472
• 22.2 PROPERTIES AND APPLICATIONS.................................................................................. 473
o 22.2.1 Water filtration................................................................................................................. 475
o 22.2.2 Gas separation............................................................................................................... 475
o 22.2.3 Photocatalytic absorbents............................................................................................. 475
o 22.2.4 Air filtration....................................................................................................................... 476
• 22.3 GLOBAL MARKET SIZE AND OPPORTUNITY................................................................ 477
The Global Market for Graphene 2018-2027
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• 22.4 MARKET CHALLENGES....................................................................................................... 479
• 22.5 PRODUCT DEVELOPERS.................................................................................................... 480
23 LIFE SCIENCES AND MEDICAL.................................................... 482
• 23.1 MARKET DRIVERS AND TRENDS..................................................................................... 483
• 23.2 PROPERTIES AND APPLICATIONS.................................................................................. 486
o 23.2.1 Cancer therapy............................................................................................................... 490
▪ 23.2.1.1 Graphene oxide for therapy and drug delivery..................................................... 490
▪ 23.2.1.2 Graphene nanosheets.............................................................................................. 490
▪ 23.2.1.3 Gene delivery............................................................................................................. 490
▪ 23.2.1.4 Photodynamic Therapy............................................................................................. 491
o 23.2.2 Medical implants and devices...................................................................................... 491
o 23.2.3 Wound dressings............................................................................................................ 492
o 23.2.4 Biosensors....................................................................................................................... 492
▪ 23.2.4.1 FRET biosensors for DNA detection...................................................................... 493
o 23.2.5 Medical imaging.............................................................................................................. 494
o 23.2.6 Tissue engineering......................................................................................................... 494
o 23.2.7 Dental............................................................................................................................... 494
o 23.2.8 Electrophysiology........................................................................................................... 494
o 23.2.9 Wearable and mobile health monitoring..................................................................... 494
▪ 23.2.9.1 Graphene devices..................................................................................................... 496
▪ 23.2.9.2 Patch-type skin sensors........................................................................................... 499
▪ 23.2.9.3 Skin temperature monitoring.................................................................................... 502
▪ 23.2.9.4 Hydration sensors...................................................................................................... 503
▪ 23.2.9.5 Wearable sweat sensors.......................................................................................... 504
▪ 23.2.9.6 Smart footwear........................................................................................................... 506
• 23.3 GLOBAL MARKET SIZE AND OPPORTUNITY................................................................ 506
The Global Market for Graphene 2018-2027
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• 23.3.1 Wearable healthcare...................................................................................................... 508
• 23.4 MARKET CHALLENGES....................................................................................................... 513
• 23.5 PRODUCT DEVELOPERS.................................................................................................... 516
24 LUBRICANTS................................................................................. 517
• 24.1 MARKET DRIVERS AND TRENDS..................................................................................... 517
• 24.2 PROPERTIES AND APPLICATIONS.................................................................................. 518
• 24.3 GLOBAL MARKET SIZE AND OPPORTUNITY................................................................ 519
• 24.4 MARKET CHALLENGES....................................................................................................... 521
• 24.5 PRODUCT DEVELOPERS.................................................................................................... 522
25 RUBBER AND TIRES..................................................................... 522
• 25.1 APPLICATIONS....................................................................................................................... 523
• 25.2 GLOBAL MARKET SIZE AND OPPORTUNITY................................................................ 523
• 25.3 MARKET CHALLENGES....................................................................................................... 525
• 25.4 PRODUCT DEVELOPERS.................................................................................................... 526
26 SENSORS....................................................................................... 527
• 26.1 MARKET DRIVERS AND TRENDS..................................................................................... 527
• 26.2 PROPERTIES AND APPLICATIONS.................................................................................. 528
o 26.2.1 Infrared (IR) sensors...................................................................................................... 532
o 26.2.2 Electrochemical and gas sensors................................................................................ 532
o 26.2.2.1 Graphene foam.......................................................................................................... 533
o 26.2.3 Pressure sensors........................................................................................................... 533
o 26.2.4 Biosensors....................................................................................................................... 533
o 26.2.5 Optical sensors............................................................................................................... 535
o 26.2.6 Humidity sensors............................................................................................................ 536
o 26.2.7 Strain sensors................................................................................................................. 536
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o 26.2.8 Acoustic sensors............................................................................................................ 536
o 26.2.9 Wireless sensors............................................................................................................ 536
o 26.2.10 Surface enhanced Raman scattering.......................................................................... 536
• 26.3 GLOBAL MARKET SIZE AND OPPORTUNITY................................................................ 537
• 26.4 MARKET CHALLENGES....................................................................................................... 539
• 26.5 PRODUCT DEVELOPERS.................................................................................................... 540
27 SMART TEXTILES AND APPAREL............................................... 543
• 27.1 MARKET DRIVERS AND TRENDS..................................................................................... 543
• 27.2 PROPERTIES AND APPLICATONS................................................................................... 547
o 27.2.1 Conductive coatings....................................................................................................... 552
o 27.2.2 Conductive yarns............................................................................................................ 553
• 27.3 GLOBAL MARKET SIZE........................................................................................................ 554
• 27.4 MARKET CHALLENGES....................................................................................................... 559
• 27.5 PRODUCT DEVELOPERS.................................................................................................... 560
28 OTHER MARKETS.......................................................................... 562
• 28.1 CEMENT ADDITIVES............................................................................................................. 562
o 28.1.1 PRODUCT DEVELOPERS........................................................................................... 562
29 GRAPHENE PRODUCERS............................................................. 563 (120 company profiles)
30 GRAPHENE PRODUCT AND APPLICATION DEVELOPERS....... 646 (110 company profiles)
31 REFERENCES................................................................................ 717
TABLES
• Table 1: Demand for graphene (tons), 2010-2027................................................................................. 66
• Table 2: Consumer products incorporating graphene............................................................................ 68
The Global Market for Graphene 2018-2027
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• Table 3: Graphene investments and financial agreements 2017......................................................... 69
• Table 4: Market opportunity assessment matrix for graphene applications....................................... 72
• Table 5: Graphene target markets-Applications and potential addressable market size................. 77
• Table 6: Main graphene producers by country and annual production capacities............................ 79
• Table 7: Categorization of nanomaterials................................................................................................. 91
• Table 8: Properties of graphene................................................................................................................ 96
• Table 9: Comparison of graphene QDs and semiconductor QDs........................................................ 98
• Table 10: Graphene quantum dot producers........................................................................................ 101
• Table 11: Comparative properties of carbon materials........................................................................ 104
• Table 12: Comparative properties of graphene with nanoclays and carbon nanotubes................ 106
• Table 13: Competitive analysis of Carbon nanotubes and graphene by application area and potential impact by 2027.................................................................................................................... 107
• Table 14: 2D materials types................................................................................................................... 109
• Table 15: Electronic and mechanical properties of monolayer phosphorene, graphene and MoS2................................................................................................................................................................. 114
• Table 16: Market opportunity assessment for phosphorene applications........................................ 119
• Table 17: Market opportunity assessment for graphitic carbon nitride applications....................... 122
• Table 18: Market opportunity assessment for germanene applications........................................... 125
• Table 19: Market opportunity assessment for graphdiyne applications............................................ 128
• Table 20: Market opportunity assessment for graphane applications............................................... 130
• Table 21: Market opportunity assessment for hexagonal boron nitride applications...................... 134
• Table 22: Market opportunity assessment for molybdenum disulfide applications......................... 139
• Table 23: Market opportunity assessment for Rhenium disulfide (ReS2) and diselenide (ReSe2) applications........................................................................................................................................... 141
• Table 24: Market opportunity assessment for silicene applications.................................................. 145
• Table 25: Market opportunity assessment for stanine/tinene applications....................................... 147
• Table 26: Market opportunity assessment for tungsten diselenide applications............................. 149
• Table 27: Comparative analysis of graphene and other 2-D nanomaterials.................................... 153
• Table 28: Large area graphene films-Markets, applications and current global market................ 155
The Global Market for Graphene 2018-2027
© Future Markets, Inc. 2017 All rights reserved.
• Table 29: Graphene oxide flakes/graphene nanoplatelets-Markets, applications and current global market.................................................................................................................................................... 156
• Table 30: Main production methods for graphene................................................................................ 157
• Table 31: Large area graphene films-Markets, applications and current global market................ 164
• Table 32: Graphene synthesis methods, by company......................................................................... 175
• Table 33: Graphene market structure..................................................................................................... 177
• Table 34: Published patent publications for graphene, 2004-2014................................................... 185
• Table 35: Leading graphene patentees.................................................................................................. 186
• Table 36: Industrial graphene patents in 2014...................................................................................... 186
• Table 37: Global production of graphene, 2010-2027 in tons/year. Base year for projections is 2015................................................................................................................................................................. 241
• Table 38: Types of graphene and prices................................................................................................ 243
• Table 39: Pristine graphene flakes pricing by producer...................................................................... 245
• Table 40: Few-layer graphene pricing by producer.............................................................................. 246
• Table 41: Graphene nanoplatelets pricing by producer....................................................................... 246
• Table 42: Reduced graphene oxide pricing, by producer................................................................... 247
• Table 43: Graphene quantum dots pricing by producer...................................................................... 248
• Table 44: Graphene oxide nanosheets pricing by producer............................................................... 248
• Table 45: Multi-layer graphene pricing by producer............................................................................. 249
• Table 46: Production capacities of graphene producers, current and planned, metric tons......... 251
• Table 47: Market drivers for use of graphene in 3D printing............................................................... 253
• Table 48: Graphene properties relevant to application in 3D printing............................................... 254
• Table 49: Market size for graphene in 3D printing.............................................................................. 255
• Table 50: Market opportunity assessment for graphene in 3D printing............................................ 255
• Table 51: Market challenges rating for nanotechnology and nanomaterials in the 3D printing market................................................................................................................................................................. 256
• Table 52: Market drivers for use of graphene in adhesives................................................................ 258
• Table 53: Graphene properties relevant to application in adhesives................................................ 260
• Table 54: Applications and benefits of graphene in adhesives.......................................................... 260
The Global Market for Graphene 2018-2027
© Future Markets, Inc. 2017 All rights reserved.
• Table 55: Market size for graphene in adhesives................................................................................. 261
• Table 56: Market opportunity assessment for graphene in adhesives.............................................. 262
• Table 57: Demand for graphene in adhesives (tons), 2018-2027..................................................... 263
• Table 58: Market challenges rating for graphene in the adhesives market...................................... 264
• Table 59: Market drivers for use of graphene in aerospace............................................................... 266
• Table 60: Applications and benefits of graphene in aerospace......................................................... 269
• Table 61: Market size for graphene in aerospace................................................................................ 270
• Table 62: Market opportunity assessment for graphene in aerospace............................................. 271
• Table 63: Demand for graphene in aerospace (tons), 2018-2027..................................................... 273
• Table 64: Market challenges rating for graphene in the aerospace market..................................... 274
• Table 65: Market drivers for use of graphene in the automotive sector............................................ 277
• Table 66: Applications and benefits of graphene in the automotive industry................................... 281
• Table 67: Market size for graphene in the automotive industry......................................................... 282
• Table 68: Market opportunity assessment for graphene in the automotive industry...................... 282
• Table 69: Demand for graphene in automotive (tons), 2018-2027.................................................... 285
• Table 70: Market challenges rating for graphene in the automotive sector..................................... 286
• Table 71: Properties of nanocoatings..................................................................................................... 289
• Table 72: Graphene properties relevant to application in coatings................................................... 295
• Table 73: Markets for nanocoatings........................................................................................................ 305
• Table 74: Market opportunity assessment for graphene in the coatings market............................. 309
• Table 75: Demand for graphene in coatings (tons), 2018-2027......................................................... 311
• Table 76: Market challenges rating for graphene in the coatings market......................................... 312
• Table 77: Market drivers for use of graphene in composites.............................................................. 316
• Table 78: Graphene properties relevant to application in polymer composites............................... 319
• Table 79: Applications and benefits of graphene in composites........................................................ 319
• Table 80: Market size for graphene in composites............................................................................... 322
• Table 81: Market opportunity assessment for graphene in the composites market....................... 323
The Global Market for Graphene 2018-2027
© Future Markets, Inc. 2017 All rights reserved.
• Table 82: Demand for graphene in composites (tons), 2018-2027................................................... 325
• Table 83: Market challenges rating for graphene in the composites market................................... 327
• Table 84: Market drivers for use of graphene in flexible electronics and conductive films............ 331
• Table 85: Applications and benefits of graphene in flexible electronics and conductive films...... 335
• Table 86: Comparison of ITO replacements.......................................................................................... 336
• Table 87: Wearable electronics devices and stage of development................................................. 340
• Table 88: Graphene properties relevant to application in sensors.................................................... 346
• Table 89: Market size for graphene in flexible electronics and conductive films............................. 350
• Table 90: Market opportunity assessment for graphene in flexible electronics, wearables, conductive films and displays............................................................................................................ 352
• Table 91: Global market for wearable electronics, 2015-2027, by application, billions $.............. 354
• Table 92: Market challenges rating for graphene in the flexible electronics, wearables, conductive films and displays market................................................................................................................... 358
• Table 93: Market drivers for use of graphene in conductive inks....................................................... 361
• Table 94: Comparative properties of conductive inks.......................................................................... 362
• Table 95: Printable electronics products................................................................................................ 364
• Table 96: Opportunities for advanced materials in printed electronics............................................. 366
• Table 97: Applications in flexible and stretchable batteries, by nanomaterials type and benefits thereof................................................................................................................................................... 368
• Table 98: Potential addressable market for graphene in conductive inks........................................ 372
• Table 99: Market opportunity assessment for graphene in conductive inks.................................... 373
• Table 100: Conductive inks in the flexible and stretchable electronics market 2017-2027 revenue forecast (million $), by ink types........................................................................................................ 376
• Table 101: Market impediments for graphene in conductive inks...................................................... 376
• Table 102: Market drivers for use of graphene in transistors, integrated circuits and other components.......................................................................................................................................... 378
• Table 103: Comparative properties of silicon and graphene transistors........................................... 382
• Table 104: Applications and benefits of graphene in transistors, integrated circuits and other components.......................................................................................................................................... 383
• Table 105: Market size for graphene in transistors, integrated circuits and other components.... 385
The Global Market for Graphene 2018-2027
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• Table 106: Market opportunity assessment for graphene in transistors, integrated circuits and other components.......................................................................................................................................... 385
• Table 107: Market challenges rating for graphene in the transistors and integrated circuits market................................................................................................................................................................. 388
• Table 108: Market drivers for use of graphene in memory devices................................................... 391
• Table 109: Market size for graphene in memory devices.................................................................... 396
• Table 110: Applications and commercialization challenges for graphene in the memory devices market.................................................................................................................................................... 397
• Table 111: Market drivers for use of graphene in photonics............................................................... 398
• Table 112: Graphene properties relevant to application in optical modulators................................ 400
• Table 113: Applications and benefits of graphene in photonics......................................................... 403
• Table 114: Market size for graphene in photonics................................................................................ 404
• Table 115: Market challenges rating for graphene in the photonics market.................................... 405
• Table 116: Market drivers for use of graphene in batteries................................................................ 408
• Table 117: Wearable energy and energy harvesting devices and stage of development............. 414
• Table 118: Applications in flexible and stretchable batteries, by materials type and benefits thereof................................................................................................................................................................. 416
• Table 119: Market size for graphene in batteries................................................................................. 418
• Table 120: Potential addressable market for thin film, flexible and printed batteries..................... 419
• Table 121: Market opportunity assessment for graphene in batteries.............................................. 420
• Table 122: Demand for graphene in batteries (tons), 2018-2027...................................................... 421
• Table 123: Market challenges rating for graphene in the batteries market...................................... 423
• Table 124: Market drivers for use of graphene in supercapacitors................................................... 428
• Table 125: Comparative properties of graphene supercapacitors and lithium-ion batteries......... 430
• Table 126: Applications and benefits of graphene in supercapacitors.............................................. 430
• Table 127: Applications in flexible and stretchable supercapacitors, by nanomaterials type and benefits thereof.................................................................................................................................... 433
• Table 128: Market size for graphene in supercapacitors.................................................................... 434
• Table 129: Market opportunity assessment for graphene in supercapacitors................................. 435
The Global Market for Graphene 2018-2027
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• Table 130: Demand for graphene in supercapacitors (tons), 2018-2027......................................... 435
• Table 131: Market challenges rating for graphene in the supercapacitors market......................... 437
• Table 132: Market drivers for use of graphene in photovoltaics........................................................ 439
• Table 133: Market size for graphene in photovoltaics......................................................................... 444
• Table 134: Market size for graphene in photovoltaics......................................................................... 445
• Table 135: Potential addressable market for photovoltaics................................................................ 445
• Table 136: Market challenges rating for graphene in the solar market............................................. 446
• Table 137: Market drivers for use of graphene in fuel cells and hydrogen storage........................ 447
• Table 138: Applications and benefits of graphene in fuel cells and hydrogen storage.................. 450
• Table 139: Market size for graphene in fuel cells and hydrogen storage......................................... 451
• Table 140: Market opportunity assessment for graphene in fuel cells and hydrogen storage...... 451
• Table 141: Market challenges rating for graphene in the fuel cells market...................................... 452
• Table 142: Market drivers for use of graphene in LED lighting and UVC......................................... 454
• Table 143: Applications of graphene in lighting.................................................................................... 454
• Table 144: Market size for graphene in LED lighting and UVC.......................................................... 456
• Table 145: Investment opportunity assessment for graphene in the lighting market..................... 457
• Table 146: Market impediments for graphene in lighting.................................................................... 457
• Table 147: Market drivers for graphene in oil and gas........................................................................ 460
• Table 148: Applications of graphene in the oil and gas market......................................................... 460
• Table 149: Application markets, competing materials, graphene advantages and current market size in oil and gas................................................................................................................................ 466
• Table 150: Market summary and revenues for graphene in the oil and gas market...................... 467
• Table 151: Investment opportunity assessment for graphene in the oil and gas market............... 468
• Table 152: Market challenges rating for graphene in the oil and gas market.................................. 468
• Table 153: Market drivers for use of graphene in filtration.................................................................. 470
• Table 154: Applications and benefits of graphene in filtration and separation................................ 472
• Table 155: Market size for graphene in filtration................................................................................... 475
• Table 156: Market opportunity assessment for graphene in the filtration and separation market. 476
The Global Market for Graphene 2018-2027
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• Table 157: Demand for graphene in filtration (tons), 2018-2027....................................................... 477
• Table 158: Market challenges rating for graphene in the filtration and separation market............ 478
• Table 159: Market drivers for use of graphene in the life sciences and medical market............... 481
• Table 160: Graphene properties relevant to application in biomedicine and healthcare............... 485
• Table 161: Applications and benefits of graphene in life sciences and medical............................. 485
• Table 162: Applications in flexible and stretchable health monitors, by advanced materials type and benefits thereof.................................................................................................................................... 495
• Table 163: Market size for graphene in biomedical and healthcare.................................................. 504
• Table 164: Market opportunity assessment for graphene in biomedical & healthcare markets... 508
• Table 165: Potential addressable market for graphene in biomedical & healthcare markets....... 509
• Table 166: Demand for graphene in life sciences and medical (tons), 2018-2027......................... 510
• Table 167: Market challenges in graphene in biomedicine and healthcare..................................... 512
• Table 168: Market challenges rating for graphene in the biomedical and healthcare market....... 513
• Table 169: Market drivers for use of graphene in lubricants............................................................... 515
• Table 170: Applications of graphene in the lubricants market............................................................ 516
• Table 171: Applications of carbon nanomaterials in lubricants.......................................................... 517
• Table 172: Market size for graphene in lubricants................................................................................ 518
• Table 173: Market opportunity assessment for graphene in lubricants............................................ 518
• Table 174: Demand for graphene in lubricants (tons), 2018-2027.................................................... 519
• Table 175: Market challenges rating for graphene in the lubricants market.................................... 520
• Table 176: Applications of graphene in rubber and tires..................................................................... 521
• Table 177: Market summary and revenues for graphene in the rubber and tires market.............. 521
• Table 178: Investment opportunity assessment for graphene in the rubber and tires market...... 522
• Table 179: Demand for graphene in rubber and tires (tons), 2018-2027......................................... 522
• Table 180: Market challenges for graphene in rubber and tires......................................................... 523
• Table 181: Market drivers for use of graphene in sensors.................................................................. 525
• Table 182: Applications and benefits of graphene in sensors............................................................ 527
The Global Market for Graphene 2018-2027
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• Table 183: Graphene properties relevant to application in sensors.................................................. 529
• Table 184: Comparison of ELISA (enzyme-linked immunosorbent assay) and graphene biosensor................................................................................................................................................................. 533
• Table 185: Market size for graphene in sensors................................................................................... 535
• Table 186: Market opportunity assessment for graphene in the sensors market........................... 536
• Table 187: Market challenges rating for graphene in the sensors market....................................... 538
• Table 188: Types of smart textiles.......................................................................................................... 541
• Table 189: Smart textile products............................................................................................................ 542
• Table 190: Market drivers for use of graphene in smart textiles and apparel.................................. 542
• Table 191: Nanocoatings applied in the textiles industry-type of coating, nanomaterials utilized, benefits and applications.................................................................................................................... 545
• Table 192: Desirable functional properties for the textiles industry afforded by the use of nanomaterials....................................................................................................................................... 549
• Table 193: Applications and benefits of graphene in textiles and apparel....................................... 550
• Table 194: Global smart clothing, interactive fabrics and apparel market........................................ 553
• Table 195: Market opportunity assessment for graphene in smart textiles and apparel................ 556
• Table 196: Demand for graphene in textiles (tons), 2018-2027......................................................... 556
• Table 197: Market impediments for graphene in textiles..................................................................... 557
• Table 198: Market challenges for graphene in textiles and apparel.................................................. 558
• Table 199: Graphene producers and types produced......................................................................... 561
• Table 200: Graphene producers target market matrix......................................................................... 566
• Table 201: Graphene industrial collaborations, licence agreements and target markets.............. 645
• Table 202: Graphene product developers and end users target market matrix.............................. 648
FIGURES
• Figure 1: Graphene production capacity, current and planned............................................................ 66
• Figure 2: Demand for graphene, 2010-2027........................................................................................... 67
• Figure 3: Vittoria bike tires incorporating graphene................................................................................ 68
• Figure 4: Demand for graphene, by market, 2027.................................................................................. 71
The Global Market for Graphene 2018-2027
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• Figure 5: Global government funding for graphene in millions USD to 2017..................................... 77
• Figure 6: Global consumption of graphene 2016, by region................................................................. 83
• Figure 7: 15-inch single-layer graphene sheet being prepared in the Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences........................................................... 87
• Figure 8: Graphene layer structure schematic........................................................................................ 93
• Figure 9: Graphite and graphene............................................................................................................... 94
• Figure 10: Graphene and its descendants: top right: graphene; top left: graphite = stacked graphene; bottom right: nanotube=rolled graphene; bottom left: fullerene=wrapped graphene. .................................................................................................................................................................. 95
• Figure 11: Schematic of (a) CQDs and (c) GQDs. HRTEM images of (b) C-dots and (d) GQDs showing combination of zigzag and armchair edges (positions marked as 1–4)........................ 98
• Figure 12: Green-fluorescing graphene quantum dots........................................................................ 100
• Figure 13: Graphene quantum dots........................................................................................................ 101
• Figure 14: Graphene can be rolled up into a carbon nanotube, wrapped into a fullerene, and stacked into graphite........................................................................................................................... 103
• Figure 15: Schematic of 2-D materials................................................................................................... 110
• Figure 16: Black phosphorus structure................................................................................................... 112
• Figure 17: Black Phosphorus crystal...................................................................................................... 114
• Figure 18: Bottom gated flexible few-layer phosphorene transistors with the hydrophobic dielectric encapsulation....................................................................................................................................... 116
• Figure 19: Graphitic carbon nitride.......................................................................................................... 120
• Figure 20: Structural difference between graphene and C2N-h2D crystal: (a) graphene; (b) C2N-h2D crystal. Credit: Ulsan National Institute of Science and Technology.................................. 121
• Figure 21: Schematic of germanene....................................................................................................... 123
• Figure 22: Graphdiyne structure.............................................................................................................. 126
• Figure 23: Schematic of Graphane crystal............................................................................................. 129
• Figure 24: Structure of hexagonal boron nitride.................................................................................... 131
• Figure 25: BN nanosheet textiles application........................................................................................ 133
• Figure 26: Structure of 2D molybdenum disulfide................................................................................ 135
• Figure 27: SEM image of MoS2............................................................................................................... 136
• Figure 28: Atomic force microscopy image of a representative MoS2 thin-film transistor............. 137
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• Figure 29: Schematic of the molybdenum disulfide (MoS2) thin-film sensor with the deposited molecules that create additional charge.......................................................................................... 138
• Figure 30: Schematic of a monolayer of rhenium disulfide................................................................. 140
• Figure 31: Silicene structure..................................................................................................................... 142
• Figure 32: Monolayer silicene on a silver (111) substrate................................................................... 142
• Figure 33: Silicene transistor.................................................................................................................... 143
• Figure 34: Crystal structure for stanene................................................................................................. 146
• Figure 35: Atomic structure model for the 2D stanene on Bi2Te3(111)........................................... 146
• Figure 36: Schematic of tungsten diselenide........................................................................................ 148
• Figure 37: Schematic of Indium Selenide (InSe).................................................................................. 151
• Figure 38: Graphene synthesis methods............................................................................................... 159
• Figure 39: TEM micrographs of: A) HR-CNFs; B) GANF® HR-CNF, it can be observed its high graphitic structure; C) Unraveled ribbon from the HR-CNF; D) Detail of the ribbon; E) Scheme of the structure of the HR-CNFs; F) Large single graphene oxide sheets derived from GANF.. 160
• Figure 40: Graphene nanoribbons grown on germanium................................................................... 163
• Figure 41: Methods of synthesizing high-quality graphene................................................................. 165
• Figure 42: Roll-to-roll graphene production process............................................................................ 170
• Figure 43: Schematic of roll-to-roll manufacturing process................................................................. 171
• Figure 44: Microwave irradiation of graphite to produce single-layer graphene.............................. 173
• Figure 45: Schematic of typical commercialization route for graphene producer........................... 177
• Figure 46: Published patent publications for graphene, 2004-2014.................................................. 185
• Figure 47: Technology Readiness Level (TRL) for graphene............................................................. 189
• Figure 48: Global market for graphene 2010-2027 in tons/year........................................................ 242
• Figure 49: 3D Printed tweezers incorporating Carbon Nanotube Filament...................................... 254
• Figure 50: Graphene Adhesives.............................................................................................................. 260
• Figure 51: Potential addressable market for graphene in adhesives................................................ 263
• Figure 52: Demand for graphene in adhesives (tons), 2018-2027.................................................... 264
• Figure 53: Potential addressable market for graphene in aerospace............................................... 272
• Figure 54: Potential addressable market for graphene-enabled applications in aerospace.......... 273
The Global Market for Graphene 2018-2027
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• Figure 55: Demand for graphene in aerospace (tons), 2018-2027................................................... 274
• Figure 56: Graphene-based automotive components.......................................................................... 279
• Figure 57: Antistatic graphene tire.......................................................................................................... 281
• Figure 58: Potential addressable market for graphene in the automotive sector............................ 283
• Figure 59: Potential addressable market for graphene in the automotive sector............................ 285
• Figure 60: Demand for graphene in automotive(tons), 2018-2027.................................................... 285
• Figure 61: Heat transfer coating developed at MIT.............................................................................. 295
• Figure 62: Water permeation through a brick without (left) and with (right) “graphene paint” coating................................................................................................................................................................. 300
• Figure 63: Four layers of graphene oxide coatings on polycarbonate.............................................. 303
• Figure 64: Global Paints and Coatings Market, share by end user market...................................... 304
• Figure 65: Potential addressable market for graphene in the coatings market............................... 310
• Figure 66: Potential addressable market for graphene in the coatings market............................... 311
• Figure 67: Demand for graphene in coatings (tons), 2018-2027....................................................... 311
• Figure 68: Potential addressable market for graphene in composites.............................................. 324
• Figure 69: Potential addressable market for graphene in the composites market.......................... 325
• Figure 70: Demand for graphene in composites (tons), 2018-2027.................................................. 326
• Figure 71: Moxi flexible film developed for smartphone application.................................................. 334
• Figure 72: Flexible graphene touch screen........................................................................................... 334
• Figure 73: Galapad Settler smartphone................................................................................................. 334
• Figure 74: Flexible organic light emitting diode (OLED) using graphene electrode........................ 335
• Figure 75: Graphene electrochromic devices. Top left: Exploded-view illustration of the graphene electrochromic device. The device is formed by attaching two graphene-coated PVC substrates face-to-face and filling the gap with a liquid ionic electrolyte....................................................... 338
• Figure 76: Flexible mobile phones with graphene transparent conductive film............................... 338
• Figure 77: Foldable graphene E-paper.................................................................................................. 339
• Figure 78: Covestro wearables................................................................................................................ 341
• Figure 79: Softceptor sensor.................................................................................................................... 344
• Figure 80: BeBop Media Arm Controller................................................................................................ 344
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• Figure 81: LG Innotek flexible textile pressure sensor......................................................................... 345
• Figure 82: C2Sense flexible sensor........................................................................................................ 346
• Figure 83: Wearable gas sensor............................................................................................................. 348
• Figure 84: BeBop Sensors Marcel Modular Data Gloves.................................................................... 348
• Figure 85: BeBop Sensors Smart Helmet Sensor System.................................................................. 349
• Figure 86: Torso and Extremities Protection (TEP) system................................................................ 350
• Figure 87: Potential addressable market for graphene in the flexible electronics, wearables, conductive films and displays market.............................................................................................. 353
• Figure 88: Global market for wearable electronics, 2015-2027, by application, billions $............. 354
• Figure 89: Global transparent conductive electrodes market forecast by materials type, 2012-2027, millions $............................................................................................................................................... 355
• Figure 90: Schematic of the wet roll-to-roll graphene transfer from copper foils to polymeric substrates............................................................................................................................................. 357
• Figure 91: The transmittance of glass/ITO, glass/ITO/four organic layers, and glass/ITO/four organic layers/4-layer graphene...................................................................................................................... 358
• Figure 92: BGT Materials graphene ink product................................................................................... 364
• Figure 93: Flexible RFID tag.................................................................................................................... 365
• Figure 94: Enfucell Printed Battery......................................................................................................... 369
• Figure 95: Graphene printed antenna.................................................................................................... 370
• Figure 96: Printed antennas for aircraft.................................................................................................. 370
• Figure 97: Vorbeck Materials conductive ink products........................................................................ 372
• Figure 98: Potential addressable market for graphene in the conductive ink market..................... 373
• Figure 99: Conductive inks in the flexible and stretchable electronics market 2017-2027 revenue forecast (million $), by ink types........................................................................................................ 375
• Figure 100: Graphene IC in wafer tester................................................................................................ 381
• Figure 101: A monolayer WS2-based flexible transistor array........................................................... 381
• Figure 102: Schematic cross-section of a graphene based transistor (GBT, left) and a graphene field-effect transistor (GFET, right)................................................................................................... 383
• Figure 103: Potential addressable market for graphene in transistors and integrated circuits..... 386
• Figure 104: Potential addressable market for graphene in the transistors and integrated circuits
The Global Market for Graphene 2018-2027
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market.................................................................................................................................................... 387
• Figure 105: The GF1 Graphene Watch.................................................................................................. 391
• Figure 106: Graphene oxide-based RRAm device on a flexible substrate....................................... 393
• Figure 107: Layered structure of tantalum oxide, multilayer graphene and platinum used for resistive random access memory (RRAM)...................................................................................... 394
• Figure 108: A schematic diagram for the mechanism of the resistive switching in metal/GO/Pt.. 394
• Figure 109: Carbon nanotubes NRAM chip........................................................................................... 395
• Figure 110: Stretchable SWCNT memory and logic devices for wearable electronics.................. 395
• Figure 111: Hybrid graphene phototransistors...................................................................................... 401
• Figure 112: Wearable health monitor incorporating graphene photodetectors............................... 402
• Figure 113: Flexible PEN coated with graphene and a QD thin film (20nm) is highly visibly transparent and photosensitive......................................................................................................... 402
• Figure 114: The SkelStart Engine Start Module 2.0 based on the graphene-based SkelCap ultracapacitors...................................................................................................................................... 408
• Figure 115: Energy harvesting textile..................................................................................................... 411
• Figure 116: LG Chem Heaxagonal battery............................................................................................ 414
• Figure 117: Printed 1.5V battery.............................................................................................................. 416
• Figure 118: H600 concept car.................................................................................................................. 418
• Figure 119: Anion concept car................................................................................................................. 418
• Figure 120: Potential addressable market for graphene in the thin film, flexible and printed batteries market.................................................................................................................................................... 421
• Figure 121: Demand for graphene in batteries (tons), 2018-2027..................................................... 422
• Figure 122: Skeleton Technologies ultracapacitor............................................................................... 429
• Figure 123: Zapgo supercapacitor phone charger............................................................................... 431
• Figure 124: Stretchable graphene supercapacitor............................................................................... 432
• Figure 125: Demand for graphene in supercapacitors (tons), 2018-2027........................................ 436
• Figure 126: Solar cell with nanowires and graphene electrode......................................................... 441
• Figure 127: Schematic illustration of the fabrication concept for textile-based dye-sensitized solar cells (DSSCs) made by sewing textile electrodes onto cloth or paper....................................... 443
• Figure 128: Potential addressable market for graphene in photovoltaics......................................... 446
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• Figure 129: LG OLED flexible lighting panel......................................................................................... 455
• Figure 130: Flexible OLED incorporated into automotive headlight.................................................. 456
• Figure 131: Schematic of boron doped graphene for application in gas sensors........................... 462
• Figure 132: Directa Plus Grafysorber..................................................................................................... 465
• Figure 133: Nanometer-scale pores in single-layer freestanding graphene membrane can effectively filter NaCl salt from water................................................................................................................... 466
• Figure 134: Degradation of organic dye molecules by graphene hybrid composite photocatalysts................................................................................................................................................................. 474
• Figure 135: Graphene anti-smog mask.................................................................................................. 475
• Figure 136: Demand for graphene in filtration (tons), 2018-2027...................................................... 477
• Figure 137: Graphene filtration membrane............................................................................................ 479
• Figure 138: Graphene Frontiers’ Six™ chemical sensors consists of a field effect transistor (FET) with a graphene channel. Receptor molecules, such as DNA, are attached directly to the graphene channel................................................................................................................................ 491
• Figure 139: Graphene-Oxide based chip prototypes for biopsy-free early cancer diagnosis....... 492
• Figure 140: Connected human body...................................................................................................... 493
• Figure 141: Flexible, lightweight temperature sensor.......................................................................... 494
• Figure 142: Graphene-based E-skin patch............................................................................................ 495
• Figure 143: Smart e-skin system comprising health-monitoring sensors, displays, and ultra flexible PLEDs................................................................................................................................................... 499
• Figure 144: Graphene medical patch..................................................................................................... 500
• Figure 145: TempTraQ wearable wireless thermometer..................................................................... 501
• Figure 146: Mimo baby monitor............................................................................................................... 501
• Figure 147: Nanowire skin hydration patch........................................................................................... 502
• Figure 148: Wearable sweat sensor....................................................................................................... 503
• Figure 149: GraphWear wearable sweat sensor.................................................................................. 504
• Figure 150: Global medical and healthcare smart textiles and wearables market, 2015-2027, billions $.............................................................................................................................................................. 507
• Figure 151: Global medical and healthcare smart textiles and wearables market, 2015-2027, billions $.............................................................................................................................................................. 508
The Global Market for Graphene 2018-2027
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• Figure 152: Potential addressable market for graphene-enabled applications in the biomedical and healthcare market................................................................................................................................ 510
• Figure 153: Demand for graphene in life sciences and medical (tons), 2018-2027....................... 511
• Figure 154: Demand for graphene in lubricants (tons), 2018-2027................................................... 519
• Figure 155: Demand for graphene in rubber and tires (tons), 2018-2027........................................ 523
• Figure 156: GFET sensors....................................................................................................................... 531
• Figure 157: First generation point of care diagnostics......................................................................... 532
• Figure 158: Graphene Field Effect Transistor Schematic................................................................... 533
• Figure 159: Potential addressable market for graphene in the sensors market.............................. 537
• Figure 160: Conductive yarns.................................................................................................................. 552
• Figure 161: Global smart clothing, interactive fabrics and apparel market 2013-2027 revenue forecast (million $)............................................................................................................................... 553
• Figure 162 Global smart clothing, interactive fabrics and apparel sales by market segment, 2016................................................................................................................................................................. 554
• Figure 163: Global market revenues for nanotech-enabled smart clothing and apparel 2014-2021, in US$, conservative estimate........................................................................................................... 555
• Figure 164: Global market revenues for nanotech-enabled smart clothing and apparel 2014-2021, in US$, optimistic estimate................................................................................................................. 555
• Figure 165: Demand for graphene in textiles (tons), 2018-2027....................................................... 557