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Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride (PVC)

Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

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Page 1: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Synthetic Additional Polymers

PolyethenePolytetrafluoroethene (PTEF)Polymethylmethacrylate (PMMA)Polypropene (PP) Polystyrene (PS) Polyvinyl chloride (PVC)

Page 2: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Polyethene

common name: ethylene

Page 3: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Polyethene

Non- biodegradable When incinerated : burns slowly with blue fla

me having a yellow tip and gives off an odour of paraffin.

Page 4: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Polyethene - Real object

Plastic bag Geomembranes

Page 5: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Polyethene – Real Object

High Density Polyethene (HDPE)

Detergent bottle Toys Water pipies

Page 6: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Polyethene – Real Object

Low Density Polyethene (LDPE)

Plastic container Film wrap

Page 7: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Polyethene - Formation

Polymerization: radical polymerization anionic addition polymerization ion coordination polymerization  cationic addition polymerization

Page 8: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

High Density Polyethene (HDPE)

density of greater or equal to 0.941 g/cm3 low degree of branching strong intermolecular forces & tensile strength Catalysts: chromium, silica melting point :120 - 130 °C (248 - 266 °F) excellent chemical resistance

Page 9: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Low Density Polyethene (LDPE)

density range of 0.910–0.940 g/cm3. high degree of short and long chain branching chains do not pack into the crystal structure ↓strong intermolecular forces as the 

instantaneous-dipole induced-dipole attraction ↓

lower tensile strength and increased ductility

melting point : 105 - 115 °C (221 - 239 °F)

excellent chemical resistance

Page 10: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Polymethlymethacrylate (PMMA)

Poly(methyl 2-methylpropenoate)

Page 11: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Polymethlymethacrylate (PMMA)

Molecular formula: (C5O2H8)n Density: 1.17-1.20g/cm3 Melting point: 160 (320 )℃ ℉ Boiling point: 200℃ PMMA swells and dissolves in many organic 

solvents glass transition temperature :105°C organic glass at room temp

Page 12: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Polymethlymethacrylate (PMMA) – Real object After modification with additives and fillers

 aquariums

Aircraft windows

Page 13: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Polymethlymethacrylate (PMMA) – Real object

Optical Fiber

lenses of exterior lights of automobiles

Page 14: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Polymethlymethacrylate (PMMA) - Formation emulsion polymerization solution polymerization bulk polymerization molding processes: injection molding

compression molding , extrusion. 

Page 15: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Polypropene

Page 16: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Molecular formula: (C3H6)n Density: 0.855 g/cm3, amorphous

0.946 g/cm3, crystalline Melting point: 130–171 °C (266–340 °F)

Polypropene

Page 17: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Polypropene –Real object

Living hinge Carpet

Page 18: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Polypropene – Real Objects

Polypropylene lid of a tic tacs box A polypropylene chair

Page 19: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Polyvinyl Chloride (PVC)

Page 20: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Polyvinyl chloride (PVC) – Formation

57% of its mass is chlorine suspension polymerization. incorporation of additives such as heat

stabilizers before made into finished product

Page 21: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Clothing cheaper than rubber waterproof coats, skiing equipment,

shoes, jackets, aprons, and bags

Polyvinyl chloride (PVC) – Real Object

Page 22: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Polyvinyl chloride (PVC) – Real Object

Electric wires

PVC wires

Page 23: Synthetic Additional Polymers Polyethene Polytetrafluoroethene (PTEF) Polymethylmethacrylate (PMMA) Polypropene (PP) Polystyrene (PS) Polyvinyl chloride

Finish

Claudy ChanCurmen Chiu

Gladys LiNatalie KwanEsther Leung