Supplemental Limited Site Investigationocc.tupperware.com/Folder 2/X.36 - Supplemental Limited... · 2018. 9. 7. · Supplemental Limited Site Investigation Lot 22 Kissimmee, Florida

Supplemental Limited Site

Investigation

Lot 22

SW Quadrant Orange Avenue at Mary Louis Lane

Kissimmee, Osceola County, Florida

June 29, 2018

Terracon Project No. H1177166A

Prepared for:

Deerfield Land Corporation

Orlando, Florida

Prepared by:

Terracon Consultants, Inc.

Winter Park, Florida

TABLE OF CONTENTS

ii

1.0 SITE DESCRIPTION ....................................................................................................... 1 2.0 PREVIOUS ASSESSMENT ............................................................................................ 1 3.0 SCOPE OF SERVICES ................................................................................................... 2

3.1 Standard of Care.................................................................................................. 2 3.2 Additional Scope Limitations ................................................................................ 2 3.3 Reliance ............................................................................................................... 3

4.0 SUPPLEMENTAL SOIL TESTING .................................................................................. 3 5.0 CONCLUSIONS .............................................................................................................. 4

APPENDIX A – EXHIBITS

Exhibit 1 – Topographic Map

Exhibit 2 – Soil Sample Locations Map

APPENDIX B – TABLES

Table 1 – Soil Arsenic Analytical Summary

APPENDIX C – PREVIOUS SOURCE REMOVAL REPORT EXCERPTS

APPENDIX D – ANALYTICAL REPORT AND CHAIN OF CUSTODY

Responsive ■ Resourceful ■ Reliable

SUPPLEMENTAL LIMITED SITE INVESTIGATION

LOT 22

SW QUADRANT ORANGE AVENUE AT MARY LOUIS LANE

KISSIMMEE, OSCEOLA COUNTY, FLORIDA

Terracon Project No. H1177166A

June 29, 2018

1.0 SITE DESCRIPTION

The site is approximately 19.2 acres of vacant land located approximately 500 feet south of the

Mary Louis Lane and 300 feet west of Orange Avenue in Kissimmee, Osceola County, Florida.

The site is approximately 19.2 acres identified by the Osceola County property appraiser as parcel

03-25-29-4586-0001-0020. A topographic map showing the site location is included as Exhibit 1

and a site diagram is included as Exhibit 2 in Appendix A. We understand the intended future

use of the site is commercial development.

2.0 PREVIOUS ASSESSMENT

Terracon previously completed a Phase I Environmental Site Assessment report dated March 8,

2017 (Terracon Project No. H1177125) for 37.2 acres that included the site and adjoining property

to the east and south. Based on a review of the historical information, a golf course was present

onsite from the 1970s to late-1980s or early-1990s. Potential impacts to soil and shallow

groundwater attributed to the historical pesticide and herbicide application associated with the

golf course turf maintenance was deemed a recognized environmental condition. A 1984 aerial

photograph from the Phase I Environmental Assessment report is contained in Appendix C.

Terracon prepared a Limited Site Investigation, Lots 22 & 23 dated April 28, 2017 (Terracon

Project No. H1177166) discussing initial soil and groundwater testing conducted to evaluate

potential pesticide and arsenic impacts associated with the former golf course. Arsenic was

identified at a relict golf course hole green area (sample location B8) at Lot 22 in the top 2 feet of

soil at concentrations exceeding Florida’s soil cleanup target level (SCTL) for residential direct

exposure (RSCTL) of 2.1 milligrams per kilogram (mg/kg) listed in Chapter 62-777, Florida

Administrative Code (FAC). The reported arsenic concentrations in soil did not exceed the

commercial/industrial direct exposure SCTL (CSCTL) of 12 mg/kg. Organochlorine pesticide

concentrations reported in soil samples did not exceed SCTLs. Arsenic concentrations detected

in a groundwater sample (TMW-8) collected at Lot 21 did not exceed the groundwater cleanup

target level (GCTL) of 10 micrograms per liter (ug/L) established for arsenic in Chapter 62-777,

FAC. Diagrams indicating the location of boring B8 and temporary monitoring well TMW-8 are

contained in Appendix C.

Terracon prepared a Limited Site Investigation Report and No Further Action Proposal dated

March 2, 2018 (Terracon Project No. H1177166A), for the site and south adjoining San Mateo

Supplemental Limited Site Investigation

Lot 22 ■ Kissimmee, Florida

June 29, 2018 ■ Terracon Project No. H1177166A

Responsive ■ Resourceful ■ Reliable 2

property, which was submitted to the Florida Department of Environmental Protection (FDEP)

Central District for review and concurrence with the no further action proposal. The reported

included documentation of additional soil testing for arsenic at Lot 22.

The FDEP then requested completion of soil source removal activities to remove soils identified

with arsenic concentrations exceeding the CSCTL at Lot 22, and to remove soils identified with

arsenic concentrations exceeding the RSCTL at the south adjoining San Mateo property. The

defined extent of soil containing arsenic concentrations exceeding the CSCTL identified at Lot 22

in the area of boring location B8 was excavated and disposed at a permitted landfill. The defined

extent of soil containing arsenic concentrations exceeding the RSCTL identified above the normal

groundwater elevation of 83 feet NGVD at the San Mateo property was then excavated and placed

at Lot 22 in the area around boring B8. Terracon documented performance of the source removal

activities in a Soil Source Removal report dated April 5, 2018. On May 10, 2018, the FDEP issued

No Further Assessment Required letter indicating that the FDEP would not require additional

assessment or remediation of the investigated areas. Appendix C contains copies of the FDEP

letter, and diagrams from the Soil Source Removal report showing the soil sampling and soil

source removal areas.

3.0 SCOPE OF SERVICES

This Supplemental LSI included soil sampling and analysis to evaluate arsenic concentrations in

soils above the groundwater at select areas on Lot 22 where previous golf course features (tees,

greens and fairways) were perceived based on review of aerial photographs and observations

during site reconnaissance at the time soil samples were collected. The current soil sampling

locations are indicated on Exhibit 2 in Appendix A.

3.1 Standard of Care

Terracon’s services were performed in a manner consistent with generally accepted practices of

the profession undertaken in similar studies in the same geographical area during the same time.

Terracon makes no warranties, either express or implied, regarding the findings, conclusions, or

recommendations. Please note that Terracon does not warrant the work of laboratories,

regulatory agencies, or other third parties supplying information used in the preparation of the

report. These LSI services were performed in accordance with the scope of work agreed with you,

our client, as reflected in our proposal.

3.2 Additional Scope Limitations

Findings, conclusions, and recommendations resulting from these services are based upon

information derived from the on-site activities and other services performed under this scope of

work; such information is subject to change over time. Certain indicators of the presence of

hazardous substances, petroleum products, or other constituents may have been latent,





inaccessible, unobservable, nondetectable, or not present during these services. We cannot

represent that the site contains no hazardous substances, toxic materials, petroleum products, or

other latent conditions beyond those identified during this LSI. Subsurface conditions may vary

from those encountered at specific borings or wells or during other surveys, tests, assessments,

investigations, or exploratory services. The data, interpretations, findings, and our

recommendations are based solely upon data obtained at the time and within the scope of these

services.

3.3 Reliance

This report has been prepared for the exclusive use of Deerfield Land Corporation. Any

authorization for use or reliance by any other party (except a governmental entity having

jurisdiction over the site) is prohibited without the express written authorization of Deerfield Land

Corporation and Terracon. Any unauthorized distribution or reuse is at Deerfield Land

Corporation’s sole risk. Notwithstanding the foregoing, reliance by authorized parties will be

subject to the terms, conditions, and limitations stated in the proposal, Supplemental LSI report,

and Terracon’s Agreement for Services. The limitation of liability defined in the terms and

conditions is the aggregate limit of Terracon’s liability to Deerfield Land Corporation and all relying

parties unless otherwise agreed in writing.

4.0 SUPPLEMENTAL SOIL TESTING

Terracon has a commitment to the safety of all its employees. As such, and in accordance with

our Incident and Injury Free® safety culture, a site safety pre-task plan was developed to identify

potential safety concerns and prepare our personnel to handle conditions during field services.

Prior to commencement of daily on-site activities, Terracon held a meeting with assigned staff to

review the proposed work sequence and evaluate work practices for safe completion of the

project. Fieldwork was conducted by environmental staff with OSHA 1910.120 training. Terracon

contacted Sunshine 811 to mark locations of underground utilities in the work area prior to

initiating intrusive activities. Soil sampling activities were conducted in general accordance with

the FDEP Standard Operating Procedures for Field Activities, DEP-SOP-001/01.

Soil sampling was conducted at 25 soil boring locations on June 21, 2018. Soil sampling locations

F1 to F25 are plotted on Exhibits 2 in Appendix A. Global positioning coordinates were recorded

at each soil boring location. Soil samples were collected using a decontaminated hand auger at

all of the boring locations at a depth 0 to 6 inches below ground surface (bgs). Deeper soil

samples above the groundwater table interface were collected at depths of 6 to 24 inches bgs

and 2 to 3 feet bgs or 2 to 4 feet bgs, depending on groundwater depth at the boring location.

The soil samples were placed in laboratory prepared glassware, labelled, and placed on ice in a

cooler sealed with custody tape. The sample coolers and completed chain-of-custody records

were relinquished to SGS North America Inc. – Orlando, for analysis of arsenic concentrations by

EPA Method 6010. The laboratory analytical report and chain-of-custody record are attached in





Appendix D. Table 1 in Appendix B contains a summary of soil sample locations with reference

to sample collection depths, date, groundwater depths, and measured arsenic concentrations.

Laboratory analytical results for soil samples were compared to SCTLs established for arsenic

listed in Chapter 62-777, FAC. In summary:

Arsenic concentrations reported in the soil samples did not exceed SCTLs, except at

sample location F11 where an arsenic concentration of 3.1 mg/kg was measured in the

sample collected from the surface to a depth of 6 inches bgs that exceeds the RSCTL for

direct exposure specified for residential settings of 2.1 mg/kg but does not exceed the

CSCTL for direct exposure specified for commercial settings of 12 mg/kg.

5.0 CONCLUSIONS

Based on the scope of services described in this report and subject to the limitations described

herein, Terracon concludes the following.

Arsenic concentrations reported in the soil samples did not exceed the SCTL applicable

for commercial settings. Based on our understanding that the site is proposed for

commercial development, additional assessment associated with the previous site use as

a golf course does not appear warranted.

APPENDIX A – EXHIBITS

NATIONAL GEODETIC VERTICAL DATUM OF 1929CONTOUR INTERVAL 5 FEET

RANGE:

Drawn By:

Checked By:

Approved By:

Project Mngr:

File No.

Date:

Scale:

Project No. EXHIBITTOPOGRAPHIC VICINITY MAP

1

1000090008000

1

6000

1000

0

5000 7000

2000

2

4000

0

0

3000

.5

1000

1

1000

0 2000

.5

1000

1

KILOMETERS

MILES

FEET

SCALE 1:24 000

7.5 MINUTE SERIES (QUADRANGLE)

N

EK

1

29 EAST

SW

EK

EK

H1177166A

AS SHOWN

H1177166A-1

6-25-18

SECTION:TOWNSHIP:

325 SOUTH

KISSIMMEE, FLORIDAISSUED: 1953 REVISED: 1987

Consulting Engineers and Scientists

1675 LEE ROAD WINTER PARK, FLORIDA 32789FAX. (407) 740-6112PH. (407) 740-6110 KISSIMMEE, OSCEOLA COUNTY, FLORIDA


LIMITED SITE INVESTIGATIONLOT 22

SITE

Drawn By:

Checked By:

Approved By:

Project Mngr:

File No.

Date:

Scale:

Project No. EXHIBITSOIL SAMPLE LOCATIONS MAPEK

2SW

EK

EK

H1177166A

AS SHOWN

H1177166A-2

6-29-18

Consulting Engineers and Scientists

1675 LEE ROAD WINTER PARK, FLORIDA 32789FAX. (407) 740-6112PH. (407) 740-6110 KISSIMMEE, OSCEOLA COUNTY, FLORIDA


LIMITED SITE INVESTIGATIONLOT 21

N

APPROXIMATE LOCATION OFSOIL BORING / SOIL SAMPLE

APPENDIX B – TABLES

F1-0.5 0 - 0.5 3 0.31 I

F1-2 0.5 - 2 3 0.088 U

F1-3 2 - 3 3 0.082 U

F2-0.5 0 - 0.5 2.9 0.11 U

F2-2 0.5 - 2 2.9 0.088 U

F2-3 2 - 3 2.9 0.11 U

F3-0.5 0 - 0.5 2.8 0.42 I

F3-2 0.5 - 2 2.8 1.3

F3-3 2 - 3 2.8 0.81

F4-0.5 0 - 0.5 3.8 0.090 I

F4-2 0.5 - 2 3.8 0.080 U

F4-4 2 - 4 3.8 0.12 U

F5-0.5 0 - 0.5 3.9 0.099 U

F5-2 0.5 - 2 3.9 0.083 U

F5-4 2 - 4 3.9 0.087 U

F6-0.5 0 - 0.5 1.9 0.11 U

F6-2 0.5 - 2 1.9 0.11 U

F7-0.5 0 - 0.5 2.2 0.30 I

F7-2 0.5 - 2 2.2 0.40 I

F8-0.5 0 - 0.5 1.8 0.46 I

F8-2 0.5 - 2 1.8 0.71

F9-0.5 0 - 0.5 1.8 0.11 U

F9-2 0.5 - 2 1.8 0.11 U

F10-0.5 0 - 0.5 1.8 0.12 U

F11-0.5 0 - 0.5 1.8 3.1

F11-2 0.5 - 2 2 0.098 U

F12-0.5 0 - 0.5 2 0.31 I

F12-2 0.5 - 2 2 0.077 U

F13-0.5 0 - 0.5 2.1 0.26 I

F13-2 0.5 - 2 2.1 0.096 U

F14-0.5 0 - 0.5 2 0.43 I

F14-2 0.5 - 2 2 0.11 I

F15-0.5 0 - 0.5 2 0.71

F15-2 0.5 - 2 2 0.29 I

F16-0.5 0 - 0.5 2.8 0.57

F16-2 0.5 - 2 2.8 0.43

F17-0.5 0 - 0.5 2 0.27 I

F17-2 0.5 - 2 2 0.11 U

F18-0.5 0 - 0.5 2 0.48 I

F18-2 0.5 - 2 2 0.15 I

F19-0.5 0 - 0.5 2 0.19 I

F19-2 0.5 - 2 2 0.10 U

F20-0.5 0 - 0.5 2 0.14 I

F20-2 0.5 - 2 2 0.099 U

Arsenic Concentration

(mg/kg)

Soil Sample

No.

Groundwater

Interface Depth

(ft)

Soil Arsenic Analytical Summary

Table 1

Lot 22

Soil Sample

Depth (ft)


Arsenic Concentration

(mg/kg)

Soil Sample

No.

Groundwater

Interface Depth

(ft)

Soil Arsenic Analytical Summary

Table 1

Lot 22

Soil Sample

Depth (ft)


F21-0.5 0 - 0.5 2 0.13 I

F21-2 0.5 - 2 2 0.24 I

F22-0.5 0 - 0.5 2 0.18 I

F22-2 0.5 - 2 2 0.087 I

F23-0.5 0 - 0.5 2 0.035 I

F23-2 0.5 - 2 2 0.10 U

F24-0.5 0 - 0.5 2 0.19 I

F24-2 0.5 - 2 2 0.062

F25-0.5 0 - 0.5 3.9 0.29 I

F25-2 0.5 - 2 3.9 0.123 I

F25-4 2 - 4 3.9 0.089 I

*

2.1

12

mg/kg = milligrams per kilogram

ft = feet below ground surface

Exceeds RSCTL

Exceeds CSCTL

** = Laboratory reported matrix interference

SCTL = Soil Cleanup Target Level per Chapter 62-777, Florida Administrative Code

Leachability Based on Groundwater Criteria (LSCTL)

Residential Direct Exposure SCTL (RSCTL)

Commercial/Industrial Direct Exposure (CSCTL)

* = Leachability value may be determined using Synthetic Precipitation Leachability Procedure

Notes:

APPENDIX C – PREVIOUS SOURCE REMOVAL REPORT

EXCERPTS

APPENDIX D – ANALYTICAL REPORTS AND CHAIN OF

CUSTODY

06/27/18

Technical Report for

Terracon Consulting

San Mateo; Kissimmee, FL

H1177166A

SGS Job Number: FA55261

Sampling Date: 06/21/18

Report to:

Terracon1675 Lee RdWinter Park, FL [email protected]

ATTN: Eric Krebill

Total number of pages in report:

Certifications: FL(E83510), LA(03051), KS(E-10327), IL(200063), NC(573), NJ(FL002), NY(12022), SC(96038001)

DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),

AK, AR, IA, KY, MA, MS, ND, NH, NV, OK, OR, UT, WA, WV

This report shall not be reproduced, except in its entirety, without the written approval of SGS.

Test results relate only to samples analyzed.

SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: 407-425-6700 • fax: 407-425-0707

Test results contained within this data package meet the requirements

of the National Environmental Laboratory Accreditation Program

and/or state specific certification programs as applicable.

Client Service contact: Ken Overstreet 407-425-6700

Caitlin Brice, M.S.General Manager

Orlando, FL 06/27/18

e-Hardcopy 2.0Automated Report

102

SGS is the sole authority for authorizing edits or modifications to this document.Unauthorized modification of this report is strictly prohibited.Review standard terms at: http://www.sgs.com/en/terms-and-conditions

The results set forth herein are provided by SGS North America Inc.

Please share your ideas abouthow we can serve you better at:[email protected]

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mailto:[email protected]?subject=Customer care improvement idea (report FA55261)

Table of Contents-1-

Sections:

Section 1: Sample Summary ................................................................................................... 4Section 2: Summary of Hits .................................................................................................... 9Section 3: Sample Results ........................................................................................................ 14

3.1: FA55261-1: F1-0.5 ........................................................................................................ 153.2: FA55261-2: F1-2 ........................................................................................................... 163.3: FA55261-3: F1-3 ........................................................................................................... 173.4: FA55261-4: F2-0.5 ........................................................................................................ 183.5: FA55261-5: F2-2 ........................................................................................................... 193.6: FA55261-6: F2-3 ........................................................................................................... 203.7: FA55261-7: F3-0.5 ........................................................................................................ 213.8: FA55261-8: F3-2 ........................................................................................................... 223.9: FA55261-9: F3-3 ........................................................................................................... 233.10: FA55261-10: F4-0.5 .................................................................................................... 243.11: FA55261-11: F4-2 ....................................................................................................... 253.12: FA55261-12: F4-4 ....................................................................................................... 263.13: FA55261-13: F5-0.5 .................................................................................................... 273.14: FA55261-14: F5-2 ....................................................................................................... 283.15: FA55261-15: F5-4 ....................................................................................................... 293.16: FA55261-16: F6-0.5 .................................................................................................... 303.17: FA55261-17: F6-2 ....................................................................................................... 313.18: FA55261-18: F7-0.5 .................................................................................................... 323.19: FA55261-19: F7-2 ....................................................................................................... 333.20: FA55261-20: F8-0.5 .................................................................................................... 343.21: FA55261-21: F8-2 ....................................................................................................... 353.22: FA55261-22: F9-0.5 .................................................................................................... 363.23: FA55261-23: F9-2' ...................................................................................................... 373.24: FA55261-24: F10-0.5 .................................................................................................. 383.25: FA55261-25: F11-0.5 .................................................................................................. 393.26: FA55261-26: F11-2 ..................................................................................................... 403.27: FA55261-27: F12-0.5 .................................................................................................. 413.28: FA55261-28: F12-2 ..................................................................................................... 423.29: FA55261-29: F13-0.5 .................................................................................................. 433.30: FA55261-30: F13-2 ..................................................................................................... 443.31: FA55261-31: F14-0.5 .................................................................................................. 453.32: FA55261-32: F14-2 ..................................................................................................... 463.33: FA55261-33: F15-0.5 .................................................................................................. 473.34: FA55261-34: F15-2 ..................................................................................................... 483.35: FA55261-35: F16-0.5 .................................................................................................. 493.36: FA55261-36: F16-2 ..................................................................................................... 503.37: FA55261-37: F17-0.5 .................................................................................................. 513.38: FA55261-38: F17-2 ..................................................................................................... 523.39: FA55261-39: F18-0.5 .................................................................................................. 53

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Table of Contents-2-

Sections:

3.40: FA55261-40: F18-2 ..................................................................................................... 543.41: FA55261-41: F19-0.5 .................................................................................................. 553.42: FA55261-42: F19-2 ..................................................................................................... 563.43: FA55261-43: F20-0.5 .................................................................................................. 573.44: FA55261-44: F20-2 ..................................................................................................... 583.45: FA55261-45: F21-0.5 .................................................................................................. 593.46: FA55261-46: F21-2 ..................................................................................................... 603.47: FA55261-47: F22-0.5 .................................................................................................. 613.48: FA55261-48: F22-2 ..................................................................................................... 623.49: FA55261-49: F23-0.5 .................................................................................................. 633.50: FA55261-50: F23-2 ..................................................................................................... 643.51: FA55261-51: F24-0.5 .................................................................................................. 653.52: FA55261-52: F24-2 ..................................................................................................... 663.53: FA55261-53: F25-0.5 .................................................................................................. 673.54: FA55261-54: F25-2 ..................................................................................................... 683.55: FA55261-55: F25-4 ..................................................................................................... 69

Section 4: Misc. Forms ............................................................................................................ 704.1: Chain of Custody ........................................................................................................... 71

Section 5: Metals Analysis - QC Data Summaries ................................................................ 775.1: Prep QC MP33930: As .................................................................................................. 785.2: Prep QC MP33933: As .................................................................................................. 855.3: Prep QC MP33934: As .................................................................................................. 915.4: Prep QC MP33941: As .................................................................................................. 97

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SGS North America Inc.

Sample Summary

Terracon ConsultingJob No: FA55261

San Mateo; Kissimmee, FLProject No: H1177166A

Sample Collected Matrix Client Number Date Time By Received Code Type Sample ID

FA55261-1 06/21/18 07:31 MBEK 06/21/18 SO Soil F1-0.5

FA55261-2 06/21/18 07:34 MBEK 06/21/18 SO Soil F1-2

FA55261-3 06/21/18 07:40 MBEK 06/21/18 SO Soil F1-3

FA55261-4 06/21/18 08:00 MBEK 06/21/18 SO Soil F2-0.5

FA55261-5 06/21/18 08:03 MBEK 06/21/18 SO Soil F2-2

FA55261-6 06/21/18 08:06 MBEK 06/21/18 SO Soil F2-3

FA55261-7 06/21/18 08:16 MBEK 06/21/18 SO Soil F3-0.5

FA55261-8 06/21/18 08:20 MBEK 06/21/18 SO Soil F3-2

FA55261-9 06/21/18 08:24 MBEK 06/21/18 SO Soil F3-3

FA55261-10 06/21/18 08:29 MBEK 06/21/18 SO Soil F4-0.5

FA55261-11 06/21/18 08:31 MBEK 06/21/18 SO Soil F4-2

FA55261-12 06/21/18 08:34 MBEK 06/21/18 SO Soil F4-4

FA55261-13 06/21/18 08:40 MBEK 06/21/18 SO Soil F5-0.5

Soil samples reported on a dry weight basis unless otherwise indicated on result page.

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Sample Summary(continued)




FA55261-14 06/21/18 08:42 MBEK 06/21/18 SO Soil F5-2

FA55261-15 06/21/18 08:45 MBEK 06/21/18 SO Soil F5-4

FA55261-16 06/21/18 09:25 MBEK 06/21/18 SO Soil F6-0.5

FA55261-17 06/21/18 09:27 MBEK 06/21/18 SO Soil F6-2

FA55261-18 06/21/18 09:36 MBEK 06/21/18 SO Soil F7-0.5

FA55261-19 06/21/18 09:40 MBEK 06/21/18 SO Soil F7-2

FA55261-20 06/21/18 09:51 MBEK 06/21/18 SO Soil F8-0.5

FA55261-21 06/21/18 09:54 MBEK 06/21/18 SO Soil F8-2

FA55261-22 06/21/18 10:08 MBEK 06/21/18 SO Soil F9-0.5

FA55261-23 06/21/18 10:14 MBEK 06/21/18 SO Soil F9-2'

FA55261-24 06/21/18 10:19 MBEK 06/21/18 SO Soil F10-0.5

FA55261-25 06/21/18 11:25 MBEK 06/21/18 SO Soil F11-0.5

FA55261-26 06/21/18 11:28 MBEK 06/21/18 SO Soil F11-2


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FA55261-27 06/21/18 11:32 MBEK 06/21/18 SO Soil F12-0.5

FA55261-28 06/21/18 11:33 MBEK 06/21/18 SO Soil F12-2

FA55261-29 06/21/18 11:36 MBEK 06/21/18 SO Soil F13-0.5

FA55261-30 06/21/18 11:39 MBEK 06/21/18 SO Soil F13-2

FA55261-31 06/21/18 11:42 MBEK 06/21/18 SO Soil F14-0.5

FA55261-32 06/21/18 11:44 MBEK 06/21/18 SO Soil F14-2

FA55261-33 06/21/18 11:47 MBEK 06/21/18 SO Soil F15-0.5

FA55261-34 06/21/18 11:50 MBEK 06/21/18 SO Soil F15-2

FA55261-35 06/21/18 11:57 MBEK 06/21/18 SO Soil F16-0.5

FA55261-36 06/21/18 12:00 MBEK 06/21/18 SO Soil F16-2

FA55261-37 06/21/18 12:07 MBEK 06/21/18 SO Soil F17-0.5

FA55261-38 06/21/18 12:10 MBEK 06/21/18 SO Soil F17-2

FA55261-39 06/21/18 12:18 MBEK 06/21/18 SO Soil F18-0.5


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FA55261-40 06/21/18 12:20 MBEK 06/21/18 SO Soil F18-2

FA55261-41 06/21/18 12:34 MBEK 06/21/18 SO Soil F19-0.5

FA55261-42 06/21/18 12:36 MBEK 06/21/18 SO Soil F19-2

FA55261-43 06/21/18 12:39 MBEK 06/21/18 SO Soil F20-0.5

FA55261-44 06/21/18 12:41 MBEK 06/21/18 SO Soil F20-2

FA55261-45 06/21/18 12:43 MBEK 06/21/18 SO Soil F21-0.5

FA55261-46 06/21/18 12:45 MBEK 06/21/18 SO Soil F21-2

FA55261-47 06/21/18 12:55 MBEK 06/21/18 SO Soil F22-0.5

FA55261-48 06/21/18 12:57 MBEK 06/21/18 SO Soil F22-2

FA55261-49 06/21/18 12:59 MBEK 06/21/18 SO Soil F23-0.5

FA55261-50 06/21/18 13:01 MBEK 06/21/18 SO Soil F23-2

FA55261-51 06/21/18 13:10 MBEK 06/21/18 SO Soil F24-0.5

FA55261-52 06/21/18 13:12 MBEK 06/21/18 SO Soil F24-2


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1






FA55261-53 06/21/18 13:16 MBEK 06/21/18 SO Soil F25-0.5

FA55261-54 06/21/18 13:17 MBEK 06/21/18 SO Soil F25-2

FA55261-55 06/21/18 13:19 MBEK 06/21/18 SO Soil F25-4


8 of 102

FA55261

1

Summary of Hits Page 1 of 5 Job Number: FA55261Account: Terracon ConsultingProject: San Mateo; Kissimmee, FLCollected: 06/21/18

Lab Sample ID Client Sample ID Result/Analyte Qual PQL MDL Units Method

FA55261-1 F1-0.5

Arsenic 0.31 I 0.44 0.089 mg/kg SW846 6010C

FA55261-2 F1-2

No hits reported in this sample.

FA55261-3 F1-3


FA55261-4 F2-0.5


FA55261-5 F2-2


FA55261-6 F2-3


FA55261-7 F3-0.5


FA55261-8 F3-2

Arsenic 1.3 0.48 0.096 mg/kg SW846 6010C

FA55261-9 F3-3

Arsenic 0.81 0.47 0.094 mg/kg SW846 6010C

FA55261-10 F4-0.5


FA55261-11 F4-2


9 of 102

FA55261

2



FA55261-12 F4-4


FA55261-13 F5-0.5


FA55261-14 F5-2


FA55261-15 F5-4


FA55261-16 F6-0.5


FA55261-17 F6-2


FA55261-18 F7-0.5


FA55261-19 F7-2


FA55261-20 F8-0.5


FA55261-21 F8-2

Arsenic 0.71 0.42 0.083 mg/kg SW846 6010C

FA55261-22 F9-0.5


10 of 102

FA55261

2



FA55261-23 F9-2'


FA55261-24 F10-0.5


FA55261-25 F11-0.5

Arsenic 3.1 0.50 0.10 mg/kg SW846 6010C

FA55261-26 F11-2


FA55261-27 F12-0.5


FA55261-28 F12-2


FA55261-29 F13-0.5


FA55261-30 F13-2


FA55261-31 F14-0.5


FA55261-32 F14-2


FA55261-33 F15-0.5

Arsenic 0.71 0.52 0.10 mg/kg SW846 6010C

11 of 102

FA55261

2



FA55261-34 F15-2


FA55261-35 F16-0.5

Arsenic 0.57 0.52 0.10 mg/kg SW846 6010C

FA55261-36 F16-2

Arsenic 0.43 0.41 0.082 mg/kg SW846 6010C

FA55261-37 F17-0.5


FA55261-38 F17-2


FA55261-39 F18-0.5


FA55261-40 F18-2


FA55261-41 F19-0.5


FA55261-42 F19-2


FA55261-43 F20-0.5


FA55261-44 F20-2


12 of 102

FA55261

2



FA55261-45 F21-0.5


FA55261-46 F21-2


FA55261-47 F22-0.5


FA55261-48 F22-2


FA55261-49 F23-0.5


FA55261-50 F23-2


FA55261-51 F24-0.5


FA55261-52 F24-2

Arsenic 0.62 0.42 0.084 mg/kg SW846 6010C

FA55261-53 F25-0.5


FA55261-54 F25-2


FA55261-55 F25-4


13 of 102

FA55261

2


Sample Results

Report of Analysis

Orlando, FLSection 3

14 of 102

FA55261

3


Report of Analysis Page 1 of 1

Client Sample ID: F1-0.5 Lab Sample ID: FA55261-1 Date Sampled: 06/21/18 Matrix: SO - Soil Date Received: 06/21/18

Percent Solids: 88.8 Project: San Mateo; Kissimmee, FL

Metals Analysis

Analyte Result PQL MDL Units DF Prep Analyzed By Method Prep Method

Arsenic 0.31 I 0.44 0.089 mg/kg 1 06/23/18 06/25/18 LM SW846 6010C 1 SW846 3050B 2

(1) Instrument QC Batch: MA14998(2) Prep QC Batch: MP33930

PQL = Practical Quantitation Limit U = Indicates a result < MDLMDL = Method Detection Limit I = Indicates a result >= MDL but < PQL

15 of 102

FA55261

33.1



Client Sample ID: F1-2 Lab Sample ID: FA55261-2 Date Sampled: 06/21/18 Matrix: SO - Soil Date Received: 06/21/18


Metals Analysis


Arsenic 0.088 U 0.44 0.088 mg/kg 1 06/23/18 06/25/18 LM SW846 6010C 1 SW846 3050B 2



16 of 102

FA55261

33.2





Metals Analysis





17 of 102

FA55261

33.3





Metals Analysis





18 of 102

FA55261

33.4





Metals Analysis





19 of 102

FA55261

33.5





Metals Analysis





20 of 102

FA55261

33.6





Metals Analysis





21 of 102

FA55261

33.7





Metals Analysis


Arsenic 1.3 0.48 0.096 mg/kg 1 06/23/18 06/25/18 LM SW846 6010C 1 SW846 3050B 2



22 of 102

FA55261

33.8





Metals Analysis





23 of 102

FA55261

33.9





Metals Analysis





24 of 102

FA55261

33.10





Metals Analysis





25 of 102

FA55261

33.11





Metals Analysis





26 of 102

FA55261

33.12





Metals Analysis





27 of 102

FA55261

33.13





Metals Analysis





28 of 102

FA55261

33.14





Metals Analysis





29 of 102

FA55261

33.15





Metals Analysis





30 of 102

FA55261

33.16





Metals Analysis





31 of 102

FA55261

33.17





Metals Analysis





32 of 102

FA55261

33.18





Metals Analysis





33 of 102

FA55261

33.19





Metals Analysis





34 of 102

FA55261

33.20





Metals Analysis





35 of 102

FA55261

33.21





Metals Analysis





36 of 102

FA55261

33.22



Client Sample ID: F9-2' Lab Sample ID: FA55261-23 Date Sampled: 06/21/18 Matrix: SO - Soil Date Received: 06/21/18


Metals Analysis





37 of 102

FA55261

33.23





Metals Analysis





38 of 102

FA55261

33.24





Metals Analysis





39 of 102

FA55261

33.25





Metals Analysis





40 of 102

FA55261

33.26





Metals Analysis





41 of 102

FA55261

33.27





Metals Analysis





42 of 102

FA55261

33.28





Metals Analysis





43 of 102

FA55261

33.29





Metals Analysis





44 of 102

FA55261

33.30





Metals Analysis





45 of 102

FA55261

33.31





Metals Analysis





46 of 102

FA55261

33.32





Metals Analysis





47 of 102

FA55261

33.33





Metals Analysis





48 of 102

FA55261

33.34





Metals Analysis





49 of 102

FA55261

33.35





Metals Analysis





50 of 102

FA55261

33.36





Metals Analysis





51 of 102

FA55261

33.37





Metals Analysis





52 of 102

FA55261

33.38





Metals Analysis





53 of 102

FA55261

33.39





Metals Analysis





54 of 102

FA55261

33.40





Metals Analysis





55 of 102

FA55261

33.41





Metals Analysis





56 of 102

FA55261

33.42





Metals Analysis





57 of 102

FA55261

33.43





Metals Analysis





58 of 102

FA55261

33.44





Metals Analysis





59 of 102

FA55261

33.45





Metals Analysis





60 of 102

FA55261

33.46





Metals Analysis





61 of 102

FA55261

33.47





Metals Analysis





62 of 102

FA55261

33.48





Metals Analysis





63 of 102

FA55261

33.49





Metals Analysis





64 of 102

FA55261

33.50





Metals Analysis





65 of 102

FA55261

33.51





Metals Analysis





66 of 102

FA55261

33.52





Metals Analysis





67 of 102

FA55261

33.53





Metals Analysis





68 of 102

FA55261

33.54





Metals Analysis





69 of 102

FA55261

33.55


Misc. Forms

Custody Documents and Other Forms

Includes the following where applicable:

• Chain of Custody


70 of 102

FA55261

4

FA55261: Chain of CustodyPage 1 of 6

71 of 102

FA55261

44.1


72 of 102

FA55261

44.1


73 of 102

FA55261

44.1


74 of 102

FA55261

44.1


75 of 102

FA55261

44.1

Job Number: FA55261 Client: TERRACON

Date / Time Received: 6/21/2018 2:01:00 PM Delivery Method: DROP OFF

Project: LOT 22

Airbill #'s:

Cooler Information

1. Custody Seals Present

2. Custody Seals Intact

4. Cooler temp verification

3. Temp criteria achieved

5. Cooler media

IR Gun

Ice (Bag)

Trip Blank Information

1. Trip Blank present / cooler

2. Trip Blank listed on COC

2. Samples preserved properly

Sample Information

1. Sample labels present on bottles

5. Sample recvd within HT

4. Condition of sample

3. Sufficient volume/containers recvd for analysis:

Intact

Comments SAMPLE #9 THROUGH #12 NO ANALYSIS MARKED. SAMPLE #12 NO SAMPLE ID WRITTEN ON COC. BOTTLE LABEL READS F4-4.

SM001Rev. Date 05/24/17

SGS Sample Receipt Summary

Cooler Temps (Raw Measured) °C:

Cooler Temps (Corrected) °C:

Cooler 1: (3.9); Cooler 2: (4.3);

Cooler 1: (4.0); Cooler 2: (4.4);

3. Type Of TB Received

W or S N/A

6. Dates/Times/IDs on COC match Sample Label

7. VOCs have headspace

8. Bottles received for unspecified tests

9. Compositing instructions clear

10. Voa Soil Kits/Jars received past 48hrs?

11. % Solids Jar received?

Misc. Information

25-Gram 5-GramNumber of Encores: Number of 5035 Field Kits: Number of Lab Filtered Metals:

Test Strip Lot #s: pH 0-3 230315 pH 10-12 219813A Other: (Specify)

Y or N N/A

Y or N

Therm ID: IR 1; Therm CF: 0.1; # of Coolers: 2

Y or N N/A

12. Residual Chlorine Present?

Residual Chlorine Test Strip Lot #:

Technician: Reviewer:PhilipD Date:Date: 6/21/2018 2:01:00 PM


76 of 102

FA55261

44.1


Metals Analysis

QC Data Summaries

Includes the following where applicable:

• Method Blank Summaries• Matrix Spike and Duplicate Summaries• Blank Spike and Lab Control Sample Summaries• Serial Dilution Summaries


77 of 102

FA55261

5

BLANK RESULTS SUMMARY Part 2 - Method Blanks

Login Number: FA55261 Account: TERCFLWP - Terracon Consulting

Project: San Mateo; Kissimmee, FL

QC Batch ID: MP33930 Methods: SW846 6010C Matrix Type: SOLID Units: mg/kg

Prep Date: 06/23/18

MB Metal RL IDL MDL raw final

Aluminum 10 .7 1.8

Antimony 1.0 .05 .065

Arsenic 0.50 .065 .1 -0.23 <0.50

Barium 10 .05 .05

Beryllium 0.25 .01 .025

Cadmium 0.20 .01 .025

Calcium 250 2.5 2.5

Chromium 0.50 .05 .05

Cobalt 2.5 .01 .025

Copper 1.3 .05 .05

Iron 15 .85 .85

Lead 1.0 .05 .05

Magnesium 250 1.8 1.8

Manganese 0.75 .025 .025

Molybdenum 2.5 .015 .025

Nickel 2.0 .02 .025

Potassium 500 10 10

Selenium 1.0 .12 .12

Silver 0.50 .035 .041

Sodium 500 25 25

Strontium 0.50 .025 .025

Thallium 0.50 .055 .055

Tin 2.5 .045 .045

Titanium 0.50 .025 .025

Vanadium 2.5 .025 .025

Zinc 1.0 .15 .15

Associated samples MP33930: FA55261-1, FA55261-2, FA55261-3, FA55261-4, FA55261-5, FA55261-6, FA55261-7,FA55261-8, FA55261-9, FA55261-10

Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(anr) Analyte not requested

_________________________________________________________________________________________________________

Page 1

78 of 102

FA55261

55.1.1

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY




Prep Date: 06/23/18 06/23/18

FA55117-1 QC FA55117-1 QC Metal Original DUP RPD Limits Original DUP RPD Limits

Aluminum anr

Antimony

Arsenic 2.8 3.4 (a) 19.4 0-20 2.8 3.0 (a) 6.9 0-20

Barium anr

Beryllium

Cadmium anr

Calcium

Chromium anr

Cobalt

Copper

Iron

Lead anr

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium anr

Silver anr

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits(anr) Analyte not requested(a) Sample dilution required due to difficult matrix.

_________________________________________________________________________________________________________

Page 1

79 of 102

FA55261

55.1.2





Prep Date: 06/23/18

FA55117-1 Spikelot QC Metal Original MS MPFLICP2 % Rec Limits

Aluminum anr

Antimony

Arsenic 2.8 70.5 (a) 95.2 71.1N(b) 80-120

Barium anr

Beryllium

Cadmium anr

Calcium

Chromium anr

Cobalt

Copper

Iron

Lead anr

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium anr

Silver anr

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits(anr) Analyte not requested(a) Sample dilution required due to difficult matrix.(b) Spike recovery indicates possible matrix interference and/or sample non-homogeneity.

_________________________________________________________________________________________________________

Page 2

80 of 102

FA55261

55.1.2





Prep Date: 06/23/18

FA55117-1 Spikelot MSD QC Metal Original MSD MPFLICP2 % Rec RPD Limit

Aluminum anr

Antimony

Arsenic 2.8 67.6 (a) 90.9 71.3N(b) 4.2 20

Barium anr

Beryllium

Cadmium anr

Calcium

Chromium anr

Cobalt

Copper

Iron

Lead anr

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium anr

Silver anr

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits(anr) Analyte not requested(a) Sample dilution required due to difficult matrix.(b) Spike recovery indicates possible matrix interference and/or sample non-homogeneity.

_________________________________________________________________________________________________________

Page 3

81 of 102

FA55261

55.1.2

SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY




Prep Date: 06/23/18

BSP Spikelot QC Metal Result MPFLICP2 % Rec Limits

Aluminum anr

Antimony

Arsenic 93.7 100 93.7 80-120

Barium anr

Beryllium

Cadmium anr

Calcium

Chromium anr

Cobalt

Copper

Iron

Lead anr

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium anr

Silver anr

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc



_________________________________________________________________________________________________________

Page 1

82 of 102

FA55261

55.1.3

SERIAL DILUTION RESULTS SUMMARY



QC Batch ID: MP33930 Methods: SW846 6010C Matrix Type: SOLID Units: ug/l

Prep Date: 06/23/18

FA55117-1 QC Metal Original SDL 10:50%DIF Limits

Aluminum anr

Antimony

Arsenic 59.7 0.00 100.0(a) 0-10

Barium anr

Beryllium

Cadmium anr

Calcium

Chromium anr

Cobalt

Copper

Iron

Lead anr

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium anr

Silver anr

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(anr) Analyte not requested(a) Percent difference acceptable due to low initial sample concentration (< 50 times IDL).

_________________________________________________________________________________________________________

Page 1

83 of 102

FA55261

55.1.4

POST DIGESTATE SPIKE SUMMARY




Prep Date: 06/23/18

Sample Final FA55117-1 PS Spike Spike Spike QC Metal ml ml Raw Corr.** ug/l ml ug/ml ug/l % Rec Limits

Aluminum

Antimony

Arsenic 9.8 10 59.7 58.506 164.9 0.2 5 100 106.4 80-120

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(**) Corr. sample result = Raw * (sample volume / final volume)(anr) Analyte not requested

_________________________________________________________________________________________________________

Page 1

84 of 102

FA55261

55.1.5





Prep Date: 06/25/18


Aluminum 10 .7 1.8

Antimony 1.0 .05 .065

Arsenic 0.50 .065 .1 -0.22 <0.50

Barium 10 .05 .05

Beryllium 0.25 .01 .025

Cadmium 0.20 .01 .025

Calcium 250 2.5 2.5

Chromium 0.50 .05 .05

Cobalt 2.5 .01 .025

Copper 1.3 .05 .05

Iron 15 .85 .85

Lead 1.0 .05 .05


Manganese 0.75 .025 .025


Nickel 2.0 .02 .025

Potassium 500 10 10


Silver 0.50 .035 .041

Sodium 500 25 25

Strontium 0.50 .025 .025

Thallium 0.50 .055 .055

Tin 2.5 .045 .045

Titanium 0.50 .025 .025

Vanadium 2.5 .025 .025

Zinc 1.0 .15 .15

Associated samples MP33933: FA55261-11, FA55261-12, FA55261-13, FA55261-14, FA55261-15, FA55261-16,FA55261-17, FA55261-18, FA55261-19, FA55261-20, FA55261-21, FA55261-22, FA55261-23, FA55261-24, FA55261-25, FA55261-26, FA55261-27, FA55261-28, FA55261-29, FA55261-30


_________________________________________________________________________________________________________

Page 1

85 of 102

FA55261

55.2.1





Prep Date: 06/25/18 06/25/18

FA55261-11 QC FA55261-11 Spikelot QC Metal Original DUP RPD Limits Original MS MPFLICP2 % Rec Limits

Aluminum

Antimony

Arsenic 0.0 0.0 NC 0-20 0.0 79.4 86.8 91.5 80-120

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits(anr) Analyte not requested

_________________________________________________________________________________________________________

Page 1

86 of 102

FA55261

55.2.2





Prep Date: 06/25/18


Aluminum

Antimony

Arsenic 0.0 85.7 91.6 93.5 7.6 20

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc



_________________________________________________________________________________________________________

Page 2

87 of 102

FA55261

55.2.2





Prep Date: 06/25/18


Aluminum

Antimony

Arsenic 93.4 100 93.4 80-120

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc



_________________________________________________________________________________________________________

Page 1

88 of 102

FA55261

55.2.3





Prep Date: 06/25/18

FA55261-11 QC Metal Original SDL 1:5 %DIF Limits

Aluminum

Antimony

Arsenic 0.00 0.00 NC 0-10

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc



_________________________________________________________________________________________________________

Page 1

89 of 102

FA55261

55.2.4





Prep Date: 06/25/18


Aluminum

Antimony

Arsenic 9.8 10 96.1 0.2 5 100 96.1 80-120

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc



_________________________________________________________________________________________________________

Page 1

90 of 102

FA55261

55.2.5





Prep Date: 06/25/18


Aluminum 10 .7 1.8

Antimony 1.0 .05 .065

Arsenic 0.50 .065 .1 -0.030 <0.50

Barium 10 .05 .05

Beryllium 0.25 .01 .025

Cadmium 0.20 .01 .025

Calcium 250 2.5 2.5

Chromium 0.50 .05 .05

Cobalt 2.5 .01 .025

Copper 1.3 .05 .05

Iron 15 .85 .85

Lead 1.0 .05 .05


Manganese 0.75 .025 .025


Nickel 2.0 .02 .025

Potassium 500 10 10


Silver 0.50 .035 .041

Sodium 500 25 25

Strontium 0.50 .025 .025

Thallium 0.50 .055 .055

Tin 2.5 .045 .045

Titanium 0.50 .025 .025

Vanadium 2.5 .025 .025

Zinc 1.0 .15 .15



_________________________________________________________________________________________________________

Page 1

91 of 102

FA55261

55.3.1





Prep Date: 06/25/18 06/25/18


Aluminum

Antimony

Arsenic 0.43 0.43 0.0 0-20 0.43 95.7 98.6 96.6 80-120

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc



_________________________________________________________________________________________________________

Page 1

92 of 102

FA55261

55.3.2





Prep Date: 06/25/18


Aluminum

Antimony

Arsenic 0.43 111 116 95.0 14.8 20

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc



_________________________________________________________________________________________________________

Page 2

93 of 102

FA55261

55.3.2





Prep Date: 06/25/18


Aluminum

Antimony

Arsenic 94.4 100 94.4 80-120

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc



_________________________________________________________________________________________________________

Page 1

94 of 102

FA55261

55.3.3





Prep Date: 06/25/18


Aluminum

Antimony

Arsenic 7.70 8.00 3.9 0-10

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc



_________________________________________________________________________________________________________

Page 1

95 of 102

FA55261

55.3.4





Prep Date: 06/25/18


Aluminum

Antimony

Arsenic 9.8 10 7.7 7.546 106 0.2 5 100 98.5 80-120

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc



_________________________________________________________________________________________________________

Page 1

96 of 102

FA55261

55.3.5





Prep Date: 06/26/18


Aluminum 10 .7 1.8

Antimony 1.0 .05 .065

Arsenic 0.50 .065 .1 -0.040 <0.50

Barium 10 .05 .05

Beryllium 0.25 .01 .025

Cadmium 0.20 .01 .025

Calcium 250 2.5 2.5

Chromium 0.50 .05 .05

Cobalt 2.5 .01 .025

Copper 1.3 .05 .05

Iron 15 .85 .85

Lead 1.0 .05 .05


Manganese 0.75 .025 .025


Nickel 2.0 .02 .025

Potassium 500 10 10


Silver 0.50 .035 .041

Sodium 500 25 25

Strontium 0.50 .025 .025

Thallium 0.50 .055 .055

Tin 2.5 .045 .045

Titanium 0.50 .025 .025

Vanadium 2.5 .025 .025

Zinc 1.0 .15 .15

Associated samples MP33941: FA55261-51, FA55261-52, FA55261-53, FA55261-54, FA55261-55


_________________________________________________________________________________________________________

Page 1

97 of 102

FA55261

55.4.1





Prep Date: 06/26/18 06/26/18


Aluminum

Antimony

Arsenic 0.19 0.23 19.0 0-20 0.19 86.5 87.1 99.1 80-120

Barium

Beryllium

Cadmium anr

Calcium

Chromium anr

Cobalt

Copper

Iron

Lead anr

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc



_________________________________________________________________________________________________________

Page 1

98 of 102

FA55261

55.4.2





Prep Date: 06/26/18


Aluminum

Antimony

Arsenic 0.19 86.9 78.3 110.7 0.5 20

Barium

Beryllium

Cadmium anr

Calcium

Chromium anr

Cobalt

Copper

Iron

Lead anr

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc



_________________________________________________________________________________________________________

Page 2

99 of 102

FA55261

55.4.2





Prep Date: 06/26/18


Aluminum

Antimony

Arsenic 99.7 100 99.7 80-120

Barium

Beryllium

Cadmium anr

Calcium

Chromium anr

Cobalt

Copper

Iron

Lead anr

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc



_________________________________________________________________________________________________________

Page 1

100 of 102

FA55261

55.4.3





Prep Date: 06/26/18


Aluminum

Antimony

Arsenic 3.60 0.00 100.0(a) 0-10

Barium

Beryllium

Cadmium anr

Calcium

Chromium anr

Cobalt

Copper

Iron

Lead anr

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(anr) Analyte not requested(a) Percent difference acceptable due to low initial sample concentration (< 50 times IDL).

_________________________________________________________________________________________________________

Page 1

101 of 102

FA55261

55.4.4





Prep Date: 06/26/18


Aluminum

Antimony

Arsenic 9.8 10 3.6 3.528 107.8 0.2 5 100 104.3 80-120

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc



_________________________________________________________________________________________________________

Page 1

102 of 102

FA55261

55.4.5