34
TO: COMPANY NAME: SUBMITTED TO: SUBMITTAL REQUEST FORM SUBMITTAL DATE: PROJECT: PRODUCT INFORMATION: SUBMITTED PRODUCT: SPECIFIED PRODUCT: SECTION: PAGE: PARAGRAPH: DETAIL/SHEET NO.: DESCRIPTION OF APPLICATION: FOR ARCHITECT/ENGINEER USE: SUBMITTED BY: APPROVED: BRIEF EXPLANTATION, IF NOT APPROVED: NAME: COMPANY NAME: SIGNATURE: ADDRESS: PHONE: FAX: EMAIL: DATE: APPROVED AS NOTED: NOT APPROVED: BY: REMARKS: DATE: This submial package contains the product data sheet, installaon instrucons and safety data sheet needed for evaluaon of this submial request. www.atcepoxy.com 1.800.892.1880 ACCU-GROUT HD

SUBMITTAL REQUEST FORM

  • Upload
    others

  • View
    11

  • Download
    0

Embed Size (px)

Citation preview

Page 1: SUBMITTAL REQUEST FORM

TO:

COMPANY NAME:

SUBMITTED TO:

SUBMITTAL REQUEST FORM

SUBMITTAL DATE:

PROJECT:

PRODUCT INFORMATION:

SUBMITTED PRODUCT:

SPECIFIED PRODUCT:

SECTION: PAGE: PARAGRAPH: DETAIL/SHEET NO.:

DESCRIPTION OF APPLICATION:

FOR ARCHITECT/ENGINEER USE:

SUBMITTED BY:

APPROVED:

BRIEF EXPLANTATION, IF NOT APPROVED:

NAME:

COMPANY NAME:

SIGNATURE:

ADDRESS:

PHONE:

FAX:EMAIL:

DATE:

APPROVED AS NOTED: NOT APPROVED:

BY:

REMARKS:

DATE:

This submittal package contains the product data sheet, installation instructions and safety data sheet needed for evaluation of this submittal request.

www.atcepoxy.com 1.800.892.1880

ACCU-GROUT HD

Page 2: SUBMITTAL REQUEST FORM

Florida, USA | 1.800.892.1880 | WWW.ATCEPOXY.COM 1

Revision 1.3

EPOXY GROUT

Product DescriptionACCU-GROUT products are three-component, pre-proportioned, industrial grade epoxy grouting systems. ACCU-GROUT is a general construction epoxy ACCU-GROUT HD is a high strength construction epoxy ACCU-GROUT LE is a low exotherm, high strength construction epoxyThe recommended application temperature range for the grout products is between 60 °F - 95 °F (16 °C - 35 °C).

General Uses & Applications Machine base plate grouts for use in heavy equipment industries such as wind farms, gas transmissions, chemical processingandrefiningfacilities,pulpandpapermills,steelrail seating for railroads and gantry cranes and marine Designed for high-stress base plate grouting applications in the applications heavy industrial equipment industries, new equipment installations or quick re-grouting applications that are subject to chemical attack and extreme vibration or impact loading

Advantages & Features Designed for high impact resistance, dynamic or static loading conditions High early strength Greater flowability and effective bearing area Excellent oil and chemical resistance Low dust performance Precision grouting with negligible shrinkage and creep Ready to mix in pre-measured units Low toxicity Easy soap and water clean up Designed for dynamic and static loading Made in the USA

Availability: Adhesives Technology Corp. (ATC) products are available online and through select distributors serving all your construction needs. Please contact ATC for a distributor near you or visit www.atcepoxy.com to search for a distributor by zip code.

Color: ACCU-GROUT - Part A (Resin) Gray: Part B (Hardener) Amber, Mixed Color - Concrete Gray

ACCU-GROUT HD - Part A (Resin) Gray: Part B (Hardener) Amber, Mixed Color - Concrete Gray

ACCU-GROUT LE - Part A (Resin) Gray: Part B (Hardener) Amber, Mixed Color - Concrete Gray

Storage & Shelf Life: For best results, store between 40 °F (4 °C) and 95 °F (35 °C). Shelf life is 24 months when stored in unopened containers in dry conditions.

Installation: Installation Instructions are available within this Technical Data Sheet (TDS). Due to occasional updates and revisions, always verify the most current usage. In order to achieve maximum results, proper installation is imperative.

Clean-Up: Always wear appropriate personal protective equipment such as safety glasses and gloves. Clean uncured materials from tools and equipment using a mild solvent, such as a citrus based product or denatured alcohol. Cured material can only be removed mechanically using a sander or grinder.

Limitations & Warnings: For professional use only Do not thin with solvents, as this will prevent cure Do not mix partial kits Settling may occur during storage; scraping bottom of pails for thorough mixing is imperative Substrate temperature should be a minimum of 50 °F (10 °C) Consult ATC when mixing or placing outside recommended temperature range ACCU-GROUT - Maximum pour depth is 8 in. ACCU-GROUT HD - Maximum pour depth is 6 in. ACCU-GROUT LE - Maximum pour depth is 22 in.

Safety: Please refer to the Safety Data Sheet (SDS) for ACCU-GROUT products published on ATC’s website or call for more information at 1-800-892-1880.

Epoxy Grouts

ACCU GROUT

Page 3: SUBMITTAL REQUEST FORM

1.3

Florida, USA | 1.800.892.1880 | WWW.ATCEPOXY.COM

Revision

2

EPOXY GROUTACCU GROUT

Part # AG051 AG202

Pallet Qty. 72 Kits (A/B only) 36 ea. Part A144 ea. Part B

Pallet Weight (lb.) 835 2,710

1. 0.5 ft3 kit includes Part A and Part B in a box: part # B1G-AG and one 58 lb. bag of grout blend: part # AG-GB58#.2. 2.0 ft3 kit includes Part A: part # B3.2G-AG-A, Part B: part # B1G-AG-B and four 58 lb. bags of grout blend: part # AG-GB58#.

TABLE 1: ACCU-GROUT

Package Size 0.5 ft3

Kit2.0 ft3

Kit

Advantages & Features Featureshighearlystrength,lowdust,highbearingarea,negligibleshrinkageandcreep,andexcellentflowability

General Construction Epoxy Grout

psi 14,500(MPa) (100)

psi 2,200,000(MPa) (15,168)

psi 3,200(MPa) (22.1)

psi 1,900,000(MPa) (13,100)

psi 4,000(MPa) (27.6)

psi 5,000(MPa) (34.5)

psi 2,000,000(MPa) (13,790)

°F 170(°C) (77)

Water Absorption C413

1. Results based on testing conducted on a representative lot(s) of product. Average results will vary according to the tolerances of the given property.2. Results may vary due to environmental factors such as temperature, moisture and type of substrate.

% 0.05

LinearShrinkage on Cure C531 % 0.007

Property ASTMStandard Units Result

TABLE 2: ACCU-GROUT performance to ASTM Standards1,2

Compressive Modulus

Tensile StrengthC307

TensileModulus of Elasticity

Compressive Creep(400 psi at 140 °F)

C579

Gel Time D2471 min 120

Compressive Strength

in/in <0.005C1181

----

in/(in-°F) 18x10-6

C882

C884

C531

C580

Pass

D2471

---- Self-Extinguishing

Peak Exotherm

D635

Bond Strength

Flexural Strength

Thermal Compatibility

Coefficient ofThermal Expansion

Fire Resistance

Modulus of Elasticity

55 11,500

(13) (79.3)

65 12,900

(18) (88.9)

75 14,500

(24) (100)

85 15,700

(29) (108)

95 17,100

(35) (118)

105 18,000

(41) (124)

1. Epoxy resins are temperature sensitive and care should be taken to condition all parts, including Part C-Aggregate, between 65 °F - 85 °F (18 °C - 29 °C) for a minimum of 24 hrs. prior to mixing and placement. Temperatures colder than stated range increase viscosity of resins and inhibit mixing and flow of materials. Temperatures warmer than stated range decrease viscosity of resins, hasten the cure and reduce the working time.

15 hr

InitialCure

5 hr 40 hr

Cure TimeTemperature

°F(°C)

TABLE 3: ACCU-GROUT CURE SCHEDULE1

25 min 9 hr

WorkingTime

4 hr

2.5 hr

55 min

40 min

36 hr

30 hr

24 hr

CompressiveStrength

psi(MPa)

AG05 AG-GB58#

AG20

Page 4: SUBMITTAL REQUEST FORM

1.3

Florida, USA | 1.800.892.1880 | WWW.ATCEPOXY.COM

Revision

3

EPOXY GROUT

psi 19,500(MPa) (134)

psi 2,200,000(MPa) (15,168)

psi 3,600(MPa) (24.8)

psi 2,100,000(MPa) (14,479)

psi 3,700(MPa) (25.5)

psi 5,800(MPa) (40.0)

psi 1,800,000(MPa) (12,411)

°F 210(°C) (99)

TABLE 5: ACCU-GROUT HD performance to ASTM Standards1,2

Gel Time D2471 min 40

Property ASTMStandard Units Results

Compressive Strengthat 95 °F (35 °C)

C579Compressive Modulus

Compressive Creep(400 psi at 140 °F) C1181

17x10-6

<0.005

Tensile StrengthC307

TensileModulus of Elasticity

Bond Strength C882

in/in

Flexural Strength

Coefficient ofThermal Expansion C531 in/(in-°F)

C580Modulus of Elasticity

Thermal Compatibility C884 ---- Pass

Peak Exotherm D2471

Fire Resistance D635 ---- Self-Extinguishing

Water Absorption C413 % 0.08

LinearShrinkage on Cure C531 % 0.007

1. Results based on testing conducted on a representative lot(s) of product. Average results will vary according to the tolerances of the given property.2. Results may vary due to environmental factors such as temperature, moisture and type of substrate.

Advantages & Features Designedforuseasahighstrengthgroutsuitableforonshoreandoffshorewindfarminstallations

High-Strength Wind Turbine Grout

Part # AGHD051 AGHD202

Pallet Qty. 72 Kits (A/B only) 36 ea. Part A144 ea. Part B

Pallet Weight (lb.) 835 2,710

TABLE 4: ACCU-GROUT HD Packaging

Package Size 0.5 ft3

Kit2.0 ft3

Kit

1. 0.5 ft3 kit includes Part A and Part B in a box: part # B1G-AGHD and one 58 lb. bag of grout blend: part # AG-GB58#.2. 2.0 ft3 kit includes Part A: part # B3.2G-AGHD-A, Part B: part # B1G-AGHD-B and four 58 lb. bags of grout blend: part # AG-GB58#.

Cure TimeTemperature

°F(°C)

WorkingTime

InitialCure

CompressiveStrength

psi(MPa)

55 15,500

(13) (107)

65 16,000

(18) (110.3)

75 17,500

(24) (121)

85 18,200

(29) (125)

95 19,000

(35) (131)

105 21,000

(41) (145)

1 hr 42 hr

TABLE 6: ACCU-GROUT HD CURE SCHEDULE1

2 hr 48 hr

15 min 20 hr

1. Epoxy resins are temperature sensitive and care should be taken to condition all parts, including Part C-Aggregate, between 65 °F - 85 °F (18 °C - 29 °C) for a minimum of 24 hrs. prior to mixing and placement. Temperatures colder than stated range increase viscosity of resins and inhibit mixing and flow of materials. Temperatures warmer than stated range decrease viscosity of resins, hasten the cure and reduce the working time.

45 min 36 hr

30 min 30 hr

20 min 24 hr

AGHD05 AG-GB58#

AGHD20

Page 5: SUBMITTAL REQUEST FORM

1.3

Florida, USA | 1.800.892.1880 | WWW.ATCEPOXY.COM

Revision

4

EPOXY GROUTLow Exotherm Epoxy Grout for Deep Placements

Part # AGLE051 AGLE202

Pallet Qty. 72 Kits (A/B only) 36 ea. Part A144 ea.Part B

Pallet Weight (lb.) 835 2,710

1. 0.5 ft3 kit includes Part A and Part B in a box: part # B1G-AGLE and one 58 lb. bag of grout blend: part # AG-GB58#.2. 2.0 ft3 kit includes Part A: part # B3.2G-AGLE-A, Part B: part # B1G-AGLE-B and four 58 lb. bags of grout blend: part # AG-GB58#.

TABLE 7: ACCU-GROUT LE Packaging

Package Size 0.5 ft3

Kit2.0 ft3

Kit

Advantages & Features Pumpable, low exotherm epoxy grout designed for deep pour or placement capabilities May be used in warm weather Extended pot life

psi 12,500(MPa) (86.2)

psi 2,100,000(MPa) (14,479)

psi 3,000(MPa) (20.7)

psi 1,800,000(MPa) (12,411)

psi 4,000(MPa) (27.6)

psi 4,600(MPa) (31.7)

psi 1,900,000(MPa) (13,100)

°F 108(°C) (42)

Property ASTMStandard Units Results

<0.005

min

in/in

300

Compressive Strengthat 75 °F (24 °C)

C579

Compressive Modulus

Compressive Creep(400 psi at 140 °F) C1181

Bond Strength C882

Gel Time D2471

C580

Modulus of Elasticity

Tensile Strength

C307Tensile

Modulus of Elasticity

1. Results based on testing conducted on a representative lot(s) of product. Average results will vary according to the tolerances of the given property.2. Results may vary due to environmental factors such as temperature, moisture and type of substrate.

Self-Extinguishing

Water Absorption C413 % 0.05

Fire Resistance D635 ----

TABLE 8: ACCU-GROUT LE performance to ASTM Standards1,2

LinearShrinkage on Cure C531 % 0.007

Peak Exotherm D2471

19x10-6

Thermal Compatibility C884 ---- Pass

Flexural Strength

Coefficient ofThermal Expansion C531 in/(in-°F)

Cure TimeTemperature

°F(°C)

WorkingTime

InitialCure

CompressiveStrength

psi(MPa)

55 9,800

(13) (67.6)

65 11,000

(18) (75.8)

75 12,500

(24) (86)

85 13,500

(29) (93)

95 14,600

(35) (101)

105 15,500

(41) (107)1 hr 12 hr

1. Epoxy resins are temperature sensitive and care should be taken to condition all parts, including Part C-Aggregate, between 65 °F - 85 °F (18 °C - 29 °C) for a minimum of 24 hrs. prior to mixing and placement. Temperatures colder than stated range increase viscosity of resins and inhibit mixing and flow of materials. Temperatures warmer than stated range decrease viscosity of resins, hasten the cure and reduce the working time.

4 hr 56 hr

3 hr 42 hr

2 hr 28 hr

5.5 hr 70 hr

TABLE 9: ACCU-GROUT LE CURE SCHEDULE1

7.5 hr 84 hr

AGLE05 AG-GB58#

AGLE20

Page 6: SUBMITTAL REQUEST FORM

1.3

Florida, USA | 1.800.892.1880 | WWW.ATCEPOXY.COM

Revision

5

EPOXY GROUTACCU GROUT

Surface PreparationConcrete shall have reached its design strength and surface shall be free of standing water (a saturated surface dry condition, although notnecessary,isacceptable).Allsurfacecontaminationmustberemovedbymechanicalmeans,creatingasurfaceprofileofexposedsound aggregate that will provide a strong bond surface for the grout. All metal surfaces to come in contact with the grout should be sandblastedtowhitemetalfinishandwipedcleanwithsolvent.Itemsnotintendedtobondtogrout,suchaslevelingscrews,wedgesandbolts must be protected with wax, caulk, duct tape or similar.

ACCU-GROUTS are shipped in pre-measured 0.5 cu. ft. or 2.0 cu. ft. units. Mix these products as complete units ONLY. NOTE: Refer to Limitations & Warnings section on page 1. IMPORTANT! All parts, including the aggregate, should be conditioned to a temperature between65⁰F(18⁰C)and85⁰F(29°C)foratleast24hourspriortouse.

0.5 cu. ft. kit contains: Part A: (1) 1-gallon pail (partialfill) Part B: (1) 1-gallon pail (partialfill) Part C : (1) 58 lb. bag grout blend

2.0cu.ft.kitcontains: PartA:(1)5-gallonpail(partialfill) Part B: (1) 1-gallon pail Part C: (4) 58 lb. bags grout blend

Mixer SelectionIt is imperative to select the proper mixing equipment for installation in order for products to perform as published. Failure to do so may also lead to serious equipment damage. When mixing the grout, it is recommendended to use a powerful (10 amp) electric mixer with a2-speedgearbox,suchas thosedesignedspecifically for themixingofcementitiousadhesivesandresins. If this isn'tavailable,apowerful 2-speed angle head drill may be used. NOTE: Do not use a standard carpentry power drill, as the motor will likely be damaged or destroyed.

Paddle SelectionAJiffyMixerpaddleisrecommendedforpropermixing.Thisisaheavydutymixingpaddlemadeentirelyofstainlesssteelforindustrialandcommercial applications.Withapatentedbladesystemdeveloped forefficientmixing -not just stirring -ofdenseandviscousmaterialsinanopencontainer,theJiffyMixerwillhelptoeliminatewastewhileminimizingunwantedaeration.

Mixing 0.5 cu. ft. KitPour Part B into Part A container. PlacetheJiffyMixerpaddleintothePartAcontainerthatnowcontainsbothPartsAandB.Besurethe paddle is completly submerged and start the mixer unit while the paddle remains submerged as the material mixes at a low speed of 300 rpm for 3 minutes. Use the paddle to scrape bottom of container during mixing to bring up any settled pigment. Once mixing is complete, allow all mixing motion to stop before the mixing unit is pulled out of the material. Failure to keep the mixing unit submerged and/or allowing the material to be mixed at high speeds is likely to cause unwanted air entrainment. After liquid parts are mixed, transfer all liquid into a separate container (not provided) and slowly add Part C (Aggregate). Mix on low speed until all aggregate is wetted out, stop mixer. DO NOT OVER MIX!

Bulk Mixing 2.0 cu.ft. KitThe proper mixing technique must be used in order for products to perform as published. For bulk mixing, it is recommended to use a mortar mixer (i.e. stucco mixer) where the shaft and paddle rotate to mix the material. NOTE: DO NOT use a standard drum mixer, where thedrumrotatesaroundfixedfinsorvanesusinggravitytomixthematerial.Mixingsandbasedmaterialsusingthistypeofequipmentcanbedifficult,astheytendtosticktothewallsofthedruminsteadoftumblingandchurningtocreatethepropermixneededtoperformas published. Pour Part B into Part A container andmixthoroughlyfor3minuteswithaJiffyMixerpadleonalow-speed(300rpm)drillmotor until a uniform consistency is achieved. NOTE: Keep paddle at bottom of pail to avoid introducing air. Pour liquids into mortar mixer, makingsuretoremoveallresinsfromsidesandbottomofpailwithspatulaorsimilartool.IntroducefirstbagofPartC(Aggregate)priorto starting mixer. Start mixer and slowly add the remaining three bags of aggregate. Mix on low speed until all aggregate is wetted out, stop mixer. DO NOT OVER MIX!

Epoxy Grouts

1

Installation Instructions

Page 7: SUBMITTAL REQUEST FORM

1.3

Florida, USA | 1.800.892.1880 | WWW.ATCEPOXY.COM

Revision

6

EPOXY GROUTACCU GROUT

Form PreparationEpoxy grouts require heavy-duty formwork to hold the grout in place until full cure is achieved. A sheet of 3/4 in. plywood or similar and proper bracing should be used to hold the force of the weight of the grout. Forms should be coated with a minimum of two coats of an industrial grade paste wax or similar, to facilitate removal of forms after cure. It is recommended that forms have 45 degree angle chamfer at all vertical corners. Caulk, putty or similar sealant should be used to render the forms "watertight". Forms should be at least ½ in. above bottom of base to allow for a hydraulic head to facilitate the placement of the grout.

ACCU-GROUTS shouldbepouredintoformsatonelocationinordertoallowaunidirectionalflow.Useofaheaderboxwilleasetheplacementof thefinishedproduct.Strictadherence to temperatureconsiderationswillassist theplacementproperties.Check formsfrequently for leaks. Plug leaks with a hydraulic cement or putty. ACCU-GROUTS do not self-seal.

FinishingWhenformsarefilledtodesiredelevation,exposedhorizontalsurfacesofthegroutmaybefinishedwithasurfactantsuchasanindustrialcitrus cleaner or an approved solvent using a paintbrush or small hand trowel. Surfactant should be lightly sprayed or misted on the surface. However, DO NOT PUDDLE onsurface.Thisprocesscanberepeatedevery30minutesuntilsurfacesarefirm.

Post CureSharp corners may need to be addressed. The use of an angle head grinder equipped with approved abrasive or diamond wheel is recommended. CAUTION: Cured edges of grout may be very sharp, use proper PPE when grinding and inspecting grout.

Epoxy Grouts

1

Installation Instructions

Page 8: SUBMITTAL REQUEST FORM

Conforms to HCS 2012 - United States

SAFETY DATA SHEET ACCU-GROUT HD Part A

I Section 1. Identification GHS product identifier

Other means of identification Product type

ACCU-GROUT HD Part A

Epoxy Grout

Relevant identified uses of the substance or mixture and uses advised against

I Identified uses Epoxy polymer grout.

Supplier's details Adhesives Technology Corp. 450 East Copans Road Pompano Beach, FL 33064 (800) 892-1880 (800) 362-3320 www.atcepoxy.com

Emergency telephone CHEM-TEL: (800) 255-3924 24/7 number (with hours of operation)

J Section 2. Hazards identification OSHA/HCS status

Classification of the substance or mixture

GHS label elements Hazard pictograms

Signal word Hazard statements

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1 AQUATIC HAZARD (LONG-TERM) - Category 2

Warning H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H411 - Toxic to aquatic life with long lasting effects.

Precautionary statements Prevention P280 - Wear protective gloves. Wear eye or face protection.

P273 - Avoid release to the environment. P261 -Avoid breathing vapor. P264 - Wash thoroughly after handling. P272 - Contaminated work clothing must not be allowed out of the workplace.

~ KMK Regulatory Services

Tel: +1-888-GHS-7769 (447-7769) I +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 1/13

Page 9: SUBMITTAL REQUEST FORM

I Section 2. Hazards identification ACCU-OROUTHDPARTAI

Response

Storage Disposal

Hazards not otherwise classified

P391 - Collect spillage. P362 + P364 - Take off contaminated clothing and wash it before reuse. P363 - Wash contaminated clothing before reuse. P302 + P352 - IF ON SKIN: Wash with plenty of water. P333 + P313 - If skin irritation or rash occurs: Get medical advice or attention. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists: Get medical advice or attention. Not applicable.

P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations. None known.

Section 3. Composition/information on ingredients Substance/mixture Other means of identification

Mixture

Ingredient name % CAS number Formaldehyde, Oligomeric Reaction Products with 1-Chloro- ~75 - S90 9003-36-5 2,3-Epoxypropane and Phenol 1,4-bis(2,3 Epoxypropoxy)butane ~10 - S22 2425-79-8

Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8.

I section 4. First aid measures Description of necessary first aid measures Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower

eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention.

Inhalation

Skin contact

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Wash with plenty of soap and water. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 20 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.

~ KMK Regulatory Services Tel: +1-888-GHS-7769 (447-7769) I +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 2113

Page 10: SUBMITTAL REQUEST FORM

I section 4. First aid measures ACCU-OROUTH~PARTAI

Ingestion Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact Inhalation Skin contact Ingestion

Causes serious eye irritation. No known significant effects or critical hazards. Causes skin irritation. May cause an allergic skin reaction. No known significant effects or critical hazards.

Over-exposure signs/symptoms Eye contact Adverse symptoms may include the following:

pain or irritation watering redness

Inhalation No known significant effects or critical hazards. Skin contact

Ingestion

Adverse symptoms may include the following: irritation redness No known significant effects or critical hazards.

Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if large

quantities have been ingested or inhaled. Specific treatments Protection of first-aiders

No specific treatment. No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

See toxicological information (Section 11)

!section 5. Fire-fighting measures Extinguishing media Suitable extinguishing media Unsuitable extinguishing media

Specific hazards arising from the chemical

Use an extinguishing agent suitable for the surrounding fire.

None known.

This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

~ KMK Regulatory Services

Tel: +1-888-GHS-7769 (447-7769) I +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 3113

Page 11: SUBMITTAL REQUEST FORM

ACCU-GROUT HD PART A I !section 5. Fire-fighting measures

Hazardous thermal decomposition products

Special protective actions for fire-fighters

Special protective equipment for fire-fighters

Decomposition products may include the following materials: carbon dioxide carbon monoxide halogenated compounds

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from

entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non­ emergency personnel".

For emergency responders

Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.

Methods and materials for containment and cleaning up Small spill Stop leak if without risk. Move containers from spill area. Dilute with water and mop up

if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

!section 7. Handling and storage Precautions for safe handling Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a

history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Avoid release to the environment. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

- KMK ~egulatory Services

Tel: +1-888-GHS-7769 (447-7769) I +1-450-GHS-77q7 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com

4113

Page 12: SUBMITTAL REQUEST FORM

ACCU-GROUT HD PART A I I Section 7. Handling and storage Advice on general occupational hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures.

Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.

Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits

Ingredient name Exposure limits

Formaldehyde, Oligomeric Reaction Products with 1-Chloro- None. 2,3-Epoxypropane and Phenol 1,4-bis(2,3 Epoxypropoxy)butane None.

Appropriate engineering controls Environmental exposure controls

Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.

Individual protection measures Hygiene measures

Eye/face protection

Skin protection Hand protection

Body protection

Other skin protection

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

~ KMK Regulatory Services

Tel: +1-888-GHS-7769 (447-7769) I +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com

5/13

Page 13: SUBMITTAL REQUEST FORM

ACCU-GROUT HD PART A I Section 8. Exposure controls/personal protection Respiratory protection Based on the hazard and potential for exposure, if required, select a respirator that

meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Section 9. Physical and chemical properties Appearance Physical state Color

Odor Odor threshold pH Melting point Boiling point Flash point Evaporation rate Flammability (solid, gas) Lower and upper explosive (flammable) limits Vapor pressure Vapor density Relative density Solubility Solubility in water Partition coefficient: n­ octanol/water Auto-ignition temperature Decomposition temperature Viscosity Flow time (ISO 2431) Volatile organic compounds

Liquid. [Viscous.] Clear. Mild. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available.

Not available. Not available. Not available. Not available. Not available. Not applicable.

Not available. Not available. Not available. Not available.

Section 10. Stability and reactivity Reactivity No specific test data related to reactivity available for this product or its ingredients.

Chemical stability The product is stable.

Possibility of hazardous reactions

Conditions to avoid

Incompatible materials

Under normal conditions of storage and use, hazardous reactions will not occur.

No specific data.

Reactive or incompatible with the following materials: oxidizing materials.

~ KMK Regulatory Services

Tel: +1-888-GHS-7769 (447-7769) I +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com

6/13

Page 14: SUBMITTAL REQUEST FORM

ACCU-GROUT HD PART A I Section 10. Stability and reactivity Hazardous decomposition products

: Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Section 11. Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure

1,4-bis(2,3 Epoxypropoxy) LOSO Dermal Rabbit 1130 mg/kg - butane

LOSO Oral Rat 1134 mg/kg -

Irritation/Carros ion

Product/ingredient name Result Species Score Exposure Observation

Formaldehyde, Oligomeric Skin - Mild irritant Rabbit - 24 hours 500 - Reaction Products with uL 1-Chloro-2,3-Epoxypropane and Phenol 1,4-bis(2,3 Epoxypropoxy) Eyes - Moderate irritant Rabbit - 100 mg - butane

Skin - Moderate irritant Rabbit - 24 hours 10 - mg

Sensitization There is no data available.

Mutagenicity There is no data available.

Carcinogenicity There is no data available. Reproductive toxicity There is no data available.

Teratogenicity There is no data available.

Specific target organ toxicity (single exposure) There is no data available.

Specific target organ toxicity (repeated exposure) There is no data available.

Aspiration hazard There is no data available.

Information on the likely routes of exposure Potential acute health effects Eye contact Inhalation Skin contact

Routes of entry anticipated: Oral, Dermal, Inhalation.

Causes serious eye irritation. No known significant effects or critical hazards. Causes skin irritation. May cause an allergic skin reaction.

~ KMK Regulatory Services

Tel: +1-888-GHS-7769 (447-7769) I +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com

7/13

Page 15: SUBMITTAL REQUEST FORM

ACCU-GROUT HD PART A I Section 11. Toxicological information Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics Eye contact Adverse symptoms may include the following:

pain or irritation watering redness

Inhalation No known significant effects or critical hazards. Skin contact

Ingestion

Adverse symptoms may include the following: irritation redness No known significant effects or critical hazards.

Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate effects

No known significant effects or critical hazards.

Potential delayed effects Long term exposure Potential immediate effects Potential delayed effects

Potential chronic health effects

No known significant effects or critical hazards.

No known significant effects or critical hazards.

No known significant effects or critical hazards.

General

Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects

Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards.

Numerical measures of toxicity Acute toxicitv estimates Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation

kg) (mg/kg) (gases) (vapors) (dusts and (ppm) (mg/I) mists) (mg/

I)

ACCU-GROUT HD Part A 1,4- 7662.2 7635.1 N/A 74.3 N/A bis(2,3 Epoxypropoxy)butane 1134 1130 N/A 11 N/A

~ K.MK Regulatory Services

Tel: +1-888-GHS-7769 (447-7769) I +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com

8/13

Page 16: SUBMITTAL REQUEST FORM

ACCU-OROUTHDPARTAI

Section 12. Ecological information Toxicity There is no data available.

Persistence and degradability There is no data available.

Bioaccumulative potential Product/ingredient name LogPaw BCF Potential

Formaldehyde, Oligomeric 2.7 - low Reaction Products with 1-Chloro-2, 3-Epoxypropane and Phenol 1,4-bis(2,3 Epoxypropoxy) -0.269 - low butane

Mobility in soil Soil/water partition coefficient (Koc)

Other adverse effects

Not available.

: No known significant effects or critical hazards.

Section 13. Disposal considerations Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal

of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

I Section 14. Transport information DOT Classification IMDG IATA

UN number Not regulated. UN3082 UN3082

UN proper - ENVIRONMENTALLY ENVIRONMENTALLY shipping name HAZARDOUS SUBSTANCE, HAZARDOUS SUBSTANCE,

LIQUID, N.O.S. (Formaldehyde, LIQUID, N.O.S. (Formaldehyde, Oligomeric Reaction Products Oligomeric Reaction Products with 1-Chloro-2,3-Epoxypropane with 1-Chloro- and Phenol) 2,3-Epoxypropane and Phenol)

- KMK Regulatory Services

Tel: +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com

9/13

Page 17: SUBMITTAL REQUEST FORM

AADHESIVES T!E""n..~~!~R .o~:.. -

!Section 14. Transport information I

Transport - 9 9 hazard class{es)

~~ ~~

Packing group - 111 111

Environmental No. Yes. Yes. hazards

ACCU GROUT HD PART A I

AERG : 171 Additional information The limited quantity exception can be used for the transportation of this item. Certain restrictions may apply in regards to sizes and packaging. IMDG This product is not regulated as a dangerous good when transported in sizes of =,;5 L or

=,;5 kg, provided the packagings meet the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8.

IATA This product is not regulated as a dangerous good when transported in sizes of =,;5 Lor =,;5 kg, provided the packagings meet the general provisions of 5.0.2.4.1, 5.0.2.6.1.1 and 5.0.2.8.

Special precautions for user Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

Transport in bulk according : Not available. to IMO instruments

!section 15. Regulatory information U.S. Federal regulations

Clean Air Act Section 112 {b) Hazardous Air Pollutants {HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances DEA List I Chemicals {Precursor Chemicals) DEA List II Chemicals {Essential Chemicals)

TSCA 8{a) PAIR: Naphthalene TSCA 8{a) CDR Exempt/Partial exemption: Not determined Clean Water Act {CWA) 307: Naphthalene Clean Water Act {CWA) 311: Naphthalene; 1-Chloro-2,3-epoxypropane

Listed

Not listed

Not listed

Not listed

Not listed

- KMK Regulatory Services Tel: +1-888-GHS-7769 (447-7769) I +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 10/13

Page 18: SUBMITTAL REQUEST FORM

I A~HESIVES

!section 15. Regulatory information ACCU-OROUTHDPARTAI

SARA 302/304 Composition/information on ingredients

SARA 302 TPQ SARA 304 RQ

Name % EHS (lbs) (gallons) (lbs) (gallons) 1-Chloro-2,3-epoxypropane $0.001 Yes. 1000 101.6 100 10.2

SARA304 RQ SARA 311/312 Classification

: 67567567.6 lbs/ 30675675.7 kg

SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1

Composition/information on ingredients Name % Classification Formaldehyde, Oligomeric ~75 - :;;go SKIN CORROSION/IRRITATION - Category 2 Reaction Products with 1-Chloro- SKIN SENSITIZATION - Category 1 2,3-Epoxypropane and Phenol 1,4-bis(2,3 Epoxypropoxy)butane ~10 - :;;22 ACUTE TOXICITY (oral) - Category 4

ACUTE TOXICITY (dermal) - Category 4 ACUTE TOXICITY (inhalation) - Category 4 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1

State regulations Massachusetts New York New Jersey

None of the components are listed. None of the components are listed. None of the components are listed.

Pennsylvania None of the components are listed. California Prop. 65

Lt. WARNING: This product can expose you to chemicals including 1-Chloro-2,3-epoxypropane, which is known to the State of California to cause cancer and birth defects or other reproductive harm. This product can expose you to chemicals including Naphthalene, which is known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov.

Ingredient name No significant risk Maximum level acceptable dosage

level Naphthalene Yes. - 1-Chloro-2,3-epoxypropane Yes. -

International regulations Chemical Weapon Convention List Schedules I, II & Ill Chemicals Not listed.

Montreal Protocol Not listed.

Stockholm Convention on Persistent Organic Pollutants Not listed.

Rotterdam Convention on Prior Informed Consent {PIC) Not listed.

~ KMK Regulatory Services Tel: +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 11/13

Page 19: SUBMITTAL REQUEST FORM

ACCU-GROUT HD PART A I

UNECE Aarhus Protocol on POPs and Heavy Metals Not listed.

Inventory list Australia Canada China Europe Japan

New Zealand Philippines Republic of Korea Taiwan Thailand Turkey United States (TSCA Sb) Viet Nam

Not determined. Not determined. Not determined. Not determined. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Not determined. Not determined. Not determined. Not determined. Not determined. Not determined. All components are active or exempted. Not determined.

!section 16. Other information

Caution: HMIS® ratings are based on a 0-4 rating scale, with O representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.

Procedure used to derive the classification Classification Justification

SKIN CORROSION/IRRITATION - Category 2 Calculation method SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method SKIN SENSITIZATION - Category 1 Calculation method AQUATIC HAZARD (LONG-TERM) - Category 2 Calculation method

History Date of issue/Date of revision Date of previous issue Version Prepared by

04/30/2021

Not applicable

1 KMK Regulatory Services Inc.

~ KMK Regulatory Services Tel: +1-888-GHS-7769 (447-7769) I +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 12113

Page 20: SUBMITTAL REQUEST FORM

!section 16. Other information ACCU-OROUTHDPARTAI

Key to abbreviations ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods Log Pow= logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN= United Nations

Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

~ KMK Regulatory Services Tel: +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 13/13

Page 21: SUBMITTAL REQUEST FORM

Conforms to HCS 2012 - United States

SAFETY DATA SHEET ACCU-GROUT HD Part B

I Section 1. Identification GHS product identifier

Other means of identification Product type

ACCU-GROUT HD Part B

Epoxy Grout

Relevant identified uses of the substance or mixture and uses advised against

I Identified uses Epoxy polymer grout

Supplier's details

Emergency telephone number (with hours of operation)

Adhesives Technology Corp. 450 East Copans Road Pompano Beach, FL 33064 (800) 892-1880 (800) 362-3320 www.atcepoxy.com

CHEM-TEL: (800) 255-3924 24/7

Section 2. Hazards identification OSHA/HCS status

Classification of the substance or mixture

GHS label elements Hazard pictograms

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). ACUTE TOXICITY (dermal) - Category 4 SKIN CORROSION/IRRITATION - Category 1 B SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 SKIN SENSITIZATION - Category 1 TOXIC TO REPRODUCTION (Fertility) - Category 1 B TOXIC TO REPRODUCTION (Unborn child) - Category 1 B SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 AQUATIC HAZARD (ACUTE) - Category 2 AQUATIC HAZARD (LONG-TERM) - Category 3

Signal word Danger

~ KMK Regulatory Services

Tel: +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com

1/14

Page 22: SUBMITTAL REQUEST FORM

ACCU-GROUT HD PART BI Section 2. Hazards identification Hazard statements H312 - Harmful in contact with skin.

H314 - Causes severe skin burns and eye damage. H317 - May cause an allergic skin reaction. H335 - May cause respiratory irritation. H360FD - May damage fertility. May damage the unborn child. H401 - Toxic to aquatic life. H412 - Harmful to aquatic life with long lasting effects.

Precautionary statements Prevention

Response

Storage

Disposal

Hazards not otherwise classified

P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P280 - Wear protective gloves, protective clothing and eye or face protection. P271 - Use only outdoors or in a well-ventilated area. P273 - Avoid release to the environment. P261 -Avoid breathing vapor. P264 - Wash thoroughly after handling. P272 - Contaminated work clothing must not be allowed out of the workplace. P308 + P313 - IF exposed or concerned: Get medical advice or attention. P304 + P340, P310 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or doctor. P301 + P310, P330, P331 - IF SWALLOWED: Immediately call a POISON CENTER or doctor. Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353, P310 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Immediately call a POISON CENTER or doctor. P363 - Wash contaminated clothing before reuse. P302 + P312, P352 - IF ON SKIN: Call a POISON CENTER or doctor if you feel unwell. Wash with plenty of water. P333 + P313 - If skin irritation or rash occurs: Get medical advice or attention. P305 + P351 + P338, P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor. P405 - Store locked up. P403 + P233 - Store in a well-ventilated place. Keep container tightly closed. P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations. None known.

Section 3. Composition/information on ingredients Substance/mixture Other means of identification

Mixture

Ingredient name % CAS number 3,6-Diazaoctanethylenediamin ~50 - -5,75 112-24-3 Fatty Acids, Tall-oil, Reaction Products With Tetraethylenepentamine ~25 - '5.50 68953-36-6 3,6,9-Triazaundecamethylenediamine ~5 - S10 112-57-2 2,4,6-tris(Dimethylaminomethyl)phenol ~3 - S3.9 90-72-2 2-(2-Aminoethylamino )Ethanol S0.3 111-41-1

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

~ KMK Regulatory Services Tel: +1-888-GHS-7769 (447-7769) I +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 2114

Page 23: SUBMITTAL REQUEST FORM

I A ~HESIVES ACCU-GROUT HD PART BI jsection 3. Composition/information on ingredients There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8.

jsection 4. First aid measures Description of necessary first aid measures Eye contact Get medical attention immediately. Call a poison center or physician. Immediately flush

eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Chemical burns must be treated promptly by a physician. Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Get medical attention immediately. Call a poison center or physician. Wash with plenty of soap and water. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 20 minutes. Chemical burns must be treated promptly by a physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Inhalation

Skin contact

Ingestion

Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact Inhalation Skin contact Ingestion

Causes serious eye damage. May cause respiratory irritation. Causes severe burns. Harmful in contact with skin. May cause an allergic skin reaction. No known significant effects or critical hazards.

Over-exposure signs/symptoms Eye contact Adverse symptoms may include the following:

pain watering redness

~ KMK Regulatory Services Tel: +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 3/14

Page 24: SUBMITTAL REQUEST FORM

ACCU-GROUT HD PART BI

Inhalation

Skin contact

Ingestion

Adverse symptoms may include the following: respiratory tract irritation coughing reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: pain or irritation redness blistering may occur reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: stomach pains reduced fetal weight increase in fetal deaths skeletal malformations

Indication of immediate medical attention and special treatment needed, if necessary Notes to physician In case of inhalation of decomposition products in a fire, symptoms may be delayed.

The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments Protection of first-aiders

No specific treatment. No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

See toxicological information (Section 11)

!section 5. Fire-fighting measures Extinguishing media Suitable extinguishing media Unsuitable extinguishing media

Specific hazards arising from the chemical

Hazardous thermal decomposition products

Special protective actions for fire-fighters

Special protective equipment for fire-fighters

Use an extinguishing agent suitable for the surrounding fire.

None known.

This material is toxic to aquatic life. This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

~ KMK Regulatory Services

Tel: +1-888-GHS-7769 (447-7769) I +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com

4114

Page 25: SUBMITTAL REQUEST FORM

ACCU-GROUT HD PART 8 I Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from

entering. Do not touch or walk through spilled material. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non­ emergency personnel".

For emergency responders

Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities.

Methods and materials for containment and cleaning up Small spill Stop leak if without risk. Move containers from spill area. Dilute with water and mop up

if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

!section 7. Handling and storage Precautions for safe handling Protective measures

Advice on general occupational hygiene

Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures.

~ KMK Regulatory Services

Tel: +1-888-GHS-7769 (447-7769) I +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com

5114

Page 26: SUBMITTAL REQUEST FORM

ACCU-GROUT HD PART BI

Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.

Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits

Ingredient name Exposure limits

3,6-Diazaoctanethylenediamin AIHA WEEL (United States, 7/2020). Absorbed through skin. TWA: 1 ppm 8 hours.

Fatty Acids, Tall-oil, Reaction Products With Tetraethylenepentamine None. 3,6,9-Triazaundecamethylenediamine AIHA WEEL (United States, 7/2020).

Absorbed through skin. Skin sensitizer. TWA: 5 mg/m3 8 hours.

2,4,6-tris(Dimethylaminomethyl)phenol None. 2-(2-Aminoethylamino)Ethanol None.

Appropriate engineering controls

Environmental exposure controls

Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.

Individual protection measures Hygiene measures

Eye/face protection

Skin protection Hand protection

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/ or face shield. If inhalation hazards exist, a full-face respirator may be required instead.

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

~ KMK Regulatory Services

Tel: +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com

6/14

Page 27: SUBMITTAL REQUEST FORM

ACCU-GROUT HD PART B

Section 8. Exposure controls/personal protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Respiratory protection Based on the hazard and potential for exposure, if required, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Body protection

Other skin protection

!section 9. Physical and chemical properties Appearance Physical state Color

Odor Odor threshold pH Melting point Boiling point Flash point Evaporation rate Flammability (solid, gas) Lower and upper explosive (flammable) limits Vapor pressure Vapor density Relative density Solubility Solubility in water Partition coefficient: n­ octanol/water Auto-ignition temperature Decomposition temperature Viscosity Flow time (ISO 2431) Volatile organic compounds

Liquid. [Viscous.] Amber. Distinct. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available.

Not available. Not available. Not available. Not available. Not available. Not applicable.

Not available. Not available. Not available. Not available.

jsection 10. Stability and reactivity Reactivity No specific test data related to reactivity available for this product or its ingredients.

Chemical stability The product is stable.

Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

- KMK Regulatory Services

Tel: +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com

7114

Page 28: SUBMITTAL REQUEST FORM

ACCU-GROUT HD PART BI I Section 10. Stability and reactivity Conditions to avoid

Incompatible materials

Hazardous decomposition products

No specific data.

Reactive or incompatible with the following materials: oxidizing materials.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Section 11. Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure

3,6-Diazaoctanethylenediamin lD50 Dermal Rabbit 805 mg/kg - lD50 Oral Rat 2500 mg/kg -

3,6,9-Triazaundecamethylenediamine lD50 Oral Rat 3990 mg/kg - 2,4,6-tris lD50 Dermal Rat 1280 mg/kg - (Dimethylaminomethyl)phenol

lD50 Oral Rat 1200 mg/kg - 2-(2-Aminoethylamino) lD50 Dermal Rat 2250 mg/kg - Ethanol

lD50 Oral Rat 3 g/kg - Irritation/Corrosion

Product/ingredient name Result Species Score Exposure Observation

3,6-Diazaoctanethylenediamin Eyes - Moderate irritant Rabbit - 24 hours 20 - mg

Eyes - Severe irritant Rabbit - 49 mg - Skin - Severe irritant Rabbit - 24 hours 5 -

mg Skin - Severe irritant Rabbit - 490 mg -

3,6,9-Triazaundecamethylenediamine Eyes - Moderate irritant Rabbit - 24 hours 100 - mg

Eyes - Moderate irritant Rabbit - 5 mg - Skin - Severe irritant Rabbit - 24 hours 5 -

mg Skin - Severe irritant Rabbit - 495 mg -

2,4,6-tris Eyes - Severe irritant Rabbit - 24 hours 50 - (Dimethylaminomethyl)phenol µg

Skin - Mild irritant Rat - 0.025 ml - Skin - Severe irritant Rat - 0.25 ml - Skin - Severe irritant Rabbit - 24 hours 2 -

mg 2-(2-Aminoethylamino) Eyes - Severe irritant Rabbit - 50 mg - Ethanol

Skin - Mild irritant Rabbit - 445 mg - Sensitization There is no data available.

Mutagenicitv There is no data available.

Carcinogenicity There is no data available.

- KMK Regulatory Services

Tel: +1-888-GHS-7769 (447-7769) I +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com

8/14

Page 29: SUBMITTAL REQUEST FORM

ACCU-GROUT HD PART BI Section 11. Toxicological information Reproductive toxicity There is no data available.

Teratogenicity There is no data available.

Specific target organ toxicity (sinale exoosure} Name Category Route of Target organs

exposure Fatty Acids, Tall-oil, Reaction Products With Category 3 - Respiratory tract T etraethylenepentami ne irritation 2-(2-Aminoethylamino)Ethanol Category 3 - Respiratory tract

irritation Specific target organ toxicity (repeated exposure} There is no data available.

Aspiration hazard There is no data available.

Information on the likely Routes of entry anticipated: Oral, Dermal, Inhalation. routes of exposure Potential acute health effects Eye contact Causes serious eye damage. Inhalation May cause respiratory irritation. Skin contact Causes severe burns. Harmful in contact with skin. May cause an allergic skin reaction. Ingestion No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics Eye contact Adverse symptoms may include the following:

pain watering redness

Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: pain or irritation redness blistering may occur reduced fetal weight increase in fetal deaths skeletal malformations

Skin contact

Ingestion Adverse symptoms may include the following: stomach pains reduced fetal weight increase in fetal deaths skeletal malformations

~ KMK Regulatory Services Tel: +1-888-GHS-7769 (447-7769) I +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 9114

Page 30: SUBMITTAL REQUEST FORM

ACCU-GROUT HD PART Bl Section 11. Toxicological information Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate effects Potential delayed effects

No known significant effects or critical hazards.

No known significant effects or critical hazards. Long term exposure Potential immediate No known significant effects or critical hazards. effects Potential delayed effects No known significant effects or critical hazards.

Potential chronic health effects General

Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects

Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. No known significant effects or critical hazards. No known significant effects or critical hazards. May damage the unborn child. No known significant effects or critical hazards. May damage fertility.

Numerical measures of toxicity Acute toxicitv estimates Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation

kg) (mg/kg) (gases) (vapors) (dusts and (ppm) (mg/I) mists) (mg/

I) ACCU-GROUT HD Part B 6663.2 1732.6 NIA NIA NIA 3,6-Diazaoctanethylenediamin 2500 1100 NIA NIA NIA 3,6,9-Triazaundecamethylenediamine 500 1100 NIA NIA NIA 2,4,6-tris(Dimethylaminomethyl)phenol 1200 1280 NIA NIA NIA 2-(2-Aminoethylamino)Ethanol 3000 2250 NIA NIA NIA

jsection 12. Ecological information Toxicity

Product/ingredient name Result Species Exposure 3,6-Diazaoctanethylenediamin Acute EC50 3700 µgll Fresh water Algae - Pseudokirchneriella 96 hours

subcapitata Acute LC50 33900 µgll Fresh water Daphnia - Daphnia magna 48 hours

Persistence and degradability There is no data available.

~ KMK Regulatory Services Tel: +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 10114

Page 31: SUBMITTAL REQUEST FORM

Section 12. Ecological information ACCU-GROUT HD PART BI

Bioaccumulative potential

Product/ingredient name LogPow BCF Potential 3,6-Diazaoctanethylenediamin -1.66 to -1.4 - low 2,4,6-tris 0.219 - low (Dimethylaminomethyl)phenol 2-(2-Aminoethylamino)Ethanol -1.46 <0.2 low

Mobility in soil Soil/water partition coefficient (Koc)

Not available.

Other adverse effects : No known significant effects or critical hazards.

I Section 13. Disposal considerations Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal

of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

!section 14. Transport information DOT Classification IMDG IATA

UN number UN2735 UN2735 UN2735

UN proper AMINES, LIQUID, AMINES, LIQUID, CORROSIVE, AMINES, LIQUID, shipping name CORROSIVE, N.O.S. N.O.S. CORROSIVE, N.O.S.

(3,6-Diazaoctanethylenediamin, (3,6-Diazaoctanethylenediamin, (3,6-Diazaoctanethylenediamin, 3,6,9-Triazaundecamethylenediamine) 3,6,9-Triazaundecamethylenediamine) 3,6,9-Triazaundecamethylenediamine)

Transport 8 8 8 hazard class(es)

• + + Packing group II II II Environmental No. No. No. hazards

AERG : 153

Special precautions for user Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

~ KMK Regulatory Services Tel: +1-888-GHS-7769 (447-7769) I +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 11114

Page 32: SUBMITTAL REQUEST FORM

I AADHESIVES

j Section 14. Transport information ACCU-GROUT HD PART 8 I

Transport in bulk according : Not available. to IMO instruments

jsection 15. Regulatory information U.S. Federal regulations TSCA 8(a) CDR Exempt/Partial exemption: Not determined

Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances DEA List I Chemicals (Precursor Chemicals) DEA List II Chemicals (Essential Chemicals) SARA 302/304 Composition/information on ingredients No products were found.

Not listed

Not listed

Not listed

Not listed

Not listed

SARA 304 RQ SARA 311/312 Classification

: Not applicable.

ACUTE TOXICITY (dermal) - Category 4 SKIN CORROSION/IRRITATION - Category 1 B SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 SKIN SENSITIZATION - Category 1 TOXIC TO REPRODUCTION (Fertility) - Category 1 B TOXIC TO REPRODUCTION (Unborn child) - Category 18 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3

Composition/information on ingredients Name % Classification 3,6-Diazaoctanethylenediamin ;,:50 - 5.75 ACUTE TOXICITY (dermal) - Category 4

SKIN CORROSION/IRRITATION - Category 18 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 SKIN SENSITIZATION - Category 1

Fatty Acids, Tall-oil, Reaction ;::25 - 5.50 SKIN CORROSION/IRRITATION - Category 2 Products With SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A T etraethylenepentam ine SKIN SENSITIZATION - Category 1

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3

3,6, 9-Triazaundecamethylenediamine ;,:5 - 5.8.3 ACUTE TOXICITY (oral) - Category 4 ACUTE TOXICITY (dermal) - Category 4 SKIN CORROSION/IRRITATION - Category 18 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 SKIN SENSITIZATION - Category 1

2,4,6-tris(Dimethylaminomethyl) ;,:3 - 5.3.9 ACUTE TOXICITY (oral) - Category 4 phenol ACUTE TOXICITY (dermal) - Category 4

SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A

~ KMK Regulatory ~ervices Tel: +1-888-GHS-7769 (447-7769) I +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 12/14

Page 33: SUBMITTAL REQUEST FORM

Section 15. Regulatory information ACCU-GROUT HD PART BI

2-(2-Aminoethylamino)Ethanol :50.3 SKIN CORROSION/IRRITATION - Category 18 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 SKIN SENSITIZATION - Category 1 TOXIC TO REPRODUCTION (Fertility) - Category 18 TOXIC TO REPRODUCTION (Unborn child) - Category 18 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3

State regulations Massachusetts

New York New Jersey

Pennsylvania

The following components are listed: 3,6-Diazaoctanethylenediamin; 3,6, 9-Triazaundecamethylenediamine None of the components are listed. The following components are listed: 3,6-Diazaoctanethylenediamin; 3,6, 9-Triazau ndecamethylenediamine The following components are listed: 3,6-Diazaoctanethylenediamin; 3,6,9-Triazaundecamethylenediamine

California Prop. 65

This product does not require a Safe Harbor warning under California Prop. 65. International regulations Chemical Weapon Convention List Schedules I. II & Ill Chemicals Not listed.

Montreal Protocol Not listed.

Stockholm Convention on Persistent Organic Pollutants Not listed.

Rotterdam Convention on Prior Informed Consent (PIC) Not listed.

UNECE Aarhus Protocol on POPs and Heavy Metals Not listed.

Inventory list Australia Canada China Europe Japan

New Zealand Philippines Republic of Korea Taiwan Thailand Turkey United States (TSCA 8b) Viet Nam

Not determined. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. All components are listed or exempted. All components are listed or exempted. Not determined. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. All components are active or exempted. All components are listed or exempted.

~ KMK Regulatory Services Tel: +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 13/14

Page 34: SUBMITTAL REQUEST FORM

ACCU-GROUT HD PART BI I Section 16. Other information

Caution: HMIS® ratings are based on a 0-4 rating scale, with O representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc.

The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.

Procedure used to derive the classification

Classification Justification ACUTE TOXICITY (dermal) - Category 4 Calculation method SKIN CORROSION/IRRITATION - Category 1 B Calculation method SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 Calculation method SKIN SENSITIZATION - Category 1 Calculation method TOXIC TO REPRODUCTION (Fertility) - Category 1 B Calculation method TOXIC TO REPRODUCTION (Unborn child) - Category 1 B Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract Calculation method irritation) - Category 3 AQUATIC HAZARD (ACUTE) - Category 2 Calculation method AQUATIC HAZARD (LONG-TERM) - Category 3 Calculation method History Date of issue/Date of revision Date of previous issue Version Prepared by

Key to abbreviations

04/30/2021

Not applicable 1 KMK Regulatory Services Inc. ATE= Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods Log Pow= logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) NIA = Not available SGG = Segregation Group UN = United Nations

Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

~ KMK Regulatory Services

Tel: +1-888-GHS-7769 (447-7769) I +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 14/14