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SH
STh
Ath
tiTh
Ath
tiSSt
tit
tiHH
ddSS
ll
SH
SS
tatic
Headspace
Sampler
The
Aut
hent
ic
The
Aut
hent
ic SS
tati
c ta
tic HH
aeds
pace
aeds
pace
SSam
pler
ampl
er
SH
SS
HS
Sta
tic
Headspace
Sampler
The
FIR
ST u
nive
rsal
head
spac
e
OV
ER t
hree
-dec
ades
ofex
peri
ence
OV
ER 2
0000
Hea
dspa
cepr
oduc
ed
SH
SS
HS
Sta
tic
Headspace
Sampler
MA
STER
SH
S
desi
gned
wit
hou
rcu
stom
erin
min
d
flex
ible
syst
em t
om
eet
alln
eeds
robu
stan
d tr
oubl
efr
ee d
esig
n
SH
SS
HS
Sta
tic
Headspace
Sampler
RO
BU
ST&
FLEX
IBLE
TEC
NIQ
UE
RO
BU
ST&
FLE
XIB
LETE
CN
IQU
E
PR
OV
EN&
SEN
SITI
VE
TEC
HN
IQU
E
UN
IVER
SAL
CO
MP
ATI
BIL
ITY
OU
TSTA
ND
ING
REP
RO
DU
CIB
ILIT
Y
HIG
HES
TP
RO
DU
CTI
VIT
Y
AC
CU
RA
CY
&D
ATA
TRA
CEA
BIL
ITY
AC
CU
RA
CY
& D
ATA
TRA
CEA
BIL
ITY
ENV
IRO
MEN
TALL
YSA
FE
Why
Why
a a St
atic
Stat
icH
eads
pace
Hea
dspa
ceSa
mpl
erSa
mpl
er??
Sta
tic
Head
Space
Samplershs
Sta
tic
Head S
pace
Sampler
Stat
icH
eadS
pace
sam
plin
gte
chni
que
isth
em
ost
com
mon
lyus
edSt
atic
Hea
dSpa
cesa
mpl
ing
tech
niqu
eis
the
mos
tco
mm
only
used
tech
niqu
efo
r t
he a
naly
sis
of v
olat
ile a
nd s
emiv
olat
ile c
ompo
unds
RRO
BU
STO
BU
ST&
&
FFLE
XIB
LELE
XIB
LETTE
CH
NIQ
UE
ECH
NIQ
UE
Sta
tic
Head
Space
Sampler
shs
Sta
tic
Head S
pace
Sampler
Sam
ple
flow
path
isen
tirel
ych
emic
alin
ert
(Si
lcon
ert
2000
)�
Sam
ple
flow
pat
his
entir
ely
chem
ical
iner
t(
Silc
oner
t20
00)�
Elim
inat
edan
alyt
ical
carr
yove
r
Hig
h te
mpe
ratu
re h
eads
pace
sam
pler
(300�
C)
Wki
tili
bi
hih
iti
itd
hih
Wor
king
ateq
uilib
rium
mea
nsan
hig
her
sens
itiv
ity
and
a hi
gher
accu
racy
of t
he m
easu
re
PPR
OV
ENR
OV
ENSE
NSI
TIV
ESE
NSI
TIV
ETTE
CH
NIQ
UE
ECH
NIQ
UE
Sta
tic
Head
Space
Samplershs
Sta
tic
Head S
pace
Sampler
Valv
e &
Loo
pis
the
mos
tre
liabl
ed
bt
th
ian
d ro
bust
tech
niqu
e
Com
pact
man
ifold
desi
gn e
nsur
esm
axim
um t
herm
alco
ntro
l
Carr
ier
gas
flow
rat
e is
uni
nter
rupt
edly
mai
ntai
ned
OOU
TSTA
ND
ING
UTS
TAN
DIN
GR
EPR
OD
UC
IBIL
ITY
REP
RO
DU
CIB
ILIT
Y
Sta
tic
Head S
pace
Samplershs
VE
NT
CA
RR
IER
AU
XIL
IAR
Y G
AS
MA
NIF
OLD
LOO
P
TOG
CTO
GC
Sli
h
SA
MP
LE
Sam
plin
g ph
ases
STEP
1:
OV
EN
VIA
LSh
akin
gLe
akC
heck
Pre
ssur
izat
ion
OOU
TSTA
ND
ING
UTS
TAN
DIN
GR
EPR
OD
UC
IBIL
ITY
REP
RO
DU
CIB
ILIT
Y
Sta
tic
Head
Space
Samplershs
Sta
tic
Head S
pace
Sampler
VE
NT
CA
RR
IER
AU
XIL
IAR
Y G
AS
MA
NIF
OLD
LOO
P
TOG
CTO
GC
SA
MP
LE
Sam
plin
g ph
ases
STEP
2:
OV
EN
VIA
LV
enti
ng
OOU
TSTA
ND
ING
UTS
TAN
DIN
GR
EPR
OD
UC
IBIL
ITY
REP
RO
DU
CIB
ILIT
Y
Sta
tic
Head
Space
Samplershs
Sta
tic
Head S
pace
Sampler
VE
NT
CA
RR
IER
AU
XIL
IAR
Y G
AS
MA
NIF
OLD
LOO
P
TOG
CTO
GC
SA
MP
LE
Sam
plin
g ph
ases
STEP
3:
OV
EN
VIA
LIn
ject
ion
OOU
TSTA
ND
ING
UTS
TAN
DIN
GR
EPR
OD
UC
IBIL
ITY
REP
RO
DU
CIB
ILIT
Y
Sta
tic
Head
Space
Samplershs
Sta
tic
Head S
pace
Sampler
Up
to 1
20 v
ialp
osit
ions
18 v
ials
oven
capa
city
for
max
imiz
edsa
mpl
e th
roug
hput
Uni
limit
edpr
iori
tyvi
al
Max
imum
com
pati
bilit
yw
ithhe
adsp
ace
vial
sof
10m
L,20
mL,
Uni
limit
edpr
iori
tyvi
al
Max
imum
com
pati
bilit
yw
ith h
eads
pace
vial
sof
10
mL,
20
mL,
22
mL
to m
eet
ever
yap
plic
atio
nne
ed
HHIG
HES
TIG
HES
TP
RO
DU
CTI
VIT
YP
RO
DU
CTI
VIT
Y
Sta
tic
Head
Space
Samplershs
Sta
tic
Head S
pace
Sampler
NO
nee
dof
Ext
erna
lSta
ndar
d
Mul
tipl
e H
eadS
pace
Extr
acti
on(M
HE)
Q
uant
itativ
em
etho
dfo
rco
mpl
exm
atric
esth
atel
imin
ates
sam
ple
mat
rixef
fect
and
allo
ws
toob
tain
the
tota
lpe
akar
easa
mpl
em
atrix
effe
ctan
dal
low
sto
obta
inth
eto
tal
peak
area
prop
ortio
nal
toth
eto
tal
amou
ntof
anal
yte
ofth
eor
igin
alsa
mpl
ean
da
cons
eque
ntm
ore
prec
ise
quan
tizat
ion.
HHIG
HES
TIG
HES
TP
RO
DU
CTI
VIT
YP
RO
DU
CTI
VIT
Y
Sta
tic
Head
Space
Samplershs
Sta
tic
Head S
pace
Sampler
Sam
ple
too
dilu
ited
Mul
tipl
eH
eadS
pace
Inje
ctio
n(M
HI)
lllti
ll
&l
ij
tii
allo
ws
am
ultip
leva
lve&
loop
inje
ctio
nin
apr
oper
prog
ram
mab
lete
mpe
ratu
rein
ject
orfil
led
with
dedi
cate
dso
rben
tm
ater
iali
nor
der
toim
prov
eth
ean
alyt
ical
syst
emse
nsiti
vity
.
HHIG
HES
TIG
HES
TP
RO
DU
CTI
VIT
YP
RO
DU
CTI
VIT
Y
Sta
tic
Head
Space
Samplershs
Sta
tic
Head S
pace
Sampler
New
Ana
lisys
Met
hod
Met
hod
Dev
elop
men
tO
ptim
izat
ion
(MD
O)
any
sing
lem
etho
dca
nbe
asso
ciat
edw
ithan
optim
izat
ion
proc
edur
e,in
whi
chth
eva
lue
ofa
sele
cted
para
met
eris
ato
mat
ial
lin
emen
ted
ofa
onst
ant
amo
ntin
ase
ies
of
Met
hod
Dev
elop
men
tO
ptim
izat
ion
(MD
O)
auto
mat
ical
lyin
crem
ente
dof
aco
nsta
ntam
ount
ina
serie
sof
cons
ecut
ive
sam
plin
gsof
iden
tical
sam
ples
.Ove
nte
mpe
ratu
rean
din
cuba
tion
time
can
beop
timiz
edse
para
tely
.
HHIG
HES
TIG
HES
TP
RO
DU
CTI
VIT
YP
RO
DU
CTI
VIT
Y
Sta
tic
Head
Space
Samplershs
Sta
tic
Head S
pace
Sampler
Bar
Cod
e R
eade
r gu
aran
tees
sam
ple
ratif
icat
ion
and
valid
atio
n,
assu
ring
data
trac
eabi
lity
assu
ring
data
tra
ceab
ility
At
tiL
kC
hk
dth
Aut
omat
ic L
eak
Che
ck p
roce
dure
ens
ures
the
pro
per
pres
suriz
atio
n an
d th
e pe
rfec
t se
al o
f ea
ch v
ial
Sam
ple
tray
cool
ing
devi
cepr
eser
ves
sam
ple
inte
grity
CFR
21
Par
t 11
com
plia
nce
AAC
CU
RA
CY
CC
UR
AC
Y&
D&
DA
TAA
TATTR
AC
EAB
ILIT
YR
AC
EAB
ILIT
Y
Sta
tic
Head
Space
Samplershs
Sta
tic
Head S
pace
Sampler
Full
cont
rolle
dby
Touc
h Sc
reen
and
SHS
Man
ager
SWSc
reen
and
SH
S M
anag
er S
W
or C
lari
ty d
ata
stat
ion.
AAC
CU
RA
CY
CC
UR
AC
Y&
D&
DA
TAA
TATTR
AC
EAB
ILIT
YR
AC
EAB
ILIT
Y
Sta
tic
Head
Space
Samplershs
Sta
tic
Head S
pace
Sampler
IQ O
Q /
PQ
Pro
cedu
re
[V]
Voltage
0,6
0,8
1,0
Dichlorobenzene
Nitrobenzene2,52
2,71
[min
.]Ti
me
01
23
45
V
0,0
0,2
0,4
2
Exam
ple
ofan
alys
isw
ith
SL/I
N -
FID
con
figu
rati
on
AAC
CU
RA
CY
CC
UR
AC
Y&
D&
DA
TAA
TATTR
AC
EAB
ILIT
YR
AC
EAB
ILIT
Y
Sta
tic
Head
Space
Samplershs
Sta
tic
Head S
pace
Sampler
Eti
ithki
df
GC
GCM
St
Easy
con
nect
ion
with
any
kind
ofG
C or
GCM
S sy
stem
UUN
IVER
SAL
NIV
ERSA
LCC
OM
PA
TIB
ILIT
YO
MP
ATI
BIL
ITY
Sta
tic
Head
Space
Samplershs
Sta
tic
Head S
pace
Sampler
Hea
dspa
cesa
mpl
ing
tech
niqu
eis
a To
tally
Gre
en p
roce
dure
, the
reis
none
edof
solv
ents
no n
eed
of s
olve
nts
Gas
Sav
ing
Func
tion
Tim
e &
Ene
rgy
Savi
ngFu
ncti
on
Two
sepa
rate
pne
umat
icci
rcui
tfo
rA
uxili
ary
and
carr
ier
gas
EENV
IRO
MEN
TALL
YN
VIR
OM
ENTA
LLY
SSAFE
AFE
SH
SS
tatic
Headspace
Sampler
WID
ER
AN
GE
OF
AP
PLI
CA
TIO
NS
WID
ER
AN
GE
OF
AP
PLI
CA
TIO
NS
Lim
ited
orno
sam
ple
prep
arat
ion
Lim
ited
or n
o sa
mpl
e pr
epar
atio
n
No
cont
amin
atio
nris
k
Redu
ced
inle
tan
dco
lum
nm
aint
enan
ceRe
duce
din
let
and
colu
mn
mai
nten
ance
Anal
ysis
of
subs
tanc
es t
hat
can
not
be
dire
ctly
inje
cted
into
GC
Itis
a ve
ryfl
exib
lete
chni
que
suit
able
for
solid
and
liqui
dsa
mpl
e m
atric
es
SH
SS
tatic
Headspace
Sampler
FOR
ENSI
C
PH
AR
MA
CEU
TIC
AL
ENV
IRO
NM
ENTA
L
PA
CK
AG
ING
F&
BFO
OD
& B
EVER
AG
E
PO
LYM
ERS
PO
LYM
ERS
BIO
DIE
SEL
SH
SS
tatic
Headspace
Sampler
DET
ERM
INAT
ION
OF
BLO
OD
ALC
OH
OL
ALC
1M
hl
ALC
2Ac
etha
ldeh
yde
Met
hano
lAc
etha
ldeh
yde
Etha
nol
2-pr
opan
olAc
eton
e+ A
ceto
nitr
ileM
EK
Acet
hald
ehyd
eM
etha
nol
Etha
nol
Acet
one
2-pr
opan
olAc
eton
itrile
Ethy
lace
tate
Ethy
l ace
tate
Ethy
l ace
tate
MEK
Mas
ter
GC
GC
Cond
ition
sO
35�
CM
aste
r SH
S Co
nditi
ons
O60�
CO
ven:
35�
CIn
j:SL
/IN
150�
C D
et:
FID
300�
C Ca
rrie
r: H
e 18
.8 p
siSp
lit:
1:5
Ove
n: 6
0�C
Man
ifold
:70�
C Tu
be:
80�
C Pr
ess:
11.
8 ps
iIn
cuba
tion
time:
15 m
in.
FFOR
ENSI
CO
REN
SIC
SH
SS
tatic
Headspace
Sampler
DET
ERM
INAT
ION
OF
BLO
OD
ALC
OH
OL
700
Eth
anol
Lin
eari
tyC
arry
over
Cal
cula
ted
DB-
ALC1
= 0
.006
%R
2 =
0,9
99
5
500
600
x s)
DB-
ALC2
= 0
.012
%
300
400
response (mV x
LOD
= 9
3 pp
b
0
100
200
r
pp
00
500
1000
1500
2000
2500
3000
3500
conc
entr
atio
n (p
pm)
FFOR
ENSI
CO
REN
SIC
SH
SS
tatic
Headspace
Sampler
RESI
DU
AL V
OLA
TILE
SO
LVEN
TS I
N P
HAR
MAC
EUTI
CAL USP
467
PPH
AR
MA
CEU
TIC
AL
HA
RM
AC
EUTI
CA
L
SH
SS
tatic
Headspace
Sampler
RESI
DU
AL V
OLA
TILE
SO
LVEN
TS I
N P
HAR
MAC
EUTI
CAL
USP
467
Mt
SHS
liith
USP
467
thd
hi
ifill
id
Mas
ter
SHS
com
plie
sw
ithU
SP 4
67 m
etho
dw
here
issp
ecifi
cally
requ
ired
a H
eads
pace
syst
em.
PPH
AR
MA
CEU
TIC
AL
HA
RM
AC
EUTI
CA
L
SH
SS
tatic
Headspace
Sampler
DET
ERM
INAT
ION
OF
BTEX
AN
D S
TYRE
NE
IN
WAT
ER M
aste
rSH
SCo
nditi
ons
Mas
ter
SHS
Cond
ition
sO
ven:
60�
C M
anifo
ld:
70�
C Tu
be:
80�
C Pr
ess:
11.
8 ps
iIn
cuba
tion
time:
15 m
in.
GC
Cond
ition
sO
ven:
35�
CIn
j:SL
/IN
150�
C D
tFI
D30
0�C
Det
: FI
D 3
00�
C Ca
rrie
r: H
e 18
.8 p
siSp
lit:
1:5
EENV
IRO
NM
ENTA
LN
VIR
ON
MEN
TAL
SH
SS
tatic
Headspace
Sampler
DET
ERM
INAT
ION
OF
BTEX
AN
D S
TYRE
NE
IN
WAT
ER
benz
ene
tolu
ene
ethy
lben
zene
p-xy
lene
m-x
ylen
eo-
xyle
nest
yren
eav
erag
e22
,02
26,0
428
,65
28,6
729
,28
24,9
420
,38
devs
td0,
280,
200,
410,
340,
250,
270,
19
RSD
%1,
270,
771,
431,
190,
861,
070,
92
EENV
IRO
NM
ENTA
LN
VIR
ON
MEN
TAL
RSD
%1,
270,
771,
431,
190,
861,
070,
92
SH
SS
tatic
Headspace
Sampler
DET
ERM
INAT
ION
OF
BTEX
AN
D S
TYRE
NE
IN
WAT
ER
EPA
Met
hod
Com
plia
nce
Mas
ter
SHS
ispe
rfec
tlyco
mpl
ianc
esw
ithEP
A M
etho
dw
here
isre
quire
da
Hea
dspa
cesy
stem
.
Prep
arat
ive
met
hod
EPA
5021
( E
PA 6
24, E
PA 8
260,
etc
….)
Anal
ityca
lmet
hod
EPA
8021
EENV
IRO
NM
ENTA
LN
VIR
ON
MEN
TAL
SH
SRE
SID
UAL
SO
LVEN
TS I
N F
OO
D P
ACKA
GIN
G
Sta
tic
Headspace
Sampler
1M
etha
nol
2Et
hano
l3
2-Pr
opan
ol4
Acet
one
5M
ethy
lace
tate
61-
prop
anol
7Se
c-Bu
tano
l8
2-Bu
tano
ne9
Ethy
lace
tate
10Is
obut
anol
11TH
F12
2-M
etho
xyet
hano
l13
Cycl
ohex
ane
14is
opro
ylac
etat
ep
y15
n-Bu
tano
l16
1-M
etho
xy-2
-pro
pano
l17
n-pr
opyl
acet
ate
182-
Etho
xyet
hano
l19
4-M
ethy
l2pe
ntan
one
4M
ethy
l2pe
ntan
one
20Is
obut
ylac
etat
e21
Tolu
ene
22n-
Buty
l ace
tate
23M
ethy
lcel
loso
lvea
ceta
te24
2-Et
oxye
thyl
acet
ate
PPA
CK
AG
ING
AC
KA
GIN
G
242
Etox
yeth
ylac
etat
e25
Cycl
ohex
anon
e
SH
SRE
SID
UAL
SO
LVEN
TS I
N F
OO
D P
ACKA
GIN
G
Sta
tic
Headspace
Sampler
R2
Met
hano
l1,
0000
Etha
nol
0,99
992-
Prop
anol
0,99
48Ac
eton
e0
9967
Acet
one
0,99
67M
ethy
lace
tate
0,99
951-
prop
anol
0,99
73Se
c-Bu
tano
l0,
9994
2-Bu
tano
ne0,
9905
Ethy
lace
tate
099
89Et
hyla
ceta
te0,
9989
Isob
utan
ol0,
9939
THF
0,99
892-
Met
hoxy
etha
nol
0,99
94Cy
cloh
exan
e0,
9990
isop
royl
acet
ate
1,00
00n-
Buta
nol
0,99
921-
Met
hoxy
-2-p
ropa
nol
0,98
71n-
prop
ylac
etat
e0,
9998
2-Et
hoxy
etha
nol
0,99
754-
Met
hyl2
pent
anon
e0,
9993
Ib
tl
tt
Isob
utyl
acet
ate
0,99
77To
luen
e0,
9971
n-Bu
tyl a
ceta
te0,
9950
Met
hylc
ello
solv
eace
tate
0,99
632-
Etox
yeth
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etat
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9716
Cycl
ohex
anon
e0
9978
PPA
CK
AG
ING
AC
KA
GIN
G
Cycl
ohex
anon
e 0,
9978
SH
SS
tatic
Headspace
Sampler
FRU
ITFR
AG
RA
NC
ES
Stra
wbe
rrie
sPr
ofile
9gr
ofsa
mpl
e in
10m
l via
l
Mas
ter
SHS
Cond
ition
sO
60�
CO
ven:
60�
C M
anifo
ld:
150�
C Tr
Line
: 19
0�C
Pres
s: 0
.64b
arIn
cuba
tion
time:
60 m
in.
FFOO
DO
OD
&
& BB
EVER
AG
EEV
ERA
GE
SH
SS
tatic
Headspace
Sampler
FRU
ITFR
AG
RA
NC
ES
Bana
na P
rofil
e
6gr
ofsa
mpl
e in
10m
l via
l
Mas
ter
SHS
Cond
ition
sO
60�
CO
ven:
60�
C M
anifo
ld:
150�
C Tr
Line
: 19
0�C
Pres
s: 0
.64b
arIn
cuba
tion
time:
60 m
in.
FFOO
DO
OD
&
& BB
EVER
AG
EEV
ERA
GE
SH
SS
tatic
Headspace
Sampler
RES
IDU
AL
AC
ETA
LDEH
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EIN
PET
Sam
ple
prep
ower
edin
a
liqui
dni
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liqui
dni
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frge
rate
mill
200m
gof
sam
ple
in20
mlv
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Acet
alde
hyde
Mas
ter
SHS
Cond
ition
sO
ven:
140�
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anifo
ld:
140�
C
200m
g of
sam
ple
in 2
0ml v
ial
Man
ifold
:14
0C
TrLi
ne:
140�
C Pr
ess:
0.6
4bar
Incu
batio
ntim
e:30
min
.
PPO
LYM
ERS
OLY
MER
S
SH
SS
tatic
Headspace
Sampler
UN
I EN
ISO
14
110:
200
3
GA
SC
HR
OM
ATO
GR
AP
HP
AR
AM
ETER
S
Ove
n:70�
C,20
min
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n:70
C,20
min
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ctor
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150�
CC
arri
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s:H
eliu
m,1
mL/
min
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nsta
ntflo
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ject
ion
mod
e:sp
lit,5
0ml/m
in.
Det
ecto
r:FI
D,
150�
CC
olu
mn:
DN
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Die
sel:
30m
,0.
32m
m,1
μm,
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Sam
ple:
stan
dard
mix
ture
ofm
etha
nol0
,1%
+5u
lof
2-pr
opan
ol
Mas
ter
SHS
PA
RA
MET
ERS
Ove
n:
80�
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ifol
d:80�
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cuba
tion
Tim
e:45
min
.A
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as:
1ba
rV
ent:
10se
cSa
mpl
ing:
10se
c.P
10
BBIOIO
DDIE
SEL
IESE
L
Pre
ss:
10se
c.
CCON
CLU
SIO
NS
ON
CLU
SIO
NS
The
mos
tu
sed
tech
niq
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in t
he
fiel
dof
VO
C a
nal
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Uti
lized
for
liqu
idan
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e
Easy
tous
eEa
sy t
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e
Fully
auto
mat
ed
Ver
sati
le
MSH
SM
AST
ERSH
S TH
ED
AN
ISO
LUTI
ON
FOR
HEA
DSP
AC
EA
NA
LIY
SIS
CO
NC
LUSI
ON
S
THE
DA
NI
SOLU
TIO
NFO
RH
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SPA
CE
AN
ALI
YSI
S
