STACK EMISSIONS MONITORING REPORT · ESG Job Number: Report Date: Version: 1 Report By: Cormac Dunne MCERTS Number: MM 07 885 MCERTS Level: MCERTS Level 2 - Team Leader Technical

ESG Job Number:

Report Date:

Version: 1

Report By: Cormac Dunne

MCERTS Number: MM 07 885

MCERTS Level: MCERTS Level 2 - Team Leader

Technical Endorsements: 1, 2, 3 & 4

Report Approved By: Andrew O'Neil

MCERTS Number: MM 08 985

Business Title: MCERTS Level 2 - Team Leader

Technical Endorsements: 1, 2, 3 & 4

Signature:

STACK EMISSIONS MONITORING REPORT

LEK 10072

Sampling Date(s):

18th November 2015

6th January 2016

David Hay

Business Manager - North

Tel: 01355 246 730

Email: [email protected]

Release Point:

SO2 B

Operator & Address:

Derryoughter

Co. Leitrim

Ireland

Drumsna

Masonite Ireland

Carrick-on-Shannon

2-4 Langlands Place

Kelvin South Business Park

East Kilbride

G75 0YF

Tel: 01355 246 730

Fax: 01355 249 669

Your contact at ESG

Permit:

IPPC Licence: PO021-02

Report Template Issue 21 (Apr 2015) Page 1 of 39

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EXECUTIVE SUMMARY

Stack Emissions Monitoring Objectives

- Plant

- Operator

- Stack Emissions Monitoring Test House

Emissions Summary

Monitoring Times

Process Details

Monitoring Methods

Analytical Methods

- Sampling Methods with Subsequent Analysis

- On-Site Testing

Sampling Location

- Sampling Plane Validation Criteria

- Duct Characteristics

- Sampling Lines & Sample Points

- Sampling Platform

- Sampling Location / Platform Improvement Recommendations

Sampling and Analytical Method Deviations

APPENDICES

APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team

APPENDIX 2 - Summaries, Calculations, Raw Data and Charts

APPENDIX 3 - Measurement Uncertainty Budget Calculations

CONTENTS

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SO2 B

LEK 10072 / Version 1

18th November 2015


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Plant

SO2 B

Operator

Masonite Ireland

Derryoughter

Drumsna

Carrick-on-Shannon

Co. Leitrim

Ireland


Stack Emissions Monitoring Test House

ESG - East Kilbride Laboratory

2-4 Langlands Place

Kelvin South Business Park

East Kilbride

G75 0YF

UKAS and MCERTS Accreditation Number: 1015

Opinions and interpretations expressed herein are outside the scope of UKAS accreditation.

MCERTS accredited results will only be claimed where both the sampling and analytical stages are UKAS accredited.

This test report shall not be reproduced, except in full, without written approval of ESG.

MONITORING OBJECTIVES

ESG were commissioned by Masonite Ireland to carry out stack emissions monitoring to determine the release of prescribed pollutants from the

following Plant under normal operating conditions.

Masonite Ireland operates a first stage fibre drier process at Carrick-on-Shannon which is subject to IPPC Licence PO021-02, under the EPA Act 1992.

EXECUTIVE SUMMARY

The results of these tests shall be used to demonstrate compliance with a set of emission limit values for prescribed pollutants as specified in the Plant's

IPPC Licence, PO021-02.

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Parameter Units Result Calculated

Uncertainty

Limit

+/-

Total Particulate Matter mg/m³ 3.66 0.31 20

Particulate Emission Rate kg/hr 0.50 0.04 2.1

Formaldehyde mg/m³ 1.14 0.145 12

Formaldehyde Emission Rate kg/hr 0.16 0.020 0.8

CVOCs mg/m³ 6.78 1.46 100

CVOCs Emission Rate kg/hr 0.93 0.201 6.7

Total Aldehydes mg/m³ 3.50 0.752 20

Total Aldehydes Emission Rate kg/hr 0.49 0.1 2

Oxides of Nitrogen (as NO2) mg/m³ 51.8 8.4 200

Oxides of Nitrogen (as NO2) Emission Rate g/hr 7037 1140 -

Carbon Monoxide mg/m³ 32.9 5.20 100

Carbon Monoxide Emission Rate g/hr 4476 706.2 -

Oxygen (Dry) % v/v 18.6 0.4 - P

Oxygen (Wet) % v/v 16.2 - - P

Moisture % 13.3 0.65 - P

Stack Gas Temperature oC 56 - -

Stack Gas Velocity m/s 9.0 0.22 -

Gas Volumetric Flow Rate (Actual) m³/hr 135330 6902 -

Gas Volumetric Flow Rate (STP, Wet) m³/hr 112120 5718 -

Gas Volumetric Flow Rate (STP, Dry) m³/hr 97200 4957 -

Gas Volumetric Flow Rate at Reference Conditions m³/hr 135925 6932 -

P

EXECUTIVE SUMMARY

EMISSIONS SUMMARY

Reference conditions are 273K, 101.3kPa, wet gas 17% Oxygen.

ND = None Detected,

Results at or below the limit of detection are highlighted by bold italic text.

The above volumetric flow rate is calculated using data from the preliminary survey. Mass emissions for non isokinetic tests are calculated using these

values. For all isokinetic testing the mass emission is calculated using test specific flow data and not the above values.

MCERTS

accredited

result

P

O

P

P

P

O

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Total Particulate Matter Run 1

Formaldehyde Run 1

CVOCs Run 1

Total Aldehydes Run 1

Combustion Gases

18 November 2015 11:37

12:36 - 13:06 30 minutes

-

61 minutes18 November 2015

12:33 - 13:38

60 minutes

Stack Gas Flow Rate & Temperature Run 1

18 November 2015

18 November 2015

18 November 2015 12:33 - 13:38

Sampling TimesSampling Date(s)Parameter

EXECUTIVE SUMMARY

Sampling Duration

MONITORING TIMES

60 minutes

12:33 - 13:38

60 minutes

18 November 2015

10:13 - 11:20

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Description of process First stage fibre drier

Continuous or batch Continuous

Product Details Door skin manufacturing

Part of batch to be monitored (if applicable) N/A

Normal load, throughput or continuous rating Normal

Fuel used during monitoring N/A

Abatement Scrubber

Plume Appearance Yes

PROCESS DETAILS

Parameter Process Details

EXECUTIVE SUMMARY

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Species ESG UKAS Lab MCERTS Limit of Calculated

Technical Number Accredited Detection MU

Procedure Method (LOD) +/- %

TPM AE 104 1015 Yes 0.15 mg/m³ 8.4 %

Formaldehyde AE 114 1015 Yes 0.01 mg/m³ 12.7 %

CVOCs AE112 1015 Yes 0.02 mg/m³ 21.5 %

Total Aldehydes Based on AE114 1015 Yes 0.27 mg/m³ 21.5 %

NOX AE 102 1015 Yes 0.51 mg/m³ 16.20%

CO AE 102 1015 Yes 0.35 mg/m³ 15.78%

O2 AE 102 1015 Yes 0.01% 1.90%

H2O AE 105 1015 Yes 0.01% 4.90%

Velocity AE 154 1015 Yes 5 Pa 2.4 %

EN 14791

SRM - EN 14792

SRM - EN 15058

USEPA M316

USEPA M0011

SRM - BS EN 14790

SRM - EN ISO 16911-1

MONITORING METHODS

Method

Standard Reference Method /

Alternative Method

The selection of standard reference / alternative methods employed by ESG is determined, wherever possible by the hierarchy of method selection

outlined in Environment Agency Technical Guidance Note (Monitoring) M2. i.e. CEN, ISO, BS, US EPA etc.

AM - EN 14789

Monitoring Methods

SRM - EN 13284-1

EXECUTIVE SUMMARY

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The following tables list the analytical methods employed together with the custody and archiving details:

Species Analytical UKAS Lab Analysis Lab Sample Archive

Procedure Number Archive Period

Location

TPM AE 106 1015 Yes ESG East Kilbride ESG East Kilbride 3 months

Formaldehyde M103 0605 Yes RPS RPS 3 months

CVOCs Based on AE112 1015 No ESG ESG 3 months

Total AldehydesASC/SOP/237

Issue 11015 No

ESG -

Specialist

Chemistry

ESG -

Specialist

Chemistry

3 months

Species Analytical UKAS Lab MCERTS Laboratory Data Archive

Procedure Number Accredited Archive Period

Analysis Location

NOX AE 102 1015 Yes ESG East Kilbride ESG East Kilbride 5 years

CO AE 102 1015 Yes ESG East Kilbride ESG East Kilbride 5 years

O2 AE 102 1015 Yes ESG East Kilbride ESG East Kilbride 5 years

H2O AE 105 1015 Yes ESG East Kilbride - -

ON-SITE TESTING

(ESG or

Subcontract)

Gravimetric

Zirconia Cell

SAMPLING METHODS WITH SUBSEQUENT ANALYSIS

Analytical Technique

UKAS

Accredited Lab

Analysis

EXECUTIVE SUMMARY

HPLC using Diode Array

Detection

Gravimetric

Analytical Methods

Analysis for TOC by uv-

persulphate oxidation / IR

detection

Spectrophotometry

Analytical Technique

Chemiluminescence

Non Dispersive Infra Red

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Sampling Plane Validation Criteria Value Units Requirement Compliant Method

Lowest Differential Pressure 54 Pa >= 5 Pa Yes BS EN 15259

Lowest Gas Velocity 8.70 m/s - - -

Highest Gas Velocity 9.36 m/s - - -

Ratio of Gas Velocities 1.08 : 1 < 3 : 1 Yes BS EN 15259

Mean Velocity 8.97 m/s - - -

Maximum angle of flow with regard to duct axis <15 o < 15

o Yes BS EN 15259

No local negative flow Yes - - Yes BS EN 15259

Highly homogeneous flow stream / gas velocity Yes - - Yes BS EN 15259

Value Units Isokinetic Isokinetic

Shape Circular - (CEN Methods) (ISO Methods)

Depth 2.31 m Sample port size 4" (Non BSP) - 4" (Non BSP)

Width - m Number of lines used 2 - 1

Area 4.19 m2 Number of points / line 10 - 1

Port Depth 360 mm Duct orientation Vertical - Vertical

Out Stack - -

General Platform Information

Permanent / Temporary Platform / Ground level / Floor Level / Roof

Inside / Outside

AG1 Platform requirements

Is there a sufficient working area so work can be performed in a compliant manner

Platform has 2 levels of handrails (approximately 0.5 m & 1.0 m high)

Platform has vertical base boards (approximately 0.25 m high)

Platform has removable chains / self closing gates at the top of ladders

Handrail / obstructions do not hamper insertion of sampling equipment

Depth of Platform = >Stack depth / diameter + wall and port thickness + 1.5m

Sampling Platform Improvement Recommendations (if applicable)

EXECUTIVE SUMMARY

Permanent

Filtration for TPM

DUCT CHARACTERISTICS

No

As far as reasonably practical the location meets the requiremnts of AG1. Please extend the clearance in front of Line B where possible.

SAMPLING LOCATION

Yes

Yes

Outside

SAMPLING LINES & POINTS

Yes

Yes

Non-Iso &

Gases

SAMPLING PLATFORM

No

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Sampling Line B

Transfer Line

USEPA M316

USEPA M0011

EXECUTIVE SUMMARY

The full number of sampling points could not be completed on sampling line B due to probe overhang (see stack diagram)

Total Aldehyde samples were filtered at the request of Masonite therefore the monitoring does not completely adhere to US EPA Method

0011.

A transfer line between the first impinger & filter holder was employed due to handrails hampering the insertion of sampling equipment.

Formaldehyde samples were filtered at the request of Masonite therefore the monitoring does not completely adhere to US EPA Method 316.

Sampling & Analytical Method Deviations

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APPENDICES


CONTENTS

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Species ESG UKAS Lab MCERTS

Technical Number Accredited

Procedure Method

TPM AE 104 1015 Yes 1

Formaldehyde AE 114 1015 Yes 1

CVOCs AE112 1015 Yes 1

Total Aldehydes Based on AE114 1015 Yes 1

NOx AE 102 1015 Yes 1

CO AE 102 1015 Yes 1

O2 AE 102 1015 Yes 1

H2O AE 105 1015 Yes 1

Velocity AE 154 1015 Yes 1

Method

SRM - EN 14792

SRM - EN ISO 16911-1

SRM - BS EN 14790


USEPA M316

EN 14791

SRM - EN 13284-1

Number of

Samples

USEPA M0011

Standard Reference Method /

Alternative Method

MONITORING SCHEDULE

AM - EN 14789

SRM - EN 15058

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Equipment I.D. Equipment I.D. Equipment I.D.

LEK 9.29 LEK 12.7 LEK 15.21

LNO 03-02 - LEK 20.2

- - LEK 17.16

- - -

- - LEK 16.5

LNO 09-04 - LEK 15.7

- - LNO 03-CD

- - LEK 3.165

LNO 11-61 - -

LNO 10-61 - -

LEK 6.48 - -

- - -

LEK 23.13 LNO 21-33 -

- LEK 8.18 -

- - -

LEK 15-1F - -

- - -

LEK 13.17 - LEK 8.18

LNO 23-IH - -

NOTE: If the equipment I.D is represented by a dash (-), then this piece of equipment has not been used for this test.

Cylinder I.D

Number Supplier ppm %

Analytical

Tolerance +/-

%

Oxygen Fresh Air BOC - 20.95 -

Nitric Oxide LEK 078 BOC 193.8 - 2

Carbon Monoxide LEK 073 BOC 148.7 - 2

- - - - -

TE1 TE2 TE3 TE4 H&S

Cormac Dunne MM 07 885 Sep 16 Mar 17 Dec 16 Dec 16 Oct 17

Hugh McMahon MM 15 1347 - - - - Sep 20

Chiller (JCT/MAK 10)

Horiba PG-250 Analyser

Stopwatch

Mass Flow Controller

10m Heated Line (2)

15m Heated Line (1)

1m Heated Line (3)

Meter Out Thermocouple

Control Box Timer

Stack Thermocouple

Equipment

Oven Box

Probe JCT Heated Head Filter

Protractor

Digital Micromanometer

FT-IR

Bernath 3006 FID

Signal 3030 FID Barometer

Thermo FID

Digital Temperature Meter

Box Thermocouples Tape Measure


FT-IR Oven BoxMeter In Thermocouple

CALIBRATION GASES

MCERTS QualificationPersonnelMCERTS

Number

MCERTS Level 2 - Team

Leader

MCERTS Trainee

MONITORING TEAM

20m Heated Line (1)

S-Pitot

1m Heated Line (2)

Anemometer 1m Heated Line (1)

L-Pitot Ecophysics NOx Analyser

Last Impinger Arm

Dioxins Cond. Thermocouple Heated Line Controller (2)

CALIBRATEABLE EQUIPMENT CHECKLIST

Equipment

Servomex

Probe Thermocouple

0

MFC Display module

Probe

Probe Thermocouple

Stackmaster

FTIR Heater Box for Heated Line

Callipers

STACK EMISSIONS MONITORING TEAM

Site Balance

5m Heated Line (1)

Small DGM

Extractive Sampling Instrumental Analyser/s

Gas (traceable to ISO 17025)

Heater Controller

20m Heated Line (2)

-

Miscellaneous

Equipment

Heated Line Controller (1)

TE / H&S Qualifications and Expiry Date

10m Heated Line (1)

Control Box DGM

Inclinometer (Swirl Device)

Laboratory Balance

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Uncertainty Limit Emission

mg/m³ mg/m³ Rate g/hr

0.31 20 0.50

Blank - - -


TestFilter & Probe

Rinse Number

Filter Start

Weight

Filter End

Weight

Mass Gained

on Filter

Probe Rinse

Start Weight

Probe Rinse

End Weight

Mass Gained

on Probe

Combined

Total Mass

Gained

g g g g g g g

Run 1 AC 6447 0.09298 0.09419 0.00121 195.82240 195.82620 0.00380 0.00501

If total mass gained is less than the LOD then the LOD is reported

TestFilter & Probe

Number

Filter Start

Weight

Filter End

Weight

Mass Gained

Filter

Probe Start

Weight

Probe End

Weight

Mass Gained

Probe

Combined

Total Mass

Gained

g g g g g g g

Run 1 AC 6451 0.09287 0.09287 0.00000 172.43050 172.43120 0.00070 0.00070

If total mass gained is less than the LOD then the LOD is reported

mg/l

FILTER INFORMATION

mg/l

Acceptable Value

2.0 10

Sampling Times

3.66

TOTAL PARTICULATE MATTER SUMMARY

12:33 - 13:38

18 November 2015

mg/m³

SAMPLES

BLANKS

0.62

Acetone Blank Value

Concentration


Parameter

-

Run 1

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ISOKINETIC SAMPLING EQUATIONS - RUN 1 TPM

Absolute pressure of stack gas, Ps Molecular weight of dry gas, Md

Barometric pressure, Pb mm Hg 758.26 CO2 % 1.80

Stack static pressure, Pstatic mm H2O 4.59 O2 % 16.15

Ps = Pb + (Pstatic) mm Hg 758.59 Total % 17.95

N2 (100 -Total) % 82.05

Vol. of water vapour collected, Vwstd Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 28.93

g 120.5 Molecular weight of wet gas, Ms

Vwstd = (0.001246)(Vlc) m3 0.150143 Ms = Md(1 - Bwo) + 18(Bwo) g/gmol 27.48

Volume of gas metered dry, Vmstd Actual flow of stack gas, Qa

Volume of gas sample through gas meter, Vm m31.143 Area of stack, As m

2 4.19

Gas meter correction factor, Yd 0.905 Qa = (60)(As)(Vs) m³/min 2245.1

Mean dry gas meter temperature, Tm oC15.800 Total flow of stack gas, Q

28.278 Conversion factor (K/mm.Hg) 0.3592

Vmstd = (0.3592)(Vm)(Pb+(DH/13.6))(Yd) m30.978 Qstd = (Qa)Ps(0.3592)(1-Bwo) Dry 1639.9

(Ts) +273

Volume of gas metered wet, Vmstw @O2ref 1987.21

Vmstw = Vmstd + Vwstd m3 1.1283 (Ts) +273

Qstw = (Qa)Ps(0.3592) Wet 1891.64

(Ts) +273

No Percent isokinetic, %I

Nozzle diameter, Dn mm 6.88

% oxygen measured in gas stream, act%O2 16.2 Nozzle area, An mm2 37.13

% oxygen reference condition 17 Total sampling time, q min 60

1.21 %I = (4.6398E6)(Ts+273)(Vmstd) % 112.2

(Ps)(Vs)(An)(q)(1-Bwo)

Vmstd@X%oxygen = (Vmstd) (O2 Ref) m3 1.3678 Acceptable isokinetic range 95% to 115% Yes

Moisture content, Bwo Particulate Concentration, C

Bwo = Vwstd 0.1331 Mass collected on filter, Mf g 0.00121

% 13.31 Mass collected in probe, Mp g 0.00380

Moisture by FTIR % - Total mass collected, Mn g 0.00501

Velocity of stack gas, Vs Cwet = Mn mg/m³ 4.440

Pitot tube velocity constant, Kp 34.97 Vmstw

Velocity pressure coefficient, Cp 0.807 Cdry = Mn mg/m³ 5.122

Mean of velocity heads, DPavg mm H2O 6.45 Vmstd

Mean square root of velocity heads, ÖDP 2.54 Cdry@X%O2 = Mn mg/m³ 3.663

Mean stack gas temperature, TsoC 50

Vs = (Kp)(Cp)(ÖDP)(Ö(Ts + 273)) m/s 8.93 Particulate Emission Rates, E

(Ms)(Ps) E = [(Cwet)(Qstw)(60)] / 1000 0.50

Moisture trap weight increase,Vlc

13.6

Tm + 273

QstdO2 = (Qa)Ps(0.3592)(1-Bwo)(O2REF)


O2 Ref = 21.0 - act%O2

21.0 - ref%O2

Vmstd@X%oxygen

Vol. of gas metered at O2 Ref. Cond., Vmstd@X%O2

Vmstd + Vwstd

Mean pressure drop across orifice, DH mmH2O

O2 Reference

Factor

Is the process burning hazardous waste? (If yes, no

favourable oxygen correction)

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litre/min litre/min litre/min mm Hg litre/min

Run 1 17.24 0.02 0.02 -279.4 0.34 Yes

% mg/m³ mg/m³

Run 1 112.22 Yes Run 1 0.15 1 Yes

Acceptable isokinetic range 95% to 115% The above is based on both the Filter and rinse uncertainty

mg/m3

mg/m3

mg/m3

mg/m3

mm °C

Run 1 GF 47 160

GF = Glass Fibre

QF = Quartz Fibre

0.62

°C

Post-sampling

Leak RateRun

Acceptable

Leak Rate

Overall Blank

Value

Leak Tests

Acceptable?

Result

Blank 1

5% ELVAcceptable

Isokineticity

2.0

Max Filtration

Temperature

LEAK RATE

Filter SizeFilter Material

ISOKINETICITY

FILTERS

°C

Maximum

Vacuum

Run

180

Run

160

Yes

Isokinetic

Variation

Daily Emission

Limit Value

Overall Blank

Acceptable

Mean

Sampling Rate

Pre-use Filter Conditioning

Temperature

Post-use Filter Conditioning

Temperature

TOTAL PARTICULATE MATTER QUALITY ASSURANCE CHECKLIST

LOD < 5% ELVRun

WEIGHING BALANCE UNCERTAINTY

BLANK VALUE

Pre-sampling

Leak Rate

20


Acceptable

Blank Value

Run

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LOD Limit Emission


0.01 12 0.16

Field Blank - - -

Please note figures in bold italic font are at the limit of detection


Leak Test Results

l/min l/min l/min l/min

Run 1 17.2 0.02 0.02 0.34 Yes

Filter Material Filter Size

mm

°C °C

Run 1 GF 47 160 20 Glass

GF = Glass Fibre

QF = Quartz Fibre

Parameter Total IMP C Absorption

ug ug Efficiency %

1566 Not Determined Not Determined Not Determined

Absorption Solutions

Concentration

Post sampling

leak rate

FORMALDEHYDE QUALITY ASSURANCE CHECKLIST

Absorption Efficiency

Acceptable

leak rate

Type of

Absorbers

Max. Storage /

Transit Temp.

FORMALDEHYDE SUMMARY

Acceptable ?

Leak Tests

Acceptable?

Run 1

Run 112:33 - 13:38

18

November 2015

1.14

95

Sampling Times

0.021

Acceptable Absorption

FORMALDEHYDE ABSORPTION EFFICIENCY

mg/m³

-

Efficiency %

Mean Sampling

Rate

ND - None Detected

Max. Filtration

Temp.

HPLC Water

Pre sampling

leak rate

Test

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ISOKINETIC SAMPLING EQUATIONS 1 Formaldehyde

Absolute pressure of stack gas, Ps Velocity of stack gas, Vs

Barometric pressure, Pb mm Hg 758 Pitot tube velocity constant, Kp 34.97

Stack static pressure, Pstatic mm H2O 5 Velocity pressure coefficient, Cp 0.807

Ps = Pb + (Pstatic) mm Hg 759 Mean of velocity heads, DPavg mm H2O 6.45

Mean square root of velocity heads, ÖDP 2.54

Vol. of water vapour collected, Vwstd Mean stack gas temperature, TsoC 50

g -

Vwstd = (0.001246)(Vlc) m3 - Vs = (Kp)(Cp)(ÖDP)(Ö(Ts + 273)) m/s 8.9

(Ms)(Ps)



2 4.19

Gas meter correction factor, Yd 0.905 Qa = (60)(As)(Vs) m³/min 2245

Mean dry gas meter temperature, Tm oC15.80 Dry total flow of stack gas, Qstd

Mean pressure drop across orifice, DH mmH2O 28.28 Conversion factor (K/mm.Hg) 0.3592

Vmstd = (0.3592)(Vm)(Pb+(DH/13.6))(Yd) m30.98 Qstd = (Qa)Ps(0.3592)(1-Bwo) m³/min 1640

(Ts) +273

Volume of gas metered wet, Vmstw Wet total flow of stack gas, Qstw

Vmstw = Vmstd + Vwstd m3 1.1283 Qstw = (Qa)Ps(0.3592) m³/min 1892

(Ts) +273

No

m³/min 1988

% oxygen measured in gas stream, act%O2 16.15 (Ts) +273

% oxygen reference condition 17 Percent isokinetic, %I

O2 Ref = 21.0 - act%O2 1.21 Nozzle diameter, Dn mm 6.88

21.0 - ref%O2 Nozzle area, An mm2 37.13

Vmstd@X%oxygen = (Vmstd) (O2 Ref) m3 1.3678 Total sampling time, q min 60

Moisture content, Bwo %I = (4.6398E6)(Ts+273)(Vmstd) % 112

Bwo = Vwstd 0.1331 (Ps)(Vs)(An)(q)(1-Bwo)

% 13.31 Acceptable isokinetic range 95% to 115% Yes

Moisture by FTIR % -

Molecular weight of dry gas, Md Mass collected , M ug 1566

CO2 1.80 Cwet = Mn mg/m³ 1.388

O2 16.15 Vmstw

Total 17.95 Cdry = Mn mg/m³ 1.601

N2 (100 -Total) 82.05 Vmstd

Cdry@X%O2 = Mn mg/m³ 1.145

Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 28.93

Molecular weight of wet gas, Ms Formaldehyde Emission Rates, E

Ms = Md(1 - Bwo) + 18(Bwo) g/gmol 27.5 E = [(Cwet)(Qstw)(60)] / 1000 kg/hr 0.16

Tm + 273

Is the process burning hazardous waste? (If yes,

no favourable oxygen correction)

Vmstd@X%oxygen


Dry total flow of stack gas at X% O2, QstdO2



13.6

Formaldehyde Concentration, C

Vmstd + Vwstd

O2 Reference

Factor


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LOD Limit Emission


0.02 100 0.93

Field Blank - - -

Please note figures in bold italic font are at the limit of detection


Leak Test Results


Run 1 17.2 0.02 0.02 0.34 Yes


mm

°C °C

Run 1 GF 47 160 20 Glass

GF = Glass Fibre

QF = Quartz Fibre


ug ug Efficiency %

9280 Not Determined Not Determined

-

Concentration

Run 1

CVOCS ABSORPTION EFFICIENCY

Not Determined

HPLC Water


Run 1


6.78

Test

12:33 - 13:38

18 November 2015

Pre sampling

leak rate

Acceptable ?

95

CVOCS SUMMARY

Efficiency %

Leak Tests

Acceptable?

Mean Sampling

Rate

0.04

mg/m³

ND - None Detected



CVOCS QUALITY ASSURANCE CHECKLIST

Max. Storage /

Transit Temp.

Type of

Absorbers

Max. Filtration

Temp.

Post sampling

leak rate

Acceptable

leak rate

Sampling Times

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ISOKINETIC SAMPLING EQUATIONS 1 CVOCs







g -


(Ms)(Ps)



2 4.19



Mean pressure drop across orifice, DH mmH2O 27.71 Conversion factor (K/mm.Hg) 0.3592


(Ts) +273



(Ts) +273

No

m³/min 1988











CO2 1.80 Cwet = Mn mg/m³ 8.225

O2 16.15 Vmstw




Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 28.93

Molecular weight of wet gas, Ms CVOCs Emission Rates, E

Ms = Md(1 - Bwo) + 18(Bwo) g/gmol 27.5 E = [(Cwet)(Qstw)(60)] / 1000 kg/hr 0.93



O2 Reference

Factor

Vmstd + Vwstd

Vmstd@X%oxygen

Dry total flow of stack gas at X% O2, QstdO2Is the process burning hazardous waste? (If yes,


Tm + 273

13.6


CVOCs Concentration, C


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LOD Limit Emission


0.27 20 486.7

Field Blank - - -


Leak Test Results


Run 1 17.2 0.02 0.02 0.34 Yes


mm

°C °C

Run 1 QF 47 160 20 Glass

GF = Glass Fibre

QF = Quartz Fibre


ug ug Efficiency %

4520 Not Determined Not Determined



Acceptable ?


3.50

TOTAL ALDEHYDES ABSORPTION EFFICIENCY

10:13 - 11:20

18 November 2015

Type of

Absorbers

Max. Storage /

Transit Temp.

Run 1 Not Determined

Mean Sampling

Rate


Efficiency %

Acceptable

leak rate

DNPH Solution

Pre sampling

leak rate

Post sampling

leak rate

TOTAL ALDEHYDES QUALITY ASSURANCE CHECKLIST

ConcentrationTest

-

mg/m³

Run 1

0.57

TOTAL ALDEHYDES SUMMARY

Leak Tests

Acceptable?

95

Max. Filtration

Temp.

Sampling Times

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ISOKINETIC SAMPLING EQUATIONS 1 Total Aldehydes







g -


(Ms)(Ps)



2 4.19



Mean pressure drop across orifice, DH mmH2O28.03 Conversion factor (K/mm.Hg) 0.3592


(Ts) +273



(Ts) +273

No

m³/min 2011











CO2 1.80 Cwet = Mn mg/m³ 4.240

O2 16.15 Vmstw




Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 28.93

Molecular weight of wet gas, Ms Total Aldehydes Emission Rates, E

Ms = Md(1 - Bwo) + 18(Bwo) g/gmol 27.5 E = [(Cwet)(Qstw)(60)] / 1000 g/hr 486.68


Tm + 273


Vmstd + Vwstd


Vmstd@X%oxygen

Dry total flow of stack gas at X% O2, QstdO2


Total Aldehydes Concentration, C

O2 Reference

Factor

13.6

Is the process burning hazardous waste? (If yes,


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LOD Limit Emission


0.51 200 7037

0.35 100 4476

LOD

%

0.01


Date Chiller Temperature (°C) 2.5

Start Time Requirement < 4°C

End Time Compliant Yes

Gas Range Zero Reading Span Reading Zero Check Zero Check Span Check Response Leak Rate

(ppm / %) at analyser at analyser at analyser down line down line Time (Secs) %

NO 250 0 193.8 0 0 193 64 0.41

CO 200 0 148.8 0 -0.2 148.7 43 0.07

O2 25 0 20.95 0.03 0.08 20.97 47 -0.10

Date Chiller Temperature (°C) 2.8

Start Time Requirement < 4°C

End Time Compliant Yes

Gas Zero Check Span Check Zero Drift Span Drift

down line down line (%) (%)

NO 0.4 192.1 0.16 -0.52

CO 0.1 148.2 0.15 -0.40

O2 0.06 20.96 -0.08 0.04

12:20

Sampling Time and Date

12:02

%Test

O2

POST-SAMPLING CALIBRATION DATA

18 November 2015

Test

COMBUSTION GASES SUMMARY

mg/m³

32.93

12:36 - 13:06


CO12:36 - 13:06

18 November 2015

PRE-SAMPLING CALIBRATION DATA

14:06

14:17

18 November 2015

Concentration

Concentration

18.6


NOx12:36 - 13:06

51.8

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OXIDES OF NITROGEN (as NO2) EMISSIONS CHART

CARBON MONOXIDE EMISSIONS CHART

0.0

50.0

100.0

150.0

200.0

250.0

12:36

12:37

12:38

12:39

12:40

12:41

12:42

12:43

12:44

12:45

12:46

12:47

12:48

12:49

12:50

12:51

12:52

12:53

12:54

12:55

12:56

12:57

12:58

12:59

13:00

13:01

13:02

13:03

13:04

13:05

13:06

Co

nce

ntr

atio

n m

g/m

³

Time

Oxides of Nitrogen NOx

Limit

0.0

20.0

40.0

60.0

80.0

100.0

120.0

12:36

12:37

12:38

12:39

12:40

12:41

12:42

12:43

12:44

12:45

12:46

12:47

12:48

12:49

12:50

12:51

12:52

12:53

12:54

12:55

12:56

12:57

12:58

12:59

13:00

13:01

13:02

13:03

13:04

13:05

13:06

Co

nce

ntr

atio

n m

g/m

³

Time

Carbon Monoxide CO

Limit

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OXYGEN EMISSIONS CHART

0.0

5.0

10.0

15.0

20.0

25.0

12:36

12:37

12:38

12:39

12:40

12:41

12:42

12:43

12:44

12:45

12:46

12:47

12:48

12:49

12:50

12:51

12:52

12:53

12:54

12:55

12:56

12:57

12:58

12:59

13:00

13:01

13:02

13:03

13:04

13:05

13:06

Co

nce

ntr

atio

n %

v/v

Time

O2

O2

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Test Number Start Weight End Weight Total gain Concentration LOD Uncertainty

kg kg kg % % %

Run 1 4.4702 4.5907 0.1205 13.3 0.011 4.9

Test NumberSampling

Duration

Total Volume

SampledSampling Rate Start Leak Rate End Leak Rate

Acceptable

Leak Rate

mins l l/min l/min l/min l/min

Run 1 60 1128 17.2 0.02 0.02 0.34 Yes

Stack Diameter / Depth, D 2.31 m

Stack Width, W - m

Stack Area, A 4.19 m2

Average stack gas temperature 56oC

Stack static pressure 0.042 kPa

Barometric Pressure 101.1 kPa

Pitot tube calibration coefficient, Kpt 0.84 -

Component Molar Density Conc Dry Volume Dry Conc Conc Wet Volume Wet Conc

Mass kg/m3

Dry Fraction kg/m3

Wet Fraction kg/m3

M p % Vol r pi % Vol r pi

CO2 44 1.963059 1.801909 0.018019 0.035373 1.562122 0.015621 0.030665

O2 32 1.427679 20.950000 0.209500 0.299099 18.162102 0.181621 0.259297

N2 28 1.249219 77.248091 0.772481 0.964998 66.968389 0.669684 0.836582

H2O 18 0.803070 - - - 13.307387 0.133074 0.106868

Where: p = M / 22.41 pi = r x p

Determinand

Dry Density (STP), P STD

Wet Density (STP), P STW

Dry Density (Actual), P Actual

Average Wet Density (Actual), P ActualW

Where:

P STD = sum of component concentrations, kg/m3 (not including water vapour) P Actual = P STD x (Ts / Ps) x (Pa / Ta)

P STW = (P STD + pi of H2O) / (1 + (pi of H2O / 0.8036)) P ActualW = P STW x (Ts / Ps) x (Pa / Ta)

Result

PRELIMINARY STACK SURVEY

Leak Tests

Acceptable?

1.022

kg/m3

Units

1.0766

Calculation of Stack Gas Densities

Stack Characteristics

MOISTURE CALCULATIONS

kg/m3

Moisture Quality Assurance


1.2334

kg/m3

1.2995

kg/m3

12:33 - 13:38

18 November 2015

Stack Gas Composition & Molecular Weights

Moisture Determination - Isokinetic


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TRAVERSE 1

Traverse Distance DP pt DP pt Temp Velocity O2 Angle

Point into mmH2O Pa oC m/s % of Swirl

duct (m) (average of 3) (average of 3) m³/s Vol o

1 0.06 6.4 63 56 9.13 38.25 - <15

2 0.19 6.2 60 56 8.95 37.50 - <15

3 0.34 6.3 62 56 9.07 38.00 - <15

4 0.52 6.5 64 56 9.18 38.50 - <15

5 0.79 6.5 64 56 9.18 38.50 - <15

6 1.52 6.0 59 56 8.82 36.99 - <15

7 1.79 6.1 60 56 8.89 37.24 - <15

8 1.97 6.3 61 56 9.01 37.75 - <15

9 2.12 6.2 60 56 8.95 37.50 - <15

10 2.25 6.0 59 56 8.82 36.99 - <15

Mean - 6.2 61 56 9.00 37.72 -

Traverse Distance DP pt DP pt Temp Velocity O2 Angle

Point into mmH2O Pa oC m/s % of Swirl

duct (m) (average of 3) (average of 3) m³/s Vol o

1 0.06 5.9 58 56 8.76 36.73 - <15

2 0.19 6.2 60 56 8.95 37.50 - <15

3 0.34 6.0 59 56 8.82 36.99 - <15

4 0.52 5.8 57 56 8.70 36.47 - <15

5 0.79 6.1 60 56 8.89 37.24 - <15

6 1.52 6.0 59 56 8.82 36.99 - <15

7 1.79 6.0 59 56 8.82 36.99 - <15

8 1.97 6.3 61 56 9.01 37.75 - <15

9 2.12 6.6 65 56 9.24 38.74 - <15

10 2.25 6.8 66 56 9.36 39.23 - <15

Mean - 6.2 60 56 8.94 37.46 -

Start Value End Value Difference Start Value End Value Difference

mmH

₂

O mmH

₂

O % mmH

₂

O mmH

₂

O %

Run 1 164 160 2.4 Pass 170 162 4.7 Pass

RunStagnation

(Pa)

Reference

(Pa)

Difference

(Pa)

Outcome

(Permitted

+/- 10 Pa)

Run 1 42 44 -2.0 Pass

Sampling Line B

11:37

18 November 2015

Sampling Line A

S-Type Pitot

PRELIMINARY STACK SURVEY


Run

Velocity Measurement Device:

PRELIMINARY STACK SURVEY QUALITY ASSURANCE CHECKLIST

Time of Survey

Date of Survey

Volumetric

Flow Rate

(actual)

Volumetric

Flow Rate

(actual)

Pre Traverse Leak Rate

Outcome

Post Traverse Leak Rate

Outcome

PITOT LEAK CHECK

To complete a compliant pitot leak check a pressure of over 80 mmH

₂

O (or 800 Pa) is applied and the pressure drop monitored over 5 mins. A drop of

less than 5% must be observed.

S-Type Pitot Stagnation Check

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EA Technical Guidance Note (Monitoring) M1 Units Requirement Compliant

Lowest Differential Pressure Pa >= 5 Pa Yes

Lowest Gas Velocity m/s - -

Highest Gas Velocity m/s - -

Ratio of Gas Velocities - < 3 : 1 Yes

Maximum angle of flow with regard to duct axis o < 15o

Yes

No local negative flow - - Yes

Velocity at Traverse Point, V = Kpt x (1-e) * Ö(2 * DP pt / P ActualW)

Where:

Kpt = Pitot tube calibration coefficient

(1-e) = Compressibility correction factor, assumed at a constant 0.998

Average Stack Gas Velocity, Va 8.97 m/s

Duct gas flow conditions Actual Reference Units

Temperature 56 0oC

Total Pressure 101.142 101.3 kPa

Oxygen 16.2 17 %

Moisture 13.31 13.31 %

Gas Volumetric Flowrate Units

Average Stack Gas Velocity (Va) m/s

Stack Area (A) m2

Gas Volumetric Flowrate (Actual), QActual m3/hr

Gas Volumetric Flowrate (STP, Wet), QSTP m3/hr

Gas Volumetric Flowrate (STP, Dry), QSTP,Dry m3/hr

Gas Volumetric Flowrate (REF), QRef m3/hr

Where:QActual = Va x A x 3600

QSTP = Q (Actual) x (Ts / Ta) x (Pa / Ps) x 3600

QSTP,Dry = Q (STP) / (100 - (100 / Ma)) x 3600

QRef = Q (STP) x ((100 - Ma) / (100 - Ms)) x ((20.9 - O2a) / (20.9 - O2s))

Nomenclature:

Ts = Absolute Temperature, Standard Conditions, 273 K

Ps = Absolute Pressure, Standard Conditions, 101.3 kPa

Ta = Absolute Temperature, Actual Conditions, K

Pa = Absolute Pressure, Actual Conditions, kPa

Ma = Water vapour, Actual Conditions, % Vol

Ms = Water vapour, Reference Conditions, % VolO2a = Oxygen, Actual Conditions, % Vol

O2s = Oxygen, Reference Conditions, % Vol

<15

8.97

4.19

Result

9.36

Yes


Sampling Plane Validation Criteria

54

97200

8.70

Result

Calculation of Stack Gas Volumetric Flowrate, Q

135330

Calculation of Stack Gas Velocity, V

112120

135925

PRELIMINARY STACK SURVEY (CONTINUED)

1.08

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Value Units

Stack Depth 2.31 m Sampling Distance Distance into Units

Stack Width - m Point (% of Depth) Stack

Area 4.19 m2 A 50 1.16 m

Sampling Distance Distance into Swirl

Point (% of Depth) Stack (m) o

1 2.6 0.06 < 15

2 8.2 0.19 < 15

3 14.6 0.34 < 15

4 22.6 0.52 < 15

5 34.2 0.79 < 15

6 65.8 1.52 < 15

7 77.4 1.79 < 15

8 85.4 1.97 < 15

9 91.8 2.12 < 15

10 97.4 2.25 < 15

11 2.6 0.06 < 15

12 8.2 0.19 < 15

13 14.6 0.34 < 15

14 22.6 0.52 < 15

15 34.2 0.79 < 15

16 65.8 1.52 < 15

Isokinetic sampling point 17 77.4 1.79 < 15

Isokinetic sampling points not used 18 85.4 1.97 < 15

Non Isokinetic/Gases sampling point 19 91.8 2.12 < 15

20 97.4 2.25 < 15

STACK DIAGRAM

Isokinetic Sampling CEN Methods

SAMPLING LOCATION


Non-Isokinetic/Gases Sampling

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Run Sampled

Volume

Sampled Gas

Temp

Sampled Gas

Pressure

Sampled Gas

Humidity

Oxygen

Content

Limit of

Detection

Leak Uncollected

Mass

m³ K kPa % by volume % by volume % by mass % mg

MU required < 2% < 2% < 1% < 1% < 10% < 5% of ELV < 2% < 10% of ELV

Run 1 0.001 2 0.5 1 0.1 0.170 - -

as a % 0.09 0.69 0.49 1.00 0.62 0.621 0.12 0.003

compliant? Yes Yes Yes Yes Yes Yes Yes Yes

Run Uncollected

Mass

m³ mg - mg/m³ mg

Run 1 1.06 5.0100 0.82 0.002 0.0004 -

MU as mg/m3

0.05 0.1243 0.08 0.002 0.0003 0.15

MU as % 1.32 3.3932 - 0.067 0.0081 -

0.31 mg/m³ 8.37 %

(k is a coverage factor which gives a 95% confidence in the quoted figures)

Developed for the STA by R Robinson, NPL

MEASUREMENT UNCERTAINTY BUDGET - TOTAL PARTICULATE MATTER


O2 Correction

R1 - Uncertainty expressed at a 95% confidence level (where k = 2)

Combined

uncertainty

Volume (STP) Mass of

particulate

Leak

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Run Sampled

Volume

Sampled Gas

Temp

Sampled Gas

Pressure

Sampled Gas

Humidity

Oxygen

Content

Concentration

in impinger

Limit of

Detection

Leak

m³ K kPa % by volume % by volume mg % by mass %

MU required <=2% <2.5 k <=1% <=1% <=5% <5% < 5% of ELV <=2%

Run 1 1.37 288.8 101.6 1.0 16.15 0.0186 0.0054 -

as a % 0.07 0.69 0.49 1.00 0.62 3.00 0.29 0.12


Run Lab

Uncertainty

m³ mg - mg/m³ mg

Run 1 1.2962 0.0054 0.8249 0.0008 - -

MU as mg/m3

0.0150 0.0346 0.0236 0.0008 0.0572 0.0725

MU as % 1.3145 3.0198 2.0622 0.0670 5.0 -

0.15 mg/m³ 12.67 %



MEASUREMENT UNCERTAINTY BUDGET - ISOKINETIC FORMALDEHYDE


O2 CorrectionVolume (STP)


Combined

uncertainty

Mass of

Formaldehyde

Leak

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Run Sampled

Volume

Sampled Gas

Temp

Sampled Gas

Pressure

Sampled Gas

Humidity

Oxygen

Content

Concentration

in impinger

Limit of

Detection

Leak



Run 1 1.368 288.8 101.6 1 16.15 0.110 0.032 -

as a % 0.07 0.69 0.49 1.00 0.62 3.00 0.20 0.12


Run Lab

Uncertainty

m³ mg - mg/m³ mg

Run 1 1.2961 0.0320 0.8249 0.0045 - -

MU as mg/m3

0.0892 0.2049 0.1399 0.0045 0.6785 0.7279

MU as % 1.3145 3.0198 2.0622 0.0670 10.0 -

1.46 mg/m³ 21.46 %



O2 Correction


LeakMass of

CVOCs


Combined

uncertainty

Volume (STP)

MEASUREMENT UNCERTAINTY BUDGET - ISOKINETIC CVOCS

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Run Sampled

Volume

Sampled Gas

Temp

Sampled Gas

Pressure

Sampled Gas

Humidity

Oxygen

Content

Concentration

in impinger

Limit of

Detection

Leak



Run 1 1.29 288 101.6 1 16.15 0.02 0.00904 -

as a % 0.08 0.70 0.49 1.00 0.62 3.00 0.53 0.12


Run Lab

Uncertainty

m³ mg - mg/m³ mg

Run 1 1.2303 0.0090 0.8249 0.0023 - -

MU as mg/m3

0.0460 0.1052 0.0721 0.0023 0.3497 0.3751

MU as % 1.3164 3.0067 2.0622 0.0670 10.0 -

0.75 mg/m³ 21.45 %



O2 Correction


Volume (STP) LeakMass of Total

Aldehydes

Combined

uncertainty

MEASUREMENT UNCERTAINTY BUDGET - ISOKINETIC TOTAL ALDEHYDES

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Run Sampled

Volume

Sampled Gas

Temp

Sampled Gas

Pressure

Sampled Gas

Humidity

Oxygen

Content

Leak

m³ K kPa % by volume % by volume %

MU required < 2% < 2% < 1% < 1% < 10% < 2%

Run 1 0.001 2 0.5 1 0.1 -

as a % 0.09 0.69 0.49 1.00 0.62 0.12

compliant? Yes Yes Yes Yes Yes Yes

Run Uncollected

Mass

m³ mg - mg/m³ mg

Run 1 1.06 120500 0.82 71.54 57.74 -

MU as % v/v 0.18 0.01 0.28 0.01 0.006 0.33

MU as % 1.32 0.08 2.06 0.07 0.05 -

0.66 % v/v 4.90 %



Volume (STP)


Leak


O2 CorrectionMass Gained Combined

uncertainty

MEASUREMENT UNCERTAINTY BUDGET - MOISTURE

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200 mg/m3

51.8 mg/m3

397.29 mg/m3

513 mg/m3

Value MU Met?

64 Yes

60 -

30 -

30 -

0.25 Yes

0.15 Yes

0.7 Yes

0.16 Yes

-0.52 Yes

0.02 Yes

0.8 Yes

0.01 Yes

0.1 Yes

0.41 Yes

1 Yes

Uncertainty

ur0

urs

ufit

u0dr

uspres

uapres

utemp

uvolt

uleak

ucalib

uf

73.14 mg/m3

5.92 mg/m3

11.85 mg/m3

5.92 % ELV

11.85 mg/m3

16.20 % value

Standard deviation of repeatability at zero

Standard deviation of repeatability at span level

Lack of fit

0.04

2.07

Expanded uncertainty expressed with a level of confidence of 95%

0.42

0.44

volume or pressure flow dependence 0.00

% of value

dependence on voltage

Span drift

minutes


Dependence on voltage

< 2% of value

% full scale/10K

<2 % range

% full scale

<2% range/24hr

-

Repeatability at zero

Measurement period

-

Units

Concentration @ Ref conditions

% full scale

% full scale

Number of readings in measurement

seconds

-

Combined uncertainty

Expanded at a 95% confidence interval

< 2% of value

Limit value


Analyser Full Scale

5.51

% full scale

% of full scale/2 kPa

specification

MEASUREMENT UNCERTAINTY BUDGET - OXIDES OF NITROGEN

<2 % range

<1 % range

atmospheric pressure dependence

Zero drift

< 0.1%vol /10 volt

<3% / 2 kPa

% full scale/10V

seconds

Cal gas conc

Measured concentration

<2 % / 3 kPa

<2% range / 24hr

0.17

Value of uncertainty quantity

0.00

Drift

Response time

ambient temperature dependence

Uncertainty of calibration gas


0.03

Deviation from linearity

volume or pressure flow dependence

losses in the line (leak) % of value

Performance characteristics


Performance characteristic

Repeatability at span level

Logger sampling interval

losses in the line (leak)

% of value

180

-

Uncertainty in factor


<3% range / 10 K

atmopsheric pressure dependence 0.13

0.03



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100 mg/m3

32.9 mg/m3

185.875 mg/m3

250 mg/m3

Value MU Met?

43 Yes

60 -

30 -

30 -

0.25 Yes

0.15 Yes

0.7 Yes

0.15 Yes

-0.40 Yes

0.02 Yes

0.80 Yes

0.01 Yes

0.10 Yes

0.07 Yes

1 Yes

Uncertainty

ur0

urs

ufit

u0dr

uspres

uapres

utemp

uvolt

uleak

ucalib

uf

45.8 mg/m3

3.61 mg/m3

7.23 mg/m3

7.23 % ELV

7.23 mg/m3

15.78 % value


Units

Limit value

MEASUREMENT UNCERTAINTY BUDGET - CARBON MONOXIDE

Cal gas conc

Analyser Full Scale


seconds


% full scale/10V


0.00

% full scale/10K




Expanded uncertainty


<2 % range

seconds

% full scale

% of value

-




0.03

atmopsheric pressure dependence





< 2% of value

0.22



0.02

0.26

0.03

0.03

0.06


-

-

specification

% full scale


% of value

% of value

% full scale


<2 % / 3 kPavolume or pressure flow dependence

<2% range/24hr

< 2% of value

<3% / 2 kPa


% full scale


1.01


Lack of fit

<2% range / 24hr

-

<1 % range

Response time



Concentration @ Ref conditions

<3% range / 10 K

< 0.1%vol /10 volt

Measurement period

0.00

Zero drift


Span drift

Drift


<2 % range

180

minutes

Uncertainty in factor 3.45



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17 %vol

18.63 %vol

20.95 %vol

25 %vol

Value MU Met?

47 Yes

60 -

30 -

30 -

0.015 Yes

0.014 Yes

0.13 Yes

-0.02 Yes

0.01 Yes

0.02 Yes

0.80 Yes

0.01 Yes

0.14 Yes

0.10 Yes

-0.10 Yes

1.00 Yes

Uncertainty

ur0

urs

ufit

u0dr

uspres

uapres

utemp

-

uvolt

uleak

ucalib

18.63 %vol

0.18 %vol

0.95 %

1.90 % of value

0.355 % vol


specification

-

< 200 sseconds

minutes



MEASUREMENT UNCERTAINTY BUDGET - OXYGEN

% vol <0.3 % volume

% vol at zero level

Measurement period

Reference

Analyser Full Scale

-

-

seconds -

Response time

Lack of fit

% of value




Reported Concentration

Calibration gas

% by volume <0.2 % range

% by volume <0.4 % range



Zero drift (during measurement period)



Combined interference (from mcerts)




0.0862

<2% of volume / 24hr

Units

% by volume /10K <0.3% volume 10 K

0.0808

Combined interference

0.1076

Losses in the line (leak)



0.0122

0.0005

< 2% of value







% of value < 2% of value

% of value

<2% volume/24hr

% of fs / 10l/h <1% range

% of fs/kPa < 1.5 % range

0.0751

-0.0064

0.00003

0.0026

-0.0103


% vol at span level



-

Drift

Span drift (during measurement period)




% range <2% range

% by volume /10V < 0.1%vol /10 volt

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9.0 m/s

135330 m³/hr

Performance Characteristics & Source of Value Units Values Requirement Compliant

Uncertainty of Local Gas Velocity Determination

Uncertainty of pitot tube coefficient - 0.010

Uncertainty of mean local dynamic pressures - 0.35

Factor loading, function of the number of measurements. 3 readings 0.591 minimum 3 Yes

Range of measurment device pa 1000

Resolution pa 1.00

Calibration uncertainty pa 2.85<1% of Value or 20

Pa whichever is

greater

Yes

Drift % range 0.10

Linearity % range 0.06 <2% of value Yes

Uncertainty of gas density determination

Uncertainty of molar mass determination kg/mol 0.00003

Uncertainty of temperature measurement K 1.68 <1% of value Yes

Uncertainty of absolute pressure in the duct pa 516

Uncertainty associated with the estimate of density - 0.008

Uncertainty associated with the measurement of local velocity - 0.0001

Uncertainty associated with the measurement of mean velocity - 0.0002

m/s

0.11

0.22

%

1.24

2.43

m³/hr

3547.13

6952.38

%

2.62

5.14

Expanded Measurement Uncertainty of Volumetric Flow Rate at a 95% Confidence Interval

Expressed as a % of the Measured Concentration

Expanded uncertainty at a 95% Confidence Interval


MEASUREMENT UNCERTAINTY BUDGET - VELOCITY & VOLUMETRIC FLOW RATE

Measured Velocity at Actual Conditions

Measured Volumetric Flow rate at Actual Conditions

Measurement Uncertainty - Velocity



Note - The expanded uncertainty uses a coverage factor of k = 2.

Expanded Measurement Uncertainty of Velocity at a 95% Confidence Interval

Expressed as a % of the Measured Concentration


Measurement Uncertainty Volumetric Flow Rate



Note - The expanded uncertainty uses a coverage factor of k = 2.

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END OF REPORT

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Documents

STACK EMISSIONS MONITORING REPORT · ESG Job Number: Report Date: Version: 1 Report By: Cormac Dunne MCERTS Number: MM 07 885 MCERTS Level: MCERTS Level 2 - Team Leader Technical