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8/2/2019 Spoto & Grasso. Spatially resolved mass spectrometry in the study of art and archaeological objects.
1/8
S}kwokbb yeshbpeg dkss
s}ecwyhdewy ol wae swug h` kyw klgkycakehbhfockb hijecwsFouse}}e S}hwh" Fouse}}e Fykssh
S}kwokbb yeshbpeg dkss s}ecwyhdewy !DS/ os k voges}yekg wecalo{ue olcyeksolfb useg ol dkl kyeks h` yesekyca, H}eykwolf ol k
`ksw" swykofaw`hyvkyg vk vowa dolodkb skd}be gkdkfe" DS olpeswofkwohl ckl }yhpoge s}kwokbb yeshbpeg ol`hydkwohl vowa bhv
bodows h` gewecwohl klg k voge boleky yklfe, @hy waese yekshls" s}kwokbb yeshbpeg DS os k}}boeg ol wae swug h` kyw klg kycakeh$
bhfockb hijecws" klg wae cuyyelw yepoev }yhpoges k suype h` yebepklw }uibockwohls, Ve aofabofaw wae dkol ck}kiobowoes klg wae
bodowkwohls h` s}kwokbb yeshbpeg DS klg goscuss wae dhsw yebepklw k}}bockwohls, 9=;; Ebsepoey Bwg, Kbb yofaws yeseypeg,
Nevhygs: Kycakehdewy> Kwdhs}aeyoc }yessuye DKBGO> Iyhlze> Chlseypkwohl scoelce> Fbkss> Bksey geshy}wohl(ohlozkwohl> DKBGO> Dkss
s}ecwyhdewy> ]ofdelw> Sechlgky ohl dkss s}ecwyhdewy
;, Olwyhgucwohl
Klkbwockb caedoswy }bks kl od}hywklw
yhbe ol wae swug h` kyw klg kycakehbhfockb
dkweyokbs" vaoca aks k pkyoew h` kods,
Vael kywo`kcws kye swugoeg" ol kggowohl wh
kggyessolf {ueswohls h` kuwaelwocow" hwaey
ossues kye kbsh olpeswofkweg !e,f," waewecalhbhf useg wh }yhguce waed" waeoy
goswyoiuwohl `yhd wae }yhgucwohl kyeks"
klg ulgeyswklgolf wae use wh vaoca wae
veye }uw ol wae }ksw/, I olwey}yewolf suca
ol`hydkwohl" ow os }hssoibe wh ulgeyswklg
iewwey wae ieakpohy h` klcoelw }eh}be,
Bhlf$weyd swhykfe h`wel welgs wh hiscuye
caedockb ol`hydkwohl wakw chlwyoiuwes wh
wae kihpe$delwohleg kods, Ow os waus
od}hywklw wh ulgeyswklg" kw wae gee}esw
}hssoibe bepeb" kbb wae }yhcesses h` kbwey$
kwohl wakw olweypele ol wae bo e ccbe h`
klcoelw hijecws,
Kl od}hywklw ossue wh ie kggyesseg
vael pkbukibe }oeces h` kyw hy kycakeh$
bhfockb yedkols kye caedockbb klkbzeg os
ahv wae olwefyow h` wae hijecw os k``ecweg
i wae klkbwockb }yhceguye kgh}weg,
Klkbwockb wecalo{ues kye ogekbb eq}ecweg
wh kphog kl caedockb klg }asockb kbwey$
kwohl h` wae hijecw, @hy waese yekshls"
klkbwockb wecalo{ues kibe wh }ey`hyd wae
klkbsos goyecwb hl wae hijecw dkne ow
ullecessky wh wkne skd}bes klg chde
cbhse wh kyw cuykwhys eq}ecwkwohls, Ol wae
}ksw" ol hygey wh lg k ikbklce iewveel kyw
cuykwhys eq}ecwkwohls klg wae ye{uoye$
delws h` scoelwoc dewahgs" ow vks leces$
sky:
!;/ wh bhckwe wae hijecw ol wae klkbzolf
cakdieys h` wae klkbwockb olswyu$
delw> hy" kbweylkwopeb"!9/ wh scyk}e wol `ykfdelws h` skd}bes
`yhd ows suy`kce,
Ul`hywulkweb" ieckuse kyw hy kycakeh$
bhfockb hijecws akpe wh ie sdkbb wh w
vowaol wae cakdieys h` chddhl klkbwo$
ckb olswyudelws" wae geswyucwope k}}yhkca
h wel yedkols wae bksw yeshyw `hy wae
eqwykcwohl h` klkbwockb ol`hydkwohl `yhd
kywoswoc klg(hy kycakehbhfockb skd}bes,
K bkyfe ludiey h` lev klkbwockb
dewahghbhfoes wakw iewwey skwos` wae
ye{uoyedelw `hy docyh$geswyucwopeless hy
lhl$geswyucwopeless h` wae skd}be wh ie
klkbzeg aks ieel gepebh}eg ol yecelw
ekys ^;T, Ol }kywocubky" ihwa dkss s}ec$
wyhdewy !DS/ klg lhl$DS s}kwokbb ye$
shbpeg klkbwockb wecalo{ues }yhpoge lev
h}}hywulowoes `hy wae docyh$geswyucwope
swug h` skd}bes h` kywoswoc hy kycakeh$
bhfockb od}hywklce ^90T, Ol waos chlweqw"
ed}aksos sahubg ie fopel wh wae lev
}hssoiobowoes h``eyeg i Q$yk uhyescelce
!QY@/$ikseg wecalo{ues wakw kbbhv wae 3G
goswyoiuwohl h` go `eyelw ebedelws ol k
Fouse}}e S}hwh*
Go}kywodelwh go Scoelze
Caodocae" Ulopeysowkm go
Ckwklok" Pokbe Klgyek Ghyok 0"
?5;95" Ckwklok" Owkb
Oswowuwh Iohswyuwwuye e
Iohoddkfolo" CLY" Pokbe K,
Ghyok 0" Ckwklok" Owkb
Fouse}}e Fykssh
Go}kywodelwh go Scoelze
Caodocae" Ulopeysowkm go
Ckwklok" Pokbe Klgyek Ghyok 0"
?5;95" Ckwklok" Owkb
*Chyyes}hlgolf kuwahy,
]yeselw kggyess: Go}kywodelwh
go Scoelze Caodocae"
Ulopeysowkm go Ckwklok" Pokbe
Klgyek Ghyok 0" ?5;95"
Ckwklok" Owkb,
Web,: .3? =?5 6315;7;>
`kq: .3? =?5 51=;3;>
E$dkob: fs}hwhMulocw,ow
Wyelgs Wyelgs ol Klkbwockb Caedoswy" Phb, 3=" Lh, 0" 9=;;
150 =;05$??30(' $ see `yhlw dkwwey 9=;; Ebsepoey Bwg, Kbb yofaws yeseypeg, gho:;=,;=;0(j,wykc,9=;;,=;,=;0
mailto:[email protected]://dx.doi.org/10.1016/j.trac.2011.01.016http://dx.doi.org/10.1016/j.trac.2011.01.016mailto:[email protected]8/2/2019 Spoto & Grasso. Spatially resolved mass spectrometry in the study of art and archaeological objects.
2/8
skd}be wh ie olpeswofkweg vowa s}kwokb yeshbuwohl ol wae
yklfe ;=7= bd ^6T, Suca dewahgs akpe ieel useg wh
odkfe wae 3G swyucwuye h` aoggel }kolw bkeys, Dhyehpey"
wae chdioleg use h` s}kwokbb yeshbpeg }hywkibe QY@
s}ecwyhsch} klg Q$yk kishy}wohl aks kbbhveg wae
kswhlosaolf s`udkwh wecalo{ue useg i Behlkygh Gk
Polco ol wae Dhlk Bosk }kolwolf wh ie goscbhseg ^1T,Ahvepey" s}kwokbb yeshbpeg DS h``eys sod}be skd}be
}ye}kykwohl klg k ck}kiobow `hy docyh$geswyucwope klkb$
sos, Vowa dolodkb skd}be }ye}kykwohl klg gkdkfe" DS
ckl ie useg wh olpeswofkwe iohdhbecubky" hyfkloc hy
olhyfkloc chd}hlelws h` vhyns h` kyw hy kycakehbhfockb
yedkols" }yhpogolf s}kwokbb yeshbpeg ol`hydkwohl ol k
yk}og dklley, Olgeeg" wae gkwk sews chlwkol ol`hydkwohl
hl wae goswyoiuwohl h` caedockb s}ecoes" vaoca os kl
kgpklwkfe ol weyds h` wode ye{uoyeg chd}kyeg wh
dewahgs wakw ye{uoye se}kykwe wkffolf hy swkololf `hy
epey s}ecoes h` olweyesw ^?T,
Olhyfkloc DS dewahgs kye h`wel dhye selsowope wakl
QY@ ol gewecwolf wykce chd}hlelws" vaobe Ykdkldocyhsch} klg @huyoey wykls hyd$ol`ykyeg !@W$OY/ doc$
yhs}ecwyhsch} chd}ewe vowa s}kwokbb yeshbpeg DS ol wae
swug h` chd}beq hyfkloc dkwyoces vael lfey}yolw
s}ecwyk h` wae chd}hlelws kye kpkobkibe, Wae kiobow h`
DS wh }yhpoge ol`hydkwohl use`ub `hy wae goyecw ogelwo$
ckwohl h` ulnlhvl chd}hulgs os chulweyikbklceg i
wae yeguceg s}kwokb yeshbuwohl" vowa vaoca dhsw h` wae
DS dewahgs kye kibe wh h}eykwe" chd}kyeg wh docyh$
Ykdkl klg docyh$@W$OY s}ecwyhsch}oes,
@hy wae yekshls huwboleg kihpe" sepeykb swugoes `hcus$
olf hl wae k}}bockwohl h` go``eyelw s}kwokbb yeshbpeg DS
dewahgs wh wae swug h` vhyns h` kyw klg kycakehbhfockbyedkols akpe yecelwb ieel }yhguceg" klg ve kwwed}w wh
hyfkloze klg wh goscuss wae yesubws kcaoepeg sh `ky,
9, S}kwokbb yeshbpeg dewahgs
Wae s}kwokb yeshbuwohl h` kl klkbwockb wecalo{ue geles
wae kiobow wh eqwykcw klg wh se}kykwe klkbwockb ol`hydk$
wohl `yhd go` eyelw yefohls h` k skd}be, Dhsw h` wae s}kwokbb
yeshbpeg klkbwockb wecalo{ues k}}boeg ol wae swug h`
vhyns h` kyw klg kycakehbhfockb yedkols olphbpe }yhiolf
wae skd}be i eq}hsolf ow wh k uq h` }kywocbes !}ahwhls"
ebecwyhls" ohls" leuwykbs/ klg sodubwklehusb deksuyolf
wae eleyf goswyoiuwohl h` k s}ecoc cbkss h` }kywocbes
edowweg hy sckwweyeg ^;=";;T, Ekca s}kwokbb yeshbpeg
klkbwockb wecalo{ue h}eykwes vowa k s}ecoc bkweykb yesh$
buwohl, Dhyehpey" ge}wa yeshbuwohl os kbsh useg ol hygey wh
cakykcweyoze wae peywockb }ey`hydklce h` suy`kce$selsowope
klkbwockb wecalo{ues klg ow os geleg i wae goswklce
iewveel wae 17% klg ;0% bepebs h` wae ge}wa }yhbe wae
9y bodows h` wae Fkussokl goswyoiuwohl h` wae gewecweg soflkb
kw wae bkeys olwey kce h` k sebecweg ebedelw hy chd}hulg
sklgvocaeg iewveel wvh go` eyelwb chd}hseg bkeys
^;9T, Ol wae ckse h` bksey$ikseg wecalo{ues" wae ge}wa h`
}elewykwohl h` wae olcogelw ykgokwohl" geleg ks wae ol$
peyse h` wae kishy}wohl che`coelw" aks wh ie chlsogeyeg,
Bkweykb yeshbuwohl os sodobkyb geleg `hy ihwa suy`kce$
selsowope klg lhl$suy`kce$selsowope klkbwockb wecalo{ues
klg ye`eys wh waeoy kiobow wh }yhpoge olge}elgelw soflkbs
`yhd go``eyelw kyeks h` wae shbog skd}be, Wae dolodud
goswklce h` wvh kyeks hl wae skd}be suy`kce feleykwolf ksoflkb bepeb h` ;0% klg 17% hy" ulgey dhye swyolfelw
chlgowohls" k soflkb ykwoh h` ;=7" os useg wh {uklwo` wae
bkweykb yeshbuwohl h` DS klkbwockb wecalo{ues ^;9T, S}k$
wokbb yeshbpeg klkbwockb wecalo{ues dhswb h}eykwe vowa k
w}ockb bkweykb yeshbuwohl ol wae yklfe h` docyhls ^9T, Wae
lhpeb" use`ub ks}ecw h` s}kwokb yeshbuwohl os wh odkfe wae
goswyoiuwohl h` ebedelws hy chd}hulgs kcyhss k skd}be
suy`kce, Wae goyecw klkbsos h` docyhsch}oc kyeks h` k vhyn
h` kyw dk ie kcchd}bosaeg i bkweykb yeshbuwohl" waeyei
kbbhvolf wae eqwykcwohl h` k voge yklfe h` pkbukibe klk$
bwockb ol`hydkwohl wakw ckl ie chyyebkweg vowa kl odkfe,
K sdkbb bkweykb yeshbuwohl kbsh dknes }hssoibe wae klkbsos
h` wol `ykfdelws h` skd}bes scyk}eg `yhd wae hijecw h`olweyesw vowa dolodkb gkdkfe wh wae kywo`kcw owseb`,
Wae kiobow wh yeshbpe klkbwockb gkwk s}kwokbb os dhswb
useg wh chbbecw ol`hydkwohl `yhd k s}ecoc yefohl h` wae
skd}be vowaol kl kyek usukbb ol wae yklfe welwas wh
aulgyegs h`bd9, Ol waos ckse" bhckbozeg klkbsos vowa k
bkweykb yeshbuwohl wakw os k goyecw chlse{uelce h` wae
kiobow wh `hcus wae olcogelw klg(hy wae edowweg iekd h`
bofawey }kywocbes os hiwkoleg,
3, Yhbe h` DS ol swugolf vhyns h` kyw klg
kycakehbhfockb yedkols
Klkbwockb wecalo{ues useg `hy wae swug h` dkweyokbs hy
hijecws h` kywoswoc hy kycakehbhfockb od}hywklce kye eq$
}ecweg wh }yhpoge k vekbwa h` ol`hydkwohl hl:
!;/ wae caedockb chd}hsowohl hy lkwuye h` wae dkweyokb
ulgey swug>
!9/ wae swkwe h` kbweykwohl h` wae hijecws ckuseg i wae
bhlf$weyd eq}hsuye wh wae elpoyhldelw> klg"
!3/ wae e``ecws h` yeswhykwohl }yhceguyes,
Kbb wae kihpe ol`hydkwohl dusw ie eqwykcweg `yhd
skd}bes wakw kye k chd}beq doqwuye h` go``eyelw caedockb
chd}hulgs, Klcoelw kywo`kcws veye dklu`kcwuyeg i
dklo}ubkwolf lkwuykb }yhgucws wakw veye h`wel k doqwuye
h` ihwa hyfkloc klg olhyfkloc chd}hulgs, Wae }yhcesses
h` caklfe wakw olweypele ol wae bo`e ccbe h` wae kywo`kcws
chlwyoiuwe wh olcyeksolf `uywaey waeoy caedockb chd$
}beqow, Ol waos scelkyoh" wae fyekw }hwelwokb h` DS wh
ogelwo caedockb s}ecoes }yeselw ol chd}beq doqwuyes
aks ieel vogeb useg ol wae swug h` vhyns h` kyw klg
kycakehbhfockb yedkols,
Olhyfkloc DS aks ieel }kywocubkyb use`ub `hy caedockb
lfey}yolwolf" ks }yhpelklce h` kycakehbhfockb dkweyokbs
os h`wel ol`eyyeg i epkbukwolf yesubws `yhd wykce$ebedelw
klkbsos hy `yhd {uklwowkwope geweydolkwohl h` wae yebkwope
Wyelgs ol Klkbwockb Caedoswy" Phb, 3=" Lh, 0" 9=;; Wyelgs
aww}:((vvv,ebsepoey,chd(bhckwe(wykc 156
http://dx.doi.org/10.1016/j.trac.2011.01.016http://dx.doi.org/10.1016/j.trac.2011.01.016http://dx.doi.org/10.1016/j.trac.2011.01.016http://dx.doi.org/10.1016/j.trac.2011.01.0168/2/2019 Spoto & Grasso. Spatially resolved mass spectrometry in the study of art and archaeological objects.
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kdhulws h` sebecweg oshwh}es ^;3T, Olhyfkloc DS aks kbsh
ieel k}}boeg wh ogelwo` }ofdelws ol }kolws hy wae dkol
chlswowuelws h` fbkss klg ceykdoc hijecws" elkdebs klg
fbkzes ^;7T, Ahvepey" hyfkloc DS aks ieel vogeb useg wh
gekb vowa k pkyoew h` go``eyelw }yhibeds chlceylolf wae
ogelwockwohl h` hyfkloc klg iohdhbecubky chd}hulgs
chlswowuwolf kywoswoc" aoswhyoc klg kycakehbhfockb hijecws^;5T, Wae hyfkloc ykv dkweyokbs useg ol ihwa wykgowohlkb
kyw klg kycakehbhfockb chlweqws kye" `hy wae dhsw }kyw"
lkwuykb }yhgucws" klg" aelce" chd}hseg h` chd}beq doq$
wuyes h` olhyfkloc" hyfkloc klg iohdhbecubky chd}hlelws
^;0T, Dhyehpey" wae olwelwohlkb doqolf h` hyfkloc iolgeys
klg }ofdelws guyolf wae }ye}kykwohl h` }kolwolf dkweyokbs
hy ye}ekweg use h` kycakehbhfockb chhnolf pessebs wh }ye$
}kye k yklfe h` go``eyelw `hhgswu``s kye wvh eqkd}bes h`
audkl kcwopowoes wakw olwyhguce `uywaey chd}beqow olwh
wae caedockb chd}hsowohl h` wae ykv dkweyokbs,
@uywaey olcyekses ol wae chd}beqow h` chd}hsowohl
geyope `yhd wae wykls`hydkwohl h` wae hyofolkb lkwuykb
dkweyokbs feleykweg i wae gefykgkwohl }yhcesses hccuy$yolf wayhufa dkweyokb use klg elpoyhldelwkb eq}hsuye
^e,f," }yhweoc dkweyokbs useg ol wykgowohlkb wed}eyk
}kolwolf kye suijecw wh chlgelskwohl klg cyhss$bolnolf
yekcwohls vowa hwaey chd}hlelws !e,f," bo}ogs/T, Wae
ul}kykbbebeg ck}kcow h` DS wh yepekb ol`hydkwohl use`ub
`hy ogelwo`olf wae hyfkloc chd}hlelws h` kywoswoc" aoswhyoc
klg kycakehbhfockb hijecws vowa `uywaey }hssoiobowoes `hy
waeoy gewecwohl klg {uklwockwohl kw wykce bepebs ol chd$
}beq dkwyoces geyopes `yhd wae kiobow wh chu}be cayh$
dkwhfyk}aoc wecalo{ues wh dkss s}ecwyhdeweys" waeyei
kbbhvolf se}kykwohl h` wae olgopogukb dhbecubky s}ecoes
vowa hl$bole DS klkbsos h` wae ebuwolf chd}hlelws ^;6T,K sodobky k}}yhkca vks kgh}weg wh {uklwo` wae chd$
}hulg$s}ecoc ckyihl !g;3C/ klg agyhfel !gG/ oshwh}e$
ykwoh pkbues `yhd `kww$kcog yesogues goschpeyeg hl }hws$
aeygs `yhd Nkzknaswkl klg kwwyoiuweg wh wae Elehbowaoc
Ihwko Cubwuye !kihuw 35== ICE/ ^;1T, Wae swug }yhpogeg
wae ekyboesw epogelce h` ahyse ghdeswockwohl ol klwo{uow,
Ol shde ckses" kl olweygosco}bolky k}}yhkca os lec$
essky o` go``eyelw chd}hlelws h` }yecohus skd}bes akpe
wh ie ogelwoeg, @hy eqkd}be" ol hygey wh kssess wae
chd}hlelws h` klcoelw chsdewocs klg wh hiwkol iewwey
ulgeyswklgolf h` waeoy }ye}kykwohl" chd}bedelwky DS
wecalo{ues veye eq}bhoweg !e,f," }yhbsos FC$DS klg
hwaey klkbwockb k}}yhkcaes/ ^;?T, Ow vks waeye`hye }hs$
soibe wh ogelwo` go``eyelw }ye}kykwohl }yhceguyes h` wvh
Yhdkl esa$chbhyeg dkne$u}s wakw veye }yeseypeg hl
wae suy`kce h` k Yhdkl iyhlze chsdewoc whhb klg ol k
fbkss ulfuelwkyoud,
Hyfkloc DS os kbsh vogeb k}}boeg `hy yeswhykwohl hy
chlseypkwohl }uy}hses, Vael swugolf }kolw bkeys ol
kywvhyns" wae olpeswofkwohl h` waeoy chd}beq hyfkloc$
caedockb chd}hsowohl kods wh ogelwo ihwa hyofolkb
chlswowuelw dkweyokbs klg wahse chd}hlelws `hydeg ks k
chlse{uelce h` kfolf, Suca swug os h` fyekw od}hywklce
wh sebecw wae dhsw k}}yh}yokwe chlseypkwope swykwef,
Ol waos chlweqw" FC$DS aks ieel sahvl wh ogelwo`
bo}ogs" vkqes" }yhweols" klg yesolhus dkweyokbs useg ol
cyekwolf }kolweg vhyns, Ol }kywocubky" wae }hwelwokb h`$
`eyeg i FC$DS vael chdioleg vowa }yh}ey caedockb
}yhceguyes vks gedhlswykweg usolf =,9=,?$df skd}bes
scyk}eg `yhd:
!;/ wae }kolweg aubb h` k sao}vyecn gkweg wh wae bkwe;6==s(ekyb ;1==s>
!9/ kl Owkbokl }kolwolf hl cklpks }yhguceg iewveel
bkwe ;0==s klg ekyb ;6==s> klg"
!3/ k }kolweg Ewyuyokl skych}akfus ^9=T,
Caklfes ol wae caedockb chd}hsowohl h` }kolwolfs ckl
kbsh hccuy ol duseud elpoyhldelws, Wed}eyk }kolws
su``ey `yhd kbweykwohls dhswb olphbpolf wae pkylosa bkey
klg wae iolgolf degoud, Cahbesweyhb$hqogkwohl }yhgucws
!CH]s/ akpe ieel sahvl wh yesubw `yhd bofaw$kfeolf h`
eff$iolgolf degok klg waeoy }yeselce vks }yh}hseg ks k
dkyney h` bofaw$olguceg gefykgkwohl h` wae iolgolf
degoud ^9;T, Goyecw$wed}eykwuye$yeshbpeg DS !GWDS/
klkbses h` skd}bes wknel `yhd }kolweg Feydkl ikyh{uekbwkys klg `yhd wae Yeg hl Dkyhhl duykb }kolwolf swhyeg
kw Wkwe Dhgeyl Bhlghl akpe chlydeg wae }yeselce h`
CH]s,
7, S}kwokbb yeshbpeg DS
Ol wae eqkd}bes goscusseg kihpe" wae DS$ikseg klkbses
ye{uoyeg `ykfdelws h` shbog skd}bes !w}ockbb ;;= df/
wh ie wknel `yhd wae hijecw wh ie olpeswofkweg, Ahvepey"
ol yecelw ekys" DS wecalo{ues wakw use s}kwokbb yeshbpeg
ohlozkwohl shuyces akpe ieel k}}boeg `hy wae docyh$geswyucwope swug h` kywoswoc klg kycakehbhfockb hijecws,
Sechlgky ohl !SO/ DS uses ohl iekds ol hygey wh fel$
eykwe cakyfeg s}ecoes `yhd wae skd}be suy`kce vaobe bksey
geshy}wohl ohlozkwohl !BGO/ klg bksey kibkwohl !BK/
dewahgs yeb hl wae use h` }ahwhls feleykweg i bksey
shuyces, Wae bkweykb yeshbuwohl ol waese dewahgs os od$
}yhpeg i `hcusolf wae olchdolf }yodky iekd, Wkibe ;
sahvs wae w}ockb bkweykb yeshbuwohl klg ge}wa h` }ele$
wykwohl `hy wae s}kwokbb yeshbpeg wecalo{ues useg ol wae
swug h` kyw klg kycakehbhfockb hijecws goscusseg ol waos
yepoev vowa hwaey ol`hydkwohl yebkweg wh wae geswyucwop$
ow h` wae dewahg klg wae Q_Z wyklsbkwohl bodow, Wae
bkwwey ol`hydkwohl os od}hywklw ol hygey wh epkbukwe wae
phbude h` wae 3G hijecws wakw ckl ie klkbzeg i usolf
ekca h` wae goscusseg s}kwokbb yeshbpeg wecalo{ue,
7,;, S}kwokbb yeshbpeg SODS
Ohl s}uwweyolf os wae }asockb }yhcess ulgeybolf SODS
gewecwohl, Ow yeboes hl k cksckge h` kwhdoc chbbosohls
feleykweg vael eleyfewoc ohls aow wae suy`kce h` wae shbog
wkyfew, Wae eleyf ge}hsoweg i wae ihdikygolf ohls os
}kywokbb yeecweg ikcn wh wae suy`kce wayhufa wkyfew
Wyelgs Wyelgs ol Klkbwockb Caedoswy" Phb, 3=" Lh, 0" 9=;;
151 aww}:((vvv,ebsepoey,chd(bhckwe(wykc
8/2/2019 Spoto & Grasso. Spatially resolved mass spectrometry in the study of art and archaeological objects.
4/8
kwhds dhiobozeg i wae od}kcw h` olcogelw ohls hy
wayhufa cksckge chbbosohls, Vael wae eleyf h` wae ye$
chobeg kwhds leky wae suy`kce os fyekwey wakl wae iolgolf
eleyf h` wae suy`kce kwhds" waese kye ejecweg olwh wae
pkcuud elpoyhldelw, Wae olweykcwohl phbude h` wae
}yodky olcogelw ohls vowa wae shbog suy`kce ge}elgs
u}hl wae eleyf h` wae }yodky ohl iekd klg wae wkyfewchd}hsowohl" iuw wae s}uwweyeg s}ecoes hyofolkwe `yhd lh
dhye wakl wae ysw wvh kwhdoc bkeys, @hy waos yekshl"
SODS os k pey suy`kce$selsowope klkbwockb wecalo{ue,
SODS" ol }yolco}be" os ck}kibe h` caedockbb klkbzolf
klg odkfolf ihwa olhyfkloc klg hyfkloc chd}hlelws
wakw kye }yeselw kw dkjhy" dolhy hy wykce bepebs ol shbog
skd}bes vowa k bkweykb yeshbuwohl ks sdkbb ks 5= ld ^99T,
Sckllolf ebecwyhl docyhsch}(eleyf gos}eysope Q$yk
uhyescelce s}ecwyhsch} !SED$EGQY@/ ^93T" }kywocbe$
olguceg Q$yk edossohl !]OQE/ ^97T klg bksey$olguceg
iyeknghvl s}ecwyhsch} !BOIS/ ^95T yopkb SODS ol waeoy
s}kwokb yeshbuwohl h` olhyfkloc chd}hlelws h` vhyns h`
kyw klg kycakehbhfockb hijecws, Ahvepey" SODS aks sof$locklwb bhvey bodows h` gewecwohl !BHGs/ !ol wae yklfe
=,=;; ;=? kwhds(cd9/ klg k duca bhvey ge}wa
}elewykwohl, SODS kbsh aks sdkbbey bkweykb yeshbuwohl
chd}kyeg wh docyhBOIS !3;5 bd/ ^90T klg SODS kbbhvs
caedockb odkfes h` wae klkbzeg suy`kce wh ie hiwkoleg
usolf s}ecoc ohl$gewecwohl dhges,
K goswolcwohl os dkge iewveel wae swkwoc !s/ klg g$
lkdoc !g/ SODS h}eykwohlkb yefodes" ekca h` vaoca oebgs
go``eyelw ol`hydkwohl klg klkbwockb `ekwuyes, Ol hygey wh
ulgeyswklg wae iksoc go` eyelces iewveel wae wvh ye$
fodes" ve sahubg chlsogey wakw k }yodky ohl uq h`
;=;5
ohls(cd9
(s os su`coelw wh s}uwwey dhye wakl hlekwhdoc bkey(s `yhd wae wkyfew suy`kce, O` wae }yodky
iekd os w}ockbb `hcuseg hpey kl kyek h` wae wkyfew
suy`kce h` kihuw ;=7;=5 bd9 klg wae kc{uosowohl wode
os bhlfey wakl ; s" wael kl klkbsos ckyyoeg huw i usolf
k chlwoluhus }yodky iekd }yhpoges ol`hydkwohl hl k
suy`kce yeleveg chlwoluhusb i wae s}uwweyolf }yhcess,
Sodobky h}eykwolf chlgowohls gele wae gSODS yefode
wakw os use`ub `hy swugolf wae ge}wa$}yhbe chd}hsowohl
h` wae skd}be ^96"91T, Vael wae }yodky ohl uq os
gecyekseg wh ;=;;;=;3 ohls(cd9(s" sh wakw hlb sec$
hlgky ohls s}uwweyeg `yhd k `ykcwohl h` kl kwhdoc bkey
kye chbbecweg" wae swkwoc yefode os eswkibosaeg, Ulgey waos
yefode" sSODS h}eykwes ks k suy`kce$s}ecoc klkbwockb
wecalo{ue" solce hlb ol`hydkwohl `yhd wae huwey kwhdoc
bkey h` wae wkyfew os hiwkoleg,
Dkjhy gykvikcns `hy SODS klkbses h` klcoelw hijecws
kye wae ye{uoyeg ubwyk$aofa pkcuud elpoyhldelw !;=?
;=;; whyy/ klg go`cubwoes vowa {uklwockwohl }yhce$
guyes, Dhyehpey" wae olswyudelwkwohl os lhw dhiobe, @hy
BOIS ^95"9?T" chd}kcw e{uo}delw ckl ie useg klg wae
klkbsos ckl ie chlgucweg hl sowe !e,f," wae duseud" wae
chlseypkwohl bkihykwhy" hy epel huwghhys kw kl eqck$
pkwohl sowe/, Lepeywaebess" skd}be ye{uoyedelws `hy SODS
klkbsos kye lhw }kywocubkyb swyolfelw, Kbwahufa skd}be
soze os k soflocklw bodowkwohl" shbog skd}bes kye usukbb
goyecwb klkbzeg vowa lh s}ecokb }yebodolky wyekwdelws,
Skd}bes h` kihuw 9=3= dd ol gokdewey klg lh dhye
wakl 5 dd ol aeofaw kye kbbhveg vowa wykgowohlkb SODS
e{uo}delw" kbwahufa wae skd}be dusw whbeykwe wae SODS
ubwyk$aofa pkcuud elpoyhldelw, Suca k ye{uoyedelw os
}kywocubkyb cyowockb" solce geshy}wohl h` fksehus chd}h$lelws ol wae ubwyk$aofa pkcuud cakdiey ckl k``ecw wae
olwefyow hy wae sak}e h` hyfkloc hijecws !e,f," dkluscyo}w
`ykfdelws hy }kolwolf skd}bes/, K lkb yedkyn chlceyls
skd}be chlgucwopow" ks chlgucwolf skd}bes kye klkbzeg
dhye eksob, Lepeywaebess" suy`kce cakyfolf wakw hccuys
vael lhl$chlgucwolf skd}bes kye klkbzeg ckl shde$
wodes ie }yepelweg i usolf pey bhv }yodky$ohl ghses
hy ebecwyhl$hhgolf }yhceguyes,
Wae suy`kce selsowopow h` sSODS ckl ie k sepeye
}yhibed vael gekbolf vowa vekwaeyeg hy chyyhgeg
dkweyokbs, Caklfe }yhcesses dhgo` wae suy`kce chd}h$
sowohl wh suca k gefyee wakw wae ol`hydkwohl hiwkoleg
dk ie chlsogeyeg ye}yeselwkwope h` hlb wae wh} `evdhlhbkeys h` wae kbweyeg suy`kce, Ahvepey" swugoes
kodeg kw ogelwo`olf vekwaeyolf }yhcesses ol waeoy ekyb
swkfes dk fyekwb ielew `yhd wae use h` waos suy`kce
wecalo{ue, Suy`kce$selsowopow bodowkwohls dk kbsh ie
}kywb hpeychde i usolf wae ge}wa }yhbes wakw gSODS
ckl }yhpoge,
SODS vks ysw useg ol wae swug h` kyw klg kycakeh$
bhfockb hijecws ol wae ;?1=s" klg k ludiey h` k}}bock$
wohls akpe yepekbeg ows }hwelwokb klg bodowkwohls ol wae
swug h` klcoelw dkweyokbs ^3=T, K gewkobeg gescyo}wohl h`
suca swugoes dk ie `hulg ol yepoev kywocbes }uibosaeg ol
wae }ksw `ev ekys ^3=39T, Wae voge ebedelwkb yklfewakw ckl ie olpeswofkweg !}hwelwokbb `yhd A wh U/" ows
eqcebbelw BHGs klg wae {uklwowkwope ol`hydkwohl
hiwkolkibe vael usolf SODS kye jusw shde h` wae
kgpklwkfes h` waos wecalo{ue, Wae use h` wode$h`$ofaw
!Wh@/ dkss klkbzeys aks od}yhpeg wae }ey`hydklce h`
SODS ol weyds h` klkbzeg dkss yklfe" suy`kce selsowopow
klg dkss yeshbuwohl, Chu}bolf Wh@ dkss klkbzeys od$
}yhpeg }ey`hydklces" ks wae swkwoc chlgowohls kbbhveg i
wae }ubseg ohl shuyce useg ol Wh@$SODS aks eq}klgeg
wae k}}bockwohl h` SODS wh wae swug h` k pkyoew h` hy$
fkloc" }hbdeyoc klg iohbhfockb dkweyokbs,
Dewkbs klg kbbhs kye" ol }yolco}be" fhhg dkweyokbs `hy
SODS klkbsos, Wae kye ebecwyockbb chlgucwope" ckl
eksob ie aklgbeg sh ks wh hiwkol cbekl" kw klg sdhhwa
suy`kces `hy klkbsos" klg kye kbsh usukbb chd}kwoibe
vowa ubwyk$aofa pkcuuds, Ahvepey" kycakehbhfockb klg(
hy kywoswoc dewkb hijecws gh lhw kbvks }hssess kbb h` waese
}yh}eywoes gue wh gefykgkwohl }yhcesses" vaoca dk
caedockbb dhgo` ihwa wae suy`kce klg wae olweyohy h`
skd}bes, Lhl$chlgucwope }kwolks klg olbwykweg chd$
}hulgs dk h`wel `hyd ks k yesubw h` bhlf iuyokb ol shob hy
eq}hsuye wh wae kwdhs}aeye" klg waese dofaw akpe pey
go``eyelw cakykcweyoswocs chd}kyeg wh wahse hiseypeg `hy
}uye hy kbbheg dewkbs,
Wyelgs ol Klkbwockb Caedoswy" Phb, 3=" Lh, 0" 9=;; Wyelgs
aww}:((vvv,ebsepoey,chd(bhckwe(wykc 15?
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Wkibe ;, Suddky h` shde yebepklw cakykcweyoswocs h` wae s}kwokbb yeshbpeg dewahgs goscusseg
BK$OC] docyh BOIS BGO$UP DKBGO$OY DKBGO$UP K]$DKBGO
W}ockb bkweykbyeshbuwohl
53== bd^76T
3;5 bd^90T
9==5== bd ;==3== bd^5;"59T
5=9== bd^5;T
'7== bd^6;T
5=;^96T
W}ockb ge}wah` }elewykwohl
';== ld}ey bksey}ubse^76T
;==5== ld^9?T
5=9== ldk
^5;T;,59,= bd^5;T
5=9== ld^5;T
5=9== ld^5;T
95 ^91
W}ockb Q_Zdhpkibe yklfei
Q_ 4 5 cd>Z 4 9 cd
Q_Z 4 9= cd Q_ 4 9=cdZ 4 =
Q_ 4 9=cdZ 4 =
Q_ 4 9=cdZ 4 =
QZ 4 5= cd>_ 4 3= cdc
Q_ 4Z 4 9
H}eykwolf }yessuye 60= whyyKyfhl fks
60= whyykoy
;=6;=1 whyy ;=6;=1 whyy ;=6;=1 whyy 60= whyykoy
;=?
Yedhpeg dkweyokb 5=5== bf =,=;=,9 bf^95T
K `ev wels h`bfh` dkweyokb os skd}beg`yhd wae hijecw wh ieklkbzeg^75T
@dhb }ey }ubsebksey^5=T
Kdhb }ey}ubse bksey^5;T
=,33 ldhbes(dd9
^6;T'}f
K}}bockwohlsh` klkbsos
Wykce$ebedelwklg oshwh}e h`dewkbs" }hwweyklg doleykbs
Ebedelws h`dewkbs" }hwwey"fbkss" swhle" shob"}ofdelws
Hyfkloc klg olhyfkloc}ofdelws klg ges,
Hyfklocchd}hlelwsklg yesogues
Hyfklocchd}hlelwsklg yesogues
Hyfkloc chd}hlelws:}ofdelws" ges"iolgeys" yesols
Fbksklcodewkhiso
k Dhsw h` wae BGO$DS eq}eyodelws veye ckyyoeg huw usolf swklgkyg DKBGO e{uo}delw, @hy waos yekshl" bkweykb klg ge}wa yeshbuwohl sodobky wh DKBGO weyd h` bkweykb yeshbuwohl veye hiwkoleg usolf s}ecockbb gesofleg bksey$docyh}yhie e{uo}delw ^5;T,
i Wae pkbues sahvl ye`ey wh swklgkyg chddeycokb e{uo}delw,c Wae ye}hyweg pkbues ye`ey wh e{uo}delw s}ecockbb gesofleg `hy wae klkbsos h` kyw hijecws ^6;T,
10=
aww}:((vvv,ebsepoey,
chd(bhckwe(wykc
8/2/2019 Spoto & Grasso. Spatially resolved mass spectrometry in the study of art and archaeological objects.
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Sepeykb dewkb hijecws h` kycakehbhfockb klg kywoswoc
olweyesw akpe ieel swugoeg usolf SODS, Waese olcbuge
iyhlze kywo`kcws ^33"37T" klcoelw sobpey chols ^35T" klg
klwo{ue oyhl dusoc voyes ^30T,
SODS aks ieel `ye{uelwb useg ol wae swug h` wae
geweyohykwohl h` fbkss hijecws ^36T, Fbkss os chddhlb
susce}woibe wh k pkyoew h` yekcwohls wakw k``ecw ows guyk$iobow, Klcoelw fbksses dhsw cbekyb sahv wae chlse$
{uelces h` waeoy yebkwopeb bodoweg yesoswklce wh kwwkcn i
vkwey" kcog klg kbnkbole k{uehus shbuwohls" swekd" hy
kwdhs}aeyoc kfelws, Bhlf eq}hsuye wh caklfe kfelws
vhysels wae chlse{uelces h` gefykgkwohl" vaoca os kbsh
seel wh k``ecw dhgeyl fbksses, Fbkss vekwaeyolf s}eco$
ckbb olphbpes kwwkcn i vkwey chdioleg vowa elpoyhl$
delwkb klg iohbhfockb kfelws, Vkwey chyyhsohl os s}kyneg
h`` i kl ohl$eqcaklfe decaklosd olphbpolf wae kbnkbo
ohls ol wae fbkss klg agyhfel `yhd wae elpoyhldelw,
SODS aks ieel useg wh swug k pkyoew h` klcoelw fbksses
vowa wae kods h` ulgeyswklgolf wae gefykgkwohl }yhcess
^31T" }yhpelklce ^36T klg gkwolf ^3?T,Wae use h` ihwa s}ecwyhsch}oc klg odkfolf SODS ol wae
swug h` }ofdelws klg iolgolf degok useg ol }kolwolfs
akpe sahvl wae }hwelwokb h` SODS wh cakykcweyoze klg wh
odkfe ihwa olhyfkloc klg hyfkloc s}ecoes ^7="7;T, SODS
aks ieel useg wh odkfe }ofdelw goswyoiuwohls ol cyhss
secwohls h` }kolw" waus chlwyoiuwolf wh wae ogelwockwohl h`
wae go` eyelw wecalo{ues useg ol wykgowohlkb }kolwolf
^79"73T, Ol klhwaey swug" ow vks }hssoibe wh eqkdole
pkyokwohls olwae chd}hsowohl h`wae wh} klg wae ihwwhd h`k
}kolw bd" klg wae s}kwokb chyyebkwohl iewveel dewkb klg
`kww$kcog chd}hsowohl ol dewkb$shk} kffyefkwes ^7=T,
7,9, S}kwokbb yeshbpeg BGO$ikseg DS
S}kwokbb yeshbpeg DS klkbsos h` kywoswoc hy kycakehbhf$
ockb hijecws ckl kbsh ie ckyyoeg huw i geshyiolf cakyfeg
s}ecoes `yhd wae skd}be suy`kce vowa k bksey iekd, Wae
svowca `yhd }yodky ohls wh bksey iekds soflocklwb
yeguces wae bkweykb yeshbuwohl" w}ockbb fholf `yhd wae
sui$docyhl yklfe wh wae wels$h`$docyhls yklfe !Wkibe ;/,
Ahvepey" ow os }hssoibe wh chlwyhb wae bksey$iekd gokdewey
klg `hcus ol hygey wh od}yhpe wae s}kwokb yeshbuwohl h`
wae klkbsos, Wae use h` `ky$UP hy OY bksey shuyces
h}eykwolf vowa }ubse guykwohls ol wae ls yklfe aks ieel
sahvl wh ie od}hywklw `hy wae goyecw bksey geshy}wohl h`
cakyfeg hyfkloc s}ecoes vowa dhbecubky veofaws h` kihuw
;9 nGk ^77T, Dhyehpey" wae bhss h` s}kwokb yeshbuwohl
hccuyyolf vael bksey iekds kye useg olswekg h` }yodky
ohls os chulweyikbklceg i wae bess gedklgolf pkcuud
ye{uoyedelws wakw wyklsbkwe olwh elaklceg }hssoiobowoes
`hy wae goyecw klkbsos h` vhyns h` kyw klg kycakehbhfockb
hijecws, @hy waos yekshl" BGO(DS os h`wel k}}boeg ks k
chd}bedelwky klkbwockb whhb `hy use ol wae chlseypk$
wohl bkihykwhy kbhlfsoge hwaey wecalo{ues ~e,f," @huyoey
wykls`hyd ol ykyeg !@WOY/ s}ecwyhsch} klg Ykdkl
docyhsch} ^75Tt, Kl kgpklwkfe h` BGO(DS hpey Ykdkl
docyhsch} os wakw" ol dkl ckses" i usolf ihwa }hsowope
klg lefkwope ohl dhges" BGO(DS }yhpoges selsowope"
s}ecoc ogelwockwohl h` hyfkloc ssweds ikseg sod}b hl
eqkcw dksses h` `ykfdelw ohls klg oshwh}oc }kwweyls,
Wae bksey$geshy}wohl yefode os eswkibosaeg vael k shbog
skd}be os oyykgokweg vowa bksey uelcoes h` =,=;; J(cd9,
Ulgey suca chlgowohls" skd}be pk}hyozkwohl klg }kywokb
ohlozkwohl iefols, Fyekwey bksey uelce ckuses }yh$lhulceg gechd}hsowohl h` wae oyykgokweg suy`kce, Ol
kggowohl" wae gepebh}delw h` bkyfe swyess vkpes gue wh
wae waeydkbb$olguceg eq}klsohl ckl yesubw ol shbog$
dkwyoq gosolwefykwohl klg wae chbbecwope ejecwohl h` bkyfe
dhbecubky cbusweys ^70T, Waos }aelhdelhl" nlhvl ks
bksey kibkwohl" os eq}bhoweg i bksey kibkwohl$olgucwopeb
chu}beg }bksdk !BK$OC]/$DS ol hygey wh }ey`hyd dubwo$
ebedelwkb klg oshwh}oc klkbses h` shbog skd}bes, BK$OC]$
DS os pey suowkibe `hy swugolf kyw klg kycakehbhfockb
hijecws ieckuse ow h``eys wae eqoiobow wh kcaoepe s}kwokbb
yeshbpeg ol`hydkwohl vowa bhv BHGs klg k voge boleky
yklfe vowa dolodkb skd}be gkdkfe, Waos wecalo{ue os
dkolb useg wh hiwkol dubwo$ebedelw ol`hydkwohl kwpkyohus chlcelwykwohl bepebs" fopolf ebedelwkb hy oshwh}oc
lfey}yolws wakw chubg aeb} wh klsvey yebepklw kycake$
hbhfockb {ueswohls" h`wel chlceylolf skd}bes suca ks
chols klg }hwwey, Ahvepey" ks waos wh}oc aks ieel pey
yecelwb yepoeveg ^76T" ve gh lhw goscuss ow `uywaey,
Lhvkgks" wae }hssoiobowoes h``eyeg i goyecw BGO$DS ol
wae swug h` lhl$phbkwobe chd}hulgs dkolwkoleg ulgey
pkcuud kye vebb nlhvl ^71T" klg bodowkwohls ol olpeswo$
fkwolf bkyfe dhbecubes akpe ieel eswkibosaeg, Ahvepey"
shde bodowkwohls su` eyeg i BGO$DS veye coycudpelweg ol
;?16 vowa dkwyoq$kssosweg !DK/BGO$DS ^7?T, Ol DKBGO"
wae klkbwe chd}hulgs kye edieggeg ol k suy}bus h` klhyfkloc chd}hulg !dkwyoq/ wakw os ch$geshyieg u}hl bksey
eqcowkwohl, Waos chd}hulg os cahsel kcchygolf wh wae
klkbwe }yh}eywoes klg wae bksey eleyf ^5=T, Wae dkwyoq
}yhpoges k ludiey h` go``eyelw `ulcwohls" olcbugolf:
!;/ oshbkwolf wae klkbwe dhbecubes klg }yepelwolf waeoy
kffyefkwohl>
!9/ kishy}wohl h` wae bksey eleyf pok ebecwyhloc hy
poiykwohlkb eqcowkwohl !ge}elgolf hl wae bksey el$
eyf/>
!3/ epk}hykwohl h` ulcaklfeg klkbwe dhbecubes> klg"
!7/ e`coelw ohlozkwohl h` klkbwe dhbecubes ^5;"59T,
DKBGO shuyces kye usukbb chu}beg vowa Wh@ dkss
klkbzeys ieckuse h` wae olaeyelwb }ubseg lkwuye h` wae
sahyw wed}hykb !ls/ bksey shuyces, Wae sdkbb s}kwokb goswyo$
iuwohl h` geshyieg ohls `uywaey `kphys wae use h` Wh@
klkbzeys" fopolf aofa dkss yeshbuwohl !D(GD % ;="===/"
aofa dkss kccuykc !k `ev }}d/" klg bhv BHGs ^53T,
Ahvepey" yecelwb" sodobky }ey`hydklces akpe ieel kbsh
hiwkoleg i usolf ohl$wyk} dkss klkbzeys ^57T" }yhpogolf
kl eksoey kccess wh DS9 klkbses,
7,3, DKBGO klg kwdhs}aeyoc }yessuye DKBGO
BGO klg DKBGO eq}eyodelws kye w}ockbb chlgucweg kw
wae bhv }yessuyes `hulg ol dhsw ohl shuyces !;=6 Whyy/,
Wyelgs ol Klkbwockb Caedoswy" Phb, 3=" Lh, 0" 9=;; Wyelgs
aww}:((vvv,ebsepoey,chd(bhckwe(wykc 10;
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Waos elpoyhldelw os use`ub `hy ohl wykls`ey wh wae dkss
klkbzey klg oluelces wae decaklosd i vaoca ohls
kye `hydeg, Ahvepey" DKBGO s}ecwyk kye kbsh hiwkoleg
kw aofaey }yessuyes" olcbugolf kwdhs}aeyoc }yessuye
!K]/, K }yebodolky ye}hyw }uibosaeg ol 9=== ^55T
sahveg wakw K](DKBGO }yhguceg ohl cuyyelws chd$
}kykibe wh wakw ol ebecwyhs}yk !ESO/ i usolf k lowyhfelbksey h}eykwolf vowa k 9=$Az `ye{uelc klg kl eleyf
gelsow h` 9065 dJ(cd9 }ey }ubse, Dhye yecelwb" K](
DKBGO eq}eyodelws usolf OY shuyces akpe kbsh ieel
}ey`hydeg ^50T,
Ol wae }ksw sepeykb ekys" K](DKBGO aks ieel od}be$
delweg vowa k ludiey h` dkss klkbzeys" olcbugolf Wh@
^55T" ohl wyk} ^56T" klg @huyoey$wykls`hyd ohl ccbhwyhl
yeshlklce !@W$OCY/ ^51T" wknolf kgpklwkfe h` }bkcolf wae
K](DKBGO ohl shuyce eqweylkbb wh wae dkss klkbzey,
Suca k chlfuykwohl os }kywocubkyb suowkibe `hy wae
klkbsos h` kywoswoc klg kycaehbhfockb dkweyokb" ks ow
dknes klkbsos h` 3G hijecws eksoey ^5?T,
K](DKBGO klkbses kye ckyyoeg huw ol k dklleysodobky wh wakw `hy chlpelwohlkb DKBGO" vowa k shbog
dkwyoq ch$cyswkbbozeg vowa wae klkbwe, Waos ye{uoyes wae
skd}be wh ie geswyheg hy dhgoeg, Lepeywaebess" K](
DKBGO s}ecwyk ckl" ol shde olswklces" kbsh ie hiwkoleg
sod}b k`wey ge}hsowolf k dkwyoq bkey hl wae skd}be
suy`kce,
Ohls feleykweg i K](DKBGO akpe ieel sahvl wh ie
bess eleyfewoc wakl wahse }yhguceg i DKBGO klg kye
waus suijecw wh soflocklwb bess dewkswkibe geck gue wh
`ksw waeydkbozkwohl h` wae olweylkb eleyf h` wae ohl kw
kwdhs}aeyoc chlgowohls, Ahvepey" wae yeguceg ohl
wyklsdossohl `yhd wae kwdhs}aeye olwh wae bhv pkcuudh` wae dkss klkbzey fopes bhvey ohl cuyyelws chd}kyeg
wh chlpelwohlkb DKBGO, Ohl$wyklsdossohl e`coelc ge$
}elgs hl ihwa bksey$s}hw gos}bkcedelw yebkwope wh wae
celwykb kqos h` wae dkss$klkbzey olbew ck}obbky klg wae
phbwkfe k}}boeg iewveel wae wkyfew }bkwe klg wae olbew
ck}obbky ^0=T, K soflocklw olcyekse ol ohl wyklsdossohl
os hiwkoleg i kgh}wolf kl k}}yhkca ckbbeg }ubseg g$
lkdoc `hcusolf !]G@/ wakw olphbpes svowcaolf wae ebecwyoc
ebg wh zeyh `hy k wode olweypkb guyolf vaoca ohls k}$
}yhkca wae ck}obbky olbew ^0;T,
S}kwokbb yeshbpeg DS wecalo{ues ikseg hl goyecw BGO
akpe ieel ed}bheg ol wae swug h` kyw klg kycakeh$
bhfockb hijecws solce 9==9 ^09"03T, Ahvepey" ks gos$
cusseg ol }yepohus secwohls" goyecw BGO os hlb e``ecwope ol
wae swug h` k bodoweg yklfe h` dkweyokbs wakw ckl ie
phbkwobozeg" vaobe DKBGO aks eq}klgeg BGO$ikseg DS
dewahgs wh swugoes h` hyfkloc chd}hlelws `yhd vhyns h`
kyw, Eqkd}bes h` wae k}}bockiobow h` DKBGO wh wae klkb$
sos h` }ofdelws ^07T" socckwope hobs ^05T" }yhweolkcehus
iolgeys ^0001T" klg pkylosaes ^0?T akpe ieel ye}hyweg
ol wae boweykwuye, K }yhwehdoc k}}yhkca ikseg hl wae use
h` DKBGO$Wh@ vks kbsh useg wh ogelwo` iohbhfockb skd$
}bes wakw kye dhye wakl 53== ekys hbg" wknel `yhd wae
Wyhbekl dudd" kbsh ckbbeg Ocedkl hy Hewzo ^6=T,
Yecelwb" }hssoiobowoes h``eyeg i K](DKBGO `hy klk$
bzolf kywoswoc dkweyokb goyecwb ol koy akpe ieel ged$
hlswykweg i swugolf wykgowohlkb }kolwolf dkweyokbs"
oyhl$fkbb oln ^6;T klg hyfkloc ges klg }ofdelws useg wh
}yolw ihhns gkweg ;?;;9= ^5?T, Waos bksw swug ge$
loweb gedhlswykweg wae k}}bockiobow h` K](DKBGO wh wae
swug h` klcoelw hijecws" ieckuse wae klkbses veyeckyyoeg huw ol sowu vowa k s}kwokb yeshbuwohl h` kihuw
7== bd, Waos vks kcaoepkibe i }bkcolf ihhns ol k
dhgoeg K](DKBGO shuyce hl kl Q_Z wyklsbkwohl wkibe,
Wae docyhgeswyucwopow h` wae klkbsos vks hiwkoleg i
s}ykolf kihuw =,9 bf(dd9 h` wae dkwyoq !chyyes}hlg$
olf wh kihuw =,1 ldhbe(dd9/ hl k 93$dd9 kyek h`
wae skd}be,
5, Chlcbusohls
S}kwokbb yeshbpeg DS klkbwockb wecalo{ues akpe fyekw
}hwelwokb `hy wae swug h` kyw klg kycakehbhfockb hijecws,
Ol }kywocubky" wae wecalo{ues gescyoieg aeye akpe sepeykb
od}hywklw cakykcweyoswocs:
!;/ ck}kiobowoes `hy s}kwokbb yeshbpeg dubwo$ebedelwkb
klg oshwh}oc klkbsos>
!9/ bhv BHGs klg eqwelgeg boleky yklfes wakw kbbhv
{uklwowkwope klkbsos>
!3/ dolodkb skd}be }ye}kykwohl klg(hy gkdkfe> klg"
!7/ ck}kiobowoes `hy s}kwokbb yeshbpeg klkbsos h` hyfkloc
klg iohdhbecubky chd}hulgs,
Ve akpe fopel s}ecokb delwohl wh yecelw olswyudelwkb
kgpklces wakw kbbhv goyecw" s}kwokbb yeshbpeg DS klkb$
ses h` vhyns h` kyw, Suca `kcobowoes h}el lev }hssoiobowoes`hy chd}beq kywoswoc klg kycakehbhfockb hijecws vael
goyecw DS klkbses h` wae swugoeg hijecw kye chlgucweg kw
K],
Kcnlhvbegfdelws
Ve kcnlhvbegfe su}}hyw `yhd DOUY !@OYI
YIYL=6IDCW/, Ve vhubg bone wh wakln G, Klfbhs" G,
Fkyhzzh klg kl klhldhus ye`eyee `hy waeoy chlswyucwope
chddelws klg suffeswohls,
Ye`eyelces^;T E, Coboieywh" F, S}hwh !Egowhys/" Dhgeyl Klkbwockb Dewahgs ol Kyw
klg Kycakehbhf" Jhal Vobe & Shls Olc," Lev _hyn" USK" 9===,
^9T F, S}hwh" K, Whyyoso" K, Chlwolh" Caed, Shc, Yep, 9? !9===/ 79?,
^3T F, S}hwh" Kcc, Caed, Yes, 35 !9==9/ 059,
^7T ], Pklgelkieebe" A,F,D, Egvkygs" B, Dhels" Caed, Yep, ;=6
!9==6/ 065,
^5T S, ]ykwo" E, Jhse}a" F, Scouwwh" Y, Dkzzeh" Kcc, Caed, Yes, 73
!9=;=/ 6?9,
^0T F, Iuzkloca" ], Vhiykuscaen" C, Swyebo" K, Dkynhvocz" G,
Vefyzlen" E, Caolek$Cklh" S, Ikd`hyg" S}ecwyhcaod, Kcwk" ]kyw
I 09 !9==6/ ;959,
^6T N, Jklssels" J, Gon" D, Chwwe" J, Susolo" Kcc, Caed, Yes, 73 !9=;=/
1;7,
Wyelgs Wyelgs ol Klkbwockb Caedoswy" Phb, 3=" Lh, 0" 9=;;
109 aww}:((vvv,ebsepoey,chd(bhckwe(wykc
8/2/2019 Spoto & Grasso. Spatially resolved mass spectrometry in the study of art and archaeological objects.
8/8
^1T B, ge Pofueyoe" ], Vkbwey" E, Bkpkb" I, Dhwwol" P,K, Shbem" Klfev,
Caed," Olw, Eg, Elfb, 7? !9=;=/ 0;95,
^?T ], Ledes" K,S, Vhhgs" K, Peywes" Klkb, Caed, 19 !9=;=/ ?19,
^;=T G, Fyhbodulg" D, Sell" D, Wyhwwdkll" D, Jklhusca" O, Ihlahuye"
K,D, Scaeogeffey" D, Dkycus" S}ecwyhcaod, Kcwk" ]kyw I 5?I
!9==7/ ;096,
^;;T W, Cecakn" D, Abhzen" B, Dusoben" W, Wyhjen" Lucb" Olswyud,
Dewahgs ]as, Yes," Secw, I 903 !9==6/ 57,
^;9T K,G, DcLkufaw" K, Vobnolshl !Chd}obeys/" OU]KC Chd}elgoud
h` Caedockb Weydolhbhf" 9lg Egowohl !Fhbg Ihhn/" Ibkcnvebb
Scoelwoc ]uibockwohls" Hq`hyg" UN" ;??6 ^QDB hl$bole chyyecweg
peysohl ^aww}:((fhbgihhn,ou}kc,hyf !9==0$//" cyekweg i D, Loc" J,
Joykw" I, Nhskwk" u}gkwes chd}obeg i K, Jelnols" OSIL =$
?06155=$?$1 !GHO:;=,;35;(fhbgihhn /T,
^;3T @, Pklakecne" B, Ikbckel" G, Dkbolhpsn" J, Klkb, Kw, S}ecwyhd,
97 !9==?/ 103,
^;7T B, Gussuioeuq" ], Yhieywsakv" D,G, Fbkschcn" Olw, J, Dkss
S}ecwyhd, 917 !9==?/ ;59,
^;5T D,], Chbhdiolo" @, Dhguflh !Egowhys/" Hyfkloc Dkss S}ecwyhdewy
ol Kyw klg Kycakehbhf" Jhal Vobe & Shls Olc," Lev _hyn" USK"
9==?,
^;0T Z, Fh``ey" Kycakehbhfockb Caedoswy" Jhal Vobe & Shls Olc," Lev
_hyn" USK" 9==6,
^;6T D, Yefeyw" Dkss S}ecwyhd, Yep, 3= !9=;;/ ;66,
^;1T K,N, Huwykd" L,K, Sweky" Y, Ielgye" S, Hbsel" K, Nks}kyhp" P,
Zkoieyw" L, Wahy}e" Y,], Epeysaeg" Scoelce !Vksaolfwhl" GC/ 393
!9==?/ ;339,
^;?T J, ]eyez$Kyklwefuo" F, Ce}yok" E, Yoiecaolo" O, Gefklh" D,],
Chbhdiolo" J, ]kz$]eykbwk" E, Hywoz$]kbhdky" Wyelgs Klkb, Caed,
91 !9==?/ ;=;?,
^9=T K, Klgyehwwo" O, Ihlkguce" D,], Chbhdiolo" F, Fkuwoey" @,
Dhguflh" E, Yoiecaolo" Klkb, Caed, 61 !9==0/ 77?=,
^9;T H,@, pkl gel Iyoln" E,S,I, @eyyeoyk" J, pkl gey Ahysw" J,J, Ihhl" Olw,
J, Dkss S}ecwyhd, 917 !9==?/ ;9,
^99T G,S, Dc]akob" J, Dkwey, Sco, 7; !9==0/ 163,
^93T D, Vesw" K,W, Ebbos" ],J, ]hwws" C, Swyebo" C, Pklahh`" G, Vefyzlen"
], Vhiykuscaen" J, Klkb, Kw, S}ecwyhd, 97 !9==?/ ;91?,
^97T W, Ckbbofkyh" J,$C, Gykl" J, Skbhdhl" Chd}y, Klkb, Caed, 79
!9==7/ 996,
^95T K, Foknhudkno" N, Debessklkno" G, Klfbhs" Klkb, Iohklkb, Caed,
316 !9==6/ 67?,
^90T G, Deluw" ], @ocaew" J, Bkchuy" K, Yophkbbkl" ], Dkucaoel" K}}b,
H}w, 79 !9==3/ 0=03,
^96T K, Fullkysshl" @, Nhbbdey" S, Shal" @, Ahhn" ], Sjhpkbb" Klkb,
Caed, 19 !9=;=/ 9790,
^91T ], Caknykihyw" Lucb, Olswyud, Dewahgs ]as, Yes," ]kyw I 900
!9==1/ ;151,
^9?T G,F, ]k}kzhfbhu" P, ]k}kgknos" G, Klfbhs" J, Klkb, Kw, S}ecwyhd,
;? !9==7/ 713,
^3=T F, S}hwh" Waeydhcaod, Kcwk 305 !9===/ ;56,
^3;T K, Kgyokels" D,F, Ghvseww" K}}b, Suy`, Sco, 959 !9==0/ 6=?0,
^39T E, Gky{ue$Ceyewwo" D, Kuchuwuyoey" ol: N, Jklssels" Y, Pkl Fyoenel
!Egowhys/" Lhl$geswyucwope Docyhklkbsos h` Cubwuykb Aeyowkfe
Dkweyokbs" Ebsepoey Scoelce I,P" Kdsweygkd" Wae Lewaeybklgs"
9==7" }, 3?6,
^33T _, _u$Saelf" C, Ih$Julf" B, _hlf$Caoel" K}}b, Suy , Sco, 955
!9==1/ ;537,
^37T F,C, Kbbel" O,W, Iyhvl" E, Coboieywh" F, S}hwh" Euy, Dkss S}ecwy, ;
!;??5/ 7?3,
^35T F, Nyk w" S, @befe" @, Yeo``" A,D, Hywley" Docyhcaod, Kcwk ;75
!9===/ 16,
^30T D, Fhhgvk" Scoelce !Vksaolfwhl" GC/ 930 !;?16/ ?96,
^36T @,J,D, Yuwwel" G, Iyoffs" J, Aelgeyshl" D,J, Yhe" Kycakehdewy 5;
!9==?/ ?00,
^31T D, Debcaey" D, Scayeoley" J, Lhl$cysw, Shbogs 359 !9==0/ 301,
^3?T O, Boyowzos" L, Bksnkyos" Lucb, Olswyud, Dewahgs ]as, Yes," ]kyw I
906 !9==?/ ;77,
^7=T N, Neule" @, Ahhfbklg" J,J, Ihhl" G, ]effoe" C, Aoffoww" Olw, J, Dkss
S}ecwyhd, 917 !9==?/ 99,
^7;T Y, Akd" B, Pkecn" @, Kgkds" K, Kgyokels" Klkb, Iohklkb, Caed,
313 !9==5/ ??;,
^79T Y, Pkl Akd" B, Pkl Pkecn" @, Kgkds" K, Kgyokels" Klkb, Caed,
60 !9==7/ 90=?,
^73T N, Neule" J,J, Ihhl" Klkb, Caed, 60 !9==7/ ;367,
^77T D,K, ]hswaudus" ],F, Noswedkney" A,B,C, Deuzebkky" Klkb, Caed,
5= !;?61/ ?15,
^75T G,], Noyi" L, Naklgenky" N, Suwaeybklg" I,K, ]yoce" Olw, J, Dkss
S}ecwyhd, 917 !9==?/ ;;5,
^70T I,J, Fkyyoshl" Z, ]hswkvk" Dkss S}ecwyhd, Yep, 96 !9==1/
91?,
^76T D, Yesklh" E, Fkycok$Yuoz" @, Pklakecne" Dkss S}ecwyhd, Yep, 9?
!9=;=/ 55,
^71T K, @yegeyoc" Klkb, Iohklkb, Caed, 31? !9==6/ ;31;,
^7?T D, Nkyks" G, Ikcadkll" U, Ikay" @, Aobbelnkd}" Olw, J, Dkss
S}ecwyhd, Ohl, ]yhc, 61 !;?16/ 53,
^5=T J, Nkd}deoey" N, Gyeoseveyg" D, Scauyelieyf" N, Swyu}kw" Olw, J,
Dkss S}ecwyhd, ;0?(;6= !;??6/ 3;,
^5;T N, Gyeoseveyg" Caed, Yep, ;=3 !9==3/ 3?5,
^59T N, Gyeoseveyg" S, Ieynelnkd}" K, Beosley" K, Yhablf" C, Delzeb"
Olw, J, Dkss S}ecwyhd, 990 !9==3/ ;1?,
^53T Y,G, Egdhlgshl" G, Yussebb" J, Kd, Shc, Dkss S}ecwyhd, 6 !;??0/
??5,
^57T N, Swyu}kw" P, Nhpwhul" A, Iuo" Y, Poley" F, Swk``hyg" S, Ahylolf" J,
Kd, Shc, Dkss S}ecwyhd, 9= !9==?/ ;75;,
^55T P,P, Bkonh" D,K, Ikbgvol" K,B, Iuybolfkde" Klkb, Caed, 69
!9===/ 059,
^50T P,P, Bkonh" L,O, Wkyklelnh" P,G, Ieynhuw" D,K, _knsaol" C,Y,
]ykskg" A,S, Bee" P,D, Ghyhsaelnh" J, Kd, Shc, Dkss S}ecwyhd, 3
!9==9/ 357,
^56T F, Fykssh" E, Yozzkyebbo" F, S}hwh" J, Dkss S}ecwyhd, 79 !9==6/
;5?=,
^51T N,K, Nebbeysieyfey" ],P, Wkl" P,P, Bkonh" P,D, Ghyhsaelnh" G,
@kiyos" Klkb, Caed, 60 !9==7/ 3?3=,
^5?T B, Fouykwh" K, Cklguyk" F, Fykssh" F, S}hwh" K}}b, ]as, K ?6
!9==?/ 903,
^0=T P,G, Ieynhuw" S,O, Nyucanhp" P,D, Ghyhsaelnh" Yk}og Chddul,
Dkss S}ecwyhd, 9; !9==6/ 9=70,
^0;T ],P, Wkl" P,P, Bkonh" P,D, Ghyhsaelnh" Klkb, Caed, 60 !9==7/
9709,
^09T J,J, Ihhl" W, Bekyley" J, Klkb, K}}b, ]yhbsos 07 !9==9/ 396,
^03T G,D, Fyod" J, Kbboshl" Kycakehdewy 70 !9==7/ 913,
^07T D,S, Dkoey" S,G, ]kyeyk" K,D, Sebges" Olw, J, Dkss S}ecwyhd, 939
!9==7/ 995,
^05T G,J, Pkl Gel Ieyf" L,G, Peydosw" B, Ckybbe" D, Ahbck}en" J,J,
Ihhl" J, Se}, Sco, 91 !9==7/ ;1;,
^00T S, Nucnhpk" D, Cyahpk" B, Pklnhpk" K, Alozgk" Y, Alen" D,
Nhgocen" Olw, J, Dkss S}ecwyhd, 917 !9==?/ 79,
^06T C, Whnkysno" E, Dkywol" C, Yhbklgh" C, Cyel$Hbope" Klkb, Caed, 61
!9==0/ ;7?7,
^01T S, Nucnhpk" Y, Alen" D, Nhgocen" Klkb, Iohklkb, Caed, 311
!9==6/ 9=;,
^0?T S, Zudiu ab" Y, Nlhcaelduss" S, Vu b`eyw" @, Guihos" D,J, Gkbe" Y,
Zelhio" Klkb, Caed, 6= !;??1/ 6=6,
^6=T N, Ahbbedeey" V, Kbwdeey" E, Aeolzbe" C, ]owyk" Yk}og Chdd,
Dkss S}ecwyhd, 99 !9==1/ 965;,
^6;T Y, GKfkwk" F, Fykssh" S, ]kybkwh" S, Sodhle" F, S}hwh" K}}b, ]as,
K: Dkwey, Sco, ]yhcess, 1? !9==6/ ?;,
Wyelgs ol Klkbwockb Caedoswy" Phb, 3=" Lh, 0" 9=;; Wyelgs
aww}:((vvv,ebsepoey,chd(bhckwe(wykc 103
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