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Source: Stewart et al., 2001
Strontium vs. Calcium
• Both are alkaline earth elements with +2 valence charge
• Strontium – Atomic number = 38– Ionic Radius = 1.18 angstroms
• Calcium– Atomic number = 20– Ionic Radius = 1.00 angstroms
Source: Kennedy et al., 2002
Source: Capo et al., 1998
Source: Capo et al., 1998
Strontium Isotope System
• Indicator of both age and geochemical origin– Older rocks with same initial Rb/Sr will have
higher 87Sr/86Sr than younger ones.– Rocks of a given age composed of different
minerals will show differentiation in strontium ratios
– The combination of these factors allows strontium to be used a tracer of cation source
Source: Capo et al., 1998
Strontium as a Tracer of Soil Cation Source: Weathering vs. Atmospheric Deposition
• Mass Balance – Two Member Mixing
• Must have sufficient difference between the two end members
• Must assume steady-state weathering or use more complex models to simulate changes in end members
Source: Bullen et al., 1997
Source: White et al., 1999
Source: Blum et al., 2002
Source: Kennedy et al., 2002
Figure 2: Location of proposed field sites in the San Juan Mountains in relation to the western US deserts.
Field Sites
87/86Sr 143/144Nd εNd
Surface rocks 0.707397 (0.000013) 0.512216 -8.23
Dust Events
April 1, 2005 0.720471 (0.000013) 0.512089 -10.71
April 4, 2005 0.716402 (0.000012) 0.512084 -10.81
April 8, 2005 0.714878 (0.000009) 0.512104 -10.42
May 9, 2005 0.713525 (0.000007) 0.512103 -10.44
Source: Chadwick et al., 1999
Source: Stewart et al., 2001