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Soils of Molokai Jonathan Deenik Assistant Specialist, Soil Fertility Department of Tropical Plant and Soil Sciences Fertility and Crop Nutrition

Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

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Page 1: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Soils of Molokai

Jonathan DeenikAssistant Specialist, Soil Fertility

Department of Tropical Plant and Soil Sciences

Fertility and Crop Nutrition

Page 2: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Outline• Importance of Soils• Soils of Molokai• Fertility Status• Management Strategies

Page 3: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

5 Functions of Soil

Medium forPlant growth

Recyclingsystem

Habitat forSoil organismsWater supply

and purification

Engineering Medium

Page 4: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Soil Plant Relationships

Havlin et al., 2005. Soil Fertility and Fertilizers

Page 5: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Idealized Soil Composition

25% H2O

25% Air

45% Mineral

5% Organic Matter

50% Solids 50% Pores

Page 6: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Fundamental Principles

Cation ExchangeCapacity

Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+

Brady & Weil, 2004. Elements of the Nature and Properties of Soils

Page 7: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Soil pH and Nutrient Availability

Soil pH controls nutrient solubilityIdeal range 6.0-6.5As pH drops below 5.0 Al3+ can become toxicManganese toxicity common in soils with pH <5.5

Brady & Weil, 2004. Elements of the Nature and Properties of Soils

Page 8: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Solid Component

Clays

KaoliniteNutrient poor clay

Properties:

• Non-expanding• pH dependent charge• Low Cation Exchange Capacity• Exists in weathered environments• Most common clay mineral in Molokai soils

http://soil.gsfc.nasa.gov/forengeo/thnsec.htm

Page 9: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Clays

MontmorilloniteNutrient rich clay

Properties:

• Expanding• High CEC• Sticky• Exists in less weatheredenvironments

Solid Component

http://webmineral.com/specimens/picshow.php?id=1285

Page 10: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Organic Matter

Humus

http://www.sct.embrapa.br/diacampo/2004/releases.htm

Page 11: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Importance of Organic Matter in Soils

Physical- Improves aggregation (glue)- Improves water holding capacity (surface area)

Chemical- Increases nutrient availability (N cycling, P and

micronutrient solubility)- Increases CEC (200 cmolc kg-1)- Buffers the soil against pH changes

Biological- Increases microbial diversity- Assists in pathogen suppression

Page 12: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Know Your Soil!

• Water storage and movement

• Nutrient availability• Trafficability

Soil Controls:

Page 13: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Hawaii`s Diverse Soils

1. Processes:Physical weatheringChemical weathering

2. Factors

Page 14: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Soil Forming Factors

Parent rockAgeClimate (rainfall, temperature)Biota (vegetation, micro-organisms)Topography (drainage)

Page 15: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Geography of Molokai≈1,200 ft ≈4,500 ft

15” 30” 80” >100”

Page 16: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Soils of Molokai

Kalaupapa/Oli

Lahaina/Molokai

Kalae

Hoolehua

Pamoa

Page 17: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Important Soils of Molokai

Lahaina Series:• Acid pH ≈5.5• Sum of bases = 7.1 cmolc kg-1

• Low organic matter• If pH <5.0 Mn toxicity likely

Molokai Series:• Slightly acid to neutral• Sum of bases = 16.4 cmolc kg-1

• Low organic matter• Good physical properties

Page 18: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Important Soils of Molokai

Page 19: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Important Soils of MolokaiHoolehua Series:• Extremely acid pH 3.9• Sum of bases = 2.6 cmolc kg-1

• Low organic matter• Al and Mn toxicity likely

Page 20: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Important Soils of Molokai

Page 21: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Important Soils of MolokaiKalae Series:• Strongly acid pH ≈ 5.0• Sum of bases = 1.3 cmolc kg-1

• Moderate organic matter• Al toxicity likely

Similar soils:AlaeloaHalawaOlelo

Page 22: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Important Soils of Molokai

Page 23: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Important Soils of MolokaiPamoa Series:• Neutral pH ≈ 7.0• Sum of bases = 18.5 cmolc kg-1

• Moderate organic matter• Fertile soil

Similar soils:HaleiwaPulehuWaikapu

Page 24: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Important Soils of Molokai

Page 25: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Important Soils of MolokaiOli Series:• Acid pH ≈ 5.5• Sum of bases = 27.1 cmolc kg-1

• High organic matter• Fertile soil

Similar soils:Kalaupapa

Page 26: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Important Soils of Molokai

Page 27: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Important Soils of MolokaiJaucus Series:• Sandy• Neutral pH• Low organic matter• Rapid drainage• Infertile soil

Similar soils:Mala

Page 28: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Soil AcidityNatural Sources of Acidity:

Precipitation and cationleaching Carbonic acid and organic acidsOrganic matterCation uptakeDeprotonation of pH-dependent charge

Human Induced Acidity:

Acid rainUreaAmmonium fertilizersMono and diammonium phosphateElemental S

Page 29: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Adverse Effects of Soil Acidity

Aluminum toxicityManganese toxicityNutrient deficienciesDecreased microbial activity

Page 30: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Manganese

A mineral in basalt - MnO2, Mn2O3, Mn3O4Exists as Mn2+, Mn3+, Mn4+

Mn2+ is an essential plant nutrient, but at high concentrations it becomes toxicMn2+ concentration depends on:• Soil pH - high Mn in acid soils • O2 availability - Mn solubility increases in flooded

soils• organic matter - Mn solubility increases with OM

Page 31: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Critical level

Mn solubility and soil pH

Source: Hue et al., 1998

Page 32: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Mn Toxicity Increases with Organic Inputs

Source: Hue et al., 2001

Page 33: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Molokai Soils with Potential for Mn Toxicity

% MnO20.31.49

0.81

Page 34: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Phosphorus Deficient in Acid Soils

Page 35: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Factors Affecting P Fixation

Soil type

Andisol>Ultisol≈Oxisol>Inceptisol>Mollisol>EntisolOli Kalae Hoolehua Pamoa JaucusKalaupapa Alaeloa Pulehu Mala

HalawaLahainaMolokai

Organic matter- OM imparts negative charge to surfaces inhibiting reaction between phosphate and oxide surface

Page 36: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Correcting Soil Acidity with Lime

1. To raise pH- Reduces P fixation- Reduces Al & Mn solubility- Increases N, S, B, Cu and Mo

availability2. To supply Ca

Page 37: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Liming

1.5 T/a

4 T/a 1.5 T/a

Page 38: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Summary

Soils give us lifeSoils vary on the landscapeSome soils are inherently more fertile than othersSome Molokai soils have high reserves on MnIf we know our soils we can manage them well

Page 39: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Resources

BooksBrady, N.C. and R.R. Weil. 2004. Elements of the Nature and Properties of Soils. Pearson Education, Inc., Upper Saddle River, NJ

Page 40: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Resources

Webhttp://ortho.ftw.nrcs.usda.gov/cgi-bin/osd/osdnamequery.cgi

Page 41: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

Resources

Page 42: Soils of Molokai - University of Hawaii · Fundamental Principles Cation ExchangeCapacity Negatively charged sites that adsorb cations: Ca2+, Mg2+, K+, NH4+ Brady & Weil, 2004. Elements

ResourcesWeb

http://ssldata.nrcs.usda.gov/querypage.asp?chksa=1&ac=244&as=3962#sitevar