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insider tells me that some 10 years ago Unilever and certain other companies considered launching superconcentrated liquid laundry detergents based on phosphate-built, structured surfactant systems. Unilever invested significantly in R&D, for example, developing deflocculant polymer technology that enabled the ‘pourability’ of the formulation to be maintained while doubling the surfactant and builder concentration. Presumably, the market was tested and found to be unreceptive as certainly no such product made it into the stores. It was an idea before its time! What’s different now? Then, as now, consumer convenience would have been a significant selling point – the concentrated products are much lighter to lift and carry and take up less room in shopping bags and storage cupboards. However, back then big dosing balls were the norm for measuring out liquid detergents and perhaps customers felt in some way ‘conned’ by the idea of a half- size dose? Now, in the UK at least, we’ve become accustomed to small doses with liquitabs and compact tablets. Of course, a decade back the systems under consideration were phosphate built, unlike the new generation of 2x concentrates, and perhaps the industry had already realized such products didn’t have a long-term future? The concentrated formulations represent a 60% reduction in water usage in their production and a >40% reduction in petrochemical-based plastic packaging per bottle. Smaller containers also mean there is less packaging to recycle or dispose of and less fuel is needed per bottle to ship these products, cutting transport costs and helping to control greenhouse gas and other emissions. These arguments were equally valid 10 years ago but they have added resonance now on top of recent soaring oil prices and the increased level of environmental concern among Western consumers. The latter factor has also contributed to a significant recent shift in US consumer preferences towards high- efficiency, front-loading washing machines, which are much better suited to low-dose, high-concentration laundry products. Sustainability issues come to the fore once again. Well, the proof of the liquid is in the laundry, so I’ll just go and put a wash on. . . Caroline Edser RAW MATERIALS Linear alkylbenzene BASF to sell Wibarco LAB subsidiary to Hansa BASF AG has signed an agreement to sell its detergent ingredients subsidiary Chemische Fabrik Wibarco GmbH to Swiss company Hansa Chemie International AG, for an undisclosed sum. The deal is expected to close in Jul 2007. Wibarco, located in Ibbenburen, northern Germany, mainly produces detergent raw material linear alkylbenzene (LAB). Hansa will take over the Ibbenburen site, which has a workforce of around 80 employees. The deal marks BASF’s withdrawal from the LAB sector, which it no longer considers of strategic importance. However, Wibarco will be part of Hansa’s core activities and will allow it to establish a presence in the LAB market. Hansa has undertaken to invest in building a sulfonation unit to produce alkylbenzene sulfonates at the Ibbenburen site. Press release from: BASF AG, Germany. Website: http://www.basf.com (16 Apr 2007) & ICIS Chemical Business Americas, 23 Apr 2007, (Website: http://www.icbamericas.com) & Chimie Pharma Hebdo, 23 Apr 2007, (379), 10 (Website: http://www.france-chimie.com) (in French) Firms get set to bid for Nizhnekamsk contract Invitations to bid for the refining and petrochemicals complex of CJSC Nizhnekamsk Refinery in Nizhnekamsk, Tartarstan, Russia, are poised to be set out. Investment for the project is likely to reach several billion dollars. It will comprise manufacturing units for polypropylene (PP), polyethylene terephthalate (PET) and linear alkylbenzene (LAB) [see Focus on Surfactants, Oct 2006]. Phase 1 of the project may likely begin in 2010. Basell, Advansa/ Chemtex and Advansa will serve as technology licensors for the 200,000 tonne/y PP plant; the 250,000 tonne/y PET plant; and the PTA unit, respectively. Technology for the 80,000 tonne/y LAB plant will come from UOP. ICIS Chemical Business, 9 Apr 2007, (Website: http://icischemicalbusiness.com) Oleochemicals Snia snaps up Undesa Oleochemicals producer Undesa has been acquired by Italian company Snia for 24.5 M. Completion is due on 31 May 2007. The deal, partly financed by a 11 M midterm loan, includes Undesa Italia and Union Derivan. Undesa had sales of 80 M in 2006 and has 200 employees. Undesa Italia manufactures fatty acids and glycerine in Bologna, Italy, and Union Derivan manufactures esters, esterquats, stabilizers and stearates at plants in Barcelona and Zaragoza, Spain. ICIS Chemical Business Americas, 23 Apr 2007, (Website: http://www.icbamericas.com) PPB Group shareholders give nod for merger The shareholders of PPB Group Bhd have given their assent for the merger of the Singapore-based Wilmar International Ltd and PPB’s subsidiary, PPB Oil Palms Bhd. The assent also signals the merger of the group’s edible oils, speciality fats, oleochemicals and trading businesses under the umbrella of PGEO Group Sdn Bhd and Kuok Oils & Grains Pte Ltd. The process of the merger and the de-listing from Bursa Malaysia are likely to be completed by 2Q 2007. As a result of the deal, PPB Group is all set to notch up a huge profit margin of about Ringgit 6.1 bn. As part of the transaction, which is to take place by means of a share exchange, PPB Group will be in receipt of 1.16 bn shares in Wilmar subsequent to the sale of its 55.6% stake in PPB Oil Palms, 65.8% stake in PGEO Group and 28% of Kuok Oils & Grains. PPB Group had originally expected that the proposed sale of assets would result in a gain of about Ringgit 3.22 bn when 2 JUNE 2007 FOCUS ON SURFACTANTS

Snia snaps up Undesa

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insider tells me that some 10 yearsago Unilever and certain othercompanies considered launchingsuperconcentrated liquid laundrydetergents based on phosphate-built,structured surfactant systems.Unilever invested significantly in R&D,for example, developing deflocculantpolymer technology that enabled the‘pourability’ of the formulation to bemaintained while doubling thesurfactant and builder concentration.Presumably, the market was testedand found to be unreceptive ascertainly no such product made it intothe stores. It was an idea before itstime!

What’s different now? Then, asnow, consumer convenience wouldhave been a significant selling point –the concentrated products are muchlighter to lift and carry and take upless room in shopping bags andstorage cupboards. However, backthen big dosing balls were the normfor measuring out liquid detergentsand perhaps customers felt in someway ‘conned’ by the idea of a half-size dose? Now, in the UK at least,we’ve become accustomed to smalldoses with liquitabs and compacttablets. Of course, a decade back thesystems under consideration werephosphate built, unlike the newgeneration of 2x concentrates, andperhaps the industry had alreadyrealized such products didn’t have along-term future?

The concentrated formulationsrepresent a 60% reduction in waterusage in their production and a >40%reduction in petrochemical-basedplastic packaging per bottle. Smallercontainers also mean there is lesspackaging to recycle or dispose ofand less fuel is needed per bottle toship these products, cutting transportcosts and helping to controlgreenhouse gas and other emissions.These arguments were equally valid10 years ago but they have addedresonance now on top of recentsoaring oil prices and the increasedlevel of environmental concernamong Western consumers. Thelatter factor has also contributed to asignificant recent shift in USconsumer preferences towards high-efficiency, front-loading washingmachines, which are much bettersuited to low-dose, high-concentrationlaundry products. Sustainabilityissues come to the fore once again.

Well, the proof of the liquid is in thelaundry, so I’ll just go and put a washon. . .

Caroline Edser

RAWMATERIALS

Linear alkylbenzene

BASF to sell Wibarco LAB subsidiary toHansa

BASF AG has signed an agreement tosell its detergent ingredients subsidiaryChemische Fabrik Wibarco GmbH toSwiss company Hansa ChemieInternational AG, for an undisclosedsum. The deal is expected to close inJul 2007. Wibarco, located inIbbenburen, northern Germany, mainlyproduces detergent raw material linearalkylbenzene (LAB). Hansa will takeover the Ibbenburen site, which has aworkforce of around 80 employees.The deal marks BASF’s withdrawalfrom the LAB sector, which it no longerconsiders of strategic importance.However, Wibarco will be part ofHansa’s core activities and will allow itto establish a presence in the LABmarket. Hansa has undertaken toinvest in building a sulfonation unit toproduce alkylbenzene sulfonates at theIbbenburen site.

Press release from: BASF AG, Germany. Website:http://www.basf.com (16 Apr 2007) & ICIS ChemicalBusiness Americas, 23 Apr 2007, (Website:http://www.icbamericas.com) & Chimie PharmaHebdo, 23 Apr 2007, (379), 10 (Website:http://www.france-chimie.com) (in French)

Firms get set to bid for Nizhnekamskcontract

Invitations to bid for the refining andpetrochemicals complex of CJSCNizhnekamsk Refinery inNizhnekamsk, Tartarstan, Russia, arepoised to be set out. Investment forthe project is likely to reach severalbillion dollars. It will comprisemanufacturing units for polypropylene(PP), polyethylene terephthalate(PET) and linear alkylbenzene (LAB)[see Focus on Surfactants, Oct 2006].Phase 1 of the project may likelybegin in 2010. Basell, Advansa/Chemtex and Advansa will serve as

technology licensors for the 200,000tonne/y PP plant; the 250,000 tonne/yPET plant; and the PTA unit,respectively. Technology for the80,000 tonne/y LAB plant will comefrom UOP.

ICIS Chemical Business, 9 Apr 2007, (Website:http://icischemicalbusiness.com)

Oleochemicals

Snia snaps up Undesa

Oleochemicals producer Undesa hasbeen acquired by Italian companySnia for €24.5 M. Completion is dueon 31 May 2007. The deal, partlyfinanced by a €11 M midterm loan,includes Undesa Italia and UnionDerivan. Undesa had sales of €80 Min 2006 and has 200 employees.Undesa Italia manufactures fattyacids and glycerine in Bologna, Italy,and Union Derivan manufacturesesters, esterquats, stabilizers andstearates at plants in Barcelona andZaragoza, Spain.

ICIS Chemical Business Americas, 23 Apr 2007,(Website: http://www.icbamericas.com)

PPB Group shareholders give nod formerger

The shareholders of PPB Group Bhdhave given their assent for the mergerof the Singapore-based WilmarInternational Ltd and PPB’ssubsidiary, PPB Oil Palms Bhd. Theassent also signals the merger of thegroup’s edible oils, speciality fats,oleochemicals and tradingbusinesses under the umbrella ofPGEO Group Sdn Bhd and Kuok Oils& Grains Pte Ltd. The process of themerger and the de-listing from BursaMalaysia are likely to be completedby 2Q 2007.

As a result of the deal, PPB Groupis all set to notch up a huge profitmargin of about Ringgit 6.1 bn. Aspart of the transaction, which is totake place by means of a shareexchange, PPB Group will be inreceipt of 1.16 bn shares in Wilmarsubsequent to the sale of its 55.6%stake in PPB Oil Palms, 65.8% stakein PGEO Group and 28% of KuokOils & Grains. PPB Group hadoriginally expected that the proposedsale of assets would result in a gainof about Ringgit 3.22 bn when

2 JUNE 2007

F O C U S O N S U R F A C T A N T S