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    Foundations of MaterialsScience

    andEngineering

    Fourth Edition

    William F. Smith

    Javad Hashemi

    PowerPoint Lecture Slides

    for

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    CHAPTER

    1Introduction to

    Materials Science

    and

    Engineering

    1-1

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    The Mars Rovers - Spirit and Opportunity

    Spirit and Opportunity are made up of materials such as

    * Metals * Ceramics * Composites * Polymers * Semiconductors

    www.nasa.gov

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    What are Materials?

    Materials may be defined as substance of

    which something is composed or made.

    We obtain materials from earth crust and

    atmosphere.

    Examples :- Silicon and Iron constitute 27.72

    and 5.00 percentage of weight of

    earths crust respectively.

    Nitrogen and Oxygen constitute78.08 and 20.95 percentage of dry

    air by volume respectively.

    1-2

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    Why the Study of Materials is Important?

    Production and processing of materials constitute alarge part of our economy.

    Engineers choose materials to suite design.

    New materials might be needed for some newapplications.

    Example:- High temperature resistant materials.

    Space station and Mars Rovers should sustainconditions in space.

    * High speed, low temperature, strong butlight.

    Modification of properties might be needed for someapplications.

    Example :- Heat treatment to modify properties.

    1-3

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    Materials Science and Engineering

    Materials science deals with basic knowledge

    about the internal structure, properties andprocessing of materials.

    Materials engineering deals with the application

    of knowledge gained by materials science to

    convert materials to products.

    Resultant

    Knowledgeof Structure and

    Properties

    Applied

    Knowledgeof Materials

    Materials ScienceMaterials Science and

    Engineering Materials Engineering

    Basic

    Knowledgeof

    Materials

    1-4

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    Types of Materials

    Metallic Materials

    Composed of one or more metallic elements.

    Example:- Iron, Copper, Aluminum.

    Metallic element may combine with

    nonmetallic elements.

    Example:- Silicon Carbide, Iron Oxide.

    Inorganic and have crystalline structure.

    Good thermal and electric conductors.

    Metals and Alloys

    Ferrous

    Eg: Steel,

    Cast Iron

    Nonferrous

    Eg:Copper

    Aluminum

    1-5

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    Types of Materials

    Polymeric (Plastic) Materials Organic giant molecules and mostly

    noncrystalline.

    Some are mixtures of crystalline andnoncrystalline regions.

    Poor conductors of electricity and hence

    used as insulators. Strength and ductility vary greatly.

    Low densities and decompositiontemperatures.

    Examples :- Poly vinyl Chloride (PVC),Polyester.

    Applications:- Appliances, DVDs, Fabricsetc.

    1-6

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    Types of Materials

    Ceramic Materials Metallic and nonmetallic elements are chemically

    bonded together.

    Inorganic but can be either crystalline, noncrystalline

    or mixture of both.

    High hardness, strength and wear resistance.

    Very good insulator. Hence used for furnace lining for

    heat treating and melting metals.

    Also used in space shuttle to insulate it during exit and

    reentry into atmosphere.

    Other applications : Abrasives, construction materials,utensils etc.

    Example:- Porcelain, Glass, Silicon nitride.

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    Types of Materials

    Composite Materials Mixture of two or more materials.

    Consists of a filler material and a binding material.

    Materials only bond, will not dissolve in each other.

    Mainly two types :-

    o Fibrous: Fibers in a matrix

    o Particulate: Particles in a matrix

    o Matrix can be metals, ceramic or polymer

    Examples :-

    Fiber Glass ( Reinforcing material in a polyesteror epoxy matrix)

    Concrete ( Gravels or steel rods reinforced incement and sand)

    Applications:- Aircraft wings and engine, construction.

    1-8

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    Types of Materials

    Electronic Materials

    Not Major by volume but veryimportant.

    Silicon is a common electronic

    material.

    Its electrical characteristics arechanged by adding impurities.

    Examples:- Silicon chips, transistorsApplications :- Computers, Integrated

    Circuits, Satellites etc.

    1-9

    C i h Th M G Hill C i I P i i i d f d i di l

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    Competition Among Materials

    Materials compete with each

    other to exist in new market

    Over a period of time usage

    of different materials changes

    depending on cost andperformance.

    New, cheaper or better

    materials replace the oldmaterials when there is a

    breakthrough in technology

    Example:-

    0

    200

    400

    600

    800

    1000

    1200

    1400

    1600

    lb/C

    ar

    1985 1992 1997

    Model Year

    Aluminum

    Iron

    Plastic

    Steel

    Predictions and use of

    materials in US automobiles.

    Figure 1.14

    After J.G. Simon, Adv. Mat. & Proc., 133:63(1988) and new data1-10

    C i ht Th M G Hill C i I P i i i d f d ti di l

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    Future Trends

    Metallic Materials

    Production follows US economy closely.

    Alloys may be improved by better chemistry andprocess control.

    New aerospace alloys being constantly

    researched.o Aim: To improve temperature and corrosion

    resistance.

    o Example: Nickel based high temperature superalloys.

    New processing techniques are investigated.o Aim: To improve product life and fatigue

    properties.

    o Example: Isothermal forging, Powder metallurgy.

    Metals for biomedical applications

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    Future Trends

    Polymeric (Plastic Materials)

    Fastest growing basic material (9%

    per year).

    After 1995 growth rate decreased

    due to saturation.

    Different polymeric materials can

    be blend together to produce new

    plastic alloys.

    Search for new plastic continues.

    1-12

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    Future Trends

    Ceramic Materials

    New family ofengineering ceramics are produced

    last decade

    New materials and applications are constantly

    found.

    Now used in Auto and Biomedical applications.

    Processing of ceramics is expensive.

    Easily damaged as they are highly brittle.

    Better processing techniques and high-impact

    ceramics are to be found.

    1-13

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    Future Trends

    Composite Materials

    Fiber reinforced plastics are primary

    products.

    On an average 3% annual growth from

    1981 to 1987.

    Annual growth rate of 5% is predicted

    for new composites such as Fiberglass-

    Epoxy and Graphite-Epoxy

    combinations.

    Commercial aircrafts are expected to

    use more and more composite materials.

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    Future Trends

    Electronic Materials

    Use of electronic materials such as silicon

    increased rapidly from 1970.

    Electronic materials are expected to play

    vital role in Factories of Future.

    Use of computers and robots will increase

    resulting in extensive growth in use of

    electronic materials.

    Aluminum for interconnections in

    integrated circuits might be replaced by

    copper resulting in better conductivity.

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    Future Trends

    Smart Materials :Change their properties bysensing external stimulus.

    Shape memory alloys: Strained material reverts

    back to its original shape above a critical

    temperature.

    Used in heart valves and to expand arteries.

    Piezoelectric materials: Produce electric field when

    exposed to force and vice versa.

    Used in actuators and vibration reducers.

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    MEMS and Nanomaterials

    MEMS: Microelectromechanical systems.

    Miniature devices

    Micro-pumps, sensors

    Nanomaterials:Characteristic length < 100 nmExamples: ceramics powder and grain size < 100

    nm

    Nanomaterials are harder and stronger than bulkmaterials.

    Have biocompatible characteristics ( as inZirconia)

    Transistors and diodes are developed on ananowire.

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    Case Study Material Selection

    Problem: Select suitable material for bicycle

    frame and fork.

    Steel and

    alloysWood

    Carbon fiber

    Reinforced

    plastic

    Aluminum

    alloys

    Ti and Mg

    alloys

    Low cost but

    Heavy. Less

    Corrosionresistance

    Light and

    strong. But

    Cannot beshaped

    Very light and

    strong. No

    corrosion.Very expensive

    Light, moderately

    Strong. Corrosion

    Resistance.expensive

    Slightly better

    Than Al

    alloys. But muchexpensive

    Cost important? Select steel

    Properties important? Select CFRP