Seminar on Storage of Hc

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    GUIDED BY:

    Mr. PIYUSH VANJARA

    PREPARED BY:

    Ms. MANISHA VAID

    SEMINAR ON

    STORAGE OF HYDROCARBONS INTANK FARMS OF A REFINERY COMPLEX

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    INTRODUCTION TO THE TOPIC

    Vapor PressureReid Vapor Pressure

    Classification of liquids

    CLASS 1: liquids having flash point below 37.8c

    Class 1 a : flash points below 22.8c and boiling point below 37.8c

    Class 1 b : flash points below 22.8c and boiling point at or above 37.8c

    Class 1 c : flash points at or above 22.8c and boiling point below 37.8c

    CLASS 2 : liquids having flash point at or above 37.8c

    CLASS 3 : liquids having flash point at or above 60c

    Class 3 a : liquids having flash point at or above 60c and below 93.4c

    Class 3 b : liquids having flash point at or above93.4c

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    STORAGE OF PETROLEUM

    PRODUCTS NEED OF STORAGE

    BASIC CLASSIFICATION OF STORAGE (BASED ONPHASE)

    Storage of liquids Storage of gases

    based on internal pressure

    based on roof shape based on service

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    BASED ON INTERNAL

    PRESSURE ATMOSPHERIC TANKSInternal pressure slightly above atmospheric pressure

    pressure varies from atmospheric up to 0.5Psi above atmospheric

    pressure

    LOW PRESSURE TANKS

    Higher pressure from atmospheric up to 15Psig

    PRESSURE VESSELS

    Pressure above 15Psig

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    BASED ON ROOF SHAPE FIXED ROOFTANKS

    Cone rooftanks

    : bottom is flat and top made in form of shallow cone

    : storage of large quantity of fluids

    : roof rafters and support column

    Umbrella and dome rooftanks

    : tank roofs are self supporting

    FLOATING ROOFTANKS

    External floating roofs

    : diameter 30 100 ft.

    : roof is steel deck having annular compartment that provides buoyancy

    : double deck built for small floating roofs

    : strong and durable because of double deck: suitable for large diameter tanks

    Internal floating roofs

    : pan roofs are simple sheet steel disks

    : bulk head pan roof

    : skin and pontoon roofs

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    BASED ON SERVICE PRESSURE VESSELS

    Unfired

    Cylindrical

    : Bullets

    : Reactors (with agitator): Columns

    : Road tankers

    Cuboidal

    Spherical (HORTON SPHERE)

    Fired

    Boilers

    Heaters

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    TYPESOF VERTICAL CYLINDRICAL

    TANKSFO

    R PET

    ROLEU

    MLIQUIDSPETROLEUM LIQUID TYPE OF TANK

    CLASS 1:Petroleum (flash point below

    21c e.g. motor and aviation gasoline)

    (a) floating roof

    (b) non pressure fixed roof with

    internal floating deck

    (c) pressure fixed roof

    CLASS 2 : Petroleum (flash point

    between 21c and 55c) e.g. kerosene,

    special boiling point liquids

    (a) Floating roof

    (b) Non pressure fixed roof with

    internal floating deck(c) Non pressure fixed roof with

    atmospheric vent

    CLASS 3 : Petroleum (flash point

    above 55c ) e.g. diesel and gas oils,

    medium and heavy fuel oils, lubricatingoils and bitumen

    Non pressure fixed roof with

    atmospheric vent.Tanks which content

    heavy fuel oils or bitumen areinsulated and heated

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    STORAGE OF GASES GAS HOLDER

    Liquid seal holder :Seal tanks : size up to 2,80,000 m3 andFlexible fabric diaphragm

    SOLUTIONOFGASES INLIQUIDScertain gases will dissolve readily in liquidsexample : ammonia in water, acetylene in acetone and hydrochloric acid in

    water

    STORAGE IN PRESSUE VESSLES,BOTTLESAND PIPELINESGasses are stored under pressure

    A storage pressure vessel is usually a permanent installation, storing a gasunder pressure and liquifying it at ambient temperaturefor example : carbon dioxide

    Bottle is usually applied to a pressure vessel that is small enough to beconveniently portable

    Bottles range from about 57 lit. (2ft3) down to CO2 capsules of about 16.4ml(1 in3 )example : air , Hydrogen , Nitrogen , Oxygen etc

    PipelinesPipes buried in series of connected parallel lines and used for storage

    Storage is also obtained by increasing the pressure in operating pipe lines and thus usingthe pipe volume as a tank

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    LOSS MECHANISMS

    GENERAL DISCRIPTION

    Evaporative losses :

    Finite vapor pressure produced by the liquid stockdepending on surface temperature and composition of

    liquid.Establishment of an equilibrium concentration of

    vapors above the liquid surface.

    Floating roof tanks are exposed to dynamicconditions disturbing equilibrium and leading to

    additional evaporation.Evaporative losses primarily occur duringstanding storage and influenced by ambient wind.

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    Design losses RIM SEAL LOSS:vapor loss from Rim

    establishment of low pressure zone above floating roof.

    DECK FITTING LOSS:

    fittings have openings that allow stock vapors to flow to

    atmospheremechanism governing is vertical mixing.

    DECK SEAM LOSS:

    when seams are not completely vapor tight they become source of

    evaporative loss.

    WITHDRAWAL LOSS:

    as floating roof descends during stock withdrawal some of the

    liquid stock clings to the inside surface of the tank shell and it exposed

    to the atmosphere.

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    CAUSES OF LEAKS AND SPILLS

    AND

    THEIR PREVENTION Causes of Losses

    Leak or spill source Characteristics Root causes Preventive measures

    Corrosion most common in tank bottoms and corrosion; materials selection; careful design and engineering,

    Underground piping; low rate; lack costs of corrosion prevention inspection per API 653; tank

    Or warning; may continue for years methods management programUndetected; large volumes released

    Over long periods; column

    Operations

    Overf il ls or Transfers Larger quantit ies released; operator error; instrumentation or tank management program having Quickly discovered; hazardous equipment failure; lack of written operating procedures;

    Potential for fires; relatively training; failure to maintain training and drills; periodic

    Common overfill systems testing of instrumentation

    Roof drains large volumes released; easi ly equipment fai lure; fai lure to use tank management program having

    Discovered; usually occur in secondary containment properly written operating procedures;

    Stormy weather; relatively rare training and drills; periodic

    Testing of instrumentation

    Leaks leaks relatively common in piping, tank management program having

    Valves, and fittings, pump seals, written operating procedures;

    Or in penetrations through training and drills; periodic

    Secondary-containment areas testing of instrumentation

    Tank breakage Brittle fracture occurs in cold weather; material selection; poor careful design and actual

    Catastrophic failure mode; entire fabrication details; failure to solution; assessment of brittle

    Tank contents can empty; extremely hydrotest fracture and seismic after each

    Rare significant charge of service;

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    SUMMARY

    TYPESOFSTORAGE VESSELS

    FACTORSTO BE CONSIDERED DURINGSTORAGE THAT

    ISSTORAGE BASED ON CLASSOF PETROLEUM LIQUID

    LOSSESAND SPILL PREVENTION

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    BIBLIOGRAPHYBOOKS :

    Encyclopedia of Chemical Technology vol. 23

    By: KIRK OTHMER

    Chemical Engineering. Book

    By: PERRY

    Process Equipment design

    By : M. V. JOSHI

    JOURNALS :

    I.P.C.L. , BARODA

    WEBLINKS :

    www.Google.com

    www.altavista.com

    www.sciencedirect.com

    www.hydrocarbonprocessing.com

    www.chemweb.com