SDS MANUAL - keithlawson.com SDS 02-14-20.pdfAcetylene. Section 7. Handling and storage. Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities

KEITH LAWSON COMPANY, INC.

Plumbing & Mechanical Contractors ~ Proudly Serving the Southeast Since 1980 www.KeithLawson.com

‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗‗ Panama City Satellite Office Tallahassee Main Office Phenix City Satellite Office 2630 Twilight Avenue Post Office Box 37309 3015 Lakewood Drive Panama City, FL 32405 Tallahassee, FL 32315‐7309 Phenix City, AL 36867 (850) 257‐5195 Phone (850) 562‐2600 Phone (706) 940‐0290 Phone (850) 257‐5346 FAX (850) 562‐3795 FAX (706) 940‐0292 FAX [email protected] [email protected] [email protected] AL • MPG1639 •AC13002 • GC S52331 FL CFC033793 CMC041104 CGC1505898 GA • MP210460 ▪ CN210764

SDS

MANUAL

CHEMICAL INVENTORY LIST

CHEMICAL (PROCUCT IDENTIFIER)

MANUFACTURER EMERGENCY NUMBER

AMOUNT LOCATION

ACEYTLENE AIR GAS 911 NA

NO HUB LUBRICANT BLACK SWAN 911 NA

HYDRAULIC OIL CAT 911 NA

CLEAR COAT RUST-O-LEUM 911 NA

KNOCK’ER LOOSE CRC 911 NA

OIL MIX ECHO 911 NA

FS-ONE-MIX HILTI 911 NA

EXPANSION FOAM GREATSTUFF 911 NA

5W-30 OIL HAVOLINE 911 NA

LEAK DETECTOR HERCULES 911 NA

HYDRAULIC CEMENT QUICKCRETE 911 NA

LUCAS GREASE LUCAS 911 NA

MAPP GAS AIRGAS 911 NA

MASTER SEAL BASF 911 NA

NOKORODE FLUX RECTORSEAL 911 NA

O2 AIRGAS 911 NA

CPVC SINGLE STAGE CEMENT

OATEY 911 NA

THREAD CUTTING OIL OATEY 911 NA

CPVC HEAVY DUTY CEMENT

OATEY 911 NA

PIPE JOINT LUBRICANT

OATEY 911 NA

PRIMER OATEY 911 NA

PVC HEAVY DUTY CEMENT

OATEY 911 NA

RAIN-R-SHINE CEMENT

OATEY 911 NA

PRO-PEX GREASE MILWAUKEE 911 NA

PIPE THREAD LUBRICANT

RECTORSEAL 911 NA

MARKING PAINT RUST-O-LEUM 911 NA

GASOLINE SHELL 911 NA

SMOKE CANDLE OATEY 911 NA

WD-40 WD-40 911 NA

DIESEL SHELL 911 NA

kellyg

Typewritten Text

REVISED 2/14/2020

Acetylene

Ethyne; Ethine; Narcylen; C2H2; Acetylen; UN 1001; Vinylene

Gas.

SAFETY DATA SHEET

GHS product identifier

Other means of identification

Product type

Section 1. Identification:

:

:

Chemical name : acetylene

Supplier's details :

Acetylene

Product use : Synthetic/Analytical chemistry.

Synonym : Ethyne; Ethine; Narcylen; C2H2; Acetylen; UN 1001; Vinylene

SDS # : 001001Airgas USA, LLC and its affiliates259 North Radnor-Chester RoadSuite 100Radnor, PA 19087-52831-610-687-5253

1-866-734-3438:24-hour telephone

Section 2. Hazards identification

FLAMMABLE GASES - Category 1GASES UNDER PRESSURE - Compressed gas

Classification of the substance or mixture

:

Signal word : Danger

Hazard statements : Extremely flammable gas.May form explosive mixtures with air.Contains gas under pressure; may explode if heated.May displace oxygen and cause rapid suffocation.

Hazard pictograms :

Precautionary statements

Prevention : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Response : Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Eliminate all ignition sources if safe to do so.

Storage : Protect from sunlight. Store in a well-ventilated place.

Disposal : Not applicable.

GHS label elements

General : Read and follow all Safety Data Sheets (SDS’S) before use. Read label before use.Keep out of reach of children. If medical advice is needed, have product container or label at hand. Close valve after each use and when empty. Use equipment rated for cylinder pressure. Do not open valve until connected to equipment prepared for use.Fusible plugs in top, bottom, or valve melt at 98°C to 107°C (208°F to 224°F). Do not discharge at pressures above 15psig (103kpa). Use a back flow preventative device in the piping. Use only equipment of compatible materials of construction. Approach suspected leak area with caution.

Hazards not otherwise classified

: In addition to any other important health or physical hazards, this product may displace oxygen and cause rapid suffocation.

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Date of issue/Date of revision : 1/18/2018 Date of previous issue : 10/10/2017 Version : 1.01 1/11

Acetylene

Section 3. Composition/information on ingredients

acetylene 100 74-86-2

Ingredient name CAS number%

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Chemical name : acetylene


: Ethyne; Ethine; Narcylen; C2H2; Acetylen; UN 1001; Vinylene

CAS number : 74-86-2

Substance/mixture

CAS number/other identifiers

:

Occupational exposure limits, if available, are listed in Section 8.

Substance

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Product code : 001001

As this product is a gas, refer to the inhalation section.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs.

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. To avoid the risk of static discharges and gas ignition, soak contaminated clothing thoroughly with water before removing it. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,tie, belt or waistband.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

:

:

:

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Description of necessary first aid measures

Specific treatments : No specific treatment.

Most important symptoms/effects, acute and delayed

Inhalation : No known significant effects or critical hazards.

As this product is a gas, refer to the inhalation section.:Ingestion

Skin contact : Contact with rapidly expanding gas may cause burns or frostbite.

Contact with rapidly expanding gas may cause burns or frostbite.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation No specific data.

No specific data.

No specific data.

:

:

:

Eye contact : No specific data.

Potential acute health effects

Indication of immediate medical attention and special treatment needed, if necessary

Frostbite : Try to warm up the frozen tissues and seek medical attention.


Acetylene

Section 4. First aid measuresProtection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may

be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Contact supplier immediately for specialist advice. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. If involved in fire, shut off flow immediately if it can be done without risk. If this is impossible, withdraw from area and allow fire to burn. Fight fire from protected location or maximum possible distance. Eliminate all ignition sources if safe to do so.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:carbon dioxidecarbon monoxide

Contains gas under pressure. Extremely flammable gas. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

:

:

:

None known.

Suitable extinguishing media

:

Unsuitable extinguishing media

:

Special protective actions for fire-fighters

:

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof tools and explosion-proof equipment. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

:

: Accidental releases pose a serious fire or explosion hazard. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas.Keep unnecessary and unprotected personnel from entering. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing gas. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Ensure emergency procedures to deal with accidental gas releases are in place to avoid contamination of the environment. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Large spill :

Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof tools and explosion-proof equipment.

Small spill :

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".


Acetylene

Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage,including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in a segregated and approved area.Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10). Eliminate all ignition sources. Cylinders should be stored upright, with valve protection cap in place, and firmly secured to prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C (125 °F). Keep container tightly closed and sealed until ready for use. See Section 10 for incompatible materials before handling or use.

:

:

Protective measures Put on appropriate personal protective equipment (see Section 8). Contains gas under pressure. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Do not puncture or incinerate container. Use equipment rated for cylinder pressure. Close valve after each use and when empty.Protect cylinders from physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement. Use only non-sparking tools. Avoid contact with eyes, skin and clothing. Empty containers retain product residue and can be hazardous. Store and use away from heat,sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment.

:

Precautions for safe handling

acetylene NIOSH REL (United States, 10/2016). CEIL: 2662 mg/m³ CEIL: 2500 ppmACGIH TLV (United States, 3/2017). Oxygen Depletion [Asphyxiant].

California PEL for Chemical Contaminants (Table AC-1) (United States). Oxygen Depletion [Asphyxiant].

Section 8. Exposure controls/personal protection

Ingredient name Exposure limits

Environmental exposure controls

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineering controls

: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas,vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Control parameters

Individual protection measures

Occupational exposure limits


Acetylene


Hand protection

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.

Eye/face protection

Respiratory protection :

:

:

Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.

:

Skin protection

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Section 9. Physical and chemical properties

Physical state

Melting point

Relative density

Solubility

Gas.

-81°C (-113.8°F)

Not applicable.

Not available.

Mild. Ethereal.Odor

pH

Colorless.Color

Evaporation rate Not available.

Auto-ignition temperature

Flash point

305°C (581°F)

Closed cup: -18.15°C (-0.67°F)

0.37

Not available.

Not available.Odor threshold

Partition coefficient: n-octanol/water

:

:

:

:

:

:

:

:

:

:

:

:

Appearance

Boiling point : Not available.

Flammability (solid, gas) : Extremely flammable in the presence of the following materials or conditions: open flames, sparks and static discharge and oxidizing materials.Highly flammable in the presence of the following materials or conditions: heat.

Lower and upper explosive (flammable) limits

: Lower: 2.5%Upper: 100%

Solubility in water : 1.2 g/l

Vapor pressure

Vapor density 0.907 (Air = 1)

635 (psig):

:

Specific Volume (ft 3/lb) : 14.7058

Gas Density (lb/ft 3) : 0.0691

Critical temperature : 35.25°C (95.5°F)


Acetylene


Viscosity Not applicable.:

Decomposition temperature : Not available.

Heat of combustion : -48257522 J/kg

Aerosol product

: 26.04 g/moleMolecular weight

Flow time (ISO 2431) : Not available.

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

Oxidizers

:

:

:

Incompatible materials :

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Under normal conditions of storage and use, hazardous polymerization will not occur.Hazardous polymerization :

Section 11. Toxicological information

Acute toxicity

Not available.

Carcinogenicity

Not available.

Mutagenicity

Not available.

Teratogenicity

Not available.

Reproductive toxicity

Not available.

Irritation/Corrosion

Not available.

Sensitization

Not available.

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Not available.

Not available.

Aspiration hazard

Information on toxicological effects


Acetylene


Not available.

Information on the likely routes of exposure





No known significant effects or critical hazards.General :

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion


No specific data.

No specific data.

:

:

:


Potential chronic health effects

Delayed and immediate effects and also chronic effects from short and long term exposure

Numerical measures of toxicity

Not available.

Acute toxicity estimates

Not available.

: Not available.


Potential immediate effects

: Not available.

Short term exposure

Potential delayed effects : Not available.


: Not available.

Long term exposure


Section 12. Ecological information

Bioaccumulative potential

Toxicity

Not available.

Persistence and degradability

Not available.


Acetylene

Section 12. Ecological informationLogPow BCF Potential

Other adverse effects : No known significant effects or critical hazards.

Product/ingredient name

acetylene 0.37 - low

Soil/water partition coefficient (KOC)

: Not available.

Mobility in soil

Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Empty Airgas-owned pressure vessels should be returned to Airgas. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container.

:Disposal methods

Section 14. Transport information

ACETYLENE,DISSOLVED

2.1

-

ACETYLENE,DISSOLVED

2.1

-

ACETYLENE,DISSOLVED

UN1001

2.1

-

UN1001 UN1001

Limited quantity Yes.Quantity limitation Passenger aircraft/rail: Forbidden. Cargo aircraft: 15 kg.

DOT IMDG IATA

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Additional information

Environmental hazards

No. No. No.

TDG

UN1001

ACETYLENE,DISSOLVED

2.1

-

No.

Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.13-2.17 (Class 2).

Explosive Limit and Limited Quantity Index0

Passenger Carrying Ship Index75

Passenger Carrying Road or Rail IndexForbidden

Mexico

UN1001

ACETYLENE,DISSOLVED

2.1

-

No.

DOT Classification

TDG Classification

:

:

“Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the product.”


Acetylene


Quantity limitation Passenger and Cargo Aircraft: Forbidden. Cargo Aircraft Only: 15 kg.

Special precautions for user

Transport in bulk according to Annex II of MARPOL and the IBC Code

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

: Not available.

:

Special provisions38

IATA :

Section 15. Regulatory informationU.S. Federal regulations

This material is listed.

Clean Air Act (CAA) 112 regulated flammable substances: acetylene

Massachusetts

:

:

Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs)

: Not listed

Clean Air Act Section 602 Class I Substances

: Not listed

Clean Air Act Section 602 Class II Substances

: Not listed

DEA List I Chemicals (Precursor Chemicals)

: Not listed

DEA List II Chemicals (Essential Chemicals)

: Not listed

New York : This material is not listed.

New Jersey : This material is listed.

Pennsylvania : This material is listed.

State regulations

TSCA 8(a) CDR Exempt/Partial exemption: Not determined

SARA 302/304

SARA 304 RQ : Not applicable.

No products were found.

Composition/information on ingredients

International regulations

Chemical Weapon Convention List Schedules I, II & III Chemicals

Montreal Protocol (Annexes A, B, C, E)

Not listed.

Stockholm Convention on Persistent Organic Pollutants

Not listed.

Rotterdam Convention on Prior Informed Consent (PIC)

Not listed.

Not listed.

UNECE Aarhus Protocol on POPs and Heavy Metals

SARA 311/312

Classification : Refer to Section 2: Hazards Identification of this SDS for classification of substance.


Acetylene

Section 15. Regulatory informationNot listed.

Inventory list

Australia : This material is listed or exempted.

Canada : This material is listed or exempted.

China : This material is listed or exempted.

Europe : This material is listed or exempted.

Japan : Japan inventory (ENCS): This material is listed or exempted.Japan inventory (ISHL): Not determined.

Republic of Korea : This material is listed or exempted.

Malaysia : Not determined.

New Zealand : This material is listed or exempted.

Philippines : This material is listed or exempted.

Taiwan : This material is listed or exempted.

Turkey : This material is listed or exempted.

United States : This material is listed or exempted.

Thailand : Not determined.

Viet Nam : Not determined.

Section 16. Other informationHazardous Material Information System (U.S.A.)

0

4

3

34

0

/

National Fire Protection Association (U.S.A.)

Health

Special

Instability/Reactivity

Flammability

Health

Flammability

Physical hazards

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc.

The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.

Procedure used to derive the classification

Classification Justification

FLAMMABLE GASES - Category 1 Expert judgmentGASES UNDER PRESSURE - Compressed gas According to package

Note: The instability hazard rating for acetylene, dissolved (stabilized acetylene) is 2.


Acetylene

Section 16. Other information

1/18/2018

History

Date of printing

Date of issue/Date of revision

Version

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Notice to reader

Date of previous issue

:

:

:

:

Indicates information that has changed from previously issued version.

References : Not available.

Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations

1/18/2018

10/10/2017

1.01


BLACK SWAN MFG. CO.

GHS

SECTION 1

Manufacturer:

Black Swan Mfg. Co.

4540 W. Thomas St.

Chicago, IL 60651-3318

Tel.: 800-252-5796

Fax: 773-227-3705

Web Site : www.blackswanmfg.com

E-mail : [email protected]

Product Name: No-Hub Sealant

SECTION 2

Labels

Health Hazard Flammable

NFPA

HEALTH HAZARD FIRE HAZARD4 – Deadly Flash Points

3 - Extreme Danger 4

2 – Hazardous

1 - Slight Hazardous 2

0 - Normal Material

SPECIFIC HAZARD REACTIVITY Oxidizer OX 4

Acid ACID 3

Alkali ALK may detonateCorrosive COR 2

Use NO WATER W

Radioactive

Signal Word Danger

HMIS

Hazardous Statements H225: Highly flammable liquid and vapor

H304: May be fatal if swallowed and enters airways

H312: Harmful in contact with skin

H319: Causes serious eye irritation

H332: Harmful if inhaled

H335: May cause respiratory irritation

H336: May cause drowsiness or dizziness

SECTION 3 – COMPOSITION / INFORMATION ON INGREDIENTS

Chemicals CAS#

ETHYL ALCOHOL 64-17-5

METHYL ALCOHOL 67-56-1

ETHYL ACETATE 141-78-6

ACETONE 67-64-1

POLYVINYL BUTYRAL 7723-18-5 N/A N/A 10

*Unlisted ingredients are not classified as hazardous according to OSHA 1910.1200.

SECTION

Inhalation: Move into fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and call physici

Skin: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water.

Eyes: Flush with water for 15 minutes. If irritation persists, get medical attention.

Ingestion: Give 1 or 2 glasses of water. DO NOT INDUCE VOMITING. Contact physician immediately.

31

HEALTH

FLAMMABILITY

REACTIVITY

1

3

0

`

BLACK SWAN MFG. CO.

GHS SAFETY DATA SHEET

SECTION 1 - IDENTIFICATION

www.blackswanmfg.com

For any Transportation or Medical Chemical Emergencies call:

INFOTRAC

(800) 535-5053 OR

24 hours per day -

Recommended Use: A sealant specifically

for cast iron pipe to improve leak-free sealing of no

SECTION 2 – HAZARD(S) IDENTIFICATION

NFPA

HAZARD FIRE HAZARD Deadly Flash Points

Extreme Danger 4 – Below 73°F

3 – Below 100°F

Slight Hazardous 2 – Above 100°F, Not

Normal Material exceeding 200°F

1 – Above 200°F 0 – Will not burn

SPECIFIC HAZARD REACTIVITY Oxidizer OX 4 – May detonate

Acid ACID 3 – Shock and heat

lkali ALK may detonate Corrosive COR 2 – Violent chemical

change

1 – Unstable if heated

0 – Stable

GHS Classification

Health Acute Toxicity: Not Established

Skin Irritation: Not Established Acute Aquatic Toxicity: Not Established

Eye Irritation: Not Established Chronic Aquatic Toxicity: Not Established

Skin Sensitization: NO

Physical Flammability: Cat.

Precautionary StatementsP102: Keep out of reach of children

P103: Read label before use

P210: Keep away from heat/sparks/open flames/hot surfaces

P233/P235: Keep container tightly closed and cooled

P243: Take precautionary measures against static

P261: Avoid breathing dust/fume/gas/mist/vapors/spray

P262: Do not get in eyes, on skin, or on clothing

P264: Wash thoroughly after handling

P270: Do not eat, drink or smoke when using this product

P271: Use only outdoors or in a well-ventilate

P280/P284: Wear protective gloves/protective clothing/eye protection/face

protection. Wear a NIOSH approved respirator for organic solvents.

COMPOSITION / INFORMATION ON INGREDIENTS

EINECS# REACH

Pre-registration Number 5 200-578-6 N/A 25

1 200-659-6 N/A 1

205-500-4 N/A <1%

1 200-662-2 N/A 35

5 N/A N/A 10

*Unlisted ingredients are not classified as hazardous according to OSHA 1910.1200.

SECTION 4 – FIRST-AID MEASURES

: Move into fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and call physici

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water.

Flush with water for 15 minutes. If irritation persists, get medical attention.

Give 1 or 2 glasses of water. DO NOT INDUCE VOMITING. Contact physician immediately.

Page 1 of 3

3 0

any Transportation or Medical Chemical Emergencies call:

INFOTRAC

(352) 323-3500

7 days a week

A sealant specifically designed as a coating

free sealing of no-hub couplings.

GHS Classification

Environmental

Acute Aquatic Toxicity: Not Established

Chronic Aquatic Toxicity: Not Established

Cat. 2

autionary Statements

P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking

P233/P235: Keep container tightly closed and cooled

P243: Take precautionary measures against static discharge

P261: Avoid breathing dust/fume/gas/mist/vapors/spray

P262: Do not get in eyes, on skin, or on clothing

P270: Do not eat, drink or smoke when using this product

ventilated area

P280/P284: Wear protective gloves/protective clothing/eye protection/face

protection. Wear a NIOSH approved respirator for organic solvents.

COMPOSITION / INFORMATION ON INGREDIENTS

REACH Approx %

N/A 25-30%

N/A 1-2%

N/A <1%

N/A 35-45%

5 N/A N/A 10-20%

: Move into fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and call physician.

`


SECTION 5 – FIRE-FIGHTING MEASURES

Fire Hazard: Vapors may travel considerable distance to sources of ignition and flash back.

Combustion Products: None.

Extinguishing Media: Foam, Carbon Dioxide, Dry Chemical.

Unsuitable Extinguishing Media: None Known.

Protective Equipment: Self-contained breathing apparatus {(SCBA), MSHA/NIOSH}. Full protective gear.

Special Fire Fighting Procedures: Evacuate enclosed areas, stay upwind. Closed or confined quarters require self-contained breathing

apparatus, positive pressure hose masks or airline masks. Use agents appropriate for surrounding fires.

SECTION 6 – ACCIDENTAL RELEASE MEASURES

Personal Precautions: None.

Protective Equipment: Wear suitable respiratory protective equipment.

Emergency Procedures: None.

Environmental Precautions: Avoid runoff into storm sewers, ditches and waterways.

Methods for Cleaning Up: Absorb with suitable inert material. Remove all sources of ignition.

SECTION 7 – HANDLING AND STORAGE

Handling Use good personal hygiene practice. Avoid inhalation of vapors and

personal contact with the product. Repeated and prolonged

overexposure to solvents may cause brain and nervous system

damage. Concentrating and inhaling the contents may be harmful or

fatal.

Storage Keep and store in a cool, dry place from sources of ignition. Ground

during transfer. Keep container tightly closed when not in use.

Incompatible Materials: Strong oxidizing agents, strong acids.

SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Limits

Hazardous Chemicals ACGIH-TLV ACGIH-STEL OSHA-PEL ETHYL ALCOHOL 1000 ppm N/A 1000 ppm

METHYL ALCOHOL 200 ppm N/A 200 ppm

ETHYL ACETATE 400 ppm N/A 400 ppm

ACETONE 500 ppm 750 ppm 1000 ppm

Engineering Controls: A source of running water to flush or wash the eyes and skin in case of contact.

Ventilation: Mechanical.

Personal Protective Equipment – Respiratory: If use conditions generate vapors or mists, wear a NIOSH-approved respirator appropriate

for those emission levels. Appropriate respirators may be a full face piece or a half mask air-purifying cartridge respirator equipped for

organic vapors/mists, a self-contained breathing apparatus in the pressure demand mode, or a supplied-air respirator.

Personal Protective Equipment – Skin: Impermeable gloves. Chemical resistant coveralls.

Personal Protective Equipment – Eyes: Safety glasses with side shields or chemical goggles.

SECTION 9 – PHYSICAL & CHEMICAL PROPERTIES Appearance: Amber Viscous Liquid Flash Point: 65°F (T.C.C.) Vapor Pressure: Not Established

Odor: Characteristic Solvent Specific Gravity: Approx. 0.70 Flammability: Not Established

pH: Not Established Solubility (H2O): Insoluble Flammability Limits: LEL – 0.9%

Melting Point: Not Established Evaporation Rate: > 1.0 UEL – 7.0%

Freezing Point: Not Established Vapor Density: > 1.0

Boiling Point: 170°F VOC: 250 g/l

Page 2 of 3

`


SECTION 10 – STABILITY AND REACTIVITY

Stability: Stable.

Hazardous polymerization: Will not occur.

Conditions to avoid: Sparks, open flames, hot surfaces and strong oxidizing agents.

Incompatible materials: Strong oxidizing agents, strong acids.

Hazardous decomposition products: Carbon Monoxide, Carbon Dioxide

SECTION 11 – TOXICOLOGICAL INFORMATION

Toxicity

Hazardous Chemicals LD50 LC50

ETHYL ALCOHOL N/A N/A

METHYL ALCOHOL N/A N/A

ETHYL ACETATE N/A N/A

ACETONE N/A N/A

POLYVINYL BUTYRAL N/A N/A

Likely Routes of Exposure: Inhalation, Skin Contact, Eye Contact and Ingestion.

Symptoms and Effect - Inhalation: It is a respiratory tract irritant and anesthetic and causes central nervous system depression (e.g.

headache, drowsiness, dizziness, loss of coordination & fatigue). Skin Contact: May cause mild skin irritation. Prolonged or repeated

contact may cause redness, burning, and drying and cracking of the skin. Eye Contact: May cause mild eye irritation. Direct contact with

the liquid or exposure to vapors or mists may cause stinging, tearing and redness. Ingestion: Ingestion of excessive quantities may cause

irritation of the digestive tract and signs of nervous system depression.

Long-Term Effect: None known.

Pre-Existing Conditions: Any pre-existing heart or skin condition or an impaired lung function.

SECTION 12 – ECOLOGICAL INFORMATION

Ecotoxicity: None known.

Persistance & Degradability: None known.

Bioaccumulative Potential: None known.

Mobility in soil: In normal use, emission of Volatile Organic Compounds (VOC’s) to the air takes place, typically at a rate of <250 g/l.

SECTION 13 – DISPOSAL CONSIDERATION

Dispose of product or container in accordance with federal, state or local regulations.

SECTION 14 – TRANSPORTATION INFORMATION

Shipping Information Shipping Name: Adhesives, Containing a Flammable Liquid Exception to the rule: If the package that contains the hazardous

Hazardous Class: 3 material is in a small consumer size (Less than 1L), then the rules

I.D. Number: UN1133 that apply to shipping hazardous materials do not apply. This is

Packing Group: II called an “Exception”.

Label Required: Flammable Liquid This is classified as Consumer Commodity ORM-D.

Marine Pollutant: No

SECTION 15 – REGULATORY INFORMATION

Precautionary Label Information: Flammable, and Health Hazard.

Risk Phrases: R10-Flammable. R36/37-Irritant to eyes and respiratory system.

Safety Phrases: S2-Keep out of reach of children. S9-Keep container in a well-ventilated place. S16-Keep away from sources of ignition-No

smoking. S25-Avoid contact with eyes. S26-In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S33-

Take precautionary measures against static discharges.

SECTION 16 – OTHER INFORMATION Information on this form is furnished solely for the purpose of compliance with the Occupational Safety and Health Act and shall not be used for any other purpose. Black

Swan Mfg. Co. urges the customers receiving this Material Safety Data Sheet to study it carefully to become aware of the hazards, if any, of the product involved. In the

interest of safety, you should notify your employees, agents and contractors of the information on the sheets. DATE: 01/01/2015

Page 3 of 3

Product Name: CAT HYDRAULIC OIL (HYDO) SAE 10W Revision Date: 02 Mar 2015 Page 1 of 10

______________________________________________________________________________________________________________________

SAFETY DATA SHEETSECTION 1 PRODUCT AND COMPANY IDENTIFICATION

PRODUCTProduct Name: CAT HYDRAULIC OIL (HYDO) SAE 10WProduct Description: Base Oil and AdditivesProduct Code: 20202050B020, 478909-00, 971670Intended Use: Hydraulic/transmission fluid

COMPANY IDENTIFICATIONSupplier: EXXON MOBIL CORPORATION

3225 GALLOWS RD.FAIRFAX, VA. 22037 USA

24 Hour Health Emergency 609-737-4411 Transportation Emergency Phone 800-424-9300 or 703-527-3887 CHEMTREC Product Technical Information 800-662-4525 MSDS Internet Address http://www.exxon.com, http://www.mobil.com

SECTION 2 HAZARDS IDENTIFICATION

This material is not hazardous according to regulatory guidelines (see (M)SDS Section 15).

Other hazard information:

HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1900.1200.

PHYSICAL / CHEMICAL HAZARDS No significant hazards.

HEALTH HAZARDS High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, orrespiratory irritation.

ENVIRONMENTAL HAZARDS No significant hazards.

NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0

NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert


______________________________________________________________________________________________________________________

advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary fromperson to person.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

This material is defined as a mixture.

Hazardous Substance(s) or Complex Substance(s) required for disclosureName CAS# Concentration* GHS Hazard CodesZINC DITHIOPHOSPHATE 68649-42-3 1 - 2.5% H315, H318, H401,

H411

* All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume.

As per paragraph (i) of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity andexact percentage (concentration) of composition may have been withheld. Specific chemical identity and exactpercentage composition will be provided to health professionals, employees, or designated representatives inaccordance with applicable provisions of paragraph (i).

SECTION 4 FIRST AID MEASURES

INHALATIONRemove from further exposure. For those providing assistance, avoid exposure to yourself or others. Useadequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seekimmediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or usemouth-to-mouth resuscitation.

SKIN CONTACTWash contact areas with soap and water. If product is injected into or under the skin, or into any part of thebody, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by aphysician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimalor absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.

EYE CONTACTFlush thoroughly with water. If irritation occurs, get medical assistance.

INGESTIONFirst aid is normally not required. Seek medical attention if discomfort occurs.

SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIAAppropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguishflames.

Inappropriate Extinguishing Media: Straight Streams of Water

FIRE FIGHTING


______________________________________________________________________________________________________________________

Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams,sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosedspaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and toprotect personnel.

Unusual Fire Hazards: Pressurized mists may form a flammable mixture.

Hazardous Combustion Products: Aldehydes, Oxides of carbon, Smoke, Fume, Sulfur oxides, Incompletecombustion products

FLAMMABILITY PROPERTIESFlash Point [Method]: >200°C (392°F) [ASTM D-92]Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0Autoignition Temperature: N/D

SECTION 6 ACCIDENTAL RELEASE MEASURES

NOTIFICATION PROCEDURESIn the event of a spill or accidental release, notify relevant authorities in accordance with all applicableregulations. US regulations require reporting releases of this material to the environment which exceed theapplicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. TheNational Response Center can be reached at (800)424-8802.

PROTECTIVE MEASURESAvoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard IdentificationSection for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimumrequirements for personal protective equipment. Additional protective measures may be necessary, dependingon the specific circumstances and/or the expert judgment of the emergency responders.

For emergency responders: Respiratory protection: respiratory protection will be necessary only in specialcases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or SelfContained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level ofexposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible oranticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended.Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use.Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistaticwork clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material isrecommended.

SPILL MANAGEMENTLand Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent.

Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn othershipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialistbefore using dispersants.

Water spill and land spill recommendations are based on the most likely spill scenario for this material; however,geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction andspeed may greatly influence the appropriate action to be taken. For this reason, local experts should beconsulted. Note: Local regulations may prescribe or limit action to be taken.


______________________________________________________________________________________________________________________

ENVIRONMENTAL PRECAUTIONSLarge Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers,basements or confined areas.

SECTION 7 HANDLING AND STORAGE

HANDLING Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which maycause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could igniteany flammable vapors from liquids or residues that may be present (e.g., during switch-loading operations). Useproper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard fromstatic accumulation. Consult local applicable standards for guidance. Additional references include AmericanPetroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) orNational Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404(Electrostatics - Code of practice for the avoidance of hazards due to static electricity).

Static Accumulator: This material is a static accumulator.

STORAGEThe container choice, for example storage vessel, may effect static accumulation and dissipation. Do not storein open or unlabelled containers. Keep away from incompatible materials.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosolscan occur the following are recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction), 5 mg/m³ - OSHA PEL.

NOTE: Limits/standards shown for guidance only. Follow applicable regulations.

No biological limits allocated.

ENGINEERING CONTROLS

The level of protection and types of controls necessary will vary depending upon potential exposure conditions.Control measures to consider:

No special requirements under ordinary conditions of use and with adequate ventilation.

PERSONAL PROTECTION

Personal protective equipment selections vary based on potential exposure conditions such as applications,handling practices, concentration and ventilation. Information on the selection of protective equipment for usewith this material, as provided below, is based upon intended, normal usage.

Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a levelwhich is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection,use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to


______________________________________________________________________________________________________________________

be considered for this material include: No special requirements under ordinary conditions of use and with adequate ventilation.

For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vaporwarning properties are poor, or if air purifying filter capacity/rating may be exceeded.

Hand Protection: Any specific glove information provided is based on published literature and glovemanufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your useconditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this materialinclude:

No protection is ordinarily required under normal conditions of use.

Eye Protection: If contact is likely, safety glasses with side shields are recommended.

Skin and Body Protection: Any specific clothing information provided is based on published literature ormanufacturer data. The types of clothing to be considered for this material include:

No skin protection is ordinarily required under normal conditions of use. In accordance with goodindustrial hygiene practices, precautions should be taken to avoid skin contact.

Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing afterhandling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protectiveequipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.Practice good housekeeping.

ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water andsoil. Protect the environment by applying appropriate control measures to prevent or limitemissions.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Note: Physical and chemical properties are provided for safety, health and environmental considerations onlyand may not fully represent product specifications. Contact the Supplier for additional information.

GENERAL INFORMATIONPhysical State: LiquidColor: AmberOdor: CharacteristicOdor Threshold: N/D

IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATIONRelative Density (at 15 °C): 0.878 Flammability (Solid, Gas): N/AFlash Point [Method]: >200°C (392°F) [ASTM D-92]Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/DBoiling Point / Range: > 316°C (600°F) [Estimated]Decomposition Temperature: N/DVapor Density (Air = 1): > 2 at 101 kPa [Estimated]


______________________________________________________________________________________________________________________

Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C [Estimated]Evaporation Rate (n-butyl acetate = 1): N/DpH: N/ALog Pow (n-Octanol/Water Partition Coefficient): > 3.5 [Estimated]Solubility in Water: NegligibleViscosity: 37.7 cSt (37.7 mm2/sec) at 40 °C | 6.1 cSt (6.1 mm2/sec) at 100°COxidizing Properties: See Hazards Identification Section.

OTHER INFORMATIONFreezing Point: N/DMelting Point: N/APour Point: -18°C (0°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt

SECTION 10 STABILITY AND REACTIVITY

REACTIVITY: See sub-sections below.

STABILITY: Material is stable under normal conditions.

CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition.

MATERIALS TO AVOID: Strong oxidizers

HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.

POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

INFORMATION ON TOXICOLOGICAL EFFECTS

Hazard Class Conclusion / RemarksInhalationAcute Toxicity: No end point data formaterial.

Minimally Toxic. Based on assessment of the components.

Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures.IngestionAcute Toxicity: No end point data formaterial.


SkinAcute Toxicity: No end point data formaterial.


Skin Corrosion/Irritation: No end point datafor material.

Negligible irritation to skin at ambient temperatures. Based onassessment of the components.

EyeSerious Eye Damage/Irritation: No end pointdata for material.

May cause mild, short-lasting discomfort to eyes. Based onassessment of the components.

SensitizationRespiratory Sensitization: No end point data Not expected to be a respiratory sensitizer.


______________________________________________________________________________________________________________________for material.Skin Sensitization: No end point data formaterial.

Not expected to be a skin sensitizer. Based on assessment of thecomponents.

Aspiration: Data available. Not expected to be an aspiration hazard. Based onphysico-chemical properties of the material.

Germ Cell Mutagenicity: No end point datafor material.

Not expected to be a germ cell mutagen. Based on assessment ofthe components.

Carcinogenicity: No end point data formaterial.

Not expected to cause cancer. Based on assessment of thecomponents.

Reproductive Toxicity: No end point datafor material.

Not expected to be a reproductive toxicant. Based on assessmentof the components.

Lactation: No end point data for material. Not expected to cause harm to breast-fed children.Specific Target Organ Toxicity (STOT)Single Exposure: No end point data formaterial.

Not expected to cause organ damage from a single exposure.

Repeated Exposure: No end point data formaterial.

Not expected to cause organ damage from prolonged or repeatedexposure. Based on assessment of the components.

OTHER INFORMATION

Contains:Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Amestest, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration ofimmune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals.

The following ingredients are cited on the lists below: None.

--REGULATORY LISTS SEARCHED-- 1 = NTP CARC 3 = IARC 1 5 = IARC 2B 2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC

SECTION 12 ECOLOGICAL INFORMATION

The information given is based on data available for the material, the components of the material, and similar materials.

ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms.

MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to

partition to sediment and wastewater solids.

PERSISTENCE AND DEGRADABILITYBiodegradation: Base oil component -- Expected to be inherently biodegradable


______________________________________________________________________________________________________________________

BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may

reduce the bioconcentration or limit bioavailability.

SECTION 13 DISPOSAL CONSIDERATIONS

Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable lawsand regulations, and material characteristics at time of disposal.

DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervisedincineration at very high temperatures to prevent formation of undesirable combustion products. Protect theenvironment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents,brake fluids or coolants.

REGULATORY DISPOSAL INFORMATION RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardouswaste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. Itdoes not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated withcontaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used productmay be regulated.

Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue andcan be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should becompletely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be takenfor recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmentalregulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCHCONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEYMAY EXPLODE AND CAUSE INJURY OR DEATH.

SECTION 14 TRANSPORT INFORMATION

LAND (DOT): Not Regulated for Land Transport

LAND (TDG): Not Regulated for Land Transport

SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code

Marine Pollutant: No


______________________________________________________________________________________________________________________

AIR (IATA): Not Regulated for Air Transport

SECTION 15 REGULATORY INFORMATION

OSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance withOSHA HazCom 2012, 29 CFR 1910.1200.

Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, ENCS, IECSC,KECI, PICCS, TSCA

EPCRA SECTION 302: This material contains no extremely hazardous substances.

SARA (311/312) REPORTABLE HAZARD CATEGORIES: None.

SARA (313) TOXIC RELEASE INVENTORY:

Chemical Name CAS Number Typical ValueZINC DITHIOPHOSPHATE 68649-42-3 1 - 2.5%

The following ingredients are cited on the lists below:

Chemical Name CAS Number List CitationsZINC DITHIOPHOSPHATE 68649-42-3 13, 15, 17, 19

--REGULATORY LISTS SEARCHED--1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK5 = TSCA 4 10 = CA P65 CARC 15 = MI 293

Code key: CARC=Carcinogen; REPRO=Reproductive

SECTION 16 OTHER INFORMATION

N/D = Not determined, N/A = Not applicable

KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only):H315: Causes skin irritation; Skin Corr/Irritation, Cat 2H318: Causes serious eye damage; Serious Eye Damage/Irr, Cat 1H401: Toxic to aquatic life; Acute Env Tox, Cat 2H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2


______________________________________________________________________________________________________________________

THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:Updates made in accordance with implementation of GHS requirements.

-----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurateand reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most currentavailable from ExxonMobil. The information and recommendations are offered for the user's consideration andexamination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyerrepackages this product, it is the user's responsibility to insure proper health, safety and other necessary information isincluded with and/or on the container. Appropriate warnings and safe-handling procedures should be provided tohandlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-publicationor retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used forconvenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or anyaffiliates in which they directly or indirectly hold any interest.

-----------------------------------------------------------------------------------------------------------------------------------------------------

Internal Use OnlyMHC: 0B, 0B, 0, 0, 0, 0 PPEC: A

DGN: 2004671XUS (546411)

-----------------------------------------------------------------------------------------------------------------------------------------------------Copyright 2002 Exxon Mobil Corporation, All rights reserved

Date Printed: 8/6/2018

Safety Data Sheet* Trusted Quality Since 1921 *

www.rustoleum.com

1. Identification

Product Name: ROHPER LSPR 6PK GLOSS CRYSTALCLEAR

Revision Date: 8/6/2018

Product Identifier: V2102838 Supercedes Date: 3/14/2018

Recommended Use: Clear Topcoat/Aerosols

Supplier: Rust-Oleum Corporation11 Hawthorn ParkwayVernon Hills, IL 60061USA

Rust-Oleum Canada (ROCA)200 Confederation ParkwayConcord, ON L4K 4T8CanadaEmergency Phone: 800-387-3625

Manufacturer: Rust-Oleum Corporation11 Hawthorn ParkwayVernon Hills, IL 60061USA

Preparer: Regulatory Department

24 Hour Hotline: 847-367-7700Emergency Telephone:

2. Hazard Identification

Classification

Symbol(s) of Product

Signal WordDanger

Possible Hazards25% of the mixture consists of ingredient(s) of unknown acute toxicity.

GHS HAZARD STATEMENTSFlammable Aerosol, category 1 H222 Extremely flammable aerosol.

Compressed Gas H280 Contains gas under pressure; may explode if heated.

Carcinogenicity, category 2 H351 Suspected of causing cancer.

STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness.

Eye Irritation, category 2 H319 Causes serious eye irritation.

Page 1 / 6


GHS LABEL PRECAUTIONARYSTATEMENTSP210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P211 Do not spray on an open flame or other ignition source.

P251 Do not pierce or burn, even after use.

P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C / 122°F.

P410+P403 Protect from sunlight. Store in a well-ventilated place.

P201 Obtain special instructions before use.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P405 Store locked up.

P501 Dispose of contents/container in accordance with local, regional and national regulations.

P261 Avoid breathing dust/fume/gas/mist/vapors/spray.

P271 Use only outdoors or in a well-ventilated area.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P264 Wash hands thoroughly after handling.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if presentand easy to do. Continue rinsing.

P337+P313 If eye irritation persists: Get medical advice/attention.

3. Composition / Information On Ingredients

HAZARDOUS SUBSTANCES

Chemical Name CAS-No. Wt.% GHS Symbols GHS Statements

Acetone 67-64-1 31 GHS02-GHS07 H225-319-332-336

n-Butyl Acetate 123-86-4 22 GHS02-GHS07 H226-336

Page 2 / 6


Propane 74-98-6 15 GHS04 H280

1-Methoxy-2-Propyl Acetate 108-65-6 7.5 GHS02 H226

n-Butane 106-97-8 7.1 GHS04 H280

Ethyl 3-Ethoxypropionate 763-69-9 2.3 GHS06 H331

Xylenes (o-, m-, p- isomers) 1330-20-7 1.8 GHS02-GHS07 H226-315-319-332

Ethylbenzene 100-41-4 0.4 GHS02-GHS07-GHS08 H225-304-332-351-373

4. First-Aid Measures

FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed.

FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.

FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.

FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention.

5. Fire-Fighting Measures

EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Water Fog

UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20°F. EXTREMELY FLAMMABLE LIQUID AND VAPOR!Water spray may be ineffective. Closed containers may explode when exposed to extreme heat due to buildup of steam. Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a source of ignition and flash back. Isolate from heat, electrical equipment, sparks and open flame. Perforation of the pressurized container may cause bursting of the can. No unusual fire or explosion hazards noted. Keep containers tightly closed.

SPECIAL FIREFIGHTING PROCEDURES: Full protective equipment including self-contained breathing apparatus should be used. Evacuate area and fight fire from a safe distance. Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.

Special Fire and Explosion Hazard (Combustible Dust): No Information

6. Accidental Release Measures

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Ventilate area, isolate spilled material, and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations.

7. Handling and Storage

HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Follow all SDS and label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Contents under pressure. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of flammable aerosols. Product should be stored in tightly sealed containers and protected from heat, moisture, and foreign materials. Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep away from heat, sparks, flame and sources of ignition. Avoid excess heat.Advice on Safe Handling of Combustible Dust: No Information

Page 3 / 6


8. Exposure Controls / Personal Protection

Chemical Name CAS-No. Weight %Less Than

ACGIH TLV-TWA

ACGIH TLV-STEL

OSHA PEL-TWA

OSHA PEL-CEILING

Acetone 67-64-1 35.0 250 ppm 500 ppm 1000 ppm N.E.n-Butyl Acetate 123-86-4 25.0 50 ppm 150 ppm 150 ppm N.E.Propane 74-98-6 20.0 N.E. N.E. 1000 ppm N.E.1-Methoxy-2-Propyl Acetate 108-65-6 10.0 N.E. N.E. N.E. N.E.n-Butane 106-97-8 10.0 N.E. 1000 ppm N.E. N.E.Ethyl 3-Ethoxypropionate 763-69-9 5.0 N.E. N.E. N.E. N.E.Xylenes (o-, m-, p- isomers) 1330-20-7 5.0 100 ppm 150 ppm 100 ppm N.E.Ethylbenzene 100-41-4 1.0 20 ppm N.E. 100 ppm N.E.

PERSONAL PROTECTION

ENGINEERING CONTROLS: Use explosion-proof ventilation equipment. Provide general dilution of local exhaust ventilation in volume and pattern to keep TLV of hazardous ingredients below acceptable limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation. Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits.

RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits.

SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin protection.

EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.

OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications.

HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.

Engineering Measures for Combustible Dust: No Information

9. Physical and Chemical Properties

Appearance: Aerosolized Mist Physical State: LiquidOdor: Solvent Like Odor Threshold: N.E.Relative Density: 0.764 pH: N.A.Freeze Point, °C: ND Viscosity: N.D.Solubility in Water: Slight Partition Coefficient, n-

octanol/water: N.D.Decompostion Temp., °C: N.D.Boiling Range, °C: -37 - 375 Explosive Limits, vol%: 1.0 - 13.0Flammability: Supports Combustion Flash Point, °C: -96Evaporation Rate: Faster than Ether Auto-ignition Temp., °C: N.D.Vapor Density: Heavier than Air Vapor Pressure: N.D.

(See "Other information" Section for abbreviation legend)

10. Stability and Reactivity

CONDITIONS TO AVOID: Avoid temperatures above 120°F (49°C). Avoid all possible sources of ignition.

INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.

HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.

HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.

STABILITY: This product is stable under normal storage conditions.

11. Toxicological Information

EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation

EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation. Allergic reactions are possible.

Page 4 / 6


EFFECTS OF OVEREXPOSURE - INHALATION: High gas, vapor, mist or dust concentrations may be harmful if inhaled. High vapor concentrations are irritating to the eyes, nose, throat and lungs. Harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. Prolonged or excessive inhalation may cause respiratory tract irritation.

EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed.

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. IARC lists Ethylbenzene as a possible human carcinogen (group 2B). May cause central nervous system disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage.

PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact

ACUTE TOXICITY VALUESThe acute effects of this product have not been tested. Data on individual components are tabulated below:CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC5067-64-1 Acetone 5800 mg/kg Rat >15700 mg/kg Rabbit 50.1 mg/L Rat123-86-4 n-Butyl Acetate 10768 mg/kg Rat >17600 mg/kg Rabbit > 21 mg/L Rat108-65-6 1-Methoxy-2-Propyl Acetate 8532 mg/kg Rat >5000 mg/kg Rabbit N.E.106-97-8 n-Butane N.E. N.E. 658 mg/L Rat763-69-9 Ethyl 3-Ethoxypropionate 5000 mg/kg Rat >9500 mg/kg Rabbit >5.96 mg/L Rat1330-20-7 Xylenes (o-, m-, p- isomers) 3500 mg/kg Rat >4350 mg/kg Rabbit 29.08 mg/L Rat100-41-4 Ethylbenzene 3500 mg/kg Rat 15400 mg/kg Rabbit 17.4 mg/L Rat

N.E. - Not Established

12. Ecological Information

ECOLOGICAL INFORMATION: Product is a mixture of listed components.

13. Disposal Information

DISPOSAL INFORMATION: Do not incinerate closed containers. This product as supplied is a USEPA defined ignitable hazardous waste. Dispose of unusable product as a hazardous waste (D001) in accordance with local, state, and federal regulation.

14. Transport InformationDomestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)

UN Number: N.A. 1950 1950 N.A.

Proper Shipping Name: Paint Products inLimited Quantities Aerosols Aerosols Paint Products in

Limited Quantities

Hazard Class: N.A. 2.1 2.1 N.A.

Packing Group: N.A. N.A. N.A. N.A.

Limited Quantity: Yes Yes Yes Yes

15. Regulatory Information

U.S. Federal Regulations:CERCLA - SARA Hazard Category

This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of theSuperfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, tomeet the following categories:

Page 5 / 6


Gas under pressure, Carcinogenicity, Serious eye damage or eye irritation, Specific target organ toxicity (single or repeatedexposure)

Sara Section 313:

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of theSuperfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

Chemical Name CAS-No.Xylenes (o-, m-, p- isomers) 1330-20-7Ethylbenzene 100-41-4

Toxic Substances Control Act:This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exportedfrom the United States:

No TSCA 12(b) components exist in this product.

16. Other Information

HMIS RATINGSHealth: 2* Flammability: 4 Physical Hazard: 0 Personal Protection: X

NFPA RATINGSHealth: 2 Flammability: 4 Instability 0

Volatile Organic Compounds 613 g/L

SDS REVISION DATE: 8/6/2018

REASON FOR REVISION: Substance Hazardous Flag ChangedSubstance Hazard Threshold % ChangedSubstance and/or Product Properties Changed in Section(s): 02 - Hazard Identification 03 - Composition/Information on Ingredients 15 - Regulatory Information 16 - Other InformationRevision Statement(s) Changed

Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

The manufacturer believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. The manufacturer makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.

Page 6 / 6

SAFETY DATA SHEET

1. Identification

Knock'er Loose® Penetrating SolventProduct identifier


No. 03020 (Item# 1003270)Product code

PenetrantRecommended use

None known.Recommended restrictions

Manufacturer/Importer/Supplier/Distributor information

Manufactured or sold by:

CRC Industries, Inc.Company name

885 Louis Dr.Address

Warminster, PA 18974 US

Telephone

215-674-4300General Information

800-521-3168Technical Assistance

800-272-4620Customer Service

800-424-9300 (US)24-Hour Emergency

703-527-3887 (International)(CHEMTREC)

www.crcindustries.comWebsite

2. Hazard(s) identification

Compressed gasGases under pressurePhysical hazards

Category 2Skin corrosion/irritationHealth hazards

Category 2ASerious eye damage/eye irritation

Category 1ASensitization, skin

Category 1Aspiration hazard

Category 2Hazardous to the aquatic environment,long-term hazard


Not classified.OSHA defined hazards

Label elements

Signal word Danger

Hazard statement Contains gas under pressure; may explode if heated. May be fatal if swallowed and entersairways. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.Toxic to aquatic life with long lasting effects.

Precautionary statement

Prevention Do not puncture or incinerate container. Do not expose to heat or store at temperatures above49°C/120°F. Use with adequate ventilation. Open doors and windows or use other means toensure a fresh air supply during use and while product is drying. If you experience any symptomslisted on this label, increase ventilation or leave the area. Avoid breathing mist or vapor. Washthoroughly after handling. Contaminated work clothing must not be allowed out of the workplace.Wear protective gloves/eye protection/face protection. Avoid release to the environment.

Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Washwith plenty of water. If skin irritation or rash occurs: Get medical advice/attention. Take offcontaminated clothing and wash before reuse. If in eyes: Rinse cautiously with water for severalminutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritationpersists: Get medical advice/attention. Collect spillage.

1 / 11

Material name: Knock'er Loose® Penetrating Solvent

No. 03020 (Item# 1003270) Version #: 04 Revision date: 08-17-2017 Issue date: 11-19-2013

SDS US

Storage Store locked up. Protect from sunlight. Store in a well-ventilated place. Exposure to hightemperature may cause can to burst.

Disposal Dispose of contents/container in accordance with local/regional/national regulations.

Hazard(s) not otherwise

classified (HNOC)None known.

3. Composition/information on ingredients

Mixtures

CAS number %Chemical name Common name and synonyms

64742-46-7distillates (petroleum), hydrotreatedmiddle

40 - 50

88917-22-0dipropylene glycol monomethylether acetate

5 - 10

29911-27-1dipropylene glycol monopropylether (dpmp)

5 - 10

8006-64-2turpentine, oil 5 - 10

108-83-82,6-dimethyl-4-heptanone 3 - 5

124-38-9carbon dioxide 1 - 3

64742-47-8distillates (petroleum), hydrotreatedlight

1 - 3

64742-48-9naphtha (petroleum), hydrotreatedheavy

1 - 3

8002-09-3pine oil 1 - 3

Specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures

Move to fresh air. Call a physician if symptoms develop or persist.Inhalation

Remove contaminated clothing immediately and wash skin with soap and water. If skin irritation orrash occurs: Get medical advice/attention. Wash contaminated clothing before reuse.

Skin contact

Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.

Eye contact

Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. Ifvomiting occurs, keep head low so that stomach content doesn't get into the lungs.

Ingestion

Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms mayinclude stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause rednessand pain. May cause an allergic skin reaction. Dermatitis. Rash.

Most important

symptoms/effects, acute and

delayed

Provide general supportive measures and treat symptomatically. Keep victim under observation.Symptoms may be delayed.

Indication of immediate

medical attention and special

treatment needed

Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves. Wash contaminated clothing before reuse.

General information

5. Fire-fighting measures

Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media

None known.Unsuitable extinguishing

media

Pressurized container may rupture when exposed to heat or flame. Pressurized container mayrupture when exposed to heat or flame. During fire, gases hazardous to health may be formed.

Specific hazards arising from

the chemical

Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.

Special protective equipment

and precautions for firefighters

Fire-fighting

equipment/instructionsIn case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so withoutrisk. Containers should be cooled with water to prevent vapor pressure build up.

Contents under pressure. Pressurized container may rupture when exposed to heat or flame.General fire hazards

2 / 11



SDS US

6. Accidental release measures

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out oflow areas. Many gases are heavier than air and will spread along ground and collect in low orconfined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothingduring clean-up. Avoid breathing gas, mist or vapor. Emergency personnel need self-containedbreathing equipment. Do not touch damaged containers or spilled material unless wearingappropriate protective clothing. Ventilate closed spaces before entering them. Local authoritiesshould be advised if significant spillages cannot be contained. For personal protection, see section8 of the SDS.

Personal precautions,

protective equipment and

emergency procedures

Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keepcombustibles (wood, paper, oil, etc.) away from spilled material. Wipe up with absorbent material(e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Stop the flow ofmaterial, if this is without risk. Prevent product from entering drains. For waste disposal, seesection 13 of the SDS.

Methods and materials for

containment and cleaning up

Avoid release to the environment. Inform appropriate managerial or supervisory personnel of allenvironmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge intodrains, water courses or onto the ground.


7. Handling and storage

Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missingor defective. Do not spray on a naked flame or any other incandescent material. Do not smokewhile using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, orexpose containers to heat, flame, sparks, or other sources of ignition. Use caution aroundenergized equipment. The metal container will conduct electricity if it contacts a live source. Thismay result in injury to the user from electrical shock and/or flash fire. Avoid breathing mist orvapor. Avoid breathing gas. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure.Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash handsthoroughly after handling. Avoid release to the environment. Observe good industrial hygienepractices. For product usage instructions, see the product label.


Level 1 Aerosol.

Contents under pressure. Do not expose to heat or store at temperatures above 120°F/49°C ascan may burst. Do not puncture, incinerate or crush. Do not handle or store near an open flame,heat or other sources of ignition. Store in a well-ventilated place. Store away from incompatiblematerials (see Section 10 of the SDS).

Conditions for safe storage,

including any incompatibilities

8. Exposure controls/personal protection


US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

ValueComponents FormType

PEL 290 mg/m32,6-dimethyl-4-heptanone(CAS 108-83-8)

50 ppm

PEL 9000 mg/m3carbon dioxide (CAS124-38-9)

5000 ppm

PEL 400 mg/m3distillates (petroleum),hydrotreated light (CAS64742-47-8)

100 ppm

PEL 5 mg/m3 Mist.distillates (petroleum),hydrotreated middle (CAS64742-46-7)

400 mg/m3

100 ppm

PEL 400 mg/m3naphtha (petroleum),hydrotreated heavy (CAS64742-48-9)

100 ppm

PEL 560 mg/m3turpentine, oil (CAS8006-64-2)

100 ppm

3 / 11



SDS US

US. ACGIH Threshold Limit Values


TWA 25 ppm2,6-dimethyl-4-heptanone(CAS 108-83-8)

STEL 30000 ppmcarbon dioxide (CAS124-38-9)

TWA 5000 ppm

TWA 5 mg/m3 Inhalable fraction.distillates (petroleum),hydrotreated middle (CAS64742-46-7)

TWA 20 ppmturpentine, oil (CAS8006-64-2)

US. NIOSH: Pocket Guide to Chemical Hazards


TWA 150 mg/m32,6-dimethyl-4-heptanone(CAS 108-83-8)

25 ppm

STEL 54000 mg/m3carbon dioxide (CAS124-38-9)

30000 ppm

TWA 9000 mg/m3

5000 ppm

TWA 100 mg/m3distillates (petroleum),hydrotreated light (CAS64742-47-8)

STEL 10 mg/m3 Mist.distillates (petroleum),hydrotreated middle (CAS64742-46-7)

TWA 5 mg/m3 Mist.

TWA 400 mg/m3naphtha (petroleum),hydrotreated heavy (CAS64742-48-9)

100 ppm

TWA 560 mg/m3turpentine, oil (CAS8006-64-2)

100 ppm

No biological exposure limits noted for the ingredient(s).Biological limit values

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation ratesshould be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,or other engineering controls to maintain airborne levels below recommended exposure limits. Ifexposure limits have not been established, maintain airborne levels to an acceptable level. Provideeyewash station.

Appropriate engineering

controls

Individual protection measures, such as personal protective equipment

Wear safety glasses with side shields (or goggles).Eye/face protection

Skin protection

Wear protective gloves such as: Nitrile. Rubber.Hand protection

Wear appropriate chemical resistant clothing.Other

If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use aNIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-containedbreathing apparatus in confined spaces and for emergencies. Air monitoring is needed todetermine actual employee exposure levels.

Respiratory protection

Wear appropriate thermal protective clothing, when necessary.Thermal hazards

When using do not smoke. Always observe good personal hygiene measures, such as washingafter handling the material and before eating, drinking, and/or smoking. Routinely wash workclothing and protective equipment to remove contaminants. Contaminated work clothing should notbe allowed out of the workplace.

General hygiene

considerations

9. Physical and chemical properties

Appearance

Liquid.Physical state

4 / 11



SDS US

Aerosol.Form

Red.Color

Pleasant pine.Odor

Odor threshold Not available.

pH Not available.

Melting point/freezing point -121 °F (-85 °C) estimated

Initial boiling point and boiling

range

311 °F (155 °C) estimated

Flash point 147 °F (63.9 °C) Tag Closed Cup

Evaporation rate Moderate

Not available.Flammability (solid, gas)

Upper/lower flammability or explosive limits

Flammability limit - lower

(%)

0.7 % estimated

Flammability limit - upper

(%)

8.3 % estimated

Vapor pressure 1958.7 hPa estimated

Vapor density > 1 (air = 1)

Relative density 0.86

Solubility (water) Negligible.

Partition coefficient

(n-octanol/water)

Not available.

Auto-ignition temperature 401 °F (205 °C) estimated

Decomposition temperature Not available.

Viscosity (kinematic) Not available.

Percent volatile 98.4 % estimated

10. Stability and reactivity

The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity

Material is stable under normal conditions.Chemical stability

No dangerous reaction known under conditions of normal use.Possibility of hazardous

reactions

Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding theflash point. Contact with incompatible materials.

Conditions to avoid

Strong acids. Strong bases. Strong oxidizing agents.Incompatible materials

Aldehydes. Ketones. Organic acids. Carbon oxides.Hazardous decomposition

products

11. Toxicological information

Information on likely routes of exposure

Inhalation Prolonged inhalation may be harmful.

Skin contact Causes skin irritation. May cause an allergic skin reaction.

Eye contact Causes serious eye irritation.

Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.

Symptoms related to the

physical, chemical and

toxicological characteristics

Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms mayinclude stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause rednessand pain. May cause an allergic skin reaction. Dermatitis. Rash.


Acute toxicity May be fatal if swallowed and enters airways. May cause an allergic skin reaction.

5 / 11



SDS US

Test ResultsComponents Species

2,6-dimethyl-4-heptanone (CAS 108-83-8)

Dermal

Acute

LD50 Rabbit 16200 mg/kg

Inhalation

LC50 Rat > 5 mg/l, 4 hours

Oral

LD50 Rat 5285 mg/kg

dipropylene glycol monomethyl ether acetate (CAS 88917-22-0)

Dermal

Acute

LD50 Rabbit > 2000 mg/kg

Inhalation

LC50 Rat > 20 mg/l, 4 Hours

Oral

LD50 Rat > 5000 mg/kg

dipropylene glycol monopropyl ether (dpmp) (CAS 29911-27-1)

Dermal

Acute


5340 mg/kg

Oral


1475 mg/kg

distillates (petroleum), hydrotreated light (CAS 64742-47-8)

Dermal

Acute


distillates (petroleum), hydrotreated middle (CAS 64742-46-7)

Dermal

Acute


Oral


naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9)

Dermal

Acute


turpentine, oil (CAS 8006-64-2)

Inhalation

Acute

LC50 Rat 3590 mg/l, 1 Hours

Oral

* Estimates for product may be based on additional component data not shown.

LD50 Rat 5760 mg/kg

Causes skin irritation.Skin corrosion/irritation

Causes serious eye irritation.Serious eye damage/eye

irritation

6 / 11



SDS US

Respiratory or skin sensitization

ACGIH sensitization

TURPENTINE AND SELECTED MONOTERPENES(CAS 8006-64-2)

Dermal sensitization

Respiratory sensitization Not a respiratory sensitizer.

May cause an allergic skin reaction.Skin sensitization

No data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.

Germ cell mutagenicity

Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

IARC Monographs. Overall Evaluation of Carcinogenicity

Not listed.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not regulated.

US. National Toxicology Program (NTP) Report on Carcinogens

Not listed.

This product is not expected to cause reproductive or developmental effects.Reproductive toxicity

Specific target organ toxicity -

single exposure

Not classified.


repeated exposure

Not classified.

Aspiration hazard May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting,may cause chemical pneumonia, pulmonary injury or death.

Chronic effects Prolonged inhalation may be harmful.

12. Ecological information

Toxic to aquatic life with long lasting effects.Ecotoxicity

Components Test ResultsSpecies

dipropylene glycol monomethyl ether acetate (CAS 88917-22-0)

Aquatic

Acute

LC50Crustacea 2701 mg/l, 48 hoursWater flea (Daphnia magna)

LC50Fish 151 mg/l, 96 hoursFathead minnow (Pimephales promelas)

111 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss)

dipropylene glycol monopropyl ether (dpmp) (CAS 29911-27-1)

Aquatic

Acute

EC50Crustacea > 100 mg/l, 48 hoursWater flea (Daphnia magna)

LC50Fish > 100 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss)


Aquatic

Acute

EC50Crustacea 1.1 mg/l, 48 hoursWater flea (Daphnia magna)

LC50Fish 3 mg/l, 96 hoursFathead minnow (Pimephales promelas)


Aquatic

EC50Crustacea 2.7 - 5.1 mg/l, 48 hoursWater flea (Daphnia pulex)

LC50Fish 8.8 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss)

8.8 mg/l, 96 hours

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SDS US



Aquatic

EC50Crustacea 2.7 - 5.1 mg/l, 48 hoursWater flea (Daphnia pulex)

LC50Fish 8.8 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss)


8.8 mg/l, 96 hours

No data is available on the degradability of this product.Persistence and degradability

No data available.Bioaccumulative potential

Partition coefficient n-octanol / water (log Kow)

dipropylene glycol monomethyl ether acetate 0.61 OECD 107

dipropylene glycol monopropyl ether (dpmp) 0.87 OECD 107

0.88 OECD 107

No data available.Mobility in soil

Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

The dispensed liquid product is not a RCRA hazardous waste (See 40 CFR Part 261.20 - 261.33).Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to draininto sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or usedcontainer. Dispose in accordance with all applicable regulations.

Disposal of waste from

residues / unused products

Not regulated.Hazardous waste code

Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal.

Contaminated packaging

14. Transport information

DOT

UN1950UN number

Aerosols, non-flammable, Limited QuantityUN proper shipping name

2.2Class


-Subsidiary risk

2.2Label(s)

Not applicable.Packing group

Read safety instructions, SDS and emergency procedures before handling.Special precautions for user

306Packaging exceptions

NonePackaging non bulk

NonePackaging bulk

IATA

UN1950UN number

Aerosols, non-flammable, Limited QuantityUN proper shipping name

2.2Class


-Subsidiary risk


2LERG Code


Allowed with restrictions.Passenger and cargo

aircraft

Other information

Allowed with restrictions.Cargo aircraft only

IMDG

UN1950UN number

AEROSOLS, Limited QuantityUN proper shipping name

8 / 11



SDS US

2.2Class


-Subsidiary risk


No.Marine pollutant


F-D, S-UEmS


15. Regulatory information

This product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.

US federal regulations

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

SARA 304 Emergency release notification

Not regulated.


Not regulated.

US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance

Not listed.

CERCLA Hazardous Substance List (40 CFR 302.4)

Not listed.

CERCLA Hazardous Substances: Reportable quantity

Not listed.

Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the NationalResponse Center (800-424-8802) and to your Local Emergency Planning Committee.

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Not regulated.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Not regulated.

Not regulated.Safe Drinking Water Act

(SDWA)

FEMA Priority Substances Respiratory Health and Safety in the Flavor Manufacturing Workplace

2,6-dimethyl-4-heptanone (CAS 108-83-8) Other Flavoring Substances with OSHA PEL's

Not regulated.Food and Drug

Administration (FDA)

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Immediate Hazard - YesDelayed Hazard - NoFire Hazard - NoPressure Hazard - YesReactivity Hazard - No

Section 311/312

Hazard categories

NoSARA 302 Extremely

hazardous substance

US state regulations

US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd.

(a))



US. New Jersey Worker and Community Right-to-Know Act


carbon dioxide (CAS 124-38-9)


pine oil (CAS 8002-09-3)


US. Massachusetts RTK - Substance List


9 / 11



SDS US




US. Pennsylvania Worker and Community Right-to-Know Law




US. Rhode Island RTK





US. California Proposition 65

WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or otherreproductive harm.

US - California Proposition 65 - CRT: Listed date/Carcinogenic substance

benzene (CAS 71-43-2) Listed: February 27, 1987

ethylbenzene (CAS 100-41-4) Listed: June 11, 2004

naphthalene (CAS 91-20-3) Listed: April 19, 2002

US - California Proposition 65 - CRT: Listed date/Developmental toxin

benzene (CAS 71-43-2) Listed: December 26, 1997

toluene (CAS 108-88-3) Listed: January 1, 1991

US - California Proposition 65 - CRT: Listed date/Male reproductive toxin

benzene (CAS 71-43-2) Listed: December 26, 1997

Volatile organic compounds (VOC) regulations

EPA

VOC content (40 CFR

51.100(s))

98.4 %

Not regulatedConsumer products

(40 CFR 59, Subpt. C)

State

This product is regulated as a Penetrant. This product is compliant for use in all 50 states.Consumer products

VOC content (CA) 23.6 %

VOC content (OTC) 23.6 %

International Inventories

Country(s) or region Inventory name On inventory (yes/no)*

NoAustralia Australian Inventory of Chemical Substances (AICS)

YesCanada Domestic Substances List (DSL)

NoCanada Non-Domestic Substances List (NDSL)

NoChina Inventory of Existing Chemical Substances in China (IECSC)

NoEurope European Inventory of Existing Commercial ChemicalSubstances (EINECS)

NoEurope European List of Notified Chemical Substances (ELINCS)

NoJapan Inventory of Existing and New Chemical Substances (ENCS)

NoKorea Existing Chemicals List (ECL)

NoNew Zealand New Zealand Inventory

NoPhilippines Philippine Inventory of Chemicals and Chemical Substances(PICCS)

YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).

16. Other information, including date of preparation or last revision

11-19-2013Issue date

08-17-2017Revision date

Allison YoonPrepared by

10 / 11



SDS US

Version # 04

CRC # 548A/1002565Further information

Health: 1Flammability: 1Physical hazard: 0Personal protection: B

HMIS® ratings

Health: 1Flammability: 1Instability: 0

NFPA ratings

NFPA ratings

01

1

The information contained in this document applies to this specific material as supplied. It may notbe valid for this material if it is used in combination with any other materials. This information isaccurate to the best of CRC's knowledge or obtained from sources believed by CRC to beaccurate. Before using any product, read all warnings and directions on the label. For furtherclarification of any information contained on this (M)SDS consult your supervisor, a health & safetyprofessional, or CRC Industries, Inc..

Disclaimer

Product and Company Identification: Product CodesHazard(s) identification: PreventionHazard(s) identification: ResponseHazard(s) identification: Supplemental label informationComposition/information on ingredients: Component informationHandling and storage: Precautions for safe handlingPhysical & Chemical Properties: Multiple PropertiesToxicological Information: Toxicological DataEcological Information: EcotoxicityTransport Information: Material Transportation InformationTransport information: General informationOther information, including date of preparation or last revision: DisclaimerOther information, including date of preparation or last revision: Further informationGHS: Classification

Revision Information

11 / 11



SDS US

Safety Data SheetAccording to OSHA HCS 2012 (29 CFR 1910.1200), Health Canada HPR

(SOR/2015-17), and Mexico NOM-018-STPS-2015

SECTION 1: IdentificationProduct Identifier Echo Power Blend XCode 829445Relevant identified uses 2-Cycle Engine OilUses advised against All others24 Hour Emergency Phone Number CHEMTREC 1-800-424-9300

CHEMTREC México 01-800-681-9531

SECTION 2: Hazard identification

SECTION 4: First aid measures

Manufacturer/SupplierPhillips 66 Spectrum Corporation500 Industrial Park DriveSelmer, TN 38375-3276United States of America

SDS InformationURL: www.Phillips66.comPhone: 800-762-0942Email: [email protected]

Technical Information1-800-264-6457 or +1-731-645-4972

Classified Hazards Hazards Not Otherwise Classified (HNOC)

H227 - Flammable liquids -- Category 4H315 -- Skin corrosion/irritation -- Category 2H412 -- Hazardous to the aquatic environment, chronic toxicity -- Category 3

PHNOC: None known

HHNOC: None known

Label Elements

SECTION 3: Composition/information on ingredients

Chemical Name CASRN Concentration¹Distillates, petroleum, solvent-dewaxed heavy paraffinic 64742-65-0 25-50Petroleum distillates, hydrotreated light 64742-47-8 10-<20Distillates, petroleum, hydrotreated heavy paraffinic 64742-54-7 <5Distillates, petroleum, solvent-refined heavy paraffinic 64741-88-4 <3

¹ All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

WARNINGCombustible liquidCauses skin irritationHarmful to aquatic life with long lasting effects

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _829445 - Echo Power Blend X Page 1/7Issue Date: 24-Apr-2017 Status: FINAL

Keep away from heat/sparks/open flames/hot surfaces. - No smoking; Wash skin thoroughly after handling; Avoid release to theenvironment; Wear protective gloves/protective clothing and eye/face protection; IF ON SKIN: Wash with plenty of soap and water;If skin irritation occurs: Get medical advice/attention; Take off contaminated clothing and wash before reuse; In case of fire: UseCO2, dry chemical, or foam for extinction; Store in a well-ventilated place. Keep cool; Dispose of contents/container to an approvedwaste disposal plant

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

829445 - Echo Power Blend X Page 2/7Issue Date: 24-Apr-2017 Status: FINAL

Eye Contact: If irritation or redness develops from exposure, flush eyes with clean water. If symptoms persist, seek medicalattention.

Skin Contact: Remove contaminated shoes and clothing, and flush affected area(s) with large amounts of water. If skin surface isdamaged, apply a clean dressing and seek medical attention. If skin surface is not damaged, cleanse affected area(s) thoroughlyby washing with mild soap and water or a waterless hand cleaner. If irritation or redness develops, seek medical attention. Washcontaminated clothing before reuse. Remove contaminated shoes and clothing and cleanse affected area(s) thoroughly by washingwith mild soap and water or a waterless hand cleaner. If irritation or redness develops and persists, seek medical attention.

Inhalation: First aid is not normally required. If breathing difficulties develop, move victim away from source of exposure and intofresh air in a position comfortable for breathing. Seek immediate medical attention.

Ingestion: First aid is not normally required; however, if swallowed and symptoms develop, seek medical attention.

Most important symptoms and effects, both acute and delayed: While significant vapor concentrations are not likely, highconcentrations can cause minor respiratory irritation, headache, drowsiness, dizziness, loss of coordination, disorientation andfatigue. Ingestion can cause irritation of the digestive tract, nausea, diarrhea, and vomiting. Prolonged or repeated contact may dryskin and cause irritation

Notes to Physician: Acute aspirations of large amounts of oil-laden material may produce a serious aspiration pneumonia.Patients who aspirate these oils should be followed for the development of long-term sequelae. Inhalation exposure to oil mistsbelow current workplace exposure limits is unlikely to cause pulmonary abnormalities.

SECTION 5: Firefighting measures

NFPA 704 Hazard Class

Extinguishing Media: Dry chemical, carbon dioxide, foam, or water spray is recommended. Water or foam may cause frothing ofmaterials heated above 212°F / 100°C. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide inconfined spaces. Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam.


Unusual Fire & Explosion Hazards: Combustible. This material can be ignited by heat, sparks, flames, or other sources ofignition (e.g., static electricity, pilot lights, or mechanical/electrical equipment). May create vapor/air explosion hazard if heated.This product will float and can be reignited on surface water. Vapors are heavier than air and can accumulate in low areas. Ifcontainer is not properly cooled, it can rupture in the heat of a fire.

Hazardous Combustion Products: Combustion may yield smoke, carbon monoxide, and other products of incompletecombustion. Oxides of sulfur, nitrogen or phosphorus may also be formed.

Special protective actions for fire-fighters: For fires beyond the initial stage, emergency responders in the immediate hazardarea should wear protective clothing. When the potential chemical hazard is unknown, in enclosed or confined spaces, a selfcontained breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions warrant(see Section 8). Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Stop spill/release if it can bedone safely. Move undamaged containers from immediate hazard area if it can be done safely. Water spray may be useful inminimizing or dispersing vapors and to protect personnel. Cool equipment exposed to fire with water, if it can be done safely. Avoidspreading burning liquid with water used for cooling purposes.

See Section 9 for Flammable Properties including Flash Point and Flammable (Explosive) Limits

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures: Combustible. Keep all sources of ignition away fromspill/release. The use of explosion-proof electrical equipment is recommended. Stay upwind and away from spill/release. Avoiddirect contact with material. For large spillages, notify persons down wind of the spill/release, isolate immediate hazard area and

Health: 1 Flammability: 2 Instability: 0 0 (Minimal)1 (Slight)2 (Moderate)3 (Serious)4 (Severe)

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _


keep unauthorized personnel out. Wear appropriate protective equipment, including respiratory protection, as conditions warrant(see Section 8). See Sections 2 and 7 for additional information on hazards and precautionary measures.

Environmental Precautions: Stop and contain spill/release if it can be done safely. Prevent spilled material from entering sewers,storm drains, other unauthorized drainage systems, and natural waterways. Use water sparingly to minimize environmentalcontamination and reduce disposal requirements. If spill occurs on water notify appropriate authorities and advise shipping of anyhazard. Spills into or upon navigable waters, the contiguous zone, or adjoining shorelines that cause a sheen or discoloration onthe surface of the water, may require notification of the National Response Center (phone number 800-424-8802).

Methods and material for containment and cleaning up: Notify relevant authorities in accordance with all applicableregulations. Immediate cleanup of any spill is recommended. Dike far ahead of spill for later recovery or disposal. Absorb spill withinert material such as sand or vermiculite, and place in suitable container for disposal. If spilled on water remove with appropriatemethods (e.g. skimming, booms or absorbents). In case of soil contamination, remove contaminated soil for remediation ordisposal, in accordance with local regulations.

Recommended measures are based on the most likely spillage scenarios for this material; however local conditions andregulations may influence or limit the choice of appropriate actions to be taken. See Section 13 for information on appropriatedisposal.

SECTION 7: Handling and storage

Precautions for safe handling: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.Use only non-sparking tools. Take precautionary measures against static discharge. Wash thoroughly after handling. Wearprotective gloves/protective clothing/eye protection/face protection. Use good personal hygiene practices and wear appropriatepersonal protective equipment (see section 8). Spills will produce very slippery surfaces. Open container slowly to relieve anypressure. Electrostatic charge may accumulate and create a hazardous condition when handling or processing this material. Toavoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment beforetransferring material. The use of explosion-proof electrical equipment is recommended and may be required (see appropriate firecodes). Refer to NFPA-70 and/or API RP 2003 for specific bonding/grounding requirements. Do not enter confined spaces such astanks or pits without following proper entry procedures such as ASTM D-4276 and 29CFR 1910.146. Do not wear contaminatedclothing or shoes. Keep contaminated clothing away from sources of ignition such as sparks or open flames.

Conditions for safe storage: Keep container(s) tightly closed and properly labeled. Use and store this material in cool, dry,well-ventilated area away from heat and all sources of ignition. Post area "No Smoking or Open Flame." Store only in approvedcontainers. Keep away from any incompatible material (see Section 10). Protect container(s) against physical damage. Outdoor ordetached storage is preferred. Indoor storage should meet OSHA standards and appropriate fire codes.

"Empty" containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose suchcontainers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury or death. "Empty" drums shouldbe completely drained, properly bunged, and promptly shipped to the supplier or a drum reconditioner. All containers should bedisposed of in an environmentally safe manner and in accordance with governmental regulations. Before working on or in tankswhich contain or have contained this material, refer to OSHA regulations, ANSI Z49.1, and other references pertaining to cleaning,repairing, welding, or other contemplated operations.

SECTION 8: Exposure controls/personal protection

Chemical Name ACGIH OSHA Mexico Phillips 66Distillates, petroleum,solvent-dewaxed heavyparaffinic

TWA: 5mg/m3

STEL: 10 mg/m3

as Oil Mist, if Generated

--- --- ---

Petroleum distillates,hydrotreated light

--- --- --- TWA: 200 mg/m3 (28 ppm)(8hr)

TWA: 100 mg/m3 (14 ppm)(12hr)Skin

Distillates, petroleum,hydrotreated heavyparaffinic

TWA: 5mg/m3

STEL: 10 mg/m3


--- --- ---

Distillates, petroleum,solvent-refined heavyparaffinic

TWA: 5mg/m3

STEL: 10 mg/m3


--- --- ---

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _


Note: State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrialhygienist or similar professional, or your local agencies, for further information.

Engineering controls: If current ventilation practices are not adequate to maintain airborne concentrations below the establishedexposure limits, additional engineering controls may be required.

Eye/Face Protection: The use of eye protection that meets or exceeds ANSI Z.87.1 is recommended to protect against potentialeye contact, irritation, or injury. Depending on conditions of use, a face shield may be necessary.

Skin/Hand Protection: The use of gloves impervious to the specific material handled is advised to prevent skin contact. Usersshould check with manufacturers to confirm the breakthrough performance of their products. Suggested protective materials:Depending on exposure and use conditions, additional protection may be necessary to prevent skin contact including use of itemssuch as chemical resistant boots, aprons, arm covers, hoods, coveralls, or encapsulated suits. Nitrile

Respiratory Protection: Where there is potential for airborne exposure above the exposure limit a NIOSH certified air purifyingrespirator equipped with organic vapor cartridges/canisters with R or P95 filters may be used.

A respiratory protection program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followedwhenever workplace conditions warrant a respirator's use. Air purifying respirators provide limited protection and cannot be used inatmospheres that exceed the maximum use concentration (as directed by regulation or the manufacturer's instructions), in oxygendeficient (less than 19.5 percent oxygen) situations, or under conditions that are immediately dangerous to life and health (IDLH).

Other Protective Equipment: Eye wash and quick-drench shower facilities should be available in the work area. Thoroughlyclean shoes and wash contaminated clothing before reuse.

Suggestions provided in this section for exposure control and specific types of protective equipment are based on readilyavailable information. Users should consult with the specific manufacturer to confirm the performance of their protectiveequipment. Specific situations may require consultation with industrial hygiene, safety, or engineering professionals.

SECTION 9: Physical and chemical properties Note: Unless otherwise stated, values are determined at 20°C (68°F) and 760 mm Hg (1 atm). Data represent typical values and are not intendedto be specifications.

SECTION 10: Stability and reactivity

Reactivity: Not chemically reactive.

Chemical stability: Stable under normal ambient and anticipated conditions of use.

Possibility of hazardous reactions: Hazardous reactions not anticipated.

Conditions to avoid: Extended exposure to high temperatures can cause decomposition. Avoid all possible sources of ignition.

Incompatible materials: Avoid contact with strong oxidizing agents and strong reducing agents.

Hazardous decomposition products: Not anticipated under normal conditions of use.

SECTION 11: Toxicological information

Information on Toxicological Effects

Appearance: Greenish blue Flash Point: 154.4 °F / 68 °CPhysical Form: Liquid Test Method: Pensky-Martens Closed Cup (PMCC), ASTM D93, EPA 1010Odor: Petroleum Initial Boiling Point/Range: No dataOdor Threshold: No data Vapor Pressure: <1 mm HgpH: Not applicable Partition Coefficient (n-octanol/water) (Kow): No dataVapor Density (air=1): >1 Melting/Freezing Point: No dataUpper Explosive Limits (vol % in air): No data Auto-ignition Temperature: No dataLower Explosive Limits (vol % in air): No data Decomposition Temperature: No dataEvaporation Rate (nBuAc=1): No data Specific Gravity (water=1): 0.87 @ 60ºF (15.6ºC)Particle Size: Not applicable Bulk Density: 7.25 lbs/galPercent Volatile: No data Viscosity: 77 cSt @ 40°CFlammability (solid, gas): Not applicable Solubility in Water: Insoluble

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _


Substance / Mixture

Aspiration Hazard: Not expected to be an aspiration hazard

Skin Corrosion/Irritation: Causes skin irritation. Repeated exposure may cause skin dryness or cracking.

Serious Eye Damage/Irritation: Causes mild eye irritation.

Skin Sensitization: No information available on the mixture, however none of the components have been classified for skinsensitization (or are below the concentration threshold for classification). Based on component information

Respiratory Sensitization: No information available. Based on component information

Specific Target Organ Toxicity (Single Exposure): Not expected to cause organ effects from single exposure. Based oncomponent information

Specific Target Organ Toxicity (Repeated Exposure): Not expected to cause organ effects from repeated exposure.

Carcinogenicity: Not expected to cause cancer.

Germ Cell Mutagenicity: Not expected to cause heritable genetic effects.

Reproductive Toxicity: Not expected to cause reproductive toxicity.

Information on Toxicological Effects of ComponentsLubricant Base Oil (Petroleum) Carcinogenicity: The petroleum base oils contained in this product have been highly refined by a variety of processesincluding severe hydrocracking/hydroprocessing to reduce aromatics and improve performance characteristics. All of the oilsmeet the IP-346 criteria of less than 3 percent PAH's and are not considered carcinogens by NTP, IARC, or OSHA.

SECTION 12: Ecological information

Toxicity: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment

Persistence and Degradability: The hydrocarbons in this material are not readily biodegradable, but since they can be degradedby microorganisms, they are regarded as inherently biodegradable.

Bioaccumulative Potential: Log Kow values measured for the hydrocarbon components of this material are greater than 5.3, andtherefore regarded as having the potential to bioaccumulate. In practice, metabolic processes may reduce bioconcentration.

Mobility in Soil: Volatilization to air is not expected to be a significant fate process due to the low vapor pressure of this material.In water, base oils will float and spread over the surface at a rate dependent upon viscosity. There will be significant removal ofhydrocarbons from the water by sediment adsorption. In soil and sediment, hydrocarbon components will show low mobility withadsorption to sediments being the predominant physical process. The main fate process is expected to be slow biodegradation ofthe hydrocarbon constituents in soil and sediment.

Other adverse effects: None anticipated.

SECTION 13: Disposal considerations

The generator of a waste is always responsible for making proper hazardous waste determinations and needs to consider state

Acute Toxicity Hazard Additional Information LC50/LD50 Data

Inhalation Unlikely to be harmful >5 mg/L (mist, estimated)

Dermal Unlikely to be harmful > 2 g/kg (estimated)

Oral Unlikely to be harmful > 5 g/kg (estimated)

GHS Classification: H412 -- Hazardous to the aquatic environment, chronic toxicity -- Category 3Harmful to aquatic life with long lasting effects.

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _


and local requirements in addition to federal regulations. This material, if discarded as produced, would not be a federallyregulated RCRA "listed" hazardous waste and is not believed to exhibit characteristics of hazardous waste. See Sections 7 and 8for information on handling, storage and personal protection and Section 9 for physical/chemical properties. It is possible that thematerial as produced contains constituents which are not required to be listed in the SDS but could affect the hazardous wastedetermination. Additionally, use which results in chemical or physical change of this material could subject it to regulation as ahazardous waste.This material under most intended uses would become "Used Oil" due to contamination by physical or chemicalimpurities. Whenever possible, Recycle used oil in accordance with applicable federal and state or local regulations. Containercontents should be completely used and containers should be emptied prior to discard.

SECTION 14: Transport information

U.S. Department of Transportation (DOT) UN Number: Not regulatedUN proper shipping name: NoneTransport hazard class(es): NonePacking Group: NoneEnvironmental Hazards: This product does not meet the DOT/UN/IMDG/IMO criteria of a marine pollutantSpecial precautions for user: If shipped by land in a packaging having a capacity of 3,500 gallons or more, the provisions of 49CFR, Part 130 apply. (Contains oil)Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable

SECTION 15: Regulatory information

CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs (in pounds)This material does not contain any chemicals subject to the reporting requirements of SARA 302 and 40 CFR 372.

CERCLA/SARA - Section 311/312 (Title III Hazard Categories)US EPA has published a final rule aligning hazardous chemical reporting under sections 311 and 312 of the Emergency Planningand Community Right-to-Know Act (EPCRA) with OSHA HCS. See Section 2 for hazard classifications under EPCRA.

CERCLA/SARA - Section 313 and 40 CFR 372This material does not contain any chemicals subject to the reporting requirements of SARA 313 and 40 CFR 372.

EPA (CERCLA) Reportable Quantity (in pounds)This material contains the following chemicals subject to the reporting requirements of 40 CFR 302.4:

California Proposition 65This material does not contain any chemicals which are known to the State of California to cause cancer, birth defects or otherreproductive harm at concentrations that trigger the warning requirements of California Proposition 65. Ethylbenzene (CASRN100-41-4)

International InventoriesAll components are either listed on the US TSCA Inventory, or are not regulated under TSCA.All components are either on the DSL, or are exempt from DSL listing requirements.

SECTION 16: Other information

Legend (pursuant to NOM-018-STPS-2015):The information within is considered correct but is not exhaustive and will be used for guidance only, which is based on the current knowledge ofthe substance or mixture and is applicable to the appropriate safety precautions for the product.

Precautionary Statements:P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking

Revised Sections or Basis for Revision:New SDS

Issue Date: Previous Issue Date: SDS Number Status:

24-Apr-2017 31-Jul-2015 829445 FINAL

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _


P264 - Wash skin thoroughly after handlingP273 - Avoid release to the environmentP280 - Wear protective gloves/protective clothing/eye protection/face protectionP302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP332 + P313 - If skin irritation occurs: Get medical advice/attentionP362 - Take off contaminated clothing and wash before reuseP370 + P378 - In case of fire: Use dry chemical, carbon dioxide, or foam to extinguishP403 + P235 - Store in a well-ventilated place. Keep coolP501 - Dispose of contents/ container to an approved waste disposal plant

Guide to Abbreviations:ACGIH = American Conference of Governmental Industrial Hygienists; CASRN = Chemical Abstracts Service Registry Number; CEILING = CeilingLimit (15 minutes); CERCLA = The Comprehensive Environmental Response, Compensation, and Liability Act; EPA = Environmental ProtectionAgency; GHS = Globally Harmonized System; HPR = Hazardous Products Regulations; IARC = International Agency for Research on Cancer;INSHT = National Institute for Health and Safety at Work; IOPC = International Oil Pollution Compensation; LEL = Lower Explosive Limit; NE = NotEstablished; NFPA = National Fire Protection Association; NTP = National Toxicology Program; OSHA = Occupational Safety and HealthAdministration; PEL = Permissible Exposure Limit (OSHA); SARA = Superfund Amendments and Reauthorization Act; STEL = Short TermExposure Limit (15 minutes); TLV = Threshold Limit Value (ACGIH); TWA = Time Weighted Average (8 hours); UEL = Upper Explosive Limit;WHMIS = Worker Hazardous Materials Information System (Canada)

Disclaimer of Expressed and implied Warranties:The information presented in this Safety Data Sheet is based on data believed to be accurate as of the date this Safety Data Sheet was prepared.HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY ISEXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED ABOVE, THERESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THEHAZARDS RELATED TO ITS USE. No responsibility is assumed for any damage or injury resulting from abnormal use or from any failure toadhere to recommended practices. The information provided above, and the product, are furnished on the condition that the person receiving themshall make their own determination as to the suitability of the product for their particular purpose and on the condition that they assume the risk oftheir use. In addition, no authorization is given nor implied to practice any patented invention without a license.

FS-ONE MAX; CFS-FIL

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Date of issue: 07/04/2017 Revision date: 07/04/2017 Supersedes: 12/17/2015 Version: 1.3

05/07/2017 US-OSHA - en 1/7

SECTION 1: Identification

1.1. Identification

Product form Mixture

Name FS-ONE MAX; CFS-FIL

Product code BU Fire Protection

Chemical structure

1.2. Relevant identified uses of the substance or mixture and uses advised against

No additional information available

1.3. Details of the supplier of the safety data sheet

Hilti, Inc. Legacy Tower, Suite 1000 75024 Plano - USA T +1 9724035800 1-800-879-8000 toll free - F +1 918 254 0522

Supplier Hilti, Inc. Legacy Tower, Suite 1000 75024 Plano - USA T +1 9724035800 1-800-879-8000 toll free - F +1 918 254 0522

Department issuing data specification sheet Hilti AG Feldkircherstraße 100 9494 Schaan - Liechtenstein T +423 234 2111 [email protected]

1.4. Emergency telephone number

Emergency number Chem-Trec Tel.: 1 800 424 9300 (USA, PR, Virgin Islands, Canada) Tel.: 703 527 3887 (Other countries)

+1 918 8723000 1-800-879-8000 toll free

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

GHS-US classification

Not classified

2.2. Label elements

GHS-US labelling

No labelling applicable

2.3. Other hazards


2.4. Unknown acute toxicity (GHS US)

Not applicable

mailto:[email protected]

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SECTION 3: Composition/information on ingredients

3.1. Substance

Not applicable

3.2. Mixture

Name Product identifier % GHS-US classification

Quartz (CAS No) 14808-60-7 2.5 - 5 Carc. 1A, H350

Full text of H-statements: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures after inhalation Get medical advice/attention if you feel unwell.

First-aid measures after skin contact Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention.

First-aid measures after eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

First-aid measures after ingestion Get medical advice/attention if you feel unwell.

4.2. Most important symptoms and effects, both acute and delayed


4.3. Indication of any immediate medical attention and special treatment needed


SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Water spray. Dry powder. Foam. Carbon dioxide.

5.2. Special hazards arising from the substance or mixture

Reactivity The product is non-reactive under normal conditions of use, storage and transport.

5.3. Advice for firefighters

Protection during firefighting Self-contained breathing apparatus. Complete protective clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel


6.1.2. For emergency responders

Protective equipment For further information refer to section 8: "Exposure controls/personal protection".

6.2. Environmental precautions


6.3. Methods and material for containment and cleaning up

Methods for cleaning up Mechanically recover the product.

6.4. Reference to other sections

For further information refer to section 13.

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SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling Wear personal protective equipment.

Hygiene measures Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions Keep cool. Store in a dry place.

Storage temperature 41 - 77 °F

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Quartz (14808-60-7)

OSHA Remark (OSHA) (3) See Table Z-3.

Additional information The product has a pasty consistency. Exposure limit values for respirable dusts are not relevant for this product

8.2. Exposure controls

Personal protective equipment Protective clothing. Safety glasses. Gloves.

Hand protection Protective gloves. EN 374.

Eye protection Chemical goggles or safety glasses.

Skin and body protection Wear suitable protective clothing.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state Liquid

Appearance Pasty.

Colour red

Odour characteristic

Odour threshold Not determined

pH ≈ 7.85

Melting point Not applicable

Freezing point No data available

Boiling point No data available

Flash point Not applicable

Relative evaporation rate (butylacetate=1) No data available

Flammability (solid, gas) No data available

Explosive limits No data available

Explosive properties No data available

Oxidising properties No data available

Vapour pressure No data available

Relative density No data available

Relative vapour density at 20 °C No data available

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Density ≈ 1.35 g/cm³ Molecular mass Not determined

Solubility No data available

Log Pow No data available

Auto-ignition temperature No data available

Decomposition temperature No data available

Viscosity No data available

Viscosity, kinematic No data available

Viscosity, dynamic No data available

9.2. Other information

VOC content 9 g/l

SECTION 10: Stability and reactivity

10.1. Reactivity

The product is non-reactive under normal conditions of use, storage and transport.

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

No dangerous reactions known under normal conditions of use.

10.4. Conditions to avoid

None under recommended storage and handling conditions (see section 7).

10.5. Incompatible materials


10.6. Hazardous decomposition products


SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity Not classified

Skin corrosion/irritation Not classified

pH: ≈ 7.85

Serious eye damage/irritation Not classified

pH: ≈ 7.85

Respiratory or skin sensitisation Not classified

Germ cell mutagenicity Not classified

Carcinogenicity Not classified

Quartz (14808-60-7)

IARC group 1 - Carcinogenic to humans

Reproductive toxicity Not classified

Specific target organ toxicity (single exposure) Not classified


Not classified

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Aspiration hazard Not classified

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment.

12.2. Persistence and degradability


12.3. Bioaccumulative potential


12.4. Mobility in soil


12.5. Other adverse effects

Effect on the global warming No known effects from this product.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste treatment methods Dispose of contents/container in accordance with licensed collector’s sorting instructions. Waste disposal recommendations Dispose in a safe manner in accordance with local/national regulations.

SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN

ADR IMDG IATA RID

14.1. UN number Not regulated for transport

14.2. UN proper shipping name Not applicable Not applicable Not applicable Not applicable

14.3. Transport hazard class(es) Not applicable Not applicable Not applicable Not applicable

Not applicable Not applicable Not applicable Not applicable

14.4. Packing group Not applicable Not applicable

Not applicable Not applicable

14.5. Environmental hazards Dangerous for the environment : No

Dangerous for the environment : No Marine pollutant : No

Dangerous for the environment : No

Dangerous for the environment : No

No supplementary information available

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14.6. Special precautions for user

- Overland transport

- Transport by sea

No data available

- Air transport

No data available

- Rail transport

Carriage prohibited (RID) No

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

SECTION 15: Regulatory information

15.1. US Federal regulations

All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory

15.2. International regulations

CANADA

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WHMIS Classification Uncontrolled product according to WHMIS classification criteria

EU-Regulations No additional information available

Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified

National regulations

Quartz (14808-60-7)

Listed on IARC (International Agency for Research on Cancer)

15.3. US State regulations

California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm

SECTION 16: Other information

Revision date 07/04/2017

Full text of H-statements:

------ H350 May cause cancer

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NFPA health hazard 0 - Materials that, under emergency conditions, would offer no hazard beyond that of ordinary combustible materials.

NFPA fire hazard 0 - Materials that will not burn under typical dire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand.

NFPA reactivity 0 - Material that in themselves are normally stable, even under fire conditions.

Hazard Rating

Health 0 Minimal Hazard - No significant risk to health

Flammability 0 Minimal Hazard - Materials that will not burn

Physical 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives.

Personal protection B

B - Safety glasses, Gloves

SDS_US_Hilti

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product

® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated company of Dow

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SAFETY DATA SHEET THE DOW CHEMICAL COMPANY

Product name: GREAT STUFF PRO™ Gaps & Cracks Insulating Foam Sealant 24oz HC EF RU 12ct

Issue Date: 01/04/2016

Print Date: 06/10/2016

THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions.

1. IDENTIFICATION

Product name: GREAT STUFF PRO™ Gaps & Cracks Insulating Foam Sealant 24oz HC EF RU 12ct Recommended use of the chemical and restrictions on use Identified uses: Polyurethane foam. COMPANY IDENTIFICATION THE DOW CHEMICAL COMPANY 2030 WILLARD H DOW CENTER MIDLAND MI 48674-0000 UNITED STATES Customer Information Number: 800-258-2436

[email protected] EMERGENCY TELEPHONE NUMBER 24-Hour Emergency Contact: CHEMTREC +1 800-424-9300 Local Emergency Contact: 800-424-9300

2. HAZARDS IDENTIFICATION

Hazard classification This material is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200. Flammable aerosols - Category 2 Gases under pressure - Liquefied gas Acute toxicity - Category 4 - Inhalation Skin irritation - Category 2 Eye irritation - Category 2A Respiratory sensitisation - Category 1 Skin sensitisation - Category 1 Effects on or via lactation Specific target organ toxicity - single exposure - Category 3 Specific target organ toxicity - repeated exposure - Category 2 - Inhalation Label elements Hazard pictograms



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Signal word: DANGER! Hazards Flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause harm to breast-fed children. May cause damage to organs (Respiratory Tract) through prolonged or repeated exposure if inhaled. Precautionary statements

Prevention Obtain special instructions before use. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Avoid contact during pregnancy/ while nursing. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/ eye protection/ face protection. In case of inadequate ventilation wear respiratory protection. Response IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/ attention. If skin irritation or rash occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Take off contaminated clothing and wash before reuse. Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F.



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Disposal Dispose of contents/ container to an approved waste disposal plant.

Other hazards Water Reactive

3. COMPOSITION/INFORMATION ON INGREDIENTS

This product is a mixture.

Component CASRN Concentration

Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer

57029-46-6 >= 30.0 - <= 60.0 %

Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol copolymer

53862-89-8 >= 5.0 - <= 10.0 %

Diphenylmethane Diisocyanate, isomers and homologues

9016-87-9 >= 10.0 - <= 30.0 %

Paraffin waxes and Hydrocarbon waxes, chlorinated

63449-39-8 >= 5.0 - <= 10.0 %

Isobutane 75-28-5 >= 3.0 - <= 7.0 % Propane 74-98-6 >= 1.0 - <= 5.0 % Methyl ether 115-10-6 >= 1.0 - <= 5.0 % 4,4' -Methylenediphenyl diisocyanate 101-68-8 >= 7.0 - <= 13.0 % N,N'-Dimorpholinodiethylether 6425-39-4 >= 0.5 - <= 5.0 % Note Note: CAS 101-68-8 is an MDI isomer that is part of CAS 9016-87-9.

4. FIRST AID MEASURES

Description of first aid measures General advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specific personal protective equipment. Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility.



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Skin contact: Remove material from skin immediately by washing with soap and plenty of water. Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists. Wash clothing before reuse. An MDI skin decontamination study demonstrated that cleaning very soon after exposure is important, and that a polyglycol-based skin cleanser or corn oil may be more effective than soap and water. Discard items which cannot be decontaminated, including leather articles such as shoes, belts and watchbands. Suitable emergency safety shower facility should be available in work area. Eye contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5 minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately available. Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel. Most important symptoms and effects, both acute and delayed: Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), any additional important symptoms and effects are described in Section 11: Toxicology Information. Indication of any immediate medical attention and special treatment needed Notes to physician: Excessive exposure may aggravate preexisting asthma and other respiratory disorders (e.g. emphysema, bronchitis, reactive airways dysfunction syndrome). Repeated excessive exposure may aggravate preexisting lung disease. Maintain adequate ventilation and oxygenation of the patient. May cause respiratory sensitization or asthma-like symptoms. Bronchodilators, expectorants and antitussives may be of help. Treat bronchospasm with inhaled beta2 agonist and oral or parenteral corticosteroids. Respiratory symptoms, including pulmonary edema, may be delayed. Persons receiving significant exposure should be observed 24-48 hours for signs of respiratory distress. Exposure may increase "myocardial irritability". Do not administer sympathomimetic drugs such as epinephrine unless absolutely necessary. If you are sensitized to diisocyanates, consult your physician regarding working with other respiratory irritants or sensitizers. Although cholinesterase depression has been reported with this material, it is not of benefit in determining exposure and need not be considered in the treatment of persons exposed to the material. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.

5. FIREFIGHTING MEASURES

Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective. Unsuitable extinguishing media: Do not use direct water stream. Straight or direct water streams may not be effective to extinguish fire. Special hazards arising from the substance or mixture Hazardous combustion products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Nitrogen oxides. Isocyanates. Hydrogen chloride. Carbon monoxide. Carbon dioxide. Hydrogen cyanide.



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Unusual Fire and Explosion Hazards: Contains flammable propellant. Aerosol cans exposed to fire can rupture and become flaming projectiles. Propellant release may result in a fireball. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Dense smoke is produced when product burns. Advice for firefighters Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay upwind. Keep out of low areas where gases (fumes) can accumulate. Water may not be effective in extinguishing fire. Do not use direct water stream. May spread fire. Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Eliminate ignition sources. Move container from fire area if this is possible without hazard. Use water spray to cool fire-exposed containers and fire-affected zone until fire is out. Special protective equipment for firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer to the relevant sections.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures: Evacuate area. Only trained and properly protected personnel must be involved in clean-up operations. Keep personnel out of low areas. Keep personnel out of confined or poorly ventilated areas. Keep upwind of spill. Ventilate area of leak or spill. No smoking in area. For large spills, warn public of downwind explosion hazard. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Vapor explosion hazard. Keep out of sewers. See Section 10 for more specific information. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection. Refer to section 7, Handling, for additional precautionary measures. Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. Methods and materials for containment and cleaning up: Contain spilled material if possible. Ground and bond all containers and handling equipment. Isolate area until gas has dispersed. Use non-sparking tools in cleanup operations. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Collect in suitable and properly labeled containers. Absorb with materials such as: Clay. Dirt. Milsorb®. Sand. Sawdust. Vermiculite. See Section 10 for more specific information. See Section 13, Disposal Considerations, for additional information.

7. HANDLING AND STORAGE

Precautions for safe handling: Keep away from heat, sparks and flame. Avoid contact with eyes. Avoid contact with skin and clothing. Avoid prolonged or repeated contact with skin. Avoid breathing



Page 6 of 18

vapor. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. Keep out of reach of children. No smoking, open flames or sources of ignition in handling and storage area. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Contents under pressure. Do not puncture or incinerate container. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers. Do not enter confined spaces unless adequately ventilated. Never use air pressure for transferring product. Use of non-sparking or explosion-proof equipment may be necessary, depending upon the type of operation. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION. Conditions for safe storage: Minimize sources of ignition, such as static build-up, heat, spark or flame. Store in a dry place. See Section 10 for more specific information. Storage stability

Storage temperature: Shelf life: Use within 49 °C (120 °F) 12 Month

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters Exposure limits are listed below, if they exist. Component Regulation Type of listing Value/Notation

Isobutane ACGIH STEL 1,000 ppm Propane ACGIH Asphyxiant OSHA Z-1 TWA 1,800 mg/m3 1,000

ppm Methyl ether US WEEL TWA 1,000 ppm 4,4' -Methylenediphenyl diisocyanate

ACGIH TWA 0.005 ppm

OSHA Z-1 C 0.2 mg/m3 0.02 ppm NIOSH REL TWA 0.05 mg/m3 0.005 ppm NIOSH REL C 0.2 mg/m3 0.02 ppm Exposure controls Engineering controls: Use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations. Provide general and/or local exhaust ventilation to control airborne levels below the exposure guidelines. Exhaust systems should be designed to move the air away from the source of vapor/aerosol generation and people working at this point. The odor and irritancy of this material are inadequate to warn of excessive exposure. Lethal concentrations may exist in areas with poor ventilation. Individual protection measures

Eye/face protection: Use safety glasses (with side shields). Skin protection

Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove barrier materials include: Butyl rubber. Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Examples of acceptable glove barrier materials include: Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Viton. Polyvinyl chloride ("PVC" or "vinyl"). NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity,



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thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier. Other protection: Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task.

Respiratory protection: Atmospheric levels should be maintained below the exposure guideline. When atmospheric levels may exceed the exposure guideline, use an approved air-purifying respirator equipped with an organic vapor sorbent and a particle filter. For situations where the atmospheric levels may exceed the level for which an air-purifying respirator is effective, use a positive-pressure air-supplying respirator (air line or self-contained breathing apparatus). For emergency response or for situations where the atmospheric level is unknown, use an approved positive-pressure self-contained breathing apparatus or positive-pressure air line with auxiliary self-contained air supply. In confined or poorly ventilated areas, use an approved self-contained breathing apparatus or positive pressure air line with auxiliary self-contained air supply. The following should be effective types of air-purifying respirators: Organic vapor cartridge with a particulate pre-filter.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Physical state Foam

Color Orange

Odor Odorless

Odor Threshold No test data available

pH Not applicable

Melting point/range No test data available

Freezing point No test data available

Boiling point (760 mmHg) Not applicable

Flash point closed cup -104 °C ( -155 °F) Estimated.

Evaporation Rate (Butyl Acetate = 1)

No test data available

Flammability (solid, gas) No data available

Lower explosion limit No test data available

Upper explosion limit No test data available

Vapor Pressure 1,100 kPa at 55 °C (131 °F) Supplier

Relative Vapor Density (air = 1) No test data available

Relative Density (water = 1) 1.06 Calculated.

Water solubility Insoluble


No data available

Auto-ignition temperature No test data available

Decomposition temperature No test data available

Kinematic Viscosity Not applicable

Explosive properties Not explosive

Oxidizing properties No



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Molecular weight No data available

NOTE: The physical data presented above are typical values and should not be construed as a specification.

10. STABILITY AND REACTIVITY

Reactivity: No data available Chemical stability: Stable under recommended storage conditions. See Storage, Section 7. Unstable at elevated temperatures. Possibility of hazardous reactions: Can occur. Exposure to elevated temperatures can cause product to decompose and generate gas. This can cause pressure build-up and/or rupturing of closed containers. Acids. Conditions to avoid: Avoid temperatures above 50 °C Elevated temperatures can cause container to vent and/or rupture. Exposure to elevated temperatures can cause product to decompose. Incompatible materials: Avoid contact with: Acids. Alcohols. Amines. Ammonia. Bases. Metal compounds. Strong oxidizers. Products based on diisocyanates like TDI and MDI react with many materials to release heat. The reaction rate increases with temperature as well as with increased contact; these reactions can become violent. Contact is increased by stirring or if the other material acts as a solvent. Products based on diisocyanates such as TDI and MDI are not soluble in water and will sink to the bottom, but react slowly at the interface. The reaction forms carbon dioxide gas and a layer of solid polyurea. Reaction with water will generate carbon dioxide and heat. Hazardous decomposition products: Decomposition products depend upon temperature, air supply and the presence of other materials. Toxic gases are released during decomposition.

11. TOXICOLOGICAL INFORMATION

Toxicological information appears in this section when such data is available. Acute toxicity

Acute oral toxicity Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury. Observations in animals include: Gastrointestinal irritation. As product: Single dose oral LD50 has not been determined. LD50, Rat, > 2,000 mg/kg Estimated. Acute dermal toxicity Prolonged skin contact is unlikely to result in absorption of harmful amounts. As product: The dermal LD50 has not been determined.



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LD50, Rabbit, > 2,000 mg/kg Estimated. Acute inhalation toxicity In confined or poorly ventilated areas, vapor can easily accumulate and can cause unconsciousness and death due to displacement of oxygen. Excessive exposure may cause irritation to upper respiratory tract (nose and throat) and lungs. May cause pulmonary edema (fluid in the lungs.) Effects may be delayed. May cause central nervous system depression. Symptoms of excessive exposure may be anesthetic or narcotic effects; dizziness and drowsiness may be observed. Excessive exposure may increase sensitivity to epinephrine and increase myocardial irritability (irregular heartbeats). Decreased lung function has been associated with overexposure to isocyanates. The LC50 has not been determined.,

Skin corrosion/irritation Prolonged contact may cause moderate skin irritation with local redness. Material may stick to skin causing irritation upon removal. May stain skin. Serious eye damage/eye irritation May cause eye irritation. May cause slight temporary corneal injury. Sensitization Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with isocyanates may play a role in respiratory sensitization. May cause allergic respiratory reaction. MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in individuals already sensitized. Asthma-like symptoms may include coughing, difficult breathing and a feeling of tightness in the chest. Occasionally, breathing difficulties may be life threatening. Specific Target Organ Systemic Toxicity (Single Exposure) May cause respiratory irritation. Route of Exposure: Inhalation Specific Target Organ Systemic Toxicity (Repeated Exposure) Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after repeated excessive exposures to MDI/polymeric MDI aerosols. Contains component(s) which have been reported to cause effects on the following organs in animals: kidney Liver. Carcinogenicity Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory irritation and lung injury. Current exposure guidelines are expected to protect against these effects reported for MDI.



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Teratogenicity In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only at high doses which were toxic to the mother. Reproductive toxicity Based on information for component(s): May cause harm to breastfed babies. Mutagenicity In vitro genetic toxicity studies were negative for component(s) tested. Genetic toxicity data on MDI are inconclusive. MDI was weakly positive in some in vitro studies; other in vitro studies were negative. Animal mutagenicity studies were predominantly negative. Aspiration Hazard Based on physical properties, not likely to be an aspiration hazard. Carcinogenicity Component List Classification Paraffin waxes and Hydrocarbon waxes, chlorinated

IARC Group 2B: Possibly carcinogenic to humans

US NTP Reasonably anticipated to be a human carcinogen

12. ECOLOGICAL INFORMATION

Ecotoxicological information appears in this section when such data is available. Toxicity Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer

Acute toxicity to fish For this family of materials: Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).


Acute toxicity to fish Not expected to be acutely toxic to aquatic organisms.


Acute toxicity to fish The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested). Based on information for a similar material: LC50, Danio rerio (zebra fish), static test, 96 Hour, > 1,000 mg/l, OECD Test Guideline 203 or Equivalent Acute toxicity to aquatic invertebrates Based on information for a similar material:



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EC50, Daphnia magna (Water flea), static test, 24 Hour, > 1,000 mg/l, OECD Test Guideline 202 or Equivalent Acute toxicity to algae/aquatic plants Based on information for a similar material: NOEC, Desmodesmus subspicatus (green algae), static test, 72 Hour, Growth rate inhibition, 1,640 mg/l, OECD Test Guideline 201 or Equivalent

Toxicity to bacteria Based on information for a similar material: EC50, activated sludge, static test, 3 Hour, Respiration rates., > 100 mg/l

Toxicity to soil-dwelling organisms EC50, Eisenia fetida (earthworms), Based on information for a similar material:, 14 d, > 1,000 mg/kg

Toxicity to terrestrial plants EC50, Avena sativa (oats), Growth inhibition, 1,000 mg/l EC50, Lactuca sativa (lettuce), Growth inhibition, 1,000 mg/l


Acute toxicity to fish Material is highly toxic to aquatic organisms on an acute basis (LC50/EC50 between 0.1 and 1 mg/L in the most sensitive species tested). LC50, Oncorhynchus mykiss (rainbow trout), 96 Hour, > 0.1 mg/l

Isobutane

Acute toxicity to fish No relevant data found.

Propane

Acute toxicity to fish No relevant data found.

Methyl ether

Acute toxicity to fish Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested). LC50, Poecilia reticulata (guppy), semi-static test, 96 Hour, > 4,000 mg/l Acute toxicity to aquatic invertebrates LC50, Daphnia magna (Water flea), 48 Hour, > 4,000 mg/l, OECD Test Guideline 202 or Equivalent

4,4' -Methylenediphenyl diisocyanate

Acute toxicity to fish The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested). Based on information for a similar material: LC50, Danio rerio (zebra fish), static test, 96 Hour, > 1,000 mg/l, OECD Test Guideline 203 or Equivalent



Page 12 of 18

Acute toxicity to aquatic invertebrates Based on information for a similar material: EC50, Daphnia magna (Water flea), static test, 24 Hour, > 1,000 mg/l, OECD Test Guideline 202 or Equivalent Acute toxicity to algae/aquatic plants Based on information for a similar material: NOEC, Desmodesmus subspicatus (green algae), static test, 72 Hour, Growth rate inhibition, 1,640 mg/l, OECD Test Guideline 201 or Equivalent

Toxicity to bacteria Based on information for a similar material: EC50, activated sludge, static test, 3 Hour, Respiration rates., > 100 mg/l

Toxicity to soil-dwelling organisms EC50, Eisenia fetida (earthworms), Based on information for a similar material:, 14 d, > 1,000 mg/kg

Toxicity to terrestrial plants EC50, Avena sativa (oats), Growth inhibition, 1,000 mg/l EC50, Lactuca sativa (lettuce), Growth inhibition, 1,000 mg/l

N,N'-Dimorpholinodiethylether

Acute toxicity to fish Material is practically non-toxic to fish on an acute basis (LC50 > 100 mg/L). May increase pH of aquatic systems to > pH 10 which may be toxic to aquatic organisms. LC50, Danio rerio (zebra fish), static test, 96 Hour, > 2,150 mg/l, OECD Test Guideline 203 or Equivalent Acute toxicity to aquatic invertebrates EC50, Daphnia (water flea), static test, 48 Hour, > 100 mg/l, OECD Test Guideline 202 or Equivalent Acute toxicity to algae/aquatic plants ErC50, Algae, static test, 72 Hour, > 100 mg/l, OECD Test Guideline 201 or Equivalent

Toxicity to bacteria EC50, Bacteria, static test, 3 Hour, 100 mg/l, activated sludge test (OECD 209)

Persistence and degradability Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer

Biodegradability: For this family of materials: Material is readily biodegradable. Passes OECD test(s) for ready biodegradability.


Biodegradability: Expected to degrade slowly in the environment. Diphenylmethane Diisocyanate, isomers and homologues

Biodegradability: In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric



Page 13 of 18

environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. 10-day Window: Not applicable Biodegradation: 0 % Exposure time: 28 d Method: OECD Test Guideline 302C or Equivalent


Biodegradability: Expected to degrade slowly in the environment.

Theoretical Oxygen Demand: 2.89 mg/mg Isobutane

Biodegradability: Biodegradation may occur under aerobic conditions (in the presence of oxygen).

Theoretical Oxygen Demand: 3.58 mg/mg

Photodegradation Test Type: Half-life (indirect photolysis) Sensitizer: OH radicals Atmospheric half-life: 4.4 d Method: Estimated.

Propane

Biodegradability: No relevant data found.



Methyl ether

Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. 10-day Window: Fail Biodegradation: 5 % Exposure time: 28 d Method: OECD Test Guideline 301A or Equivalent






Page 14 of 18

Biodegradability: In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates. 10-day Window: Not applicable Biodegradation: 0 % Exposure time: 28 d Method: OECD Test Guideline 302C or Equivalent


Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. 10-day Window: Fail Biodegradation: 0 - 10 % Exposure time: 28 d Method: OECD Test Guideline 301A or Equivalent



Bioaccumulative potential Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer

Bioaccumulation: No relevant data found. Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol copolymer

Bioaccumulation: In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas.


Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Reacts with water. In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Bioconcentration factor (BCF): 92 Cyprinus carpio (Carp) 28 d


Bioaccumulation: Bioconcentration potential is low (BCF less than 100 or log Pow greater than 7). Partition coefficient: n-octanol/water(log Pow): 7.4 Estimated.

Isobutane

Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient: n-octanol/water(log Pow): 2.76 Measured

Propane

Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient: n-octanol/water(log Pow): 2.36 Measured



Page 15 of 18

Methyl ether Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient: n-octanol/water(log Pow): 0.10 Measured


Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Reacts with water. In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. Bioconcentration factor (BCF): 92 Cyprinus carpio (Carp) 28 d


Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient: n-octanol/water(log Pow): 0.5 Estimated.

Mobility in soil Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer

No relevant data found. Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol copolymer

In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas.




Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected to be an important fate process. Expected to be relatively immobile in soil (Koc > 5000). Partition coefficient(Koc): > 5000 Estimated.

Isobutane

Potential for mobility in soil is very high (Koc between 0 and 50). Partition coefficient(Koc): 35 Estimated.

Propane

Potential for mobility in soil is very high (Koc between 0 and 50). Partition coefficient(Koc): 24 - 460 Estimated.

Methyl ether

Potential for mobility in soil is very high (Koc between 0 and 50). Partition coefficient(Koc): 1.29 - 14 Estimated.




Potential for mobility in soil is low (Koc between 500 and 2000). Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is not expected to be an important fate process.



Page 16 of 18

Partition coefficient(Koc): 784 Estimated.

13. DISPOSAL CONSIDERATIONS

Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed, permitted: Incinerator or other thermal destruction device.

14. TRANSPORT INFORMATION

DOT Proper shipping name Aerosols UN number UN 1950 Class 2.1

Packing group

Classification for SEA transport (IMO-IMDG):

Proper shipping name AEROSOLS UN number UN 1950 Class 2.1

Packing group Marine pollutant Paraffin waxes and Hydrocarbon waxes, chlorinated

Transport in bulk according to Annex I or II of MARPOL 73/78 and the IBC or IGC Code

Consult IMO regulations before transporting ocean bulk

Classification for AIR transport (IATA/ICAO):

Proper shipping name Aerosols, flammable UN number UN 1950 Class 2.1

Packing group

This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Transportation classifications may vary by container volume and may be influenced by regional or country variations in regulations. Additional transportation system information can be obtained through an authorized sales or customer service representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material.



Page 17 of 18

15. REGULATORY INFORMATION

OSHA Hazard Communication Standard This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Sections 311 and 312 Acute Health Hazard Chronic Health Hazard Fire Hazard Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Section 313 This product contains the following substances which are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and which are listed in 40 CFR 372. Components CASRN Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 4,4' -Methylenediphenyl diisocyanate 101-68-8 Pennsylvania Worker and Community Right-To-Know Act: The following chemicals are listed because of the additional requirements of Pennsylvania law: Components CASRN Isobutane 75-28-5 Propane 74-98-6 Methyl ether 115-10-6 California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986) This product contains no listed substances known to the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute. United States TSCA Inventory (TSCA) All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.

16. OTHER INFORMATION

Revision Identification Number: 101216112 / A001 / Issue Date: 01/04/2016 / Version: 4.0 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document.



Page 18 of 18

Legend ACGIH USA. ACGIH Threshold Limit Values (TLV) Asphyxiant Asphyxiant C Ceiling NIOSH REL USA. NIOSH Recommended Exposure Limits OSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air

Contaminants STEL Short-term exposure limit TWA 8-hour, time-weighted average US WEEL USA. Workplace Environmental Exposure Levels (WEEL) Information Source and References This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from information supplied by internal references within our company. THE DOW CHEMICAL COMPANY urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version.

Safety Data Sheet

Product Name: HAVOLINE ENERGY SAE 5W-30 Reference No: CAL0001801 Issued: 2015-10-12 Version: 2.0 Page 1 of 5

NON-Hazardous Substance, NON-Dangerous Goods

1. MATERIAL AND SUPPLY COMPANY IDENTIFICATION

Product name: HAVOLINE ENERGY SAE 5W-30

Synonyms Product Code HAVOLINE ENERGY SAE 5W-30 3192 Recommended use: Automotive Engine Oil Supplier: Caltex Australia Petroleum Pty Ltd ABN: 17 000 032 128 Street Address: 2 Market Street Sydney NSW 2000 Australia Telephone: +612 9250-5000 Facsimile: +612 9250-5742 Emergency telephone number: 1800 033 111

2. HAZARDS IDENTIFICATION

Based on available information, this material is not classified as hazardous according to criteria of Safe Work Australia. Poison Schedule: Not Applicable DANGEROUS GOOD CLASSIFICATION

3. COMPOSITION INFORMATION

CHEMICAL ENTITY

CAS NO PROPORTION

Ingredients determined to be non-hazardous 100 %

100 %


If poisoning occurs, contact a doctor or Poisons Information Centre (Phone Australia 131 126, New Zealand 0800 764 766). Inhalation: Remove victim from exposure - avoid becoming a casualty. Remove contaminated clothing and loosen remaining clothing. Allow patient to assume most comfortable position and keep warm. Keep at rest until fully recovered. Seek medical advice if effects persist. Skin Contact: If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. If swelling, redness, blistering or irritation occurs seek medical assistance. Eye contact: If in eyes wash out immediately with water. In all cases of eye contamination it is a sensible precaution to seek medical advice.

Safety Data Sheet


Ingestion: Rinse mouth with water. If swallowed, do NOT induce vomiting. Give a glass of water to drink. Never give anything by the mouth to an unconscious patient. If vomiting occurs give further water. Seek medical advice. Notes to physician: Treat symptomatically.

5. FIRE FIGHTING MEASURES

Hazchem Code: Not applicable. Suitable extinguishing media: If material is involved in a fire use water fog (or if unavailable fine water spray), alcohol resistant foam, standard foam, dry agent (carbon dioxide, dry chemical powder). Specific hazards: Combustible material. Fire fighting further advice: On burning or decomposing may emit toxic fumes. Fire fighters to wear self-contained breathing apparatus and suitable protective clothing if risk of exposure to vapour or products of combustion or decomposition.


SMALL SPILLS Wear protective equipment to prevent skin and eye contamination. Avoid inhalation of vapours or dust. Wipe up with absorbent (clean rag or paper towels). Collect and seal in properly labelled containers or drums for disposal. LARGE SPILLS Clear area of all unprotected personnel. Slippery when spilt. Avoid accidents, clean up immediately. Wear protective equipment to prevent skin and eye contamination and the inhalation of vapours. Work up wind or increase ventilation. Contain - prevent run off into drains and waterways. Use absorbent (soil, sand or other inert material). Collect and seal in properly labelled containers or drums for disposal. If contamination of crops, sewers or waterways has occurred advise local emergency services. Dangerous Goods Initial Emergency Response Guide No: Not applicable


Handling: Avoid eye contact and repeated or prolonged skin contact. Avoid inhalation of vapour, mist or aerosols. Storage: Store in a cool, dry, well-ventilated place and out of direct sunlight. Store away from foodstuffs. Store away from incompatible materials described in Section 10. Store away from sources of heat and/or ignition. Keep container standing upright. Keep containers closed when not in use - check regularly for leaks.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

National occupational exposure limits: No value assigned for this specific material by Safe Work Australia. Biological Limit Values: Substances (Safe National occupational exposure limits: Natural ventilation should be adequate under normal use conditions.. Personal Protection Equipment: SAFETY SHOES, OVERALLS, GLOVES, SAFETY GLASSES.

Safety Data Sheet


Wear safety shoes, overalls, gloves, safety glasses.Available information suggests that gloves made from nitrile rubber should be suitable for intermittent contact. However, due to variations in glove construction and local conditions, the user should make a final assessment. Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated clothing and other protective equipment before storing or re-using. Hygiene measures: Keep away from food, drink and animal feeding stuffs. When using do not eat, drink or smoke. Wash hands prior to eating, drinking or smoking. Avoid contact with clothing. Avoid eye contact and repeated or prolonged skin contact. Avoid inhalation of vapour, mist or aerosols. Ensure that eyewash stations and safety showers are close to the workstation location.


Form: Liquid Colour: Light to brown Odour: Petroleum Solubility: Insoluble in water. Soluble in hydrocarbons Specific Gravity (20 °C): 0.851 kg/l at 15°C (Typical) Density: 0.851 kg/l at 15°C (Typical) Relative Vapour Density (air=1): >1 Vapour Pressure (20 °C): <0.01 mmHg @ 37.8 oC Flash Point (°C): >200°C (ASTM D92) Flammability Limits (%): N App Autoignition Temperature (°C): N Av Melting Point/Range (°C): N Av Pour Point/Range (°C): -45°C (ISO 3016) Boiling Point/Range (°C): >315 pH: N App Viscosity: 51 mm²/s at 40°C (Typical) Total VOC (g/Litre): N Av

(Typical values only - consult specification sheet) N Av = Not available, N App = Not applicable


Chemical stability: This material is thermally stable when stored and used as directed. Conditions to avoid: Elevated temperatures and sources of ignition. Incompatible materials: Oxidising agents. Hazardous decomposition products: Oxides of carbon and nitrogen, smoke and other toxic fumes. Hazardous reactions: No known hazardous reactions.


No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are: Acute Effects Inhalation: Material may be an irritant to mucous membranes and respiratory tract. Skin contact: Contact with skin may result in irritation.

Safety Data Sheet


Ingestion: Swallowing can result in nausea, vomiting and irritation of the gastrointestinal tract. Eye contact: May be an eye irritant. Acute toxicity Inhalation: This material has been classified as non-hazardous. Acute toxicity estimate (based on ingredients): >20 mg/L Skin contact: This material has been classified as non-hazardous. Acute toxicity estimate (based on ingredients): >2,000 mg/Kg Ingestion: This material has been classified as non-hazardous. Acute toxicity estimate (based on ingredients): >2,000 mg/Kg Corrosion/Irritancy: Eye: this material has been classified as not corrosive or irritating to eyes. Skin: this material has been classified as not corrosive or irritating to skin. Sensitisation: Inhalation: this material has been classified as not a respiratory sensitiser. Skin: this material has been classified as not a skin sensitiser. Aspiration hazard: This material has been classified as non-hazardous. Specific target organ toxicity (single exposure): This material has been classified as non-hazardous. Chronic Toxicity Mutagenicity: This material has been classified as non-hazardous. Carcinogenicity: This material has been classified as non-hazardous. Reproductive toxicity (including via lactation): This material has been classified as non-hazardous. Specific target organ toxicity (repeat exposure): This material has been classified as non-hazardous.


Avoid contaminating waterways. Acute aquatic hazard: This material has been classified as non-hazardous. Acute toxicity estimate (based on ingredients): >100 mg/L Long-term aquatic hazard: This material has been classified as non-hazardous. Non-rapidly or rapidly degradable substance for which there are adequate chronic toxicity data available OR in the absence of chronic toxicity data, Acute toxicity estimate (based on ingredients): >100 mg/L, where the substance is not rapidly degradable and/or BCF < 500 and/or log Kow < 4. Ecotoxicity: No information available. Persistence and degradability: No information available. Bioaccumulative potential: No information available. Mobility: No information available.

13. DISPOSAL CONSIDERATIONS

Persons conducting disposal, recycling or reclamation activities should ensure that appropriate personal

this SDS.

Safety Data Sheet


If possible material and its container should be recycled. If material or container cannot be recycled, dispose in accordance with local, regional, national and international Regulations.


ROAD AND RAIL TRANSPORT

MARINE TRANSPORT Not classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea. AIR TRANSPORT Not classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air.

15. REGLATORY INFORMATION

HSNO Group Standard: Not Allocated This material is not subject to the following international agreements: Montreal Protocol (Ozone depleting substances) The Stockholm Convention (Persistent Organic Pollutants) The Rotterdam Convention (Prior Informed Consent) Basel Convention (Hazardous Waste) International Convention for the Prevention of Pollution from Ships (MARPOL) This material/constituent(s) is covered by the following requirements: All the constituents of this material are listed on the Australian Inventory of Chemical Substances (AICS).


Literary reference Reason for issue: Revised Material Safety Data Sheets are updated frequently. Please ensure that you have a current copy. CHEMICAL EMERGENCIES: 1 800 033 111 TECHNICAL ADVICE, RING TECHNICAL SOLUTIONS: 1300 364 169 PLEASE NOTE that although every care has been taken in compiling the above information, it is solely reliant upon data available to us at the date hereof. We believe the data to be correct, however for the reason just stated we are not in a position to warrant its accuracy. With that in mind and given that the full range of possibilities and conditions under which the information may be applied simply cannot be anticipated, YOU ARE CAUTIONED to make your own determinations as to the veracity and the suitability of the information to the particular circumstances that apply, or may apply, to you from time to time. Consistent with that approach it is recommended that where you have a particular purpose which would necessitate a reliance on information of the nature herein you obtain your own independent expert advice particularly structured to the relevant purpose. If this material is printed, circulated, distributed or copied in any manner, it is not to be modified without prior written permission, and further, it is to include the wording of the above disclaimer. This MSDS has been prepared by Chemical Data Services Pty Ltd (chemdata.com.au) on behalf of it s client.

SAFETY DATA SHEET

1. IdentificationProduct identifier Hercules MegaBubble

Other means of identificationProduct code 7322E

Synonyms Part Numbers: 45801, 45802, 45803, 45804

Recommended use Leak Detector

Recommended restrictions None known.


Company Name HCC Holdings, Inc. an Oatey AffiliateAddress 4700 West 160th Street

Cleveland, OH 44135Telephone 216-267-7100E-mail [email protected] Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)Emergency First Aid 1-877-740-5015Contact person MSDS Coordinator


Not classified.Physical hazards

Not classified.Health hazards

Not applicableHazardous to the aquatic environment, acutehazard



Label elements

None.Hazard symbol

Signal word None.

Hazard statement The mixture does not meet the criteria for classification.


Prevention Observe good industrial hygiene practices.

Response Wash hands after handling.

Storage Store away from incompatible materials.

Disposal Dispose of waste and residues in accordance with local authority requirements.

Hazard(s) not otherwiseclassified (HNOC)

None known.


Mixtures

57-55-6 30-60Propylene glycol

CAS number %Chemical name

7732-18-5 30-60Water

56-81-5 10-30Glycerol

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measuresInhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.

Call a physician if symptoms develop or persist.

Skin contact Rinse skin with water/shower. Get medical attention if irritation develops and persists.

Hercules MegaBubble SDS US

924586 Version #: 01 Revision date: - Issue date: 05-February-2015 1 / 6

Eye contact Rinse with water. Get medical attention if irritation develops and persists.

Ingestion Rinse mouth. If ingestion of a large amount does occur, call a poison control center immediately.

Most importantsymptoms/effects, acute anddelayed

Direct contact with eyes may cause temporary irritation.

Indication of immediatemedical attention and specialtreatment needed

Treat symptomatically.

General information Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves.

5. Fire-fighting measuresSuitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).

Unsuitable extinguishingmedia

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards arising fromthe chemical

During fire, gases hazardous to health may be formed.

Special protective equipmentand precautions for firefighters

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

Fire fightingequipment/instructions

Move containers from fire area if you can do so without risk.

Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.

General fire hazards No unusual fire or explosion hazards noted.

6. Accidental release measuresPersonal precautions,protective equipment andemergency procedures

Keep unnecessary personnel away. For personal protection, see section 8 of the SDS.

Methods and materials forcontainment and cleaning up

Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors ordivert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet toprevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Followingproduct recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.

Environmental precautions Avoid discharge into drains, water courses or onto the ground.

7. Handling and storagePrecautions for safe handling Avoid prolonged exposure. Observe good industrial hygiene practices.


Store in original tightly closed container. Store away from incompatible materials (see Section 10of the SDS).

8. Exposure controls/personal protectionOccupational exposure limits


ValueType FormComponents

PEL 5 mg/m3 Respirable fraction.Glycerol (CAS 56-81-5)15 mg/m3 Total dust.

US. Workplace Environmental Exposure Level (WEEL) Guides


TWA 10 mg/m3 Aerosol.Propylene glycol (CAS57-55-6)

Biological limit values No biological exposure limits noted for the ingredient(s).



Appropriate engineeringcontrols

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation ratesshould be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,or other engineering controls to maintain airborne levels below recommended exposure limits. Ifexposure limits have not been established, maintain airborne levels to an acceptable level.

Individual protection measures, such as personal protective equipmentEye/face protection Wear safety glasses with side shields (or goggles).

Skin protectionHand protection Wear appropriate chemical resistant gloves.

Other Wear suitable protective clothing.

Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.

Thermal hazards Wear appropriate thermal protective clothing, when necessary.

General hygieneconsiderations

Always observe good personal hygiene measures, such as washing after handling the materialand before eating, drinking, and/or smoking. Routinely wash work clothing and protectiveequipment to remove contaminants.

9. Physical and chemical propertiesAppearance

Physical state Liquid.

Form Liquid.

Color Blue.

Odor Odorless.


pH 7.2

Melting point/freezing point Not available.

Initial boiling point and boilingrange

212 °F (100 °C)

Flash point > 212.0 °F (> 100.0 °C)


Flammability (solid, gas) Not available.


Flammability limit - lower(%)

Not available.

Flammability limit - upper(%)

Not available.

Explosive limit - lower (%) Not available.

Explosive limit - upper (%) Not available.

Vapor pressure Not available.

Vapor density Not available.

Relative density 1.05

Solubility(ies)

Solubility (water) Not available.

Partition coefficient(n-octanol/water)

Not available.

Auto-ignition temperature Not available.


Viscosity 100 cP

Other information

VOC (Weight %) 435 g/l

10. Stability and reactivityReactivity The product is stable and non-reactive under normal conditions of use, storage and transport.

Chemical stability Material is stable under normal conditions.

Possibility of hazardousreactions

No dangerous reaction known under conditions of normal use.



Conditions to avoid Contact with incompatible materials.

Incompatible materials Strong oxidizing agents.

Hazardous decompositionproducts

No hazardous decomposition products are known.

11. Toxicological informationInformation on likely routes of exposure

Inhalation Prolonged inhalation may be harmful.

Skin contact No adverse effects due to skin contact are expected.

Eye contact Direct contact with eyes may cause temporary irritation.

Ingestion Expected to be a low ingestion hazard.

Symptoms related to thephysical, chemical andtoxicological characteristics



Acute toxicity


Glycerol (CAS 56-81-5)

LD50 Rat

OralAcute

12600 mg/kg

Propylene glycol (CAS 57-55-6)

LD50 Rat

OralAcute

30 g/kg


Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.

Serious eye damage/eyeirritation




Skin sensitization This product is not expected to cause skin sensitization.

Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.

Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.


Not listed.

Reproductive toxicity This product is not expected to cause reproductive or developmental effects.

Specific target organ toxicity -single exposure

Not classified.

Specific target organ toxicity -repeated exposure

Not classified.

Aspiration hazard Not an aspiration hazard.


Further information This product has no known adverse effect on human health.

12. Ecological informationEcotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the

possibility that large or frequent spills can have a harmful or damaging effect on the environment.




Propylene glycol (CAS 57-55-6)

Aquatic

LC50Crustacea 18340 mg/l, 48 hoursCeriodaphnia dubia


LC50Fish 46500 mg/l, 96 hoursPimephales promelas

Persistence and degradability No data is available on the degradability of this product.


Partition coefficient n-octanol / water (log Kow)Glycerol (CAS 56-81-5) -1.76Propylene glycol (CAS 57-55-6) -0.92

Mobility in soil No data available.


13. Disposal considerationsDisposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site.

Local disposal regulations Dispose in accordance with all applicable regulations.

Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the wastedisposal company.

Waste from residues / unusedproducts

Dispose of in accordance with local regulations. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe manner (see:Disposal instructions).

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.


DOT

Not regulated as dangerous goods.

IATA


IMDG


Not established.Transport in bulk according toAnnex II of MARPOL 73/78 andthe IBC Code

15. Regulatory informationUS federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard

Communication Standard, 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.


Not regulated.OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.CERCLA Hazardous Substance List (40 CFR 302.4)

Not listed.

Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - No

Delayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No

SARA 302 Extremely hazardous substance

Not listed.



SARA 311/312 Hazardouschemical

No

SARA 313 (TRI reporting)Not regulated.

Other federal regulations


Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Not regulated.

Safe Drinking Water Act(SDWA)

Not regulated.



Glycerol (CAS 56-81-5)US. New Jersey Worker and Community Right-to-Know Act

Glycerol (CAS 56-81-5)Propylene glycol (CAS 57-55-6)


Glycerol (CAS 56-81-5)Propylene glycol (CAS 57-55-6)


Not regulated.

US. California Proposition 65California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to containany chemicals currently listed as carcinogens or reproductive toxins.


Country(s) or region Inventory name On inventory (yes/no)*Australian Inventory of Chemical Substances (AICS) YesAustralia

Domestic Substances List (DSL) YesCanada

Inventory of Existing Chemical Substances in China (IECSC) YesChina

European Inventory of Existing Commercial ChemicalSubstances (EINECS)

YesEurope

Inventory of Existing and New Chemical Substances (ENCS) NoJapan

New Zealand Inventory YesNew Zealand

Philippine Inventory of Chemicals and Chemical Substances(PICCS)

YesPhilippines

*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).

Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico

16. Other information, including date of preparation or last revisionIssue date 05-February-2015

Revision date -

Version # 01

HMIS® ratings Health: 0Flammability: 0Physical hazard: 0

Disclaimer HCC Holdings Inc. an Oatey Affiliate cannot anticipate all conditions under which this informationand its product, or the products of other manufacturers in combination with its product, may beused. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal ofthe product, and to assume liability for loss, injury, damage or expense due to improper use. Theinformation in the sheet was written based on the best knowledge and experience currentlyavailable.



SDS C6 QUIKRETE Companies, LLC 3/11/2019

Page 1 of 11

C6: Portland Cement Based Concrete Products SAFETY DATA SHEET (Complies with OSHA 29 CFR 1910.1200)

SECTION I: PRODUCT IDENTIFICATION The QUIKRETE® Companies Emergency Telephone Number 5 Concourse Parkway, Suite 1900 INFOTRAC (800) 535-5053 Atlanta, GA 30328 Information Telephone Number (800) 282-5828 Revision: Mar-19 SDS C6 QUIKRETE® Product Name Item #(s) Fast-Setting Concrete Mix 1004-50, -60 All-Star Fast Setting Concrete Mix 1004-50 Commercial Grade FastSetTM Concrete Mix 1004-51 Post Haste 1004-65 Q-MAX Pro Concrete Mix 1004-81 Commercial Grade Fast Setting Pro Concrete Mix 1004-84 All-Star 10 Minute Instant Post Mix 1005-51 Fence & Post Mix 1105-30 FastSetTM Water-Stop Cement –Zip & Mix 1121-15 Commercial Grade FastSetTM Cement 1124-92 Hydraulic Water Stop 1126-00 Concrete Resurfacer 1131-40 Recap Concrete Resurfacer Multipurpose Concrete Resurfacer 1131-45 Bonded Topping Mix 1133-04, 1018, 1017 FastSetTM Stucco Patch 1139-92 Architectural Finish 1220-55 Commercial Grade FastSetTM Repair Mortar – Zip And Mix 1241 Commercial Grade FastSetTM Repair Mortar 1241-60 Polymer Modified Structural Concrete – Extended Set 1242-85 Commercial Grade FastSetTM Polymer Modified DOT Mix 1244-54 Commercial Grade FastSetTM DOT Mix 1244-56 Commercial Grade FastSetTM DOT Deck Repair – Polymer Modified 1244-58 Commercial Grade FastSetTM DOT Mix – Extended 1244-81 Commercial Grade FastSetTM Non-Shrink Grout 1585-09, -20, -50 Commercial Grade FastSetTM All-Crete 1585-59 Mix 801 FastSetTM DOT PM Overlay NR801552/80801552 Rapid Road Repair – CA


Page 2 of 11

Product Use: Portland cement-based, rapid-setting materials for general construction or repair. See most current revision of this document at www.QUIKRETE.com.

SECTION II - HAZARD IDENTIFICATION Hazard-determining components of labeling: Silica, Portland cement 2.1 Classification of the substance or mixture Carcinogen – Category 1A Skin Corrosion – Category 1B Skin Sensitization – Category 1B Specific Target Organ Toxicity Repeat Exposure – Category 1 Specific Target Organ Toxicity: Single Exposure – Category 3 2.2a Signal word DANGER! 2.2b Hazard Statements May cause cancer through chronic inhalation Causes severe skin burns and serious eye damage May cause an allergic skin reaction Causes damage to lungs through prolonged or repeated inhalation May cause respiratory irritation 2.2c Pictograms

2.2d Precautionary statements Do not handle until all safety precautions have been read and understood. Wear impervious gloves, such as nitrile. Wear eye protection, protective clothing and rubber boots. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Use only in a well-ventilated area. Do not breathe dust. If swallowed: Rinse mouth. Do NOT induce vomiting. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and


Page 3 of 11

easy to do. Continue rinsing. If on skin (or hair): Remove immediately all contaminated clothing and wash before re-use. Rinse skin or hair with water. If significant skin irritation or rash occurs: get medical advice or attention. Immediately seek medical advice if symptoms are significant or persist. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/containers in accordance with all regulations. 2.3 Additional Information The Portland cement in this product can cause serious, potentially irreversible damage to skin, eye, respiratory and digestive tracts due to chemical (caustic) burns, including third degree burns. Burns from Portland cement may not cause immediate pain or discomfort. You cannot rely on pain to alert you to cement burns. Therefore precautions must be taken to prevent all contact with Portland cement. Cement burns can become worse even after contact has ended. If there is contact with this product, immediately remove all product from body and thoroughly rinse with water. If you experience or suspect a cement burn or inflammation you should immediately see a health care professional. Skin burns and irritation may be caused by brief exposure, though often are caused by extended exposure of 15 minutes, an hour, or longer. Interaction of Portland cement with water or sweat releases a caustic solution which produces the burns or irritation. Any extended exposure should be treated as though a burn has occurred until determined otherwise. Skin contact with Portland cement can also cause inflammation of the skin, referred to as dermatitis. Signs and symptoms of dermatitis can include itching, redness, swelling, blisters, scaling, and other changes in the normal condition of the skin. Signs and symptoms of burns include the above and whitening, yellowing, blackening, peeling or cracking of skin. The Portland cement in this product may cause allergic contact dermatitis in sensitized individuals. This overreaction of the immune system can lead to severe inflammation. Sensitization may result from a single exposure to the low levels of Cr(VI) in Portland cement or repeated exposures over months or years. Sensitization is long lasting and, after sensitization, even very small quantities can trigger the dermatitis. Sensitization is uncommon. Individuals who experience skin problems, including seemingly minor ones, are advised to seek medical attention. 2.3a HNOC – Hazards not otherwise classified: Not applicable 2.3b Unknown Acute Toxicity: None


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SECTION III - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION Hazardous Components CAS No. % by Weight Sand, Silica, Quartz 14808-60-7 40-70* Portland Cement 65997 15 1 10-30* Calcium Sulfoaluminate 65997-16-2 10-30* Calcium Aluminate 12042-68-1 5-10* Calcium Sulfate 10101-41-4 1-5* Limestone Dust 01317-65-3 1-5* *The concentrations ranges are provided due to batch-to-batch variability. None of the constituents of this material are of unknown toxicity.

SECTION IV – FIRST AID MEASURES 4.1 Description of the first-aid measures General information: After inhalation: Remove person to fresh air. If breathing is difficult, administer oxygen. If not breathing, give artificial respiration. In case of unconsciousness, place patient stably in side position for transportation. After skin contact: Wash skin with cool water and pH-neutral soap or a mild detergent. If significant skin irritation or rash occurs: get medical advice or attention. After eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. After swallowing: Do not induce vomiting. If conscious, have the victim drink plenty of water and call a physician immediately. Never give anything by mouth to an unconscious person. 4.2 Most important symptoms/effects, acute and delayed Inhalation: May cause respiratory tract irritation. Causes damage to organs through prolonged or repeated inhalation. This product contains crystalline silica. Prolonged or repeated inhalation of respirable silica from this product can cause silicosis. Skin contact: The Portland cement in this product can cause serious, potentially irreversible damage to skin, eye, respiratory and digestive tracts due to chemical (caustic) burns, including third degree burns. Burns from Portland cement may not cause immediate pain or discomfort. You cannot rely on pain to alert you to cement burns. Therefore precautions must be taken to prevent all contact with Portland cement. Cement burns can become worse even after contact has ended. If there is contact with this product, immediately remove all product from body and thoroughly rinse with water. If you experience or suspect a cement burn or inflammation you should immediately see a health care professional.


Page 5 of 11

Skin burns and irritation may be caused by brief exposure, though often are caused by extended exposure of 15 minutes, an hour, or longer. Interaction of Portland cement with water or sweat releases a caustic solution which produces the burns or irritation. Any extended exposure should be treated as though a burn has occurred until determined otherwise. Skin contact with Portland cement can also cause inflammation of the skin, referred to as dermatitis. Signs and symptoms of dermatitis can include itching, redness, swelling, blisters, scaling, and other changes in the normal condition of the skin. Signs and symptoms of burns include the above and whitening, yellowing, blackening, peeling or cracking of skin. The Portland cement in this product may cause allergic contact dermatitis in sensitized individuals. This overreaction of the immune system can lead to severe inflammation. Sensitization may result from a single exposure to the low levels of Cr(VI) in Portland cement or repeated exposures over months or years. Sensitization is long lasting and, after sensitization, even very small quantities can trigger the dermatitis. Sensitization is uncommon. Individuals who experience skin problems, including seemingly minor ones, are advised to seek medical attention. Eye Contact: Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Ingestion: May be harmful if swallowed. Ingestion may cause discomfort and/or distress, nausea or vomiting. 4.3 Indication of immediate medical attention and special treatment needed: Immediately seek medical advice if symptoms are significant or persist.

SECTION V - FIRE FIGHTING MEASURES 5.1 Flammability of the Product: Non-flammable and non-combustible 5.2 Suitable extinguishing agents: Treat for surrounding material 5.3 Special hazards arising from the substance or mixture: None 5.3a Products of Combustion: None 5.3b Explosion Hazards in Presence of Various Substances: Non-explosive in presence of shocks

SECTION VI – ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures: Wear personal protective equipment (See section VIII). Keep unprotected persons away. 6.2 Methods and material for containment and cleaning up:


Page 6 of 11

Do not allow to enter sewers/ surface or ground water. Dispose of unwanted materials and containers properly in accordance with all regulations.

SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND STORAGE 7.1 Handling Precautions for safe handling: Ensure good ventilation/exhaustion at the workplace. DO NOT BREATHE DUST. In dusty environments, the use of an OSHA, MSHA or NIOSH approved respirator and tight fitting goggles is recommended. Wear appropriate PPE (See section 8).Do not mix with other chemical products, except as indicated by the manufacturer. Do not get in eyes, on skin or clothing. Good housekeeping is important to prevent accumulation of dust. 7.2 Storage Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep out of the reach of children. Keep container tightly closed and prevent exposure to humidity. Do not allow water to contact the product until time of use to preserve product utility.

SECTION VIII – EXPOSURE CONTROL MEASURES / PERSONAL PROTECTION 8.1 Components with limit values that require monitoring at the workplace: Hazardous Components CAS No. PEL (OSHA) TLV (ACGIH) mg/M3 mg/M3 Silica Sand, crystalline 14808-60-7 0.05 0.025 (resp) Portland Cement 65997-15-1 5 (resp) 15 (total) 10 (resp) Calcium Sulfoaluminate 65997-16-2 15 10 Calcium Aluminate 12042-68-1 5 (resp) 15 (total) 1 (resp) Calcium Sulfate 10101-41-4 5 (resp) 15 (total) 10 (resp) Limestone Dust 01317-65-3 5 (resp) 15 (total) 10 (resp) 8.2 Exposure Controls Use ventilation adequate to keep exposures below recommended exposure limits. 8.3 General protective and hygienic measures Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. 8.3a Personal protective equipment Protection of hands and feet:


Page 7 of 11

Wear gloves of adequate length to offer appropriate skin protection from splashes. Nitrile, Butyl and PVC gloves have been found to offer adequate protection for incidental contact. Wear rubber boots when stepping in concrete. You cannot rely on pain to alert you to cement burns. Portland cement can cause dermatitis or sensitization. Eye protection: Wear approved eye protection properly fitted dust- or splash-proof chemical safety glasses. Respiratory protection: A NIOSH-approved dust mask or filtering face piece is recommended in poorly ventilated areas or when permissible exposure limits may be exceeded. Respirators should be selected by and used under the direction of a trained health and safety professional, following requirements found in OSHA’s respirator standard (29 CFR 1910.134) and ANSI’s standard for respiratory protection (Z88.2).

SECTION IX - PHYSICAL/CHEMICAL CHARACTERISTICS General Information Appearance Form: Granular Solid Color: Gray to gray-brown colored Odor: None pH-value at 20°C (68 °F): 13 (10%) Boiling point/Boiling range: Not applicable Flash point: Not applicable Auto igniting: Product is not self-igniting Vapor pressure at 21°C (70°F) Not available Density at 25°C (77 °F): 2.6 to 3.15

Solubility in / Miscibility with Water: Insoluble VOC content: 0 g/L VOC

SECTION X – STABILITY AND REACTIVITY 10.1 Reactivity No dangerous reaction known under conditions of normal use. 10.2 Chemical stability Stable under normal storage conditions. Keep in dry storage. 10.3 Possibility of hazardous reaction No dangerous reaction known under conditions of normal use. 10.4 Thermal decomposition / conditions to be avoided No decomposition if used according to specifications.


Page 8 of 11

10.5 Incompatible materials Contact of silica with powerful oxidizing agents such as fluorine, chlorine trifluoride, manganese trioxide, or oxygen difluoride may cause fires 10.6 Hazardous Decomposition or By-products Silica will dissolve in Hydrofluoric Acid and produce a corrosive gas – silicon tetrafluoride.

SECTION XI – TOXICOLOGICAL INFORMATION 11.1 Exposure Routes: Skin contact, skin adsorption, eye contact, inhalation, or ingestion. 11.2 Symptoms related to physical/chemical/toxicological characteristics:

Inhalation: May cause respiratory tract irritation. Causes damage to organs through prolonged or repeated exposure. This product contains crystalline silica. Prolonged or repeated inhalation of respirable silica from this product can cause silicosis. Skin contact: Causes skin irritation. Handling can cause dry skin, discomfort, irritation, and dermatitis. May cause sensitization by skin contact. Product becomes extremely alkaline when exposed to moisture, and can cause alkali burns and affect the mucous membranes. Eye Contact: Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Ingestion: Harmful if swallowed. Ingestion may cause discomfort and/or distress, nausea or vomiting.

11.3 Delayed, immediate and chronic effects of short-term and long-term exposure Short Term

Skin Corrosion/Irritation: Causes severe skin burns. Serious Eye Damage/Irritation: Causes severe eye damage. Respiratory Sensitization: Not available Skin Sensitization: May cause an allergic skin reaction. Specific Target Organ Toxicity-Single Exposure: (Category 3) may cause respiratory irritation. Aspiration Hazard: Not available

Long Term Carcinogenicity: May cause cancer through chronic inhalation. Germ Cell Mutagenicity: Not available Reproductive Toxicity: Not available Specific Target Organ Toxicity- Repeated Exposure: (Category 1) Causes damage to lungs through prolonged/repeated exposure Synergistic/Antagonistic Effects: Not available.


Page 9 of 11

SECTION XII – ECOLOGICAL INFORMATION

12.1 Ecotoxicity May cause long-term adverse effects to the aquatic environment. Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Must not reach bodies of water or drainage ditch undiluted or un-neutralized 12.2 Persistence and degradability No further relevant information available. 12.3 Bioaccumulative potential: No further relevant information available. 12.4 Mobility in soil No further relevant information available. 12.5 Other Adverse Effects No further relevant information available.

SECTION XIII – DISPOSAL CONSIDERATIONS 13.1 Waste Disposal Method The packaging and material may be land filled; however, material should be covered to minimize generation of airborne dust. This product is not classified as a hazardous waste under the authority of the RCRA (40CFR 261) or CERCLA (40CFR 117&302). Disposal must be made in accordance with local, state and federal regulations. 13.2 Other disposal considerations Uncleaned packaging Recommendation: Disposal must be made in accordance with local, state and federal regulations. Recommended cleansing agent: Water, if necessary with cleansing agents.

SECTION XIV – TRANSPORT INFORMATION DOT (U.S.) TDG (Canada) UN-Number Not Regulated Not Regulated UN proper shipping name Not Regulated Not Regulated Transport Hazard Class(es) Not Regulated Not Regulated Packing Group (if applicable) Not Regulated Not Regulated 14.1 Environmental hazards:


Page 10 of 11

Not Available 14.2 Transport in bulk according to Annex II of Marpol 73/78 and the IBC Code Not available 14.3 Special precautions for user Do not handle until all safety precautions have been read and understood.

SECTION XV – OTHER REGULATORY INFORMATION 15.1 Safety, Health and Environmental Regulations/Legislations specific for the chemical

Canada WHMIS Classification: Considered to be a hazardous material under the Hazardous Products Act as defined by the Controlled Products Regulations and subject to the requirements of Health Canada’s Workplace Hazardous Material Information (WHMIS). This document complies with the WHMIS requirements of the Hazardous Products Act (HPA) and the CPR.

15.2 US Federal Information

SARA 302/311/312/313 Components No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302, 311, 312 or 313. RCRA: Crystalline silica (quartz) is not classified as a hazardous waste under the Resource Conservation and Recovery Act, or its regulations, 40 CFR §261 et seq. CERCLA: Crystalline silica (quartz) is not classified as a hazardous substance under regulations of the Comprehensive Environmental Response Compensation and Liability Act (CERCLA), 40 CFR §302. Emergency Planning and Community Right to Know Act (SARA Title III): Crystalline silica (quartz) is not an extremely hazardous substance under Section 302 and is not a toxic chemical subject to the requirements of Section 313. FDA: Silica is included in the list of substances that may be included in coatings used in food contact surfaces, 21 CFR §175.300(b)(3)(xxvi). NTP: Respirable crystalline silica, primarily quartz dusts occurring in industrial and occupational settings, is classified as Known to be a Human Carcinogen. OSHA Carcinogen: Crystalline silica (quartz) is not listed.

15.3 State Right to Know Laws

California Prop. 65 Components


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WARNING: This product can expose you to chemicals including crystalline silica which is known to the State of California to cause cancer and Portland cement which is known to the State of California to cause birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov. California Inhalation Reference Exposure Level (REL): California established a chronic REL of 3 µg for silica (crystalline, respirable). A chronic REL is an airborne level of a substance at or below which no adverse health effects are anticipated in individuals indefinitely exposed to the substance at that level. Massachusetts Toxic Use Reduction Act: Silica, crystalline (respirable size, <10 microns) is “toxic” for purposes of the Massachusetts Toxic Use Reduction Act.

15.4 Global Inventories

DSL All components of this product are on the Canadian DSL list. TSCA No.: Crystalline silica (quartz) appears on the EPA TSCA inventory under the CAS No. 14808-60-7. All constituents are listed in the TSCA inventory.

SECTION XVI – OTHER INFORMATION Last Updated: March 11, 2019 NOTE: The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, express or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to silica contained in our products. Prepared by The QUIKRETE Companies, LLC

End of SDS

Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 1

Conforms to HazCom 2012/United States

SAFETY DATA SHEET

Lucas X-Tra Heavy Duty Grease NLGI # 2

Section 1. Identification

GHS product identifier Other means of identification

: Lucas X-Tra Heavy Duty Grease NLGI # 2 : Not available.

Product number : 10301, 10305, 10316, 10330, 10335

Identified uses Not available.

Supplier's details : Lucas Oil Products, Inc

302 North Sheridan Street Corona, California 92880-2067 Toll Free: (800) 342-2512 Tel: (951) 270-0154 Fax: (951) 270-1902 Website: www.LucasOil.com

Emergency telephone number (with hours of operation)

: (951) 493-1149 (951) 847-5949 [email protected]

7:00A.M. to 5:00P.M. Monday thru Friday


OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product.


: Not classified.

GHS label elements

Signal word : No signal word. Hazard statements : No known significant effects or critical hazards. Precautionary statements

General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.

Prevention : Not applicable. Response : Not applicable. Storage : Not applicable. Disposal : Not applicable.


: None known.




Substance/mixture : Mixture


: Not available.


CAS number : Not applicable. Product code : 10301, 10305, 10316, 10330, 10335

Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8.


Description of necessary first aid measures Eye contact

Inhalation

Skin contact

: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs.

: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur.

: Flush contaminated skin with plenty of water. Get medical attention if symptoms occur. Ingestion : Wash out mouth with water. Remove victim to fresh air and keep at rest in a position

comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur.


Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards.

Over-exposure signs/symptoms Eye contact : No known significant effects or critical hazards. Inhalation Skin contact Ingestion

: No known significant effects or critical hazards. : No known significant effects or critical hazards. : No known significant effects or critical hazards.

Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large

quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.





Extinguishing media Suitable extinguishing media Unsuitable extinguishing media

: Use an extinguishing agent suitable for the surrounding fire.

: None known.



: No specific fire or explosion hazard.

: Decomposition products may include the following materials:

carbon dioxide carbon monoxide metal oxide/oxides

Special protective actions for fire-fighters Special protective equipment for fire-fighters

: No special measures are required.

: Fire-fighters should wear appropriate protective equipment and self-contained breathing

apparatus (SCBA) with a full face-piece operated in positive pressure mode.


Personal precautions, protective equipment and emergency procedures For non-emergency personnel

: No action shall be taken involving any personal risk or without suitable training. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment.

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains

and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).


Small spill : Move containers from spill area. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor.

Large spill : Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.


Precautions for safe handling Protective measures Advice on general occupational hygiene

: Put on appropriate personal protective equipment (see Section 8). : Eating, drinking and smoking should be prohibited in areas where this material is

handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures.



Section 7. Handling and storage Conditions for safe storage, including any incompatibilities

: Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.


Control parameters Occupational exposure limits None.

Appropriate engineering controls Environmental exposure controls

: Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.

Individual protection measures Hygiene measures :

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Eye/face protection

Skin protection Hand protection

Body protection

: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields.

: Chemical-resistant, impervious gloves complying with an approved standard should be

worn at all times when handling chemical products if a risk assessment indicates this is necessary.

: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.


Respiratory protection : Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.


Appearance Physical state Color

Odor Odor threshold pH

: Solid. [Grease.] : Green. : Mild. Petroleum oil : Not available. : Not available.




Melting point : Not available. Boiling point : Not available. Flash point Evaporation rate

: Not available. : Not available.

Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits

: Not available.

Vapor pressure Vapor density Relative density Solubility Partition coefficient: n- octanol/water Auto-ignition temperature

: Not available. : Not available. : 0.9 : Negligible. : Not available.

: Not available.

Decomposition temperature : Not available. Viscosity : Kinematic (40°C (104°F)): 1.29 cm2/s (129 cSt)



Chemical stability : The product is stable.


: Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to avoid : No specific data.

Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials.


: Under normal conditions of storage and use, hazardous decomposition products should not be produced.


Information on toxicological effects Acute toxicity There is no data available. Irritation/Corrosion There is no data available. Sensitization There is no data available. Carcinogenicity There is no data available. Specific target organ toxicity (single exposure) There is no data available. Specific target organ toxicity (repeated exposure)




There is no data available. Aspiration hazard There is no data available.



: Dermal contact. Eye contact. Inhalation. Ingestion.

Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics Eye contact : No known significant effects or critical hazards. Inhalation Skin contact Ingestion

: No known significant effects or critical hazards. : No known significant effects or critical hazards. : No known significant effects or critical hazards.

Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure


: No known significant effects or critical hazards.

Potential delayed effects : No known significant effects or critical hazards. Long term exposure


: No known significant effects or critical hazards.

Potential delayed effects : No known significant effects or critical hazards. Potential chronic health effects

General : Carcinogenicity : Mutagenicity : Teratogenicity :

No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards.

Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity Acute toxicity estimates There is no data available.




Toxicity There is no data available.

Persistence and degradability There is no data available.

Bioaccumulative potential There is no data available.

Mobility in soil


: Not available.


Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal

of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.


DOT Classification IMDG IATA

UN number Not regulated. Not regulated.

Not regulated.

UN proper - - - shipping name

Transport - - - hazard class(es)

Packing group - - -



No. No. No. - - -

AERG : Not applicable





Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

: Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

: Not available.

Section 15. Regulatory information

U.S. Federal regulations : TSCA 8(a) CDR Exempt/Partial exemption: Not determined

United States inventory (TSCA 8b): All components are listed or exempted.

Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances




SARA 302/304

: Not listed : Not listed : Not listed : Not listed : Not listed


No products were found. SARA 304 RQ : Not applicable.

SARA 311/312 Classification : Not applicable. Composition/information on ingredients

State regulations

Massachusetts

: None of the components are listed.

New York : None of the components are listed. New Jersey : None of the components are listed. Pennsylvania : None of the components are listed. California Prop. 65



Hazardous Material Information System (U.S.A.) Health : 0 Flammability : 0 Physical hazards : 0 Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.





Health : 0 Flammability : 0

Instability : 0



History Date of issue mm/dd/yyyy

: 03/15/2014

Version : 1 Revised Section(s) : Not applicable. Prepared by : KMK Regulatory Services Inc.

Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations

Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

MAPP GAS (Petroleum Gas, MAPD)

MAP,MAPP,Methylacetylene-Propadiene, Mixture of Methylacetylene and Propadiene

Liquefied gas

SAFETY DATA SHEET



Product type


:

:




Synonym : MAP,MAPP,Methylacetylene-Propadiene, Mixture of Methylacetylene and PropadieneSDS # : 002015

Airgas USA, LLC and its affiliates259 North Radnor-Chester RoadSuite 100Radnor, PA 19087-52831-610-687-5253



FLAMMABLE GASES - Category 1GASES UNDER PRESSURE - Liquefied gas


:


Hazard statements : Extremely flammable gas.May form explosive mixtures with air.Contains gas under pressure; may explode if heated.May cause frostbite.May displace oxygen and cause rapid suffocation.

Hazard pictograms :


Prevention : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Response : Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Eliminate all ignition sources if safe to do so.



GHS label elements

General : Read and follow all Safety Data Sheets (SDS’S) before use. Read label before use.Keep out of reach of children. If medical advice is needed, have product container or label at hand. Close valve after each use and when empty. Use equipment rated for cylinder pressure. Do not open valve until connected to equipment prepared for use.Use a back flow preventative device in the piping. Use only equipment of compatible materials of construction. Always keep container in upright position. Approach suspected leak area with caution.


: Liquid can cause burns similar to frostbite.





propylene 37 - 55 115-07-1methyl acetylene 27 - 33 74-99-71,2-propadiene 13 - 15 463-49-0isobutane 2 - 5 75-28-5N-Butane 2 - 5 106-97-8Propane 1 - 5 74-98-6




: MAP,MAPP,Methylacetylene-Propadiene, Mixture of Methylacetylene and Propadiene

Substance/mixture :


Mixture



Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if adverse health effects persist or are severe. Ingestion of liquid can cause burns similar to frostbite. If frostbite occurs, get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. As this product rapidly becomes a gas when released, refer to the inhalation section.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs.

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. To avoid the risk of static discharges and gas ignition, soak contaminated clothing thoroughly with water before removing it. Get medical attention if symptoms occur. In case of contact with liquid, warm frozen tissues slowly with lukewarm water and get medical attention. Do not rub affected area. Wash clothing before reuse.Clean shoes thoroughly before reuse.



Eye contact

Skin contact

Inhalation

Ingestion :

:

:

:




Ingestion of liquid can cause burns similar to frostbite.:Ingestion

Skin contact : Dermal contact with rapidly evaporating liquid could result in freezing of the tissues or frostbite.

Liquid can cause burns similar to frostbite.:Eye contact


Inhalation No specific data.:

Eye contact : Adverse symptoms may include the following:, frostbite






Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.



Skin contact

Ingestion Adverse symptoms may include the following:, frostbite

Adverse symptoms may include the following:, frostbite

:

:




Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Contact supplier immediately for specialist advice. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. If involved in fire, shut off flow immediately if it can be done without risk. If this is impossible, withdraw from area and allow fire to burn. Fight fire from protected location or maximum possible distance. Eliminate all ignition sources if safe to do so.



Decomposition products may include the following materials:carbon dioxidecarbon monoxide

Contains gas under pressure. Extremely flammable gas. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. For incidents involving large quantities, thermally insulated undergarments and thick textile or leather gloves should be worn.



Extinguishing media

:

:

:

None known.


:


:


:




:

: Accidental releases pose a serious fire or explosion hazard. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas.Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing gas. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Ensure emergency procedures to deal with accidental gas releases are in place to avoid contamination of the environment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).







Large spill :


Small spill :






Store in accordance with local regulations. Store in a segregated and approved area.Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10). Eliminate all ignition sources. Cylinders should be stored upright, with valve protection cap in place, and firmly secured to prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C (125 °F). Keep container tightly closed and sealed until ready for use. See Section 10 for incompatible materials before handling or use.

:

:

Protective measures Put on appropriate personal protective equipment (see Section 8). Contains gas under pressure. Do not get in eyes or on skin or clothing. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Do not puncture or incinerate container. Use equipment rated for cylinder pressure. Close valve after each use and when empty. Protect cylinders from physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling)equipment.

:


propylene ACGIH TLV (United States, 3/2017). TWA: 500 ppm 8 hours.ACGIH TLV (United States, 1/2005). TWA: 500 ppm 8 hours. Form: All forms

methyl acetylene ACGIH TLV (United States, 3/2017). TWA: 1640 mg/m³ 8 hours. TWA: 1000 ppm 8 hours.NIOSH REL (United States, 10/2016). TWA: 1650 mg/m³ 10 hours. TWA: 1000 ppm 10 hours.OSHA PEL (United States, 6/2016). TWA: 1650 mg/m³ 8 hours. TWA: 1000 ppm 8 hours.OSHA PEL 1989 (United States, 3/1989). TWA: 1650 mg/m³ 8 hours. TWA: 1000 ppm 8 hours.

1,2-propadiene None.isobutane NIOSH REL (United States, 10/2016).

TWA: 1900 mg/m³ 10 hours. TWA: 800 ppm 10 hours.



Control parameters




Section 8. Exposure controls/personal protectionACGIH TLV (United States, 3/2017). STEL: 1000 ppm 15 minutes.

N-Butane NIOSH REL (United States, 10/2016). TWA: 1900 mg/m³ 10 hours. TWA: 800 ppm 10 hours.OSHA PEL 1989 (United States, 3/1989). TWA: 1900 mg/m³ 8 hours. TWA: 800 ppm 8 hours.ACGIH TLV (United States, 3/2017). STEL: 1000 ppm 15 minutes.

Propane NIOSH REL (United States, 10/2016). TWA: 1800 mg/m³ 10 hours. TWA: 1000 ppm 10 hours.OSHA PEL (United States, 6/2016). TWA: 1800 mg/m³ 8 hours. TWA: 1000 ppm 8 hours.OSHA PEL 1989 (United States, 3/1989). TWA: 1800 mg/m³ 8 hours. TWA: 1000 ppm 8 hours.ACGIH TLV (United States, 3/2017). Oxygen Depletion [Asphyxiant].

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. If contact with the liquid is possible, insulated gloves suitable for low temperatures should be worn. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.


Eye/face protection

:

:

Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.

:




: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas,vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.


Hygiene measures :


Skin protection




Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.



Thermal hazards : If there is a risk of contact with the liquid, all protective equipment worn should be suitable for use with extremely low temperature materials.


Physical state

Melting point

Relative density

Solubility

Gas. [Liquefied gas]

-102.7°C (-152.9°F) This is based on data for the following ingredient: Methyl Acetylene.Weighted average: -152.81°C (-243.1°F)

Not applicable.

Not available.

Not available.Odor

pH

Not available.Color



Flash point

Not available.

Not available.

Not available.

Not available.

Viscosity Not applicable.



:

:

:

:

:

:

:

:

:

:

:

:

:

Appearance

Boiling point : Not available.

Flammability (solid, gas) : Not available.


: Lower: 2%Upper: 13%


Solubility in water : Not available.

: 42 g/molMolecular weight


Vapor pressure

Vapor density Highest known value: 2.1 (Air = 1) (butane). Weighted average: 1.52 (Air = 1)

Not available.:

:

Gas Density (lb/ft 3) : Weighted average: 0.11

Critical temperature : Lowest known value: 91.85°C (197.3°F) (Propylene).


Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition.

The product is stable.Chemical stability

Oxidizers

:

:



: Hazardous reactions or instability may occur under certain conditions of storage or use.







:

May Occur.

Conditions to Avoid: Elevated tempertures and pressures. Polymerization catalysts,such as metal alkyls, can cause uncontrolled polymerization. Contamination with oxygen can cause propadiene to form hazardous peroxides.

INHIBITORS/STABILIZERS

An ihibitor is added to the MAPD mixture to prevent potential unstable peroxide formation. Butanes (iso and/or normal) are also added to the MAPD mixture to prevent potential concentration of the methylacetylene and propadiene from reaching concentration levels that would render the mixture unstable in case of weathering off (evaporation of light components).

Hazardous polymerization :


Acute toxicity

isobutane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hoursN-Butane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours

Product/ingredient name Result Species Dose Exposure

Carcinogenicity

Not available.

Mutagenicity

Not available.

Teratogenicity

Not available.


Not available.


Not available.

Sensitization

Not available.



Not available.

Not available.

Aspiration hazard

Not available.


Classification

propylene - 3 -

Product/ingredient name NTPIARCOSHA




Not available.



Ingestion of liquid can cause burns similar to frostbite.:Ingestion

Skin contact : Dermal contact with rapidly evaporating liquid could result in freezing of the tissues or frostbite.

Liquid can cause burns similar to frostbite.:Eye contact








Skin contact

Ingestion




:

:

:

Eye contact : Adverse symptoms may include the following:, frostbite




Not available.


: Not available.



: Not available.

Short term exposure



: Not available.

Long term exposure




Toxicity

Not available.


Not available.



Section 12. Ecological informationLogPow BCF Potential



propylene 1.77 - lowmethyl acetylene 0.94 - low1,2-propadiene 1.45 - lowisobutane 2.8 - lowN-Butane 2.89 - lowPropane 1.09 - low


: Not available.

Mobility in soil


:Disposal methods


Methyl Acetylene andPropadiene mixtures,stabilized

2.1

-


2.1

-


UN1060

2.1

-

UN1060 UN1060

DOT IMDG IATA

UN number



Packing group



No. No. No.

TDG

UN1060


2.1

-

No.

Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.13-2.17 (Class 2).Explosive Limit and Limited Quantity Index 0.125ERAP Index 3000Passenger Carrying Road or Rail Index Forbidden

Mexico

UN1060


2.1

-

No.

TDG Classification :




Section 14. Transport informationSpecial precautions for user



: Not available.

:


The following components are listed: PROPYLENE; PROPENE; PROPYNE; METHYL ACETYLENE; ISOBUTANE; BUTANE; PROPANE

Clean Air Act (CAA) 112 regulated flammable substances: Propylene; Methyl Acetylene; Propadiene; Isobutane; butane; propane

Massachusetts

:

:

SARA 313

Product name CAS number %

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.

Propylene 115-07-1 37 - 55

Propylene 115-07-1 37 - 55

Form R - Reporting requirements

Supplier notification


: Not listed


: Not listed


: Not listed


: Not listed


: Not listed

New York : None of the components are listed.

New Jersey : The following components are listed: PROPYLENE; 1-PROPENE; METHYL ACETYLENE; 1-PROPYNE; PROPADIENE; 1,2-PROPADIENE; Isobutane; PROPANE,2-METHYL-; BUTANE; PROPANE

Pennsylvania : The following components are listed: 1-PROPENE; 1-PROPYNE; PROPANE,2-METHYL-; BUTANE; PROPANE

State regulations

TSCA 8(a) CDR Exempt/Partial exemption: Not determined

SARA 302/304







Not listed.

Not listed.

SARA 311/312




Section 15. Regulatory informationStockholm Convention on Persistent Organic Pollutants

Not listed.


Not listed.


Not listed.

Inventory list

Australia : All components are listed or exempted.

Canada : All components are listed or exempted.

China : Not determined.

Europe : All components are listed or exempted.

Japan : Japan inventory (ENCS): Not determined.Japan inventory (ISHL): Not determined.

Republic of Korea : All components are listed or exempted.


New Zealand : All components are listed or exempted.

Philippines : All components are listed or exempted.

Taiwan : All components are listed or exempted.

Turkey : Not determined.

United States : All components are listed or exempted.



Section 16. Other informationHazardous Material Information System (U.S.A.)

1

4

3

14

1

/


Health

Special


Flammability

Health

Flammability

Physical hazards







10/22/2018

History

Date of printing


Version


Notice to reader


:

:

:

:


Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations

10/22/2018

2/6/2018

1.01




FLAMMABLE GASES - Category 1 Expert judgmentGASES UNDER PRESSURE - Liquefied gas Expert judgment


Safety Data Sheet MasterSeal NP 1 White also NP1 WHT Revision date : 2015/05/06 Page: 1/12 Version: 2.1 (30617032/SDS_GEN_US/EN)

1. Identification

Product identifier used on the label

MasterSeal NP 1 White also NP1 WHT

Recommended use of the chemical and restriction on use Recommended use*: for industrial and professional users * The “Recommended use” identified for this product is provided solely to comply with a Federal requirement and is not part of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement.

Details of the supplier of the safety data sheet Company: BASF CORPORATION 100 Park Avenue Florham Park, NJ 07932, USA

Telephone: +1 973 245-6000

Emergency telephone number CHEMTREC: 1-800-424-9300 BASF HOTLINE: 1-800-832-HELP (4357)

Other means of identification Chemical family: sealant

2. Hazards Identification

According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200

Classification of the product Acute Tox. 4 (Inhalation - vapour) Acute toxicity Eye Dam./Irrit. 2A Serious eye damage/eye irritation Resp. Sens. 1 Respiratory sensitization Skin Sens. 1 Skin sensitization Carc. 2 Carcinogenicity STOT RE 1 Specific target organ toxicity — repeated

exposure

Label elements


Pictogram:

Signal Word: Danger Hazard Statement: H332 Harmful if inhaled. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if

inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H372 Causes damage to organs (Central nervous system) through prolonged

or repeated exposure. Precautionary Statements (Prevention): P280 Wear protective gloves/protective clothing/eye protection/face

protection. P271 Use only outdoors or in a well-ventilated area. P260 Do not breathe dust/gas/mist/vapours. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and

understood. P284 [In case of inadequate ventilation] wear respiratory protection. P270 Do not eat, drink or smoke when using this product. P264 Wash with plenty of water and soap thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. Precautionary Statements (Response): P308 + P311 IF exposed or concerned: Call a POISON CENTER or doctor/physician. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing. P304 + P341 + P311 IF INHALED: If breathing is difficult, remove to fresh air and keep at rest

in a position comfortable for breathing. Call a POISON CENTER or doctor/physician.

P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P303 + P352 IF ON SKIN (or hair): Wash with plenty of soap and water. P333 + P311 If skin irritation or rash occurs: Call a POISON CENTER or

doctor/physician. P362 + P364 Take off contaminated clothing and wash before reuse. P337 + P311 If eye irritation persists: Call a POISON CENTER or doctor/physician. Precautionary Statements (Storage): P405 Store locked up. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection

point.



If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture. Labeling of special preparations (GHS): CONTAINS ISOCYANATES. INHALATION OF ISOCYANATE MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST DISCOMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG-TERM EXPOSURE TO ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED LUNG FUNCTION WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE SENSITIZATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPIRATORY REACTIONS INCLUDING WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING. ANIMAL TESTS INDICATE THAT SKIN CONTACT MAY PLAY A ROLE IN CAUSING RESPIRATORY SENSITIZATION.

3. Composition / Information on Ingredients

According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 CAS Number Content (W/W) Chemical name 1317-65-3 >= 15.0 - < 20.0 % Limestone 13463-67-7 >= 3.0 - < 5.0 % Titanium dioxide 14807-96-6 >= 3.0 - < 5.0 % talc 1305-78-8 >= 1.0 - < 3.0 % calcium oxide 8052-41-3 >= 1.0 - < 3.0 % Stoddard solvent 91-08-7 >= 0.4 - < 0.5 % toluene-2,6-diisocyanate 2530-83-8 >= 0.3 - < 1.0 % trimethoxy(3-(oxiranylmethoxy)propyl)silane 584-84-9 >= 0.03 - < 0.04 % toluene-2,4-diisocyanate

4. First-Aid Measures

Description of first aid measures General advice: Remove contaminated clothing. If inhaled: Remove the affected individual into fresh air and keep the person calm. Assist in breathing if necessary. Immediate medical attention required. If on skin: Wash affected areas thoroughly with soap and water. If irritation develops, seek medical attention. If in eyes: In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water. Immediate medical attention required. If swallowed: Rinse mouth and then drink plenty of water. Do not induce vomiting. Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Immediate medical attention required.

Most important symptoms and effects, both acute and delayed


Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11. Hazards: No applicable information available. Symptoms can appear later.

Indication of any immediate medical attention and special treatment needed Note to physician Antidote: Specific antidotes or neutralizers to isocyanates do not exist. Treatment: Treatment should be supportive and based on the judgement of the

physician in response to the reaction of the patient.

5. Fire-Fighting Measures

Extinguishing media Suitable extinguishing media: foam, water spray, dry powder, carbon dioxide Unsuitable extinguishing media for safety reasons: water jet

Special hazards arising from the substance or mixture Hazards during fire-fighting: nitrous gases, fumes/smoke, isocyanate, vapour

Advice for fire-fighters Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear. Further information: Keep containers cool by spraying with water if exposed to fire. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.


Personal precautions, protective equipment and emergency procedures Clear area. Ensure adequate ventilation. Wear suitable personal protective clothing and equipment.

Environmental precautions Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.

Methods and material for containment and cleaning up For small amounts: Absorb isocyanate with suitable absorbent material (see § 40 CFR, sections 260, 264 and 265 for further information). Shovel into open container. Do not make container pressure tight. Move container to a well-ventilated area (outside). Spill area can be decontaminated with the following recommended decontamination solution: Mixture of 90 % water, 8 % concentrated ammonia, 2 % detergent. Add at a 10 to 1 ratio. Allow to stand for at least 48 hours to allow escape of evolved carbon dioxide. For large amounts: If temporary control of isocyanate vapor is required, a blanket of protein foam or other suitable foam (available from most fire departments) may be placed over the spill. Transfer as


much liquid as possible via pump or vacuum device into closed but not sealed containers for disposal. For residues: The following measures should be taken for final cleanup: Wash down spill area with decontamination solution. Allow solution to stand for at least 10 minutes. Dike spillage.


Precautions for safe handling Provide suitable exhaust ventilation at the processing machines. Ensure thorough ventilation of stores and work areas. Avoid aerosol formation. When handling heated product, vapours of the product should be ventilated, and respiratory protection used. Wear respiratory protection when spraying. Danger of bursting when sealed gastight. Protect against moisture. If bulging of drum occurs, transfer to well ventilated area, puncture to relieve pressure, open vent and let stand for 48 hours before resealing. Protection against fire and explosion: Keep away from sources of ignition - No smoking. The relevant fire protection measures should be noted.

Conditions for safe storage, including any incompatibilities No applicable information available. Further information on storage conditions: Keep only in the original container in a cool, well-ventilated place. Protect from direct sunlight. Store protected against freezing. Storage stability: Storage temperature: 5 - 32 °C Protect from temperatures below: -17 °C Protect from temperatures above: 48 °C

8. Exposure Controls/Personal Protection

Components with occupational exposure limits

toluene-2,6-diisocyanate ACGIH TLV TWA value 0.005 ppm ; STEL value 0.02 ppm

; calcium oxide OSHA PEL PEL 5 mg/m3 ; TWA value 5 mg/m3 ;

ACGIH TLV TWA value 2 mg/m3 ; Limestone OSHA PEL PEL 5 mg/m3 Respirable fraction ; PEL 15

mg/m3 Total dust ; TWA value 15 mg/m3 Total dust ; TWA value 5 mg/m3 Respirable fraction ;

Titanium dioxide OSHA PEL PEL 15 mg/m3 Total dust ; TWA value 10

mg/m3 Total dust ; ACGIH TLV TWA value 10 mg/m3 ;


talc OSHA PEL TWA value 20 millions of particles per cubic foot of air ; TWA value 2.4 millions of particles per cubic foot of air Respirable ; The exposure limit is calculated from the equation, 250/(%SiO2+5), using a value of 100% SiO2. Lower percentages of SiO2 will yield higher exposure limits. TWA value 0.1 mg/m3 Respirable ; The exposure limit is calculated from the equation, 10/(%SiO2+2), using a value of 100% SiO2. Lower percentages of SiO2 will yield higher exposure limits. TWA value 0.3 mg/m3 Total dust ; The exposure limit is calculated from the equation, 30/(%SiO2+2), using a value of 100% SiO2. Lower percentages of SiO2 will yield higher exposure limits. TWA value 2 mg/m3 Respirable dust ; TWA value 0.3 mg/m3 Total dust ; The exposure limit is calculated from the equation, 30/(%SiO2+2), using a value of 100% SiO2. Lower percentages of SiO2 will yield higher exposure limits. TWA value 0.1 mg/m3 Respirable ; The exposure limit is calculated from the equation, 10/(%SiO2+2), using a value of 100% SiO2. Lower percentages of SiO2 will yield higher exposure limits. TWA value 2.4 millions of particles per cubic foot of air Respirable ; The exposure limit is calculated from the equation, 250/(%SiO2+5), using a value of 100% SiO2. Lower percentages of SiO2 will yield higher exposure limits. TWA value 20 millions of particles per cubic foot of air ;

ACGIH TLV TWA value 2 mg/m3 Respirable fraction ; The value is for particulate matter containing no asbestos and <1% crystalline silica.

Stoddard solvent OSHA PEL PEL 500 ppm 2,900 mg/m3 ;

ACGIH TLV TWA value 100 ppm ; Advice on system design: Provide adequate exhaust ventilation to control work place concentrations.

Personal protective equipment

Respiratory protection: When workers are facing concentrations above the occupational exposure limits they must use appropriate certified respirators. When atmospheric levels may exceed the occupational exposure limit (PEL or TLV) NIOSH-certified air-purifying respirators equipped with an organic vapor sorbent and particulate filter can be used as long as appropriate precautions and change out schedules are in place. For emergency or non-routine, high exposure situations, including confined space entry, use a NIOSH-certified full facepiece pressure demand self-contained breathing apparatus (SCBA) or a full facepiece pressure demand supplied-air respirator (SAR) with escape provisions.


Hand protection: Chemical resistant protective gloves should be worn to prevent all skin contact., Suitable materials may include, chloroprene rubber (Neoprene), nitrile rubber (Buna N), chlorinated polyethylene, polyvinylchloride (Pylox), butyl rubber, depending upon conditions of use. Eye protection: Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists. Body protection: Cover as much of the exposed skin as possible to prevent all skin contact., Suitable materials may include, saran-coated material, depending upon conditions of use. General safety and hygiene measures: Avoid contact with the skin, eyes and clothing. No special measures necessary if stored and handled correctly. Handle in accordance with good building materials hygiene and safety practice. Wearing of closed work clothing is recommended. Wear protective clothing as necessary to prevent contact. Eye wash fountains and safety showers must be easily accessible. Observe the appropriate PEL or TLV value. Wash soiled clothing immediately. Contaminated equipment or clothing should be cleaned after each use or disposed of.


Form: paste Odour: mild Odour threshold: No applicable information available. Colour: white pH value: No applicable information available. Melting point: No applicable information available. Boiling point: No applicable information available. Sublimation point: No applicable information available. Flash point: Non-flammable. Flammability: not flammable (UN Test N.1 (ready combustible solids)) Lower explosion limit: No applicable information available. Upper explosion limit: No applicable information available. Autoignition: No applicable information available. Vapour pressure: No applicable information available. Density: 10.1 lb/USg ( 25 °C) Relative density: No applicable information available. Vapour density: No applicable information available. Partitioning coefficient n-octanol/water (log Pow):

No applicable information available.

Self-ignition temperature:

not self-igniting

Thermal decomposition: No decomposition if stored and handled as prescribed/indicated.

Viscosity, dynamic: No applicable information available. Viscosity, kinematic: No applicable information available. Solubility in water: ( 15 °C) insoluble Miscibility with water: ( 15 °C) not (e.g. <10%) Solubility (quantitative): No applicable information available. Solubility (qualitative): No applicable information available. Evaporation rate: No applicable information available. Other Information: If necessary, information on other physical and chemical

parameters is indicated in this section.



Reactivity No hazardous reactions if stored and handled as prescribed/indicated. Oxidizing properties: Not an oxidizer.

Chemical stability The product is stable if stored and handled as prescribed/indicated.

Possibility of hazardous reactions The product is stable if stored and handled as prescribed/indicated.

Conditions to avoid See MSDS section 7 - Handling and storage.

Incompatible materials strong acids, strong bases, strong oxidizing agents, strong reducing agents

Hazardous decomposition products Decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. Thermal decomposition: No decomposition if stored and handled as prescribed/indicated.


Primary routes of exposure Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases.

Acute Toxicity/Effects Acute toxicity Assessment of acute toxicity: Harmful by inhalation. Inhalation Type of value: ATE Value: 14.8 mg/l Determined for vapor Assessment other acute effects No applicable information available. Irritation / corrosion Assessment of irritating effects: Eye contact causes irritation. Skin contact causes irritation. The product has not been tested. The statement has been derived from the properties of the individual components. Sensitization


Assessment of sensitization: Sensitization after skin contact possible. The substance may cause sensitization of the respiratory tract.

Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: Prolonged exposure may cause chronic effects. Genetic toxicity Assessment of mutagenicity: The substance was mutagenic in various bacterial test systems; however, a mutagenic effect could not be confirmed in mammalian cell culture. Carcinogenicity Assessment of carcinogenicity: Contains a compound classified as IARC Group 2B (possibly carcinogenic to humans). Information on: Titanium dioxide Assessment of carcinogenicity: IARC (International Agency for Research on Cancer) has classified this substance as group 2B (The agent is possibly carcinogenic to humans). In long-term studies in rats in which the substance was given by inhalation, a carcinogenic effect was observed. Tumors were only observed in rats after chronic inhalative exposure to high concentrations which caused sustained lung inflammation. In long-term studies in rats and mice in which the substance was given by feed, a carcinogenic effect was not observed. Dermal exposure is not expected to be carcinogenic. Information on: toluene-2,6-diisocyanate Assessment of carcinogenicity: IARC (International Agency for Research on Cancer) has classified this substance as group 2B (The agent is possibly carcinogenic to humans). ---------------------------------- Reproductive toxicity Assessment of reproduction toxicity: The results of animal studies gave no indication of a fertility impairing effect. Teratogenicity Assessment of teratogenicity: No indications of a developmental toxic / teratogenic effect were seen in animal studies. Other Information Based on our experience and the information available, no adverse health effects are expected if handled as recommended with suitable precautions for designated uses. The product has not been tested. The statements on toxicology have been derived from the properties of the individual components.

Symptoms of Exposure The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11. Medical conditions aggravated by overexposure The isocyanate component is a respiratory sensitizer. It may cause allergic reaction leading to asthma-like spasms of the bronchial tubes and difficulty in breathing. Medical supervision of all employees who handle or come into contact with isocyanates is recommended. Contact may aggravate pulmonary disorders. Persons with history of respiratory disease or hypersensitivity should not be exposed to this product. Preemployment and periodic medical examinations with respiratory function tests (FEV, FVC as a minimum) are suggested. Persons with asthmatic conditions, chronic bronchitis, other chronic respiratory diseases, recurrent eczema or pulmonary sensitization should


be excluded from working with isocyanates. Once a person is diagnosed as having pulmonary sensitization (allergic asthma) to isocyanates, further exposure is not recommended.


Toxicity Aquatic toxicity Assessment of aquatic toxicity: Based on available Data, the classification criteria are not met.

Persistence and degradability Assessment biodegradation and elimination (H2O) Poorly biodegradable. The product is unstable in water. The elimination data also refer to products of hydrolysis. Assessment biodegradation and elimination (H2O) Information on: TDI Poorly biodegradable. The product is unstable in water. The elimination data also refer to products of hydrolysis. ----------------------------------

Mobility in soil Assessment transport between environmental compartments Adsorption to solid soil phase is not expected.

Additional information Other ecotoxicological advice: Do not discharge product into the environment without control. The product has not been tested. The statements on ecotoxicology have been derived from the properties of the individual components.


Waste disposal of substance: Dispose of in accordance with local authority regulations. Do not discharge into drains/surface waters/groundwater.

14. Transport Information

Land transport USDOT

Not classified as a dangerous good under transport regulations

Sea transport IMDG



Air transport IATA/ICAO



Federal Regulations Registration status: Chemical TSCA, US released / listed EPCRA 311/312 (Hazard categories): Acute; Chronic CERCLA RQ CAS Number Chemical name 5000 LBS 7664-38-2 phosphoric acid 1000 LBS 108-88-3 Toluene 100 LBS 108-90-7; 584-84-

9; 91-08-7 chlorobenzene; toluene-2,4-diisocyanate; toluene-2,6-diisocyanate

State regulations CA Prop. 65: WARNING: THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. NFPA Hazard codes: Health : 2 Fire: 1 Reactivity: 1 Special: HMIS III rating Health: 2¤ Flammability: 1 Physical hazard: 1


SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2015/05/06 We support worldwide Responsible Care® initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products.

IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR


TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE ASSUME NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. END OF DATA SHEET

S A F E T Y D A T A S H E E T

NOKORODE® REGULARSoldering paste flux

Page 1

EMERGENCY OVERVIEW

OSHA Hazards Irritant

GHS CLASSIFICATION

Physical Hazards None

Health Hazards

Acute Toxicity: Oral: Not Classified Dermal: Not Classified Inhalation: Not Classified Skin Corrosion/Irritation: Not Classified Serious Eye Damage/Eye Irritation: Not Classified Respiratory or Skin Sensitization: Not Classified

Section 2 – HazardS identification

Section 1 – Product and comPany information

Product Name Nokorode® Regular Paste Flux

Product Codes 14000, 14003, 14010, 14020, 14030

Chemical Family Organic/Inorganic

Use Soldering flux

Manufacturer's Name The RectorSeal Corporation 2601 Spenwick Drive Houston, Texas 77055 USA

Date of Validation January 23, 2015

Date of Preparation May 2, 2012

HMIS Codes Health 1 Flammability 1 Reactivity 0 PPI B

Emergency Telephone No. Chemtrec 24 Hours (800)-424-9300 USA (703)-527-3887 International

Technical Service Telephone No. ( 800)-231-3345 or (713)-263-8001

NOKORODE® REGULAR

Page 2

Germ Cell Mutagenicity: Not Classified Carcinogenicity: Not Classified Reproductive Toxicology: Not Classified Target Organ Systemic Toxicity - Single Exposure: Not Classified Target Organ Systemic Toxicity - Repeated Exposure: Not Classified

Aspiration Toxicity: Not Classified

ENVIRONMENTAL HAZARDS Hazardous to the Aquatic Environment: Not Classified Acute aquatic toxicity: Not Classified Chronic aquatic toxicity: Not Classified Bioaccumulation potential: Not Classified Rapid degradability: Not Classified

GHS Label elements, including precautionary statements

GHS07: Exclamation Mark/Irritant Signal Word: Warning

Hazard Statements: H302 - Harmful if swallowed. H315 - Causes skin irritation. H319 - Causes serious eye irritation.

Precautionary Statements: P102 - Keep out of reach of children. P262 - Do not get in eyes, on skin, or on clothing. P264 - Wash hands thoroughly after handling. P281 Use personal protective equipment as required.

Summary Of Acute Hazards

Irritation to respiratory system from fumes evolved during soldering. Eye contact may cause intense irritation and injury.

Route Of Exposure, Signs And Symptoms

INHALATION Irritation to respiratory system from fumes evolved during soldering.

EYE CONTACT Contact may cause intense irritation and injury.

SKIN CONTACT May cause skin irritation.

INGESTION Nausea, vomiting, irritation to digestive system.

NOKORODE® REGULAR

Page 3

Section 3 – comPoSition/information on ingredientS

Ingredient: Zinc Chloride

Percentage By Weight: 10-25

CAS Number: 7646-85-7

EC#: 231-592-0

Ingredient: Ammonium Chloride


CAS#: 12125-02-9

EC#: 235-186-4

Ingredient: Petrolatum


CAS#: 8009-03-8

EC#: 232-373-2

SUMMARY OF CHRONIC HAZARDS Short term effects to liver and kidneys can occur. Chemical irritation from continued skin contact can occur. Continuous industrial use in small unventilated areas may result in sufficient inhalation of solder and flux fumes to cause lung damage and irritation of respiratory tract.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Individuals with pre-existing or chronic diseases of the eyes, skin, respiratory system, cardiovascular system, gastrointestinal system, liver, or kidneys may have increased susceptibility to excessive exposure.

Section 4 – firSt aid meaSureS

If inhaled: If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial respiration as needed. Obtain emergency medical attention. Prompt action is essential.

If on skin: Immediately wash with soap and water. Remove and wash any contaminated clothing.

If in eyes: Immediately flush with large amounts of water for at least 15 minutes. Get prompt medical attention if irritation persists.

If swallowed: If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person.

NOKORODE® REGULAR

Page 4

Section 5 – fire figHting meaSureS

Section 6 – accidental releaSe meaSureS

Extinguishing Media Foam, dry chemical, carbon dioxide or water fog.

Special Fire Fighting Procedures: Wear self-contained full face piece breathing apparatus and other protective clothing. Hazardous decomposition products possible (see Section 10). May release ZnO and HCl fumes.

Unusual Fire And Explosion Hazards: Heat may build up pressure and rupture closed containers.

Steps To Be Taken In Case Material Is Released Or Spilled: Wipe up spills to prevent footing hazard. Avoid flushing into sewers, drains, waterways and soil. Wear protective clothing during clean up.

Section 7 – Handling and Storage

Precautions To Be Taken In Handling And Storing: Keep container closed and upright when not in use. Store flux at ambient conditions. Wash thoroughly after handling to remove all residue.

Other Precautions: Avoid prolonged or repeated contact with skin or clothing. Empty containers may contain residues; treat as if full and observe all products precautions. Do not reuse empty containers.

Section 8 – exPoSure controlS/PerSonal Protection

Ingredient Units

Zinc Chloride ACGIH TLV: 1 mg/m3 OSHA PEL: 1 mg/m3

Ammonium Chloride ACGIH TLV: 10 mg/m3 OSHA PEL: 10 mg/m3

Petrolatum ACGIH TLV: N/D OSHA PEL: N/D

Respiratory Protection (Specify Type): In confined poorly ventilated areas, use NIOSH/MSHA approved air purifying or supplied air purifying or supplied air respirators during soldering operations until fumes have dissipated.

Ventilation − Local Exhaust: Acceptable

Special: N/A

Mechanical (General): Acceptable.

Other: N/A

Protective Gloves: Wear rubber gloves.

NOKORODE® REGULAR

Page 5

Section 10 – Stability and reactivity

Stability: Stable

Conditions To Avoid: None

Incompatibility (Materials To Avoid): None known

Hazardous Decomposition Products: Toxic fumes of zinc, chlorine, and HCL may be evolved during soldering.

Hazardous Polymerization: Will not occur.

Eye Protection: Safety glasses (ANSI Z-87.1 or equivalent)

Other Protective Clothing Or Equipment: Coveralls recommended.

Work/Hygienic Practices: Where use can result in skin contact, wash exposed areas thoroughly before eating, drinking, smoking, or leaving work area. Launder contaminated clothing before reuse.

Section 9 – PHySical and cHemical ProPertieS

Boiling point: N/A Specific gravity (H20 = 1): 1.06

Vapor pressure (mmHg): < 0.01 @ 68°F (20°C)

Melting point: 120° – 150°F (52° – 66°C)

Vapor Density (Air = 1): N/A

Evaporation rate (Ethyl Acetate = 1): N/A

Appearance/Odor: Tan/Petroleum odor

Solubility in water: Insoluble

Volatile Organic Compounds (VOC) Content (theoretical percentage by weight): 0% or (0 g/L)

Flash point: > 400°F (204°C) SETA CC

Lower explosion limit: N/D

Upper explosion limit: N/D

Section 11 – toxicology information

Chronic Health Hazards No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.

Toxicology Data

Ingredient Name

Zinc Chloride Oral-Rat LD50: 350 mg/kg Inhalation-Rat LCLo: 1960 mg/m3/10M

NOKORODE® REGULAR

Page 6

Section 12 – ecological information

Ecological Data

Ingredient Name: Zinc Chloride

Food Chain Concentration Potential None

Waterfowl Toxicity N/A

BOD None

Aquatic Toxicity 7.2 ppm/96 hr/medium bluegill/TLm

Ingredient Name: Ammonium Chloride

Food Chain Concentration Potential None


BOD N/A

Aquatic Toxicity 6 ppm/96 hr/sunfish TLm

Ingredient Name: Petrolatum

Food Chain Concentration Potential N/D

Waterfowl Toxicity N/D

BOD N/D

Aquatic Toxicity N/D

Ammonium Chloride Oral-Rat LD50: 1650 mg/kg Inhalation-Rat LC50: N/D

Petrolatum Oral-Rat LD50: N/D Inhalation-Rat LC50: N/D

Section 13 – diSPoSal conSiderationS

Waste Classification: Non-regulated solid waste

Disposal Method: Approved landfill

Waste from this product is not considered hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Dispose of in accordance with Federal, State, and Local regulation regarding pollution.

NOKORODE® REGULAR

Page 7

Section 15 – regulatory information

Regulatory Data

Ingredient Name: Zinc Chloride

SARA 313 Yes

TSCA Inventory Yes

CERCLA RQ 1,000 lb.

RCRA Code N/A

Ingredient Name: Ammonium Chloride

SARA 313 No

TSCA Inventory Yes

CERCLA RQ N/A

RCRA Code N/A

Ingredient Name: Petrolatum

SARA 313 No

TSCA Inventory Yes

CERCLA RQ N/A

RCRA Code N/A

Section 14 – tranSPortation information

DOT: Non-regulated

Ocean (IMDG): Non-regulated

Air (IATA): Non-regulated

WHMIS (Canada): Non-regulated

Section 16 – otHer information

This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200). The information herein is given in good faith, but no warranty, expressed or implied is made.

Consult RectorSeal for further information: (713) 263-8001

Oxygen

Molecular oxygen; Oxygen molecule; Pure oxygen; O2; UN 1072; Dioxygen; Oxygen USP, Aviator’s Breathing Oxygen (ABO)

Gas.

SAFETY DATA SHEET



Product type


:

:

Chemical name : oxygen


Oxygen


Synonym : Molecular oxygen; Oxygen molecule; Pure oxygen; O2; UN 1072; Dioxygen; Oxygen USP, Aviator’s Breathing Oxygen (ABO)

SDS # : 001043Airgas USA, LLC and its affiliates259 North Radnor-Chester RoadSuite 100Radnor, PA 19087-52831-610-687-5253



OXIDIZING GASES - Category 1GASES UNDER PRESSURE - Compressed gas


:


Hazard statements : May cause or intensify fire; oxidizer.Contains gas under pressure; may explode if heated.

Hazard pictograms :


Prevention : Keep away from clothing, incompatible materials and combustible materials. Keep reduction valves, valves and fittings free from oil and grease.

Response : In case of fire: Stop leak if safe to do so.



GHS label elements

General : Read and follow all Safety Data Sheets (SDS’S) before use. Read label before use.Keep out of reach of children. If medical advice is needed, have product container or label at hand. Close valve after each use and when empty. Use equipment rated for cylinder pressure. Do not open valve until connected to equipment prepared for use.Use a back flow preventative device in the piping. Use only equipment of compatible materials of construction. Open valve slowly. Use only with equipment cleaned for Oxygen service.


: None known.



Oxygen


oxygen 100 7782-44-7



Chemical name : oxygen


: Molecular oxygen; Oxygen molecule; Pure oxygen; O2; UN 1072; Dioxygen; Oxygen USP, Aviator’s Breathing Oxygen (ABO)

CAS number : 7782-44-7

Substance/mixture


:


Substance



As this product is a gas, refer to the inhalation section.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.



Eye contact

Skin contact

Inhalation

Ingestion :

:

:

:










Skin contact

Ingestion


No specific data.

No specific data.

:

:

:






Oxygen

Section 4. First aid measuresProtection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may

be dangerous to the person providing aid to give mouth-to-mouth resuscitation.



Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Contact supplier immediately for specialist advice. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. If involved in fire, shut off flow immediately if it can be done without risk.



No specific data.

Contains gas under pressure. Oxidizing material. This material increases the risk of fire and may aid combustion. Contact with combustible material may cause fire. In a fire or if heated, a pressure increase will occur and the container may burst or explode.




Extinguishing media

:

:

:

None known.


:


:


:





:

: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Shut off all ignition sources. No flares, smoking or flames in hazard area.Avoid breathing gas. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Ensure emergency procedures to deal with accidental gas releases are in place to avoid contamination of the environment. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Large spill :


Small spill :




Section 7. Handling and storagePrecautions for safe handling


Oxygen





Store in accordance with local regulations. Store in a segregated and approved area.Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10). Cylinders should be stored upright, with valve protection cap in place, and firmly secured to prevent falling or being knocked over.Cylinder temperatures should not exceed 52 °C (125 °F). Separate from reducing agents and combustible materials. Store away from grease and oil. Keep container tightly closed and sealed until ready for use. See Section 10 for incompatible materials before handling or use.

:

:

Protective measures Put on appropriate personal protective equipment (see Section 8). Contains gas under pressure. Avoid breathing gas. Do not puncture or incinerate container. Use equipment rated for cylinder pressure. Close valve after each use and when empty.Protect cylinders from physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement. Avoid contact with eyes, skin and clothing. Empty containers retain product residue and can be hazardous. Keep away from clothing, incompatible materials and combustible materials. Keep reduction valves free from grease and oil.

:

oxygen None.



Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.


Eye/face protection

:

:




: Good general ventilation should be sufficient to control worker exposure to airborne contaminants.


Hygiene measures :

Control parameters



Skin protection


Oxygen


Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.


Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

:



Physical state

Melting point

Relative density

Solubility

Gas. [Compressed gas.]

-218.4°C (-361.1°F)

Not applicable.

Not available.

Odorless.Odor

pH

Colorless. Blue.Color



Flash point

Not available.

[Product does not sustain combustion.]

0.65

Not available.

Viscosity Not applicable.



:

:

:

:

:

:

:

:

:

:

:

:

:

Appearance

Boiling point : -183°C (-297.4°F)

Flammability (solid, gas) : Extremely flammable in the presence of the following materials or conditions: reducing materials, combustible materials and organic materials.


: Not available.


Solubility in water : Not available.

: 32 g/moleMolecular weight


Vapor pressure

Vapor density 1.1 (Air = 1)

Not available.:

:

Specific Volume (ft 3/lb) : 12.0482

Gas Density (lb/ft 3) : 0.083

Critical temperature : -118.15°C (-180.7°F)


The product is stable.Chemical stability :


: Hazardous reactions or instability may occur under certain conditions of storage or use.Conditions may include the following:contact with combustible materialsReactions may include the following:risk of causing fire



Oxygen



Conditions to avoid No specific data.


Highly reactive or incompatible with the following materials:combustible materialsreducing materialsgreaseoil

:

:


Under normal conditions of storage and use, hazardous polymerization will not occur.Hazardous polymerization :


Acute toxicity

Not available.

Carcinogenicity

Not available.

Mutagenicity

Not available.

Teratogenicity

Not available.


Not available.


Not available.

Sensitization

Not available.









Not available.

Not available.

Aspiration hazard

Not available.


: Not available.



Oxygen


Not available.







Skin contact

Ingestion


No specific data.

No specific data.

:

:

:





Not available.



: Not available.

Short term exposure



: Not available.

Long term exposure



LogPow BCF Potential




oxygen 0.65 - low

Toxicity

Not available.



: Not available.

Mobility in soil

Not available.


Oxygen


:Disposal methods


OXYGEN,COMPRESSED

2.2 (5.1)

-

OXYGEN,COMPRESSED

2.2 (5.1)

-

OXYGEN,COMPRESSED

UN1072

2.2 (5.1)

-

UN1072 UN1072

Limited quantity Yes.Quantity limitation Passenger aircraft/rail: 75 kg. Cargo aircraft: 150 kg.Special provisions A52

Quantity limitation Passenger and Cargo Aircraft: 75 kg. Cargo Aircraft Only: 150 kg.

DOT IMDG IATA

UN number



Packing group





No. No. No.


: Not available.

:

TDG

UN1072

OXYGEN,COMPRESSED

2.2

-

No.

Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.13-2.17 (Class 2), 2.23-2.25 (Class 5).Explosive Limit and Limited Quantity Index 0.125ERAP Index 3000Passenger Carrying Ship Index 50Passenger Carrying Road or Rail Index 75Special provisions 42

Mexico

UN1072

OXYGEN,COMPRESSED

2.2 (5.1)

-

No.

DOT Classification

TDG Classification

IATA

:

:

:



Oxygen


This material is listed.Massachusetts

:

:


: Not listed


: Not listed


: Not listed


: Not listed


: Not listed

New York : This material is not listed.

New Jersey : This material is listed.

Pennsylvania : This material is listed.

State regulations

TSCA 8(a) CDR Exempt/Partial exemption: This material is listed or exempted.

SARA 302/304







Not listed.

Stockholm Convention on Persistent Organic Pollutants

Not listed.


Not listed.

Not listed.


Not listed.

Inventory list

Australia : This material is listed or exempted.

Canada : This material is listed or exempted.

China : This material is listed or exempted.

Europe : This material is listed or exempted.

Japan : Japan inventory (ENCS): Not determined.Japan inventory (ISHL): Not determined.

Republic of Korea : This material is listed or exempted.


New Zealand : This material is listed or exempted.

Philippines : This material is listed or exempted.

SARA 311/312



Oxygen

Section 15. Regulatory informationTaiwan : This material is listed or exempted.

Turkey : Not determined.

United States : This material is listed or exempted.




2/3/2018

History

Date of printing


Version


:

:

:

:

Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships, 1973

2/3/2018

1/27/2017

0.03

Hazardous Material Information System (U.S.A.)

0

0

3

00

0

/


Health

Special


Flammability

Health

Flammability

Physical hazards







OXIDIZING GASES - Category 1 Expert judgmentGASES UNDER PRESSURE - Compressed gas According to package

OX


Oxygen



Notice to readerIndicates information that has changed from previously issued version.


as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations


SAFETY DATA SHEET

1. IdentificationOatey CPVC Flowguard Gold UVI One-Step Yellow CementProduct identifier

Other means of identification1203EProduct code

Part Numbers: 31910(TV), 31911(TV), 31912, 31913, 31914, 31656, 31657, 32200, 32201, 32202,32203, 31660, 31661, 31662, 31663, 31917, 31918, 31919

Synonyms

Joining CPVC PipesRecommended use



Company Name Oatey Co.Address 4700 West 160th St.

Cleveland, OH 44135

Telephone 216-267-7100E-mail [email protected] Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)Emergency First Aid 1-877-740-5015Contact person MSDS Coordinator


Category 2Flammable liquidsPhysical hazards

Category 4Acute toxicity, oralHealth hazards

Category 2Skin corrosion/irritation


Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure

Category 3 narcotic effectsSpecific target organ toxicity, single exposure



Label elements

Signal word Danger

Hazard statement Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and entersairways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Maycause drowsiness or dizziness.


Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightlyclosed. Ground/bond container and receiving equipment. Use explosion-proofelectrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionarymeasures against static discharge. Avoid breathing mist or vapor. Wash thoroughly afterhandling. Do not eat, drink or smoke when using this product. Use only outdoors or in awell-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection.

SDS USOatey CPVC Flowguard Gold UVI One-Step Yellow Cement

926350 Version #: 01 Revision date: 12-6-2017 Issue date: 5-27-2015 1 / 10

Response If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately allcontaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air andkeep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor ifyou feel unwell. Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medicaladvice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminatedclothing and wash before reuse. In case of fire: Use appropriate media to extinguish.

Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.

Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.


Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.May form explosive peroxides. Contains a chemical classified by the US EPA as a suspectedpossible carcinogen.

Supplemental information

Not applicable.


Mixtures

109-99-9 30-60Furan, Tetrahydro-


78-93-3 10-30Methyl ethyl ketone

68648-82-8 10-20Ethene, chloro-, homopolymer,chlorinated

67-64-1 5-15Acetone

108-94-1 5-15Cyclohexanone

112945-52-5 1-5Silica, amorphous, fumed


4. First-aid measuresRemove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISONCENTER or doctor/physician if you feel unwell.

Inhalation

Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skinirritation occurs: Get medical advice/attention.

Skin contact

Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Eye contact

Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs,keep head low so that stomach content doesn't get into the lungs. Aspiration may causepulmonary edema and pneumonitis.

Ingestion

Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eyeirritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Maycause respiratory irritation. Vapors have a narcotic effect and may cause headache, fatigue,dizziness and nausea. Skin irritation. May cause redness and pain.


Provide general supportive measures and treat symptomatically. Thermal burns: Flush with waterimmediately. While flushing, remove clothes which do not adhere to affected area. Call anambulance. Continue flushing during transport to hospital. In case of shortness of breath, giveoxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.


Take off all contaminated clothing immediately. Ensure that medical personnel are aware of thematerial(s) involved, and take precautions to protect themselves. Wash contaminated clothingbefore reuse.

General information

5. Fire-fighting measuresAlcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media

Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishingmedia

Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a sourceof ignition and flash back. During fire, gases hazardous to health may be formed.


Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipmentand precautions for firefighters



In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can doso without risk.


Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods

Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosiveorganic peroxide when exposed to air or light or with age.

General fire hazards

6. Accidental release measuresKeep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out oflow areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist orvapor. Do not touch damaged containers or spilled material unless wearing appropriate protectiveclothing. Ventilate closed spaces before entering them. Local authorities should be advised ifsignificant spillages cannot be contained. For personal protection, see section 8 of the SDS.

Personal precautions,protective equipment andemergency procedures

Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Takeprecautionary measures against static discharge. Use only non-sparking tools. Keep combustibles(wood, paper, oil, etc.) away from spilled material. This product is miscible in water.

Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors ordivert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet toprevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up theproduct and place into a container for later disposal. Prevent entry into waterways, sewer,basements or confined areas. Following product recovery, flush area with water.

Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containersfor later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.



Avoid discharge into drains, water courses or onto the ground.Environmental precautions

7. Handling and storageVapors may form explosive mixtures with air. Do not handle, store or open near an open flame,sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proofgeneral and local exhaust ventilation. Take precautionary measures against static discharges. Allequipment used when handling the product must be grounded. Use non-sparking tools andexplosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, andclothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink orsmoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling.Observe good industrial hygiene practices.


Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic chargebuild-up by using common bonding and grounding techniques. Store in a cool, dry place out ofdirect sunlight. Store in original tightly closed container. Store in a well-ventilated place. Storeaway from incompatible materials (see Section 10 of the SDS).




ValueTypeComponents

PEL 2400 mg/m3Acetone (CAS 67-64-1)1000 ppm

PEL 200 mg/m3Cyclohexanone (CAS108-94-1)

50 ppmPEL 590 mg/m3Furan, Tetrahydro- (CAS

109-99-9)200 ppm

PEL 590 mg/m3Methyl ethyl ketone (CAS78-93-3)

200 ppmUS. OSHA Table Z-3 (29 CFR 1910.1000)

ValueTypeComponents

TWA 0.8 mg/m3Silica, amorphous, fumed(CAS 112945-52-5)

Oatey CPVC Flowguard Gold UVI One-Step Yellow Cement SDS US


US. OSHA Table Z-3 (29 CFR 1910.1000)

ValueTypeComponents

20 mppcf


ValueTypeComponents

STEL 750 ppmAcetone (CAS 67-64-1)TWA 500 ppmSTEL 50 ppmCyclohexanone (CAS

108-94-1)TWA 20 ppmSTEL 100 ppmFuran, Tetrahydro- (CAS

109-99-9)TWA 50 ppmSTEL 300 ppmMethyl ethyl ketone (CAS

78-93-3)TWA 200 ppm


ValueTypeComponents

TWA 590 mg/m3Acetone (CAS 67-64-1)250 ppm

TWA 100 mg/m3Cyclohexanone (CAS108-94-1)

25 ppmSTEL 735 mg/m3Furan, Tetrahydro- (CAS

109-99-9)250 ppm

TWA 590 mg/m3200 ppm

STEL 885 mg/m3Methyl ethyl ketone (CAS78-93-3)

300 ppmTWA 590 mg/m3

200 ppmTWA 6 mg/m3Silica, amorphous, fumed

(CAS 112945-52-5)

Biological limit values

ACGIH Biological Exposure Indices

Value Sampling TimeDeterminant SpecimenComponents

50 mg/l Acetone Urine *Acetone (CAS 67-64-1)80 mg/l 1,2-Cyclohexan

ediol, withhydrolysis

Urine *Cyclohexanone (CAS108-94-1)

8 mg/l Cyclohexanol,with hydrolysis

Urine *

2 mg/l Tetrahydrofuran

Urine *Furan, Tetrahydro- (CAS109-99-9)

2 mg/l MEK Urine *Methyl ethyl ketone (CAS78-93-3)* - For sampling details, please see the source document.

Exposure guidelines

US - California OELs: Skin designation

Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.US - Minnesota Haz Subs: Skin designation applies

Cyclohexanone (CAS 108-94-1) Skin designation applies.



US - Tennessee OELs: Skin designation

Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.US ACGIH Threshold Limit Values: Skin designation

Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.Furan, Tetrahydro- (CAS 109-99-9) Can be absorbed through the skin.


Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.

Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 airchanges per hour) should be used. Ventilation rates should be matched to conditions. Ifapplicable, use process enclosures, local exhaust ventilation, or other engineering controls tomaintain airborne levels below recommended exposure limits. If exposure limits have not beenestablished, maintain airborne levels to an acceptable level. Eye wash facilities and emergencyshower must be available when handling this product.


Individual protection measures, such as personal protective equipmentFace shield is recommended. Wear safety glasses with side shields (or goggles).Eye/face protection

Skin protectionWear appropriate chemical resistant gloves.Hand protection


If engineering controls do not maintain airborne concentrations below recommended exposurelimits (where applicable) or to an acceptable level (in countries where exposure limits have notbeen established), an approved respirator must be worn.



When using, do not eat, drink or smoke. Always observe good personal hygiene measures, suchas washing after handling the material and before eating, drinking, and/or smoking. Routinely washwork clothing and protective equipment to remove contaminants.




Translucent liquid.Form

Yellow / GoldColor

Solvent.Odor


pH Not available.



151 °F (66.11 °C)

Flash point 14.0 - 23.0 °F (-10.0 - -5.0 °C)

Evaporation rate 5.5 - 8




1.8


11.8



Vapor pressure 145 mm Hg @ 20 C

Vapor density 2.5

Relative density 0.94 +/- 0.02

Solubility(ies)

Solubility (water) Negligible


Not available.




Decomposition temperature

Viscosity

Other information

Bulk density

VOC (Weight %)

10. Stability and reactivityReactivity

Chemical stability


Conditions to avoid

Incompatible materials

Not available.

500 - 1500 cP

7.8 lb/gal

< 490 g/l SQACMD 1168/M316A

The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions.


Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials.

Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics.

No hazardous decomposition products are known.Hazardous decompositionproducts


Inhalation May be fatal if swallowed and enters airways. Headache. Nausea, vomiting. May cause irritationto the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue,dizziness and nausea. Prolonged inhalation may be harmful.

Skin contact Causes skin irritation.


Ingestion May be fatal if swallowed and enters airways. Harmful if swallowed. Harmful if swallowed. Dropletsof the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.


Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severeeye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Maycause respiratory irritation. Skin irritation. May cause redness and pain. Symptoms ofoverexposure may be headache, dizziness, tiredness, nausea and vomiting.


Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation.


Acetone (CAS 67-64-1)

LD50 Rabbit

DermalAcute

20 ml/kg

LC50 Rat

Inhalation50 mg/l, 8 Hours

LD50 Rat

Oral5800 mg/kg

Cyclohexanone (CAS 108-94-1)

LD50 Rabbit

DermalAcute

948 mg/kg

LC50 Rat

Inhalation8000 ppm, 4 hours

LD50 Rat

Oral1540 mg/kg



Causes serious eye irritation.Serious eye damage/eyeirritation




Respiratory sensitization Not available.

This product is not expected to cause skin sensitization.Skin sensitization



Carcinogenicity In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalationlifetime study on THF conducted by NTP (1998). Male rats developed renal tumors and femalemice developed liver tumors while neither the female rats nor the male mice showed similarresults. Because the carcinogenic mechanisms could not be identified clearly in either species foreither tumor, the EPA determined that the male rat and female mouse findings are relevant to theassessment of carcinogenic potential in humans. Therefore, the IRIS review concludes that thesedata in aggregate indicate that there is "suggestive evidence of carcinogenic potential" followingexposure to THF by all routes of exposure.


Cyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans.Silica, amorphous, fumed (CAS 112945-52-5) 3 Not classifiable as to carcinogenicity to humans.


Not listed.



Narcotic effects. May cause drowsiness and dizziness. Respiratory tract irritation.


Not classified.

Aspiration hazard May be fatal if swallowed and enters airways.


12. Ecological informationThe product is not classified as environmentally hazardous. However, this does not exclude thepossibility that large or frequent spills can have a harmful or damaging effect on the environment.

Ecotoxicity



Aquatic

LC50Fish > 100 mg/l, 96 hoursFathead minnow (Pimephales promelas)



Aquatic

LC50Fish 481 - 578 mg/l, 96 hoursFathead minnow (Pimephales promelas)



Partition coefficient n-octanol / water (log Kow)Acetone (CAS 67-64-1) -0.24Cyclohexanone (CAS 108-94-1) 0.81Furan, Tetrahydro- (CAS 109-99-9) 0.46Methyl ethyl ketone (CAS 78-93-3) 0.29



13. Disposal considerationsCollect and reclaim or dispose in sealed containers at licensed waste disposal site. This materialand its container must be disposed of as hazardous waste. Do not allow this material to drain intosewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or usedcontainer. Dispose of contents/container in accordance with local/regional/national/internationalregulations.

Disposal instructions

Dispose in accordance with all applicable regulations.Local disposal regulations

The waste code should be assigned in discussion between the user, the producer and the wastedisposal company.

Hazardous waste code






DOT

Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).

Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied.

UN1133UN numberAdhesivesUN proper shipping name

3Class


-Subsidiary risk3Label(s)IIPacking groupRead safety instructions, SDS and emergency procedures before handling.Special precautions for userT11, TP1, TP8, TP27Special provisions

Packaging exceptionsPackaging non bulk

150 201 243Packaging bulk

IATA


3Class


-Subsidiary riskIIPacking groupNo.Environmental hazards3LERG CodeRead safety instructions, SDS and emergency procedures before handling.Special precautions for user

IMDG

UN number UN1133ADHESIVESUN proper shipping name

3Class


-Subsidiary riskIIPacking group

No.Marine pollutant


F-E, S-DEmSRead safety instructions, SDS and emergency procedures before handling.Special precautions for userNot available.Transport in bulk according to

Annex II of MARPOL 73/78 andthe IBC Code

15. Regulatory informationThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.





Acetone (CAS 67-64-1) LISTEDCyclohexanone (CAS 108-94-1) LISTEDFuran, Tetrahydro- (CAS 109-99-9) LISTEDMethyl ethyl ketone (CAS 78-93-3) LISTED



Superfund Amendments and Reauthorization Act of 1986 (SARA)Immediate Hazard - YesDelayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No

Hazard categories


Not listed.

NoSARA 311/312 Hazardouschemical





Not regulated.

Not regulated.Safe Drinking Water Act(SDWA)

Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) andChemical Code Number

Acetone (CAS 67-64-1) 6532Methyl ethyl ketone (CAS 78-93-3) 6714

Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))

Acetone (CAS 67-64-1) 35 %WVMethyl ethyl ketone (CAS 78-93-3) 35 %WV

DEA Exempt Chemical Mixtures Code Number




Acetone (CAS 67-64-1)Cyclohexanone (CAS 108-94-1)Furan, Tetrahydro- (CAS 109-99-9)Methyl ethyl ketone (CAS 78-93-3)Silica, amorphous, fumed (CAS 112945-52-5)


Acetone (CAS 67-64-1)Cyclohexanone (CAS 108-94-1)Furan, Tetrahydro- (CAS 109-99-9)Methyl ethyl ketone (CAS 78-93-3)







Country(s) or region Inventory name On inventory (yes/no)*Domestic Substances List (DSL) YesCanada





Toxic Substances Control Act (TSCA) Inventory NoUnited States & Puerto Rico

16. Other information, including date of preparation or last revision27-May-2015Issue date

-Revision date

Version # 01

Health: 2Flammability: 3Physical hazard: 0

HMIS® ratings

NFPA ratings

023

The information in the sheet was written based on the best knowledge and experience currentlyavailable. Oatey Co. cannot anticipate all conditions under which this information and its product,or the products of other manufacturers in combination with its product, may be used. It is theuser’s responsibility to ensure safe conditions for handling, storage and disposal of the product,and to assume liability for loss, injury, damage or expense due to improper use.

Disclaimer



Oatey Dark Cutting Oil SDS US SDS # Version #: 01 Revision date: Issue date: 12-May-2015 Page 1 of 6

SAFETY DATA SHEET

1. Identification

Product identifier Oatey Dark Cutting Oil


Product code

Synonyms Part Numbers: 30203, 30204, 30205

Recommended use Cutting oil for high speed thread cutting machines.



Company Name Oatey Inc.

Address 4700 West 160th Street

Cleveland, OH 44135

Telephone 216-267-7100

E-mail [email protected]

Transport Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)

Emergency First Aid 1-877-740-5015

Contact person MSDS Coordinator


Physical hazards Not Classified.

Health hazards Not Classified

OSHA defined hazards Not Classified.

Label elements

Hazard symbol None.

Signal word None

Hazard statement This product does not require any hazard statements.


Prevention This product does not require any precautionary statements.

Response This product does not require any precautionary statements.

Storage Not applicable.

Disposal Not applicable.

Hazard(s) not otherwise classified (HNOC)

Used Oil may contain harmful impurities.


Mixtures

Chemical name CAS number %

Petroleum Hydrocarbon Mixture Mixture >95


Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur.

Skin contact Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur.

Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs.

Ingestion Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical


personnel. Get medical attention if symptoms occur. Most important symptoms/effects, acute and delayed

Ingestion may result in nausea, vomiting, and or diarrhea.

Indication of immediate medical attention and special treatment needed.

Immediate medical attention is not required.

General information Note to physician, treat symptomatically.


Suitable extinguishing media Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only.

Unsuitable extinguishing media Do not use water in a jet.


Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases, oxides of sulfur and phosphorous (smoke). Carbon monoxide.

Special protective equipment and precautions for firefighters


Fire fighting equipment/instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Use water spray to keep fire-exposed containers cool. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Specific methods None

General fire hazards None



Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".


Large Spills: Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see section 1 of SDS for emergency contact information and section 13 of SDS for waste disposal.

Small Spills: Move containers from spill area. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see section 1 of SDS for emergency contact information and section 13 of SDS for waste disposal.

Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).


Precautions for safe handling Use local exhaust ventilation if there is risk of inhalation of vapors, mists or aerosols. Properly dispose of any contaminated rags or cleaning materials to prevent fires. Put on appropriate personal protective equipment (see section 8 of SDS). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures.

Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10 of SDS) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.





Components Type Value

Oil Mist, Mineral TLV or PEL 5 mg/m3

US OSHA Permissible Exposure Limits


Biological limit values Data Not available.


No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits.

Individual protection measures, such as personal protective equipment Eye/face protection Safety eyewear complying with an approved standard should be used when a risk assessment

indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. Skin protection

Hand Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.

Other Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Respiratory protection Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Thermal hazards None.

General hygiene considerations

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.


Appearance Physical state Liquid Form Liquid Color Dark, brown Odor Slight hydrocarbon Odor threshold Not available. pH Not applicable Melting point/freezing point No data available. Initial boiling point and boiling range

Not determined

Flash point > 340 °F (> 171°C) Upper/lower flammability or explosive limits Flammability limit – lower (%) Not available Flammability limit – upper (%) Not available Explosive limit - lower (%) Not available Explosive limit - upper (%) Not available Vapor pressure Not applicable Vapor density Not applicable Relative density 0.92 Solubility(ies) Solubility (water) Negligible Partition coefficient (n-octanol/water) >6 based on similar products Auto-ignition temperature Not applicable


Decomposition temperature Not available Viscosity, kinematic 182 SUS at 100 F (typical) Other information VOC (Weight %) < 1% by weight, < 10 g/L


Reactivity The product does not pose any further reactivity hazards in addition to those listed in the following sub-paragraph..

Chemical stability The product is stable.

Possibility of hazardous reaction

Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to avoid Extreme temperature and direct sunlight.

Incompatible materials Strong Oxidizing Agents.




Information on likely routes of exposure Inhalation Mist from processing.

Skin contact Skin contact.

Eye contact Eye contact.

Ingestion No known significant effects or critical hazards.


No specific data.

Information on likely routes of exposure Acute Toxicity

Components Species Results

Skin corrosion/irritation May cause skin irritation after prolonged exposure. Prolonged exposure or repeated exposure

without proper cleaning can clog pores of the skin. Serious eye damage/eye irritation

Expected to be slightly irritating.

Respiratory or skin sensitization Respiratory sensitization Inhalation of vapors or mists may cause irritation to the respiratory system.

Skin sensitization This product is not expected to cause skin irritation.

Germ cell mutagenicity Not considered a mutagenic hazard

Carcinogenicity No component of this product is identified as a probable, possible, or confirmed carcinogen by IARC, NTP, Monographs, or OSHA.

Reproductive toxicity No known significant effects or critical hazards.

Specific target organ toxicity

Single exposure Repeated exposure

Not expected to be a hazard. Not expected to be a hazard.

Aspiration Hazard Contains Distillates (petroleum), hydrotreated – Which is a category 1 Aspiration Hazard. The likely hood of aspirating the product in this form is very low due to the high viscosity.

Chronic effects Not Classified.

Further information Used oils may contain harmful impurities that have accumulated during use. The concentration of such impurities will depend on use and may present risks to health and the environment on disposal. Used oil should be handled with caution and skin contact should be avoided when possible.


Ecotoxicity Product/ingredient name Results Species Exposure Petroleum Distillates Acute LC50 2,900 μg/l Fresh water Fish - Rainbow trout,Donaldson trout

96 h


Acute LC50 2,200 μg/l Fresh water Fish - Bluegill 96 h

Persistence and degradability Not Available.

Bio accumulative potential Not Available.

Mobility in soil Liquid under most conditions. Floats on water. If it enters soil, it will adsorb to soil particles and will not be mobile.

Other adverse effects No known significant effects of critical hazards.


Disposal instructions The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Local disposal regulations Not Applicable

Hazardous waste code Not Applicable

14. Transportation information

DOT Not Regulated

UN number

UN Proper Shipping Name

Transportation Hazard classes

Packing group IATA Not Regulated

UN number



Packing group IMDG Not Regulated

UN number



Packing group Environmental hazards Marine polluntant 15. Regulatory information

U.S. Federal regulations TSCA 12(b) - Chemical export notification: None required. TSCA 5(a)2 - Final significant new use rules: Not listed TSCA 5(a)2 - Proposed significant new use rules: Not listed TSCA 5(e) - Substances consent order: Not listed SARA 311/312

Classification Not applicable

US state regulations California Prop 65 This product does not contain a chemical known to the State of California to cause cancer, birth

defects, or other reproductive harm.



Issue Date 12-May-2015

Revision Date -

Version # 01

HMIS Rating Health: 1 Flammability: 1 Physical Hazards: 0

Disclaimer Oatey Inc. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available.

SAFETY DATA SHEET

Oatey EP42 Lo VOC CPVC Heavy Duty Industrial Gray Cement

5204E

Joining CPVC Pipes

None known.

1. Identification

Product identifier


Product code

Recommended use Recommended restrictions



Cleveland, OH 44135











Label elements

Signal word Danger





SDS USOatey EP42 Lo VOC CPVC Heavy Duty Industrial Gray Cement 926335 Version

#: 01 Revision date: 12-1-2017 Issue date: 5-27-2015 1 / 9






Not applicable.


Mixtures



68648-82-8 15-25Ethene, chloro-, homopolymer,chlorinated

67-64-1 5-15Acetone




Inhalation


Skin contact


Eye contact


Ingestion






General information











SDS USOatey EP42 Lo VOC CPVC Heavy Duty Industrial Gray Cement 926335 Version #:

01 Revision date: 12-1-2017 Issue date: 5-27-2015 2 / 9















ValueTypeComponents




109-99-9)200 ppm


ValueTypeComponents



109-99-9)TWA 50 ppm

Oatey EP42 Lo VOC CPVC Heavy Duty Industrial Gray Cement SDS US



ValueTypeComponents




109-99-9)250 ppm









Urine *


Urine *Furan, Tetrahydro- (CAS109-99-9)* - For sampling details, please see the source document.

Exposure guidelines



Cyclohexanone (CAS 108-94-1) Skin designation applies.US - Tennessee OELs: Skin designation



















Opaque liquid.Form

Gray.Color

Solvent.Odor


pH Not available.



151 °F (66.11 °C)

Flash point 14.0 - 23.0 °F (-10.0 - -5.0 °C)





1.8


11.8




Vapor density 2.5


Solubility(ies)



Not available.



Viscosity 500 - 1500 cP

Other information

Bulk density 8.1 lb/gal

VOC (Weight %) < 490 g/l SQACMD 1168/M316A

10. Stability and reactivityThe product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity


No dangerous reaction known under conditions of normal use.Possibility of hazardousreactions


Conditions to avoid

Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics.Incompatible materials















LD50 Rabbit

DermalAcute

20 ml/kg

LC50 Rat


LD50 Rat

Oral5800 mg/kg


LD50 Rabbit

DermalAcute

948 mg/kg

LC50 Rat


LD50 Rat

Oral1540 mg/kg











Cyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans.OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.





Not classified.




Ecotoxicity





Aquatic




Aquatic




Partition coefficient n-octanol / water (log Kow)Acetone (CAS 67-64-1) -0.24Cyclohexanone (CAS 108-94-1) 0.81Furan, Tetrahydro- (CAS 109-99-9) 0.46



13. Disposal considerationsDisposal instructions

Local disposal regulations





DOT

Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.

Dispose in accordance with all applicable regulations.

The waste code should be assigned in discussion between the user, the producer and the waste disposal company.




3Class





IATA


3Class





IMDG

UN1133UN numberADHESIVESUN proper shipping name

3Class



No.Marine pollutant









Acetone (CAS 67-64-1) LISTEDCyclohexanone (CAS 108-94-1) LISTEDFuran, Tetrahydro- (CAS 109-99-9) LISTED


Hazard categories


Not listed.






Not regulated.



Acetone (CAS 67-64-1) 6532Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))

Acetone (CAS 67-64-1) 35 %WVDEA Exempt Chemical Mixtures Code Number

Acetone (CAS 67-64-1) 6532





01 Revision date: 1-Dec-2017 Issue date: 5-27-2015 8 / 9

Cyclohexanone (CAS 108-94-1)Furan, Tetrahydro- (CAS 109-99-9)


Acetone (CAS 67-64-1)Cyclohexanone (CAS 108-94-1)Furan, Tetrahydro- (CAS 109-99-9)











-Revision date

Version # 01


HMIS® ratings

NFPA ratings

023


Disclaimer

SDS USOatey EP42 Lo VOC CPVC Heavy Duty Industrial Gray Cement 926335 Version #: 01

Revision date: 12-1-2017 Issue date: 5-27-2015 9 / 9

Oatey Pipe Joint Lubricant SDS US SDS # Version #: 01 Revision date: Issue date: 12-May-2015 Page 1 of 6

SAFETY DATA SHEET

1. Identification

Product identifier Oatey Pipe Joint Lubricant


Product code

Synonyms Part Numbers: 30599, 30600, 30601, 30602

Recommended use Lubricant



Company Name Oatey Inc.

Address 4700 West 160th Street

Cleveland, OH 44135

Telephone 216-267-7100

E-mail [email protected]

Transport Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)

Emergency First Aid 1-877-740-5015

Contact person MSDS Coordinator


Physical hazards Not Classified.

Health hazards Skin Irritant

Eye Irritation

Cat 3

Cat 2B

OSHA defined hazards This chemical is considered non-hazardous according to the OSHA Hazard Communication Standard 2012 (29 CFR 1910.1200)

Label elements

Hazard symbol None.

Signal word Warning

Hazard statement Causes mild skin irritation. Causes eye irritation.


Prevention Wash skin thoroughly after handling.

Response If skin irritation occurs: Get medical advice/attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Storage Not applicable.

Disposal Not applicable.

Hazard(s) not otherwise classified (HNOC)

None.


Mixtures

The product contains no substances which at their given concentration, are considered to be hazardous to health.

Chemical name CAS number %

Mixed sodium and potassium salts of tall oil (soap) 68606-06-4 15 - 25


Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur.

Skin contact Wash off immediately with soap and water. If skin irritation persists, call a physician.


Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs.

Ingestion Do NOT induce vomiting. Drink plenty of water. Rinse mouth. Never give anything by mouth to an unconscious person. Call a physician or poison control center immediately


Direct contact with eyes may cause temporary irritation. Prolonged or repeated skin contact may cause irritation.

Indication of immediate medical attention and special treatment needed.

Immediate medical attention is not required.

General information Note to physician, treat symptomatically.


Suitable extinguishing media Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only.

Unsuitable extinguishing media Do not use water in a jet.


No information available.

Special protective equipment and precautions for firefighters


Fire fighting equipment/instructions

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Use water spray to keep fire-exposed containers cool. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Specific methods None

General fire hazards None



Avoid contact with the skin and the eyes. Evacuate personnel to safe areas. Use personal protective equipment. Keep people away from and upwind of spill/leak.


Dike to collect large liquid spills. Prevent leakage or spillage if safe to do so. Dam up. Soak up with inert absorbent material Place the bulk of any spilled material into properly labeled containers. Rinse any remaining material to sewage treatment facility. Clean up in accordance with all applicable regulations.

Environmental precautions Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Do not flush into surface water or sanitary sewer system. Prevent entry into waterways, sewers, basements or confined areas. See Section 12 for additional Ecological information


Precautions for safe handling Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Do not breathe vapors or spray mist. Ensure adequate ventilation. Use only in area provided with appropriate exhaust ventilation. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Do not take internally.

Conditions for safe storage, including any incompatibilities

Keep containers tightly closed in a dry, cool and well-ventilated place. Keep in properly labeled containers. Keep out of the reach of children.


Occupational exposure limits US. ACGIH Threshold Limit Values


Biological limit values Data Not available.


No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure


limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits.

Individual protection measures, such as personal protective equipment Eye/face protection Safety eyewear complying with an approved standard should be used when a risk assessment

indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. Skin protection

Hand Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.

Other Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Respiratory protection Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Thermal hazards None.

General hygiene considerations

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.


Appearance Physical state Liquid Form Paste Color Off-White Odor Slight Odor threshold Not available. pH 9 (5% Solution) Melting point/freezing point No data available. Initial boiling point and boiling range

Not determined

Flash point > 220 °F (> 104°C) Upper/lower flammability or explosive limits Flammability limit – lower (%) Not available Flammability limit – upper (%) Not available Explosive limit - lower (%) Not available Explosive limit - upper (%) Not available Vapor pressure Not applicable Vapor density Not applicable Relative density 1.2 Solubility(ies) Solubility (water) Completely soluble. Partition coefficient (n-octanol/water) Not determined. Auto-ignition temperature Not applicable Decomposition temperature Not available Viscosity, kinematic Not determined/ Other information VOC (Weight %) < 1% by weight, < 12 g/L


Reactivity Not reactive under normal conditions

Chemical stability The product is stable.

Possibility of hazardous reaction

Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to avoid Contact with incompatible materials.

Incompatible materials Strong Oxidizing Agents.


Carbon oxides.



Information on likely routes of exposure Inhalation Not a likely route

Skin contact May cause mild skin irritation.

Eye contact Causes Eye irritation

Ingestion No known significant effects or critical hazards.


Direct contact with eyes may cause temporary irritation. Prolonged or repeated contact may dry skin and cause irritation

Information on likely routes of exposure Acute Toxicity

Components Species Results

Skin corrosion/irritation Prolonged exposure may cause skin irritation.

Serious eye damage/eye irritation

Expected to be slightly irritating.

Respiratory or skin sensitization Respiratory sensitization Inhalation of vapors or mists may cause irritation to the respiratory system.

Skin sensitization This product is not expected to cause skin irritation.

Germ cell mutagenicity Not considered a mutagenic hazard

Carcinogenicity No component of this product is identified as a probable, possible, or confirmed carcinogen by IARC, NTP, Monographs, or OSHA.

Reproductive toxicity No known significant effects or critical hazards.

Specific target organ toxicity

Single exposure Repeated exposure

Not expected to be a hazard. Not expected to be a hazard.

Aspiration Hazard Not expected to be a hazard

Chronic effects Not Classified.

Further information None Provided.


Ecotoxicity Product/ingredient name Results Species Exposure

Persistence and degradability Not Available.

Bio accumulative potential Not Available.

Mobility in soil Not determined.

Other adverse effects No known significant effects of critical hazards.


Disposal instructions The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Local disposal regulations Not Applicable

Hazardous waste code Not Applicable

14. Transportation information


DOT Not Regulated

UN number



Packing group IATA Not Regulated

UN number



Packing group IMDG Not Regulated

UN number



Packing group Environmental hazards Marine polluntant 15. Regulatory information

U.S. Federal regulations TSCA 12(b) - Chemical export notification: None required. TSCA 5(a)2 - Final significant new use rules: Not listed TSCA 5(a)2 - Proposed significant new use rules: Not listed TSCA 5(e) - Substances consent order: Not listed US Federal Regulations

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.

SARA 311/312 Hazard Categories

Acute Health Hazard Yes

Chronic Health Hazard No

Fire Hazard No

Sudden Release of Pressure Hazard No

Reactive Hazard No

CWA (Clean Water Act)

This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42): None known

CERCLA

This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): None Known

US state regulations California Prop 65 This product does not contain a chemical known to the State of California to cause cancer, birth

defects, or other reproductive harm. International regulations

Country(s) or region Inventory Name On inventory list (yes/no)*

Canada DSL/NDSL Yes

United States & Puerto Rico Toxic Substances Control Act (TSCA 8b) Yes



Issue Date 12-May-2015

Revision Date -

Version # 01

HMIS Rating Health: 1 Flammability: 0 Physical Hazards: 0

Disclaimer Oatey Inc. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available.

SAFETY DATA SHEET

1. IdentificationOatey Purple Primer- NSF Listed for PVC and CPVCProduct identifier


Part Numbers: 30755(TV), 30756(TV), 30757(TV), 30758, 30759, 30927Synonyms

Joining PVC PipesRecommended use




Cleveland, OH 44135











Label elements

Signal word Danger





Oatey Purple Primer- NSF Listed for PVC and CPVC SDS US

926733 Version #: 01 Revision date: - Issue date: 27-May-2015 1 / 10






Not applicable.


Mixtures

67-64-1 25-40Acetone







Inhalation


Skin contact


Eye contact


Ingestion






General information



























ValueTypeComponents




109-99-9)200 ppm


200 ppm


ValueTypeComponents



109-99-9)




ValueTypeComponents

TWA 50 ppmSTEL 300 ppmMethyl ethyl ketone (CAS

78-93-3)TWA 200 ppm


ValueTypeComponents




109-99-9)250 ppm




200 ppm








Urine *




Exposure guidelines























PurpleColor

Solvent.Odor


pH Not available.



151 °F (66.11 °C)

Flash point 14.0 - 23.0 °F (-10.0 - -5.0 °C)





1.8


11.8




Vapor density 2.5

Relative density 0.84 +/- 0.02 @20°C

Solubility(ies)



Not available.



Viscosity Not available.

Other information

Bulk density 7 lb/gal

VOC (Weight %) 505 g/l SQACMD Method 24

10. Stability and reactivityThe product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity


No dangerous reaction known under conditions of normal use.Possibility of hazardousreactions


Conditions to avoid

Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics.Incompatible materials















LD50 Rabbit

DermalAcute

20 ml/kg

LC50 Rat


LD50 Rat

Oral5800 mg/kg


LD50 Rabbit

DermalAcute

948 mg/kg

LC50 Rat


LD50 Rat

Oral1540 mg/kg











Cyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans.




Not listed.





Not classified.




Ecotoxicity



Aquatic




Aquatic







13. Disposal considerationsCollect and reclaim or dispose in sealed containers at licensed waste disposal site. This materialand its container must be disposed of as hazardous waste. Do not allow this material to drain intosewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or usedcontainer. Dispose of contents/container in accordance with local/regional/national/internationalregulations.







Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.



DOT

UN1993UN numberFlammable liquids, n.o.s. (Methyl ethyl ketone RQ = 26274 LBS, Acetone RQ = 13130 LBS)UN proper shipping name

3Class


-Subsidiary risk3Label(s)IIPacking group



Read safety instructions, SDS and emergency procedures before handling.Special precautions for userIB2, T7, TP1, TP8, TP28Special provisions150Packaging exceptions202Packaging non bulk242Packaging bulk

IATA

UN1993UN numberFlammable liquid, n.o.s. (Methyl ethyl ketone, Acetone)UN proper shipping name

3Class


-Subsidiary riskIIPacking groupNo.Environmental hazards3HERG CodeRead safety instructions, SDS and emergency procedures before handling.Special precautions for user

IMDG

UN1993UN numberFLAMMABLE LIQUID, N.O.S. (Methyl ethyl ketone, Acetone)UN proper shipping name

3Class



No.Marine pollutant


F-E, S-EEmSRead safety instructions, SDS and emergency procedures before handling.Special precautions for userNot available.Transport in bulk according to









Hazard categories


Not listed.








Not regulated.























-Revision date

Version # 01


HMIS® ratings



NFPA ratings

023


Disclaimer



SAFETY DATA SHEET

1. IdentificationProduct identifier Oatey PVC Heavy Duty Clear or Gray Cement

Other means of identificationSDS number 1102E

Synonyms Part Numbers: Clear 30850, 30863, 30876(TV), 30882, 31008(TV), 31011, 31950, 31951, 31952,31953 Gray 30349, 31093, 31094, 31095, 31105, 31118, 31978, 31979, 31980, 31981, 32050,32051, 32052, 32210, 32211

Recommended use Joining PVC Pipes




Cleveland, OH 44135Telephone 216-267-7100E-mail [email protected] Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)Emergency First Aid 1-877-740-5015Contact person MSDS Coordinator










Label elements

Signal word Danger



Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only outdoors or in awell-ventilated area. Keep container tightly closed. Ground/bond container and receivingequipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparkingtools. Take precautionary measures against static discharge. Avoid breathing mist or vapor. Washthoroughly after handling. Do not eat, drink or smoke when using this product. Wear protectivegloves/protective clothing/eye protection/face protection.

Response Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/attention. Ifeye irritation persists: Get medical advice/attention. Take off contaminated clothing and washbefore reuse. In case of fire: Use appropriate media to extinguish.



Oatey PVC Heavy Duty Clear or Gray Cement SDS US

920700 Version #: 02 Revision date:12-5-2017 Issue date:8-4-2014 1 / 10




Not applicable.


Mixtures



67-64-1 10-302-Propanone


9002-86-2 10-30Polyvinyl chloride


112945-52-5 1-5Colloidal silicon dioxide


4. First-aid measuresInhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON

CENTER or doctor/physician if you feel unwell.

Skin contact Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skinirritation occurs: Get medical advice/attention. Take off contaminated clothing and wash beforereuse.

Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Ingestion Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs,keep head low so that stomach content doesn't get into the lungs. Aspiration may causepulmonary edema and pneumonitis.


Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation.Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Maycause redness and pain.



General information Take off all contaminated clothing immediately. IF exposed or concerned: Get medicaladvice/attention. Ensure that medical personnel are aware of the material(s) involved, and takeprecautions to protect themselves. Wash contaminated clothing before reuse.

5. Fire-fighting measuresSuitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).

Unsuitable extinguishingmedia

Do not use water jet as an extinguisher, as this will spread the fire.



Special protective equipmentand precautions for firefighters

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.



Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.

General fire hazards Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosiveorganic peroxide when exposed to air or light or with age.

SDS USOatey PVC Heavy Duty Clear or Gray Cement


6. Accidental release measuresPersonal precautions,protective equipment andemergency procedures

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out oflow areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation of vapors ormists. Do not touch damaged containers or spilled material unless wearing appropriate protectiveclothing. Ventilate closed spaces before entering them. Local authorities should be advised ifsignificant spillages cannot be contained. For personal protection, see section 8 of the SDS.


Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Takeprecautionary measures against static discharge. Use only non-sparking tools. Keep combustibles(wood, paper, oil, etc.) away from spilled material.

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible. Cover with plastic sheet to prevent spreading. Use a non-combustible material likevermiculite, sand or earth to soak up the product and place into a container for later disposal. Usewater spray to reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewer,basements or confined areas. Following product recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.


Environmental precautions Avoid discharge into drains, water courses or onto the ground.

7. Handling and storagePrecautions for safe handling Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame,

sources of heat or sources of ignition. Protect material from direct sunlight. Take precautionarymeasures against static discharges. All equipment used when handling the product must begrounded. Use non-sparking tools and explosion-proof equipment. Do not taste or swallow. Avoidbreathing mist or vapor. Avoid contact with skin. Avoid contact with eyes. Avoid prolongedexposure. Avoid contact with clothing. Provide adequate ventilation. Wear appropriate personalprotective equipment. Observe good industrial hygiene practices. When using, do not eat, drink orsmoke. Wash hands thoroughly after handling.


Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic chargebuild-up by using common bonding and grounding techniques. Store in original tightly closedcontainer. Store in a cool, dry place out of direct sunlight. Store in a well-ventilated place. Storeaway from incompatible materials (see Section 10 of the SDS). Keep in an area equipped withsprinklers.


U.S. - OSHA


TWA 0.8 mg/m3 Unspecified.Colloidal silicon dioxide(CAS 112945-52-5)

20 mppcf Unspecified.US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

ValueTypeComponents

STEL 5 ppmPolyvinyl chloride (CAS9002-86-2)

TWA 1 ppmUS. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)


PEL 2400 mg/m32-Propanone (CAS 67-64-1)1000 ppm



109-99-9)200 ppm






200 ppmPEL 5 mg/m3 Respirable fraction.Polyvinyl chloride (CAS

9002-86-2)15 mg/m3 Total dust.


ValueTypeComponents

TWA 0.8 mg/m3Colloidal silicon dioxide(CAS 112945-52-5)

20 mppcf



STEL 750 ppm2-Propanone (CAS 67-64-1)TWA 500 ppmSTEL 50 ppmCyclohexanone (CAS



78-93-3)TWA 200 ppmTWA 1 mg/m3 Respirable fraction.Polyvinyl chloride (CAS

9002-86-2)

U.S. - NIOSH


REL 6 mg/m3 Unspecified.Colloidal silicon dioxide(CAS 112945-52-5)US. NIOSH: Pocket Guide to Chemical Hazards

ValueTypeComponents

TWA 590 mg/m32-Propanone (CAS 67-64-1)250 ppm

TWA 6 mg/m3Colloidal silicon dioxide(CAS 112945-52-5)



109-99-9)250 ppm




200 ppm






50 mg/l Acetone Urine *2-Propanone (CAS 67-64-1)80 mg/l 1,2-Cyclohexan




Urine *




Exposure guidelines










Individual protection measures, such as personal protective equipmentEye/face protection Wear safety glasses with side shields (or goggles).

Skin protectionHand protection Wear appropriate chemical resistant gloves.

Other Wear appropriate chemical resistant clothing.

Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposurelimits (where applicable) or to an acceptable level (in countries where exposure limits have notbeen established), an approved respirator must be worn.

Thermal hazards Wear appropriate thermal protective clothing, when necessary.


When using, do not eat, drink or smoke. Wash hands after handling and before eating.

9. Physical and chemical propertiesAppearance Opaque.or Translucent.

Physical state Liquid.

Form Liquid.

Color Gray or Clear.

Odor Solvent.


pH Not available.



151 °F (66.11 °C)

Flash point 14.0 - 23.0 °F (-10.0 - -5.0 °C)




Flammability (solid, gas) Not available.



Not available.


Not available.




Vapor density 2.5

Relative density 0.88 - 0.92

Solubility(ies)





Viscosity

Other information

Bulk density

VOC (Weight %)


Chemical stability


Conditions to avoid


Hazardous decompositionproducts

Not available.

Not available.

Not available.

1200 - 2500 cP

7.5 lb/gal

<510 g/l SQACMD 1168/M316A





No hazardous decomposition products are known.


Inhalation May be fatal if swallowed and enters airways. Vapors have a narcotic effect and may causeheadache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. May causeirritation to the respiratory system.



Ingestion May be fatal if swallowed and enters airways. Harmful if swallowed.


Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. Maycause redness and pain. Symptoms of overexposure may be headache, dizziness, tiredness,nausea and vomiting.





LD50 Rabbit

DermalAcute

948 mg/kg

LC50 Rat





LD50 Rat

Oral1540 mg/kg


Skin corrosion/irritation Causes skin irritation.

Serious eye damage/eyeirritation

Causes serious eye irritation.



Skin sensitization This product is not expected to cause skin sensitization.

Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.

Carcinogenicity Suspected of causing cancer. In 2012 USEPA Integrated Risk Information System (IRIS)reviewed a two species inhalation lifetime study on THF conducted by NTP (1998). Male ratsdeveloped renal tumors and female mice developed liver tumors while neither the female rats northe male mice showed similar results. Because the carcinogenic mechanisms could not beidentified clearly in either species for either tumor, the EPA determined that the male rat andfemale mouse findings are relevant to the assessment of carcinogenic potential in humans.Therefore, the IRIS review concludes that these data in aggregate indicate that there is"suggestive evidence of carcinogenic potential" following exposure to THF by all routes ofexposure. This product contains polyvinyl chloride (PVC) that is not a fabricated product, and istherefore, defined and regulated as a toxic and hazardous substance under 29 C.F.R. §1910.1017 due to the presumed presence of residual vinyl chloride monomer. The concentrationsof residual vinyl chloride calculated to be contained in this product are well below the threshold forclassification in accordance with 29 C.F.R. § 1910.1200.


Colloidal silicon dioxide (CAS 112945-52-5) 3 Not classifiable as to carcinogenicity to humans.Cyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans.Polyvinyl chloride (CAS 9002-86-2) 3 Not classifiable as to carcinogenicity to humans.


Polyvinyl chloride (CAS 9002-86-2) Cancer

Reproductive toxicity This product is not expected to cause reproductive or developmental effects.


Respiratory tract irritation. Narcotic effects.


Not classified.



12. Ecological informationEcotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the

possibility that large or frequent spills can have a harmful or damaging effect on the environment.




Aquatic


Persistence and degradability No data is available on the degradability of this product.

Bioaccumulative potential No data available.

Partition coefficient n-octanol / water (log Kow)2-Propanone (CAS 67-64-1) -0.24Cyclohexanone (CAS 108-94-1) 0.81Furan, Tetrahydro- (CAS 109-99-9) 0.46Methyl ethyl ketone (CAS 78-93-3) 0.29

Mobility in soil No data available.




13. Disposal considerationsDisposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material

and its container must be disposed of as hazardous waste. Do not allow this material to drain intosewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or usedcontainer. Dispose of contents/container in accordance with local/regional/national/internationalregulations.

Local disposal regulations Dispose in accordance with all applicable regulations.

Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the wastedisposal company.



Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.


DOT


3Class


-Subsidiary risk3Label(s)IIPacking groupRead safety instructions, SDS and emergency procedures before handling.Special precautions for userT11, TP1, TP8, TP27Special provisions150Packaging exceptions201Packaging non bulk243Packaging bulk

IATA


3Class



IMDG

UN1133UN numberADHESIVESUN proper shipping name

3Class



No.Marine pollutant






15. Regulatory informationUS federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication

Standard, 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.



Polyvinyl chloride (CAS 9002-86-2) CancerCentral nervous systemLiverBloodFlammability


2-Propanone (CAS 67-64-1) LISTEDCyclohexanone (CAS 108-94-1) LISTEDFuran, Tetrahydro- (CAS 109-99-9) LISTEDMethyl ethyl ketone (CAS 78-93-3) LISTED

Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - Yes

Delayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No


Not listed.

SARA 311/312 Hazardouschemical

No





Not regulated.

Safe Drinking Water Act(SDWA)

Not regulated.


2-Propanone (CAS 67-64-1) 6532Methyl ethyl ketone (CAS 78-93-3) 6714


2-Propanone (CAS 67-64-1) 35 %WVMethyl ethyl ketone (CAS 78-93-3) 35 %WV


2-Propanone (CAS 67-64-1) 6532Methyl ethyl ketone (CAS 78-93-3) 6714



2-Propanone (CAS 67-64-1)Colloidal silicon dioxide (CAS 112945-52-5)Cyclohexanone (CAS 108-94-1)Furan, Tetrahydro- (CAS 109-99-9)Methyl ethyl ketone (CAS 78-93-3)


2-Propanone (CAS 67-64-1)Cyclohexanone (CAS 108-94-1)Furan, Tetrahydro- (CAS 109-99-9)Methyl ethyl ketone (CAS 78-93-3)



Polyvinyl chloride (CAS 9002-86-2)US. Pennsylvania Worker and Community Right-to-Know Law

2-Propanone (CAS 67-64-1)Colloidal silicon dioxide (CAS 112945-52-5)Cyclohexanone (CAS 108-94-1)Furan, Tetrahydro- (CAS 109-99-9)Methyl ethyl ketone (CAS 78-93-3)


2-Propanone (CAS 67-64-1)Cyclohexanone (CAS 108-94-1)Furan, Tetrahydro- (CAS 109-99-9)Methyl ethyl ketone (CAS 78-93-3)

US. California Proposition 65California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to containany chemicals currently listed as carcinogens or reproductive toxins. This product contains trace amounts of chemicalsknown to the state of California to cause cancer. Under normal use conditions, exposure to these chemicals at levels abovethe State of California “No significant Risk Level” (NSRL) are unlikely. The use of proper personal protective equipment(PPE) and ventilation guidelines noted in Section 8 will minimize exposure levels to these chemicals.


Country(s) or region Inventory name On inventory (yes/no)*Australian Inventory of Chemical Substances (AICS) YesAustralia


Non-Domestic Substances List (NDSL) NoCanada


European Inventory of Existing Commercial ChemicalSubstances (EINECS)

NoEurope

European List of Notified Chemical Substances (ELINCS) NoEurope

Inventory of Existing and New Chemical Substances (ENCS) YesJapan

Existing Chemicals List (ECL) YesKorea



YesPhilippines



16. Other information, including date of preparation or last revisionIssue date 04-August-2014

Revision date 15-December-2014

Version # 02

HMIS® ratings Health: 2Flammability: 3Physical hazard: 0

Disclaimer The information in the sheet was written based on the best knowledge and experience currentlyavailable.

Oatey PVC Heavy Duty Clear or Gray Cement SDS US


SAFETY DATA SHEET

1. IdentificationRain-R Shine Blue PVC CementProduct identifier


Part Numbers: 30890, 30891, 30893, 30894, 30895, 30896, 31954, 31955, 31956, 31957Synonyms

Joining PVC PipesRecommended use




Cleveland, OH 44135











Label elements

Signal word Danger





SDS USRain-R Shine Blue PVC Cement







Not applicable.


Mixtures



9002-86-2 10-20Polyvinyl chloride

67-64-1 5-15Acetone



112945-52-5 1-5Silica, amorphous, fumed



Inhalation


Skin contact


Eye contact


Ingestion






General information


























US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

ValueTypeComponents

STEL 5 ppmPolyvinyl chloride (CAS9002-86-2)

TWA 1 ppmUS. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)





109-99-9)200 ppm


200 ppmPEL 5 mg/m3 Respirable fraction.Polyvinyl chloride (CAS

9002-86-2)15 mg/m3 Total dust.

Rain-R Shine Blue PVC Cement SDS US



ValueTypeComponents

TWA 0.8 mg/m3Silica, amorphous, fumed(CAS 112945-52-5)

20 mppcf






78-93-3)TWA 200 ppmTWA 1 mg/m3 Respirable fraction.Polyvinyl chloride (CAS

9002-86-2)


ValueTypeComponents




109-99-9)250 ppm




200 ppmTWA 6 mg/m3Silica, amorphous, fumed

(CAS 112945-52-5)








Urine *






Exposure guidelines





















Clear.Color

Solvent.Odor


pH Not available.



151 °F (66.11 °C)

Flash point 14.0 - 23.0 °F (-10.0 - -5.0 °C)





1.8


11.8




Vapor density 2.5


Rain-R Shine Blue PVC Cement SDS US

927279 Version #: 01 Revision date: - Issue date: 05-27-2015 5 / 10

Solubility(ies)





Viscosity

Viscosity temperature

Other information

Bulk density

VOC (Weight %)


Chemical stability


Conditions to avoid


Not available.

Not available.

Not available.

1200 - 2500 cP

77 °F (25 °C)

7.7 lb/gal

< 510 g/l SQACMD 1168/M316A

















LD50 Rabbit

DermalAcute

20 ml/kg

LC50 Rat


LD50 Rat

Oral5800 mg/kg


LD50 Rabbit

DermalAcute

948 mg/kg

LC50 Rat





LD50 Rat

Oral1540 mg/kg











Cyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans.Polyvinyl chloride (CAS 9002-86-2) 3 Not classifiable as to carcinogenicity to humans.Silica, amorphous, fumed (CAS 112945-52-5) 3 Not classifiable as to carcinogenicity to humans.


Polyvinyl chloride (CAS 9002-86-2) Cancer





Not classified.




Ecotoxicity



Aquatic




Aquatic









13. Disposal considerationsDisposal instructions

Local disposal regulations





DOT

Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.

Dispose in accordance with all applicable regulations.

The waste code should be assigned in discussion between the user, the producer and the waste disposal company.




3Class





IATA


3Class



IMDG

UN number UN1133ADHESIVESUN proper shipping name

3Class




Marine pollutant No.EmS F-E, S-DSpecial precautions for user Read safety instructions, SDS and emergency procedures before handling.

Not available.Transport in bulk according toAnnex II of MARPOL 73/78 andthe IBC Code







Polyvinyl chloride (CAS 9002-86-2) CancerCentral nervous systemLiverBloodFlammability




Hazard categories


Not listed.






Not regulated.












Acetone (CAS 67-64-1)Cyclohexanone (CAS 108-94-1)Furan, Tetrahydro- (CAS 109-99-9)Methyl ethyl ketone (CAS 78-93-3)Polyvinyl chloride (CAS 9002-86-2)





Methyl ethyl ketone (CAS 78-93-3)Silica, amorphous, fumed (CAS 112945-52-5)







Toxic Substances Control Act (TSCA) Inventory NoUnited States & Puerto Rico

16. Other information, including date of preparation or last revision05-27-2015Issue date

-Revision date

Version # 01


HMIS® ratings

NFPA ratings

023


Disclaimer



Page 1 of 7 58‐97‐1280

ProPEX Grease 03A

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Product Name: ProPEX Grease Drawing Number: 58‐97‐1280 Product Models: 49‐08‐2400 Issue Date: March 2015 Supersedes Date: November 2011 Milwaukee Electric Tool Corporation Company Phone Number: 262‐781‐3600 or 13135 West Lisbon Road 1‐800‐729‐3878 Brookfield, Wisconsin 53005 Emergency Contact Number: 1‐800‐424‐9300 www.milwaukeetool.com Chemtrec: United States only Recommended intended purpose to be used as a lubricant.

SECTION 2: HAZARDS IDENTIFICATION

Health Environmental Physical

Eye Irritation: No classified hazards Acute Toxicity: No classified hazards Flammable liquid: No classified hazards

Skin Irritation: No classified hazards Chronic Toxicity: No classified hazards

Skin Sensitisation: Category 1

Acute Toxicity, Oral: No classified hazards

Acute Toxicity, Inhalation: No classified hazards

GHS Label

Warning

Hazard Statements Precautionary Statements

May cause eye irritation IF IN EYES: rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.

IF eye irritation persists: get medical attention/advice.

May cause allergic skin reaction Contaminated work clothing should not be allowed out of the work place.

Wear protective gloves/clothing/eye protection/face protection

IF ON SKIN: wash with plenty of soap and water

IF SKIN irritation or rash occurs call and get medical advice/attention

Wash contaminated clothing before reuse

May be harmful if swallowed IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell.

Safety Data SheetMay be used to comply with OSHA’s Hazard Communication Standard 29 CFR 1910.1200. This standard must be consulted for specific requirements.

Page 2 of 7 58‐97‐1280

ProPEX Grease 03A

May be harmful if inhaled IF INHALED: call a POISON CENTER or doctor/physician if you feel unwell.

May cause allergic skin reaction Avoid breathing, dust/fumes/gas/mist/vapors/spray.

Classified Hazards

This material is not hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200. This SDS contains valuable information for the safe handling and proper use of this product. Save this SDS for future reference.

Other Hazards None known

SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS Components listed in this section may contribute to the potential hazards associated with exposure to the concentrate. The product may contain additional non‐hazardous or trade‐secret components. Chemical characterization Lubricating grease: thickening agent, additives and solid lubricants in highly‐refined mineral oil

Chemical Name CAS # Concentration1

Petrolatum 8009‐03‐8 30~40

Triethanolamine 102‐71‐6 <1

Molybdenum Disulfide 1317‐33‐5 50~60

Mineral Oil Trade Secret 5~10

Lubricating Additives Trade Secret 1~5

Note: This product has been evaluated and does not require any hazard warning label under the OSHA Hazard Communication Standard.

1 All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume

SECTION 4: FIRST AID MEASURES

EYE CONTACT: Hold eyelids open and flush with a steady, gentle stream of water for at least 15 minutes. If symptoms persist, contact a

physician. SKIN CONTACT: Remove product from the skin by washing with a mild soap and water. Contaminated clothing should be removed to prevent

prolonged exposure. If symptoms of exposure persist, contact physician. If product is injected into or under the skin, seek treatment immediately. (see Note to Physician)

INHALATION: If signs or symptoms of overexposure occur, remove the person to fresh air. If symptoms persist, seek medical attention. INGESTION: First aid is not normally required; however, if symptoms of ingestion persist, seek medical attention. NOTE TO PHYSICIAN:

When using high‐pressure equipment, injection of product under the skin can occur. In this case, the casualty should be sent immediately to hospital. Do not wait for symptoms to develop. High‐pressure hydrocarbon injection injuries may produce substantial necrosis of underlying tissue despite an innocuous appearing external wound. These injuries often require extensive

Page 3 of 7 58‐97‐1280

ProPEX Grease 03A

emergency surgical debridement and all injuries should be evaluated by a specialist in order to assess the extent of injury. Early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.

SECTION 5: FIRE FIGHTING MEASURES NFPA 704 Hazard Class HMIS No Data

EXTINGUISHING MEDIA: In accordance with NFPA guidance, dry chemical, foam, or CO2 fire extinguishers are all acceptable. Note that while water fog

extinguishers are also acceptable, DO NOT apply a direct stream of water onto burning product because it may cause spreading and increase fire intensity.

UNUSUAL FIRE & EXPLOSION HAZARDS: No further data known. FIRE‐FIGHTING PROCEDURES AND EQUIPMENT:

Emergency responders in the danger area should wear bunker gear and self‐contained breathing apparatus for fires beyond the incipient stage. See Section 8 of the MSDS for other PPE to be worn as conditions warrant. See Section 9 for Flammable Properties including Flash Point and Flammable (explosive) limits.

SECTION 6: ACCIDENTAL RELEASE MEASURES Clean‐Up Measures: Important: As with any spill or lead, before responding ensure that you are familiar with the potential hazards and

recommendations of the MSDS. Appropriate personal protective equipment must be worn. See Section 8 of this MSDS for PPE recommendations.

If possible, safely contain the spill with dikes or other spill response equipment appropriate for petroleum or organic material

releases. Take measures to prevent spreading of product. Note that while product will ignite it will not readily burn. However, as a precaution eliminate ignition sources. Prevent from entering sewers or waterways. Large volumes may be transferred to an appropriate container for proper disposal. Small volumes or residues may be soaked up with absorbents. Spill response materials should be collected for proper disposal.

SECTION 7: HANDLING AND STORAGE HANDLING: As with any industrial chemical, handle the product in a manner that minimizes exposure to practicable levels. Prior to handling,

consult Section 8 of this MSDS to evaluate personal protective equipment needs. Open containers slowly to relieve any pressure. Follow all other standard industrial hygiene practices.

Empty containers may contain product residue. All safety precautions taken when handling this product should also be taken

when handling empty drums and containers. Keep containers closed when not in use. Product residue in empty containers is combustible but will not readily burn. NOTE however, that excessive heating or cutting

of empty containers may create an ignitions source sufficient to start a fire and in extreme cases, cause an explosion.

Page 4 of 7 58‐97‐1280

ProPEX Grease 03A

STORAGE: Protect product quality by storing indoors and away from extreme temperatures. Close all containers when not in use.

SPECIAL COMMENTS:

No further data known.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Selection of personal protective equipment should be based upon the anticipated exposure and made in accordance with OSHA’s Personal Protective Equipment Standard found in 29 CFR 1910 Subpart I. The following information may be used to assist in PPE selection.

Ingredient OSHAPEL

ACGIHTLV

California Prop 65 Reg. Y/N

IARC/NTPY/N

Petrolatum Notestablished

Not established

N N

Triethanolamine TWA5mg/m3*

TWA5mg/m3*

N N

Molybdenum Disulfide TWA3mg/m3*

TWA3mg/m3*

N N

Mineral Oil TWA5mg/m3*

TWA5mg/m3*

N N

Lubricating Additives Notestablished

Not established

N N

Note: This product has been evaluated and does not require any hazard warning label under the OSHA Hazard Communication Standard.

* As oil mist, if generating

EYE PROTECTION

Wear eye protection appropriate to prevent eye exposure. Where splashing is not likely, chemical safety glasses with side shields are recommended. Where splashing may occur, chemical goggles or full face shield is recommended.

SKIN PROTECTION:

Gloves are not normally needed during normal conditions of use. If health effects are experienced, oil or chemical resistant gloves such as butyl or nitrile are recommended.

Where splashing or soaking is likely, wear oil or chemical resistant clothing to prevent exposure.

RESPIRATORY PROTECTION:

A respirator may be worn to reduce the exposure to dust. Select a NIOSH/MSHA approved respirator appropriate for the type and physical character of the airborne material. A self‐contained breathing apparatus is recommended in all situations where airborne contaminant concentration has not been confirmed to be below safe levels. Respirator use should comply with the OSHA Respirator Protection Standard found in CFR 1910.134.

ENGINEERING CONTROLS:

Normal general ventilation is expected to be adequate. It is recommended that ventilation be designed in all instances to maintain airborne concentrations at lowest practicable levels. Ventilation should at a minimum, prevent airborne concentrations from exceeding any exposure limits listed in Section 2 of this MSDS.

Page 5 of 7 58‐97‐1280

ProPEX Grease 03A

The user may wish to refer to 29 CFR 1910.1000 (d) (2) and the ACGIH “Threshold Limit Values for Chemical Substances and Physical Agents Biological Exposure Indices” (Appendix C) for the determination of exposure limits of mixtures. An industrial hygienist or similar professional may be consulted to confirm that the calculated exposure limits apply.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Data represent typical values and are not intended to be specifications. NA=Not Applicable; ND=Not Determined Physical state: ................................. Semi‐Solid Flammability (solid, gas): ............................. NA Colour: ............................................ Dark Gray Upper Explosive Limits (vol % in air): .......... NA Odor: .............................................. Oil Odor Lower Explosive Limits (vol % in air): ........... NA Odor Threshold: ............................. ND Vapor pressure: ............................................ NA pH: ................................................. NA Vapor density: .............................................. NA Melting/Freezing Point: ................. NA Relative density: ........................................... 1.45 VOC Content: .................................. NA Solubility: ...................................................... Insoluable Boiling Point: .................................. NA Partition Coefficient: .................................... NA Flash Point: ..................................... 200oC Auto‐ignition Temperature: ......................... NA Evaporation Rate:........................... ND Decomposition Temperature: ...................... NA Specific Gravity: ............................ ND Viscosity: ....................................................... ND

SECTION 10: STABILITY AND REACTIVITY

INCOMPATIBLE MATERIALS: This product is incompatible with strong acids.

DECOMPOSITION PRODUCTS MAY INCLUDE: Thermal decomposition products are dependent on combustion conditions. A complex mixture of airborne solid, liquid,

particulates and gasses may evolve when the material burns. CONDITIONS TO AVOID:

Avoid contact with incompatible materials and exposure to extreme temperatures. POLYMERIZATION:

This product is not expected to polymerize. CHEMICAL STABILITY:

This product is stable. REACTIVITY: Stable under normal ambient and anticipated conditions of use.

SECTION 11: TOXICOLOGY INFORMATION

LIKELY ROUTES OF EXPOSURE: Inhalation, Eye and Skin contact ACUTE SYMPTOMS AND EFFECTS:

Inhalation: No further toxicological data known Eye contact: No further toxicological data known Skin contact: No further toxicological data known Ingestion: No further toxicological data known

Page 6 of 7 58‐97‐1280

ProPEX Grease 03A

OTHER: No further data known.

SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION:

This product has not been evaluated for ecotoxicity. As with any industrial chemical, exposure to the environment should be prevented and minimized wherever possible.

TOXICITY: No data available PERSISTENCE AND DEGRADABILITY (BIOPERSISTENCY & BIODEGRADABILITY):

The degree of biodegradability and persistence of this product has not been determined. POTENTIAL OF BIOACCUMULATION: No data available MOBILITY IN SOIL: No data available OTHER ADVERSE EFFECTS: No data available

SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL:

Ensure that collection, transport, treatment, and disposal of waste product, containers and rinsate complies with all applicable laws and regulations. Note that use, mixture, processing, or contamination of the product may cause the material to be classified as a hazardous waste. It is the responsibility of the product user or owner to determine at the time of disposal, whether the product is regulated as a hazardous waste.

SECTION 14: TRANSPORT INFORMATION DOT HAZARDOUS MATERIAL INFORMATION:

Not otherwise DOT regulated.

SECTION 15: REGULATORY INFORMATION FEDERAL REGULATIONS: SARA 313: This product contains NONE of the substances subject to the reporting requirements of Section 313 of Title III of the

Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. Clean Water Act / Oil Pollution Act:

This product contains mineral oil and is subject to regulation by Section 311 of the Clean Water Act and the Oil Pollution Act. Releases of the product into or leading to surface waters must be reported to the National Response Center at 1‐800‐424‐8802.

Page 7 of 7 58‐97‐1280

ProPEX Grease 03A

CERCLA Reportable Quantity: Any components listed below have been assigned a reportable quantity (RQ) by the Federal EPA. Releases of the product

into the environment that exceed the RQ for a particular component must be reported to the National Response Center at 1‐800‐424‐8802.

Toxic Substance Control Act:

The components of this product are listed on the TSCA Inventory. Ozone Depleting Substances: This product contains no ozone depleting substances as defined by the Clean Air Act. Hazardous Air Pollutants: Any components listed below are defined by the Federal EPA as hazardous air pollutants. STATE REGULATIONS: This product contains mineral oil, and as used, may be regulated by the state used oil regulations. Check with the appropriate state agency to determine whether such a regulation exists.

No further data known.

SECTION 16: OTHER INFORMATION

ABBREVIATIONS: TSCA ..................... Toxic Substance Control Act ICAO ..................... International Civil Aviation Organization IMDG ...................... International Maritime Dangerous OSHA .................... Occupational Safety and Health IARC/NTP ............... International Agency for Research on Cancer/National Toxicology Program SARA ..................... Superfund Amendments and Reauthorization Act of 1986 ACGIH ................... American Conference of Governmental Industrial Hygienists NIOSH/MSHA ........ National Institute for Occupational Safety Health/ Mine Safety and Health Administration WHMIS ................... Workplace Hazardous Materials Information System Prepared by: Milwaukee Electric Tool Corporation The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation. MILWAUKEE ELECTRIC TOOL CORPORATION makes no warranty, expressed or implied, regarding the accuracy of this data or the results to be obtained from the use thereto. All risks associated with product use are assumed by the user.

S A F E T Y D A T A S H E E T

RECTORSEAL® T PLUS 2®

Pipe Thread Sealant with PTFE

Page 1

GHS CLASSIFICATION

Physical Hazards None

Health Hazards

Acute Toxicity: Oral: Not Classified Dermal: Not Classified Inhalation: Not Classified Skin Corrosion/Irritation: Not Classified Serious Eye Damage/Eye Irritation: Not Classified Respiratory or Skin Sensitization: Not Classified Germ Cell Mutagenicity: Not Classified Carcinogenicity: Not Classified Reproductive Toxicology: Not Classified Target Organ Systemic Toxicity - Single Exposure: Not Classified Target Organ Systemic Toxicity - Repeated Exposure: Not Classified

Aspiration Toxicity: Not Classified

Section 2 – HazardS identification

Section 1 – Product and comPany information

Product Name Rectorseal® T Plus 2®

Product Codes 23112, 23191, 23271, 23391, 23431, 23551, 23552, 23631, 23633, 23710, 23714

Chemical Family Organic

Use Pipe thread sealant

Manufacturer's Name The RectorSeal Corporation 2601 Spenwick Drive Houston, Texas 77055 USA

Date of Validation January 23, 2015

Date of Preparation May 30, 2013

HMIS Codes Health 1 Flammability 1 Reactivity 0 PPI B

Emergency Telephone No. Chemtrec 24 Hours (800)-424-9300 USA (703)-527-3887 International

Technical Service Telephone No. ( 800)-231-3345 or (713)-263-8001


Page 2

Section 3 – comPoSition/information on ingredientS

ENVIRONMENTAL HAZARDS Hazardous to the Aquatic Environment: Not Classified Acute aquatic toxicity: Not Classified Chronic aquatic toxicity: Not Classified Bioaccumulation potential: Not Classified Rapid degradability: Not Classified

GHS Label elements, including precautionary statements

Pictogram: None

Signal Word: None

Hazard Statements: None

Precautionary Statements: P102 - Keep out of reach of children. P264 - Wash hands thoroughly after handling.

May produce slight to moderate skin and eye irritation.

Route Of Exposure, Signs And Symptoms

INHALATION None known.

EYE CONTACT Irritation, watering may occur.

SKIN CONTACT Frequent or prolonged contact may irritate and cause dermatitis.

INGESTION May cause nausea and vomiting. Not expected to produce toxic effects unless large amounts are ingested.

SUMMARY OF CHRONIC HAZARDS None known.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Individuals with pre-existing or chronic diseases of the eyes, skin or persons with chemical sensitivity may have increased susceptibility to excessive exposures.

% by WT CAS Number INGREDIENT UNITS

None as defined by OSHA Hazard Communication Standard 29 CFR 1910.1200.


Page 3

Section 5 – fire figHting meaSureS

Section 6 – accidental releaSe meaSureS

Section 7 – Handling and Storage

Extinguishing Media Foam, dry chemical, carbon dioxide or water fog.

Special Fire Fighting Procedures: Wear self-contained breathing apparatus (SCBA) and other protective clothing. Hazardous decomposition products possible (see Section 10).

Unusual Fire And Explosion Hazards: Heat may build up pressure and rupture closed containers. Above 500°F (260°C) the fumes are acutely toxic.

Steps To Be Taken In Case Material Is Released Or Spilled: Wipe or scrape up spilled material to prevent footing hazard and place in trash.

Precautions To Be Taken In Handling And Storing: Keep container closed and upright when not in use.

Other Precautions: Avoid prolonged or repeated contact with skin or clothing. Empty containers may contain residues; treat as if full and observe all products precautions. Do not reuse empty containers.

KEEP OUT OF REACH OF CHILDREN.

Section 4 – firSt aid meaSureS

If inhaled: N/A

If on skin: Wash with soap and water. Seek medical attention if irritation persists.

If in eyes: Flush with large amounts of water. Get medical attention if irrtation persists.

If swallowed: If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person.


Page 4

Section 8 – exPoSure controlS/PerSonal Protection

Section 9 – PHySical and cHemical ProPertieS

Respiratory Protection (Specify Type): None required.

Ventilation - Local Exhaust: N/A

Special: N/A

Mechanical (General): N/A

Other: N/A

Protective Gloves: Wear rubber gloves.

Eye Protection: Chemical splash goggles (ANSI Z-87.1 or equivalent)

Other Protective Clothing Or Equipment: Coveralls recommended.

Work/Hygienic Practices: Where use can result in skin contact, wash exposed areas thoroughly before eating, drinking, smoking, or leaving work area. Launder contaminated clothing before reuse.

Boiling point: N/D Specific gravity (H20 = 1): 1.32

Vapor pressure (mmHg): < 1 @77°F (25°C)

Melting point: N/A

Vapor Density (Air = 1): N/A

Evaporation rate (Ethyl Acetate = 1): N/A

Appearance/Odor: White paste/Slight odor

Solubility in water: Negligible

Volatile Organic Compounds (VOC) Content (theoretical percentage by weight): 0% or (0 g/L)

Flash point: >300°F (149°C) SETA CC

Lower explosion limit: N/D

Upper explosion limit: N/D

Section 10 – Stability and reactivity

Stability: Stable

Conditions To Avoid: None known.

Incompatibility (Materials To Avoid): Gaseous oxygen and strong oxidizing materials.

Hazardous Decomposition Products: CO, CO2 and fragmented hydrocarbons.

Hazardous Polymerization: Will not occur.


Page 5

Section 12 – ecological information

Section 11 – toxicology information

Chronic Health Hazards No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.

Toxicology Data

Ingredient Name

Oral-Rat LD50: N/A Inhalation-Rat LC50: N/A

Ecological Data

Ingredient Name:

Food Chain Concentration Potential N/A


BOD N/A

Aquatic Toxicity N/A

Section 13 – diSPoSal conSiderationS

Waste Classification: Non-regulated solid waste

Disposal Method: Approved landfill

Waste from this product is not considered hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Dispose of in accordance with Federal, State, and Local regulation regarding pollution.

Section 14 – tranSPortation information

DOT: Non-regulated

Ocean (IMDG): Non-regulated

Air (IATA): Non-regulated

WHMIS (Canada): Non-regulated


Page 6

Section 15 – regulatory information

Section 16 – otHer information

Regulatory Data

Ingredient Name:

SARA 313 N/A

TSCA Inventory All components listed

CERCLA RQ N/A

RCRA Code N/A

This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200). The information herein is given in good faith, but no warranty, expressed or implied is made.

Consult RectorSeal for further information: (713) 263-8001


Safety Data Sheet* Trusted Quality Since 1921 *

www.rustoleum.com

1. Identification

Product Name: PRO LSPR 6PK MARK FLUORESCENTORANGE

Revision Date: 5/12/2017

Product Identifier: 2554838 Supercedes Date: 6/5/2015

Product Use/Class: Marking Paint/Aerosols

Supplier: Rust-Oleum Corporation11 Hawthorn ParkwayVernon Hills, IL 60061USA

Manufacturer: Rust-Oleum Corporation11 Hawthorn ParkwayVernon Hills, IL 60061USA

Preparer: Regulatory Department

24 Hour Hotline: 847-367-7700Emergency Telephone:

2. Hazard Identification

Classification

Symbol(s) of Product

Signal Word

Danger

Possible Hazards

27% of the mixture consists of ingredient(s) of unknown acute toxicity.

GHS HAZARD STATEMENTSCarcinogenicity, category 2 H351 Suspected of causing cancer.

Compressed Gas H280 Contains gas under pressure; may explode if heated.

Flammable Aerosol, category 1 H222 Extremely flammable aerosol.

STOT, repeated exposure, category 2 H373 May cause damage to organs through prolonged or repeated exposure.

GHS LABEL PRECAUTIONARYSTATEMENTSP201 Obtain special instructions before use.

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Nosmoking.

P211 Do not spray on an open flame or other ignition source.

P251 Do not pierce or burn, even after use.

P260 Do not breathe dust/fume/gas/mist/vapors/spray.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P314 Get medical advice/attention if you feel unwell.

P405 Store locked up.

P410+P403 Protect from sunlight. Store in a well-ventilated place.

P410+P412 Protect from sunlight. Do no expose to temperatures exceeding 50°C/ 122°F.

Page 1 / 6


P501 Dispose of contents/container in accordance with local, regional and national regulations.

3. Composition/Information On Ingredients

HAZARDOUS SUBSTANCES

Chemical Name CAS-No. Wt.%Range

GHS Symbols GHS Statements

Propane 74-98-6 10-25 GHS04 H280

Naphtha, Petroleum, Hydrotreated Light 64742-49-0 2.5-10 GHS08 H304

n-Butane 106-97-8 2.5-10 GHS04 H280

Hydrotreated Light Distillate 64742-47-8 2.5-10 GHS08 H304

Xylenes (o-, m-, p- isomers) 1330-20-7 2.5-10 GHS02-GHS07 H226-315-319-332

Barium Sulfate 7727-43-7 2.5-10 Not Available Not Available

Ethylbenzene 100-41-4 1.0-2.5GHS02-GHS07-GHS08

H225-304-332-351-373

Stoddard Solvent 8052-41-3 0.1-1.0 GHS08 H304-372

Pigment Orange 13 3520-72-7 0.1-1.0 Not Available Not Available

Crystalline Silica / Quartz 14808-60-7 0.1-1.0 Not Available Not Available

4. First-aid Measures

FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed.

FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.

FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.

FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention.

5. Fire-fighting Measures

EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog

UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20°F. EXTREMELY FLAMMABLE LIQUID AND VAPOR!Water spray may be ineffective. Closed containers may explode when exposed to extreme heat due to buildup of steam. Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a source of ignition and flash back. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Perforation of the pressurized container may cause bursting of the can. No unusual fire or explosion hazards noted.

SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Full protective equipment including self-contained breathing apparatus should be used. Evacuate area and fight fire from a safe distance. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.

6. Accidental Release Measures

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STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Ventilate area, isolate spilled material, and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations.


HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse. Use only in a well-ventilated area. Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.

STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Contents under pressure. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of flammable aerosols. Keep away from heat, sparks, flame and sources of ignition. Contents under pressure. Do not expose to heat or store above 120 ° F. Avoid excess heat. Product should be stored in tightly sealed containers and protected from heat, moisture, and foreign materials.

8. Exposure Controls/Personal Protection

Chemical Name CAS-No.Weight %Less Than

ACGIH TLV-TWA

ACGIH TLV-STEL

OSHA PEL-TWA

OSHA PEL-CEILING

Propane 74-98-6 20.0 N.E. N.E. 1000 ppm N.E.Naphtha, Petroleum,Hydrotreated Light

64742-49-0 10.0 N.E. N.E. N.E. N.E.

n-Butane 106-97-8 10.0 N.E. 1000 ppm N.E. N.E.Hydrotreated Light Distillate 64742-47-8 10.0 N.E. N.E. N.E. N.E.Xylenes (o-, m-, p- isomers) 1330-20-7 5.0 100 ppm 150 ppm 100 ppm N.E.Barium Sulfate 7727-43-7 5.0 5 mg/m3 N.E. 15 mg/m3 N.E.Ethylbenzene 100-41-4 5.0 20 ppm N.E. 100 ppm N.E.Stoddard Solvent 8052-41-3 1.0 100 ppm N.E. 500 ppm N.E.Pigment Orange 13 3520-72-7 1.0 N.E. N.E. N.E. N.E.Crystalline Silica / Quartz 14808-60-7 1.0 0.025 mg/m3 N.E. 50 µg/m3 N.E.

PERSONAL PROTECTION

ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use explosion-proof ventilation equipment. Provide general dilution of local exhaust ventilation in volume and pattern to keep TLV of hazardous ingredients below acceptable limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation.

RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits.

SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection.

EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.

OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications. Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application.

HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.

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Appearance: Aerosolized Mist Physical State: Liquid

Odor: Solvent Like Odor Threshold: N.E.

Relative Density: 0.857 pH: N.A.

Freeze Point, °C: N.D. Viscosity: N.D.

Solubility in Water: Slight Partition Coefficient, n-octanol/water: N.D.

Decompostion Temp., °C: N.D.

Boiling Range, °C: -37 - 537 Explosive Limits, vol%: 0.9 - 12.6

Flammability: Supports Combustion Flash Point, °C: -96

Evaporation Rate: Faster than Ether Auto-ignition Temp., °C: N.D.

Vapor Density: Heavier than Air Vapor Pressure: N.D.

(See "Other information" Section for abbreviation legend)


CONDITIONS TO AVOID: Avoid temperatures above 120°F (49°C). Avoid contact with strong acid and strong bases. Avoid all possible sources of ignition.

INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.

HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.

HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.

STABILITY: This product is stable under normal storage conditions.


EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation

EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin irritation. May cause skin irritation. Allergic reactions are possible. Prolonged or repeated contact may cause skin irritation.

EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and lungs. Prolonged or excessive inhalation may cause respiratory tract irritation.

EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed. Aspiration hazard if swallowed; can enter lungs and cause damage.

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: May cause central nervous system disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. IARC lists Ethylbenzene as a possible human carcinogen (group 2B).

PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact

ACUTE TOXICITY VALUESThe acute effects of this product have not been tested. Data on individual components are tabulated below:

CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50

74-98-6 Propane N.I. N.I. 658 mg/L Rat64742-49-0 Naphtha, Petroleum, Hydrotreated Light >5000 mg/kg Rat >3160 mg/kg Rabbit >4951 mg/L Rat106-97-8 n-Butane N.I. N.I. 658 mg/L Rat64742-47-8 Hydrotreated Light Distillate >5000 mg/kg Rat >2000 mg/kg Rabbit >5000 mg/L Rat1330-20-7 Xylenes (o-, m-, p- isomers) 3500 mg/kg Rat >4350 mg/kg Rabbit 29.08 mg/L Rat100-41-4 Ethylbenzene 3500 mg/kg Rat 15400 mg/kg Rabbit 17.4 mg/L Rat3520-72-7 Pigment Orange 13 >5000 mg/kg Rat N.I. N.I.14808-60-7 Crystalline Silica / Quartz 5500 mg/kg Rat 5500 100 mg/L

N.I. - No Information

Page 4 / 6



ECOLOGICAL INFORMATION: Product is a mixture of listed components. Product is a mixture of listed components.

13. Disposal Information

DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow to enter waterways, wastewater, soil, storm drains or sewer systems.

14. Transport Information

Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)

UN Number: N.A. 1950 1950 N.A.

Proper Shipping Name:Paint Products inLimited Quantities

Aerosols AerosolsPaint Products inLimited Quantities

Hazard Class: N.A. 2.1 2.1 N.A.

Packing Group: N.A. N.A. N.A. N.A.

Limited Quantity: Yes Yes Yes Yes


U.S. Federal Regulations:

CERCLA - SARA Hazard Category

This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of theSuperfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, tomeet the following categories:

Fire Hazard, Pressure Hazard, Acute Health Hazard, Chronic Health Hazard

Sara Section 313:

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of theSuperfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

Chemical Name CAS-No.

Xylenes (o-, m-, p- isomers) 1330-20-7Ethylbenzene 100-41-4

Toxic Substances Control Act:

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exportedfrom the United States:

Chemical Name CAS-No.

Castor oil, sulfated, sodium salt 68187-76-8

Page 5 / 6



HMIS RATINGSHealth: 2* Flammability: 4 Physical Hazard: 0 Personal Protection: X

NFPA RATINGSHealth: 2 Flammability: 4 Instability 0

VOLATILE ORGANIC COMPOUNDS, g/L: 551

SDS REVISION DATE: 5/12/2017

REASON FOR REVISION: Product Composition ChangedSubstance and/or Product Properties Changed in Section(s): 02 - Hazard Identification 05 - Fire-fighting Measures 16 - Other InformationStatement(s) Changed

Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.

Page 6 / 6

SAFETY DATA SHEET Gasoline, Conventional and Reformulated

1. IDENTIFICATION Product Identifier Gasoline, Unleaded With Ethanol

Synonyms: 87 Octane Conventional (Oxygenated and Non-oxygenated) and Reformulated (RFG) Regular

Unleaded Gasoline; 89 Octane Conventional (Oxygenated and Non-oxygenated) and Reformulated (RFG) Regular Unleaded Gasoline; 91-93 Octane Conventional (Oxygenated and Non-oxygenated) and Reformulated (RFG) Regular Unleaded Gasoline

Intended use of the product:

Fuel

Contact: Global Companies LLC Water Mill Center 800 South St. Waltham, MA 02454-9161 www.globalp.com

Contact Information: EMERGENCY TELEPHONE NUMBER (24 hrs): CHEMTREC (800) 424-9300 COMPANY CONTACT (business hours): 800-542-0778

2. HAZARD IDENTIFICATION

According to OSHA 29 CFR 1910.1200 HCS Classification of the Substance or Mixture Classification (GHS-US): Flammable Liquid Category 2 H225 Acute Toxicity Category 4 H332 Skin Corrosion/Irritation Category 2 H315 Carcinogenicity Category 1A H350 Germ Cell Mutagenicity Category 1B H340 Reproductive Toxicity Category 2 H361d STOT RE Category 1 H372 Aspiration Hazard Category 1 H304

Labeling Elements

Signal Word (GHS-US): Danger Hazard Statements (GHS-US): H225 – Highly flammable liquid and vapor.

H304 - May be fatal if swallowed and enters airways. H332 - Harmful if inhaled. H315 - Causes skin irritation. H350 – May cause cancer. H340 – May cause genetic defects. H361 – Suspected of damaging fertility or the unborn child. H372 – Causes damage to organs through prolonged or repeated exposure.

Precautionary Statements (GHS-US): P201 - Obtain special instructions before use.

P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

Page 1 of 13 May 2016

http://www.globalp.com/


P233 - Keep container tightly closed. P240 – Ground/bond container and receiving equipment. P241 – Use explosion-proof electrical/ventilating/lighting equipment pursuant to applicable electrical code. P242 – Use only non-sparking tools. P243 – Take precautionary measures against static discharge. P260 - Do not breathe dust/fume/gas/mist/vapors/spray. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P303+361+353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse with water/shower. P308+311 - If exposed or concerned: Get medical advice/attention. P301+310 - If swallowed: Immediately call a poison center/doctor/… P331 - Do NOT induce vomiting. P370+P378 – In case of fire use firefighting foam or other appropriate media for Class B fires to extinguish. P403 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 – Dispose of contents/container in accordance with local/regional/national/international regulation.

Other information: NFPA Health: 1 Fire: 3 Reactivity:0

3. COMPOSITION / INFORMATION ON INGREDIENTS

Chemical Composition Information

Name Product Identifier (CAS#) % (w/w) Classification Gasoline 8006-61-9 100 Carc 1B, H350; Muta 1B,

H340; Asp 1, H304 Benzene 71-43-2 0.1 to 4.9 (0.1 to 1.3*) Flam liq 2, H225; Carc 1A,

H350; Muta 1B H340; STOT RE 1, H372; Asp 1, H304; Eye Irrit 2, H319; Skin Irrit 2, H315

Ethyl Alcohol (Ethanol) 64-17-5 0 – 10 Flam Liq 2 H225

Toluene 108-88-3 0 – 15 Flam liq 2, H225; Repro 2, H361d; STOT RE 2, H373; Asp 1, H304; Skin Irrit 2, H315; STOT SE 3, H336

Xylene, mixed isomers 1330-20-7 0 – 15 Flam Liq 3, H226; Acute Tox 4, H332; Acute Tox 4, H312; Skin Irrit 2, H315

Ethyl Benzene 100-41-4 < 4 Flam Liq 2, H225; Acute Tox 4, H332; STOT RE 2, H373; Asp 1, H304

1,2,4- Trimethylbenzene 95-63-6 <5 Flam Liq 3, H226; Acute Tox 4, H332; Acute Tox 4, H312; Skin Irrit 2, H315; Eye Irrit 2, H319; STOT SE 3, H335; Acute Aquatic 2, H411

*for reformulated gasoline

1

3

0



Additional Formulation Information A complex blend of petroleum-derived normal and branched-chain alkane, cycloalkane, alkene, and aromatic hydrocarbons. Butane is often added to increase volatility, especially in winter. May contain antioxidant and multifunctional additives. Oxygenated and reformulated gasoline will have legally-required amounts of oxygenates (Ethanol) to increase octane levels.

RBOB and PBOB are gasoline base stocks and do not contain any Oxygenates (Ethanol).

*Also see Section 15 for list of SARA Section 313 toxic chemicals.


Route Measures Inhalation Remove person to fresh air. If person is not breathing, ensure an open airway and provide artificial

respiration. If necessary, provide additional oxygen once breathing is restored if trained to do so. Seek medical attention immediately.

Ingestion Aspiration Hazard: DO NOT INDUCE VOMITING. Do not give liquids. Obtain immediate medical attention. If spontaneous vomiting occurs, lean victim forward to reduce the risk of aspiration. Small amounts of material which enter the mouth should be rinsed out until the taste is dissipated.

Eye Contact If present, remove contact lenses. In case of contact with eyes, immediately flush with clean, low-pressure water for at least 15 mm. Hold eyelids open to ensure adequate flushing. Seek medical attention.

Skin Contact Remove contaminated clothing and shoes. Wash contaminated areas thoroughly with soap and water or waterless hand cleanser. Obtain medical attention if irritation or redness develops.

Absorption As with skin contact, remove contaminated clothing and flush with copious amounts of water. Flush affected area for at least 15 minutes to minimize potential for further absorption. Seek medical attention if significant portions of skin have been exposed.

Most Important Symptoms Contact may cause eye, skin and mucous membrane irritation. Harmful if absorbed through the skin. Avoid prolonged breathing of vapors or mists. Inhalation may cause irritation, anesthetic effects (dizziness, nausea, headache, intoxication), and respiratory system effects.

Long-term exposure may cause effects to specific organs, such as to the liver, kidneys, blood, nervous system, and skin. Contains benzene, which can cause blood disease, including anemia and leukemia.

Immediate Medical Attention and Special Treatment If ingested, do NOT induce vomiting, as this may cause chemical pneumonia (fluid in the lungs).

Application of epinephrine may cause cardiac arrhythmia in persons exposed to large quantities of hydrocarbon vapor or due to skin absorption. Observe for development of symptoms leading to cardiac arrhythmia.

Urine samples may be obtained to determine biological effects of benzene exposure and should be collected in accordance with the medical surveillance criteria in 29 CFR 1910.1028.

Contaminated clothing, including shoes may present a fire hazard and should be discarded

Medical Conditions Aggravated by Exposure Irritation from skin exposure may aggravate existing open wounds, skin disorders, and dermatitis (rash). Chronic respiratory disease, liver or kidney dysfunction, or pre-existing central nervous system disorders may be aggravated by exposure.

5. FIRE-FIGHTING MEASURES

Extinguishing Media SMALL FIRES: Any extinguisher suitable for Class B fires, dry chemical, C02, water spray, fire fighting foam, or Halon.

LARGE FIRES: Water spray, fog or fire fighting foam. Water may be ineffective for fighting the fire, but may be used to cool fire-exposed containers.

During certain times of the year and/or in certain geographical locations, gasoline may contain additional additives. Firefighting



foam suitable for polar solvents is recommended for fuel with greater than 10% oxygenate concentration - refer to NFPA 11 ‘Low Expansion Foam -1994 Edition.”

Specific Hazards / Products of Combustion Vapors may be ignited rapidly when exposed to heat, spark, open flame or other source of ignition. Flowing product may be ignited by self-generated static electricity. When mixed with air and exposed to an ignition source, flammable vapors can burn in the open or explode in confined spaces. Being heavier than air, vapors may travel long distances to an ignition source and flash back. Runoff to sewer may cause fire or explosion hazard.

Combustion may produce smoke, carbon monoxide and other products of incomplete combustion.

Special Precautions and Protective Equipment for Firefighters Small fires in the incipient (beginning) stage may typically be extinguished using handheld portable fire extinguishers and other firefighting equipment.

Firefighting activities that may result in potential exposure to high heat, smoke or toxic by-products of combustion should require NIOSH/MSHA- approved pressure-demand self-contained breathing apparatus with full face piece and full protective clothing.

Isolate area around container involved in fire. Cool tanks, shells, and containers exposed to fire and excessive heat with water. For massive fires the use of unmanned hose holders or monitor nozzles may be advantageous to further minimize personnel exposure. Major fires may require withdrawal, allowing the tank to burn. Large storage tank fires typically require specially trained personnel and equipment to extinguish the fire, often including the need for properly applied fire fighting foam.

See Section 9 for fire properties of this chemical including flash point, autoignition temperature, and explosive limits


Personal Precautions

ACTIVATE FACILITY SPCC, SPILL CONTINGENCY or EMERGENCY PLAN.

Depending on the size of the spill, downwind receptors may need to be notified.

Evacuate nonessential personnel and remove or secure all ignition sources (flame, spark, hot work, hot metal, etc.). Consider wind direction; stay upwind and uphill, if possible. Evaluate the direction of product travel, diking, sewers, etc. to confirm spill areas. Do not touch or walk-through spilled material.

Highly flammable material, even small spills may pose a fire danger for emergency responders. Due to high vapor density, flammable / toxic vapors may be present in low lying areas, dikes, pits, drains, or trenches. Ventilate the area. Use of non-sparking tools and intrinsically safe equipment is recommended. Potential for flammable atmosphere should be monitored using a combustible gas indicator positioned down wind of the spill area. See Sections 2 and 7 for further hazard warnings and handling instructions.

Use appropriate personal protective equipment to prevent eye/skin contact and absorption. Use NIOSH approved respiratory protection, if warranted, to prevent exposures above permissible limits (see Section 8). Contaminated clothing should not be near sources of ignition.

Environmental Precautions Stop the spill to prevent environmental release if it can be done safely. Product is toxic to aquatic life. Take action to isolate environmental receptors including drains, storm sewers and natural water bodies. Keep on impervious surface if at all possible. Use water sparingly to prevent product from spreading. Foam and absorbents may be used to reduce / prevent airborne release.

Spills may infiltrate subsurface soil and groundwater; professional assistance may be necessary to determine the extent of subsurface impact.

Follow federal, state or local requirements for reporting environmental release where necessary (see Section 15 for further information)

Containment and Clean-Up Methods Carefully contain and stop the source of the spill, if safe to do so. Protect bodies of water by diking absorbents, or absorbent



boom, if possible. Do not flush down sewer or drainage systems, unless system is designed and permitted to handle such material. The use of fire fighting foam may be useful in certain situations to reduce vapors. The proper use of water spray may effectively disperse product vapors or the liquid itself, preventing contact with ignition sources or areas/equipment that require protection.

Take up with dry earth, sand or other non-combustible, inert oil absorbing materials. Carefully shovel, scoop or sweep up into a waste container with clean, non-sparking tools for reclamation or disposal. Response and clean-up crews must be properly trained and must utilize proper protective equipment (see Section 8).


Handling Precautions

USE ONLY AS A MOTOR FUEL DO NOT SIPHON BY MOUTH

Handle as a flammable liquid. Keep away from heat, sparks, and open flame. No smoking. Electrical equipment should be approved for classified area. Bond and ground containers during product transfer pursuant to NFPA 70 and API RP 2003 to reduce the possibility of static-initiated fire or explosion. Follow precautions to prevent static initiated fire.

Use good personal hygiene practices. Use only with protective equipment specified in Section 8. Avoid repeated and/or prolonged skin exposure. Use only outdoors or in well ventilated areas. Wash hands before eating, drinking, smoking, or using toilet facilities. Do not use as a cleaning solvent on the skin. Do not use solvents or harsh abrasive skin cleaners for washing this product from exposed skin areas. Waterless hand cleaners are effective. Promptly remove contaminated clothing and launder before reuse. Use care when laundering to prevent the formation of flammable vapors which could ignite via washer or dryer. Consider the need to discard contaminated leather shoes and gloves. Emergency eye wash capability should be available in the near proximity to operations presenting a potential splash exposure.

Vapors are heavier than air and can accumulate in low lying areas (e.g., tanks, pits, vaults, dikes, drains, etc.) Follow specific procedures for confined space entry in areas where product may be present pursuant to OSHA requirements in 29 CFR 1910.146. Atmospheric testing using a combustible gas indicator may be necessary in confined areas where product may be present.

Special slow load procedures for “switch loading” must be followed to avoid the static ignition hazard that can exist when higher flash point material (such as fuel oil) is loaded into tanks previously containing low flash point products (such as this product) - see API Publication 2003, “Protection Against Ignitions Arising Out Of Static, Lightning and Stray Currents.

Storage Keep away from flame, sparks, excessive temperatures and open flame. Store in approved tanks or containers. Keep containers closed and clearly labeled. Label all secondary containers that this material is transferred into with the chemical name and associated hazard(s). Empty product containers or vessels may contain explosive vapors. Do not pressurize, cut, heat, weld or expose such containers to sources of ignition. Separate from incompatible materials (see Section 10) by distance or secondary containment.

Store in a well-ventilated area. Protect containers from damage and vehicular traffic. Post “No Smoking” signs in product storage areas. This storage area should comply with NFPA 30 “Flammable and Combustible Liquid Code”. Avoid storage near incompatible materials. The cleaning of tanks previously containing this product should follow API Recommended Practice (RP) 2013 “Cleaning Mobile Tanks In Flammable and Combustible Liquid Service” and API RP 2015 “Cleaning Petroleum Storage Tanks”.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Occupational Exposure Limits

Component CAS # List Value Gasoline 8006-61-9 ACGIH TWA

ACGIH STEL 300 ppm 500 ppm

Benzene 71-43-2 ACGIH TLV-TWA ACGIH STEL OSHA AL

0.5 ppm* 2.5 ppm* 0.5 ppm



Component CAS # List Value OSHA TWA OSHA STEL

1 ppm 5 ppm

Ethyl Alcohol (Ethanol) 64-17-5 ACGIH STEL OSHA PEL

1000 ppm 1000 ppm

Toluene 108-88-3 ACGIH TWA OSHA TWA OSHA Ceiling limit OSHA Ceiling limit Peak

20 ppm 200 ppm 300 ppm 500 ppm (10 min)

Xylene, mixed isomers 1330-20-7 ACGIH TWA ACGIH STEL OSHA PEL

100 ppm 150 ppm 100 ppm

Ethyl Benzene 100-41-4 ACGIH TWA OSHA PEL OSHA STEL

20 ppm 100 ppm 125 ppm

1,2,4- Trimethylbenzene 95-63-6 ACGIH TWA

25 ppm

*Skin designation indicates the chemical is skin absorbable

Engineering Controls Use adequate ventilation to keep vapor concentrations of this product below occupational exposure and flammability limits, particularly in confined spaces. Intrinsically safe equipment and non-sparking tools shall be used in circumstances where concentrations may exceed lower flammable limits. Grounding and bonding shall be used to prevent accumulation and discharge of static electricity.

Emergency shower and eyewash should be provided in proximity to handling areas in the event of exposure to decontaminate.

Personal Protective Equipment

Exposure Equipment Eye / Face Safety glasses or goggles are recommended where there is a possibility of splashing or spraying.

Skin Gloves constructed of nitrile or neoprene are recommended when handling this material. If contact with the body is expected, chemical protective clothing such as of E.l. DuPont Tychem ®, Barricade®, or equivalent recommended based on degree of exposure.

Note: The resistance of specific material may vary from product to product as well as with degree of exposure. Consult manufacturer specifications for further information.

Respiratory A NIOSH/MSHA-approved air-purifying respirator with organic vapor cartridges or canister may be permissible under certain circumstances where airborne concentrations are or may be expected to exceed exposure limits or for odor or irritation. Protection provided by air-purifying respirators is limited. Refer to OSHA 29 CFR 1910.134, ANSI Z88.2-1992, NIOSH Respirator Decision Logic, and the manufacturer for additional guidance on respiratory protection selection and limitations.

Use a positive pressure, air-supplied respirator if there is a potential for uncontrolled release, exposure levels are not known, in oxygen-deficient atmospheres, or any other circumstance where an air-purifying respirator may not provide adequate protection.

Specific requirements under the OSHA occupational exposure to Benzene may apply if concentrations exceed the action level or permissible limits. Consult 29 CFR 1910.1028 for further information)

Thermal Product is stored at ambient temperature. No thermal protection is required except for emergency operations involving actual or potential for fire.




Property Value Comments Appearance A clear, water-like liquid

Odor A strong, characteristic aromatic hydrocarbon odor. Oxygenated gasoline with Ethanol may have a alcohol-like odor and is detectable at a lower concentration than non-oxygenated gasoline.

Odor Threshold Parameter Odor Detection Odor Recognition Non-oxygenated gasoline

0.5-0.6 ppm 0.8-1.1 ppm

Gasoline with 10% Ethanol

0.2-0.3 ppm 0.4-0.7 ppm

pH Not available

Melting / Freeze Point - 150 ˚F

Boiling Point And Range 85 to 437 0F (39 to 200 C)

Flash Point -45 0F (-43 C)

Evaporation Rate 10-11 (n-butyl acetate = 1)

Flammability Flammable liquid

Flammability Limits 1.4 – 7.6% (est)

Vapor Pressure 7-15 RVP @100 0F (38 C) 275-475mm Hg @ 68 0F (20 C)

Vapor Density 3- 4

Specific Gravity 0.76 (water =1)

Solubility Non-oxygenated gasoline-negligible (<0.1% @770F). Gasoline with 10% Ethanol has greater solubility than other oxygenates

Partition Coefficient 2-7 as Log P

Autoignition Temperature highly variable; >530 0F (>280 C)

Decomposition Temperature

Evaporation or ignition likely before decomposition will occur

Viscosity 0.64 – 0.88 mm2/sec

Percent Volatiles 100%


Reactivity Material is not self reacting, flammable concentrations may be present in air.

Stability Normally stable unless mixed with incompatibles or fire in presence of an ignition source. Material is flammable liquid.

Reactions / Polymerization Stable. Hazardous polymerization will not occur.

Conditions to Avoid Avoid high temperatures, open flames, sparks, welding, smoking and other ignition sources



Incompatible Materials Keep away from strong acids and oxidizers.

Hazardous Decomposition Products Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke). Contact with nitric and sulfuric acids will form nitrocresols that can decompose violently.


Acute Toxicity: Acute Toxicity (Inhalation LC50)

Gasoline (8006-61-9) LC50 Inhalation Human 2000 ppm/1 hr

Benzene (71-43-2) LC50 Inhalation Rat 10,000 ppm/7 hr

Ethanol (64-17-5) LC50 Inhalation Rat >20,000 ppm/10 hr

Toluene (108-88-3) LC50 Inhalation Mouse 400 ppm/4 hr

1,2,4 Trimethylbenzene (95-63-6) LC50 Inhalation Mouse 2000 ppm/48 hr

Xylene (1330-20-7) LC50 Inhalation Rat 6350 ppm/4 hr

Acute Toxicity (Oral LC50)

Gasoline (8006-61-9) LC50 Oral Rat 14,063 mg/l/4h

Benzene (71-43-2) LC50 Oral Rat 3306 mg/kg

Ethanol (64-17-5) LC50 Oral Rat 7060 mg/kg

Toluene (108-88-3) LC50 Oral Rat 2600 mg/kg

1,2,4 Trimethylbenzene (95-63-6) LC50 Oral Rat 3550 mg/kg

Xylene (1330-20-7) LC50 Oral Rat >3500 mg/kg

Ethylbenzene (100-41-4) LC50 Oral Rat 3500 mg/kg

Acute Toxicity (Dermal LC50)

Gasoline (8006-61-9) LD50 Dermal Rabbit >5 mL/kg

Benzene (71-43-2) LD50 Dermal Rabbit >8260 mg/kg

Toluene (108-88-3) LC50 Dermal Rabbit 12,200 mg/kg



1,2,4 Trimethylbenzene (95-63-6) LC50 Dermal Rabbit >3160 mg/kg

Xylene (1330-20-7) LC50 Dermal Rabbit >43 g/kg

Ethylbenzene (100-41-4) LC50 Dermal Rabbit 17,800 mg/kg

Skin Corrosion/Irritation: Causes skin irritation.

Serious Eye Damage/Irritation: Not classified

Respiratory or Skin Sensitization: Not classified

Germ Cell Mutagenicity: May cause genetic defects.

Carcinogenicity: OSHA: NO IARC: YES - 2B NTP: NO ACGIH: YES (A3)

IARC has determined that gasoline and gasoline exhaust are possibly carcinogenic in humans. Inhalation exposure to completely vaporized unleaded gasoline caused kidney cancers in male rats and liver tumors in female mice. EPA has determined that the male kidney tumors are species-specific and are irrelevant for human health risk assessment. The significance of the tumors seen in female mice is not known. Exposure to light hydrocarbons in the same boiling range as this product has been associated in animal studies with effects to the central and peripheral nervous systems, liver, and kidneys. The significance of these animal models to predict similar human response to gasoline is uncertain.

This product contains benzene. Human health studies indicate that prolonged and/or repeated overexposure to benzene may cause damage to the blood-forming system (particularly bone marrow), and serious blood disorders such as aplastic anemia and leukemia. The NTP, ARC, OSHA and ACGIH list benzene as a human carcinogen.

Reproductive Toxicity: May damage/Suspected of damaging fertility or the unborn child.

Teratogenicity: Not available

Specific Target Organ Toxicity (Repeated Exposure): Excessive exposure may cause irritations to the nose, throat, lungs and respiratory tract. Central nervous system (brain) effects may include headache, dizziness, loss of balance and coordination, unconsciousness, coma, respiratory failure, and death.

Specific Target Organ Toxicity (Single Exposure): Single over-exposure likely to cause central nervous system effects (dizziness and drowsiness), excessive exposure could cause paralysis or cardiac arrhythmia.

Aspiration Hazard: This chemical is considered to be an aspiration hazard. Aspiration may result in chemical pneumonia (fluid in the lungs), severe lung damage, respiratory failure and even death.

Potential Health Effects: Vapor irritating to eyes, nose, and throat. Ingestion may cause gastrointestinal disturbances, including irritation, nausea, vomiting and diarrhea, and central nervous system (brain) effects similar to alcohol intoxication. In severe cases, tremors, convulsions, loss of consciousness, coma, respiratory arrest, and death may occur. Inhalation at high concentrations in confined spaces with less than 16% oxygen needed to sustain life, skin and /or eye contact (liquid).

Chronic effects: Human inhalation (chronic) >500 ppm (approx 1.8 mg/L)/ day. Effects: May cause vomiting, diarrhea, insomnia, headache dizziness, anemia, muscle & neurological symptoms.

WARNING: the burning of any hydrocarbon as a fuel in an area without adequate ventilation may result in hazardous levels of combustion products, including carbon monoxide, and inadequate oxygen levels, which may cause unconsciousness, suffocation, and death.


Toxicity Material is toxic to aquatic organisms on an acute basis (LC50/EC50 between 1 and 10 mg/L in the most sensitive species tested).

EC50 Daphnia 30 mmol/m3 (Exposure time: 48 h - Species: Daphnia magna) LC 50 Fish 7.7 mg/l (Exposure time: 96 h - Species: Pimephales promelas)



Persistence and Degradation: Not available

Bioaccumulative Potential: Not available

Mobility in Soil: Not available

Other Adverse Effects: None known

Other Information: Avoid release to the environment.

13. DISPOSAL CONSIDERATIONS Consult federal, state and local waste regulations to determine appropriate disposal options. May be considered a hazardous waste if disposed. Direct solid waste (landfill) or incineration at a solid waste facility is not permissible. Do not discharge to sanitary or storm sewer. Personnel handling waste containers should follow precautions provided in this document.

Shipping containers must be DOT authorized packages. Follow licensure and regulations for transport of hazardous material and hazardous waste as applicable.


US DOT UN Identification Number UN 1203 Proper Shipping Name Gasoline Hazard Class and Packing Group 3, PG II Shipping Label Flammable Liquid Placard / Bulk Package Flammable / 1203 Emergency Response Guidebook Guide Number 128

IATA Cargo UN Identification Number UN1203 Shipping Name / Description Gasoline Hazard Class and Packing Group 3, PG II ICAO Label 3 Packing Instructions Cargo 364, Y341 Max Quantity Per Package Cargo 60 L

IATA Passenger UN Identification Number UN1203 Shipping Name / Description Gasoline Hazard Class and Packing Group 3, PG II ICAO Label 3 Packing Instructions Passenger 353, Y341 Max Quantity Per Package 5 L

IMDG UN Identification Number UN1203 Shipping Name / Description Gasoline Hazard Class and Packing Group 3, PG II IMDG Label 3 EmS Number F-E S-E Marine Pollutant No

15. REGULATORY INFORMATION

U.S. Federal, State, and Local Regulatory Information Any spill or uncontrolled release of this product, including any substantial threat of release, may be subject to federal, state and/or local reporting requirements. This product and/or its constituents may also be subject to other federal, state, or local



regulations; consult those regulations applicable to your facility/operation.

OSHA Hazard Communication Standard This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.

Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Sections 311 and 312 Immediate (Acute) Health Hazard Yes Delayed (Chronic) Health Hazard Yes Fire Hazard Yes Reactive Hazard No Sudden Release of Pressure Hazard No

Clean Water Act (Oil Spills) Any spill or release of this product to “navigable waters” (essentially any surface water, including certain wetlands) or adjoining shorelines sufficient to cause a visible sheen or deposit of a sludge or emulsion must be reported immediately to the National Response Center (1-800-424-8802) or, if not practical, the U.S. Coast Guard with follow-up to the National Response Center, as required by U.S. Federal Law. Also contact appropriate state and local regulatory agencies as required.

CERCLA Section 103 and SARA Section 304 (Release to the Environment) The CERCLA definition of hazardous substances contains a “petroleum exclusion” clause which exempts crude oil, refined, and unrefined petroleum products and any indigenous components of such. However, other federal reporting requirements (e.g., SARA Section 304 as well as the Clean Water Act if the spill occurs on navigable waters) may still apply.

SARA Section 313- Supplier Notification This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372.

• Benzene (71-43-2) • Benzene (71-43-2) for reformulated gasoline • Ethyl benzene (100-41-4) • n-Hexane (110-54-3) • Toluene (108-88-3) • 1,2,4- Trimethylbenzene (95-63-6) • Xylene, mixed isomers (1330-20-7)

Information on each ingredient’s concentration can be found in Section 3 Information on each ingredient’s exposure limits can be found in Section 8

EPA Notification (Oil Spills) If the there is a discharge of more than 1,000-gallons of oil into or upon navigable waters of the United States, or if it is the second spill event of 42 gallons or more of oil into water within a twelve (12) month period, a written report must be submitted to the Regional Administrator of the EPA within sixty days of the event.

Pennsylvania Right to Know Hazardous Substance list: The following product components are cited in the Pennsylvania Special Hazardous Substance List, and are present at levels which require reporting. Component CAS Amount Benzene 71-43-2 0.1-4.9% Xylene 1330-20-7 0-15% Toluene 108-88-3 0-15% 1,2,4-Trimethylbenzene 95-63-6 <5% Ethyl Benzene 100-41-4 <4%



New Jersey Right to Know Hazardous Substance list: The following product components are cited in the New Jersey Right to Know Hazardous Substance List, and are present at levels which require reporting. Component CAS Amount Gasoline 8006-61-9 100% Benzene 71-43-2 0.1-4.9% Xylene 1330-20-7 0-15% Toluene 108-88-3 0-15% 1,2,4-Trimethylbenzene 95-63-6 <5% Ethyl Benzene 100-41-4 <4%

California Prop. 65 WARNING: This product contains chemicals known to the State of California to cause Cancer or Reproductive Toxicity.

Component CAS Amount Benzene 71-43-2 0.1-4.9% Toluene 108-88-3 0-15% Ethyl Benzene 100-41-4 <4% Ethyl Alcohol 64-17-5 0-10%

U.S. Toxic Substances Control Act All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.30.

CEPA - Domestic Substances List (DSL) All substances contained in this product are listed on the Canadian Domestic Substances List (DSL) or are not required to be listed.

Canadian Regulatory Information (WHMIS) Class B, Division 2 (Flammable Liquid) Class D, Division 2A (Very toxic by other means) and Class D, Division 2B (Toxic by other means)


Version 5 Issue Date May 20, 2016 Prior Issue Date May 3, 2015

Description of Revisions Revised to meet Globally Harmonized System for chemical hazard communication requirements pursuant to OSHA regulatory revisions 77 FR 17884, March 26, 2012.

Abbreviations˚F Degrees fahrenheit (temperature) < Less than = Equal to > Greater than AP Approximately C Centigrade (temperature) kg Kilogram L Liter

mg Milligrams mL Milliliter mm2 Square millimeters mmHg Millimeters of mercury (pressure) ppm Parts per million sec Second ug Micrograms

AcronymsACGIH American Conference of Governmental

Industrial Hygienists AIHA American Industrial Hygiene Association

AL Action Level ANSI American National Standards Institute API American Petroleum Institute



CAS Chemical Abstract Service CERCLA Comprehensive Emergency Response,

Compensation, and Liability Act DOT U.S. Department of Transportation EC50 Ecological concentration 50% EPA U.S. Environmental Protection Agency ERPG Emergency Response Planning Guideline GHS Global Harmonized System HMIS Hazardous Materials Information System IARC International Agency for Research On Cancer IATA International Air Transport Association IMDG International Maritime Dangerous Goods Koc Soil Organic Carbon LC50 Lethal concentration 50% LD50 Lethal dose 50% MSHA Mine Safety and Health Administration NFPA National Fire Protection Association NIOSH National Institute of Occupational Safety and

Health NOIC Notice of Intended Change NTP National Toxicology Program OPA Oil Pollution Act of 1990

OSHA U.S. Occupational Safety & Health Administration

PEL Permissible Exposure Limit (OSHA) RCRA Resource Conservation and Recovery Act Reauthorization Act of 1986 Title III REL Recommended Exposure Limit (NIOSH) RVP Reid Vapor Pressure SARA Superfund Amendments and SCBA Self Contained Breathing Apparatus SPCC Spill Prevention, Control, and

Countermeasures STEL Short-Term Exposure Limit (generally 15

minutes) TLV Threshold Limit Value (ACGIH) TSCA Toxic Substances Control Act TWA Time Weighted Average (8 hr.) UN United Nations UNECE United Nations Economic Commission for

Europe WEEL Workplace Environmental Exposure Level

(AIHA) WHMIS Canadian Workplace Hazardous Materials

Information System

Disclaimer of Expressed and Implied Warranties Information presented herein has been compiled from sources considered to be dependable, and is accurate and reliable to the best of our knowledge and belief, but is not guaranteed to be so. Since conditions of use are beyond our control, we make no warranties, expressed or implied, except those that may be contained in our written contract of sale or acknowledgment.

Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material, even if reasonable safety procedures are followed. Furthermore, vendee assumes the risk in their use of the material.

** End of Safety Data Sheet **


SAFETY DATA SHEET

1. Identification

Smoke BombProduct identifier

None.Other means of identification

Restricted to professional users.Recommended use



Oatey Co.Company Name

Cherne Industries IncorporatedDivision

5700 Lincoln DriveAddress

Minneapolis, MN 55436

216-267-7100Telephone

[email protected]

Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)Transport Emergency

1-877-740-5015Emergency First Aid

MSDS CoordinatorContact person


Not classified.Physical hazards

Category 1BCarcinogenicityHealth hazards


Label elements

Signal word Danger

Hazard statement May cause cancer.


Prevention Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Wear protective gloves/protective clothing/eye protection/face protection.

Response If exposed or concerned: Get medical advice/attention.

Storage Store locked up.


Hazard(s) not otherwise

classified (HNOC)None known.

Supplemental information After ignition, this product emits smoke (mild Zinc Chloride solution) that can be irritating to theeyes, respiratory tract, and mucous membranes. when used as directed exposure should belimited and normally poses no hazard. Persons with known respiratory sensitivity should not beexposed to smoke. Moderate exposure may temporarily result in irritation, inflammation, anddifficulty breathing-moving to fresh air will reverse these effects. Heavy exposure may result incoughs, chills, fever, and pulmonary edema, requiring medical treatment. Overwhelming exposurecan be dangerous and is to be avoided. Persons who will be exposed to sustained heavy smokeshould wear self contained breathing apparatus (SCBA).

NOTE: Exposure is highly unlikely when product is used as directed. Product is sealed in heavycardboard tube or metal canister. After ignition, product slowly combusts and hexachloroethane isconsumed. Direct contact with product does not occur.

Smoke Bomb SDS US

932384 Version #: 02 Revision date: 03-April-2018 Issue date: 17-October-2017 1 / 8


Mixtures

67-72-1 30-55Hexachloroethane


All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.


Move to fresh air. Call a physician if symptoms develop or persist.Inhalation

Wash off with soap and water. Get medical attention if irritation develops and persists. Removecontaminated clothing and shoes.

Skin contact

Do not rub eyes. Rinse with water. Get medical attention if irritation develops and persists.Eye contact

Rinse mouth. Get medical attention if symptoms occur. Do not induce vomiting.Ingestion

May cause cancer.Most important

symptoms/effects, acute and

delayed

Provide general supportive measures and treat symptomatically. Keep victim under observation.Symptoms may be delayed.

Indication of immediate

medical attention and special

treatment needed

IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are awareof the material(s) involved, and take precautions to protect themselves.

General information


Foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media

DO NOT use water if avoidable.Unsuitable extinguishing

media

During fire, gases hazardous to health may be formed.Specific hazards arising from

the chemical

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment

and precautions for firefighters

Move containers from fire area if you can do so without risk. Use water spray to cool unopenedcontainers.

Fire fighting

equipment/instructions


Material may react with water.General fire hazards


Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wearappropriate protective equipment and clothing during clean-up. Use a NIOSH/MSHA approvedrespirator if there is a risk of exposure to dust/fume at levels exceeding the exposure limits. Ensureadequate ventilation. Local authorities should be advised if significant spillages cannot becontained. For personal protection, see section 8 of the SDS.

Personal precautions,

protective equipment and

emergency procedures

Avoid the generation of dusts during clean-up. Collect dust using a vacuum cleaner equipped withHEPA filter. Stop the flow of material, if this is without risk.

Large Spills: Shovel the material into waste container. Clean surface thoroughly to remove residualcontamination.

Small Spills: Sweep up or vacuum up spillage and collect in suitable container for disposal. Forwaste disposal, see section 13 of the SDS.

Methods and materials for

containment and cleaning up

Avoid release to the environment. Inform appropriate managerial or supervisory personnel of allenvironmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge intodrains, water courses or onto the ground.


Smoke Bomb SDS US



Persons with known respiratory sensitivity should not be exposed to smoke. Moderate exposuremay temporarily result in irritation, inflammation, and difficulty breathing - moving to fresh air willreverse these effects. Heavy exposure may result in coughs, chills, fever, and pulmonary edema,requiring medical treatment. Overwhelming exposure can be dangerous and is to be avoided.Persons who will be exposed to sustained heavy smoke should wear self contained breathingapparatus (SCBA). Wash thoroughly after handling. Obtain special instructions before use. Do nothandle until all safety precautions have been read and understood. Minimize dust generation andaccumulation. Provide appropriate exhaust ventilation at places where dust is formed. Avoidprolonged exposure. Should be handled in closed systems, if possible. Wear appropriate personalprotective equipment. Observe good industrial hygiene practices.


Store locked up. Store in original tightly closed container. Store in a well-ventilated place. Storeaway from incompatible materials (see Section 10 of the SDS). Keep away from heat, sparks, andflame. Keep away from sources of ignition - No smoking. Store in a dry area. Protect frommoisture.

Conditions for safe storage,

including any incompatibilities




ValueComponents Type

PEL 10 mg/m3Hexachloroethane (CAS67-72-1)

1 ppm



TWA 1 ppmHexachloroethane (CAS67-72-1)



TWA 10 mg/m3Hexachloroethane (CAS67-72-1)

1 ppm

No biological exposure limits noted for the ingredient(s).Biological limit values

Exposure guidelines


Hexachloroethane (CAS 67-72-1) Can be absorbed through the skin.

US - Minnesota Haz Subs: Skin designation applies

Hexachloroethane (CAS 67-72-1) Skin designation applies.

US - Tennessee OELs: Skin designation


US ACGIH Threshold Limit Values: Skin designation






Good general ventilation should be used. Ventilation rates should be matched to conditions. Ifapplicable, use process enclosures, local exhaust ventilation, or other engineering controls tomaintain airborne levels below recommended exposure limits. If exposure limits have not beenestablished, maintain airborne levels to an acceptable level. If engineering measures are notsufficient to maintain concentrations of dust particulates below the Occupational Exposure Limit(OEL), suitable respiratory protection must be worn. If material is ground, cut, or used in anyoperation which may generate dusts, use appropriate local exhaust ventilation to keep exposuresbelow the recommended exposure limits.

Appropriate engineering

controls

Individual protection measures, such as personal protective equipment

Chemical respirator with organic vapor cartridge, full facepiece, dust and mist filter.Eye/face protection

Skin protection

Wear appropriate chemical resistant gloves.Hand protection

Smoke Bomb SDS US


Skin protection

Use of an impervious apron is recommended.Other

Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at levelsexceeding the exposure limits. Chemical respirator with organic vapor cartridge, full facepiece,dust and mist filter.



Observe any medical surveillance requirements. Always observe good personal hygienemeasures, such as washing after handling the material and before eating, drinking, and/orsmoking. Routinely wash work clothing and protective equipment to remove contaminants.

NOTE: Exposure is highly unlikely when product is used as directed. Product is sealed in heavycardboard tube or metal canister. After ignition, product slowly combusts and hexachloroethane isconsumed. Direct contact with product does not occur.

General hygiene

considerations


Appearance

Solid.Physical state

Powder contained in sealed tube or canister.Form

Gray.Color

Mothballs.Odor


pH Not available.


Initial boiling point and boiling

range

Not available.

Flash point Not available.




Flammability limit - lower

(%)

Not available.

Flammability limit - upper

(%)

Not available.



Vapor pressure Not available.

Vapor density Not available.

Relative density Not available.

Solubility(ies)

Solubility (water) Not available.

Partition coefficient

(n-octanol/water)

Not available.



Viscosity Not available.

Other information

Not explosive.Explosive properties

Not oxidizing.Oxidizing properties


May react with water, producing smoke.Reactivity


No dangerous reaction known under conditions of normal use.Possibility of hazardous

reactions

Smoke Bomb SDS US


Moisture. High temperatures. High humidity.Conditions to avoid

Strong acids. Strong bases. Water.Incompatible materials

Zinc chloride. Smoke. Carbon monoxide (CO). Carbon dioxide (CO2).Hazardous decomposition

products


Information on likely routes of exposure

Inhalation Dust may irritate respiratory system. Prolonged inhalation may be harmful.

Skin contact Dust or powder may irritate the skin.

Eye contact Dust may irritate the eyes.

Ingestion Expected to be a low ingestion hazard.

Symptoms related to the

physical, chemical and

toxicological characteristics

Dusts may irritate the respiratory tract, skin and eyes. May cause cancer.


Acute toxicity Not expected to be acutely toxic.


Hexachloroethane (CAS 67-72-1)

Dermal

Acute


Oral

LD50 Rat 4460 mg/kg

Prolonged skin contact may cause temporary irritation.Skin corrosion/irritation

Direct contact with eyes may cause temporary irritation.Serious eye damage/eye

irritation






Carcinogenicity May cause cancer. The International Agency for Research on Cancer (IARC) concluded that therewas inadequate evidence in humans for the carcinogenicity of hexachloroethane. IARC indicatesthat there is sufficient evidence in experimental animals based on oral exposure to mice and ratsthat resulted in hepatocellular carcinomas and renal tubular adenomas and carcinomas. Oralexposure is not an anticipated route of exposure for this product.


Hexachloroethane (CAS 67-72-1) 2B Possibly carcinogenic to humans.

NTP Report on Carcinogens

Hexachloroethane (CAS 67-72-1) Reasonably Anticipated to be a Human Carcinogen.


Not regulated.



single exposure

Not classified.


repeated exposure

Not classified.

Aspiration hazard Not an aspiration hazard.

Chronic effects Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.


Very toxic to aquatic life with long lasting effects.Ecotoxicity

Smoke Bomb SDS US




Aquatic

LC50Fish 0.712 - 1.03 mg/l, 96 hoursBluegill (Lepomis macrochirus)

0.967 - 1.25 mg/l, 96 hoursFathead minnow (Pimephales promelas)

No data is available on the degradability of this product. Persistence and degradability


Partition coefficient n-octanol / water (log Kow)

Hexachloroethane (CAS 67-72-1) 4.14


Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creationpotential.


Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose ofcontents/container in accordance with local/regional/national/international regulations.






Waste from residues / unused

products

Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal.



DOT


IATA


IMDG


Not applicable.Transport in bulk according to

Annex II of MARPOL 73/78 and

the IBC Code

15. Regulatory information

This product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.



Not regulated.


Hexachloroethane (CAS 67-72-1) Listed.

Zinc (CAS 7440-66-6) Listed.

SARA 304 Emergency release notification

Not regulated.


Not regulated.


Superfund Amendments and Reauthorization Act of 1986 (SARA)

Not listed.

YesSARA 311/312 Hazardous

chemical

CarcinogenicityClassified hazard

categories

Smoke Bomb SDS US


SARA 313 (TRI reporting)

Chemical name % by wt.CAS number

Hexachloroethane 30-5567-72-1

Zinc ≤ 17440-66-6




Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Not regulated.

Not regulated.Safe Drinking Water Act

(SDWA)




Zinc (CAS 7440-66-6)



Zinc (CAS 7440-66-6)



Zinc (CAS 7440-66-6)



Zinc (CAS 7440-66-6)

California Proposition 65

WARNING: This product contains a chemical known to the State of California to cause cancer.WARNING:

California Proposition 65 - CRT: Listed date/Carcinogenic substance

Hexachloroethane (CAS 67-72-1) Listed: July 1, 1990

US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,

subd. (a))


Zinc (CAS 7440-66-6)



Australian Inventory of Chemical Substances (AICS) YesAustralia


Non-Domestic Substances List (NDSL) NoCanada


Inventory of Existing and New Chemical Substances (ENCS) YesJapan

Existing Chemicals List (ECL) YesKorea



YesPhilippines

Taiwan Chemical Substance Inventory (TCSI) YesTaiwan




17-October-2017Issue date

03-April-2018Revision date

Version # 02

Smoke Bomb SDS US


Health: 1*Flammability: 0Physical hazard: 0

HMIS® ratings

NFPA ratings

00

0

Oatey Co. cannot anticipate all conditions under which this information and its product, or theproducts of other manufacturers in combination with its product, may be used. It is the user’sresponsibility to ensure safe conditions for handling, storage and disposal of the product, and toassume liability for loss, injury, damage or expense due to improper use. The information in thesheet was written based on the best knowledge and experience currently available.

Disclaimer

Smoke Bomb SDS US


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Safety Data Sheet

1 - Chemical Product and Company Identification Manufacturer: WD-40 Company Address: 1061 Cudahy Place (92110) P.O. Box 80607 San Diego, California, USA 92138 –0607 Telephone: Emergency only: 1-888-324-7596 (PROSAR) Information: 1-888-324-7596 Chemical Spills: 1-800-424-9300 (Chemtrec) 1-703-527-3887 (International Calls)

Chemical Name: Organic Mixture Trade Name: WD-40 Aerosol Product Use: Lubricant, Penetrant, Drives Out Moisture, Removes and Protects Surfaces From Corrosion MSDS Date Of Preparation: 01/09/12

2 – Hazards Identification GHS Classification: Flammable Aerosol Category 1 GHS Label Elements:

DANGER! H222 Extremely Flammable Aerosol. P210 Keep away from heat, sparks, open flames, hot surfaces – No smoking. P211 Do not spray on an open flame or other ignition source. P251 Pressurized container: Do not pierce or burn, even after use. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. 3 - Composition/Information on Ingredients

Ingredient CAS # Weight Percent GHS Classification Aliphatic Hydrocarbon 64742-47-8 <70 Flammable Liq 3 Petroleum Base Oil 64742-53-6

64742-56-9 64742-65-0

<25 Not Hazardous

Non-Hazardous Rust Inhibitors Mixture <10 Not Hazardous Non-Hazardous Lubricant Mixture <10 Not Hazardous Carbon Dioxide 124-38-9 <3 Not Hazardous Fragrance Mixture <1 Not Hazardous 4 – First Aid Measures Ingestion (Swallowed): Aspiration Hazard. DO NOT induce vomiting. Call physician, poison control center or the WD-40 Safety Hotline at 1-888-324-7596 immediately. Eye Contact: Flush thoroughly with water. Remove contact lenses if present after the first 5 minutes and continue flushing for several more minutes. Get medical attention if irritation persists. Skin Contact: Wash with soap and water. If irritation develops and persists, get medical attention. Inhalation (Breathing): If irritation is experienced, move to fresh air. Get medical attention if irritation or other symptoms develop and persist.

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Signs and Symptoms of Exposure: May cause eye and respiratory irritation. Inhalation may cause coughing, headache and dizziness. Skin contact may cause drying of the skin. 5 – Fire Fighting Measures Extinguishing Media: Use water fog, dry chemical, carbon dioxide or foam. Do not use water jet or flooding amounts of water. Burning product will float on the surface and spread fire. Special Fire Fighting Procedures: Firefighters should always wear positive pressure self-contained breathing apparatus and full protective clothing. Cool fire-exposed containers with water. Use shielding to protect against bursting containers. Unusual Fire and Explosion Hazards: Contents under pressure. Keep away from ignition sources and open flames. Exposure of containers to extreme heat and flames can cause them to rupture often with violent force. Vapors are heavier than air and may travel along surfaces to remote ignition sources and flash back. 6 – Accidental Release Measures Wear appropriate protective clothing (see Section 8). Eliminate all sources of ignition and ventilate area. Leaking cans should be placed in a plastic bag or open pail until the pressure has dissipated. Contain and collect liquid with an inert absorbent and place in a container for disposal. Clean spill area thoroughly. Report spills to authorities as required. 7 – Handling and Storage Handling: Avoid contact with eyes. Avoid prolonged contact with skin. Avoid breathing vapors or aerosols. Use only with adequate ventilation. Keep away from heat, sparks, pilot lights, hot surfaces and open flames. Unplug electrical tools, motors and appliances before spraying or bringing the can near any source of electricity. Electricity can burn a hole in the can and cause contents to burst into flames. To avoid serious burn injury, do not let the can touch battery terminals, electrical connections on motors or appliances or any other source of electricity. Wash thoroughly with soap and water after handling. Keep containers closed when not in use. Keep out of the reach of children. Do not puncture, crush or incinerate containers, even when empty. Storage: Store in a cool, well-ventilated area, away from incompatible materials Do not store above 120F or in direct sunlight. U.F.C (NFPA 30B) Level 3 Aerosol. 8 – Exposure Controls/Personal Protection Chemical Occupational Exposure Limits

Aliphatic Hydrocarbon 1200 mg/m3 TWA (manufacturer recommended)

Petroleum Base Oil

5 mg/m3 (inhalable)ACGIH TLV TWA 5 mg/m3 TWA OSHA PEL

Non-Hazardous Rust Inhibitors None Established

Non-Hazardous Lubricant None Established

Carbon Dioxide 5000 ppm TWA (OSHA/ACGIH), 30,000 ppm STEL (ACGIH)

Fragrance None Established

The Following Controls are Recommended for Normal Consumer Use of this Product Engineering Controls: Use in a well-ventilated area. Personal Protection: Eye Protection: Avoid eye contact. Always spray away from your face. Skin Protection: Avoid prolonged skin contact. Chemical resistant gloves recommended for operations where skin contact is likely. Respiratory Protection: None needed for normal use with adequate ventilation. For Bulk Processing or Workplace Use the Following Controls are Recommended Engineering Controls: Use adequate general and local exhaust ventilation to maintain exposure levels below that occupational exposure limits. Personal Protection:

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Eye Protection: Safety goggles recommended where eye contact is possible. Skin Protection: Wear chemical resistant gloves. Respiratory Protection: None required if ventilation is adequate. If the occupational exposure limits are exceeded, wear a NIOSH approved respirator. Respirator selection and use should be based on contaminant type, form and concentration. Follow OSHA 1910.134, ANSI Z88.2 and good Industrial Hygiene practice. Work/Hygiene Practices: Wash with soap and water after handling. 9 – Physical and Chemical Properties

Boiling Point: 300F (150°C) Specific Gravity: 0.8 – 0.82 @ 60F Solubility in Water: Insoluble pH: Not Applicable Vapor Pressure: 95-115 PSI @ 70F Vapor Density: Greater than 1 Percent Volatile: 65% VOC: 533 grams/liter (65%) Coefficient of Water/Oil Distribution:

Not Determined Appearance/Odor Light amber liquid/mild odor

Flash Point: 113F (45°C) Closed Cup (concentrate)

Flammable Limits: (Solvent Portion)

LEL: 0.6% UEL: 8.0%

10 – Stability and Reactivity Stability: Stable Hazardous Polymerization: Will not occur. Conditions to Avoid: Avoid heat, sparks, flames and other sources of ignition. Do not puncture or incinerate containers. Incompatibilities: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide and carbon dioxide. 11 – Toxicological Information Symptoms of Overexposure: Inhalation: High concentrations may cause nasal and respiratory irritation and central nervous system effects such as headache, dizziness and nausea. Intentional abuse may be harmful or fatal. Skin Contact: Prolonged and/or repeated contact may produce mild irritation and defatting with possible dermatitis. Eye Contact: Contact may be irritating to eyes. May cause redness and tearing. Ingestion: This product has low oral toxicity. Swallowing may cause gastrointestinal irritation, nausea, vomiting and diarrhea. This product is an aspiration hazard. If swallowed, can enter the lungs and may cause chemical pneumonitis, severe lung damage and death. Chronic Effects: None expected. Medical Conditions Aggravated by Exposure: Preexisting eye, skin and respiratory conditions may be aggravated by exposure. Suspected Cancer Agent: Yes No X The oral toxicity of this product is estimated to be greater than 5,000 mg/kg based on an assessment of the ingredients. This product is not classified as toxic by established criteria. It is an aspiration hazard. None of the components of this product is listed as a carcinogen or suspected carcinogen or is considered a reproductive hazard. 12 – Ecological Information No specific aquatic toxicity data is currently available, however components of this product are not expected to be harmful to aquatic organisms and are readily biodegradable.

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13 - Disposal Considerations If this product becomes a waste, it would be expected to meet the criteria of a RCRA ignitable hazardous waste (D001). However, it is the responsibility of the generator to determine at the time of disposal the proper classification and method of disposal. Dispose in accordance with federal, state, and local regulations. 14 – Transportation Information_ DOT Surface Shipping Description: Consumer Commodity, ORM-D until 12/31/2013 After 1/1/2014 UN1950, Aerosols, 2.1 Ltd. Qty (Note: Shipping Papers are not required for Limited Quantities unless transported by air or vessel – each package must be marked with the Limited Quantity Mark) IMDG Shipping Description: Un1950, Aerosols, 2.1, LTD QTY 15 – Regulatory Information

China Regulations on the Control over Safety of Dangerous Chemicals: This product matches this regulation. All ingredients in this product has listed in IECSC( Inventory of Existing Chemical Substances in China 2010)

16 – Other Information: HMIS Hazard Rating: Health – 1 (slight hazard), Fire Hazard – 4 (severe hazard), Reactivity – 0 (minimal hazard)

SIGNATURE: TITLE: Director of Global Consumer Relations and Regulatory Affairs REVISION DATE: January 2012 SUPERSEDES: June 2010

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