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DURA SEAL MANUA L / SECTION III / PAGE 6 SECTION 2 SECONDARY SEAL ATERIALS Se c ondar y s eal s applied to me c hani c al sealsare define d more speci fi ca ll y as s haft pac k - in g an d inse rt mo unting . Beca u se t h ey are static and are called upon to seal imperfect surfa c es , seconda r y seals must possess a degree of resi li - ency which will a ll ow them to  seat  pe r fect l y agai n st adjacent su r faces . T h e m ost e l astic o r r esilie n t of a ll seco nd ary sea l s a r e e l as t o m e r s w h ich D ura m eta lli c applies i n t h e conf g ur a ti o n of  rings. How e ver , t h e temp r at ur e a nd chemical resistance of elasto m e r ic m ate ri a l s a r e of t en exceeded , thus r eq ui r in g t h e use of oth er lessresili ent ma ter ia l s. Beca u se t h es e ot h er materials lack the e l asticity of e l asto m e r s, t h ey assume configu ratio n s that te n d t o compe n sate for their limited resiliency . T h ep u rpose of t h is sub-s ection is to discuss t h e th r ee types of sec- ondary sealsoffered by D ur ametallic . 11I 2 1 ELASTOMER 0 R IN GS It has already been pointed out t h at e l as - tomers , as use d for se co nda r y seals by Du r ame - tal l ic , assume the co n figu r atio n of  r i n gs . Figu r e I II - C i llu strates t h e a p p l ication of elasto- mer  rings as s h af t pac k i n g and i n se rt mounting . F I . III C 0 RING SECONDARY SEALS BUNA N  N I TRILE ) T h is mat e rial , o ft e n refer r ed to as Nitri l e , i sa c opo l y m er of butadiene a n d ac r ylonit ri le . Bu n aN h asan ex c ell e nt resi s tance to pet r o l eum p r od u cts , a l so f i nding wide a cc eptance i n water app l ica ti ons . Bun a N ca n be exposed to te m pe r at ur es r a n g in g f r o m - 4 F to +225° F  -40°C to + 1 07° C ) . Inh e r e n t l y B un a N Does n ot possess goo d r es i s t a n ce to ozo n e , su nli ght , o r weat h e r . T h e r e- fo r e , spa r e Bu na N  ri n gs sh ou l d not be sto r e d i n di r ec t s unl ig ht o r adjacent to e l ect r ica l eq u ip - men t th at m ay ge n er ate ozon e . NE O P RE N E Neo pr e n e , correctly called C hl o r op r e n e r u bbe r , was among the earlie s toft h e sy n t h etic ru bbe r saai l able to s ea l manufac t ur e r s . It con - tin u es t o be used for refrigerants ; s u c h as , f r eo n a n d a mm onia , a n d ot h er mild se r vices. L ike Bun a N , N eop r e n e ca n be s u bjecte d t o te mp era- tu r esf r o m -4 F to +22 5°F  - 40 ° Ct o + 1 0 7 ° C ) . BUTYL T h is is a n a ll pe tr o l e u m p r o du c t p r o du ced by co p o l y m e ri z in g iso bu ty l e n e a nd isop r e n e . B ut y l ru bbe r w ill r e s i s t th e dete r io r at in g effec t s of m a n y m i l d l iq u id s, s u c h as M EK a nd aceto n e , b u t s h o ul d not be used i n pet r o l e um o il s . I ts t empe r at u re r a ge is -40°F to +225° F  -40° C to +1078C ) . SIL I CONE RUBBER Sili c one ela s tom e r s a r e mad e from s ili co n e, o xygen , h ydrog e n , and ca r bo n . Th ey usua ll y di s - pla y poor t e n s i I e s tr e n g th , t ea r , a nd abra s ion r es istan ce . Sili c on e  rin gs a r e n o t re co mm e nd e d f o r u se in m os t p e tr o l e um f luid s or k e t o n es. Th e y ca n b e s u ccess full ya ppli e d to temp e r a t u r es r a n g i ng from - 80°F to + 4000F  -62°C to +204°C ).

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DURA SEA L M A NUA L / SECT ION III / PA GE 6

SECTION 111.2

SECONDARY SEAL MATERIALS

Secondary seals applied to mechanical

sealsare defined more specifically asshaft pack-

ing and insert mounting. Because they are static

and are called upon to seal imperfect surfaces,

secondary seals must possessa degree of resili-

ency which will allow them to "seat" perfectly

against adjacent surfaces. The most elastic or

resilient of all secondary seals are elastomers

which Durametallic applies in the configuration

of "0" rings. However, the temperature and

chemical resistance of elastomeric materials

are often exceeded, thus requiring the use of

other lessresilient materials. Becausethese othermaterials lack the elasticity of elastomers, they

assumeconfigurations that tend to compensate

for their limited resiliency. The purpose of this

sub-section is to discuss the three types of sec-

ondary sealsoffered by Durametallic.

11 I.2 .1 E L AS TO MER " 0" R ING S

It has already been pointed out that elas-

tomers, asused for secondary seals by Durame-

tallic, assume the configuration of "0" rings.

Figure III-C illustrates the application of elasto-

mer "0" rings as shaft packing and insert

mounting.

F IG . I I I - C " 0 " R IN G S E C O N D A R Y S E A L S

BUNA N (NITRILE)

This material, often referred to as Nitrile,

is a copolymer of butadiene and acrylonitrile.

Buna N hasan excellent resistance to petroleum

products, also finding wide acceptance in water

applications.

Buna N can be exposed to temperatures

ranging from -40°F to +225°F (-40°C to

+107°C).

Inherently Buna N Does not possess good

resistance to ozone, sunlight, or weather. There-

fore, spareBuna N"0" rings should not be stored

in direct sunlight or adjacent to electrical equip-

ment that may generate ozone.

NEOPRENE

Neoprene, correctly called Chloroprene

rubber, was among the earliest of the synthetic

rubbers available to seal manufacturers. It con-

tinues to be used for refrigerants; such as, freon

and ammonia, and other mild services. Like

Buna N, Neoprene can be subjected to tempera-

turesfrom -40°Fto +225°F (-40°Cto +107°C).

BUTYL

This is an all petroleum product produced

by copolymerizing isobutylene and isoprene.

Butyl rubber will resist the deteriorating

effects of many mild liquids, such as MEK and

acetone, but should not be used in petroleum

oils. Its temperature range is -40°F to +225°F

(-40°C to +1078C).

SILICONE RUBBER

Silicone elastomers are made from silicone,

oxygen, hydrogen, and carbon. They usually dis-

play poor tensi Ie strength, tear, and abrasion

resistance.

Silicone "0" rings are not recommended

for use in most petroleum fluids or ketones.

They can be successfully applied to temperatures

ranging from -80°F to +4000F (-62°C to

+204°C).