WU{J^I I^JIIU rikJillilllO^iaLfV^

RecordJDocument

00l l28 R E C E^^ECOLOGY AND ENVIRONMENT INC.. JUN 1 ^ 1565

REGION VI f9al*f')' ^——i 5--VK-"?

mU^NAKY REPORT. . . . . . „ _ , Thia Jim Trusley, Bill Barham, Bob Stewart andLarry Landry.

Station Descriptions and Chemical Analysis

Sample station locations are shown in Figure 1 .

laboratory QA/QC results are reported in Appendix A.

(Photo #1) - The sample was col tected at Mr. BillBrown's drinking water well, which is locatedapproximately 0,25 miles east of ORC. This well is 35'deep and is completed in the Rush Springs Formation,Field analytical results are as follows; pH = 7,4;conductivity - 1500 umhos; temperature - 13" C. Labora-tory analytical results did not reveal any organiccontamination or any significant inorganic contaminants.

(Photo #2) - A sediment sample was collected from GladysCreek upstream from ORC, 100' north of railroad bridge.Organic and inorganic analytical results indicated no

,̂ w^ ̂ ")Kr^^^^^i'-.'/nssri, .vrrWJn ̂ ••yA-

ssavitch001128

s1^^fiCs^^•Srounrf. nt ^centra.,,,ai^ - ̂ ,, °" " ""

ctrafcion matrix from storage pit tf5. Organic dataanalysts revealed only contaminants which were alsofound in the lab blank. Inorganic analysis detectedelevated concentrations of arsenic (10.5 ppm); cadmium(.61 ppm); lead (25.500 ppm); magnesium (15. 200 ppm);and mercury (0.38 ppm).

" (Photo #9 ) - The sample was collected as a high concen-tration matrix from storage pit ff6. Organic dataanalysis detected 100,000 ppb of phenanthrene, 7600 ppbof total xylenes, 1900 ppb toluene; 100,000 ppb pyrene;additionally, 1 tentatively identified unknown wasdetected at a concentration of 200,000 ppb; 18 hydro-carbons total ing 14,890,000 ppb; and 1 aromatic at730,000 ppb was detected. Inorganic data analysisdetected elevated levels cf antimony (84 ppm); arsenic(231 ppm); cadmium (1.6 ppm); chromium (9300 ppm);cobalt (17 ppm); copper (1050 ppm); lead (2200 ppm;)magnesium (277,000 ppm); mercury (0.38 ppm); nickel (37ppm); selenium (2.0 ppm); vanadium (3.9 ppm); and zinc(195 ppm).

- (Photo HO) - The sample was collected as a high concen-tration matrix from the API separator. Organic dataanalysis Indicated concentrations of toluene (61.000ppb); ethyl benzene (28,000 ppb); total xylenes (379,000ppb); 2-methyl naphthalene (65,000 ppb); fais(2ethylhexyl phthalate (86,000 ppb); additionally, 10 ten-tatively Identified unknowns with a total concentrationof 1,385,500 ppb, and 17 unknown hydrocarbons with atotal concentration of 5,482.000 ppb were detected.Other tentatively Identified priority pollutants andcontaminants detected were benzene, phenanthrene,naphthalene, 3-methyl hexane, 1.3-dimethyl cyclohexane.decane, tetradecdne, hexadecane, hepfcadecane andnonadecane with concentrations ranging from 560 ppb to590.000 ppb. (See organic analysis summary sheets).Inorganic analysis data review Indicated elevatedconcentrations of arsenic (104 ppm); beryllium (2.1ppm); chromium (2700 ppm); cobalt (22 ppm); copper (196ppm); lead (304 ppm); mercury (18.5 pp

c (at 490,000 ppb were detected- Inorganic analysis datareview indicated elevated concentrations of arsenic(1420 ppm); cadmium (4.4 ppm); chromium (362 ppm; cobalt(112 ppm), copper (1350 ppm); lead (1740 ppm); mercury(0.42 ppm); nickel (74 ppm); selenium (6.7 ppm); tin(1.9 ppm); vanadium (140 ppm) and zinc (205 ppm).

Station 14 - There was no organic or inorganic contamination detectedIn the field rinsate blank.

Station 15 - (Photo HI} " The sample was collected as a high concen-^ ^ , t r a t l o n liquid from monitor well ^S£-4. Organic data

. ' review indicated a concentration of 9200 ppb of totalxylenes; additionally, 1 (one) tentatively identifiedunknown at a concentration of 260,000 ppb and 5

-".> aromatics at a total concentration of 299,000 ppb were ,-»t detected. Inorganic analytical data review indicated ^

significant concentrations of aluminum (7,220.000 ppb);arsenic (730 ppb); beryllium (200 ppb); cadmium (110

c cAppendix A: QA/QC Results

The QA/QC for the organic data, station numbers 01, 02. 03, 04, and 14, wasdeeaed acceptable by FIT Chemists. The laboratory seemed to have somedifficulty with the soil matrix spike duplicates. The acid fraction had 8of 10 spikes out of QC limits and the base neutral fraction had 2 of 12 out.This was explained In a memo from the EPA Houston Laboratory that stated thelab simply did not spike all surrogates. This is not an automatic repeatanalysis and S.M.O. advises that the data is usable. The project officerstated that this methodology Is a pilot study and that there is no provision•for reanatysis; therefore, all data Is considered adequate. Methylene'chloride, l»l,l-trichlorethane, di-n-butyl phthalate and 4"methyl-4~penten-2-one were detected in the rinsate blank and therefore are considered labcontaminants. These compounds are flagged with a 8 on the attached datasheets.

INORGANIC WATER ANALYSIS SUMMARY Page 1 of 2CASE NUMBER: 5475 SAS 2112FSITE NAME/COIÎ T OK RefinTng Co. Oj

INORGANIC SOIL ANALYSIS SUMMARY Page 2 of 2CASE NUMBER: 5475_______SITE NAME/CODE:OK Refine Co. OK 3417

?^Reference for East/West Division is they6W longitudinal linewhich bisects Region YI,10/31/85 f

PARAMETER

Matrix typeAfufmni^nAntimonyArsenicSari urnBeryliiumCadmium' 3lC1Ui?)

(•^hronnumJfaalt

CopperIronLeadMagnesiumManganeseMercury•NTcfeer """"""PotassiumSelenium51iverSodiumThalliumTinVanadium.me

anideStation No.sampleStationLocation

^-indicates a

MFB 754

soi 1•TO;S(J(71

R

120OJ1

'15W15..^. -.„„-„.21 ' " .12,00014V70

••I52"1""

13""2,090

2437 • •"R""

02G^-ftWC^f/SK i/fP-sw^^^

5 £ I' I- UbW h: (W1C ANAl-ySiS S'JWWySite Hamg/fodg ORC Refinery OK3*3,7______________^ Case Nu'n.ber 5^75 Concentrat ion ppb Page l of A

^̂ M

^

Sampi? Station Number andLocation

ScanCompound No.m ?mr wwEflwyfl l i iMSTHYUNE CtiiLORlOEACETONECHLOROFORM2 BUTANOriETOLUENEETHYL B£N7.ENB

/TOTAL XUENC•)EW;£NE7-METHYLNAPHTHAi.ENePKENANTHRENEANTHRACENEFLUISANTHSNEPYRENERENZOtd )«nt.hrflcene,a^5SNe^Mmi-iiMS • • ""srsr^nHyLMmLfHTHAUTEFLUORENE 1 " • • • • " • —•BT-ff-BUm PHTHALATEb'WNflUN 3^8 -"l^KNUU^ "473"'UNKNOWN - ' 520'^-^.l^L yfcXANI;—————————•-552——UNKNOWN t^" ""

"I'.J'-ylHem1. CT'CfPtiKJC^fa'1 ^]——l.'.-mmm UUVriEAAMi ' 685''U.^KNUUN——————————————^,^3——U^hNUWN " • - -706"

"UN^NnUM HYilHOCAHfWJJ——————^——U^NUWM • '• 73^"'-

^"^WR——————————————f^——.^KNUyM ' " • • • - • --—J-^

•VWWW——————————————7^3——•U^tTOW—————————~S59—'UN^.WWS—————————————-^y;——

"U^MWff—————————————^7?——•WKnoror—————————J57—

WK.WW———————————————^!——" IWKIWWT-"————————933—-PJ^fflWH""-""-—————————gya——•" OWKNOWN'—————————————'Jgg——

2-CYCLO HEXSN -1-01 . . . ^/JUJiUiOyiL.^. . ^3.2-^CLOyEHEH-l-OMl; 31/

uam3ytLimiBocABBoy. 3 the isti

STftllPir^f.

F2131!SOIL11,000872008650JH52o6a

H

9 £ t tSite titfBg/CC

/ C L I T®ii0'^ 0'w'ic ANAiTSiS swyyS)le H

Sypie Station NuBHie*- wdloc^Uon

Sc*"Compound HO.tPA'SWE OT£H" "wiau "

ZICOSAM 139S

- iiaibC/uli flvnKr-iSPJa-.-...., . 1407-.nlt,UCTMV1 WISMfltrTMMMk lAAft-

llMltKrB^ NYlMtfltf-AflltOy-S. ' AA ?„ ;lN»f)i!nU^ t^^fHV-mtW 1 A ^ ?

llM(HnU«i l A 7 t

' "NXNOUM lA7f l1 UNKNOUT1 NYOSOCAR-RM1 1SH

ilMLN&wK H-fIWOTARMW 153*MKTHYL n'Rr.NE 15 S3

UMK.-iOMK MYDHOCARBOM 1S65MF.TMYL PYRME 1S66M&IHYL EKREtiE . 15?1WVJWW HYDRCARBOH 1616.UNiyiOWK l600000^'OOOOOJlOO^OOOJ•90pC?OJlOpOO-J

•ntifivS C

srA/s'

Ff3.i 1vAre.ft.

gnpOuPJS

ssavitch001137

^

^0

1

K

1l

-1>•Xfr-IdE

1"1

J

13*ii

?»•»

C-a

?x

*"-»•w

5xK=•

?7^

^>a•\

c0•-

2tf

ff't"(f

K

esnKV

•>

hi>

r

Kse.

-s-9ii

u

X

^5>-1

'1

cITf

1*1

1C:

Wn

11

-£.a

3*fipa

r

(T

0'a

KS3h.

V.a.3B-i0K

fr>

•̂

^

W

0

w«

nuItl1̂?

p

c•X

eo'0

ar

Kec^3p

•J0

••

-̂

e;1-1f^

'*'•<(K

Sf«

•flft:^aK)J

'"I '"0 C Iff] [•

c "5 •*T. vIff St

» N0 -

W Wec a;5 553-U M-1 ~'

gg

C

5i••<

n *^

1 ^C (fl

^

•z.Sza-£

00-»

c<

e(0

0M

f

a;

§

0nf^

M

<•a

"i

!3

»

0r^m

.̂

ft

a0

^ft

1X

"*0M

r>

uO

i^-̂0FN

•3C

•~t

ssavitch001139

ssavitch001140

ssavitch001141

ssavitch001142

ssavitch001143

ssavitch001144

ssavitch001145

barcode: *1006809*barcodetext: 1006809