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1/5 Creation Date : September 28, 2001
Revision Date : November 7, 2011
Safety data sheet for chemical products
1. PRODUCT AND COMPANY IDENTIFICATION
Product name: UB-205 Black [ uni-ball VISION ELITE ]
Manufacture's name : MITSUBISHI PENCIL CO.,LTD.Address : 5-23-37, HIGASHIOHI, SHINAGAWA, TOKYO, JAPANTelephone number : 03-3458-6281 Telefax number : 03-3450-0363Telex number : 2422337 MBPENC J.
Creation Date : September 28, 2001Revision Date : November 7, 2011File No. : 066133A Rev. 2.5.02.05
2. COMPOSITION/INFORMATION ON INGREDIENTS
The chemical product is a substance or a preparation : Preparation
Chemical nature: Component parts : Ink
Other parts : Other parts are excluded from 'chemical substances'.
3. HAZARDS IDENTIFICATION
Most important hazards : Not available.
Specific hazards : Information of components.
<Ethylene glycol>
<Carbon Black>
4. FIRST-AID MEASURES
Inhalation:
Skin contact:
Eye contact:
10- 30
Registered 2034733
Registered Polymer
10- 30107-21-1
CAS No.range (wt%)
TSCA EINECSNo.
Resins Registered
Concentration
Water 7732-18-5 Registered 2317912 50- 80
Chemical or generic name
Ethylene glycol
< 10
Additive Registered Registered Registered < 10
Carbon Black 1333-86-4 Registered 2156099
MAJOR HEALTH HAZARDS: respiratory tract irritation, skin irritation, eye
irritation, central nervous system depression, nerve damage, kidney damage
MAJOR HEALTH HAZARDS: suspect cancer hazard (in animals)
PHYSICAL HAZARDS: Dust/air mixtures may ignite or explode.
Not applicable.
(Due to its low vapor pressure. Inhalation is unlikely at room temperature.)
Wash skin with soap and water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry
contaminated clothing and shoes before reuse.
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
-UB-205 Black-
2/5 Creation Date : September 28, 2001
Revision Date : November 7, 2011
Ingestion:
[Ink quantity of refill(UBR-95) : about 1.6g]
5. FIRE-FIGHTING MEASURES
Fire and explosion measures : Slight fire hazard.
Exitinguishing media:Suitable : regular dry chemical, carbon dioxide, water, regular foam.
Large fires : Use regular foam or flood with fine water spray.
Fire fighting : The Products is no flammable.Use extinguishing agents appropriate for surrounding fire.
Avoid inhalation of material or combustion by-products.
Stay upwind and keep out of low areas.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Not available.
Environmental precautions : Do not wash away into shower or water way.
Methods for cleaning up : Wipe off by dry cloth and wash with water.
: In accordance with national, state and local regulations.
7. HANDLING AND STORAGE
Store and handle in accordance with all current regulations and standards.Keep separated from incompatible substances.
Handling:Technical measures : Don't swallow ink.
: Recap after use.
: Don't shake.
: Keep out of the reach of children.
: Avoid contact with skin and eyes.
Precautions : Not available.
Safe handling advice : Not available.
Storage:Technical measures : Keep away from oxidizing materials, ignition sources and
high temperature.
Storage condition : Avoid direct sunlight.
: Do not leave the products in high temperature space.
: Recommended temperature: 0-30 C.
Incompatible products : (Information of components.)
Ethylene glycol
Resin
Carbon Black
Packaging materials : Not applicable.
If swallowed, seek medical advice, and show the MSDS to the physician then.
oxidizing materials, bases, acids, reducing agents, metals
strong acids, alkalies, oxidizers, oxidizing materials,
reducing agents
oxidizing materials, halogens
-UB-205 Black-
3/5 Creation Date : September 28, 2001
Revision Date : November 7, 2011
8. EXPOSURE CONTROL / PERSONAL PROTECTION
Engineering measures : Not required.
Control parameters (Information of components.)
OSHAACGIH
EC
Personal protective equipment : Not required.
9. PHYSICAL AND CHEMICAL PROPERTIES
[ ] : Information of components.
Physical state and form : Low viscous liquid.
Colour : Black.
Odour : None odour.
pH : about 7.5
Boiling point : Not available. [Water/ 100 C]
Melting point : <-10 C
Flash point : Not applicable. [Ethylene glycol/ 111 C(CC)]
Autoignition temperature : Not applicable. [Ethylene glycol/ 398 C]
Explosion limits : Not applicable.
[ Lower flammable limit / 3.2% , Upper flammable limit / 15.3% <Ethylene glycol> ]
Density : about 1.1 / 25 C
Vapour density (air=1) : Not available. [Ethylene glycol/ 2.1]
Solubulity in water : Soluble.
Evaporation rate : Not available.
Volatile : 69-72%
10. STABILITY AND REACTIVITY
Stability : Stability.
Hazardous reactions : Will not occur.
Conditions to avoid : Avoid heat, flames, sparks and other sources of ignition.
Avoid contact with incompatible materials.
Materials to avoid : (Information of components.)
Ethylene glycol
Resin
Carbon Black
Hazardous decomposition products : (Information of components.)
common decomposition products
Resin
Additive
100mg/m3 ceiling (particulate)(aerosol) Ethylene glycol
3.5mg/m3 Carbon Black
52mg/m3(20ppm) TWA,
104mg/m3(40ppm) STEL(skin)Ethylene glycol
3.5mg/m3(total dust) TWA Carbon Black15mg/m3 (Total dust) Additive
3.5mg/m3 Carbon Black
oxidizing materials, bases, acids, reducing agents, metals
strong acids, alkalies, oxidizers, oxidizing materials,
reducing agents
oxides of carbon, water
oxidizing materials, halogens
oxides of nitrogen.
miscellaneous decomposition products.
-UB-205 Black-
4/5 Creation Date : September 28, 2001
Revision Date : November 7, 2011
11.TOXICOLOGICAL INFORMATION
(Information of components)
Acute toxicity
Ingestion LD50
Inhalation LC50Skin LD50
Local effects
Chronic toxicity and long term toxicity
Signs and Symptos of overexposure and aggravated by exposure
Inhalation
Skin contact
Eye contact
Ingestion
Specific effects
12. ECOLOGICAL INFORMATION
Not available.
13. DISPOSAL CONSIDERATIONS
Waste from residues : Disposal in accordance with all current regulations and standards.
Contaminated packaging : Not applicable.
14. TRANSPORT INFORMATION
HS Code : 960810
1650mg/kg-Cat,
4700mg/kg-Rat
Ethylene glycol
1040mg/kg-Rabbit,
>40000mg/kg-Mouse
Resin
>8000mg/kg-Rat Carbon Black
9530uL/kg-Rabbit Ethylene glycol
Not available.
Irritant;inhalation, skin Carbon Black
Irritant;inhalation, skin, eye Ethylene glycol
The substance may have effects on the central nervous
system, resulting in abnormal eye movements (nystagmus).Ethylene glycol
Respiratory disorders. Carbon Black
irritation Carbon Black / Additive
irritation,cough Ethylene glycol
irritation,pneumonitis Resin
irritation Carbon Black / Additive
irritation,dry Ethylene glycol
irritation,sensitization Resin
mechanical irritation,
discoloration of lids
Carbon Black
irritation,redness Ethylene glycol
irritation Resin / Additive
nausea,vomiting Ethylene glycol
diarrhea,pneumonitis Resin
IARC Group 2B Carbon Black
IARC Group 3 Resin
-UB-205 Black-
5/5 Creation Date : September 28, 2001
Revision Date : November 7, 2011
15. REGULATORY INFORMATION
Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Ethylene glycol / Carbon Black
EU labeling25%<=Xn;R22 : Ethylene glycol
R22 : Harmful if swallowed.
CANADA Hazardous Products Act - Ingredient Disclosure List1%over : Ethylene glycol / Carbon Black
Hazard and safety informationProducts are manufactured in accordance with ISO 8124-3 " Safety of Toys - Part 3"
16. OTHER INFORMATION
This sheet completes the technical sheet of use but it doesn't replace it.
The information contained in this sheet are based knowledge of the products
at the data : (November 7, 2011). They are given quite sincerely.
Moreover the attention of the users is drawn on the risks possibly taken,
when a product is used for other utilization than these which it is intended.
-UB-205 Black-
1/5 Creation Date : September 28, 2001
Revision Date : November 7, 2011
Safety data sheet for chemical products
1. PRODUCT AND COMPANY IDENTIFICATION
Product name: UB-205 Blue [ uni-ball VISION ELITE ]
Manufacture's name : MITSUBISHI PENCIL CO.,LTD.Address : 5-23-37, HIGASHIOHI, SHINAGAWA, TOKYO, JAPANTelephone number : 03-3458-6281 Telefax number : 03-3450-0363Telex number : 2422337 MBPENC J.
Creation Date : September 28, 2001Revision Date : November 7, 2011File No. : 066134A Rev. 2.5.03.05
2. COMPOSITION/INFORMATION ON INGREDIENTS
The chemical product is a substance or a preparation : Preparation
Chemical nature: Component parts : Ink
Other parts : Other parts are excluded from 'chemical substances'.
3. HAZARDS IDENTIFICATION
Most important hazards : Not available.
Specific hazards : Information of components.
<Ethylene glycol>
4. FIRST-AID MEASURES
Inhalation:
Skin contact:
Eye contact:
Ingestion:
[Ink quantity of refill(UBR-95) : about 1.6g]
Ethylene glycol 107-21-1 Registered 2034733
range (wt%)TSCA EINECSNo.
< 10
2317912 50- 80
ConcentrationChemical or generic name
Resins Registered Registered
CAS No.
Coloring agent Registered
Water 7732-18-5 Registered
Polymer
Registered Registered
10- 30
< 10
< 10Additive Registered Registered Registered
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
If swallowed, seek medical advice, and show the MSDS to the physician then.
MAJOR HEALTH HAZARDS: respiratory tract irritation, skin irritation, eye
irritation, central nervous system depression, nerve damage, kidney damage
Not applicable.
(Due to its low vapor pressure. Inhalation is unlikely at room temperature.)
Wash skin with soap and water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry
contaminated clothing and shoes before reuse.
-UB-205 Blue-
2/5 Creation Date : September 28, 2001
Revision Date : November 7, 2011
5. FIRE-FIGHTING MEASURES
Fire and explosion measures : Slight fire hazard.
Exitinguishing media:Suitable : regular dry chemical, carbon dioxide, water, regular foam.
Large fires : Use regular foam or flood with fine water spray.
Fire fighting : The Products is no flammable.Use extinguishing agents appropriate for surrounding fire.
Avoid inhalation of material or combustion by-products.
Stay upwind and keep out of low areas.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Not available.
Environmental precautions : Do not wash away into shower or water way.
Methods for cleaning up : Wipe off by dry cloth and wash with water.
: In accordance with national, state and local regulations.
7. HANDLING AND STORAGE
Store and handle in accordance with all current regulations and standards.Keep separated from incompatible substances.
Handling:Technical measures : Don't swallow ink.
: Recap after use.
: Don't shake.
: Keep out of the reach of children.
: Avoid contact with skin and eyes.
Precautions : Not available.
Safe handling advice : Not available.
Storage:Technical measures : Keep away from oxidizing materials, ignition sources and
high temperature.
Storage condition : Avoid direct sunlight.
: Do not leave the products in high temperature space.
: Recommended temperature: 0-30 C.
Incompatible products : (Information of components.)
Ethylene glycol
Coloring agent
Resin
Packaging materials : Not applicable.
oxidizing materials, bases, acids, reducing agents, metals
oxidizing materials, reducing agents
oxidizing materials
-UB-205 Blue-
3/5 Creation Date : September 28, 2001
Revision Date : November 7, 2011
8. EXPOSURE CONTROL / PERSONAL PROTECTION
Engineering measures : Not required.
Control parameters (Information of components.)
OSHA
ACGIH
EC
Personal protective equipment : Not required.
9. PHYSICAL AND CHEMICAL PROPERTIES
[ ] : Information of components.
Physical state and form : Low viscous liquid.
Colour : Blue.
Odour : None odour.
pH : about 7.5
Boiling point : Not available. [Water/ 100 C]
Melting point : <-10 C
Flash point : Not applicable. [Ethylene glycol/ 111 C(CC)]
Autoignition temperature : Not applicable. [Ethylene glycol/ 398 C]
Explosion limits : Not applicable.
[ Lower flammable limit / 3.2% , Upper flammable limit / 15.3% <Ethylene glycol> ]
Density : about 1.1 / 25 C
Vapour density (air=1) : Not available. [Ethylene glycol/ 2.1]
Solubulity in water : Soluble.
Evaporation rate : Not available.
Volatile : 83-86%
10. STABILITY AND REACTIVITY
Stability : Stability.
Hazardous reactions : Will not occur.
Conditions to avoid : Avoid heat, flames, sparks and other sources of ignition.
Avoid contact with incompatible materials.
Materials to avoid : (Information of components.)
Ethylene glycol
Coloring agent
Resin
Hazardous decomposition products : (Information of components.)
common decomposition products
Coloring agent / Resin
Additive
oxidizing materials, bases, acids, reducing agents, metals
oxides of nitrogen.
miscellaneous decomposition products.
oxidizing materials, reducing agents
oxides of carbon, water
oxidizing materials
15mg/m3 (Total dust) Additive52mg/m3(20ppm) TWA,
104mg/m3(40ppm) STEL(skin)Ethylene glycol
100mg/m3 ceiling (particulate)(aerosol) Ethylene glycol10mg/m3(Nuisance particulate) Coloring agent
5mg/m3(Respirable flaction),
15mg/m3(Total dust) [Nuisance Dust]Coloring agent
-UB-205 Blue-
4/5 Creation Date : September 28, 2001
Revision Date : November 7, 2011
11.TOXICOLOGICAL INFORMATION
(Information of components)
Acute toxicity
Ingestion LD50
Inhalation LC50Skin LD50
Local effects
Chronic toxicity and long term toxicity
Signs and Symptos of overexposure and aggravated by exposure
Inhalation
Skin contact
Eye contact
Ingestion
Specific effects
12. ECOLOGICAL INFORMATION
Not available.
13. DISPOSAL CONSIDERATIONS
Waste from residues : Disposal in accordance with all current regulations and standards.
Contaminated packaging : Not applicable.
14. TRANSPORT INFORMATION
HS Code : 960810
IARC Group 3 Resin
diarrhea,pneumonitis Resin
gastric disturbances Coloring agent
irritation Coloring agent / Resin / Additive
nausea,vomiting Ethylene glycol
irritation Additive
irritation,redness Ethylene glycol
irritation,dry Ethylene glycol
irritation,sensitization Resin
irritation Coloring agent / Additive
irritation,pneumonitis Resin
The substance may have effects on the central nervous
system, resulting in abnormal eye movements (nystagmus).Ethylene glycol
irritation,cough Ethylene glycol
9530uL/kg-Rabbit Ethylene glycol
Irritant;inhalation, skin, eye Ethylene glycol
1040mg/kg-Rabbit,
>40000mg/kg-Mouse
Resin
Not available.
1650mg/kg-Cat,
4700mg/kg-Rat
Ethylene glycol
>=5000mg/kg-Rat Coloring agent
-UB-205 Blue-
5/5 Creation Date : September 28, 2001
Revision Date : November 7, 2011
15. REGULATORY INFORMATION
Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Ethylene glycol
EU labeling25%<=Xn;R22 : Ethylene glycol
R22 : Harmful if swallowed.
CANADA Hazardous Products Act - Ingredient Disclosure List1%over : Ethylene glycol
Hazard and safety informationProducts are manufactured in accordance with ISO 8124-3 " Safety of Toys - Part 3"
16. OTHER INFORMATION
This sheet completes the technical sheet of use but it doesn't replace it.
The information contained in this sheet are based knowledge of the products
at the data : (November 7, 2011). They are given quite sincerely.
Moreover the attention of the users is drawn on the risks possibly taken,
when a product is used for other utilization than these which it is intended.
-UB-205 Blue-
1/5 Creation Date : September 28, 2001
Revision Date : November 7, 2011
Safety data sheet for chemical products
1. PRODUCT AND COMPANY IDENTIFICATION
Product name: UB-205 Red [ uni-ball VISION ELITE ]
Manufacture's name : MITSUBISHI PENCIL CO.,LTD.Address : 5-23-37, HIGASHIOHI, SHINAGAWA, TOKYO, JAPANTelephone number : 03-3458-6281 Telefax number : 03-3450-0363Telex number : 2422337 MBPENC J.
Creation Date : September 28, 2001Revision Date : November 7, 2011File No. : 066135A Rev. 2.5.02.05
2. COMPOSITION/INFORMATION ON INGREDIENTS
The chemical product is a substance or a preparation : Preparation
Chemical nature: Component parts : Ink
Other parts : Other parts are excluded from 'chemical substances'.
3. HAZARDS IDENTIFICATION
Most important hazards : Not available.
Specific hazards : Information of components.
<Ethylene glycol>
4. FIRST-AID MEASURES
Inhalation:
Skin contact:
Eye contact:
Ingestion:
[Ink quantity of refill(UBR-95) : about 1.6g]
range (wt%)TSCA EINECSNo.
< 10
Registered 2034733
Concentration
Polymer
Registered Registered
10- 30
< 10
Chemical or generic name
Resins Registered Registered
Ethylene glycol 107-21-1
CAS No.
Coloring agent Registered
Water 7732-18-5 Registered 2317912 50- 80
< 10Additive Registered Registered Registered
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
If swallowed, seek medical advice, and show the MSDS to the physician then.
MAJOR HEALTH HAZARDS: respiratory tract irritation, skin irritation, eye
irritation, central nervous system depression, nerve damage, kidney damage
Not applicable.
(Due to its low vapor pressure. Inhalation is unlikely at room temperature.)
Wash skin with soap and water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry
contaminated clothing and shoes before reuse.
-UB-205 Red-
2/5 Creation Date : September 28, 2001
Revision Date : November 7, 2011
5. FIRE-FIGHTING MEASURES
Fire and explosion measures : Slight fire hazard.
Exitinguishing media:Suitable : regular dry chemical, carbon dioxide, water, regular foam.
Large fires : Use regular foam or flood with fine water spray.
Fire fighting : The Products is no flammable.Use extinguishing agents appropriate for surrounding fire.
Avoid inhalation of material or combustion by-products.
Stay upwind and keep out of low areas.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Not available.
Environmental precautions : Do not wash away into shower or water way.
Methods for cleaning up : Wipe off by dry cloth and wash with water.
: In accordance with national, state and local regulations.
7. HANDLING AND STORAGE
Store and handle in accordance with all current regulations and standards.Keep separated from incompatible substances.
Handling:Technical measures : Don't swallow ink.
: Recap after use.
: Don't shake.
: Keep out of the reach of children.
: Avoid contact with skin and eyes.
Precautions : Not available.
Safe handling advice : Not available.
Storage:Technical measures : Keep away from oxidizing materials, ignition sources and
high temperature.
Storage condition : Avoid direct sunlight.
: Do not leave the products in high temperature space.
: Recommended temperature: 0-30 C.
Incompatible products : (Information of components.)
Ethylene glycol
Coloring agent
Resin
Packaging materials : Not applicable.
oxidizing materials, bases, acids, reducing agents, metals
oxidizing materials, reducing agents
oxidizing materials
-UB-205 Red-
3/5 Creation Date : September 28, 2001
Revision Date : November 7, 2011
8. EXPOSURE CONTROL / PERSONAL PROTECTION
Engineering measures : Not required.
Control parameters (Information of components.)
OSHAACGIH
EC
JAIH
Personal protective equipment : Not required.
9. PHYSICAL AND CHEMICAL PROPERTIES
[ ] : Information of components.
Physical state and form : Low viscous liquid.
Colour : Red.
Odour : None odour.
pH : about 7.5
Boiling point : Not available. [Water/ 100 C]
Melting point : <-10 C
Flash point : Not applicable. [Ethylene glycol/ 111 C(CC)]
Autoignition temperature : Not applicable. [Ethylene glycol/ 398 C]
Explosion limits : Not applicable.
[ Lower flammable limit / 3.2% , Upper flammable limit / 15.3% <Ethylene glycol> ]
Density : about 1.1 / 25 C
Vapour density (air=1) : Not available. [Ethylene glycol/ 2.1]
Solubulity in water : Soluble.
Evaporation rate : Not available.
Volatile : 83-86%
10. STABILITY AND REACTIVITY
Stability : Stability.
Hazardous reactions : Will not occur.
Conditions to avoid : Avoid heat, flames, sparks and other sources of ignition.
Avoid contact with incompatible materials.
Materials to avoid : (Information of components.)
Ethylene glycol
Coloring agent
Resin
Hazardous decomposition products : (Information of components.)
common decomposition products
Coloring agent / Resin
Additive
oxidizing materials, bases, acids, reducing agents,
metals
oxides of nitrogen.
miscellaneous decomposition products.
oxidizing materials, reducing agents
oxides of carbon, water
oxidizing materials
52mg/m3(20ppm) TWA,
104mg/m3(40ppm) STEL(skin)Ethylene glycol
2mg/m3(Respirable fraction),
8mg/m3(Total dust)Coloring agent
100mg/m3 ceiling (particulate)(aerosol) Ethylene glycol15mg/m3 (Total dust) Additive
Not available.
-UB-205 Red-
4/5 Creation Date : September 28, 2001
Revision Date : November 7, 2011
11.TOXICOLOGICAL INFORMATION
(Information of components)
Acute toxicity
Ingestion LD50
Inhalation LC50Skin LD50
Local effects
Chronic toxicity and long term toxicity
Signs and Symptos of overexposure and aggravated by exposure
Inhalation
Skin contact
Eye contact
Ingestion
Specific effects
12. ECOLOGICAL INFORMATION
Not available.
13. DISPOSAL CONSIDERATIONS
Waste from residues : Disposal in accordance with all current regulations and standards.
Contaminated packaging : Not applicable.
14. TRANSPORT INFORMATION
HS Code : 960810
IARC Group 3 Resin
nausea,vomiting Ethylene glycol / Coloring agent
diarrhea,pneumonitis Resin
irritation,redness Ethylene glycol
irritation Resin / Additive
irritation,sensitization Resin
irritation Additive
irritation,dry Ethylene glycol
redness,swelling Coloring agent
irritation Coloring agent / Additive
irritation,pneumonitis Resin
The substance may have effects on the central nervous
system, resulting in abnormal eye movements (nystagmus).Ethylene glycol
irritation,cough Ethylene glycol
9530uL/kg-Rabbit Ethylene glycol
Irritant;inhalation, skin, eye Ethylene glycol
1040mg/kg-Rabbit,
>40000mg/kg-Mouse
Resin
Not available.
1650mg/kg-Cat,
4700mg/kg-Rat
Ethylene glycol
>=5000mg/kg-Rat Coloring agent
-UB-205 Red-
5/5 Creation Date : September 28, 2001
Revision Date : November 7, 2011
15. REGULATORY INFORMATION
Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Ethylene glycol
EU labeling25%<=Xn;R22 : Ethylene glycol
R22 : Harmful if swallowed.
CANADA Hazardous Products Act - Ingredient Disclosure List1%over : Ethylene glycol
Hazard and safety informationProducts are manufactured in accordance with ISO 8124-3 " Safety of Toys - Part 3"
16. OTHER INFORMATION
This sheet completes the technical sheet of use but it doesn't replace it.
The information contained in this sheet are based knowledge of the products
at the data : (November 7, 2011). They are given quite sincerely.
Moreover the attention of the users is drawn on the risks possibly taken,
when a product is used for other utilization than these which it is intended.
-UB-205 Red-
1/5 Creation Date : September 28, 2001
Revision Date : November 7, 2011
Safety data sheet for chemical products
1. PRODUCT AND COMPANY IDENTIFICATION
Product name: UB-205 Blue-black [ uni-ball VISION ELITE ]
Manufacture's name : MITSUBISHI PENCIL CO.,LTD.Address : 5-23-37, HIGASHIOHI, SHINAGAWA, TOKYO, JAPANTelephone number : 03-3458-6281 Telefax number : 03-3450-0363Telex number : 2422337 MBPENC J.
Creation Date : September 28, 2001Revision Date : November 7, 2011File No. : 066136A Rev. 2.5.02.05
2. COMPOSITION/INFORMATION ON INGREDIENTS
The chemical product is a substance or a preparation : Preparation
Chemical nature: Component parts : Ink
Other parts : Other parts are excluded from 'chemical substances'.
3. HAZARDS IDENTIFICATION
Most important hazards : Not available.
Specific hazards : Not available.
4. FIRST-AID MEASURES
Inhalation:
Skin contact:
Eye contact:
Ingestion:
[Ink quantity of refill(UBR-95) : about 1.6g]
CAS No.Concentration
Chemical or generic namerange (wt%)
TSCA EINECSNo.
If swallowed, seek medical advice, and show the MSDS to the physician then.
Not applicable.
(Due to its low vapor pressure. Inhalation is unlikely at room temperature.)
Wash skin with soap and water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry
contaminated clothing and shoes before reuse.
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
< 10
Triethanolamine 102-71-6 Registered 2030498 < 10
Additive Registered Registered Polymer
< 10Resins Registered Registered Polymer
< 10Coloring agents Registered Registered Registered
50- 80
Glycerine 56-81-5 Registered 2002895 10- 30
Water 7732-18-5 Registered 2317912
-UB-205 Blue-black-
2/5 Creation Date : September 28, 2001
Revision Date : November 7, 2011
5. FIRE-FIGHTING MEASURES
Fire and explosion measures : Slight fire hazard.
Exitinguishing media:Suitable : regular dry chemical, carbon dioxide, water, regular foam.
Large fires : Use regular foam or flood with fine water spray.
Fire fighting : The Products is no flammable.Use extinguishing agents appropriate for surrounding fire.
Avoid inhalation of material or combustion by-products.
Stay upwind and keep out of low areas.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Not available.
Environmental precautions : Do not wash away into shower or water way.
Methods for cleaning up : Wipe off by dry cloth and wash with water.
: In accordance with national, state and local regulations.
7. HANDLING AND STORAGE
Store and handle in accordance with all current regulations and standards.Keep separated from incompatible substances.
Handling:Technical measures : Don't swallow ink.
: Recap after use.
: Don't shake.
: Keep out of the reach of children.
: Avoid contact with skin and eyes.
Precautions : Not available.
Safe handling advice : Not available.
Storage:Technical measures : Keep away from oxidizing materials, ignition sources and
high temperature.
Storage condition : Avoid direct sunlight.
: Do not leave the products in high temperature space.
: Recommended temperature: 0-30 C.
Incompatible products : (Information of components.)
Glycerine
Coloring agent
Resin
Additive
Triethanolamine
Packaging materials : Not applicable.
acids, bases, oxidizing materials, metal oxides, peroxides,
reducing agents
acids, metals, oxidizing materials
oxidizing materials, reducing agents
strong oxidizers
oxidizing materials
-UB-205 Blue-black-
3/5 Creation Date : September 28, 2001
Revision Date : November 7, 2011
8. EXPOSURE CONTROL / PERSONAL PROTECTION
Engineering measures : Not required.
Control parameters (Information of components.)
OSHA
ACGIH
EC
Personal protective equipment : Not required.
9. PHYSICAL AND CHEMICAL PROPERTIES
[ ] : Information of components.
Physical state and form : Low viscous liquid.
Colour : Blue-black.
Odour : None odour.
pH : about 8.6
Boiling point : Not available. [Water/ 100 C]
Melting point : <-10 C
Flash point : Not applicable. [Glycerine/ 160 C]
Autoignition temperature : Not applicable. [Triethanolamine/ 315.5 C]
Explosion limits : Not applicable. [ Lower flammable limit / 0.9% <Glycerine>]
Density : about 1.05 / 25 C
Vapour density (air=1) : Not available. [Glycerine/ 3.1]
Solubulity in water : Soluble.
Evaporation rate : Not available.
Volatile : 81-84%
10. STABILITY AND REACTIVITY
Stability : Stability.
Hazardous reactions : Will not occur.
Conditions to avoid : Avoid heat, flames, sparks and other sources of ignition.
Avoid contact with incompatible materials.
Materials to avoid : (Information of components.)
Glycerine
Coloring agent
Resin
Additive
Triethanolamine
Hazardous decomposition products : (Information of components.)
common decomposition products
Glycerine / Additive
Coloring agent
Resin / Triethanolamine
acids, bases, oxidizing materials, metal oxides,
peroxides, reducing agents
oxides of nitrogen, sulfur.
oxides of nitrogen.
oxides of carbon, water
corrosive acrolein.
strong oxidizers
acids, metals, oxidizing materials
oxidizing materials
oxidizing materials, reducing agents
Not available.
10mg/m3 (Nuisance particulate) Coloring agent5mg/m3 TWA Triethanolamine
5mg/m3(Respirable flaction),
15mg/m3(Total dust) [Nuisance Dust]Coloring agent
10mg/m3 TWA Glycerine
5mg/m3 TWA(Respirable dust fraction),
15mg/m3 TWA (Total dust)Glycerine
-UB-205 Blue-black-
4/5 Creation Date : September 28, 2001
Revision Date : November 7, 2011
11.TOXICOLOGICAL INFORMATION
(Information of components)
Acute toxicity
Ingestion LD50
Inhalation LC50Skin LD50
Local effects
Chronic toxicity and long term toxicity
Signs and Symptos of overexposure and aggravated by exposure
Inhalation
Skin contact
Eye contact
Ingestion
Specific effects
12. ECOLOGICAL INFORMATION
Not available.
13. DISPOSAL CONSIDERATIONS
Waste from residues : Disposal in accordance with all current regulations and standards.
Contaminated packaging : Not applicable.
14. TRANSPORT INFORMATION
HS Code : 960810
IARC Group 3 Resin / Triethanolamine
burns,gastrointestinal irritation Triethanolamine
gastric disturbances Coloring agent
diarrhea,pneumonitis Resin
irritation,corneal swelling Triethanolamine
nausea,vomiting Glycerine
tearing,stinging Glycerine
irritation Coloring agent / Resin
irritation,sensitization Resin
sensitization Additive
irritation,redness Glycerine / Triethanolamine
irritation Coloring agent
irritation,pneumonitis Resin
sore throat,difficulty breathing Triethanolamine
irritation,difficulty breathing Glycerine
irritation Coloring agent
Irritant;skin, eye Triethanolamine
Repeated or prolonged contact may cause skin sensitization. Triethanolamine
>16mL/kg-Rat Triethanolamine
dehydration Additive
>570mg/m3-1H-Rat Glycerine
>10000mg/kg-Rabbit Glycerine
1040mg/kg-Rabbit,
>40000mg/kg-Mouse
Resin
2200mg/kg-Rabbit,
5846mg/kg-Mouse
Triethanolamine
4090mg/kg-Mouse Glycerine
>5000mg/kg-Rat Coloring agent
-UB-205 Blue-black-
5/5 Creation Date : September 28, 2001
Revision Date : November 7, 2011
15. REGULATORY INFORMATION
Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Glycerine / Triethanolamine
EU labeling : Not restricted.
CANADA Hazardous Products Act - Ingredient Disclosure List1%over : Triethanolamine
Hazard and safety informationProducts are manufactured in accordance with ISO 8124-3 " Safety of Toys - Part 3"
16. OTHER INFORMATION
This sheet completes the technical sheet of use but it doesn't replace it.
The information contained in this sheet are based knowledge of the products
at the data : (November 7, 2011). They are given quite sincerely.
Moreover the attention of the users is drawn on the risks possibly taken,
when a product is used for other utilization than these which it is intended.
-UB-205 Blue-black-
1/5 Creation Date : March 30, 2004
Revision Date : November 7, 2011
Safety data sheet for chemical products
1. PRODUCT AND COMPANY IDENTIFICATION
Product name: UB-205 Violet [ uni-ball VISION ELITE ]
Manufacture's name : MITSUBISHI PENCIL CO.,LTD.Address : 5-23-37, HIGASHIOHI, SHINAGAWA, TOKYO, JAPANTelephone number : 03-3458-6281 Telefax number : 03-3450-0363Telex number : 2422337 MBPENC J.
Creation Date : March 30, 2004Revision Date : November 7, 2011File No. : 066172A Rev. 2.5.04.03
2. COMPOSITION/INFORMATION ON INGREDIENTS
The chemical product is a substance or a preparation : Preparation
Chemical nature: Component parts : Ink
Other parts : Other parts are excluded from 'chemical substances'.
3. HAZARDS IDENTIFICATION
Most important hazards : Not available.
Specific hazards : Not available.
4. FIRST-AID MEASURES
Inhalation:
Skin contact:
Eye contact:
Ingestion:
[Ink quantity of product : about 1.6g]
Water 7732-18-5 Registered 2317912 50- 80
Glycerine 56-81-5 Registered 2002895 10- 30
Coloring agent Registered Registered Registered < 10
< 10Resins Registered Registered Registered
Polymer
Not applicable.
(Due to its low vapor pressure. Inhalation is unlikely at room temperature.)
Wash skin with soap and water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry
contaminated clothing and shoes before reuse.
< 101,2-Propanediol 57-55-6 Registered 2003380
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
If swallowed, seek medical advice, and show the MSDS to the physician then.
CAS No.Concentration
Chemical or generic namerange (wt%)
TSCA EINECSNo.
-UB-205 Violet-
2/5 Creation Date : March 30, 2004
Revision Date : November 7, 2011
5. FIRE-FIGHTING MEASURES
Fire and explosion measures : Slight fire hazard.
Exitinguishing media:Suitable : regular dry chemical, carbon dioxide, water, regular foam.
Large fires : Use regular foam or flood with fine water spray.
Fire fighting : The Products is no flammable.Use extinguishing agents appropriate for surrounding fire.
Avoid inhalation of material or combustion by-products.
Stay upwind and keep out of low areas.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Not available.
Environmental precautions : Do not wash away into shower or water way.
Methods for cleaning up : Wipe off by dry cloth and wash with water.
: In accordance with national, state and local regulations.
7. HANDLING AND STORAGE
Store and handle in accordance with all current regulations and standards.Keep separated from incompatible substances.
Handling:Technical measures : Don't swallow ink.
: Recap after use.
: Don't shake.
: Keep out of the reach of children.
: Avoid contact with skin and eyes.
Precautions : Not available.
Safe handling advice : Not available.
Storage:Technical measures : Keep away from oxidizing materials, ignition sources and
high temperature.
Storage condition : Avoid direct sunlight.
: Do not leave the products in high temperature space.
: Recommended temperature: 0-30 C.
Incompatible products : (Information of components.)
Glycerine
Coloring agent
Resin
1,2-Propanediol
Packaging materials : Not applicable.
oxidizing materials
acids, bases, oxidizing materials, metal oxides, peroxides,
reducing agents
oxidizing materials, reducing agents
acids, bases, combustible materials, halo carbons, metals,
metal salts, oxidizing materials, reducing agents
-UB-205 Violet-
3/5 Creation Date : March 30, 2004
Revision Date : November 7, 2011
8. EXPOSURE CONTROL / PERSONAL PROTECTION
Engineering measures : Not required.
Control parameters (Information of components.)
OSHA
ACGIHECJAIH
UK
Personal protective equipment : Not required.
9. PHYSICAL AND CHEMICAL PROPERTIES
[ ] : Information of components.
Physical state and form : Low viscous liquid.
Colour : Violet.
Odour : None odour.
pH : about 8.7
Boiling point : Not available. [Water/ 100 C]
Melting point : <-10 C
Flash point : Not applicable. [1,2-Propanediol/ 99 C(CC)]
Autoignition temperature : Not applicable. [Glycerine/ 370 C]
Explosion limits : Not applicable.
[ Lower flammable limit / 2.6% , Upper flammable limit / 12.5% <1,2-Propanediol> ]
Density : about 1.05-1.10 / 25 C
Vapour density (air=1) : Not available. [1,2-Propanediol/ 2.60-2.62]
Solubulity in water : Soluble.
Evaporation rate : Not available.
Volatile : 88-91%
10. STABILITY AND REACTIVITY
Stability : Stability.
Hazardous reactions : Will not occur.
Conditions to avoid : Avoid heat, flames, sparks and other sources of ignition.
Avoid contact with incompatible materials.
Materials to avoid : (Information of components.)
Glycerine
Coloring agent
Resin
1,2-Propanediol
Hazardous decomposition products : (Information of components.)
common decomposition products
Glycerine
Coloring agent
Resin
5mg/m3 TWA(Respirable dust fraction),
15mg/m3 TWA (Total dust)Glycerine
10mg/m3 TWA GlycerineNot available.
oxidizing materials, reducing agents
oxidizing materials
2mg/m3(Respirable fraction),
8mg/m3(Total dust)Coloring agent
150ppm(474mg/m3) TWA(total(vapor and
pariclulates)), 10mg/m3 TWA(particlulates)1,2-Propanediol
miscellaneous decomposition products.
oxides of nitrogen.
oxides of carbon, water
corrosive acrolein.
acids, bases, oxidizing materials, metal oxides,
peroxides, reducing agents
acids, bases, combustible materials, halo carbons,
metals, metal salts, oxidizing materials, reducing
-UB-205 Violet-
4/5 Creation Date : March 30, 2004
Revision Date : November 7, 2011
11.TOXICOLOGICAL INFORMATION
(Information of components)
Acute toxicity
Ingestion LD50
Inhalation LC50Skin LD50
Local effects
Chronic toxicity and long term toxicity
Signs and Symptos of overexposure and aggravated by exposure
Inhalation
Skin contact
Eye contact
Ingestion
Specific effects
12. ECOLOGICAL INFORMATION
Not available.
13. DISPOSAL CONSIDERATIONS
Waste from residues : Disposal in accordance with all current regulations and standards.
Contaminated packaging : Not applicable.
14. TRANSPORT INFORMATION
HS Code : 960810
IARC Group 3 Resin
4090mg/kg-Mouse Glycerine
>=5000mg/kg-Rat Coloring agent
1040mg/kg-Rabbit,
>40000mg/kg-Mouse
Resin
20000mg/kg-Rat 1,2-Propanediol
>570mg/m3-1H-Rat Glycerine
>10000mg/kg-Rabbit Glycerine
20800mg/kg-Rabbit 1,2-Propanediol
Not available.
Repeated or prolonged contact may cause skin sensitization. 1,2-Propanediol
irritation,difficulty breathing Glycerine
irritation Coloring agent
irritation,pneumonitis Resin
nausea,headache 1,2-Propanediol
irritation,redness Glycerine
Glycerine
irritation Resin
irritation,sensitization Resin
irritation,allergic reaction 1,2-Propanediol
Resin
irritation,pain 1,2-Propanediol
tearing,stinging
allergic reaction,vomiting 1,2-Propanediol
nausea,vomiting Glycerine
diarrhea,pneumonitis
-UB-205 Violet-
5/5 Creation Date : March 30, 2004
Revision Date : November 7, 2011
15. REGULATORY INFORMATION
Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Glycerine
EU labeling : Not restricted.
CANADA Hazardous Products Act - Ingredient Disclosure List1%over : 1,2-Propanediol
Hazard and safety informationProducts are manufactured in accordance with ISO 8124-3 " Safety of Toys - Part 3"
16. OTHER INFORMATION
This sheet completes the technical sheet of use but it doesn't replace it.
The information contained in this sheet are based knowledge of the products
at the data : (November 7, 2011). They are given quite sincerely.
Moreover the attention of the users is drawn on the risks possibly taken,
when a product is used for other utilization than these which it is intended.
-UB-205 Violet-
1/5 Creation Date : March 30, 2004
Revision Date : November 7, 2011
Safety data sheet for chemical products
1. PRODUCT AND COMPANY IDENTIFICATION
Product name: UB-205 Green [ uni-ball VISION ELITE ]
Manufacture's name : MITSUBISHI PENCIL CO.,LTD.Address : 5-23-37, HIGASHIOHI, SHINAGAWA, TOKYO, JAPANTelephone number : 03-3458-6281 Telefax number : 03-3450-0363Telex number : 2422337 MBPENC J.
Creation Date : March 30, 2004Revision Date : November 7, 2011File No. : 066173A Rev. 2.5.04.03
2. COMPOSITION/INFORMATION ON INGREDIENTS
The chemical product is a substance or a preparation : Preparation
Chemical nature: Component parts : Ink
Other parts : Other parts are excluded from 'chemical substances'.
3. HAZARDS IDENTIFICATION
Most important hazards : Not available.
Specific hazards : Not available.
4. FIRST-AID MEASURES
Inhalation:
Skin contact:
Eye contact:
Ingestion:
[Ink quantity of product : about 1.6g]
102-71-6 Registered 2030498
50- 80
10- 30
< 10
< 10
Glycerine 56-81-5 Registered 2002895
Water 7732-18-5 Registered 2317912
Coloring agent Registered Registered Registered
Resins Registered Registered Registered
Polymer
Not applicable.
(Due to its low vapor pressure. Inhalation is unlikely at room temperature.)
Wash skin with soap and water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry
contaminated clothing and shoes before reuse.
< 101,2-Propanediol 57-55-6 Registered 2003380
< 10Triethanolamine
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
If swallowed, seek medical advice, and show the MSDS to the physician then.
range (wt%)TSCA EINECSNo.
ConcentrationChemical or generic name CAS No.
-UB-205 Green-
2/5 Creation Date : March 30, 2004
Revision Date : November 7, 2011
5. FIRE-FIGHTING MEASURES
Fire and explosion measures : Slight fire hazard.
Exitinguishing media:Suitable : regular dry chemical, carbon dioxide, water, regular foam.
Large fires : Use regular foam or flood with fine water spray.
Fire fighting : The Products is no flammable.Use extinguishing agents appropriate for surrounding fire.
Avoid inhalation of material or combustion by-products.
Stay upwind and keep out of low areas.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Not available.
Environmental precautions : Do not wash away into shower or water way.
Methods for cleaning up : Wipe off by dry cloth and wash with water.
: In accordance with national, state and local regulations.
7. HANDLING AND STORAGE
Store and handle in accordance with all current regulations and standards.Keep separated from incompatible substances.
Handling:Technical measures : Don't swallow ink.
: Recap after use.
: Don't shake.
: Keep out of the reach of children.
: Avoid contact with skin and eyes.
Precautions : Not available.
Safe handling advice : Not available.
Storage:Technical measures : Keep away from oxidizing materials, ignition sources and
high temperature.
Storage condition : Avoid direct sunlight.
: Do not leave the products in high temperature space.
: Recommended temperature: 0-30 C.
Incompatible products : (Information of components.)
Glycerine
Coloring agent
Resin
1,2-Propanediol
Triethanolamine
Packaging materials : Not applicable.
acids, metals, oxidizing materials
oxidizing materials
acids, bases, oxidizing materials, metal oxides, peroxides,
reducing agents
oxidizing materials, reducing agents
acids, bases, combustible materials, halo carbons, metals,
metal salts, oxidizing materials, reducing agents
-UB-205 Green-
3/5 Creation Date : March 30, 2004
Revision Date : November 7, 2011
8. EXPOSURE CONTROL / PERSONAL PROTECTION
Engineering measures : Not required.
Control parameters (Information of components.)
OSHA
ACGIH
ECUK
Personal protective equipment : Not required.
9. PHYSICAL AND CHEMICAL PROPERTIES
[ ] : Information of components.
Physical state and form : Low viscous liquid.
Colour : Green.
Odour : None odour.
pH : about 8.7
Boiling point : Not available. [Water/ 100 C]
Melting point : <-10 C
Flash point : Not applicable. [1,2-Propanediol/ 99 C(CC)]
Autoignition temperature : Not applicable. [Triethanolamine/ 315.5 C]
Explosion limits : Not applicable.
[ Lower flammable limit / 2.6% , Upper flammable limit / 12.5% <1,2-Propanediol> ]
Density : about 1.05-1.10 / 25 C
Vapour density (air=1) : Not available. [1,2-Propanediol/ 2.60-2.62]
Solubulity in water : Soluble.
Evaporation rate : Not available.
Volatile : 86-89%
10. STABILITY AND REACTIVITY
Stability : Stability.
Hazardous reactions : Will not occur.
Conditions to avoid : Avoid heat, flames, sparks and other sources of ignition.
Avoid contact with incompatible materials.
Materials to avoid : (Information of components.)
Glycerine
Coloring agent
Resin
1,2-Propanediol
Triethanolamine
5mg/m3 TWA(Respirable dust fraction),
15mg/m3 TWA (Total dust)Glycerine
5mg/m3(Respirable flaction),
15mg/m3(Total dust) [Nuisance Dust]Coloring agent
10mg/m3 TWA Glycerine10mg/m3 (Nuisance particulate) Coloring agent
1,2-Propanediol
5mg/m3 TWA TriethanolamineNot available.
acids, metals, oxidizing materials
oxidizing materials
oxidizing materials, reducing agents
150ppm(474mg/m3) TWA(total(vapor and
pariclulates)), 10mg/m3 TWA(particlulates)
acids, bases, oxidizing materials, metal oxides, peroxides,
reducing agents
acids, bases, combustible materials, halo carbons,
metals, metal salts, oxidizing materials, reducing
-UB-205 Green-
4/5 Creation Date : March 30, 2004
Revision Date : November 7, 2011
Hazardous decomposition products : (Information of components.)
common decomposition products
Glycerine
Coloring agent
Resin / Triethanolamine
11.TOXICOLOGICAL INFORMATION
(Information of components)
Acute toxicity
Ingestion LD50
Inhalation LC50Skin LD50
Local effects
Chronic toxicity and long term toxicity
Signs and Symptos of overexposure and aggravated by exposure
Inhalation
Skin contact
Eye contact
Ingestion
Specific effects
12. ECOLOGICAL INFORMATION
Not available.
cyanide, oxides of nitrogen.
oxides of nitrogen.
oxides of carbon, water
corrosive acrolein.
4090mg/kg-Mouse Glycerine
>=5000mg/kg-Rat Coloring agent
1040mg/kg-Rabbit,
>40000mg/kg-Mouse
Resin
20000mg/kg-Rat 1,2-Propanediol
2200mg/kg-Rabbit,
5846mg/kg-Mouse
Triethanolamine
>570mg/m3-1H-Rat Glycerine
>10000mg/kg-Rabbit Glycerine
20800mg/kg-Rabbit 1,2-Propanediol
Repeated or prolonged contact may cause skin sensitization.
>16mL/kg-Rat Triethanolamine
Irritant;skin, eye Triethanolamine
irritation,difficulty breathing Glycerine
irritation Coloring agent
irritation,pneumonitis Resin
nausea,headache 1,2-Propanediol
sore throat,difficulty breathing Triethanolamine
irritation,redness Glycerine / Triethanolamine
irritation Coloring agent
irritation,sensitization Resin
irritation,allergic reaction 1,2-Propanediol
tearing,stinging Glycerine
irritation Coloring agent / Resin
irritation,pain 1,2-Propanediol
diarrhea,pneumonitis Resin
irritation,corneal swelling Triethanolamine
nausea,vomiting Glycerine
allergic reaction,vomiting 1,2-Propanediol
gastric disturbances Coloring agent
IARC Group 3 Resin / Triethanolamine
1,2-Propanediol / Triethanolamine
burns,gastrointestinal irritation Triethanolamine
-UB-205 Green-
5/5 Creation Date : March 30, 2004
Revision Date : November 7, 2011
13. DISPOSAL CONSIDERATIONS
Waste from residues : Disposal in accordance with all current regulations and standards.
Contaminated packaging : Not applicable.
14. TRANSPORT INFORMATION
HS Code : 960810
15. REGULATORY INFORMATION
Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Glycerine / Triethanolamine
EU labeling : Not restricted.
CANADA Hazardous Products Act - Ingredient Disclosure List1%over : 1,2-Propanediol / Triethanolamine
Hazard and safety informationProducts are manufactured in accordance with ISO 8124-3 " Safety of Toys - Part 3"
16. OTHER INFORMATION
This sheet completes the technical sheet of use but it doesn't replace it.
The information contained in this sheet are based knowledge of the products
at the data : (November 7, 2011). They are given quite sincerely.
Moreover the attention of the users is drawn on the risks possibly taken,
when a product is used for other utilization than these which it is intended.
-UB-205 Green-
1/5 Creation Date : March 30, 2004
Revision Date : November 7, 2011
Safety data sheet for chemical products
1. PRODUCT AND COMPANY IDENTIFICATION
Product name: UB-205 Orange [ uni-ball VISION ELITE ]
Manufacture's name : MITSUBISHI PENCIL CO.,LTD.Address : 5-23-37, HIGASHIOHI, SHINAGAWA, TOKYO, JAPANTelephone number : 03-3458-6281 Telefax number : 03-3450-0363Telex number : 2422337 MBPENC J.
Creation Date : March 30, 2004Revision Date : November 7, 2011File No. : 066174A Rev. 2.5.02.03
2. COMPOSITION/INFORMATION ON INGREDIENTS
The chemical product is a substance or a preparation : Preparation
Chemical nature: Component parts : Ink
Other parts : Other parts are excluded from 'chemical substances'.
3. HAZARDS IDENTIFICATION
Most important hazards : Not available.
Specific hazards : Not available.
4. FIRST-AID MEASURES
Inhalation:
Skin contact:
Eye contact:
Ingestion:
[Ink quantity of product : about 1.6g]
102-71-6 Registered 2030498
50- 80
10- 30
< 10
< 10
Glycerine 56-81-5 Registered 2002895
Water 7732-18-5 Registered 2317912
Coloring agent Registered Registered Registered
Resins Registered Registered Registered
Polymer
Not applicable.
(Due to its low vapor pressure. Inhalation is unlikely at room temperature.)
Wash skin with soap and water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry
contaminated clothing and shoes before reuse.
< 101,2-Propanediol 57-55-6 Registered 2003380
< 10Triethanolamine
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
If swallowed, seek medical advice, and show the MSDS to the physician then.
Chemical or generic namerange (wt%)
TSCA EINECSNo.CAS No.Concentration
-UB-205 Orange-
2/5 Creation Date : March 30, 2004
Revision Date : November 7, 2011
5. FIRE-FIGHTING MEASURES
Fire and explosion measures : Slight fire hazard.
Exitinguishing media:Suitable : regular dry chemical, carbon dioxide, water, regular foam.
Large fires : Use regular foam or flood with fine water spray.
Fire fighting : The Products is no flammable.Use extinguishing agents appropriate for surrounding fire.
Avoid inhalation of material or combustion by-products.
Stay upwind and keep out of low areas.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Not available.
Environmental precautions : Do not wash away into shower or water way.
Methods for cleaning up : Wipe off by dry cloth and wash with water.
: In accordance with national, state and local regulations.
7. HANDLING AND STORAGE
Store and handle in accordance with all current regulations and standards.Keep separated from incompatible substances.
Handling:Technical measures : Don't swallow ink.
: Recap after use.
: Don't shake.
: Keep out of the reach of children.
: Avoid contact with skin and eyes.
Precautions : Not available.
Safe handling advice : Not available.
Storage:Technical measures : Keep away from oxidizing materials, ignition sources and
high temperature.
Storage condition : Avoid direct sunlight.
: Do not leave the products in high temperature space.
: Recommended temperature: 0-30 C.
Incompatible products : (Information of components.)
Glycerine
Coloring agent
Resin
1,2-Propanediol
Triethanolamine
Packaging materials : Not applicable.
acids, metals, oxidizing materials
oxidizing materials
oxidizing materials, reducing agents
acids, bases, oxidizing materials, metal oxides, peroxides,
reducing agents
acids, bases, combustible materials, halo carbons, metals,
metal salts, oxidizing materials, reducing agents
-UB-205 Orange-
3/5 Creation Date : March 30, 2004
Revision Date : November 7, 2011
8. EXPOSURE CONTROL / PERSONAL PROTECTION
Engineering measures : Not required.
Control parameters (Information of components.)
OSHA
ACGIH
ECUK
Personal protective equipment : Not required.
9. PHYSICAL AND CHEMICAL PROPERTIES
[ ] : Information of components.
Physical state and form : Low viscous liquid.
Colour : Orange.
Odour : None odour.
pH : about 8.7
Boiling point : Not available. [Water/ 100 C]
Melting point : <-10 C
Flash point : Not applicable. [1,2-Propanediol/ 99 C(CC)]
Autoignition temperature : Not applicable. [Triethanolamine/ 315.5 C]
Explosion limits : Not applicable.
[ Lower flammable limit / 2.6% , Upper flammable limit / 12.5% <1,2-Propanediol> ]
Density : about 1.05-1.10 / 25 C
Vapour density (air=1) : Not available. [1,2-Propanediol/ 2.60-2.62]
Solubulity in water : Soluble.
Evaporation rate : Not available.
Volatile : 84-87%
10. STABILITY AND REACTIVITY
Stability : Stability.
Hazardous reactions : Will not occur.
Conditions to avoid : Avoid heat, flames, sparks and other sources of ignition.
Avoid contact with incompatible materials.
Materials to avoid : (Information of components.)
Glycerine
Coloring agent
Resin
1,2-Propanediol
Triethanolamine
5mg/m3 TWA(Respirable dust fraction),
15mg/m3 TWA (Total dust)Glycerine
5mg/m3(Respirable flaction),
15mg/m3(Total dust) [Nuisance Dust]Coloring agent
10mg/m3 TWA Glycerine10mg/m3 (Nuisance particulate) Coloring agent
1,2-Propanediol
5mg/m3 TWA TriethanolamineNot available.
acids, metals, oxidizing materials
oxidizing materials
oxidizing materials, reducing agents
150ppm(474mg/m3) TWA(total(vapor and
pariclulates)), 10mg/m3 TWA(particlulates)
acids, bases, oxidizing materials, metal oxides,
peroxides, reducing agents
acids, bases, combustible materials, halo carbons,
metals, metal salts, oxidizing materials, reducing
-UB-205 Orange-
4/5 Creation Date : March 30, 2004
Revision Date : November 7, 2011
Hazardous decomposition products : (Information of components.)
11.TOXICOLOGICAL INFORMATION
(Information of components)
Acute toxicity
Ingestion LD50
Inhalation LC50Skin LD50
Local effects
Chronic toxicity and long term toxicity
Signs and Symptos of overexposure and aggravated by exposure
Inhalation
Skin contact
Eye contact
Ingestion
Specific effects
12. ECOLOGICAL INFORMATION
Not available.
oxides of carbon, water common decomposition products
corrosive acrolein. Glycerine
oxides of nitrogen. Coloring agent / Resin / Triethanolamine
4090mg/kg-Mouse Glycerine
>=5000mg/kg-Rat Coloring agent
1040mg/kg-Rabbit,
>40000mg/kg-Mouse
Resin
20000mg/kg-Rat 1,2-Propanediol
2200mg/kg-Rabbit,
5846mg/kg-Mouse
Triethanolamine
>570mg/m3-1H-Rat Glycerine
>10000mg/kg-Rabbit Glycerine
20800mg/kg-Rabbit 1,2-Propanediol
>16mL/kg-Rat Triethanolamine
irritation,difficulty breathing Glycerine
Irritant;skin, eye Triethanolamine
Repeated or prolonged contact may cause skin sensitization.
irritation Coloring agent
irritation,pneumonitis Resin
nausea,headache 1,2-Propanediol
sore throat,difficulty breathing Triethanolamine
irritation,redness Glycerine / Triethanolamine
redness,swelling of skin Coloring agent
irritation,sensitization Resin
irritation,allergic reaction 1,2-Propanediol
tearing,stinging Glycerine
irritation Resin
allergic reaction,vomiting 1,2-Propanediol
nausea,vomiting Glycerine / Coloring agent
diarrhea,pneumonitis Resin
irritation,pain 1,2-Propanediol
irritation,corneal swelling
IARC Group 3 Resin / Triethanolamine
1,2-Propanediol / Triethanolamine
burns,gastrointestinal irritation Triethanolamine
Triethanolamine
-UB-205 Orange-
5/5 Creation Date : March 30, 2004
Revision Date : November 7, 2011
13. DISPOSAL CONSIDERATIONS
Waste from residues : Disposal in accordance with all current regulations and standards.
Contaminated packaging : Not applicable.
14. TRANSPORT INFORMATION
HS Code : 960810
15. REGULATORY INFORMATION
Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Glycerine / Triethanolamine
EU labeling : Not restricted.
CANADA Hazardous Products Act - Ingredient Disclosure List1%over : 1,2-Propanediol / Triethanolamine
Hazard and safety informationProducts are manufactured in accordance with ISO 8124-3 " Safety of Toys - Part 3"
16. OTHER INFORMATION
This sheet completes the technical sheet of use but it doesn't replace it.
The information contained in this sheet are based knowledge of the products
at the data : (November 7, 2011). They are given quite sincerely.
Moreover the attention of the users is drawn on the risks possibly taken,
when a product is used for other utilization than these which it is intended.
-UB-205 Orange-
1/5 Creation Date : March 30, 2004
Revision Date : November 7, 2011
Safety data sheet for chemical products
1. PRODUCT AND COMPANY IDENTIFICATION
Product name: UB-205 Wine [ uni-ball VISION ELITE ]
Manufacture's name : MITSUBISHI PENCIL CO.,LTD.Address : 5-23-37, HIGASHIOHI, SHINAGAWA, TOKYO, JAPANTelephone number : 03-3458-6281 Telefax number : 03-3450-0363Telex number : 2422337 MBPENC J.
Creation Date : March 30, 2004Revision Date : November 7, 2011File No. : 066175A Rev. 2.5.03.03
2. COMPOSITION/INFORMATION ON INGREDIENTS
The chemical product is a substance or a preparation : Preparation
Chemical nature: Component parts : Ink
Other parts : Other parts are excluded from 'chemical substances'.
3. HAZARDS IDENTIFICATION
Most important hazards : Not available.
Specific hazards : Not available.
4. FIRST-AID MEASURES
Inhalation:
Skin contact:
Eye contact:
Ingestion:
[Ink quantity of product : about 1.6g]
(Due to its low vapor pressure. Inhalation is unlikely at room temperature.)
Wash skin with soap and water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry
contaminated clothing and shoes before reuse.
< 10Triethanolamine 102-71-6 Registered 2030498
50- 80
Glycerine 56-81-5 Registered 2002895
Water 7732-18-5 Registered 2317912
10- 30
< 10
< 10Resins Registered Registered Registered
Polymer
Coloring agent Registered Registered Registered
< 10
If swallowed, seek medical advice, and show the MSDS to the physician then.
1,2-Propanediol 57-55-6 Registered 2003380
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
Not applicable.
CAS No.Concentration
Chemical or generic namerange (wt%)
TSCA EINECSNo.
-UB-205 Wine-
2/5 Creation Date : March 30, 2004
Revision Date : November 7, 2011
5. FIRE-FIGHTING MEASURES
Fire and explosion measures : Slight fire hazard.
Exitinguishing media:Suitable : regular dry chemical, carbon dioxide, water, regular foam.
Large fires : Use regular foam or flood with fine water spray.
Fire fighting : The Products is no flammable.Use extinguishing agents appropriate for surrounding fire.
Avoid inhalation of material or combustion by-products.
Stay upwind and keep out of low areas.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Not available.
Environmental precautions : Do not wash away into shower or water way.
Methods for cleaning up : Wipe off by dry cloth and wash with water.
: In accordance with national, state and local regulations.
7. HANDLING AND STORAGE
Store and handle in accordance with all current regulations and standards.Keep separated from incompatible substances.
Handling:Technical measures : Don't swallow ink.
: Recap after use.
: Don't shake.
: Keep out of the reach of children.
: Avoid contact with skin and eyes.
Precautions : Not available.
Safe handling advice : Not available.
Storage:Technical measures : Keep away from oxidizing materials, ignition sources and
high temperature.
Storage condition : Avoid direct sunlight.
: Do not leave the products in high temperature space.
: Recommended temperature: 0-30 C.
Incompatible products : (Information of components.)
Glycerine
Coloring agent
Resin
1,2-Propanediol
Triethanolamine
Packaging materials : Not applicable.
acids, metals, oxidizing materials
oxidizing materials
acids, bases, oxidizing materials, metal oxides, peroxides,
reducing agents
oxidizing materials, reducing agents
acids, bases, combustible materials, halo carbons, metals,
metal salts, oxidizing materials, reducing agents
-UB-205 Wine-
3/5 Creation Date : March 30, 2004
Revision Date : November 7, 2011
8. EXPOSURE CONTROL / PERSONAL PROTECTION
Engineering measures : Not required.
Control parameters (Information of components.)
OSHA
ACGIH
ECUK
Personal protective equipment : Not required.
9. PHYSICAL AND CHEMICAL PROPERTIES
[ ] : Information of components.
Physical state and form : Low viscous liquid.
Colour : Wine.
Odour : None odour.
pH : about 8.7
Boiling point : Not available. [Water/ 100 C]
Melting point : <-10 C
Flash point : Not applicable. [1,2-Propanediol/ 99 C(CC)]
Autoignition temperature : Not applicable. [Triethanolamine/ 315.5 C]
Explosion limits : Not applicable.
[ Lower flammable limit / 2.6% , Upper flammable limit / 12.5% <1,2-Propanediol> ]
Density : about 1.05-1.10 / 25 C
Vapour density (air=1) : Not available. [1,2-Propanediol/ 2.60-2.62]
Solubulity in water : Soluble.
Evaporation rate : Not available.
Volatile : 81-84%
10. STABILITY AND REACTIVITY
Stability : Stability.
Hazardous reactions : Will not occur.
Conditions to avoid : Avoid heat, flames, sparks and other sources of ignition.
Avoid contact with incompatible materials.
Materials to avoid : (Information of components.)
Glycerine
Coloring agent
Resin
1,2-Propanediol
Triethanolamine
5mg/m3 TWA(Respirable dust fraction),
15mg/m3 TWA (Total dust)Glycerine
5mg/m3(Respirable flaction),
15mg/m3(Total dust) [Nuisance Dust]Coloring agent
10mg/m3 TWA Glycerine10mg/m3 (Nuisance particulate) Coloring agent
1,2-Propanediol
5mg/m3 TWA TriethanolamineNot available.
acids, metals, oxidizing materials
oxidizing materials
oxidizing materials, reducing agents
150ppm(474mg/m3) TWA(total(vapor and
pariclulates)), 10mg/m3 TWA(particlulates)
acids, bases, oxidizing materials, metal oxides,
peroxides, reducing agents
acids, bases, combustible materials, halo carbons,
metals, metal salts, oxidizing materials, reducing
-UB-205 Wine-
4/5 Creation Date : March 30, 2004
Revision Date : November 7, 2011
Hazardous decomposition products : (Information of components.)
11.TOXICOLOGICAL INFORMATION
(Information of components)
Acute toxicity
Ingestion LD50
Inhalation LC50Skin LD50
Local effects
Chronic toxicity and long term toxicity
Signs and Symptos of overexposure and aggravated by exposure
Inhalation
Skin contact
Eye contact
Ingestion
Specific effects
12. ECOLOGICAL INFORMATION
Not available.
oxides of carbon, water common decomposition products
corrosive acrolein. Glycerine
oxides of nitrogen. Coloring agent / Resin / Triethanolamine
4090mg/kg-Mouse Glycerine
>=5000mg/kg-Rat Coloring agent
1040mg/kg-Rabbit,
>40000mg/kg-Mouse
Resin
20000mg/kg-Rat 1,2-Propanediol
2200mg/kg-Rabbit,
5846mg/kg-Mouse
Triethanolamine
>570mg/m3-1H-Rat Glycerine
>10000mg/kg-Rabbit Glycerine
>3000mg/kg-Rabbit Coloring agent
20800mg/kg-Rabbit 1,2-Propanediol
Repeated or prolonged contact may cause skin sensitization. 1,2-Propanediol / Triethanolamine
>16mL/kg-Rat Triethanolamine
Irritant;skin, eye Triethanolamine
irritation,difficulty breathing Glycerine
irritation,pneumonitis Resin
nausea,headache 1,2-Propanediol
sore throat,difficulty breathing Triethanolamine
irritation,redness Glycerine / Triethanolamine
irritation,sensitization Resin
irritation,allergic reaction 1,2-Propanediol
tearing,stinging Glycerine
irritation Resin
irritation,pain 1,2-Propanediol
Resin
allergic reaction,vomiting 1,2-Propanediol
irritation,corneal swelling Triethanolamine
nausea,vomiting Glycerine
IARC Group 3 Resin / Triethanolamine
burns,gastrointestinal irritation Triethanolamine
diarrhea,pneumonitis
-UB-205 Wine-
5/5 Creation Date : March 30, 2004
Revision Date : November 7, 2011
13. DISPOSAL CONSIDERATIONS
Waste from residues : Disposal in accordance with all current regulations and standards.
Contaminated packaging : Not applicable.
14. TRANSPORT INFORMATION
HS Code : 960810
15. REGULATORY INFORMATION
Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Glycerine / Triethanolamine
EU labeling : Not restricted.
CANADA Hazardous Products Act - Ingredient Disclosure List1%over : 1,2-Propanediol / Triethanolamine
Hazard and safety informationProducts are manufactured in accordance with ISO 8124-3 " Safety of Toys - Part 3"
16. OTHER INFORMATION
This sheet completes the technical sheet of use but it doesn't replace it.
The information contained in this sheet are based knowledge of the products
at the data : (November 7, 2011). They are given quite sincerely.
Moreover the attention of the users is drawn on the risks possibly taken,
when a product is used for other utilization than these which it is intended.
-UB-205 Wine-