RUSSIAN CHEMICAL BULLETIN International Edition · Reactions of tautomeric quaternary phosphonium salts based R. A. Khachatrian, S. A. Zalinian, 148 139 on triphenylphosphine and

1066�5285/02/5112�2313 $27.00 © 2002 Plenum Publishing Corporation

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2147—2171, December, 2002.

Contents of 2002 issues

Issue 1, 2002

Reviews

Engl./Russ.

Construction of the reaction networks for heterogeneous catalytic O. N. Temkin, A. V. Zeigarnik, 1 1reactions: Fischer—Tropsch synthesis and related reactions A. E. Kuz´min, L. G. Bruk,

and E. V. Slivinskii

General and Inorganic Chemistry

Anomalies of the partition coefficient and properties of crystals Yu. I. Vesnin 37 35in the region of low concentrations of an isomorphousadmixture. 1. Unusual decomposition of solid solutionsof the NaCl—CdCl2 system

Powder X�ray diffraction study of the double complexes Yu. V. Shubin, S. V. Korenev, 41 39[M(NH3)5Cl][MĆl4] as precursors of metal K. V. Yusenko, T. M. Korda,powders (M = Ir, Rh, Co; M´ = Pt, Pd) and A. B. Venediktov

Physical Chemistry

Exoemission and catalytic activity of oxides with perovskite and I. V. Krylova 46 44spinel structures in the oxidation of CO and hydrocarbons

Chemiluminescence accompanying chitosane destruction K. Yu. Murinov, A. I. Voloshin, 54 52in hydrochloric acid solution containing hydrogen N. N. Krasnogorskaya,peroxide and Yu. F. Sokov

Crown�containing spironaphthoxazines and spiropyrans. Yu. P. Strokach, O. A. Fedorova, 58 562. Influence of metal cations on the photochromic S. P. Gromov, A. V. Koshkin,properties of spironaphthoxazines linked with T. M. Valova, V. A. Barachevsky,aza�15(18)�crown�5(6) ethers M. V. Alfimov, V. A. Lokshin,

A. Samat, and R. Guglielmetti

Electronic excitation energy transfer in solid solution of A. P. Pivovarov, M. G. Kaplunov, 67 657�diethylamino�3,4�benzophenoxazine�2�one I. K. Yakushchenko,(Nile Red dye) in bis[N�2�(oxybenzylidene)� M. Yu. Belov, G. V. Nikolaeva,4�tert�butylaniline]zinc and O. N. Efimov

Retro�Bingel reaction in the electrochemical reduction V. V. Yanilkin, N. V. Nastapova, 72 70of bis(dialkoxyphosphoryl)methanofullerenes V. P. Gubskaya, V. I. Morozov,

L. Sh. Berezhnaya, andI. A. Nuretdinov

Electrochemical reduction of 5�halo�5�nitro�1,3�dioxanes V. V. Yanilkin, Z. A. Bredikhina, 78 76and 2�halo�2�nitro�1,3�propanediols N. I. Maksimyuk, V. I. Morozov,

N. V. Nastapova, andA. A. Bredikhin

Electrochemical arylation of cobalt and nickel chelates T. V. Magdesieva, D. N. Kravchuk, 85 83with diphenyliodonium salts and K. P. Butin

RUSSIAN CHEMICAL BULLETINInternational EditionVolume 51, Number 12, December, 2002

Russ.Chem.Bull., Int.Ed., Vol. 51, No. 12, December, 20022314

Engl./Russ.

IR spectra of hydrogen fluoride solutions in n�propanol V. F. Sukhoverkhov, D. K. Buslov, 90 88N. I. Sushko, E. G. Tarakanova,and G. V. Yukhnevich

Thermal decomposition of deuterofullerite Yu. M. Shul´ga, V. M. Martynenko, 96 93B. P. Tarasov, V. N. Fokin,and N. V. Chapysheva

Influence of the position of the nitro group on the structural E. G. Atovmyan, L. A. Nikonova, 99 96and spectroscopic characteristics of N´�(nitrobenzylidene)� O. S. Filipenko, T. N. Fedotova,isonicotinic hydrazides in the crystalline state and S. M. Aldoshin

Molecular and crystal structures of 5,7�dichloro�4�nitro� F. S. Levinson, S. I. Efimov, 105 1012,1,3�benzoxadiazole and products of its reactions B. I. Buzykin, A. T. Gubaidullin,with secondary amines D. B. Krivolapov, and

I. A. Litvinov

Strong intramolecular hydrogen bond N—H...O in N. N. Chipanina, V. K. Turchaninov, 111 1072�(2�acyl�1�phenylethenyl)�5�phenylpyrroles I. I. Vorontsov, M. Yu. Antipin,

Z. V. Stepanova, L. N. Sobenina,A. I. Mikhaleva, andB. A. Trofimov

Organic Chemistry

New unsymmetrical difluoroaromatic compounds and estimation M. L. Keshtov, A. L. Rusanov, 117 112of their reactivities in nucleophilic substitution S. V. Keshtova, P. V. Petrovskii,

and A. A. Shchegolikhin

Oxidation of N�acyl�2�(cycloalk�1�enyl)anilines with ozone R. R. Gataullin, M. F. Nasyrov, 124 118and hydrogen peroxide D. I. Dýachenko, A. A. Fatykhov,

O. V. Shitikova, L. V. Spirikhin,and I. B. Abdrakhmanov

Cross�coupling of aryl iodides with paramagnetic terminal acetylenes S. V. Klyatskaya, E. V. Tretýakov, 128 122derived from 4,4,5,5�tetramethyl�2�imidazoline�1�oxyl 3�oxide and S. F. Vasilevsky

Synthesis of 5,6�indolo�12�crown�4 ethers S. V. Klyatskaya, E. V. Tretýakov, 135 128and S. F. Vasilevsky

Heterocyclic analogs of pleiadiene. 69. Synthesis and oxidative I. V. Borovlev, O. P. Demidov, 139 132hydroxylation of 1�alkyl�1,3�diazapyrenium salts A. V. Chernyshev, and

A. F. Pozharskii

New approach to the synthesis of 2�carbamoylbenzothiazoles V. N. Yarovenko, F. M. Stoyanovich, 144 136O. Yu. Zolotarskaya,E. I. Chernoburova,I. V. Zavarzin,and M. M. Krayushkin

Reactions of tautomeric quaternary phosphonium salts based R. A. Khachatrian, S. A. Zalinian, 148 139on triphenylphosphine and 3�phenylpropargyl bromide G. B. Bagdasarian,with nitrogen nucleophiles E. A. Sarkisova, and

M. H. Injikian

Synthesis of new macrocyclic aminomethylphosphines R. M. Kuznetsov, A. S. Balueva, 151 142based on 4,4´�diaminodiphenylmethane I. A. Litvinov, A. T. Gubaidullin,and its derivatives G. N. Nikonov, A. A. Karasik,

and O. G. Sinyashin

Synthesis and structures of nitroxyalkyl methylphosphonates L. T. Eremenko, G. V. Oreshko, 157 148D. A. Nesterenko,G. V. Lagodzinskaya, andI. L. Eremenko

Russ.Chem.Bull., Int.Ed., Vol. 51, No. 12, December, 2002 2315

Organometallic Chemistry

Engl./Russ.

Stereoselective formation of ansa�metallocenes in reactions of I. L. Fedushkin, Yu. A. Kurskii, 160 151radical�anionic salts of acenaphthylene with lanthanide V. I. Nevodchikov,and calcium halides M. N. Bochkarev, S. Müchle,

and H. Schumann

Synthesis and redox properties of bis�ferrocenylethynyl A. G. Belen´kaya, F. M. Dolgushin, 170 160derivatives of bis(dimethylphosphinoethane)manganese M. G. Peterleitner,

P. V. Petrovskii, andV. V. Krivykh

Synthesis of dichloro derivatives of linear and cyclic permethyl� A. I. Chernyavskii, D. Yu. Larkin, 175 165oligosilanes and cyclolinear permethylpolysilane�siloxanes and N. A. Chernyavskayaand permethylpolyoxysilane based on them

Brief Communications

Unexpected synthesis of 6�amino�2,3�dihydro�4�pyrone� V. Ya. Sosnovskikh and 181 1703�spirocyclohexane M. Yu. Melńikov

Synthesis of arylidene derivatives of N�unsubstituted pyrrolin�2�ones A. Yu. Egorova 183 172

Synthesis of α�alkyl� and α,α�dialkyl�β�phenyltryptamines B. B. Semenov and 185 174Yu. I. Smushkevich

Synthesis of 3�methoxy�5�oxo�6�phenyl�5,6�dihydro�4H�iso� N. V. Voskoboev, A. I. Gerasyuto, 187 175thiazolo[5,4�b]�1,4�thiazine 7,7�dioxide, the first and S. G. Zlotinrepresentative of a new heterocyclic system

Sulfur ylides. 10. Modified method for the synthesis of pyrrolizine� S. N. Lakeev, I. Z. Mullagalin, 189 177and indolizinediones I. O. Maidanova, F. Z. Galin,

and G. A. Tolstikov

Letters to the Editor

Unusual reaction of hexaethylphosphorous triamide with mercuric Yu. G. Gololobov, E. M. Ivanova, 191 179chloride leading to the formation of metallic mercury and P. V. Petrovskii

Information 192 182

Issue 2, 2002

Reviews

Molecular design of tautomeric interconversions of heterocycles K. N. Zelenin, V. V. Alekseyev, 205 197K. Pihlaja, and V. V. Ovcharenko

Physical Chemistry

On the problem of directed signal transmission and energy L. A. Gribov 222 213transfer in molecular systems

On the possibility of existence of η4�π�complexes of corannulene A. L. Chistyakov and I. V. Stankevich 230 220(C20H10) and С60 fullerene derivatives

Addition of Me2•CCN, Me2

•CPh, and CCl3CH2•CHPh R. G. Gasanov and B. L. Tumanskii 240 229

radicals to fullerene C60


Engl./Russ.

Adsorption of H3РW12O40 by porous carbon materials M. N. Timofeeva, M. M. Matrosova, 243 232T. V. Reshetenko, L. B. Avdeeva,E. A. Paukshtis, A. A. Budneva,A. L. Chuvilin, andV. A. Likholobov

Cyclohexane transformations over metal oxide catalysts. O. V. Masloboishchikova, 249 2371. Effect of the nature of metal and support on T. V. Vasina,the catalytic activity in cyclohexane ring opening E. G. Khelkovskaya�Sergeeva,

L. M. Kustov, and P. Zeuthen

Cyclohexane transformations over metal oxide catalysts. T. V. Vasina, 255 2422. Selective cyclohexane ring opening to form O. V. Masloboishchikova,n�hexane over mono� and bimetallic rhodium E. G. Khelkovskaya�Sergeeva,catalysts L. M. Kustov, and P. Zeuthen

Carbonylation of methyl acetate in the presence N. V. Kolesnichenko, A. E. Batov, 259 246of polymeric rhodium�containing catalysts N. A. Markova, and

E. V. Slivinskii

Electrochemical reduction and oxidation I. A. Nuretdinov, V. V. Yanilkin, 263 250of fullerenopyrrolidines and the ESR V. I. Morozov, V. P. Gubskaya,spectra of paramagnetic intermediates V. V. Zverev, N. V. Nastapova,

and G. M. Fazleeva

Electrocatalytic reactions involving Yu. H. Budnikova, D. I. Tazeev, 269 256the NiII—ZnII—2,2´�bipyridine system and D. G. Yakhvarov

Ammonia and carbon dioxide permeability through A. V. Vorobiev and I. N. Beckman 275 262perfluorosulfonic membranes

Sulfurization of polymers. 5. Poly(6�methyl�5�sulfanyl� B. A. Trofimov, A. G. Mal´kina, 282 269thieno[2,3�b]pyridine�4�thione), poly(thie� L. V. Sokolyanskaya,no[2,3�b]azepine�4,5(6H )�dithione), and related V. V. Nosyreva, G. F. Myachina,structures from poly(2�methyl�5�vinylpyridine) S. A. Korzhova, I. V. Rodionova,and elemental sulfur T. I. Vakul´skaya, L. V. Klyba,

E. S. Stoyanov, T. A. Skotheim,and Yu. V. Mikhailik

1H, 13C, and 14N NMR study of 3�methylfurazans with D. E. Dmitriev, Yu. A. Strelenko, 290 277nitrogen�containing substituents at position 4 and A. B. Sheremetev

Dipole�stabilized carbanions in the series of cyclic aldonitrones. M. A. Voinov and I. A. Grigorév 297 2833. The influence of the configuration of the nitrone groupon H—D exchange of the methine hydrogen atomand metallation of aldonitrones

Specific features of resonance electron capture mass spectra R. V. Khatymov, M. V. Muftakhov, 306 291of ecdysteroid molecules V. A. Mazunov, D. V. Nedopekin,

I. V. Galyautdinov, andV. N. Odinokov

Organic Chemistry

Selective reduction of the nitro group in the presence of the azoxy D. L. Lipilin, A. M. Churakov, 311 295group. Synthesis of 2�(alkyl�NNO�azoxy)anilines Yu. A. Strelenko, and

V. A. Tartakovsky

Synthesis of crown�containing 2�styrylbenzothiazoles. O. A. Fedorova, E. N. Andryukhina, 319 302Effect of alkali metal cations on the condensation A. V. Lindeman, S. S. Basok,of crown�ether benzaldehydes with 2�methylbenzothiazole T. Yu. Bogashchenko, and

S. P. Gromov


Engl./Russ.

Cascade cycloaddition reactions involving dimethyl� N. P. Tsvetkov, V. E. Vakhmistrov, 326 308hydrazones of α�substituted acroleins A. B. Koldobsky, A. A. Korlyukov,

and V. N. Kalinin

Synthesis of (7�polyfluoroalkyl)pyrazolo[1,5�a]pyrimidines V. I. Filyakova, O. A. Kuznetsova, 332 313based on lithium fluorine�containing β�diketonates E. N. Ulomskii, T. V. Rybalova,

Yu. V. Gatilov, M. I. Kodess,V. L. Rusinov, andK. I. Pashkevich

Reactions of carbanions of bis(dialkoxyphosphoryl)bromomethane I. A. Nuretdinov, V. P. Gubskaya, 337 317with fullerenes C60 and C70 N. I. Shishikina, G. M. Fazleeva,

L. Sh. Berezhnaya,I. P. Karaseva, F. G. Sibgatullina,and V. V. Zverev


1�Thiocarbamoyl(ferrocenyl)�4,5�dihydropyrazoles E. I. Klimova, T. Klimova, 342 321M. Martinez Garcia,E. A. Vázquez López,J. M. Méndez Stivalet,and L. Ruiz Ramirez

Synthesis and crystal structure of supramolecular adduct O. A. Gerasko, D. G. Samsonenko, 346 325of tetranuclear uranyl chloride aquacomplex A. A. Sharonova, A. V. Virovets,with macrocyclic cavitand cucurbituril J. Lipkowski, and V. P. Fedin

Synthesis and the crystal structure of the triosmium cluster A. A. Koridze, S. A. Kuklin, 350 328with the µ�dehydrobenzene ligand, P. V. Petrovskii,Os3(µ�H)2(CO)7(µ�C6H4){µ3�Ph2PCH2P(C6H4)Ph} F. M. Dolgushin, and

M. G. Ezernitskaya


Ring opening in epichlorohydrin and β�methylepichlorohydrin I. R. Chanysheva, S. L. Litvinenko, 354 332under the action of the [PtCl4]2– anion in aqueous solutions and A. N. Vdovichenko

A new approach to the one�pot synthesis of 5�substituted B. B. Semenov 357 3342�methyl�1,3,4�oxadiazoles from N�tributylstannyltetrazoles and Yu. I. Smushkevich

Stereocontrolled synthesis of trans�2�hydroxymethyl� A. V. Stepanov and V. V. Veselovsky 359 3363�methylcyclopentanone from (S)�(+)�citronellene


First multicomponent synthesis of tricyclic hydrogenated pyridines V. V. Dotsenko, S. G. Krivokolysko, 362 339V. P. Litvinov, and A. N. Chernega

Formation of dehydrogenated derivatives upon the oxidative A. I. Nekhaev and E. I. Bagrii 364 341dehydrogenation of adamantanes

Issue 3, 2002

Reviews

Cycloaddition to buckminsterfullerene C60: advancements M. A. Yurovskaya and I. V. Trushkov 367 343and future prospects



Engl./Russ.

Synthesis and the crystal structure of [Hg6As4](InCl6)Cl: A. V. Olenev, A. I. Baranov, 444 414influence of covalent and electrostatic factors M. M. Shatruk, A. S. Tyablikov,on the supramolecular structure and A. V. Shevelkov

Physical Chemistry

Free radical formation during ethylbenzene oxidation catalyzed L. M. Pisarenko and O. T. Kasaikina 449 419by cetyltrimethylammonium bromide

Femtosecond relaxation of photoexcited states in nanosized V. A. Nadtochenko, N. N. Denisov, 457 426semiconductor particles of iron oxides V. Yu. Gak, F. E. Gostev,

A. A. Titov, O. M. Sarkisov,and V. V. Nikandrov

Photo� and thermochromic spiropyrans. 21. 8´�Formyl� B. B. Safoklov, B. S. Lukýanov, 462 4313,6´�dimethyl�4�oxospiro(3,4�dihydro� A. O. Bulanov, A. V. Metelitsa,2H�1,3�benzoxazine�2,2´�[2H ]chromene) possessing V. I. Minkin, V. V. Tkachev,photochromic properties in the solid phase and S. M. Aldoshin

Redox properties of N2S2�type nickel complexes E. K. Beloglazkina, A. A. Moiseeva, 467 436with aromatic ligands. Crystal structure of A. V. Churakov, I. S. Orlov,[1,2�C6H4(SMe)NH2]2Ni2+(MeCN)2•2ClO4

– N. V. Zyk, J. A. K. Howard,and K. P. Butin

Formation of coordination polymeric structures on the basis V. F. Razumov, S. B. Brichkin, 476 444of 4,4´�dipyridylethylene and Ag+ in solutions O. M. Pilugina, T. P. Karpova,

S. Z. Vatsadze,D. A. Lemenovskii, M. Schröder,N. R. Champness, and M. V. Alfimov

Organic Chemistry

Enzymatic dissymmetrization of meso�2,3�dimethyl� A. A. Vasilév, O. Vielhauer, 481 448butane�1,4�diol and its diacetate. Synthesis L. Engman, M. Pietzsch,of scalemic (–)�lasiol and E. P. Serebryakov

Binuclear and polynuclear transition metal complexes Yu. A. Ustynyuk, N. E. Borisova, 488 454with macrocyclic ligands. 2. New macrocyclic V. M. Nosova, M. D. Reshetova,Schiff's base in the reaction of 4�tert�butyl� S. S. Talismanov, S. E. Nefedov,2,6�diformylphenol with 1,2�diaminobenzene. G. A. Aleksandrov,Synthesis and structural, spectroscopic, and I. L. Eremenko, and I. I. Moiseevtheoretical study

Synthesis of 1,2,4�triazolium 4N�nitroimides by the nitration O. P. Shitov, V. L. Korolev, 499 464of 1�substituted 4�amino�1,2,4�triazolium nitrates and V. A. Tartakovsky

Synthesis of 3�acetyl�4�amino�6�arylpyran�2�ones and ethyl V. A. Dorokhov, A. V. Vasilyev, 503 4677�aryl�4,5(1H,5H )�dioxopyrano[4,3�b]pyridine�2�carboxylates and S. V. Baranin

Synthesis and properties of [1,4]diazepino[6,5�b]indoles N. A. Lantsetti, S. Yu. Ryabova, 506 470L. M. Alekseeva, A. S. Shashkov,and V. G. Granik

Pd�Catalyzed asymmetric allylation of an o�carborane derivative R. V. Lebedev, S. K. Moiseev, 513 476O. G. Bondarev, M. M. Ilín,K. N. Gavrilov, and V. N. Kalinin



Engl./Russ.

Reaction of ruthenacarborane with trifluoro� I. A. Lobanova, S. V. Timofeev, 517 480acetoxymercuroferracarborane A. R. Kudinov,

V. I. Meshcheryakov,P. V. Petrovskii, Z. A. Starikova,and V. I. Bregadze

Palladium�catalyzed asymmetric allylation and complex O. G. Bondarev, K. N. Gavrilov, 521 484formation involving P,N�bidentate derivatives V. N. Tsarev, V. A. Davankov,of (S)�2�(anilinomethyl)pyrrolidine R. V. Lebedev, S. K. Moiseev,

and V. N. Kalinin

Chemistry of Natural Compounds, Bioorganic, and Biomolecular Chemistry

Synthesis of chromenes with isoprenoid side chains V. N. Odinokov, A. Yu. Spivak, 526 489and their selective ozonolysis G. A. Emelýanova, and

B. I. Kutepov

Study of alkaloids of the Siberian and Altai flora. 7. Synthesis J. Ganbaatar, D. Batsuren, 531 493of 18�amino�18�deoxy derivatives of elatidine S. A. Osadchii, E. E. Shults,

and G. A. Tolstikov

Steroid compounds from the starfish Lysastrosoma anthosticta E. V. Levina, P. V. Andriyashchenko, 535 497collected in the Sea of Japan A. I. Kalinovskii,

P. S. Dmitrenok, V. A. Stonik,and N. G. Prokoféva


Synthesis of 2� and 3�pyridinyl(aryl)methanones I. S. Popova, A. A. Formanovsky, 540 501and I. V. Mikhura

Replacement of an oxygen atom by chlorine atoms in the reaction T. D. Petrova, V. E. Platonov, 544 504of pentafluorobenzaldehyde with CCl3�substituted compounds and L. M. Pokrovskiiin the presence of AlCl3

Synthesis of 2�(imidazolylamino)benzothiazoles O. S. El´tsov and V. S. Mokrushin 547 506

Novel method for the synthesis of (trifluoromethyl)oxirane S. A. Lermontov, N. V. Kuryleva, 550 508and T. N. Velikokhat´ko


New tungsten carbyne complexes containing the triphenylgermyl L. N. Bochkarev, A. V. Safronova, 552 510and triphenylstannyl groups at the carbyne carbon atom V. I. Shcherbakov,(ButO)3W≡C—EPh3 (E = Ge, Sn) N. E. Stolyarova, G. V. Basova,

S. Ya. Khorshev, Yu. A. Kurskii,and G. A. Abakumov

Electroconductive polymer films obtained by plasma polymerization A. I. Drachev, E. I. Shklyarova, 554 511of 1�amino�9,10�anthraquinone T. V. Dorofeeva, A. B. Gil´man,

and A. A. Kuznetsov


Issue 4, 2002

Reviews

Engl./Russ.

Proton mobility in hydrates of inorganic acids and acid salts A. B. Yaroslavtsev and V. Yu. Kotov 555 515

Tetranuclear rhenium chalcogenide cluster complexes Yu. V. Mironov and V. E. Fedorov 569 529with a cubane core. Synthesis, structures, and properties

Synthesis and properties of styrenetricarbonylchromium L. L. Semenycheva, A. N. Artemov, 581 540and its analogs I. S. Ilíchev, and D. F. Grishin

Physical Chemistry

Conformational analysis and regioisomerism of mono� L. V. Ermolaeva, V. E. Kataev, 593 551and diadducts of O,O�diisopropyl isoxazolino� S. I. Strobykin, A. P. Timosheva,phosphonate with C60 V. I. Kovalenko, I. P. Romanova,

and O. G. Sinyashin

Reactions of mono� and bimolecular hydrogen transfer A. F. Shestakov, T. G. Denisova, 602 559in alkyl radicals: analysis using the parabolic model E. T. Denisov, andand density functional calculations N. S. Emelýanova

Kinetics, mechanism, and products of the reaction A. M. Nazarov, S. L. Khursan, 608 565of diphenylcarbonyl oxide with carboxylic acids E. M. Chainikova, and

V. D. Komissarov

New approaches to syntheses of diethers and haloethers M. Ya. Skumov, S. M. Brailovskii, 616 572from cyclopentadiene and O. N. Temkin

Modification of the polytrimethylsilylpropyne adsorption V. G. Berezkin, A. A. Korolev, 625 580layer in open capillary columns and V. S. Khotimsky

Products of reaction of fullerene C60 with fuming sulfuric O. G. Garkusha, S. P. Solodovnikov, 628 582acid studied by IR and ESR spectroscopy and B. V. Lokshin

ESR study of weak exchange interactions in binuclear G. M. Larin, V. F. Shul´gin, 632 585copper(II) complexes with acyldihydrazones E. D. Melńikova, V. Ya. Zub,of fluorinated β�diketones and Yu. V. Rakitin

ESR study of the thermal decomposition of di�tert�butoxy� L. P. Stepovik, I. M. Martinova, 638 590tert�butyl alumotrioxide formed in the reaction of V. A. Dodonov, andtri�tert�butoxyaluminum with tert�butyl hydroperoxide V. K. Cherkasov

Organic Chemistry

Ring�closing metathesis of 2,2�diallyl derivatives of pyrrolidine N. B. Bespalova, O. V. Shuvalova, 645 596and piperidine: a route to azaspiroheterocyclic structures V. G. Zaikin, R. S. Borisov,

F. V. Pastukhov, andYu. N. Bubnov

Synthesis of new CF3�containing 3,4�dihydro�2H�pyrans A. L. Krasovsky, V. G. Nenajdenko, 649 600and E. S. Balenkova

Reactions of N,N�(dialkyl)arylthioacetamides with dialkyl M. F. Kosterina, Yu. Yu. Morzherin, 653 604acetylenedicarboxylates A. V. Tkachev, T. V. Rybalova,

Yu. V. Gatilov, and V. A. Bakulev

Transetherification of difurazanyl ethers as a route A. B. Sheremetev, E. V. Mantseva, 659 609to unsymmetrical derivatives of difurazanyl ether D. E. Dmitriev, and

F. S. Sirovskii


Engl./Russ.

1,2,4�Triazino[5,6,1�i,j]quinolines: a new type of tricyclic G. N. Lipunova, E. V. Nosova, 663 613analogs of fluoroquinolones N. N. Mochul´skaya,

A. A. Andreiko,O. M. Chasovskikh,and V. N. Charushin

First example of the formation of bipolar spiro σ�complexes V. A. Voronina, A. E. Frumkin, 668 617from 6�bromo�5,7�dinitrobenzo[e]�1,2,3,4�tetrazine S. V. Kurbatov, A. M. Churakov,1,3�di�N�oxide O. Yu. Smirnov, and

L. P. Olekhnovich

Reactions of dibenzylphosphine oxide with α,β�unsaturated V. D. Kolesnik and A. V. Tkachev 671 620nitriles: synthesis of aminophospholene oxides


Heteroorganic betaines. 8. Synthesis and structures I. V. Borisova, N. N. Zemlyanskii, 678 627of silicon� and germanium�containing organo� V. N. Khrustalev, M. S. Nechaev,arsenic betaines R1

3As+—CR2R3—EMe2—S– M. G. Kuznetsova, and(E = Si, Ge) Yu. A. Ustynyuk

Half�sandwich complexes of lanthanides with tridentate ligands A. A. Trifonov, E. A. Fedorova, 684 632[RCH2CH(O)CH2OBun]2– (R = C5H4, 1�C9H6): synthesis, E. N. Kirillov, S. E. Nefedov,structures, and properties. The crystal structure of the complex I. L. Eremenko, Yu. A. Kurskii,{[(η5�C5H4)CH2CH(µ2:η1�O)CH2OBun]LaN(SiMe3)2}2 A. S. Shavyrin, and

M. N. Bochkarev

Transformations of spirocyclodimers of 1,3�bis(ferro� E. I. Klimova, T. Klimova, 691 638cenylmethylidene)�2�methylidenecycloalkanes M. Martinez Garcia,in acid medium C. Alvarez Toledano,

A. R. Toscano, andL. Ruiz Ramirez


Selective preparation of glycosyl sulfone or glycal by treatment L. O. Kononov, B. S. Komarova, 698 644of phenyl thioglycoside of N�acetylneuraminic acid and N. E. Nifantievwith m�chloroperbenzoic acid

Synthesis of 6(E )� and 6(Z )�(3�ethoxycarbonylpropyl)oximes I. S. Levina, L. E. Kulikova, 703 649of 16α,17α�cyclohexanopregn�4�ene�3,6,20�trione and study A. V. Kamernitskii,of their interaction with proteins of the rat uterine cytosol A. S. Shashkov, A. N. Smirnov,and blood serum and E. V. Pokrovskaya


Spirocyclohexadienones. 5. Synthesis of 2�R�7a�methyl�3�(spiro� V. A. Glushkov, O. G. Ausheva, 709 654cyclohexa�2,5�dien�4�one)perhydro�1�indolines and Yu. V. Shklyaev

Condensation of polyfluorinated β�diimines with aromatic aldehydes O. E. Petrova, M. A. Kurykin, 712 656and E. M. Kagramanova


Estimation of the clathrate aggregation of substances in solutions V. L. Bogatyryov 715 659from ion�exchange equilibrium data

Information 717 661


Issue 5, 2002

Reviews

Engl./Russ.

New heteroorganic betaines containing the (+)E15—C—E14—X(–) I. V. Borisova, M. S. Nechaev, 721 665and (+)E15—C—E14(–) structural fragments (E15 = P, As; V. N. Khrustalev,E14 = Si, Ge, Sn; X = C, S, O, NR) N. N. Zemlyanskii, and

Yu. A. Ustynyuk

Physical Chemistry

Crystal and molecular structures of fluorinated derivatives of C60 I. S. Neretin, K. A. Lyssenko, 754 695fullerene M. Yu. Antipin, and

Yu. L. Slovokhotov

Effect of local strain on the reactivity of carbon nanotubes T. Yu. Astakhova, G. A. Vinogradov, 764 704O. D. Gurin, and M. Menon

Simulation of the molecular and electronic structure of C60 A. L. Chistyakov and I. V. Stankevich 770 709fullerene π�complex with twelve half�sandwich species FeC5H5

Acetylene—allene rearrangement of propargyl systems X—CH2—C≡CH V. B. Kobychev, N. M. Vitkovskaya, 774 713(X = H, Me, NMe2, OMe, F, SMe): an ab initio study N. S. Klyba, and B. A. Trofimov

Mechanism of reaction of n�butane with but�2�enes in the presence A. L. Bachurikhin, E. S. Mortikov, 783 721of LaCaX faujasites V. Yu. Gribanov, and

I. A. Abronin

Simulation of optical response to complex formation of crown� Yu. V. Fedorov, O. A. Fedorova, 789 727containing 2�styrylbenzothiazoles with alkaline�earth metals S. P. Gromov, M. B. Bobrovskii,

E. N. Andryukhina, andM. V. Alfimov

The reactivity of 2,2´�bipyridine complexes in the electrochemical D. G. Yakhvarov, E. G. Samieva, 796 734reduction of organohalides D. I. Tazeev, and

Yu. H. Budnikova

Electrocatalytic СО2 reduction in methanol catalyzed by mono�, T. V. Magdesieva, I. V. Zhukov, 805 742di�, and electropolymerized phthalocyanine complexes D. N. Kravchuk,

O. A. Semenikhin,L. G. Tomilova, and K. P. Butin

ESR parameters and transformations of the products I. A. Nuretdinov, V. I. Morozov, 813 750of reduction of methanofullerenes V. P. Gubskaya, V. V. Yanilkin,

L. Sh. Berezhnaya, andA. V. Ilýasov

Copolymerization of acetylene with ethylene in the presence E. F. Kvashina, G. N. Petrova, 817 754of dibenzenetitanium(0) G. P. Belov, O. S. Roshchupkina,

and O. N. Efimov

Effect of conformational rigidity on the glass transition I. A. Ronova, L. B. Eylshina, 820 757and initial decomposition temperatures of polyimides A. N. Vasilyuk, A. L. Rusanov,

and E. G. Bulycheva

Cooperative intramolecular hydrogen bond and conformations V. I. Kovalenko, A. V. Chernova, 825 762of thiocalix[4]arene molecules E. I. Borisoglebskaya,

S. A. Katsyuba, V. V. Zverev,R. R. Shagidullin, I. S. Antipin,S. E. Solovéva, I. I. Stoikov,and A. I. Konovalov


Engl./Russ.

Equilibrium chromatographic characteristics of capillary column V. G. Berezkin, T. P. Popova, 828 765coated with polytrimethylpropyne for separating polar and V. E. Shiryaeva, A. A. Korolev,non�polar organic compounds by gas capillary chromatography and I. V. Malyukova

Organic Chemistry

Cp2TiCl2�Catalyzed hydroalkylation of α�olefins with ButBr—Et3Al I. R. Ramazanov, L. I. Djyachenko, 833 770A. G. Ibragimov, andU. M. Dzhemilev

8�Hydroxyquinolates of trivalent metals as new catalysts S. A. Lermontov, T. N. Velikokhat´ko, 836 773for the reaction of CO2 with epoxides E. Yu. Golovin, and

V. O. Zavel´skii

Photochemistry of benzothiazolylformazanes in solutions L. I. Tkachenko, Yu. E. Semenov, 839 776V. A. Smirnov, S. M. Aldoshin,G. N. Lipunova, andG. I. Sigeikin

Three�component synthesis of 3,4�dihydroisoquinoline derivatives Yu. V. Shklyaev and Yu. V. Nifontov 844 780

Chemistry of acyl(imidoyl)ketenes. 7. Synthesis and thermolysis A. N. Maslivets, N. Yu. Lisovenko, 850 785of 5�aryl�4�quinoxalinyl�2,3�dihydrofuran�2,3�diones O. P. Krasnykh, O. P. Tarasova,

Z. G. Aliev, and L. O. Atovmyan

Application of the Thorpe—Ziegler reaction for the synthesis S. A. Ryndina, A. V. Kadushkin, 854 789of functionalized thiophenes, thienopyrimidines, and thienotriazines N. P. Solovéva, and V. G. Granik

Heterocyclic analogs of pleiadiene. 70. Synthesis I. V. Borovlev, O. P. Demidov, 860 794of 6�hydroxy�1,3�diazapyrenes and A. F. Pozharskii


23�Electron Re6 metal clusters: syntheses and crystal structures N. G. Naumov, E. V. Ostanina, 866 799of (Ph4P)3[Re6S8(CN)6], (Ph4P)2(H)[Re6Se8(CN)6]•8H2O, A. V. Virovets, M. Schmidtman,and (Et4N)2(H)[Re6Te8(CN)6]•2H2O A. Müller, and V. E. Fedorov

Rhenium complexes with pyrazoles. Synthesis and crystal structure M. N. Sokolov, N. E. Fedorova, 872 804of trans�[Re(O)(OMe)L4]Br2•L•4H2O (L is V. E. Fedorov, A. V. Virovets,3,5�dimethylpyrazole) and P. Nuñez

Reactions of the Ru3(CO)10(µ�Ph2PCH2PPh2) cluster with enynes A. A. Koridze, V. I. Zdanovich, 876 807RCH=CHC≡CR (R is phenyl or ferrocenyl). Formation V. Yu. Lagunova, I. I. Petukhova,of indenone derivatives of triruthenium clusters F. M. Dolgushin, Z. A. Starikova,

M. G. Ezernitskaya, andP. V. Petrovskii


Comparative study of horseradish mutant forms by radioenzymology M. A. Orlova, T. A. Chubar´, 887 816O. V. Ignatenko, A. V. Korzhuev,and I. G. Gazaryan


Spirocyclohexadienones. 6. Three�component synthesis V. A. Glushkov, O. G. Ausheva, 894 822of 1�R�3,3�dimethyl�2�azaspiro[4.5]deca�1,6,9�trien�8�ones S. N. Shurov, and

Yu. V. Shklyaev


Engl./Russ.

α�(N�Sulfonylamino)alkylphosphonates F. I. Guseinov and R. N. Burangulova 897 825

Synthesis of sulfur�containing sydnones S. N. Lebedev, I. A. Cherepanov, 899 826and V. N. Kalinin

Regioselective splitting of 3�alkyl�1�ethylaluminacyclopentanes O. S. Vostrikova, E. F. Dekhtyar´, 901 828with orthoformates as a new route to 1�functionalized 4�methylalkanes S. S. Zlotskii, and V. A. Dokichev


Chemiluminescence activated by the Tb3+ ion in (Bui2Al)2O R. G. Bulgakov, S. P. Kuleshov, 904 831

aluminoxane oxidation with dioxygen in toluene A. N. Zuzlov, L. M. Khalilov,and R. R. Vafin

Issue 6, 2002

Reviews

High�resolution and cross�polarization magic angle spinning NMR studies Yu. F. Oprunenko 907 833of tricarbonylchromium complexes with polycyclic aromatic ligands

Role of ligands in homogeneous catalysis based on transition metals W. Keim 930 854


Influence of conditions for preparation of fullerene�containing carbon E. A. Sokolov, S. D. Babenko, 936 860black on its microwave properties and yield of fullerenes D. N. Zakharov, A. P. Moravskii,

N. P. Piven´, B. P. Tarasov,and P. V. Fursikov

Physical Chemistry

Structure and vibrational spectra of mononitroalkanes V. A. Shlyapochnikov, 940 863G. M. Khrapkovskii, andA. G. Shamov

Influence of the size of the formed cycle on the reactivity T. G. Denisova and E. T. Denisov 949 871of free radicals in cyclization reactions

Infrared spectroscopy of hydrogen bond and substituent A. N. Egorochkin and 961 881effects in electron donor molecules O. V. Kuznetsova

Structural organization of phosphorus titanate oxides prepared R. A. Kozlovskii, V. V. Yushchenko, 967 887by the alkoxo method and their catalytic activity L. E. Kitaev, O. V. Bukhtenko,in ethylene glycol oxyethylation A. M. Voloshchuk,

L. N. Vasiléva, andM. V. Tsodikov

Catalytic systems based on platinum and heteropoly compounds N. V. Kirillova, N. I. Kuznetsova, 975 894for oxidation of hydrocarbons with a dioxygen—dihydrogen L. I. Kuznetsova, andgaseous mixture V. A. Likholobov

Interaction of 2,2,6,6�tetramethylpiperidine�1�oxyl chlorite I. M. Ganiev, E. S. Suvorkina, 982 901with alcohols A. V. Igoshina, N. N. Kabalńova,

U. B. Imashev, andG. A. Tolstikov


Engl./Russ.

Femtosecond dynamics of relaxation of photoexcited V. A. Nadtochenko, D. V. Khudyakov, 986 905meso�tetraferrocenylporphyrin in the nonprotonated N. V. Abramova, E. V. Vorontsov,and diprotonated forms (Fc4PH2 and Fc4PH4

2+) N. M. Loim, F. E. Gostev,D. G. Tovbin, A. A. Titov,and O. M. Sarkisov

Luminescence of salts and copolymers containing O. A. Adamenko, G. V. Loukova, 994 913the (MoII

6Cl8)4+ cluster and V. A. Smirnov

N�Dimethoxyphenylation of highly basic pyrazoles V. A. Chauzov, V. Z. Parchinskii, 998 917during undivided electrolysis E. V. Sinel´shchikova,

N. N. Parfenov, andV. A. Petrosyan

Effect of acidity of the medium and polarization of the surface I. V. Sheveleva, V. A. Avramenko, 1006 925on albumin adsorption by carbon fibers and S. Yu. Bratskaya

ESR spectra of products of oxidation of endometallofullerenes S. P. Solodovnikov, B. L. Tumanskii, 1009 928M@C82 (M = Y, La, Ce, Gd) V. V. Bashilov, S. F. Lebedkin,

and V. I. Sokolov

Organic Chemistry

Potentially hexadentate bisazine dioximate ligands: "correct" Ya. Z. Voloshin, O. A. Varzatskii, 1015 933synthetic procedure and encapsulation reactions I. I. Vorontsov, M. Yu. Antipin,of the iron(II) ion and E. Yu. Tkachenko

Reactions of α�fluorine�containing β�functionalized vinyl A. N. Kovregin, A. Yu. Sizov, 1020 938sulfides with N�nucleophiles and A. F. Ermolov

Synthesis of substituted thiophenes based on fluorine�containing A. N. Kovregin, A. Yu. Sizov, 1028 945β�functionalized vinyl sulfides and A. F. Ermolov

Chlorolysis of β�functionalized alkyl polyfluoroalkenyl sulfides A. N. Kovregin, A. Yu. Sizov, 1031 948and A. F. Ermolov

Sulfur ylides. 11. Selected chemical transformations S. N. Lakeev, I. Z. Myllagalin, 1035 951of 1�methylthio�3,4�dihydropyrido[2,1�a]iso� F. Z. Galin, I. O. Maidanova,indole�2,6�dione G. F. Vafina, and G. A. Tolstikov

Activated bis� and tetrafluoroaromatic compounds containing M. L. Keshtov, A. L. Rusanov, 1039 954bis�phenylquinoxaline fragments and S. V. Keshtova

Easy formation of SNH products in reactions of indoles and pyrroles G. V. Zyryanov, V. L. Rusinov, 1042 957

with 3�aryl�1,2,4�triazin�5(2H )�ones in the presence of tosyl chloride and O. N. Chupakhin

Reactions of 2�(2�chloro�4,5�dihydro�3�furyl)�1,3�diphenyl� Yu. G. Trishin, V. I. Namestnikov, 1045 9601,3�diaza�2λ3�phospholidine with nitrile imines and V. K. Belsky


Synthesis and structures of triphenylantimony oximates V. A. Dodonov, A. V. Gushchin, 1051 965D. A. Gor´kaev, G. K. Fukin,T. I. Starostina, L. N. Zakharov,Yu. A. Kurskii, andA. S. Shavyrin


DNA modification by cis�diaminoplatinum(II) complexes V. D. Sen´, A. V. Shugalii, 1058 972with aminonitroxide ligands and A. V. Kulikov



Engl./Russ.

The Mn(acac)3—RCN—CCl4 system as a new efficient reagent R. I. Khusnutdinov, N. A. Schadneva, 1065 979for the oxidation of secondary alcohols into ketones A. R. Baiguzina, and

U. M. Dzhemilev

Reactions of secondary amines with derivatives F. A. Akbutina, S. A. Yumagulova, 1068 982of 5�(2�methyl�3�furyl)cyclopent�2�en�1�one A. A. Fatykhov, and

M. S. Miftakhov

Spectra and structure of mercury derivatives of primary nitramines V. A. Shlyapochnikov, 1071 984N. O. Cherskaya, V. P. Ivshin,D. V. Levchenkov, andA. B. Kharitonkin


Metathetical imidation of dioxobis(dimethyldithiocarbamato)� D. N. Zaroubine, D. S. Holovko, 1075 987molybdenum with o�substituted N�sulfinylanilines and N. A. Ustynyuk

PCP pincer ligands based on metallocenes. Crystal structure A. A. Koridze, A. M. Sheloumov, 1077 988of the rhodium complex S. A. Kuklin, V. Yu. Lagunova,cis�RhCl2(CO)[{2,5�(Pri

2PCH2)2C5H2}Fe(C5H5)] I. I. Petukhova, F. M. Dolgushin,M. G. Ezernitskaya,P. V. Petrovskii,A. A. Macharashvili, andR. V. Chedia

Information 1079 991

Issue 7, 2002

Biomolecular Chemistry

Nucleic acids as subjects of biomolecular chemistry ( foreword to the section) V. V. Vlassov 1081 995

Reviews

Oncogene mRNA imaging with 99mTc�chelator�PNA�peptides E. Wickstrom, X. Tian, P. S. Rao, 1083 997M. L. Thakur, W. Qin, andE. R. Sauter

Design and synthesis of artificial ribonucleases based D. A. Konevetz, I. E. Beck, 1100 1014on 1,4�diazabicyclo[2.2.2]octane and imidazole G. V. Shishkin, V. V. Vlassov,

and V. N. Silnikov

Site�specific synthetic ribonucleases based on oligonucleotide I. Yu. Garipova and V. N. Silnikov 1112 1025conjugates with metal�independent organic catalystsof hydrolysis of phosphodiester bonds

Biological efficacy of antisense oligonucleotides complementary N. N. Dygalo, T. S. Kalinina, 1118 1031to overlapping regions of the mRNA target and G. T. Shishkina

Full Articles

Structure�functional organization of mouse aquaporin 4 gene A. A. Bondar, T. Yu. Alikina, 1122 1035M. N. Zelenina, andS. M. Zelenin


Engl./Russ.

A fast genetic algorithm for RNA secondary structure analysis I. I. Titov, D. G. Vorobiev, 1135 1047V. A. Ivanisenko, andN. A. Kolchanov

Thermodynamic parameters of coaxial stacking on stacking D. V. Pyshnyi and E. M. Ivanova 1145 1057hybridization of oligodeoxyribonucleotides

Hybridization of antisense oligonucleotides with yeast tRNAPhe: R. N. Serikov, V. A. Petyuk, 1156 1067factors determining the efficiency of interaction V. V. Vlassov, and M. A. Zenkova

RNA targeting at any chosen site of interest by the novel H. Kawasaki, T. Kuwabara, 1166 1077RNA�protein hybrid ribozyme and the gene discovery and K. Tairabased on the hybrid ribozyme libraries

Cleavage of a DNA fragment by a binary oligonucleotide reagent S. I. Oshevski 1171 1082

Sequence�specific RNA cleavage by oligonucleotide�peptide N. L. Mironova, D. V. Pyshnyi, 1177 1088conjugates E. M. Ivanova, V. F. Zarytova,

M. A. Zenkova, H. J. Gross,and V. V. Vlassov

Directed cleavage of RNA within an imperfect complementary P. E. Vorobjev, I. A. Pyshnaya, 1187 1097complex by oligonucleotide—bleomycin A5 conjugates E. Wickstrom, and V. F. Zarytova

10�23 DNA enzymes for targeting MDR1 mRNA M. A. Kuznetsova, M. N. Repkova, 1190 1100A. A. Fokina, A. G. Venyaminova,and V. V. Vlassov

Oligoribonucleotides containing an aminoalkyl group at the N(4) M. N. Repkova, 1194 1104atom of cytosine as precursors of new reagents for site�specific M. I. Meshchaninova,modifications of biopolymers T. M. Ivanova, N. I. Komarova,

D. V. Pyshnyi, andA. G. Venyaminova

Sensitized photomodification of oligonucleotide�binding proteins T. I. Gainutdinov, O. E. Shestova, 1198 1108displayed on the eucaryotic cell surface L. A. Yakubov, M. I. Dobrikov,

and V. V. Vlassov

Investigation of surface oligonucleotide�binding proteins B. P. Chelobanov, P. P. Laktionov, 1204 1113of eucaryotic cells by affinity modification with reactive M. V. Khar´kova, E. Yu. Rykova,oligonucleotide derivatives D. V. Pyshnyi, I. A. Pyshnaya,

V. N. Silnikov, and V. V. Vlassov

Acridine�based macrocycles as potential probes for studies Yu. N. Demchenko, E. B. Brossalina, 1212 1120of the structures of nucleic acids M. A. Zenkova, and V. V. Vlassov

Chimeric oligonucleotides based on 2´�O�modified oligoribonucleotides D. S. Novopashina, 1217 1125with the terminal 3´—3´ internucleotide linkage as potential M. A. Kuznetsova,inhibitors of MDR1 gene expression N. I. Komarova, and

A. G. Venyaminova

Physical Chemistry

VALISA: a new procedure for total lineshape analysis of NMR spectra. S. V. Zubkov, S. S. Golotvin, 1222 1129Conformational analysis of trans�1,2�dibromocyclopentane and V. A. Chertkov

Oxidation of ascorbic acid in the presence of phthalocyanine metal E. G. Girenko, S. A. Borisenkova, 1231 1137complexes. Chemical aspects of catalytic anticancer therapy. and O. L. Kaliya1. Catalysis of oxidation by cobalt octacarboxyphthalocyanine

Organic Chemistry

Alkynylhalocarbenes. 4. Generation of (alk�1�ynyl)halocarbenes from K. N. Shavrin, V. D. Gvozdev, 1237 11433�substituted 1,1,1,3�tetrahalopropanes under the action of bases and O. M. Nefedov


Engl./Russ.

Halogenation of 2�alkyl�2�azabicycloalkenes as a method for S. E. Sosonyuk, M. N. Bulanov, 1254 1159the synthesis of stable aziridinium salts of a new class I. F. Leshcheva, and N. V. Zyk

Reactions of nitrogenous derivatives of substituted salicylaldehydes L. Yu. Ukhin, L. V. Belousova, 1262 1167with cyclic ketones and enamines Zh. I. Orlova, S. V. Shishkina,

and O. V. Shishkin

2�Polyfluoroalkylchromones. 10. Synthesis of regioisomeric V. Ya. Sosnovskikh, A. Yu. Sizov, 1270 11753�(2�hydroxyaryl)�5�polyfluoroalkyl� and 5�(2�hydroxy� and B. I. Usachevaryl)�3�polyfluoroalkylisoxazoles and determination oftheir structures by 1H, 19F, and 13C NMR spectroscopy

2�Polyfluoroalkylchromones. 11. Synthesis and structures V. Ya. Sosnovskikh, 1280 1184of 5�hydroxy�3�(2�hydroxyaryl)�5�polyfluoroalkyl� M. A. Barabanov, and∆2�pyrazolines and 3(5)�(2�hydroxyaryl)�5(3)�poly� A. Yu. Sizovfluoroalkylpyrazoles

E—Z�Izomerization of 2�methylenethiazolidin�4�ones Yu. Yu. Morzherin, M. F. Kosterina, 1292 1194V. S. Berseneva, W. Dehaen,and V. A. Bakulev

Aza Diels—Alder reactions of methyl trifluoropyruvate N. M. Kobel´kova, S. N. Osipov, 1298 1199sulfonyl� and phosphorylimines with 1,3�dienes and A. F. Kolomiets

Synthesis of substituted bis(3,3�dialkyl�3,4�di� V. A. Glushkov, V. I. Karmanov, 1303 1204hydro�1�isoquinolyl)methanes and Yu. V. Shklyaev

Synthesis of indole�containing analogs of (1R)�cis�chrysanthemic O. N. Burchak, A. M. Chibiryaev, 1308 1209acid and N�substituted (1R)�cis�chrysanthemylamines and A. V. Tkachev


Chromium arene complexes in synthesis of trans�resveratrol K. E. Polunin, H.�G. Schmalz, 1319 1219and I. A. Polunina


Redox reactions of GeII and SnII dihalides with triethylsilane K. S. Nosov, P. S. Koroteev, 1325 1224and triethylgermane and M. P. Egorov

Synthesis of 1�iodo�1,2,3,4,4a,9a�hexahydrocarbazoles R. R. Gataullin, F. F. Minnigulov, 1329 1227and their isomerization into 3�iodo�2,4�propano� T. V. Khakimova, A. A. Fatykhov,1,2,3,4�tetrahydroquinolines L. V. Spirikhin, and

I. B. Abdrakhmanov

Synthesis of 1,3,5�trisubstituted 1,2,4�triazolio�4�nitroimides A. I. Glushkov, O. P. Shitov, 1332 1229A. V. Mezhenin, andV. A. Tartakovsky


Synthesis of nitrobenzoazacrown compounds by ring S. P. Gromov, S. N. Dmitrieva, 1335 1232transformations of nitrobenzocrown ethers M. V. Churakova, and

A. Yu. Turchanov

Conceivably the first example of a phase transition in aqueous L. O. Kononov, D. E. Tsvetkov, 1337 1233solutions of oligosaccharide glycosides. Evidence from and A. V. Orlovavariable�temperature 1H NMR and optical rotationmeasurements for a solution of allyl lactoside


Engl./Russ.

Synthesis and molecular structure of the first vinylidene complex D. A. Pogrebnyakov, Z. A. Starikova, 1339 1235[Cp(CO)2MnCu(µ�C=CHPh)(µ�Cl)]2 with the Mn—Cu bond N. I. Pavlenko, A. I. Rubailo,

V. A. Sokolenko, O. S. Chudin,and A. B. Antonova

Issue 8, 2002

Reviews

Stereospecific 1,4�cis�hydrogenation of conjugated dienes, dienynes, A. A. Vasilév and E. P. Serebryakov 1341 1237and dienediynes catalyzed by chromium carbonyl complexesin stereocontrolled syntheses of physiologically active olefins

Derivatives of the closo�dodecaborate anion and their application I. B. Sivaev, V. I. Bregadze, 1362 1256in medicine and N. T. Kuznetsov

Exogenous donors of nitric oxide (a chemical aspect) V. G. Granik and N. B. Grigorév 1375 1268

Physical Chemistry

Chemical bonding in isolated molecules and crystals of zwitterionic A. A. Korlyukov, K. A. Lyssenko, 1423 1314pentacoordinate silicon chelates and M. Yu. Antipin

Chain and monomolecular decomposition of hexogen in solutions Yu. Shu, V. V. Dubikhin, 1433 1323V. G. Matveev, G. M. Nazin,and G. B. Manelis

Crown�containing spironaphthoxazines and spiropyrans. O. A. Fedorova, A. V. Koshkin, 1441 13303. Synthesis and investigation of the merocyanine form S. P. Gromov, V. G. Avakyan,of crown�containing spirobenzothiazolinonaphthoxazine V. B. Nazarov, S. B. Brichkin,

T. G. Vershinnikova,T. M. Nikolaeva, L. A. Chernych,and M. V. Alfimov

Copolymerization of propylene oxide with carbon dioxide A. M. Sakharov, V. V. Ilín, 1451 1339catalyzed by zinc adipate V. V. Rusak, Z. N. Nysenko,

and S. A. Klimov

Organic Chemistry

Chemistry of N,N�bis(silyloxy)enamines. 4. Study of the reactions A. V. Ustinov, A. D. Dilman, 1455 1343of N,N�bis(silyloxy)enamines with 1,3�diones S. L. Ioffe, P. A. Belyakov,

and Yu. A. Strelenko

Electrooxidative transformation of unsubstituted and substituted Yu. N. Ogibin, A. I. Ilovaiskii, 1460 1348nitrohydrocarbons into carbonyl compounds V. M. Merkulova,

A. O. Terentév, andG. I. Nikishin

Oxidative coupling of the azide ion with anions of primary I. V. Tselinskii, S. F. Melńikova, 1466 1354nitroalkanes. Synthesis of 1�azido�1�nitroalkanes and S. A. Fedotov

Reaction of bicyclo[2.2.1]hepta�2,5�diene with the arene� N. V. Zyk, E. K. Beloglazkina, 1468 1356sulfenamide—phosphorus(v) oxohalide system: M. A. Belova, I. F. Leshcheva,chemo�, regio�, and steroselectivity and N. S. Zefirov

Stereoselective electrochemical transformation M. N. Elinson, S. K. Feducovich, 1478 1365of 4�substituted cyclohexanones into D. E. Dmitriev, A. S. Dorofeev,cis�5�substituted 2,2�dimethoxycyclohexanols A. N. Vereshchagin, and

G. I. Nikishin


Engl./Russ.

Stereoselective synthesis of cis�4,7�disubstituted N. V. Vorontsova, V. I. Rozenberg, 1483 13694,7�dihydroxy�4,7�dihydro[2.2]paracyclophanes E. V. Vorontsov, D. Yu. Antonov,

Z. A. Starikova, andYu. N. Bubnov

Synthesis of a single isomer of the bis�adduct of isocyanurato� I. P. Romanova, G. G. Yusupova, 1491 1376substituted azide with [60]fullerene A. A. Nafikova, V. I. Kovalenko,

and O. G. Sinyashin

Diastereoselective synthesis of substituted A. V. Shevtsov, V. Yu. Petukhova, 1497 13811,3,6�triazabicyclo[3.1.0]hexanes N. N. Makhova, and

K. A. Lyssenko

Synthesis of carbamoylformhydroxymoyl chlorides V. N. Yarovenko, S. A. Kosarev, 1504 1387and study of their reactivities I. V. Zavarzin, and

M. M. Krayushkin

Photochromic dihetarylethenes. 13. Optimization of conditions M. M. Krayushkin, V. Z. Shirinian, 1510 1392for the acylation of 2,5�dimethylthiophene with squaric L. I. Belen´kii, A. Yu. Shadronov,acid dichloride L. G. Vorontsova, and

Z. A. Starikova

Photochromic dihetarylethenes. 14. Synthesis of symmetrical M. M. Krayushkin, V. Z. Shirinian, 1515 1396and unsymmetrical dihetarylcyclobutene�1,2�diones L. I. Belen´kii, and

A. Yu. Shadronov

New rearrangement of benzo[d]isoxazoles: recyclization A. M. Starosotnikov, 1519 1399of 4�R�6�nitrobenzo[d]isoxazole�3�carbaldehyde V. M. Vinogradov, V. V. Kachala,arylhydrazones into 2�aryl�4�(2�hydroxy�4�nitro� and S. A. Shevelev6�R�phenyl)�1,2,3�triazoles

N�Arylation of azoles with low basicity by 1,4�di� V. A. Chauzov, V. Z. Parchinskii, 1523 1402methoxybenzene during undivided electrolysis E. V. Sinel´shchikova,

A. V. Burasov, B. I. Ugrak,N. N. Parfenov, andV. A. Petrosyan

Nucleophilic substitution in the furazan series. Reactions A. B. Sheremetev, V. O. Kulagina, 1533 1411of nitrofurazans with ammonia I. A. Kryazhevskikh,

T. M. Melnikova, andN. S. Aleksandrova

Reactions of 5�dihydrocotarnyl�1,3�dimethylbarbituric acid K. A. Krasnov, V. G. Kartsev, 1540 1418and other cotarnine derivatives with 1,3�dimethylbarbituric and V. N. Khrustalevacid. X�ray diffraction analysis of a 5,5�spiro derivativeof 1,3�dimethylbarbituric acid

On the reactions of aroylacetonitriles with acetoacetates V. A. Dorokhov, A. V. Vasilyev, 1545 1422S. V. Baranin, O. V. Afanasév,and A. S. Vorushilov

Nitro derivatives of cyclic sulfoximides of the 1,2�benzoisothiazole E. A. Serebryakov and S. G. Zlotin 1549 1426series

Anilinomethylidene derivatives of cyclic 1,3�dicarbonyl compounds V. V. Dotsenko, S. G. Krivokolysko, 1556 1432in the synthesis of new sulfur�containing pyridines and A. N. Chernega, andquinolines V. P. Litvinov

2�Phenyl�1�boraadamantane complexes. Crystal structure M. E. Gurskii, V. A. Ponomarev, 1562 1437and use in the synthesis of cage compounds D. G. Pershin, Yu. N. Bubnov,

M. Yu. Antipin, andK. A. Lyssenko



Engl./Russ.

Reactions between germylenes (silylenes) and phosphaalkenes: B. G. Kimel´, V. V. Tumanov, 1568 1442an experimental and theoretical study. Preparation of the first V. I. Faustov, V. M. Promyslov,representative of germaphosphacyclopropanes M. P. Egorov, and

O. M. Nefedov

Reactions of pyrrole�2,5�dicarbaldehyde with 2�aminodiphenylamine A. Yu. Chernyadyev, Yu. A. Ustynyuk, 1575 1448in the presence of nickel and cobalt trimethylacetates G. G. Aleksandrov, A. A. Sidorov,

V. M. Novotortsev,V. N. Ikorskii, S. E. Nefedov,I. L. Eremenko, and I. I. Moiseev

Formation of cobalt(III) cations with semiquinonediimine ligands I. G. Fomina, A. A. Sidorov, 1581 1453G. G. Aleksandrov, V. N. Ikorskii,V. M. Novotortsev,S. E. Nefedov, andI. L. Eremenko

Metallation of fullerenes: electrochemical synthesis and voltammetric T. V. Magdesieva, D. N. Kravchuk, 1588 1459study of heterometallic C60 and C70 complexes V. V. Bashilov, I. V. Kusnetsova,

V. I. Sokolov, and K. P. Butin

Halo�substituted (S)�N�(2�benzoylphenyl)�1�benzylpyrolidine� Yu. N. Belokon, V. I. Maleev, 1593 14642�carboxamides as new chiral auxiliaries for the asymmetric A. A. Petrosyan, T. F. Saveléva,synthesis of (S)�α�amino acids N. S. Ikonnikov, A. S. Peregudov,

V. N. Khrustalev, andA. S. Sagiyan


New synthesis of serricornin, the sex pheromone of the cigarette M. V. Zlokazov and V. V. Veselovsky 1600 1471beetle (Lasioderma serricorne)

Issue 9, 2002

Reviews

Cationic PdII, NiII, and RuII complexes in the synthesis of G. P. Belov 1605 1475alternating copolymers of СO with vinyl monomers

Single�, double�, and triple�charged cations based on iron� M. I. Rybinskaya, A. Z. Kreindlin, 1616 1485subgroup decamethylmetallocenes and A. A. Kamyshova


Crystalline carbon nitrides: thin films and bulk samples K. P. Burdina, N. B. Zorov, 1633 1501J. I. Kim, O. V. Kravchenko,and Yu. Ya. Kuzyakov

Physical Chemistry

Estimation of dissociation energies of C—H bonds in V. E. Tumanov, E. A. Kromkin, 1641 1508oxygen�containing compounds from kinetic data and E. T. Denisovfor radical abstraction reactions


Engl./Russ.

Nature of Fe—CH2 bonds in ferrocenylmethyl and Yu. A. Borisov, Yu. S. Nekrasov, 1651 1517ferrocenylenedimethyl cations M. I. Rybinskaya, and

A. Z. Kreindlin

Analysis of vibrational spectra of naphthalene, deuterio� B. V. Lokshin, N. E. Borisova, 1656 1521naphthalenes, and chromium (η6�naphthalene)tri� V. M. Senyavin, andcarbonyl based on density functional calculations M. D. Reshetova

Calibration functions in approximate simulations of Yu. K. Tovbin, A. B. Rabinovich, 1667 1531equilibrium adsorption characteristics and E. V. Votyakov

Elution and frontal dynamics of adsorption of organic M. L. Gubkina and N. S. Polyakov 1675 1539substances on activated carbon

Investigation of chemisorption properties M. V. Vinokurov, A. A. Vinokurova, 1680 1543of the PbO surface and L. E. Derlyukova

Gas chromatographic and IR spectroscopic characteristics T. A. Misharina, A. L. Samusenko, 1684 1547of tri� and tetramethylcyclohexenyl butenyl ketones and N. V. Belyaeva

Binding of cyclic compounds by starch cryotextures M. B. Terenina, N. I. Krikunova, 1689 1552from aqueous solutions and T. A. Misharina

Influence of the texture of chromia catalysts on their M. A. Ryashentseva and T. R. Brueva 1694 1556activity in synthesis of 2�methylthiophene

Dehydrogenation of methanol on low Cu and M. A. Ryashentseva, E. V. Egorova, 1698 1559Re—Cu catalysts supported on sibunite A. I. Trusov, and S. N. Antonyuk

Electrocatalytic reduction of organic halides Yu. H. Budnikova, 1702 1562with cobalt bipyridine complexes A. G. Kafiyatullina,

Yu. M. Kargin, andO. G. Sinyashin

Sulfurization of polymers. 6. Poly(vinylene polysulfide), B. A. Trofimov, A. M. Vasil´tsov, 1709 1569poly(thienothiophene), and related structures O. V. Petrova, A. I. Mikhaleva,from polyacetylene and elemental sulfur G. F. Myachina, S. A. Korzhova,

T. A. Skotheim, Yu. V. Mikhailik,and T. I. Vakul´skaya

Crystal structure and fluorescence properties of A. G. Mirochnik, B. V. Bukvetskii, 1715 1574p�nitrobenzoylanisoylmethane and its E. V. Gukhman,complex with boron difluoride P. A. Zhikhareva, and

V. E. Karasev

Organic Chemistry

Synthesis of alkynylbenzo�15�crown�5 ethers S. V. Klyatskaya, E. V. Tretýakov, 1720 1579and S. F. Vasilevsky

Synthesis of new functionally substituted V. P. Gubskaya, N. P. Konovalova, 1723 1582fullerenopyrrolidines I. A. Nuretdinov, G. M. Fazleeva,

L. Sh. Berezhnaya,F. G. Sibgatullina, andI. P. Karaseva

Synthesis of 4�acyl(alkoxycarbonyl)�5�fluoroalkyl� M. V. Pryadeina, Ya. V. Burgart, 1727 15853,5�dihydroxyfuran�2(5H )�ones K. I. Suslova, and V. I. Saloutin

Photochromic dihetarylethenes. 17. Synthesis and M. M. Krayushkin, S. N. Ivanov, 1731 1588photochromic properties of dithienylethenes A. Yu. Martynkin,containing new heterocyclic bridging fragments B. V. Lichitsky, A. A. Dudinov,

L. G. Vorontsova,Z. A. Starikova, andB. M. Uzhinov


Engl./Russ.

Synthesis and hydroxydeamination in the series of E. N. Ulomskii, S. L. Deev, 1737 15946�aryl� and 6�benzoimidazolyl�7�aminoazo� T. S. Shestakova, V. L. Rusinov,lo[5,1�c]�1,2,4�triazines and O. N. Chupakhin

Phosphonioethylation of phenylhydrazine and M. Zh. Ovakimyan, S. K. Barsegyan, 1744 1601hydroxylamine and selected properties A. A. Karapetyan,of the resulting derivatives G. A. Panosyan, and

M. G. Injikian

First quinine�based aryl phosphite: synthesis and O. G. Bondarev, K. N. Gavrilov, 1748 1604application in the Pd�catalyzed enantioselective V. N. Tsarev, V. A. Davankov,rearrangement of allylic thiocarbamate and H.�J. Gais

Synthesis of α,ω�dichloropermethyloligosilanes by reactions A. I. Chernyavskii and 1751 1607of polydimethylsilane with metal chlorides N. A. Chernyavskaya


Selected properties of bi� and trinuclear complexes prepared S. V. Osintseva, F. M. Dolgushin, 1754 1610by the reactions of Ru3(CO)12 with β�substituted P. V. Petrovskii, N. A. Stelzer,oxadienes A. Z. Kreindlin, L. V. Rybin,

and M. I. Rybinskaya


Reactions of (1S,3S)�3�acetoxymethyl�1�(2�acetoxyvinyl)� M. A. Klimkin, O. S. Kukovinets, 1765 16202,2�dimethylcyclopropane with haloforms under V. G. Kasradze, L. V. Spirikhin,conditions of phase�transfer catalysis and F. Z. Galin

Influence of rhenium additives on the activity of Сu/sibunite M. A. Ryashentseva 1768 1622catalyst in transformations of isopropyl alcohol


Reaction of 3�(N�phenylamino)�1�p�tolylprop�2�en�1�one N. A. Stelzer, L. V. Rybin, 1771 1624with Ru3(CO)12 M. I. Rybinskaya,

S. V. Osintseva, P. V. Petrovskii,and F. M. Dolgushin


Issue 10, 2002

Reviews

Fluorinated cyclohexadienones as versatile synthons L. S. Kobrina 1775 1629for preparation of organofluorine compounds

Physical Chemistry

Electron spin and electron nuclear double resonances M. K. Kadirov, B. I. Buzykin, 1796 1650of the stable 1�(4�nitrophenyl)�3�phenyl�1,4�di� and N. G. Gazetdinovahydro�1,2,4�benzotriazin�4�yl free radical


Engl./Russ.

Synthesis and crystal structures of supramolecular adducts O. A. Gerasko, A. V. Virovets, 1800 1654of molybdenum and tungsten selenide aqua complexes M. N. Sokolov, D. N. Dybtsev,with macrocyclic cavitand cucurbituril A. V. Gerasimenko, D. Fenske,

and V. P. Fedin

Organic Chemistry

A new method for synthesis of n�(3�acyloxypropyl)�substituted Yu. N. Ogibin, A. V. Kutkin, 1806 1660six� to thirteen�membered alkan�n�olides A. O. Terentév, and

G. I. Nikishin

Solid�phase oxoalkylation of pyridines and quinolines with G. I. Nikishin, L. L. Sokova, 1812 16661�methylcycloalkanols under the action of lead tetraacetate and N. I. Kapustina

2�Polyfluoroalkylchromones. 12. Nitration of 5,7�dimethyl� V. Ya. Sosnovskikh, B. I. Usachev, 1817 16712�polyhaloalkylchromones and complete assignment of and M. I. Kodesssignals in the 1H and 13C NMR spectra of 5,7�dimethyl�2�trifluoromethylchromone and its mono� anddinitro derivatives

N� and O�Alkylation of 3�indolylcyclopropylacetic E. A. Burakova, O. N. Burchak, 1829 1682acid derivatives and A. M. Chibiryaev

Nitration and bromination of benzo�1,2,3,4�tetrazine O. Yu. Smirnov, A. M. Churakov, 1841 16941,3�dioxides Yu. A. Strelenko, S. L. Ioffe,

and V. A. Tartakovsky

Nucleophilic substitution in benzo�1,2,3,4�tetrazine O. Yu. Smirnov, A. M. Churakov, 1849 17011,3�dioxides A. Yu. Tyurin, Yu. A. Strelenko,

S. L. Ioffe, and V. A. Tartakovsky

Synthesis of 3�carbamoyl�1,2,4�oxadiazoles V. N. Yarovenko, S. A. Kosarev, 1857 1708I. V. Zavarzin, andM. M. Krayushkin

Reactions of cyclic enehydrazino ketones with arylidene� B. V. Lichitsky, D. V. Kozhinov, 1862 1713malononitriles. Synthesis of 11�aryl�1�oxo� V. N. Nesterov,2,3,4,5,10b,11�hexahydro�1H�indolo[2,3�b]quino� L. G. Vorontsova,line�10b�carbonitriles Z. A. Starikova, A. A. Dudinov,

and M. M. Krayushkin

Synthesis of 12�aryl�1�oxo�1,2,3,4,5,12�hexahydro� B. V. Lichitsky, D. V. Kozhinov, 1869 1720indolo[2,1�b]quinazoline�6�carbonitriles by L. G. Vorontsova,recyclization of 11�aryl�1�oxo�2,3,4,5,10b,11�hexa� Z. A. Starikova, A. A. Dudinov,hydro�1H�indolo[2,3�b]quinoline�10b�carbonitriles and M. M. Krayushkin

Simple synthesis of alkyl 5�oxo�5,8�dihydro� A. V. Komkov and V. A. Dorokhov 1875 1726pyrido[2,3�d]pyrimidine�7�carboxylatesfrom 5�acetyl�4�aminopyrimidines

Synthesis of thieno[3,4�d]pyrimidines by the reactions S. A. Ryndina, A. V. Kadushkin, 1879 1730of 3�amino�4�carbamoylthiophene derivatives N. P. Solovéva, and V. G. Granikwith 1,3�dicarbonyl compounds

α�Oxolactam enamines as new synthons V. M. Lyubchanskaya, 1886 1736in the Nenitzescu reaction L. M. Alekseeva, S. A. Savina,

A. S. Shashkov, and V. G. Granik

Synthesis and properties of ferrocenylalkyl derivatives V. V. Gumenyuk, Z. A. Starikova, 1894 1744of indazole Yu. S. Nekrasov, and V. N. Babin


Protonation of ferrocene, ruthenocene, and osmocene: Yu. A. Borisov and N. A. Ustynyuk 1900 1749a density functional study


Engl./Russ.

Specific chemical behavior of NdII and DyII iodides M. N. Bochkarev, A. A. Fagin, 1909 1757in reactions with aromatic compounds and G. V. Khoroshenkov

Synthesis and crystal structure of the nanosized supramolecular D. G. Samsonenko, O. A. Gerasko, 1915 1763SmIII complex with macrocyclic cavitand cucurbituril J. Lipkowski, A. V. Virovets,{[Sm(H2O)4]2(C36H36N24O12)3}Br6•44H2O and V. P. Fedin

First example of the cluster ammine complex Yu. V. Mironov, N. G. Naumov, 1919 1766[Re6Se7Br(NH3)6]3+: synthesis and structure of S. S. Yarovoi, S. Cordier,the [Re6Se7Br(NH3)6][Re6Se7BrBr6]•12H2O salt C. Perrin, and V. E. Fedorov

Synthesis and structures of nickel(II) complexes with A. I. Uraev, V. P. Kurbatov, 1924 1771thioether�containing β�aminovinyl ketones A. L. Nivorozhkin,

L. S. Tylćhenko, V. G. Vlasenko,L. N. Divaeva, K. A. Lyssenko,M. Yu. Antipin, andA. D. Garnovskii

(Arene)ruthenium complexes with the monoanionic A. R. Kudinov, D. S. Perekalin, 1928 1775carborane ligand [9�SMe2�7,8�C2B9H10]– P. V. Petrovskii, and

G. V. Grintselev�Knyazev


A convenient method for the synthesis of cationic glycerolipids M. A. Maslov, N. G. Morozova, 1931 1778with potential biological activity and G. A. Serebrennikova

New method for trimethylsilylation of hydroxy�containing V. N. Odinokov, R. G. Savchenko, 1937 1784compounds. Synthesis of persilylated ecdysteroids S. R. Nazmeeva,and carbohydrates I. V. Galyautdinov, and

L. M. Khalilov

Synthesis of phosphamide conjugates of 5´�mononucleotides I. Yu. Garipova and V. N. Silnikov 1940 1787with carcinine and its analogs

Triterpene glycosides from Pulsatilla chinensis L. I. Glebko, N. P. Krasovskaj, 1945 1792L. I. Strigina, K. P. Ulanova,V. A. Denisenko, andP. S. Dmitrenok

Ubiquinone Q9 from a marine isolate of an T. A. Kuznetsova, A. S. Dmitrenok, 1951 1798actinobacterium Nocardia sp. M. P. Sobolevskaya,

L. S. Shevchenko, andV. V. Mikhailov


2�Polyfluoroalkylchromones. 13. Synthesis and nitration V. Ya. Sosnovskikh and B. I. Usachev 1954 1801of 6,8�dibromo�2�trifluoromethylchromone

Synthesis of novel linear exo�bidentate bispyridine ligands S. Z. Vatsadze, V. N. Nuriev, 1957 1804and their complexes with silver(I) tetrafluoroborate A. V. Chernikov, and N. V. Zyk

Chemical ionization mass spectrometric determination R. S. Borisov and V. G. Zaikin 1959 1806of the configuration of decahydroquinolin�4�ols

A new method for the generation of stable phenoxyl radicals I. S. Orlov, A. A. Moiseeva, 1961 1808by the reaction of [(Me3Si)2N]2E (E = Ge, Sn) K. P. Butin, M. P. Egorovwith sterically hindered phenols

Method for mild trimethylsilylation of the V. N. Odinokov, R. G. Savchenko, 1963 181014α�hydroxy group in ecdysteroids S. R. Nazmeeva, and

I. V. Galyautdinov


Engl./Russ.

Study of alkaloids of the Siberian and Altai flora. 8. Crystal and N. V. Anferova, I. Yu. Bagryanskaya, 1965 1812molecular structure of elatidal methylimine hydrate Yu. V. Gatilov, J. Ganbaatar,

S. A. Osadchii, E. E. Shults,and G. A. Tolstikov


Calix[4]resorcinolarenes with phosphinoylalkyl substituents E. V. Popova, Yu. M. Volodina, 1968 1815on the lower rim of the molecule A. R. Burilov, M. A. Pudovik,

W. D. Habiher, andA. I. Konovalov

Alkynylsulfenylation of alkenes activated by phosphorus N. V. Zyk, E. K.Beloglazkina, 1970 1816oxohalide M. A. Belova, and N. S. Dubinina

Issue 11, 2002

Reviews

Nitric oxide synthase inhibitors: biology and chemistry V. G. Granik and N. B. Grigorév 1973 1819


123Sb NQR and 19F NMR study of potassium, rubidium, V. Ya. Kavun, L. A. Zemnukhova, 1996 1842and cesium heptafluorodiantimonates(III) V. I. Sergienko, T. A. Kaidalova,

R. L. Davidovich, andN. I. Sorokin

Selective reduction of fullerene C60 with metals in neutral A. L. Litvinov, D. V. Konarev, 2003 1849and alkaline media. Interaction of C60 with KOH E. I. Yudanova, M. G. Kaplunov,

and R. N. Lyubovskaya

Physical Chemistry

The use of saturated vapor pressure at standard temperature V. E. Bel´skii 2008 1854in correlations of physicochemical properties

The Mills—Nixon and anomeric effects in 2,3�dihydro� L. S. Khaikin, O. E. Grikina, 2014 18601H�1,3,2�benzodiazaphospholes: a gas�phase electron E. A. Zhilinskaya, B. I. Zhilinskii,diffraction study of C6H4(NMe)2PCl using quantum� and L. V. Vilkovchemical data and "a priori" force field

Concentration dependences of heat conductivity Yu. K. Tovbin and V. N. Komarov 2026 1871coefficients of inert gases in narrow pores

Features of nuclear magnetic relaxation of water and benzene E. V. Khozina, R. Sh. Vartapetyan, 2036 1881molecules during absorption on activaated carbons and and D. Sh. Idiyatullinestimation of pore size distribution in adsorbents

Adsorption of surfactants on superfine magnetite V. V. Korolev, A. G. Ramazanova, 2044 1888and A. V. Blinov

Excited�state intramolecular proton transfer in A. I. Shienok, L. S. Kol´tsova, 2050 18942,4,5�triarylimidazole molecules N. L. Zaichenko, and

V. S. Marevtsev

Dual reactivity of an intermediate cation formed in T. D. Nekipelova, L. N. Kurkovskaya, 2055 1899the photolysis of dihydroquinolines in methanol and I. I. Levina


Engl./Russ.

The influence of the sacrificial anode nature on D. G. Yakhvarov, Yu. G. Budnikova, 2059 1903the mechanism of electrochemical arylation D. I. Tazeev, and O. G. Sinyashinand alkylation of white phosphorus

Electrochemical oxidation of 2H�imidazole N�oxides I. G. Irtegova, V. F. Starichenko, 2065 1910I. A. Kirilyuk, and I. A. Grigorév

Synthesis, acid�base and spectral properties of 3�(benzo� A. A. Karasev, L. L. Lukatskaya, 2070 1915imidazol�2�yl)�2�phenylimino�2H�chromenes M. I. Rubtsov, Z. A. Sizova,

and A. O. Doroshenko

Organic Chemistry

Generation of alkyl hypochlorites in oxidation of alcohols R. I. Khusnutdinov, 2074 1919with carbon tetrachloride catalyzed by vanadium N. A. Shchadneva,and manganese compounds A. R. Baiguzina,

Yu. Yu. Lavrentieva,and U. M. Dzhemilev

Synthesis of β�trifluroacetyl�substituted vinyl sulfones A. L. Krasovsky, V. G. Nenajdenko, 2080 1925and vinyl sulfides and E. S. Balenkova

Metal�dependent stereochemistry Yu. N. Belokon, A. A. Petrosyan, 2086 1931of C—C bond formation under the asymmetric phase V. I. Maleev, T. F. Saveléva,transfer catalysis by chiral salen complexes A. V. Grachev, N. S. Ikonnikov,

and A. S. Sagiyan

New method for the synthesis of indenes V. G. Nenajdenko, D. I. Denisenko, 2090 1935and E. S. Balenkova

Photochromic dihetarylethenes. 18. New approach M. M. Krayushkin, 2097 1942to the synthesis of dithienothiophene and F. M. Stoyanovich,preparation of its photochromic derivative O. Yu. Zolotarskaya,

V. N. Yarovenko,V. N. Bulgakova, I. V. Zavarzin,and A. Yu. Martynkin

Cyclization of O�benzoyl�β�piperidinopropionamidoximes L. A. Kayukova, 2100 1945to form 5�phenyl�3�(β�piperidino)ethyl�1,2,4�oxadiazoles I. S. Zhumadil´daeva, and

K. D. Praliev

Three�component cyclization of hydroxylamino�substituted N. N. Mochul´skaya, L. P. Sidorova, 2106 1951quinoline with reactive methylene compounds and and V. N. Charushinformaldehyde: new method for the synthesis of7�(isoxazolidin�2�yl)�6�fluoroquinolones

Synthesis of 1�(2�polyfluoroacylaminophenyl)�3�polyfluoroalkyl� V. Ya. Sosnovskikh, B. I. Usachev, 2109 1954propane�1,3�diones and 2�polyfluoroalkyl�4�quinolones and A. Yu. Sizov

Indolopyridines containing a bridgehead heteroatom. 12. Synthesis A. T. Soldatenkov, S. A. Soldatova, 2116 1961and reduction of 12�arylidene�5,6�dihydro� M. A. Ryashentseva,indolo[2,1�a]isoquinolinium trifluoroacetates Zh. Ntaganda, O. V. Zvolinskii,

E. N. Smirnova, andM. D. Kharlamova

Study of the reactions of 3�chloro�4�cyanoben� A. S. Ivanov, N. Z. Tugusheva, 2121 1966zo[b][1,6]naphthyridine with nucleophilic reagents N. P. Solovéva, and V. G. Granik

Synthesis of functional 2�substituted 4�phenyl� V. P. Borovik and O. P. Shkurko 2129 19749H�pyrimido[4,5�b]indoles


Alkylation of acetylene by tert�butyl alcohol P. V. Kazakov and E. I. Demina 2134 1978

A convenient synthesis of 3,3,3�trifluoroalanine derivatives A. Yu. Aksinenko, A. N. Pushin, 2136 1979and V. B. Sokolov


Issue 12, 2002


Engl./Russ.

Crystal structure and thermal stability of Ni151.5Pb24S92. A. I. Baranov, A. A. Isaeva, 2139 1983Search for selenium� and tellurium�containing analogs B. A. Popovkin, and

R. V. Shpanchenko

Physical Chemistry

Quantum�chemical study of supramolecular complexes T. S. Zyubina, V. F. Razumov, 2145 1989(DPyEt)n(AgNO3)m S. B. Brichkin, and

V. M. Anisimov

Arylsulfonylation of N�isobutylaniline and its derivatives: T. P. Kustova, I. O. Sterlikova, 2157 2000experimental study and quantum�chemical calculations and M. V. Klyuev

Adsorption of perfluoropropane on the PAC A. A. Fomkin, Yu. V. Nikiforov, 2161 2004microporous carbon adsorbent V. A. Sinitsyn, and E. G. Savelév

Hydrogenation of CO2 to formic acid in the presence N. N. Ezhova, N. V. Kolesnichenko, 2165 2008of the Wilkinson complex A. V. Bulygin, E. V. Slivinskii,

and S. Han

The role of pressure in partial oxidation of methane V. S. Arutyunov 2170 2013

Micelle�forming, liquid�crystalline properties, and catalytic L. Ya. Zakharova, F. G. Valeeva, 2176 2019effect of the mixed cetyltrimethylammonium A. R. Ibragimova,bromide—polyethylene glycol(∼9) monoalkano� L. A. Kudryavtseva, N. N. Valeev,ate(∼14)—water micellar system T. L. Didenko, V. I. Kovalenko,

and A. I. Konovalov

The aggregartion and catalytic activity of amphiphilic I. S. Ryzhkina, Ya. A. Babkina, 2183 2026calix[4]resorcinolarenes and phenols in hydrolysis S. S. Lukashenko, K. M. Enikeev,of phosphonous esters in water—dimethyl� L. A. Kudryavtseva,formamide media and A. I. Konovalov

Formation and properties of a catalyst based on sodium A. A. Volod´kin and G. E. Zaikov 2189 2031and potassium hydroxides in the reaction of2,6�di�tert�butylphenol with methyl acrylate

Dynamics of probe in network of polymeric cation K. V. Shaitan, M. G. Mikhailyuk, 2196 2038exchanger studied by Fourier transform A. S. Plachinda, andanalysis of Mössbauer spectra V. I. Khromov

Spin exchange between transition metal complexes V. A. Livshits, B. B. Meshkov, 2207 2049and nitroxyl radicals in nonaqueous media A. L. Mikhailov, and M. V. Alfimov

ESR study of mechanism of polyaniline conductivity A. V. Kulikov, V. R. Bogatyrenko, 2216 2057O. V. Belonogova, L. S. Fokeeva,A. V. Lebedev, T. A. Echmaeva,and I. G. Shunina

Characteristic features of intra� and intermolecular B. B. Safoklov, E. G. Atovmyan, 2224 2065interactions in crystals of pyrrole�2�carbaldehyde L. A. Nikonova, V. V. Tkachev,isonicotinoyl hydrazone and its hydrate and S. M. Aldoshin

Organic Chemistry

Sulfur ylides. 12. Optically active keto stabilized sulfur S. N. Lakeev, I. Z. Mullagalin, 2230 2071ylide obtained from L�proline: synthesis and study F. Z. Galin, I. O. Maidanova,

and M. F. Abdullin

Synthesis of 1�substituted (R,S)�8�(2�methoxy� Yu. V. Shklyaev, Yu. V. Nifontov, 2234 20755�methylphenyl)�3,3,9�trimethyl�2�azaspi� A. S. Shashkov, and S. I. Firgangro[4.5]deca�1,7�dien�6�ones


Engl./Russ.

One�step synthesis of substituted 2�amino�4H�chromenes and 2�amino� A. M. Shestopalov, 2238 20794H�benzo[ f ]chromenes. Molecular and crystal structure of Yu. M. Emelianova,2�amino�3�cyano�6�hydroxy�4�phenyl�4H�benzo[ f ]chromene and V. N. Nesterov

A practical method for synthesis of stable phosphorus ylides M. R. Islami, I. Yavari, 2244 2084in aqueous media A. M. Tikdari, L. Ebrahimi,

S. Razee, and H. R. Bijanzadeh


Metallation of poly(1�trimethylsilyl�1�prop�1�yne) V. S. Khotimsky and P. V. Pivovarov 2248 2088and poly(vinyltrimethylsilane) with superbases

Synthesis and transformations of metallacycles. A. G. Ibragimov, L. O. Khafizova, 2255 209528. Reactions of allenes with EtAlCl2 and G. N. Gil´fanova, andEt2AlCl catalyzed by Ti and Zr complexes U. M. Dzhemilev

Synthesis and study of organometallic complexes O. V. Malćhugina and P. A. Stuzhin 2261 2101of octaphenyltetraazaporphyrinatoindium(III)

ESR study of weak exchange interactions in binuclear copper(II) V. F. Shul´gin, A. N. Gusev, 2268 2107complexes with 2�hydroxyacetophenone acyldihydrazones V. Ya. Zub, and G. M. Larin

Synthesis and study of binuclear vanadyl complexes with acyl� V. F. Shul´gin, S. M. Zlatogorskii, 2273 2112dihydrazones of salicylaldehyde and dicarboxylic acids V. Ya. Zub, and G. M. Larin

New polyfunctional silicon�containing amines E. Yu. Ladilina, V. V. Semenov, 2277 2115C6[CH2CH2SiMe(OCH2CH2NR2)2]6 T. G. Mushtina, M. A. Lopatin,(R = H, Me) and their reactions with Yu. A. Kurskii, A. I. Kirillov,cobalt(II) chloride and dicobalt octacarbonyl and G. A. Domrachev

Palladium nitrosoarene complexes in reductive T. A. Stromnova and S. T. Orlova 2286 2123carbonylation of nitroarenes


Study of alkaloids of the Siberian and Altai flora. J. Ganbaatar, S. A. Osadchii, 2290 21279. Synthesis of amino derivatives of elatidine E. E. Shults, and G. A. Tolstikov

Steroid polyols from the Far�Eastern starfish E. V. Levina, A. I. Kalinovskii, 2295 2132Henricia sanguinolenta P. V. Andriyashchenko,

V. A. Stonik, andP. S. Dmitrenok


Negative�ion mass spectra of some N�mesyl derivatives S. V. Pikhtovnikov, I. I. Furlei, 2299 2135of o�(cycloalk�2�enyl)�, o�(cycloalk�1�enyl)�, V. K. Mavrodiev, R. R. Gataullino�(pent�2�enyl)�, o�dibromopentylanilines and I. B. Abdrakhmanovand (α�bromoalkyl)indolines

Luminescence of lanthanides in complexes Yu. V. Korovin, N. V. Rusakova, 2303 2138with chromophoric crown ethers and Yu. A. Popkov


The first example of heterolytic fragmentation A. M. Korolev, L. T. Eremenko, 2306 2141of organic nitrates of a heterofunctional series and L. V. Meshikhina

One�pot synthesis of rac�1,2�diphenylethylene�1,2�diamine E. A. Mistryukov 2308 2142

Synthesis and structure of the Co3(µ,η2�OOCBut)2�(µ�OOCBut)4(NEt3)2 T. O. Denisova, F. M. Dolgushin, 2310 2144complex containing a linear metal core and S. E. Nefedov


VII International Conference on the Chemistry of Carbenes and Related Intermediates will beheld on June 23—26, 2003, in Kazan at the A. E. Arbuzov Institute of Organic and PhysicalChemistry of the Kazan Research Center of the Russian Academy of Sciences.

The Conference is organized by the Russian Academy of Sciences, N. D. Zelinsky Institute ofOrganic Chemistry of the RAS, A. E. Arbuzov Institute of Organic and Physical Chemistry of the KazanResearch Center of the RAS, St. Petersburg State University, Russian Foundation for Basic Research,and D. I. Mendeleev Russian Chemical Society.

The scientific program includes the following topics:— generation of carbenes, nitrenes, and carbene analogs;— kinetic, physical and chemical, and theoretical methods for the investigation of carbenes,

nitrenes, and other carbene analogs, and mechanisms of their transformations;— highly strained ring molecules formed by carbene reactions;— chemistry of related intermediates (biradicals, ylides, radical ions of carbene analogs);— complexes of carbenes and their analogs, involvement in catalytic processes;— application of reactions of carbenes, their analogs, and complexes in organic synthesis:

organic/organometallic synthesis, preparation of natural products and other compounds.

The Conference will comprise plenary (50 min) and invited lectures (30 min), as well asshort oral (15 min) and poster presentations.

English will be the official language of the Conference.

VII International Conference on the Chemistry of Carbenesand Related Intermediates

International Advisory Board:

Apeloig Y. (Israel)Doyle M. (USA)Egorov M. P. (Russia)Escudie J. (France)Jutzi P. (Germany)Kira M. (Japan)Lappert M. F. (GB)

Nefedov O. M. (Russia)Platz M. (USA)Schwarz H. (Germany)Walsh R. (GB)Weidenbruch M. (Germany)Wentrup C. (Australia)West R. (USA)

National Organizing Committee:

Chairman Nefedov O. M.

Vice�chairmen: Egorov M. P.Sinyashin O. G.Kostikov R. R.

Budnikova Yu. G.Galkin V. I.Kataeva O. N.Katsyuba S. A.Keshner T. D.

Konovalov A. I.Salikhov K. M.Tomilov Yu. V.Zakhmatov D. Yu.

A more detailed information on the International Conference is available fromProf. O. G. SinyashinA. E. Arbuzov Institute of Organic and Physical Chemistry, 8 ul. Akad. Arbuzova, 420088 Kazan, RussiaTel. +7 (843 2) 72 7424E�mail: [email protected]://carbene.knc.ru

Documents

RUSSIAN CHEMICAL BULLETIN International Edition · Reactions of tautomeric quaternary phosphonium salts based R. A. Khachatrian, S. A. Zalinian, 148 139 on triphenylphosphine and