RSL & MRSL Guidelines - esprit.com · RESTRICTED SUBSTANCES LIST (RSL) FOR RAW MATERIALS/FINISHED PRODUCTS Substance CAS NO. Limit Detection Limit Test Method Dyes – Allergenic

RSL & MRSL Guidelines

http://www.esprit.com/press/rsl.pdf

RESTRICTED SUBSTANCES LIST (RSL) FOR RAW MATERIALS/FINISHED PRODUCTS_2018

Substance CAS NO. Limit Detection Limit Test Method

Acetophenone and 2-Phenyl-propan-2-ol

Acetophenone 98-86-2 <50 mg/kg 10 mg/kg Extraction in acetone, sonication for 30 min at 60 degrees C, analysis with GC/MS 2-Phenyl-2-propanol 617-94-7 <50 mg/kg 10 mg/kg

Alkylphenols (AP) and Alkylphenols Ethoxylates (APEOs), including all isomers*

Nonlyphenol (NPs), mixed isomers Various

Not Detected

10 mg/kg Extraction: 1g sample/20 ml THF sonication for 60 minutes at 70 degrees C. Octylphenol (OPs), mixed isomers Various

Nonylphenol Ethoxylates (NPEOs) Various 50 mg/kg

Textile: EN ISO 18254-1:2016 Leather: EN ISO 18218-1:2015 Octylphenol Ethoxylates (OPEOs) Various

*Recycle wool is exempt.

Chlorinated Paraffins

Short-Chain chlorinated Paraffins (SCCP) (C10-C13) 85535-84-8 <100 mg/kg 50 mg/kg Combined CADS/ISO 18219:2015 method V1:06/17 Extraction: ISO 18219 and analysis by GC-NCI-MS. Medium-Chain chlorinated Paraffins (MCCP) (C14-C17) 85535-85-9 <1000 mg/kg 100mg/kg

Chloro Phenols

Pentachlorophenol (PCP) 87-86-5

0.5 mg/kg each

0.05 mg/kg each

1M KOH extraction,12-15 hours at

90 degrees C, derivatization and analysis

§ 64 LFGB B 82.02-08 or

DIN EN ISO 17070:2015

2,3,4,5-Tetrachlorophenol 4901-51-3



2,3,4-Trichlorophenol 15950-66-0






Dichlorophenols various

Monochlorophenols various

RESTRICTED SUBSTANCES LIST (RSL) FOR RAW MATERIALS/FINISHED PRODUCTS


Chloro Organic Carriers (COCs)

Chlorobenzene 108-90-7

Sum<1,0 mg/kg 0,1 mg/kg DIN 54232:2010

1,2-Dichlorobenzene 95-50-1



1,2,3-Trichlorobenzene 87-61-6



1,2,3,4-Tetrachlorobenzene 634-66-2



Pentachlorobenzene 608-93-5

Hexachlorobenzene 118-74-1

2-Chlorotoluene 95-49-8



2,3-Dichlorotoluene 32768-54-0





2,3,6-Trichlorotoluene 2077-46-5

2,4,5-Trichlorotoluene 6639-30-1

2,3,4,5-Tetrachlorotoluene 76057-12-0



Pentachlorotoluene 877-11-2



Dyes – Allergenic Disperse Dyes

Disperse Blue 1 2475-45-8

<50 mg/kg each 15 mg/kg DIN 54231:2005








Disperse Orange 1 2581-69-3



Disperse Orange 37/76/59 12223-33-5 13301-61-6 51811-42-8


Disperse Brown 1 23355-64-8

Disperse Red 1 2872-52-8




Disperse Yellow 1 119-15-3








Dyes - Navy Blue Colorants

Component 1: C39H23ClCrN7O12S·2Na 118685-33-9 Not Detected 15 mg/kg DIN 54231:2005

Component 2: C46H30CrN10O20S2·3Na Not allocated



Dyes - Carcinogenic Dyes

Acid Red 26 3761-53-3

<50 mg/kg each 15 mg/kg DIN 54231:2005

Basic Red 9 569-61-9

Basic Violet 14 632-99-5

Basic Blue 26 2580-56-5


Basic Green 4 (oxalate, chloride or free) 2437-29-8/569-64-2/ 10309-95-2

Direct Black 38 1937-37-7

Direct Blue 6 2602-46-2

Direct Red 28 573-58-0

Direct Brown 95 16071-86-6

4-Dimethylaminoazobenzene (Solvent Yellow 2) 60-11-7

Solvent Blue 4 6786-83-0

4,4'-bis(dimethylamino)-4''-(methylamino)trityl alcohol 561-41-1

Carcinogenic Arylamines (Free available or cleavage from dyestuff) o-Toluidine 95-53-4

<15 mg/kg each 5 mg/kg

Textile: DIN EN 14362-1:2017 (with and without extraction)

Leather: DIN EN ISO 17234-1:2015

4-Aminoazobenzene:

Textile: DIN EN 14362-3:2017


2,4-Xylidine 95-68-1

2,6-Xylidine 87-62-7

o-Anisidine (2-Methoxyaniline) 90-04-0

p-Chloroaniline 106-47-8

p-Cresidine 120-71-8

2,4,5-Trimethylaniline 137-17-7

4-Chloro-o-toluidine 95-69-2

2,4-Toluylendiamine 95-80-7

2,4-Diaminoanisole 615-05-4

2-Naphthylamine 91-59-8

2-Amino-4-nitrotoluene 99-55-8

4-Aminobiphenyl 92-67-1

4-Aminoazobenzene 60-09-3

4,4'-Oxydianiline 101-80-4

Benzidine 92-87-5

4,4'-Diaminobiphenylmethane 101-77-9

o-Aminoazotoluene 97-56-3

3,3'-Dimethyl-4,4'-diaminobiphenylmethane 838-88-0

3,3'-Dimethylbenzidine 119-93-7

4,4'-Thiodianiline 139-65-1

3,3'-Dichlorobenzidine 91-94-1

4,4'-Methylene-bis-(2-chloroaniline) 101-14-4

3,3'-Dimethoxybenzidine 119-90-4


Substance CAS No. Limit Detection Limit Test Method

Flame Retardants

Hexabromocyclododecane (HBCDD) 25637-99-4 3194-55-6

Not Detected 5 mg/kg

EN ISO 17881-1 & 2:2016

Tetrabromodiphenylether (tetraBDE) 40088-47-9

Pentabromodiphenylether (pentaBDE) 32534-81-9

Hexabromodiphenylether (hexaBDE) 36483-60-0

Heptabromodiphenylether (heptaBDE) 68928-80-3

Hexabromobiphenyl 36355-01-8

Octabromodiphenylether (octaBDE) 32536-52-0

Nonabromodiphenylether (nonaBDE) 63936-56-1

Decabromodiphenylether (decaBDE) 1163-19-5

2,2-Bis(bromomethyl)propan-1,3-diol (BBMP) 3296-90-0

Bis(2,3-dibromopropyl)phosphate (BIS) 5412-25-9

Pentabromobenzene 608-90-2

Polybrominated Biphenyles (PBB) 59536-65-1

Tris(2,3-dibromopropyl)phosphate (TRIS) 126-72-7

Tris(aziridinyl)phosphine oxide (TEPA) 545-55-1

Tetrabromobisphenol A (TBBP A) 79-94-7

Tetrabromobisphenol-A-bis (2,3-dibromopropylether) (BDBPT)

21850-44-2

1,2-Bis(pentabromophenyl)ethane (EBP) 84852-53-9

Triphenylphosphate (TPhP) 115-86-6

Tricresylphosphate (TCP) 1330-78-5

Tris(2-chloroethyl)phosphate (TCEP) 115-96-8

Tris(1,3-dichloroisopropyl)phosphate (TDCPP) 13674-87-8

Tris(2-chloro-1-methylethyl) phosphate (TCPP) 13674-84-5

Trixylyl phosphate (TXP) 25155-23-1

Formaldehyde

Formaldehyde 50-00-0 <75 mg/kg 16 mg/kg Leather: EN ISO 17226-2:2008 with UV-Vis

Textile: DIN EN ISO 14184-1:2011 with UV-Vis



Heavy Metals - Extractable

Textile Leather

Antimony (Sb) 7440-36-0 <30 mg/kg <30 mg/kg 1.0 mg/kg

Textile: DIN EN ISO 16711-2:2016


Arsenic (As) 7440-38-2 <0,2 mg/kg <0,2 mg/kg 0,1 mg/kg

Barium (Ba) 7440-39-3 <1000 mg/kg <1000 mg/kg 50 mg/kg

Cadmium (Cd) 7440-43-9 <0,1 mg/kg <0,1 mg/kg 0,05 mg/kg

Chromium (Cr) 7440-47-3 <1,0mg/kg <200 mg/kg Textile: 0,5 mg/kg Leather: 1.0 mg/kg

Cobalt (Co) 7440-48-4 <1,0 mg/kg <1,0 mg/kg 0,5 mg/kg

Copper (Cu) 7440-50-8 <25,0 mg/kg <25,0mg/kg 5,0 mg/kg

Lead (Pb) 7439-92-1 <0,2mg/kg <0,2 mg/kg 0,1 mg/kg

Mercury (Hg) 7439-97-6 <0,02 mg/kg <0,02 mg/kg 0,02 mg/kg

Nickel (Ni) 7440-02-0 <1,0 mg/kg <1,0 mg/kg 0,5 mg/kg

Selenium (Se) 7782-49-2 <500 mg/kg <500 mg/kg 50 mg/kg

Chromium VI (Cr VI) 18540-29-9 <0,5 mg/kg <3,0 mg/kg Textile: 0,5 mg/kg Leather: 3.0 mg/kg

Textile: GB/T 17593-3:2006 Leather: DIN EN ISO 17075:2015

Heavy Metals - Total

Cadmium (Cd) 7440-43-9 <40 mg/kg

10 mg/kg DIN EN 16711-1:2016 Lead (Pb) 7439-92-1 <90 mg/kg

Arsenic (As) 7440-38-2 ≤100 mg/kg

Mercury (Hg) 7439-97-6 <10 mg/kg



Isocyanate

Methylenediphenyl diisocyanate (MDI) 101-68-8 Not Detected 5 mg/kg DIN EN ISO 10283:2007

Nickel release

Nickel release 7440-02-0 <0,5 µg/cm²/week articles in skin contact

<0,1 µg/cm²/week EN 12472:2005 + A1:2009 and DIN EN 1811:2015

N-Nitrosamines

N-nitrosodimethylamine 62-75-9

<0,5 mg/kg each 0.5 mg/kg each GB/T 24153, determination using GC/MS and further confirmation with LC/MS/MS

N-nitrosodiethylamine 55-18-5

N-nitrosodiproylamine 621-64-7

N-nitrosodibutylamine 924-16-3

N-nitrosopiperidine 100-75-4

N-nitrosopyrrolidine 930-55-2

N-nitrosomorpholine 59-89-2

N-nitroso-N-methylaniline 614-00-6

N-nitroso-N-ethylaniline 612-64-6

Organotin Compounds

Monobutyltin (MBT) various

<0,5 mg/kg each 0.2 mg/kg each CEN ISO/TS 16179:2012

Dibutyltin (DBT) various

Tributyltin (TBT) various

Tricyclohexyltin (TCyHT) various

Trioctyltin (TOT) various

Triphenyltin (TPhT) various

Tripropyltin (TPT) various

Trimethyltin (TMT) various

Dioctyltin (DOT) various

Dimethyltin (DMT) various

Diphenyltin (DPT)

various

Monooctyltin (MOT) various

Methyltin (MT) various

Tetrabutyltin (TEBT) various

Trimethyltin (TMT) various

Other Banned Amine

p-Phenylenediamine 106-50-3 <50 mg/kg 15 mg/kg DIN EN ISO 14362-1:2017



Perfluorinated Compounds (PFCs)

PFOS and its derivates

1763-23-1, 2795-39-3, 29457-72-5, 29081-56-9 70225-14-8, 56773-42-3 251099-16-8

Not Detected 1 ug/m² DIN CEN/TS 15968

PFOA and its derivates

335-67-1, 3825-26-1, 335-95-5, 2395-00-8, 335-93-3, 335-66-0, 376-27-2, 3108-24-5

Perfluorobutanoic acid (PFBA) 375-22-4

Perfluoropentanoic acid (PFPeA) 2706-90-3

Perfluorohexanoic acid (PFHxA) 307-24-4

Perfluoroheptanoic acid (PFHpA) 375-85-9

Perfluorooctane sulphonamide (PFOSA) 754-91-6

N-Methyl-heptadecafluorooctane sulfonamide (N-Me-FOSA) 31506-32-8

N-Ethyl-heptadecafluorooctane sulfonamide (N-Et-FOSA) 4151-50-2

N-Methyl-heptadecafluorooctane sulfonamidoethanol (N-ME-FOSE) 24448-09-7

N-Ethyl-heptadecafluorooctane sulfonamidoethanol (N-ET-FOSE) 1691-99-2

Perfluorononanoic acids (PFNA)

various

Perfluorododecanoic acids (PFDA) various

Henicosafluoroundecanoic acid (PFUdA) 2058-94-8

Tricosafluorododecanoic acid (PFDoA) 307-55-1

Pentacosafluorotridenoic acid (PFTrDA) 72629-94-8

Heptacosafluorotetradecanoic acid (PFTeDA) 376-06-7



Pesticides, Agriculture

See Appendix A for a complete list Various <0,5 mg/kg each <0,5 mg/kg each Extraction with organic solvent, analysis with GC/MS according to DIN 38407-37.

PVC - Cause of Carcinogenic Vinyl Chloride

PVC 75-01-4 Usage ban N.A. If Beilstein Test positive, should be further analysed by FT-IR.

Phthalates

Bis-(2-ethylhexyl) phthalate (DEHP) 117-81-7

<50 mg/kg each

50 mg/kg EN ISO 14389:2014

CPSC-CH-C1001-09.3

Dibutyl phthalate (DBP) 84-74-2

Benzylbutyl phthalate (BBP) 85-68-7

Diisononyl phthalate (DINP) 28553-12-0

Diisodecyl phthalate (DIDP) 26761-40-0

Dioctyl phthalate (DNOP) 117-84-0

Diisobutyl phthalate (DIBP) 84-69-5

Di-C6-8 branched alkyl phthalate (DIHP) 71888-89-6

Di-C7-11 branched alkyl phthalate (DHNUP) 68515-42-4

Di-n-Hexyl phthalate (DnHP) 84-75-3

Bis(2-methoxyethyl) phthalate (DMEP) 117-82-8

Dipentyl phthalate (n-, iso, or mixed) (DPP) 131-18-0, 605-50-5, 776297-69-9

Dicyclohexyl phthalate (DCHP) 84-61-7

Dihexyl phthalate branched and linear (DHxP) 68515-50-4

Diisohexyl phthalate (DIHxP) 71850-09-4

Dimethyl phthalate (DMP) 131-11-3 Sum <1000mg/kg

Diethyl phthalate (DEP) 84-66-2

1,2-Benzenedicarboxylic acid, dipentylester, branched and linear (DPP) 84777-06-0 < 500 mg/kg

RESTRICTED SUBSTANCES LIST (RSL) FOR RAW MATERIALS/FINISHED PRODUCT


Polycyclic Aromatic Hydrocarbons (PAHs)

Benzo[a]pyrene 50-32-8

<0,5 mg/kg each

0,2 mg/kg AfPS GS 2014:01 PAK

Benzo[e]pyrene 192-97-2

Benz[a]anthracene 56-55-3

Benzo(b)fluoranthene 205-99-2

Benzo[j]fluoranthene 205-82-3

Benzo[k]fluoranthene 207-08-9

Chrysene 218-01-9

Dibenz[a,h]anthracene 53-70-3

Benzo[ghi]perylene 191-24-2

Indeno[1,2,3-cd]pyrene 193-39-5

Acenaphthylene 208-96-8

Sum <10,0 mg/kg

Acenaphthene 83-32-9

Anthracene 120-12-7

Fluorene 86-73-7

Fluoranthene 206-44-0

Phenanthrene 85-01-8

Pyrene 129-00-0

Naphthalene 91-20-3 < 2,0 mg/kg

Sum of above 18 PAH’s <10,0 mg/kg

Cyclopenta[c,d]pyrene 27208-37-3

<1,0 mg/kg each

Dibenz[a,e]pyrene 192-65-4

Dibenz[a,h]pyrene 189-64-0

Dibenz[a,i]pyrene 189-55-9

Dibenz[a,l]pyrene 191-30-0

1-Methylpyrene 2381-21-7

Acidic and Alkaline Substances

pH-Value

Textile: with skin contact: 4,0 - 7,5

without skin contact: 4,0 - 9,0 Textile: EN ISO 3071:2005

Leather: 3,0 - 8,5 Leather: EN ISO 4045: 2018


Substance CAS-No. Limit Detection Limit Test Method

Preservative Agents

Triclosan 3380-34-5 <10 mg/kg 5 mg/kg Extraction with organic solvent, analyzed by GC/MS or LC-MS

Dimethylfumarate 624-49-7 <0,1 mg/kg 0.1 mg/kg DIN CEN ISO/TS 16186:2012

2-Thiocyanomethylthiobenzothiazol (TCMTB) 21564-17-0 <500 mg/kg 100 mg/kg ISO 13365:2011

o-Phenylphenol (OPP) 90-43-7 <500 mg/kg 10 mg/kg ISO 13365:2011

PCB and PCT

Halogenated terphenyls including polychlorinated terphenyls (PCT)

various

Not Detected 1 mg/kg DIN ISO EN 15318

Halogenated biphenyls including polychlorinated biphenyls (PCB)

various

Solvents

N,N-Dimethylformamide (DMFa) 68-12-2 <300 mg/kg 10 mg/kg DIN CEN ISO/TS 16189:2013

Formamide 75-12-7 <200 mg/kg 15 mg/kg Extraction with organic solvent, analyzed by GC/MS.

Volatile Organic Compounds (VOCs)

Benzene 71-43-2 <5 mg/kg

1 mg/kg

General VOC Screening:

GC-MS Headspace 45 mins at 120°C

Carbon tetrachloride 56-23-5

Total: 1000 mg/kg

Chloroform 67-66-3

1,2-Dichloroethane 107-06-2

1,1-Dichlorethylene 75-35-4

Dimethylacetamide (DMAC) 127-19-5

Pentachloroethane 76-01-7

1,1,1,2- Tetrachloroethane 630-20-6

1,1,2,2- Tetrachloroethane 79-34-5

Tetrachloroethylene (PER) 127-18-4

Toluene 108-88-3

1,1,1- Trichloroethane 71-55-6

1,1,2- Trichloroethane 79-00-5

Trichloroethylene 79-01-6

Xylenes (meta-, ortho-, para-) 1330-20-7

Substance CAS No.

Chemical Supplier Commercial Formulation

Limit General Techniques for Analyzing Chemicals

Detection Limit for Formulations

Wastewater Testing

(Raw Wastewater) Status of Elimination Textile &

Synthetic. Leather Processing

Leather Processing

Standard Test Method

Reporting Limit

(in µg/L)

Alkylphenols (AP) and Alkylphenols Ethoxylates (APEOs) including all isomers

Nonylphenol (NP), mixed isomers

104-40-5 11066-49-2 25154-52-3 84852-15-3

250 ppm

GC-MS/LC-MS

50 ppm

ISO 18857-2 (modified dichloromethane extraction) or ASTM D7065 (GC/MS or LC/MS(-MS)

5

No intentional use.

Banned since July 2013.

Octylphenol (OP),

mixed isomers

140-66-9 1806-26-4 27193-28-8

Nonylphenol ethoxylates (NPEO) 9016-45-9 26027-38-3 37205-87-1 68412-54-4 127087-87-0

500 ppm

100 ppm

(n>2): ISO 18254-1;

(n=1,2): ISO 18857-2 or ASTM D7056

Octylphenol ethoxylates (OPEO) 9002-93-1 9036-19-5 68987-90-6

Substance CAS No.




Wastewater Testing



Leather Processing


Reporting Limit

(in µg/L)

Dyes – Disperse (Sensitizing)


250 ppm Not applicable

LC 50 ppm Liquid extraction, LC/MS 50 ppm Phase-out by 1 January, 2020.


Disperse Blue 35 12222-75-2 56524-77-7






Disperse Orange 37/59/76 13301-61-6

Disperse Brown 1 23355-64-8









Substance CAS No.




Wastewater Testing



Leather Processing


Reporting Limit

(in µg/L)

Dyes - Navy Blue Colorants

Component 1: C39H23ClCrN7O12S·2Na

118685-33-9

250 ppm LC 50 ppm No intentional use. Banned already before 2012. Component 2:

C46H30CrN10O20S2·3Na Not allocated

Dyes - Carcinogenic or Equivalent Concern

Direct Black 38 1937-37-7

250 ppm LC

200 ppm

Phase out by 1 January 2020.

Direct Blue 6 2602-46-2

Acid Red 26 3761-53-3

Liquid extraction, LC/MS 500

Basic Red 9 569-61-9

Direct Red 28 573-58-0


Basic Green 4 (oxalate, chloride or free)

2437-29-8 569-64-2 10309-95-2

Basic Blue 26 2580-56-


50 ppm Disperse Blue 1 52475-45-8


Substance CAS No.




Wastewater Testing



Leather Processing


Reporting Limit

(in µg/L)

Dyes – Azo (Forming Restricted Amines)

4,4'-methylene-bis- (2-chloroaniline)

101-14-4

150 ppm LC, GC, GC/MS 50 ppm

EN 14362-1

EN 14362-3

Reduction step with sodiumdithionite, solvent extraction, GC/MS or LC/MS.

0.1 No intentional use. Banned since March 2016.

4,4’methylenedianiline 101-77-9

4,4'oxydianiline 101-80-4

4-chloroaniline 106-47-8

3,3'dimethoxylbenzidine 119-90-4

3,3'-dimethylbenzidine 119-93-7

6-methoxy-m-toluidine 120-71-8

2,4,5-trimethylaniline 137-17-7

4,4'-thiodianiline 139-65-1

4-aminoazobenzene 60-09-3

4-methoxy-m-phenylenediamine 615-05-4

4,4'-methylenedi-o-toluidine 838-88-0

2,6-xylidine 87-62-7

o-anisidine (2-Methoxyaniline) 90-04-0

2-naphthylamine 91-59-8

3,3'-dichlorobenzidine 91-94-1

4-aminodiphenyl 92-67-1

Benzidine 92-87-5

o-toluidine 95-53-4

2,4-xylidine 95-68-1

4-chloro-o-toluidine 95-69-2

4-methyl-m-phenylenediamine 95-80-7

o-aminoazotoluene (Solvent Yellow 3)

97-56-3

5-nitro-o-toluidine 99-55-8

Substance CAS No.




Wastewater Testing



Leather Processing


Reporting Limit

(in µg/L)

Chlorobenzenes and Chlorotoluenes (“Chloro Organic Carriers”, COCs)

1,2-dichlorobenzene 95-50-1 1000 ppm

GC-MS

100 ppm

USEPA 82608, 8270D.

Dichloromethane extraction followed by GC/MS.

0.2

Not intentional use.


Monochlorobenzene 108-90-7

Sum = 200 ppm

1,3-dichlorobenzene 541-73-1

1,4-dichlorobenzene 106-46-7

1,2,3-trichlorobenzene 87-61-6



1,2,3,4-tetrachlorobenzene 634-66-2



2-chlorotoluene 95-49-8



2,3-dichlorotoluene 32768-54-0






2,3,4-trichlorotoluene 7359-72-0





2,3,4,5-tetrachlorotoluene 76057-12-0



Pentachlorotoluene 877-11-2

Any other isomers of mono-, di-, tri-, tetra-, penta- and hexa-chlorobenzene and mono-, di-, tri-, tetra- and penta-chlorotoluene

Substance CAS No.


Limit General Techniques

for Analyzing Chemicals


Wastewater Testing



Leather Processing


Reporting Limit

(in µg/L)

Chlorophenols

Tetrachlorophenol (TeCP) 25167-83-3 Sum = 20 ppm

GC-MS

EN ISO 17070

10 ppm

USEPA 8270 D.

Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC/MS.

ISO 14154:2005

0.5


Pentachlorophenol (PCP) 87-86-5

2-chlorophenol 95-57-8

Sum = 50 ppm



2,3-dichlorophenol 576-24-9






2,3,4-trichlorophenol 15950-66-0






2,3,4,5-tetrachlorophenol 4901-51-3



Substance CAS No.




Wastewater Testing



Leather Processing


Reporting Limit

(in µg/L)

Flame Retardants

Tris(2-chloroethyl)phosphate (TCEP)

115-96-8

250 ppm

250 ppm

GC-MS

50 ppm

US EPA 8270,

ISO 22032,

USEPA 527 and USEPA 8321B.

Dichloromethane extraction GC/MS or LC/MS(-MS)

5

No intentional use. Banned already

before 2012.

Decabromodiphenylether (DecaBDE)

1163-19-5

Tris(2,3-dibromopropyl)phosphate (TRIS)

126-72-7

Pentabromodiphenylether (PentaBDE)

32534-1-9

Octabromodiphenylether (OctaBDE)

32536-52-0

Bis(2,3-dibromopropyl)phosphate (BIS)

5412-25-9

Tris(aziridinyl)phosphine oxide (TEPA)

545-55-1

Polybromobiphenyles (PBB) 59536-65-1

Tetrabromobisphenol A (TBBP A) 79-94-7

Hexabromocyclodecane (HBCDD) 3194-55-6

2,2-bis(bromomethyl)-1,3-propanediol (BBMP)

3296-90-0

Tris(1,3-dichloro-isopropyl)phosphate (TDCP)

13674-87-8 50 ppm (textile & synth. Leather)

250 ppm (leather) Short-chain chlorinated Paraffins (SCCP) (C10-C13)

85535-84-8 50 ppm

Substance CAS No.





Wastewater Testing (Raw Wastewater)

Status of Elimination Textile &


Leather Processing


Reporting Limit

(in µg/L)

Glycols

Bis(2-methoxyethyl)-ether 111-96-6

50 ppm

50 ppm

HPLC, LC-MS 50 ppm

US EPA 8270

Liquid extraction, LC/MS

GC-MS

50 Phase out by 1 January 2020.

2-ethoxyethanol 110-80-5

2-ethoxyethyl acetate 111-15-9

Ethylene glycol dimethyl ether 110-71-4

2-methoxyethanol 109-86-4

2-methoxyethylacetate 110-49-6

Triethylene glycol dimethyl ether 112-49-2

2-methoxypropylacetate 70657-70-4 1000 ppm

Halogenated Solvents

1,2-dichloroethane 107-06-2

5 ppm GC-MS

5 ppm

US EPA 8260B

Headspace GC/MS or Purge-and-Trap-GC/MS


Methylene chloride 75-09-2

Tetrachloroethylene 127-18-4

Trichloroethylene 79-01-6 40 ppm 40 ppm

Substance CAS No.




Wastewater Testing (Raw Wastewater)

Status of Elimination Textile &


Leather Processing


Reporting Limit

(in µg/L)

Organotin Compounds

Dibutyltin (DBT) 20 ppm

20 ppm (exception: 100 ppm for poly-urethane based thickeners used at < 20 % loading)

GC-MS, LRMS 5 ppm

ISO 17353.

Derivatisation with NaB(C2H5)

GC/MS

0,01 Phase out by 1 January 2020.

Mono-, di-, and tri-methyltin derivatives

various

5 ppm Mono-, di-, and tri-butyltin derivatives

various

Mono-, di-, and tri-phenyltin derivatives

various

Mono-, di-, and tri-octyltin derivatives

various

Substance CAS No.




Wastewater Testing



Leather Processing


Reporting Limit

(in µg/L)

Polycyclic Aromatic Hydrocarbons (PAHs)

Benzo[a]pyrene (BaP) 50-32-8 20 ppm

GC-MS

5 ppm

US EPA 8270

DIN 38407-39

Solvent extraction GC/MS


Benzo[e]pyrene 192-97-2

Sum = 200 ppm

Sum = 200 ppm 20 ppm

Benz[a]anthracene 56-55-3

Benzo[b]fluoranthene 205-99-2

Benzo[j]fluoranthene 205-82-3

Benzo[k]fluoranthene 207-08-9

Chrysene 218-01-9

Dibenz[a,h]anthracene 53-70-3

Benzo[ghi]perylene 191-24-2

Indeno[1,2,3-cd]pyrene 193-39-5

Acenaphthylene 208-96-8

Acenaphthene 83-32-9

Anthracene 120-12-7

Fluorene 86-73-7

Fluoranthene 206-44-0

Phenanthrene 85-01-8

Pyrene 129-00-0

Naphthalene 91-20-3 300 ppm GC-MS, LC

Substance CAS No.





Wastewater Testing



Leather Processing


Reporting Limit

(in µg/L)

Perfluorinated Compounds (PFCs)

PFOS and related substances Various Sum = 2 ppm

LC-MS 1 ppm

0.01

No intentional use. Eliminated from production since December 2014.

PFOA and related substances Various Sum = 2 ppm

PFOS 355-46-4 432-50-7

Sum = 2 ppm

DIN 38407-42 (modified)

Ionic PFC: Concentration or direct injection, LC/MS(-MS)

Non-ionic PFC (FTOH): Derivatisation with acetic anhydride followed by GC/MS

PFOA 335-67-1 Sum = 2 ppm

PFBS 29420-49-3 29420-43-3

PFHxA 307-24-4

8:2 FTOH 678-39-7

1

6:2 FTOH 647-42-7

Substance CAS No.





Wastewater Testing



Leather Processing


Reporting Limit

(in µg/L)

Phthalates – including all esters of ortho-phthalic acid

Bis-(2-ethylhexyl) phthalate (also: Di(ethylhexylphthalate) (DEHP)

117-81-7

Sum of all phthalates

= 250 ppm GC-MS 100 ppm

US EPA 8270D,

ISO 18856

Dichloro-methane extraction GC/MS


Bis(2-methoxyethyl) phthalate (DMEP)

117-82-8

Di-n-octyl phthalate (DNOP) 117-84-0

Di-iso-decyl phthalate (DIDP) 26761-40-0

Di-isononyl phthalate (DINP) 28553-12-0

Di-n-hexyl phthalate (DnHP) 84-75-3

Dibutyl phthalate (DBP) 84-74-2

Butyl benzyl phthalate (BBP) 85-68-7

Dinonyl phthalate (DNP) 84-76-4

Diethyl phthalate (DEP) 84-66-2

Di-n-propyl phthalate (DPRP) 131-16-8

Di-isobutyl phthalate (DIBP) 84-69-5

Di-cyclohexyl phthalate (DCHP) 84-61-7

Di-iso-octyl phthalate (DIOP) 27554-26-3

Di-C7-11 branched alkyl phthalate (also: 1,2-benzenedicarboxylic acid, di-C7-11-branched and linear alkyl esters) (DHNUP)

68515-42-4

Di-C6-8 branched alkyl phthalate (also: 1,2-benzenedicarboxylic acid, di-C6-8-branched alkyl esters, C7-rich) (DIHP)

71888-89-6

Substance CAS No.





Wastewater Testing



Leather Processing


Reporting Limit

(in µg/L)

Heavy Metals

Arsenic (As) 7440-38-2 50 ppm

ICP-OES, AAS

For leather:

Cr (III) tanning agents can be monitored for Cr (VI); EN ISO 17075 (current use), ISO/DIS 19071 (draft)

10 ppm

EN ISO 11885

USEPA 200.7, USEPA 200.8, USEPA 6010c, USEPA 6020a

0.05

Phase-out by 1 January 2020.

Cadmium (Cd) 7440-43-9 20 ppm (50 ppm for pigments) 0.1

Lead (Pb) 7439-92-1 100 ppm 0.1

Chromium (VI) 18540-29-9 10 ppm EN ISO 18412

USEPA 218.6

0.05

Mercury (Hg) 7439-97-6 4 ppm (25 ppm for pigment) 2 ppm

ENISO 18412 or ISO 17852

USEPA 200.7, USEPA 200.8, USEPA 6010c, USEPA 6020a

0.01

Volatile Organic Compounds (VOCs)

Benzene 71-43-2 50 ppm

GC-MS 20 ppm

ISO 11423-1

Headspace- or Purge-and-Trap-GC/MS

US EPA 8260


o-cresol 95-48-7

500 ppm p-cresol 106-44-5

m-cresol 108-39-4

Xylenes (meta-, ortho-, para-) 1330-20-7 100 ppm

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Designation or Abbreviation Explanation

CAS No. (= CAS Registry Number®) A unique number by which only one chemical substance can be identified on an international level.

Detection Limit The minimum concentration of a substance that can be measured and reported with 99 % confidence that the analyte concentration is greater than zero.

Esprit products Apparel, footwear and accessories

mg/kg Unit for defining mass fraction (mass portion) of a chemical substance.

N.D. Not detectable.

µg/L Unit for defining the mass concentration of a chemical substance.

ppm Unit for defining the concentration of a chemical substance = 1 part per 1 million parts = 10−6

= 1 Teil pro Million = 0,0001 %

(It is only approximately the same as mg/l.)

Reporting Limit Lowest concentration that can be reliably achieved within specified limits of precision and accuracy during routine laboratory operating conditions. Good laboratory practice dictates that a reporting limit is 10 times the Detection Limit, taking into consideration variability associated with analyzing samples from a wide variety of sources with many potential complicating factors, e.g. matrix effects.

ZDHC Zero Discharge of Hazardous Chemicals Program (http://www.roadmaptozero.com/)

Pesticide Name CAS NO. Pesticide Name CAS NO. Pesticide Name CAS NO.

DDT 1,1,1-Trichlor-2,2-bis-(4-chlorophenyl)-ethane and isomers

50-29-3 Dicofol 115-32-2 Mirex 2385-85-5

DDD 53-19-0, 72-54-8

Dicrotophos 141-66-2 Monocrotophos 6923-22-4

DDE 3424-82-6, 72-55-9

Dimethoate 60-51-5 Nitenpryam 120738-89-8, 150824-47-8

Acetamiprid 135410-20-7, 160430-64-8

Endrin 72-20-8 Parathion 56-38-2

Aldicarb 116-06-4 Endosulfan and its isomers

115-29-7, 959-98-8, 33213-65-9

Parathionmethyl 298-00-0

Aldrin 309-00-2 Esfenvalerate 66230-04-4 Pentachloroanisole 1825-21-4

Azinophosmethyl 86-50-0 Ethylendibromid 106-93-4 Profenophos 41198-08-7

Azinophosethyl 2642-71-9 Fenvalerate 51630-58-1 Quinalphos 13593-03-8

Bromophosethyl 4824-78-6 Heptachlor 76-44-8 Quintozene 82-68-8

Captafol 2425-06-1 Heptachlor epoxide 1024-57-3 Strobane 8001-50-1

Carbaryl 63-25-2 Hexachlorocyclohexane (-HCH)

608-73-1 2,4,5-T (Acetic acid, (2,4,5-trichlorophenoxy)-)

93-76-5

Chlorbenzilat 510-15-6 Hexachlorobenzene 118-74-1 2,4,5-TP (Propanoic acid, 2-(2,4,5-trichlorophenoxy)-)

93-72-1

Dinoseb and salts 88-85-7 Imidacloprid 138261-41-3, 105827-78-9

Thiacloprid 111988-49-9

Dinotefuran 16525-70-0 Isobenzan (Telodrin) 297-78-9 Thiamethoxam 153719-23-4

DTTB 63405-99-2 Isodrin 465-73-6 Tolylfluanide 731-27-1

2,4-D 94-75-7 Kelevan 4234-79-1 Trifluralin 1582-09-8

DEF (Tribufos) 78-48-8 Lead hydrogen arsenate

7784-40-9 Halogenated naphthalenes (PCNs) various

Deltamethrin 52918-63-5 Malathion 121-75-5 Monomethyl-tetrachlorodiphenyl methane

76253-60-6

Diazinon 333-41-5 MCPA 94-74-6 Monomethyl-dichlorodiphenyl methane 81161-70-8

Dibromchlorpropan (DBCP)

96-12-8 MCPB 94-81-5 Monomethyl-dibromo-diphenyl methane 99688-47-8

Dieldrin 60-57-1 Mecoprop 93-65-2 Toxaphene 8001-35-2

Diclofluanide 1085-98-9 Metamidophos 10265-92-6

Dichlorprop 120-36-5 Methoxychlor 72-43-5

Documents

RSL & MRSL Guidelines - esprit.com · RESTRICTED SUBSTANCES LIST (RSL) FOR RAW MATERIALS/FINISHED PRODUCTS Substance CAS NO. Limit Detection Limit Test Method Dyes – Allergenic