REVIEW OF SEEP SAMPLE, DYE SEEP SAMPLE, & WATER … · 2019. 11. 25. · selenium results for the dye seep sample should be considered ftR10008l* Ciba-Geigy Samples Analytical Review

DESIGNERS/CONSULTANTS

5 Underwood Court Phone: 609-461-4003Delran, NJ 08075 Fax: 609-461-4916

TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RESPONSE REMOVAL AND PREVENTIONEPA CONTRACT 68-WO-0036

MEMORANDUM

TO: Terry Stilman, OSC, EPA Region III TDD #9303-02Eastern Response Section PCS #4326

THRU: Mike Zickler, TATL, Region III

FROM: Marian Murphy, TAT Region III

SUBJECT: Ciba-Geigy Samples Analytical Review

DATE: April 7, 1993

This report covers the general review of one (1) seep sample, one(1) dye seep sample and one (1) water sample collected at the Ciba-Geigy Site on March 10, 1993. All samples were collected induplicate and sent to the laboratory as blind samples. The sampleswere received at 21st Century Environmental on March 11, 1993. Theanalyses requested were as follows: biphenyl and biphenyl ether(diphenyl ether) on the seep sample; base neutrals and acidextractables (BNA) plus pyridine, and priority pollutant metalsplus molybdenum for the dye seep and water samples.

ANALYTICAL METHODOLOGY

The BNA plus pyridine samples were analyzed in accordance with EPAMethod 8270. The priority pollutant metals plus molybdenum wereanalyzed in accordance with SW846 methodologies. The sedimentsample for biphenyl and biphenyl ether were analyzed using amodified EPA Method 8015 with a GC/FID (flame ionization detector) .

Signed chain-of -custody records were received.

The GC/MS tune data and internal standard data wereacceptable. The initial calibration and continuing hadseveral outliers, however, no data was affected. Theholding times for the water samples were met, but thesediment samples were extracted outside holding times.All dye seep results should be considered approximate.The surrogate spike recoveries, matrix spike/matrix spikeduplicate recoveries and relative percent difference(RPD) values were acceptable. The method blank for thewater samples was free of contamination. The method

Roy F. Weston, Inc.MAJOR PROGRAMS DIVISIONIn Association with Foster Wheeler Enviresponse, Inc., Resource Applications, Inc., C.C. Johnson & Malhotra, P.C.,R.E. Sarriera Associates, and GRB Environmental Services, Inc.

& R I Q Q Q 8 3

Ciba-Geigy Samples Analytical ReviewApril 7, 1993Page 2

blank for the dye seep samples contained 50 ug/Kg bis(2-ethylhexyl)phthalate. The results for bis(2-ethylhexyl)phthalate should be considered not detected in the dyeseep samples. The duplicate results for both the dyeseep and water samples were acceptable.

The calibration data for the biphenyl and biphenyl ethersamples was acceptable. The method blank was free ofcontamination. The holding times for the samples wereexceeded, therefore, all results should be consideredapproximate. The surrogate spike recoveries were dilutedout due to the dilution required to bring the analyteswithin the calibration range, however no data wasqualified. The matrix spike/matrix spike duplicaterecovery and the RPD values were acceptable.

• The metals calibration data was acceptable. The holdingtimes were met. The method blanks were free ofcontamination. The matrix spike recoveries for the watersamples were acceptable except for cadmium and lead,which were both high. No water samples were qualifiedfor spike data. The matrix spike recoveries for the dyeseep were acceptable for all compounds except arsenic,selenium and thallium. The recoveries were low for allcompounds. Arsenic and selenium results should beconsidered approximate; thallium was not found,therefore, no data was qualified. The ICP serialdilution for lead for the dye seep did not meet criteria,therefore, all lead data should be consideredapproximate. The results of the field duplicates forwater were acceptable. The results for the dye seep werereasonable due to the nonhomogeneity of the matrix of thesample. The RPD values were acceptable for all samplesexcept lead in the water samples. Lead for the watersamples should be considered approximate.

CONCLUSION

Accept the data as presented with the following exception: The dyeseep BNA results should be considered approximate due to holdingtime violations. The bis(2-ethylhexly)phthalate results for thedye seep samples should be considered not detected due to blankcontamination.

The lead results for the dye seep samples should be consideredapproximate since the ICP serial dilution did not meet criteria.The lead results for the water samples should be consideredapproximate since the RPD values exceeded 20%. The arsenic andselenium results for the dye seep sample should be considered

ftR10008l*

Ciba-Geigy Samples Analytical ReviewApril 7, 1993Page 3

approximate, due to poor spike recoveries. The biphenyl andbiphenyl ether results should be considered approximate due toholding times being exceeded.

MM/mr

A R J 0 0 0 8 5

618 HERON DRIVE P.O. BOX 489 • BRIDGEPORT, NJ 08014-0489 • 609-467-9521

WESTON

PROJECT: CIBA ASSESSMENT

ANALYSIS NO;

A 1214

A 1215

A 1216

A 1217

A 1218

A 1219

CLIENT ID;

S-l

S-1A

S-2

S-2A

tf-1

W-1A

BATE RECEIVED: MARCH 11, 1993

TWENTY FIRST CENTURYENVIRONMENTAL, INC.

RICHARD V. LYNCHLABORATORY MANAGER

LICENSED ANALYTICAL LABORATORY #08031 A R I 0 0 0 8 6

NAKKATIVE

The following notes apply to the analysis of Samples A1214 and A1215 (Client IDS-l and S-1A) for Biphenyl and Phenyl Ether:

1. These samples were analyzed using a direct injection method of sampleextracts on a 30m x 0.32 mm x 0.25um OV-5 capillary column. The GCtemperature program was modified to yield.the best resolutionpossible on this column between the two analytes of interest. Thisprogram consisted of the following:

INITIAL TEMP: 40°CINITIAL HOLD: 4 MIN

RATE: 5°C/MIN.FINAL TEMP: 200°C

Complete resolution of the analyte components was difficult at highconcentrations due to the minute differences of these components.

2. Samples were anticipated to be extremely contaminated, therefore asimple methanol extraction— 5g:10mL— was performed on each sample.Massive dilutions (200000X) in methanol were necessary due to theextent of analyte contamination. Consequently all surrogate standardsand matrix spike standards were diluted out.

3. A modified matrix spike was performed, however, using additions ofspiking standard directly into the final sample dilution. Althoughthis may not determine the efficacy of sample extraction, it doesindicate that the target analytes are indeed Biphenyl and Phenyl Ether.The results for this MS/MSD were excellent and indicated that the rangeof linearity extended beyond the upper calibration range of 0.5 ug for eachcomponent.

4. Samples were confirmed by GC/MS.

Samples A1216 and A1217 are reported on a wet weight basis due to matrix.

ARI00087

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.cid Extractables D.S.E.P.A. Method 625 - Thisse Neutrals method covers the determination

of a number of organic compoundsthat are partitioned in anorganic solvent and amenable togas chromatography. This is a gaschromatography/mass spectrometer(GC/MS) method applicable to thedetermination of the compounds listedin the U.S.E.P.A. Manual entitled"Test Procedures for theAnalysis of Organic Pollutants".

A HP5970 was used with a DB-5FSCC.

Method detection limits are asstated.

Soil samples were prepared foranalysis as prescribed in Method3550 and analyzed as prescribedin Method 8270 from SW846.

|tals Soil samples for metal analysiswere run in accordance withthe methods prescribed in SW846.This includes a nitric aciddigestion followed by eitherFurnace, Flame Atomic Absorption,Flameless Atomic Absorption, orInductively Coupled Plasma analysis.

Aqueous samples for metalsanalysis were run in accordancewith the methods prescribed inMethods for Chemical Analysis ofWater and Wastes, EPA-600-4-79-020 March 1983.

AR100089

LABORATORY CHRONICLE

RECEIPT/REFRIGERATION

ORGANICSEXTRACTION

1. Acids

3/11/93

3/17/93-3/19/93

2. Base/Neutrals____________

3. Pesticides/PCBf s/Herbicides

3/17/93-3/19/93

NA

4. Petroleum Hydrocarbons /Oil & Grease

ANALYSIS

1. Volatiles

NA

NA

2. Acids 3/23/93-3/24/93

3. Base/Neutrals_____________

4. Pesticides/PCB's/Herbicides

3/23/93-3/24/93

NA

5. Petroleum Hydrocarbons/Oil & Grease___NA_

6. Total Organic Carbon_______________NA

Section SupervisorReview & Approval

INORGANICS

1. Metals 3/16/93-3/30/93

2. Cyanides_

3. Phenols__

OTHEK. ANALYTES

Mercury

NA

NA

3/16/93-3/23/93

Section SupervisorReview & ApprovalQuality Control SupervisorReview & ApprovalLaboratory DirectorReview & Approval

If fractions are re-extracted and re-analyzed because itercial endeavors did not meetquality control acceptance criteria, include dates for both.

ARI00090

RESULT SUMMARY

A R I O Q 0 9 1

CERTIFICATE OF ANALYSIS

BIPHENYL/PHENYL ETHER

ANALYSIS NO: A 1214

CLIENT ID: S-l

PARAMETER MDL (ppm) RESULT (ppm)

BIPHENYL 2000 3080

PHENYL ETHER 2000 14400

O21ST CENTURY ENVIRONMENTAL • NJDEPE CERTIFICATI



ANALYSIS NO: A 1215

CLIENT ID: S-1A

PARAMETER

BIPHENYL

PHENYL ETHER

MDL (ppm)

2000

2000

RESULT (ppm)

6400

27200

21ST CENTURY ENVIRONMENTAL • NJDEPE CERTIFICATION #08038 n I Q Q'Q"S"3"

21ST CENTURY EnvironmentalSEMIVOLATILE ANALYSIS DATA

JOG NUMBERSAMPLE NUMBERCLIENT IDDATA FILE

A1216 UESTONS-2

>C0792

MATRIXDILUTION FACTORQA BATCHDATE ANALYZED

Soil1.00

03/23/93

mnmmummmmmmmu*

COMPOUND UG/KG MDL COMPOUND IE/KG MDL

N-Nitrosoditethylaiine ND 330Phenol 290 J 330bi5(-2-Chloroethyl)Ether ND 3302-ChoIorophenol ND 3301.3-Dichlorobenzene ND 3301.4-Dichlorobenzene 220 J 330Benzyl Alcohol ND 3301,2-Dichlorobenzene 2600 3302-ttethylphenol ND 330bis(2-chloroisopropyl)Ether ND 3304-hethylphenol ND 330N-Nitroso-Di-n-Propyla«ine ND 330Hextchloroethane ND 330Nitrobenzene ND 330Isophorone ND 3302-Nitrophenol ND 3302,4-Dinethylphenol ND 330Benzoic Acid ND 1600bis(-2-Chloroethoxy)Methane ND 3302,4-Dichlorophenol ND 3301,2,4-Trichlorobenzene 64 J 330Naphthalene 50 J 3304-Chloroaniline ND 330Hexachlorobutadiene ND 3304-Chloro-3-Methyiphenol ND 3302-fte thy[naphthalene ND 330Hexachlorocyclopentadiene ND 3302,4,6-Trichloroplwnol ND 3302,4.5-TrichlorophenoI ND 16002-Chloronaphttwltne ND 3302-Nitroaniline ND 1600Dimethyl Phthalate ND 330Acenaphthylene ND 3303-Nitroaniline ND 330

Acenaphthene2,4-Dinitrophenol4-NitrophenoIDibenzofuran2,4-Dinitrotoluena2,6-DinitrotolueneDiethylphthalate4-Ch loropheny1-phenlyetherFluorene4-Nitroaniline4,6-Oinitro-2-MethylphenolN-Nit rosod iphenylamine4-Bromophenyl-phenyletherHexachlorobenzenePentachlorophenolPhenanthreneAnthraceneDi-n-ButylphthalateFluoranthenePyreneButylbenzylphthalate3,3'-DichIorobenzidineBenzo(a)AnthraceneBis(2-Ethylhexyl)PhthalateChryseneDi-n-Octyl PhthalateBenzo(b)FluorantheneBenzo(k)FluoranthenaBenzo(a)PyreneIndeno(1,2,3-cd)PyreneDibenzo(a,h)AnthraceneBenzo(g,h,i)PeryleneBenzidinePyridine

mm**:

68NDND37NDNDNDND56NDNDNDNDNDND38083ND450370NDND24058260NDND23021013057140NDND

J

J

J

j

JJBJ

JJJJJ

33016001600330330330338338330168016003383303301600338330330330330338660330330330330330330330330330330660330

Percent Solid of 100. is used for all Target compounds.

(J) Indicates detected below MDL(B) Indicates also present in blank(ND) Indicates compound not detected

AR-I0009I*

- ,.E1aemi-UOLATILE ORGAN*! CS ANALYSIS DATA SHEET

TENTATIUELY IDENTIFIED COMPOUNDS

EPA SAMPLE NUMBER

Matrix: (soil/water) SOIL

Sample wt/vol: 30 (g/mL) GM

Level: LOW

% Moisture: 100

Extraction: (Sepf/Cont/Sonc) SONC

GPC < Y or N ): N

Column: DB-5

Number TICs Found 19

I WESTONI_______

Lab Sample ID: A1216

Lab File ID: >C0792

Date Received: NA

Date Analyzed 03/23/93

Date Extracted NA

Dilution Factor: 1

CONCENTRATION(ug/L or ug/K

rsUG/KG

CAS NUMBER

1234 60447195 1731262867891011 629440212131415161718 9252419 101848

COMPOUND NAME

UNKNOWN SUBSTITUTED ALKANEUNKNOWNUNKNOWNDodecane, 6-methyl- (8CI9CI)Decane, 5-propyl- (8CI)UNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWNCyclohexane, l-bromo-4-methy 1- C8CI9CI)UNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWNl,l'-Biphenyl C9CI)Benzene, l,l'-oxybis- (9CI)

11 RT1

1112.83113.41113.58113.79113.93114.03114.43114.50114.57114.70115.05115.13115.29115.39115.86116.23116.58116.65117.011

1IEST CONC1

11 3701 4301 13001 12001 4001 4001 5301 5301 5001 15001 3701 19001 4301 5301 19001 19001 37001 63001 240001

A R I O O Q 9 5

21ST CENTURY EnvironmentalSEHIUOLATILE ANALYSIS DATA

JOB NUMBERSAMPLE NUMBER A1217 UESTQNCLIENT ID S-2ADATA FILE >C0793

MATRIX SoilDILUTION FACTOR 1.00OA BATCHDATE ANALYZED 03/24/93

COMPOUND

N-NitrosodiMthylaiinePhenolbis(-2-Chloroethyl)Ether2-Cholorophenol1 ,3-Dich lorobenzene1,4-OichlorobenzeneBenzyl Alcohol1,2-Dichlorobenzene2-Hethylphenolbis(2-chloroisopropyl)Ether4-HethylphenolN-Nitroso-Di-n-PropylaiineKexachloroethaneNitrobenzeneIsophorone2-Nitrophenol2,4-DinethylphenolBenzole Acidb is (-2-Ch loroethoxy ) Methane2,4-Dichlorophenol1 ,2 ,4-Tr ich lorobenzeneNaphthalene4-ChloroanilineHexach lorobu tad iene4-Ch loro-3-ttethy Ipheno 12-KethylnaphthaleneHexachlorocyclopentadiene2,4,6-Trichlorophenol2,4.5-Trichlorophenol2-Chloronaphth*lena2-NitroanilineDiaethyl PhthalateAcenaphthylene3-Nit roan i line

UG/KG

ND570NDNDND100 JND

1300NDNDNDNDNDNDNDNDNDNDNDNDND190 JNDNDND56 JNDNDNDNDNDNDNDND

MX

3303303303303303303303303303303303303303303303383301600330330330330330330330330330330160033016003303301600

COMPOUND

Acenaphthene2,4-Oinitrophenol4-NitrophenolDibenzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDiethylphthalate4-Ch loropheny 1-phen lyetherFluorene4-Nitroaniline4,6-Dinitro-2-MethylphenolN-Ni t rosod ipheny laiine4-BroMphenyl-phenyletherHexach lorobenzenePentachlorophenolPhenanthreneAnthraceneDi-n-ButylphthalateFluoranthenePyreneButylbenzylphthalate3,3'-DichlorobenzidineBenzo (a) AnthraceneBis(2-Ethylhexyl)PhthalateChryseneDi-n-Octyl PhthalateBenzo (b )FluorantheneBenzo (k )FluorantheneBenzo(a)PyreneIndeno ( 1 ,2 ,3-cd )PyreneDibenzo(a,h)AnthraceneBenzo (g,h,i)Pery IeneBenzidinePyridine

UG/KG

190 JNDND110 JNDNDNDND180 JNDNDNDNDNDND940230 JND

1000850NDND54059 JB550ND390360410230 JND220 JNDND

MDL

33016001600330330330330330330160016003303303301600330330330330330330660330330330330330330330330330330660330



ARI00096

semi-UQLATILE ORGAN ICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS

EPA SAMPLE NUMBER

I II UESTON II_________I


Sample wt/vol: 30 Cg/mL) GM

Leve1: LOW

X Moisture: 100


GPC ( Y or N ): N

Column: DB-5

Number TICs Found 4


Lab File ID: >C0793

Date Received: NA


Date Extracted NA

Dilution Factor: 1

CONCENTRATION UhWfS*N(ug/L or ug/Kg/UG/KGJ

\ICAS1

11 11 21 3I 41

!NUMBER 1

1

179345 1

192524 1101848 1

1

COMPOUND NAME

Ethane, 1 , 1 ,2 ,2-tet rach loro- (8CI9CI)UNKNOWNl,l'-Biphenyl C9CI)Benzene, l,l'-oxybis- (9CI)

11 RT1

11 8.32115.11116.63116.961

1EST CONCI

1— —— —— - 1

1770 1600 12300 17300 1

1

ARI00097


PRIORITY POLLUTANT PLUS MOLYBDENUM

ANALYSIS NO: A 1218

CLIENT ID: W-l

METALS

ANTIMONY

ARSENIC

BERYLLIUM

CADMIUM

CHROMIUM

COPPER

LEAD

MERCURY

MOLYBDENUM

NICKEL

SELENIUM

SILVER

THALLIUM

ZINC

MDL (ng/L) RESULT (ag/L)

0.05

0.005

0.01

0.01

0.01

0.01

0.005

0.0005

0.013

0.05

0.005

0.01

0.01

0.01

N.D.

N.D.

N.D.

N.D.

N.D.

0.01

0.009

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

0.39

21ST CENTURY ENVIRONMENTAL • NJDEPE CERTIFICATION #08031fl P j Q Q Q Q Q

21ST CENTURY EnvironmentalSEMIUOLATILE ANALYSIS DATA

JOB NUMBERSAMPLENUMBER .CLIENT IDDATA FILE

A1218 UESTONU-l

>C0790


Water1.00

03/23/93

COMPOUND UG/L IDL COMPOUND UG/L

N-Nitrosodiwthyla«ine ND 10Phenol ND 10bis(-2-Chloroethyl)Ether ND 102-Cholorophenol ND 101.3-Dichlorobenzene ND 101.4-Dichlorobenzene ND 10Benzyl Alcohol ND 101,2-Dichlorobenzene 4.6 J 102-Methylphenol NO 10bis(2-chloroisopropyl)Ether ND 104-Methylphenol ND 10N-Nitroso-Di-n-Propylaiins ND 10Hexachloroethane ND 10Nitrobenzene ND 10Isophorone ND 102-Nitrophenol ND 102,4-Diiethylphenoi ND 10Benzole Acid ND 50bis(-2-Chloroethoxy)Methene ND 102,4-DichlorophenoI ND 101,2,4-Trichlorobenzene ND 10Naphthalene ND 104-Chloroaniline 2.1 J 10Hexachlorobutadiene ND 104-Chloro-3-Nethylphenol ND 102-Methylnaphthalene ND 10Hexachlorocyclopentadiene ND 102,4,6-Trichlorophenol ND 102,4.5-Trichlorophenol ND 902-Chloronaphthalene ND 102-Nitroaniline ND 50DiMthyl Phthalate ND 10Acenaphthylene ND 103-Nitroaniline ND 90


MDL

Acenaphthene ND 102,4-Dinitrophenol ND 904-Nitrophenol ND 90Dibenzofuran ND 102,4-Dinitrotoluene ND 102,6-Dinitrotoluene ND 10Diethylphthalate ND 104-Chlorophenyl-phenlyether ND 10Fluorene ND 104-Nitroaniline ND 904,6-Dinitro-2-Nethylphenol ND 90N-Nitrosodiphenyla«ine ND 104-BroMphenyl-phenylether ND 10Hexachlorobenzene ND 10Pentachlorophenol ND 90Phenanthrene ND 10Anthracene ND 10Di-n-Butylphthalate ND 10Fluoranthene ND 10Pyrene ND 10Butylbenzylphthalate ND 103,3'-Dichlorobenzidine ND 20Benzo(a)Anthracene ND 10Bis(2-Ethylhaxyl)Phthalate ND 10Chrysene ND 10Di-n-Octyl Phthalate ND 10Benzo(b)Fluoranthene ND 10Benzo(k)Fluoranthene ND 10Benzo(a)Pyrene ND 10Indeno(l,2,3»cd)Pyrene ND 10Dibenzo(a,h)Anthracene ND 10Benzo(g,h,i)Perylene ND 10Benzidine ND 20Pyridine ND 10

AR100099

Elsemi-VOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDS

EPA SAMPLE NUMBER

Matrix: (soil/water) WATER

Sample wt/vol: 1000 (g/mL) ML

LeveI: LOW

% Moisture: 100

Extraction: (Sepf/Cont/Sonc) SEPF

GPC < Y or N >: N

Column: DB-5

Number TICs Found 4

II WESTONI_______


Lab File ID: >C0790

Date Received: NA


Date Extracted NA

Dilution Factor: 1

CONCENTRATION UHlTS~"N(ug/L or ug/KdO UG/LJ

V ^^^^

CAS

1234

NUMBER

827543101848

11 COMPOUND1

11 UNKNOWN1 UNKNOWN1 Naphthalene1 Benzene, 1,1

NAME

, 2-ethenyl- (9CI)I'-oxybis- (9Cn

1RT 1 EST

1

I3.4818.32116.63116.941

1

1CONCI

1

14 12 12 1

11 11

A R I O O I O O



ANALYSIS NO: A 1219

CLIENT ID: W-1A

METALS

ANTIMONY

ARSENIC

BERYLLIUM

CADMIUM

CHROMIUM

COPPER

LEAD

MERCURY

MOLYBDENUM

NICKEL

SELENIUM

SILVER

THALLIUM

ZINC

MDL (mg/L) RESULT (mg/L)

0.05

0.005

0.01

0.01

0.01

0.01

0.05

0.0005

0.013

0.05

0.005

0.01

0.01

0.01

1.05

N.D.

0.16

N.D.

N.D.

0.01

N.D.

N.D.

0.013

N.D.

N.D.

N.D.

N.D.

1.35

21ST CENTURY ENVIRONMENTAL • NJDEPE CERTIFICATION #0803fl-&-|-Q-Q { Q {


COMPOUND UG/L IDL COMPOUND UG/L

N-Nitrosodiaethylaaine ND 10Phenol ND 10bis(-2-Chloroethyl)Ether ND 102-Cholorophenol ND 101.3-Dichlorobenzene ND 101.4-Dichlorobenzene ND 10Benzyl Alcohol ND 101,2-Dichlorobenzene 11 102-ttethylphenol ND 10bis(2-chloroisopropyl)Ether ND 104-Methylphenol ND 10N-Nitroso-Di-n-Propylaiine ND 10Hexachloroethane ND 10Nitrobenzene ND 10Isophorone ND 162-Nitrophenol ND 102,4-DiiethylphenoI ND 10Benzoic Acid ND 58bis(-2-Chloroethoxy)Methane ND 102,4-Dichlorophenol ND 101,2,4-Trichlorobenzene ND 10Naphthalene ND 104-Chloroaniline 13 10Hexachlorobutadiene ND 104-Chloro-J-Hethylphenol ND 102-Hethylnaphthalene ND 10Hexachlorocyclopentadiene ND 102,4,6-Trichlorophenol ND 102,4.5-Trichlorophenol ND 502-Chloronaphtn«ltnt ND 102-Nitroaniline ND 50DiMthyl Phthalate ND 10Acenaphthylene ND 10J-Nitroaniline ND 50

(J) Indicates detected below IDL(B) Indicates also present in blank(ND) Indicates compound not detected

JOB NUMBERSAMPLE NUMBERCLIENT IDDATA FILE

A1219 UESTONU-1A

>C0791

MATRIXDILUTION FACTOROA BATCHDATE ANALYZED

Uater1.00

03/23/93

MDL

Acenaphthene ND 102,4-Dinitrophenol ND 504-Nitrophenol NO 50Dibenzofuran ND 102,4-Dinitrotoluene ND 102,6-Dinitrotoluene ND 10Diethylphthalate ND 104-Chlorophenyl-phenlyether ND 10Fluorene ND 104-Nitroaniline ND 504,6-Dinitro-2-Hethylphenol ND 50N-Nitrosodiphenylaiine ND 184-BroMphenyl-phenylether ND 18Hexachlorobenzene ND 10Pentachlorophenol ND 50Phenanthrene ND 10Anthracene ND 10Di-n-Butylphthalate ND 10Fluoranthene ND 10Pyrene ND 10Butylbenzylphthalate ND 103,3'-Oichlorobenzidine ND 20Benzo(a)Anthracene ND 10Bis(2-Ethylhexyl)Phthalate ND 10Chrysene ND 10Di-n-Octyl Phthalate ND 108enzo(b)Fluoranthene ND 10Benzo(k)Fluoranthene ND 10Benzo(a)Pyrene ND 10Indeno(l,2,7-cd)Pyren8 ND 10Dibenzo(a,h)Anthracene ND 10Benzo(g,h,i)Perylene ND 10Benzidine ND 20Pyridine ND 10

ERA SAMPLE NUMBERsemi-VOLATILE ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS


Sample wt/vol: 1000 (g/mL) ML

Level: LOW

% Moisture: 100


GPC < Y or N >: N

Column: DB-5

Number TICs Found 2

I II WESTON II_________I


Lab File ID: >C0791

Date Received: NA


Date Extracted NA

Dilution Factor: 1

CONCENTRATION(ug/L or ug/Kof) UG/L

CAS NUMBER

1 9199482 101848

1 COMPOUND NAME1

11 Butane, 2-ethoxy-2-methy 1- (9CI)1 Benzene, l,l'-oxybis- (9CI)1

1 RT1

11 3.49116.941

EST CONCI

340

A R I O O I Q 3

DATA PACKAGE

A R I O O I O l *



ANALYSIS NO: A 1214

CLIENT ID: S-l


BIPHENYL 2000 3080


21ST CENTURY ENVIRONMENTAL • NJDEPE CERTIFICATIofl BsjsQ Q I 0 5

-s-i

Fil« >CC

•

It

J881 35.0-500.0 *MU. ^f|TON 081-11 040193900 f 10(00 ( ld,00 1200 1300

, 12.0 ' 13.0 14'.0 ' id.O ' 16.0 ' 17.0 ' 18

Fi l« >C0881 WESTON 081-11 040193Bpk fib 12216

10000:

5000- 39 5i 63 \/ • f

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Fil« >C0881 WESTON 081-11 040193Bpk flb 31808

20000-

0-

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154

156

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la160 '

Scan 131516.80 M i n .

170/

r1 77 ^ 14239 I 65 "^ 115 f-"f \ 85 94 102 / 128 | 155 i

,.|lj.n .11], j, ^ .;l|l|.. Jij.ji li. ..'.... ._L ....f... . .At.. ..(. . -J III. .... f . I

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-80

-40

-0

>C0881 WESTON 081-11 04019335.01 500.0 TIC

Upslope: .20 Area Reject: 5.00 \Dnslope: 0.00 Results File IC0289

Max Peaks: 2 Bunching:Sorted by Time/Area INT

Peak R.T.min.

firstscan

maxscan

lastscan

peakheight

rawarea

corr.area

corrmax

\ oftotal

12

:AL,,3

16.4816.80

12791708

12841315

12901327

39314160081

87696363479

85382359292

Move cursor; then press carriage return

23.76100.00

19.20180.799

A R I O O I 0 6

Areas, times, and heights stored in; _DsBGC2B25,ATEData File = D:BGC2B25. FTS Printed on 03-26-1993 at 13;47s18S t a r t t i m e : 0 ,. 0 0 ~ m i n » S t o p t i m e : 3 5 „ 0 0 m i n „ Off s e t •Full Range: 150 millivolts *

I

10 rnv ,

f l R l O O i O ?


BIPHENTL/PHENYL ETHER

ANALYSIS NO: A 1215

CLIENT ID: S-1A


BIPHENYL 2000 6400


21ST CENTURY ENVIRONMENTAL • NJDEPE CERTIFICATION #08031 fl R I QQ I

AUtS

^ >cc

200000

100000;

!882 35.0-500.0 *»u. !j!||TON 081-12 040193900 ( 1000 t 1100 f 1200 t 1300

12. 0 'Fila >C0882Bpk flb 22960

20000

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1113.0 ' 14.0 ' l .O ' 16.0

WESTON 081-12 040193

1

1400

:80

-40

17.0 18.0Scan 1281

16.48 Min.

15239 Kt £* 76 89 93 102 \ I, 51 63 / " " , us igs 13- ^'

4!0 ;

Film >C0882Bpk fib 50728

" J

154

156

\t~~~**'60 80 100 120 140 160

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-80--40

'-0

Scan 131216.80 Min.

170

40000-

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Upslope: .20 Area Reject: 5.00 \Dnslope: 0.00 Results File IC0289

Max Peaks: 2 Bunching:Sorted by Time/Area INT

Peak R.T.min.

firstscan

maxscan

lastscan

peakhe ight

rawarea

cor r .area

corr,\ max.

96 oftotal

12

16.4816.80

12761306

12811312

12901326

69689254605

159496571168

Sum of corrected areas:

154428563833

718261.

27.39100.00

21.50078.500

flRI00109

Areas, times, and heights stored in: D: BBC2B26 . ATEData File = D : BGC2B26 .PTS Printed on 03-26-1993 aStart time: O.OO min« Stop time: 35.00 min .Full Range: 150 millivolts

19: 32? 26Offset: 10 mv,

r~

A R I O O I 1 0

TO 4614916 P.01L/L-V- iw1 J.-'-'C. UU - XC.

»ANALYSIS NO:

CLIENT ID:

METALS

ANTIMONY

ARSENIC

BERYLLIUM

CADMIUM

CHROMIUM

COPPER

U LEAD

MERCURY

MOLYBDENUM

NICKEL

SELENIUM

SILVER

THALLIUM

ZINC



A 1216

S-2

MPL (mg/Kg)

5.00

0.50

I .'00

1.00

1.00

1.00

5.00

0.25

1,25

5.00

0.50

1.00

1.00

1.00

--

RESULTS (ms/Kgl

N.D,

9.64

H».

18.1

9.06

43,7

165

N.D.

13.3

N.D.

0.76

N.D.

N.D.

1310

21ST CENTURY ENVIRONMENTAL - NJOIP6 CERTIFICATION

A R i O O l i I



A1216 UESTONS-2

>C0792


SoilIJJfl

03/23/97

COMPOUND U6/KG HDL COMPOUND UG/KG HDL

N-NitrosoditethylaiinePhenolbis(-2-Chloroethyl)Ether2-Cholorophenol1.3-Dichlorobenzene1.4-DichlorobenzeneBenzyl Alcohol1,2-Dichlorobenzene2-Hethylphenolbis(2-chloroisopropyl)Ether4-HethylphenolN-Nit roso-Di-n-PropylatineHexachloroethaneNitrobenzeneIsophorone2-NitrophenoI2,4-OiwthylphenolBenzole Acidbis(-2-Chlorcethoxy)Methane2,4-Dichlorophenol1,2,4-TrichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4-Chloro-3-Hethylphenol2-MethylnaphthaleneHexachlorocyclopentadiene2,4,6-Trichlorophenol2,4.5-Trichloropheno12-Chloronaphthalene2-NitroanilineDimethyl PhthalateAcenaphthylene3-Nitroaniline

ND290 JNDNDND220 JND

2600NDNDNDNDNDNDNDNDNDNDNDND64 J90 JNDNDNDNDNDNDNDNDNDNDNDND

330330330330330330330330330330330330330330330330330160033033033033033033033033033033016003301600330330330

Acenaphthene2,4-Dinitrophenol4-NitrophenolDibenzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDiethylphthalate4-Chlorophenyl-phenlyetherFluorene4-Nitroaniline4,6-Dinitro-2-MethylphenolN-Ni trosodiphenylaiine4-Bro»ophenyl-pnenyletherHexachlorobenzenePentachlorophenolPhenanthreneAnthraceneDi-n-ButylphthalateFluoranthenePyreneButylbenzylphthalate3j3'-0ichlorobenzidineBenzo(a)AnthraceneBis(2-Ethylhexyl)PhthalattChryseneDi-n-Octyl PhthalateBenzo(b)FluorantheneBenzo(k)FluorantheneBenzo(a)PyreneIndeno(1,2,3-cd)PyreneDibenzo(a,h) AnthraceneBenzo(g,h,i)PeryleneBenzidinePyridine

68 JNDND37 JNDNDNDND56 JNDNDNDNDNDND38083 3ND450370NDND240 J58 JB260 JNDND236 J210 J130 357 3140 3NDND

33016001600330330330330330330160016003303303301600339330330330330330660330330

. 330330330330330330330330660330


(J) Indicates detected below HDL(B) Indicates also present in blank(ND) Indicates compound not detected

A R I O O i 1 2

semi-VOLATILE ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS

EPA SAMPLE NUMBER

I II UESTON II I

Matrix: (soiI/water) SOIL

Sample wt/vol: 30 (g/mL) GM

LeveI: LOW

\ Moisture: 100


GPC ( Y or N >: N

Column: DB-5

Number TICs Found 19


Lab File ID: >C0792

Date Received: NA

Date Analyzed 03/23x93

Date Extracted NA

Dilution Factor: 1

CONCENTRATION(ug/L or ug/K

rsUG/KG

fCAS NUMBER

1234 60447195 1731262867891011 629440212131415 .161718 9252419 101848

i

COMPOUND NAME

UNKNOWN SUBSTITUTED ALKANEUNKNOWNUNKNOWNDodecane, 6-methyl- (8CI9CI)Decane, 5-propyl- (8CI)UNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWNCyclohexane, l-bromo-4-methy 1- (8CI9CI)UNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWNl,l'-Biphenyl (9CI)Benzene, l,l'-oxybis- (9CI)

1 11 RT 11 1

1 1112.831113.411113.581113.791113.931114.031114.431114.501114.571114.701115.051115.131115.291115.391115 .-861116.23!116.581116.651117.0111 1

EST CONC

3704301300120040040053053050015003701900430530190019003700630024000

A R I . O O I 13

QUANT REPORT

Operator ID: JEFFClutput File: /SC0792: : EData File: >C0792::D4

name: A1216 UIESTONMisc: 032393

D File: ID0323:: D5Title: hSL BNA STD1 ast Calibration: 930324

Compound

Quant Rev: 6 Quant Time:In jected at:

Dilut ion Factor:

930324 13:48930323 23:55

1.00000

BTL#12

12:17

R.T. Scan* Area Cone Units

Compound is ISTD

1)4)5)5)0)12)-3)? )

• 7)28)3),3)43)£)1)

53)c:6)0)ol)63)4)5)67)~*Q )1)/2)73)6)

, 7)78)9)0)

*d4-l,4-Dichlorobenzene2-Fluoropheno 1Phenol-d5Phenol1,4-Dichlorobenzene1,2-Dichlorobenzene

*d8-NaphthaleneNitrobenzene-d51,2 ,4-Tr ichlorobenzeneNaphtha lene

*dlO-Acenaphthene2-Fluorob ipheny 1AcenaphtheneDibenzof uranFluorene

*dlO- Phenanthrene2,4,6-Tr ibromopheno 1PhenanthreneAnthraceneFluoran thene*d!2-ChrysenePyreneTerphenyl-dl4Benzo (a) AnthraceneBis (2-Ethylhexyl)Phtha lateChrysene*d!2-PeryleneBenzo (k )Fluo ran theneBenzo (a ) PyreneIndeno(l,2,3-cd ) PyreneDibenzo(a,h ) AnthraceneBenzo(g,h,i)Perylene

10.387.409.799.8210.4210.8713.5911.9213.4913.6318.1116.4318.1818.5919.4821.8720.1821.9222.0424.9928.7025.5726.0328.6528.8628.7732.1431.3132.0034.6734.6835.38

674388617620678721980821971984

1410125014171456154117701608177517862069242421242168241924392430275226732739299329943061

16012175172598230742687300433633312434796

16042493137231165612891487

346255513130882818

12610181189944

21214440010314406

16120380535032155762

1846

40.0081.0591.657.556.6279.2240.0038.321.911.4940.0044.432.031.111.67

40.0090.8511.452.49

13.5840.0011.1144.257.331.757.8140.006.826.404.041.714.06

UG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/L

9482877996928879969892969184989891999493989689939994949192727379

A R I O O I I k

ION CHROMfiTOGRfiM>C079235.0-500.0 amu. PUS16 WESTON

TIC038393

590 , 1000 , 1500 t gooq . 25.00 3000

Data File: >C0792::D4Name: A1216 WESTONMisc: 032393

Id File: ID0323::D5Title: hSL BNA STDLast Calibration: 930324 12:17

Operator ID: JEFFQuant Time: 930324 13:48Injected at: 930323 23:55

Quant Output File: "SC0792::ED

BTL#12

f l R I G O l 1 5

REFERENCE: STANDARD SPECTRUMFil« MNTSTBpk Ab 100

100-••

O-40

40

40 N8 INTERNAL STDSSUB

52 56 75 76

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140

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>C0792Ab 7378

!5000

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75

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78^80

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150

115

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•100.

120 140

SAMPLE SPECTRUM <UNALTERED>Fil« >C0792Bpk Ab 7378

5000:

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160

SS 56 75 78 87 **SL 117X \ ( / " I .1.1. ....... ......it,,. ...i.. . .{. .,l.i. . .60 80 100 120 140

14.

-100

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Data F i l e : >C0792::D4.Name: A1216 UESTONMisc: 032393Quant Time! 930324 13:48In j ec t ed at: 930323 23:55

Quant Ou tpu t Fi le : ^C0792::D3

BTL*12Quant ID File: ID0323:sD5

Last Calibration: 930324 12:17

Compound No: 1 (ISTD)Compound Name: d4-l,4-DichlorobenzeneScan Number: 674Retention Time: 10.38 min.Quant Ion: 150.0Area: 16012Concentration: 40.00 UG/Lq-value: 94

A R I O O I 1 6

REFERENCE STfiHDflRD SPECTRUM^•bt >SX050 HP BNfl^Mflb 100

100-

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81

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112

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112100

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ata File: >C0792::D4Name: A1216 UIESTONMisc: 032393Quant Time: 930324 13:48Injected at: 930323 23:55

Compound No: 4Compound Name: 2-Fluoropheno1Scan Number: 388Retention Time: 7.40 min.Quant Ion: 112.0Area: 17517Concentration: 81.05 UG/Lq-value: 82

Quant Output File: AC0792::D3

BTL*12Quant ID File: ID0323::05


A R I O O I 1 7

REFERENCE STflNDflRD SPECTRUMFil« >SXQ5Q HP BNfl Standard 50 50 ng/'uL *ix*d Base Neut Scan 427Bpk fib 100 NRM

100-.

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42 Aa 52 54^.J? \ / 62 66

1 i ! 1 ' 1 ' -I f 1 1 ' 1 1 ' t J ' 1

11.66 nin.

?1' 76 82 94. ./ / .f

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1 ,40 50 60 70 80 90 10C

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SAMPLE SPECTRUM <BACK6ROUND SUBTRACTED)File >C0792Bpk fib 12500

1QQQ01: 42rt_ 1 - 1 I 1

' 40

fll216 UESTONSUB

43 52 54

2- \ / 6S 66

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71i 76 82

11. . | . r r f

70 80

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99X 1-100

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Data F i le : >C0792::D4Name: A1216 UESTONflisc: 032393Quant Time: 930324 13:48I n j e c t e d at: 930323 23:55

Compound No: 5Compound Name: Phenol-d5Scan Number : 617Re ten t ion Time: 9.79 m i n .Quant Ion: 99.0Area: 25982Concen t ra t ion : 91.65 UG/Lq-value: 87

Quant Output F i le : /SC0792::D3

BTL*12Quant ID File: ID0323::D5


18

REFERENCE STflNDRRD SPECTRUMJBLe >SX050 HP BNfl Standard BO 60 na/uL nixad Baca^B»b ice NRK^^V 94

100-•

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50 55 . 67 75.l ! l l . . . i .1 Hi. i.l . i i l i l .. .r - 1

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128\

-100•

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ata F i l e : >C0792::D4Name! A1216 WESTONMisc : 032393Quant T ime : 930324 13:48I n j e c t e d at: 930323 23:55

Compound No: 6Compound Name: PhenolScan Number : 620R e t e n t i o n Time: 9.82 m i n .Quant Ion : 94.0Area: 3074Concen t r a t ion : 7.55 UG/Lq-value: 79

Quant O u t p u t F i l e : /XC0792::D3

BTL#12Quant ID File: ID0323::D5


A R I O O - I 19

REFERENCE 8TBNDRRD SPECTRUMFil« "BI6DBBpk fib 100

100-

.^

Vo '

B«nz«rr«, 1CLP FLT

50 '&r ,fi60 80

,4-dichloro- Scan 106467NRtl NOM 0.00 Min.

146

111

1,

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i _ni66 ' iao ' 146

SflMPLE SPECTRUM <BflCK8ROUMD SUBTRACTED)File >C0792Bpk fib 1156

100th 43

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Data Fi le : >C0792::D4Name: A1216 WESTONMice : 032393Quant Time: 930324 13:48I n j e c t e d at: 930323 23:55

Quant Outpu t F i le : ^00792::D3



Compound No: 10Compound Name: 1,4-DichlorobenzeneScan Number: 678Retention Time: 10.42 min.Quant Ion: 146.0Area:, 2687Concentration: 6.62 UG/Lq-value: 96

A R I O O I 2 0

REFERENCE STflNDflRD SPECTRUMJHto "BI6DB^•Rb 100^^

100-"

O- , . , . . . . , .

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75

1 .2-dichloro-NRK NOM

111

Sc*n 955010.00 win .

146

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SRMPLE SPECTRUM (BflCKGROUND SUBTRACTED)File >C(Bpk fib 1

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7925720

37

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113 131

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Scan 72110.8? nin.

146{ -100

139-^^'-o140

ata Files >C0792::D4Name: A1216 WESTONMisc: 032393Quant Time: 930324 13:48Injected at: 930323 23:55

Quant Output File: 00792::D3



Compound No: 12Compound Name: 1,2-DichlorobenzeneScan Number: 721Retention Time: 10.87 min.Quant Ion: 146.0Area: 30043Concentration: 79.22 U6/Lq-value: 92

REFERENCE STfiNDRRD SPECTRUMFil* >DEN03Bpk fib 100

100-

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80

54 68 78

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140

l.!-""1"100 120 ' 140 ' 160 ' 180

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SflMPLE SPECTRUM <BfiCK8ROUND SUBTRACTED)File >COBpk Ab 1

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792 01216 MESTON 032393 Scan6984 SUB 13.59

13643 57 --'/ /

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155 167 178i .. J. . f . (

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SflMPLE SPECTRUM <UNfiLTERED)Fil« >COBpk Ab 3

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980• in.

-100

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Data F i le : >C0792::D4Name: A1216 WESTONMisc : 032393Quant Time: 930324 13:48I n j e c t e d at: 930323 23:55

Compound No: 18 ( ISTD)Compound Name: d8-NaphthaleneScan Number : 980R e t e n t i o n Time: 13.59 m i n .Quant Ion: 136.0Area: 36333Concen t r a t i on : 40.00 UG/Lq-va lues 88

Quant Ou tpu t F i l e : /XC0792::D3



ARIOOI22

REFERENCE STANDARD SPECTRUM^•k >SX050 HP BNfl Standard^^Wb 100^^100-]

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SAMPLE SPECTRUM <BACK6ROUND SUBTRACTED)File >C0792Bpk Ab 5516

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-100

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SAMPLE SPECTRUM (UNALTERED)Fil« >C0792Bpk Ab 6610

1•

4000-

o-

54

T' 40 " ' ""^

A1216 WESTON 032393 Scan 82111.92 Min.

82y

57 70

4 Oft

93 98 us123 f 153

... \J.. ....f \..l, ../ N.

hi 00

-o60 80 100 120 140

ata File: >C0792::D4Name: A1216 WESTONnisc: 032393Quant Time: 930324 13:48Injected at: 930323 23:55

Compound No: 19Compound Name: Nitrobenzene-d5Scan Number: 821Retention Time: 11.92 min.Quant Ion: 82.0Area: 12434Concentration: 38.32 UG/Lq-value: 79




A R I O O I 2 3

REFERENCE STflNDflRD SPECTRUMFil« "BISDBBpk fib 100

100-

•

40

B«nz*n«. 1,2.4-trlchloro-FLT NRM MOM

74 109 1/45

60 80 i6'd 120 ' 140

Scan 1208210.00 min.180

160 18

-100

-O0

SflttPLE SPECTRUM <BflCK6ROUND SUBTRflCTED)File >CCBpk fib 1

2000-

0-

79294S

541

JL40

5 *

,60

B1216 UESTON 032393 ScanSUB 13.49

>997 m

{ 1 11£ */* 139 r^ *f 8 1f°b'd ' 100 iab ' 140 ieo ' ieo

971• in.

-100

-0

SflMPLE SPECTRUM <UNOLTEREO>Fil* >CO?92 R1216 UESTON 032393 Scan 971Bpk fib 4996 13.49 Min .

55•

4000-

0-

41

Jl It. . ull

V6 1 1 1 ' 1 '

69

,,&60

9783 -x. Ill

i \i 1 "K" / 5 1/39 r49 "8 1/8°8*0 ' l6b ' 120 ' 140 160 ' 180

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-0

Data F i le : >C0792::D4Name: A1216 UESTONhisc: 032393Quant Time: 930324 13:48I n j e c t e d at: 930323 23:55

Quant Ou tpu t F i le : ^00792::D3



Compound No: 27Compound Name: 1,2,4-TrichlorobenzeneScan Number: 971Retention Time: 13.49 min.Quant Ion: 180.0Area: 796Concentration: 1.91 UG/Lq-value: 96

REFERENCE STANDARD SPECTRUMflfe "BI6DB^•flb 100^Î 100-

.Q_

40

Naphthalen* Scan 91803FLT NRfl

102I I I U I I . I | l . . l | l l l l | l l l l | l l i l

60 80 100

NOM 0.00 M i n .128

i

f

129i"1

-100*

-o120 ' 140 ' 160 ' 180

SAMPLE SPECTRUM <BACK6ROUND SUBTRACTED)FU« >CCBpk flb 7

•

4001

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792 fl!21«06

8369 *>Vl

40 51 i{ Jlj^ . , 1 j

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28I

136 153 168194

' /Tj1 / •{ i140 160 180

964• in.

-100•

-O

SAMPLE SPECTRUM <UNOLTERED>Fil* >C0792 A1216 UESTON 032393 Se*n 984Bpk Ab 3621

41 554000q

-2000 ;

o;

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4, ,,,h ,. .(IJl

' 83 97

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13.63 win.

109 111 «„ 136 ±53 1;elg.

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ata File: >C0792::D4Name: A1216 WESTONMisc: 032393Quant Time: 930324 13:48Injected at: 930323 23:55

Compound No: 28Compound Name: NaphthaleneScan Number: 984Retention Time: 13.63 min.Quant Ion: 128.0Area:. 1604Concentration: 1.49 UG/Lq-value: 98

Quant Output File: C0792::D3



A R I O O I 2 5

REFERENCE STANDARD SPECTRUMFil« >DEH03Bpk flb 100

100--•

8052 66 --,..,\^,.J4V ' '6'0' ' '8'

80 Nd STANDARD Scan 799SUB NRM 15.60 M i n .

164"

j82 108 122 „ ^^ .

r^ \ X / 146 111 x ij I LlH,/6

hlOO•

-oo' 'i6o% ' '120 ' lie' ' '160' ' 'iso' ' '260'

SAMPLE SPECTRUM (BACKGROUND SUBTRACTED)File >C0792Bpk Ab 11124

10000-

< ,-.--,-

52 66\

60

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164V.

so se 108 12g108 122 132 ±46 y! .^f-r. .\{ \ fa ' - H1

80 ' 100 ' 120 ' 140 ' 160

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168

-100

' 'l80' ' '260' ' '

SflHPLE SPECTRUH <UNALTERED>Fil« >C0792 ABpk Ab 11124

^10000-

.

J52 66 80

....\u,\ . 440 ' 60 8

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82 97 1S2

3 100\120

032393164s.II

132 146 jHA, /r .177f180

Scan 141018.11 Min.

' 260" '

-100•

-0

Data F i le : >C0792::D4Name: A1216 UIESTONnisc: 032393Quant Time: 930324 13:48I n j e c t e d at: 930323 23:55

Compound No! 33 ( ISTD)Compound Name: dlO-AcenaphtheneScan Number : 1410Re'tent ion Time: 18.11 m i n .Quant Ion: 164.0Area: 24931Concentration: 40.00 UG/Lq-value: 92

Quant Output F i l e s AC0792::D3



flRIOOI26

REFERENCE STftNOflRD SPECTRUMyp ?100-

>SX05Q HP BHfl Standard 50 50 ns'uL' 100 NRH

50 51 __ of. 94 120v s 78 OO ,, \ 133 146J^S , 174

^60 80 140 160

;• N«ut Scan 82719.79 »in.

172-100

-0i 260'

SftMPLE SPECTRUM <BflCK6ROUND SUBTRflCTED)File >C0792Bpk flb 18384

20000:

•

041 57f f

40 ' F 6V

P11216

75 85/ /

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172

133 146 3?2 i 183I /

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SflMPLE SPECTRUM <UNftLTERED)Fil« >C0792Bpk Rb 18384

20000;

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R1216

57 69 85/ / /

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172

133 146 i?S |

t

194 196

' '1401 J160 '180' ' '260' '

-100

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-0

a ta F i l e : >C0792::D4Names A1216 WESTONMisc : 032393Quant T ime: 930324 13s48I n j e c t e d at: 930323 23:55

Compound No! 38Compound Name: 2-FluorobiphcnylScan Number: 1250Retention Time: 16.43 min.Quant Ion: 172.0Area: 37231Concentration: 44.43 UG/Lq-value: 96


BTL*12Quant ID File: 100323:505


ARI00127

REFERENCE STRHDRRD SPECTRUMFil« "BI80BBpk fib 100

100-

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Bc«n*phthyl«n«. 1,2-dihydro- Sc«n 83329FLT NRtt Men 0.00 nin.

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154153

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SfiMPLE SPECTRUM <BRCK6ROUND SUBTRflCTED)File >C0792Bpk fib 668

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40

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77 8153 63 \ // . ij A ( .

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153 184* * -100

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SflMPLE SPECTRUM <UNflLTERED>Fil* >C0792Bpk fib 668

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153 184"

^ 6? 76 83 „ 109 111 Ig6

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Data File: >C0792::D4Name: A1216 WESTONnisc: 032393Quant Time: 930324 13:48Injected at: 930323 23:55

Compound No: 43Compound Name: AcenaphtheneScan Number: 1417Retention Time: 18.18 min.Quant Ion: 153.0Area: 1656Concentration: 2.03 UG/Lq-value: 91

Quant Output File: ^C0792::D3



A R I O O I 2 8

REFERENCE STflNDflRD SPECTRUMjgHt "BI

100-j.

-Q_

6DB Dib«nzofur*n00 FLT NRM NOM

139" 166

1 ^^j+0 60 80 ibo 120 ' 140 ' 160

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168

'"lib"1"

2649kin.

-100p

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SAMPLE SPECTRUM <BflCK6ROUND SUBTRflCTED>File >C0792Bpk flb 498

.400-

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57/

60

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168•**

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168"*"

1 f i j u-n-jr-T-1180

L456nin.

rlOO•

-9

ata F i l e : >C0792::D4Name: A1216 WESTONMisc: 032393Quant Time: 930324 13:48I n j e c t e d at: 930323 23:55

Compound No: 46Compound Name: DibenzofuranScan Number: 1456Retention Time: 18.59 min.Quant Ion: 168.0Area: 1289Concentration: 1.11 UG/Lq-value: 84

Quant Output File: " 0792::D3



A R I O O J 2 9

REFERENCE STflNDflRD SPECTRUMFila "BISDBBpk flb 100

100-

-

40

9H-Fluor«n«FLT NRM

63

60 ' 80 ' 100 ' 120

Sc*n 867370.00 Min.166""" -100

139 ;ruiiWi i rp i i i i iM '-0

140 160

SAMPLE SPECTRUM <BHCK8ROUND SUBTRACTED)Film >C0792 fl!2Bpk flb 545

™"

400-- 39 51 70 8

Q- \ ' rM -• • i i* • '*• f\- 1

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032393 Sc»n 154119.48 M i n .

166"Î-IQO

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115 ..„Illy i-?9 149

f f f f \\ 1 101 aib ' iVo ' iebSAMPLE SPECTRUM <UNRLTEREO>Fil« >C0792Bpk fib 545

400- 40

40

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T -, 'V3 ?t 1 HI ill i Nl I

' 60 ' 80 ' i6b

032393

115

rX120

Sc*n 154119.48 M i n .

166

139 149 •

140 ' 160

Data File: >C0792::D4Name: A1216 WESTONtlisc: 032393Quant Time: 930324 13:48Injected at: 930323 23:55

Compound No: 51Compound Name: FluoreneScan Number: 1541Retention Time: 19.48 min.Quant Ion: 166.0Area: , 1487Concentration: 1.67 UG/Lq-value: 98




A R I O O I 3 0

REFERENCE STANDARD SPECTRUMm,i°i100-

-•

0-

M0300

48i 1 i'i 1*140

80

66 8054 / {

60 80

N8 STANDARDSUB CLP NRH

94/ 108 118. 1 1 ' '•\'t\>,H'ii< \tnvr1ir

100 180

138 146 1*°

140 160

Scan19.87

188

1 f.o/i 1 1 1 1 1 fl^'Ei r

180

1016M i n .

-100

-0

SAMPLE; SPECTRUM <BACKSROUND SUBTRACTED)File >C079E fi!216Bpk Hb 13880

10000-48 32 y6 80

4*0 60 80

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9* J/* 182 138 146

100 180 140 '

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188/ 100

«« 170|fL / , lL ff

160 180

SAMPLE SPECTRUM (UNALTERED)Fil* >C0798Bpk Ab 13880

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Vflli'ij"40

A1816

58 66 g0\i- ... U . . t.l 1 _ .. .

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94 102

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188 132i'li IHII V120

146. .if .

140 '

Scan 177081.87 min.

188

*•/ ° 170.i.fcU ^ •ifj'l')'

'

I,ieo ieo '

(-100•

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Compound No: 53 (ISTD)Compound Name: dlQ-PhenanthreneScan Number: 1770Retention Time! 21.87 min.Quant Ion: 188.0Area: 34625Concentration: 40.00 UG/Lq-value: 98




A R I O O I 3 I

REFERENCE STflNDRRD SPECTRUMFil* >SX050 HP BNflBpk flb 100

100-

: 37 J2

fr'in''. f r rvnl40 80

Standard 50 50 ng/uL »ix«d B*siNRM

? ^ 1J2

120 ' 160

19? 222 250

266 240

i N«ut Sc*n 104824.28 M i n .

330"""j -1003/o± il:T1. /, i^ -o

280 320SPMPLE SPECTRUM <BflCK6ROUND SUBTRflCTED)Fi le >C0792Bpk flb 2165

2000-

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62

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141j**

91 111 | 172c r^Liîi*t i - f f f t f f i f t M - i f 4 i | i120 160

032393

Si»» 250197 { t' Mi >Li IV 1 1 fl 1 1 1 iTi 1 1 1 1 1 1 1 1

200 240 280

Scan 160820.18 Min.

332""5 -100

1

301 i|, '

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>C0792Bpk flb 2165

622000- ^

'•t\0JBH4WMMM4*0 "'" S'd

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14191 111 I 172

032393

f

IJ**1 I "

197222 260

f\ f T'r1 1 rrVf'Ti'T'TT'r^TT'T'pl T'fT't'Ff'yi'r r-120 160 200 240 2

Scan 160820.18 Min.332""•j -100

'01 Iy... • I'EV

Data F i l e : >C0792::D4Name: A1216 UESTONMisc: 032393Quant T ime: 930324 13:48Injec ted at: 930323 23:55

Quant O u t p u t F i l e : /SC0792::D3



Compound No: 56Compound Name: 2 ,4 ,6-Tribromopheno1Scan Number : 1608R e t e n t i o n Time: 20.18 m i n .Quant Ion: 330.0Area: 5513Concen t ra t ion : 90.85 UG/Lq-value: 91

A R I O O I 3 2

REFERENCE STflNDflRD SPECTRUMjM|9 "BISOB Ph«n»nthr«na 3e»n S5018^•fab 100 FLT NRH MOM 0.00 win.•r 178

100--.

o-

Jf> 89

63 .•""• 151 176r , i r- -i,

f^

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[-100

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40 ' s'd ' s'd ' 160 ' 120 ' iVo ' ied ' isbSflttPLE SPECTRUM (BOCKSROUND SUBTRfiCTED)File >C0792Bpk fib 5336

m

4000-

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39

40

01216

51 63 76/ / Xft-6ir-"îiti

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85 111 123

120

032393 Scan 177521.92 Min.178*""

126 150 152 176X NX ""1,ftl. ...•,.-. .>>... ,.'... i. A.....I

140 160 180

[-100'•

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SfiMPLE SPECTRUM <UNflLTERED>Fil« >C0792Bpk fib 5336

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51 63

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76

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89

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126 150X \

140

152

160

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176

^

1, - j.180"

hlOO••

•0

ata F i l c : >C0792::D4Name: A1216 WESTONMisc: 032393Quant T ime: 930324 13:48I n j e c t e d at: 930323 23:55

Compound No: 60Compound Name: PhenanthreneScan Number: 1775Retention Time: 21.92 min.Quant Ion: 178.0Area: 13088Concentration: 11.45 UG/Lq-value: 99




A R I O O I 3 3

REFERENCE STANDARD SPECTRUMIJf^f "BISDB flnthr*c«n«•nb 100 FLT NR» NOH^ 100-

•

o-76 89

,| |40 "^ 60 ' 80 ' i6b' ' 120

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151 175

| 1

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I

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-o140 ' 160 ' 180

SfiMPLE SPECTRUM <BflCKSROUND SUBTRACTED)File >C0792Bpk Rb 959

1000-: y 55

f^. (.. {40 60

01216 UESTONSUB

76 8® 89

80 100 1

032393 Scan 1786S2.04 nin.178

1BO 151 1751 if ' i l1

-100•

1 .20 ' l'4o 160 ' 180

SflMPLE SPECTRUH <UNRLTERED)File >C0792 01216 UESTON 032393Bpk Ob 959

1000--••

nJ

40 _., 88 _D • 150^ 55 76 v 89 .1 / ^ * * r~r^ >>li it ... 1 1 , ,il. . .ill . . ,40 60 80 100 120 140

Scan 178622.04 win.178f

151 175**** ^\. •

|1'...,..'..|.iW|... .

-100.•k-O

160 180


Compound No: 61Compound Name: AnthraceneScan Number: 1786Retention Time: 22.04 min.Quant Ion: 178.0Area: 2818Concentration: 2.49 UG/Lq-valueJ 94

Quant Output File: ">C0792::D3

'. BTL*12Quant ID File: ID0323::D5


REFERENCE STANDARD SPECTRUMFil« "B19DBBpk flb 100

100-

.

4V ' ' ' '

Fluor *n th«n«FLT NRM NOM

1011

80 ' 120

201^

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202•"" -100

__J°3 "

6 ' 240SAMPLE SPECTRUM <BACK6ROUNO SUBTRACTED)File >C0792Bpk Ab 4666

-4000-

- 40

0- f t.i

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202•****1

75 8Q ±oi 128 146 150 ±?4 80ol

80 120 160 200

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klOO

256 :,..,.>, .

240SAMPLE SPECTRUM <UNALTERED>Fil« >C0792Bpk Ab 4666

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128 146VN120

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202r2x

KOO

-a6 ' ' 240

Data File: >C0792::D4Name: A1216 UESTONMisc: 032393Quant Time: 930324 13:48Injected at: 930323 23:55 ,

Compound No: 63Compound Name: FluorantheneScan Number: 2069Retention Time: 24.99 min.Quant Ion: 202.0Area: 12610Concentrations 13.58 UG/Lq-value: 93 ».




A R I O O I 3 5

REFERENCE STANDARD SPECTRUM

SUB CLP NRMSc*n 1367

25.95 M i n .240

-100

66 78104 i£0

*

156 157 194184 / *c\ ' « I i * • • i ' i « i ' * i i » • » i » * • r » » » i • • » i

80 120 160 200 240SAMPLE SPECTRUM (BACKGROUND SUBTRACTED)film >C0792Bpk Ab 6343

-4000-

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104 !2066 78 X - . 132

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194 i

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a ta F i l e : >C0792s :D4Name: A1216 UESTONhisc: 032393Quant T ime: 930324 13:48In jec ted at: 930323 23:55

Compound No: 64 ( ISTD)Compound Name: dl2-ChryseneScan Number : 2424Re ten t ion Time: 28.70 m i n .Quant Ion: 240.0Area: . 18118Concen t ra t ion : 40.00 UG/Lq-value: 98

Quant O u t p u t F i l e : ^C0792::D3

BTL*12Quant ID F i l e : ID0323::D5

Last C a l i b r a t i o n : 930324 12:17

A R I O O I 3 6

REFERENCE STflNDflRD SPECTRUMFil* "BISGBBpk fib 100

100-

•41

40 SO

Pyr«n« Scan 129000FLT NRM 0.00 Hin.

202""I

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-100

-0120 160 200

SfiMPLE SPECTRUM <BflCK6ROUND SUBTRflCTED)File >CCBpk Rb 3

:2000

^

792 01216 UESTON 032393456 SUB 2

202"**

1743 63 75 88 3?1 122 137 150 163 /

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SflMPLE SPECTRUM <UMflLTERED)Fila >C0792Bpk Rb 3456

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2021218

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Data Fi le : >C0792::D4Name: A1216 WESTONMisc: 032393Quant Time: 930324 13:48In j ec t ed at: 930323 23:55

Compound No: 65Compound Name: PyreneScan Number : 2124Reten t ion Time: 25.57 m i n .Quant Ion: 202.0Area: 9944Concen t ra t ion : 11.11 UG/Lq-value: 96

Quant Outpu t F i le : "00792::D3



A R I O O I 3 7

REFERENCE STRNDflRD SPECTRUM>SX050 HP BNft Standard 50 50 ng/uL Mixed Qi' 100 NRH

100-

is* N«ut Scan 140831.59 Min.244

-100

54 ff nn 106 122v 66 80 v *«\ / / N!

160 162

40'"' -TV T 160

184

240SflMPLE SPECTRUM CBflCKSROUND SUBTRflCTEOFile >C0792Bpk fib 8381

5000 54

c-VAX | 1 1 1

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106 ipp 16066 80 -v 1^ 136 \

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>62 184

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Scan 216826.03 Min.244""*' -100

212 226 ;-i- -r1-! •/• !"+*• 0200 240

SfiMPLE SPECTRUM <UNflLTERED>Fila >C0792Bpk fib 8381

8000; 54

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106 lop66 80 x ^ X~ 13

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26

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ata F i le : >C0792::D4Name: A1216 WESTONMisc: 032393Quant T ime: 930324 13:48I n j e c t e d at: 930323 23:55

Compound No: 67Compound Name: Terphenyl-d!4Scan Number : 2168R e t e n t i o n Time: 26.03 m i n .Quant Ion: 244.0Area: 21214Concentration: 44.25 UG/Lq-value: 89

Quant O u t p u t F i l e : ^C0792::D3



ARI00138

REFERENCE STflNDflRD SPECTRUMFil« "BI6DB B«nzt*3*nthr*c«m«Bpk flb 100 FLT NRM MOM

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160 ' ' " '

Sc«n £41928.65 Min.288i"" -100

TK<^ ..i200 ' £40

SflMPLE SPECTRUM <UNftLTERED>Fil« >C0792Bpk flb 1539

•

ioooi 44

°Vo ' •

A1216 UESTON

57 88 101il4 185

! 1 .,,/ /. /80 180

038393

150 163 J6, ..T. .<. .160

Scan 841$88.65 Min.888(

884

™ -(r f i' • i ! fH 1"^800 84

-100

-00

Data File: >C0792::D4Name: A1216 UIESTONMisc: 032393Quant Time: 930324 13:48Injected at: 930323 23:55

Quant Output File: "'C0792::D3



Compound No: 70Compound Name: Benzo(a)AnthraceneScan Number: 2419Retention Time: 28.65 min.Quant Ion: 228.0Area: 4400Concentration: 7.33 U6/Lq-value: 93 :

A R I O O I 3 9

REFERENCE STflNDflRD SPECTRUMi^^fe "BISDB 1^•Rb 100^^^T

100-j

•

57

140 '

, £-B«nz«n«dicarboxyl ic acid, bis<2-«thylh«xyScan 117817TLT NRM N0«

7,'*7

III f80

113123

{ \' 120 ' "

149'

167

160 ' ' ' 200

2261

240

0.00 w i n .

279""1

[-100

-0

SAMPLE SPECTRUM CBfiCKSROUND SUBTRflCTED)File >C0792Bpk flb 436

400-• 55

0-' A If ,^n n

81216 UESTONSU1

? 52 104 *?3

80 120

03E393B49f

167/ 208

160 ' 800 '

Scan 343928.86 win.

j-100

258 279 ;

i i ! i i Ji i i i ' -0240

SfiMPLE SPECTRUM <UNflLTERED>Fil* >C0792Bpk flb 456

jlA

400-—

O-

/

j| ,yi j, £40 80

fll£16 UESTON

149

1 11 3 3

/ f167

f120 ' 160

032393

207.(

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Scan 243928.86 win.

g£g 258 279

{ "N "N-100

;-o

' 240 '•'•••

ata File: >C0792::D4Name: A1216 WESTONnisc: 032393Quant Time: 930324 13:48Injected at: 930323 23:55


Quant ID FileiLast Calibration:

BTL#12ID0323::D5930324 12:17

Compound No: 71Compound Name: Bis(2-EthyIhexy1>PhthalateScan Number: 2439Retention Time: 28.86 min.Quant Ion: 149.0Area: 1031Concentration! 1.75 UG/Lq-value: 99

AR I 00 11*0

REFERENCE STflNDflRD 8PECTRUHFile "BI6DB Chrvs«n«Bpk flb 100 FLT NRfl NOM

100-

0J

101 11*\ 1

4*0 ' 80 120 ' 160

Scan 2180190.00 Min.228

k

(

200 ' 24

-100

-00

SRMPLE SPECTRUM <BflCK6ROUND SUBTRf»CTED>File >C0792Bpk Ob 1431

1000-

0--I-.-. • . .44 59/ /

R1216 WESTON 032393SUB

8* 100 135 150 1™p rf . ..jl. ' . f f .

80 120 160

2021/200

Scan 243028.77 Min.228

2^7|/ j

f

\

-100

-o' ' 240

SflMPLE SPECTRUM <UNflLTERED>Fil« >C0792 fl!2Bpk Rb 1464

".

™ r „ "I 1 / ^\k

&1 (MW -f * * * Irf f «• fafc ,* 1 *

40 ' do

>16 UESTON 032393 Scan 243028.77 Min .

228

(100 ^r3 135 150

ir 202 SP AX L / / / ^ / ' L l i.i.,.4«,.. -f • ! / j ; '11 r-rl!"-j-

120 160 200 2<

-100•»

-00

Data File: >C0792!:D4Name: A1216 WESTQNMisc: 032393Quant Time: 930324 13:48Injected at: 930323 23:55

Compound No: 72Compound Name: ChryaeneScan Number: 2430Retention Time: 28.77 min.Quant Ion: 228.0Area: 4406Concentration: 7.81 UG/Lq-value: 94

Quant Output File: /SC0792::D3



A R I O O I M

REFERENCE STflNDRRD SPECTRUM>DEM03

10080 N6 STANDARD

SUB CLP NRMSc*n 162629.57 Min.264

hlOO132

64 88 102 163 180

80 IcO XoO SCO 240

SAMPLE SPECTRUM <BACK6ROUND SUBTRACTED)Film >C0792Bpk Ab 5150

.4000-

1 53

olA4V ' '

01216 UESTOH 032393SUB

13266 88 102 "-] 15° *« 180 204x__.,4 / f. 4,. \/ / ... ^ \

80 120 160 200

Scan S75S32.14 Kin.264" -100

•232 ;jL^4>'-*240 r

SAMPLE SPECTRUM <UNALT£RED>Film >COBpk Ab S

4000

792150

44

Jo' ' '

A1216

*? 83 1021 s'o

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^ 150

M 1 \Wi'tW" •-• •-"120

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156

160

032393

207 228180 v. v•'1 • *" •"'1 1 • '-• 1 •

200

Scan32.14264

232

240

2752• in.

-100

ata Fi le : >C0792::D4Name: A1216 WESTONMisc : 032393Quant Time: 930324 13:48I n j e c t e d at: 930323 23:55

Compound No: 73 ( ISTD)Compound Name: d!2-PeryleneScan Number: 2752R e t e n t i o n Time: 32.14 m i n .Quant Ion: 264.0Area: 16120Concen t ra t ion : 40.00 UG/Lq-value: 94

Quant Output Fi le : AC0792::D3

BTL*12Quant ID F i l e : ID0323::D5


f l R I O O U 2

REFERENCE STRNDBRD SPECTRUMFil« "BIGDB B«mzomfluor*nth«n«Bpk flb 100 FLT NRM NOM

100--

0-

126

1' 80 ' 120 ' ISO ' 266

Sc«n 2070890.00 Min.252"***

,

-100•

-0' 240

SOMPLE SPECTRUM <Bf)CK6ROUND SUBTRflCTED>File >C0792Bpk flb 1230

.1000-

- 57

oi.o X

81216 UESTONSUB

71 8/5 9/9 "4. 137 "Pfill H'I •*>) i-Xyj-i"/-! . > . i

80 120 16C

032393

178 198 209i i 1*1 i i { i i'* i> 200

Scan 267331.31 min.282

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224/ J[-n

240SBMPLE SPECTRUM <UNflLTERED>Fil« >C0792Bpk fib

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4«r-W{_4_4- 71

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126 133

I7'fVff'iV .120

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178• • ' 1 ' '

195207

266

Scan 267331.31 Min.262

- 14 4' 240

hlOO•

-O

Data F i lo : >C0792s:D4Name: A1216 WESTONMisc: 032393Quant Time: 930324 13:48I n j e c t e d at: 930323 23:55

Quant O u t p u t F i le : /XC0792: :D3



Compound No: 76Compound Name: BenzoCk)FluorantheneScan Number: 2673Retention Time: 31.31 min.Quant Ion: 252.0Area:. 3805Concentration: 6.82 UG/Lq-value: 91

ARIOOIW

REFERENCE STRNDflRD SPECTRUMjrife "Bi•Pb 1^ ^

100-

-

SDB B«nzoC*3pyr*n«00 FLT NRM NOtl

126

40 ' 80 ' ISO ' 160

Scan 503280.00 Min.252*"" -100

! -17200 240

SfiMPLE SPECTRUM <BflCK8ROUND SUBTRACTED)film >C0792Bpk flb 1033

1000-

01216 UESTONSUB

033393 Scan 273932.00 Min.252**" -100

105 126137 s x 187 i/./.•..>./.-...

160 200

187 209 224> f t

• i •240

SflMPLE SPECTRUM <UNRLTERED>FilBpk• >C0792flb 1033

100O-

«=

44

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57

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R

33/itriU.]i...80

L216 UESTON

12697 " 5 135/ j J /•t*' i"*!' 'T '.'!'.

120

032393

149

160"\ -r- T

260

Scan 273932.00 win.252""I

224 1

' 240

-100

-0

ata File: >C0792!:D4Name: A1216 WESTONMisc: 032393Quant Time: 930324 13:48I n j e c t e d at: 930323 23:55

Compound No: 77Compound Name: Benzo(a)PyreneScan Number: 2739Retention Time: 32.00 min.Quant Ion: 252.0Area: 3503Concentration: 6.40 UG/Lq-value: 92




A R I O O U t

REFERENCE STANDARD SPECTRUMFil« "BI6DBBpk Ab 100

100-

fr|...|...40 1

IndcnoClFLT

138

30 120

,2,3-cd3pyr«n«NRM NOM

160 200 £

Scan 1933950.00 min.

276-100

.,, , . , ,J, r -0>40 280

SAMPLE SPECTRUM <BACKSROUND SUBTRACTED)File >C0792Bpk Ab 439

400-

- 40

40

R1216 UESTONSUB

13867 91 111 1 ± f /

' 80 ' 120 160

032393

3 193 209

' 200 '

Scan 299334.67 Bin.

276{ -100

........i.:.240 280

SfiMPLE SPECTRUM <UNALTERED)Fil* >C0792 A1216 UESTON 032393Bpk Ab 752

44-|

500:•

/

i138 207£. a o^ ^ a + •*»_ 156 163 ., _ _ /69 91 111 . . 193 f

U Jll uli. IA. ,i,.i.i, M <jJL . . f / It

40 80 120 160 200 240

Scan 299334.67 win.

I

hlOO•

-n> i • •'FT -280

Data File: >CO?92::D4Name: A1216 WESTONMisc: 032393Quant Time: 930324 13:48Injected at: 930323 23:55

Quant Output File: ~C0792::D3



Compound No: 78Compound Name: Indeno(l,2,3-cdJPyreneScan Number: 2993Retention Time: 34.67 min.Quant Ion: 276.0Area: 2155Concentration: 4.04 UG/Lq-value: 72

ARIOOU5

REFERENCE STflNOftRD SPECTRUML£Mkc "BI8DB•8b 100

^^100-

•

0-40 80

Dlb«nzt a,h3*nthr»c«n«FLT NRJ1 NOfl

139

i' 120 ' 160 ' 266

Scan 037030.00 Bin.

278""*

i

-100

•

-0240 ' 280

SAMPLE SPECTRUM <B«CKSROUND SUBTRACTED)File >C0792Bpk fib 377

400-j•- 44

0-jJr V40

01216 WESTON

138

\ X V 1N .p. fl' j u,i80 120

SUB

149 *?1 \( i i'"ieo1

032393

5 191 208

/ &"•;goo-"

Scan 299434.68 Min.

276{ HIOO1 •

>S1 253 L :* { , ill, p

240 ' 280SflMPLE SPECTRUM <UNflLTEREO>FiU >C0792Bpk fib 886

44

500J

o 1 . . . . , . . . , .L 69I .u, /:,.,40 80

B1216

95 112/ /

«V^

WESTON

138 165--s. 149 /, J / . ( .0 ' ' 160 ' ' '

032393

207191 f

{ L266 '

Scan 299434.68 M i n .

>21 253 L^ * T r ' f f i 1

-100r

-O

240 ' 280

ata File: >C0792::04Name: A1216 WESTONMisc : 032393Quant Time: 930324 13:48I n j e c t e d at: 930323 23:55

Quant Output Fi le : "SC0792: :D3



Compound No: 79Compound Name: Dibenzo(a,h)AnthraceneScan Number: 2994Retention Time: 34.68 min.Quant Ion: 278.0Area: , 762Concentration: 1.71 UG/Lq-value: 73

AR I 00 11*6

REFERENCE STRNDflRD SPECTRUHFile "BI8DBBpk flb 100

100-.

•40' ' ' ' '

B«nzoCghiFLT NR

138

...........J...80 120

MPNoll *'

160 '

i« Scan 1912420.00 M i n .

276

J' -100.

T~°200 ' 240 ' 280

SflMPLE SPECTRUM <BflCK6ROUND SUBTRflCTED)File >C0792Bpk Flb 412

400-J 44

40

fl!216 WESTON 032393SUB

13878 96 >- 178 191

.t, TA/. JL...iV/ T..80 120 160 &00

Scan 306135.38 nin.

276

J' -100

•

i*240 280

SflMPLE SPECTRUM <UNfU.TEREO>File >C0792Bpk flb 846

441 f•

500:

40

A1216 WESTON 032393

-0 81 138X lljp

'so' ' 120

147 1?^ 191 T

' 160 ' 266 '

Scan 306135.38 Min.

KOO27 *

253 f ':/ J1'^

240 ' 280

Data File: >C0792::D4Name: A1216 WESTONMisc: 032393Quant Time: 930324 13:48Injected at: 930323 23:55




Compound No: 80Compound Name: Benzo<g,h,i)PeryleneScan Number: 3061Retention Time: 35.38 min.Quant Ion: 276.0Area: 1846Concentration: 4.06 UG/Lq-value: 79

ARIOOU7

1* >C0792..k fib 6832

i

\

oU40

Y 57

i -\

1* >BIGDB.k fib 9999

81216 WESTON 032393 Scan 908SUB ADD OVC 12.83 M i n .

7.1 85 .,.,- "6B { / 99 99 "2 186 137140 15B 170 '.S 1 |l vv**-^' J / / *•-•* / "l^*.--

60 80 100 ISO 140 160Undacan*, 5-»«thyl- (8CI9CI> Scan 6060

0.00 Min.43 67

j.i,° 40

' ~]; le >BI6DB: .k flb 9999

Tf1 85 T67 ! 99 100 1?'a 126 140 158 170 '.

60 ' s'd ' 166 ' iso ' i40 ' iebNonane, 4,6-dimethyl- <8CI9CI> Scan 6099

0.00 M i n .43 57

_j

j _ _ !

40r leâieofI •kJ^B|99<

^^^D

f -^

,.,.,.rjJ

3?57

^B^j 43 """"i

j, 1,14'o

' J

71 Q5

67 ,| ./ 99 100 H3 126 141 156 157 ;, , ,.>,• 1, , , , , ,.IL., .rsfr:, . ,./.., ,., ,,,<,, , ,, , ftr, ,., , , ft^rr, , :060 80 100 ISO 140 160

Nonana, 3,7-di»athyl- <8CI9CI> Scan 61000.00 Min.

71 u^ 8 5

67 / 97 100 113 127 141 156 '.

e'd so ' iob ' 126 ' i46 ' i4b

Unknown #,1•^rea - 122209.0 Tentative Concentrat ion is 11.00

1. Undecane, 5-methyl- (8CI9CI ) 170 C12H262. Nonane,3. Nonane,4. Decane,5. Decane,

4,5-dimethyl- (8CI9CI) 156 C11H243,7-dimethyl- ( 8 C I 9 C I ) 156 C11H243,6-dimethyl- (8CI9CI ) 170 C12H262 ,4-d imethy l - ( 8 C I 9 C I ) 170 C12H26

6. Undecane, 3 ,7-d ime thy 1- ( 8CI ) 184 C13H287. Undecane, 2-methyl- (8CI9CI) 170 C12H26

*

~ " e f i l e :speed :

Prob.

1. ,2.3 .

73*70*•?*

A R I O O U 8>C0792 Spectrum #: 9081 T i l t i n g opt ion : N No. of ion ranges searched : 45

CAS f CON # ROOT K DK *FLG TILT % CON C_I R_IU

1632708 6060 "BIGDB 65 33 1 0 59 24173022?7 6099 "BIGDB 60 45 2 0 70 71 n^'SOfl / l i n n niair:riea xo -z-» o n ^c <->«

32 6542 14TO rr <i

4. 60* 17312537 11148 "BIGDB 39 59 2 0 68 14 30 155. 60 2801845 6054 "BIGDB 50 37 2 0 97 14 30 17

~-6. 60 17301290 6097 "BIGDB 54 49 2 0 69 13 30 127. 52* 7045718 6095 "BIGDB 42 52 3 0 92 17 20 14

ARIOOU9

1 .le >C0792Bpk fij 5965

' •f/

4 I,- ,40

1* >BIGDBBpk flb 9999

57

40 ' " '

le >BI6DBt>pk flb 9999

01316 UESTON 032393SUB ROD DVC

5 97

67 69 81 """]• , i""" { 105 109 185 135 139

1,1, 1,1 l|l; / <-" > f ~*~60 80 100 120 140

l-Prop«n«, 2-H«thyl-, tri*«r <9CI>

*

67 69 83 v. 105112 119 135 139

e'o ' s'o ' 166 ' i2Q ' i4QCyclohexane, l-nethyl-3-pentyl- <9CI)

97

Scan 96313.41 win.

T i160

Scan0.00

153 168/ *"X

i60

Scan0.00

8388nin.

f.8393• in.

55

o^...,..67

e'669 81_

le >BI60B Cyclohexana,•k flb 9999

56

olC -,' 46"""67

1 e'o*9 Sir"^ /1 ' ' ' ' s'd '

991 160

111 125S /' 120 '

140

140

l-athyl-l-8>ethyl- <8CI9CI)97

99

••'"'ioo'"

153 168/ ^^160

Scan0.00

F.8248Min.

uill 126127 Er /Cf - f^111 'lib " 140 '160

reaUnknown #,2141935.0 Tentative Concentration is

1. 1-Propene, 2-methyl-, trimer C9CI )2. Cyclohexane,3. Cyclohexane,4. Cyc lopentane5. Cyclohexane,6. Cyclohexane,7. Cyclohexane,

13.00

1-methy 1-3-penty 1- (9CI)1-ethy 1-1-methy 1- (8CI9CI)1 ,1 ' -ethyl ideneb is- (9CI)

1-methy 1-2-penty 1- <9CI)1-methy 1-2-propyl- (8CI9CI)1-ethy 1-2-methyl- , cis- (8CI9CI)

0168 C12H24126 C9H18166 C12H22168 C12H24140 C10H20126 C9H18

Sample file: >C0792 Spectrum #:earch speed: 1 Tilting option: N

963No. of ion ranges searched: 42

Prob, CAS * CON #

3?4.5.6.7.

47*43*40*31*31*2525

775694754411028492690344132125441101742917964923777

8388839382488238839283418305

ROOT K DK #FLG TILT

2002112

CON C_I R_IU

"BIGDB"BIGDB"BIGDB"BIGDB"BIGDB"BIGDB"BIGDB

53363845354445

30615354624547

0000000

289958291959182

39385043435050

1717128877

36324119191513

A R I O O i

I .1m >C0792Bpk Rb 27569

43

j,'40

1 !• >BIGDBBpk Rb 9999

43

U-40le >BI8DB

^k Rb 999943

R1216 UESTON 032393 Scan57

Vi I'll / 160

57

,1 ?°e'o

SUB ROD DVC

71 136?*" , 98 108 126iL,,,/,,,,,!',,,,. ',,...]>.,..

80 100 ISOUndecane <8CI9CI>

13.58

141 155 170 171

979Min.

Ltt140 ' 160 ' i80

Scan0.00

«• 85-"" / 98 113 126 127 186157

' so ' 160 ' ieb i4o ' '"'ieo "' isUndecane, S-nethyl- <8CI9CI> Scan

570.00

6202• in.

L0

6096• in.

1 f ^1 71 as P3 I 69^ f" { 99 113 126 127 155 170 f

40 "i le >BI6DB1 k Rb 9999

j;40

1 " "g'b " 80 100 120 140 160 lib

Octane, 2,4,6-tri«athyl- <9CI> Scan0.00

57

?ie'o

71. / 99 113 i£fi ia7 141 1B6

80 ' l6b ' 120 '

6004Min.

E.140 160 180

Unknown #,3rea « 447233.0 Tentative Concentration

1. Undecane (8CI9CI)2. Undecane, 2-methyl- (8CI9CI)7. Octane, 2,4,6-trimethyl- (9CI)4. Decane, 6-ethy1-2-methyl- (9CI)5. Undecane, 4,6-dimethyl- (SCI)6. Decane, 2,9-dimethyl- (8CI9CI)7. Nonane, 3,7-dimethyl- (8CI9CI)

is 40.00

156 C11H24170 C12H26156 C11H24184 C13H28184 C13H28170 C12H26156 C11H24



1.2.3.4.5.6.7.

Prob. CAS * CON # ROOT

6250*4342393635*

11202147045718620163796210821817312822100217117302328

6202609560046163395760946100


82496761635451

15451838353835

DK *FLG TILT \ CON C_I R_IU

1212

0000

100929595

27303827

25191714

44283219

84 31

f l R I O O l S I58 47

1211

71 31 16 221933

1 *1« >C0792

o1. ...,..i

la >BIGDBBpk fib 9999

57

LL40le >BISDB

~.»k fib 999957

i /840 '

! le >B!8DBi ..k Rb 9999

R1216 UESTON 032393SUB ROD DVC

7170 ;**• 85 98 112125 139 141 155

, — jl / / / X -^ t60 80

Dodecan*

^r1 ?60 ' 80

Undecane,

7170 - 85

60 80

Undecane,

100 120 140 160, 6-»athyl- <8CI9CI>

98 112ig6 140 155,HV,,,,|f,,,,,"Tl ^ '100 120

3,6-diwethyl-

98 1131271 . .1'! , , , 1 | M. , I ..">?

100 1203,5-di»ethyl-

•'••i4o"""i4o<8CI>

141 155

140 ' 160

<8CI)

Scan 99913.79 Min.

169 184 EiifimTrVO

180Scan 86110.00 Min.

169 184 E

' 180

Scan 39550.00 Min.

169 184 E,, ,,,7 r0

180Scan 87540.00 Min.

57

0^7 70

J n - M J - M MVo""1 6d - 1"^s'o^111

99,(100

11/

2127

120

128

1«

140

(T '

155

160

169-415T0

Unknown #,4382884.0 Tentative Concentration is 55.00rea

1. Dodecane,2. Undecane,3. Undecane,4. Undecane,5. Undecane,6. Decane, 2 , _ , _7. Decane, 2,5,9

6-methyl- (8CI9CI)3,6-dimethyl- (SCI)3,5-dimethyl- (8CI)2,6-dimethyl- (8CI9CI)4,6-dimethyl- (8CI),6,8-trimethyl- (9CI),5,9-trimethyl- (9CI)

184 C13H28184 C13H28184 C13H28184 C13H28184 C13H28184 C13H28184 C13H28

Sample files >C0792 Spectrum #: 999"earch speed: 1 Tilting option: N No. of ion ranges searched: 49

4.5.6.7.

Prob.

95*86*83*83*76*67*67

CAS # CON # ROOT K DK *FLG TILT CON C_I R_IU

6044719173012891731281117301234173128226210826362108229

8611395587548612395739283927


84574682514458

13405220474833

0221221

0000000

f l R I O O I 5 2

9095100756910093

3351281212

72605751453434

95352178262325

> tie >C0792Bpk fib 6208— 43 57

fl!216 HESTONSUB ADO DVC

71

033393 Scan 101313.93 win.

164 1840 ' 1 t

4*0 '!• >B16DB

Bpk fib 999943

4*0 ' " ' '

le >BI6DBbpk Ob 9999

. 43

j,,l,,,40

i !• >BI6DB> .k fib 9999

43

1 HI -l'l'

60 80t100

1 I ' l l I l l l T i l ||7>I/"||||'|I120 140

D«can«, 5-propyl- <8CI>

" i 8572 f 99 112126 1£8 140

e'o " ' " s'dNonane ,

">J»n..*. ' i»rrr. , . . j .60 80

. , . . „ . .' ' " 120 ' ' " '140 ' ' '

2-*e thy 1 -5-propyl- <8CI>

85^ 99 112126 iae 140

' l6b 1 ' 'i20 ' 140 ' '

/ -K*160

155

' lib

155

"ikbl-Und«c*n«, 4-»«thyl- <9CI>

i | in i7n o180

Scan 40030.00 *in.

i!40180 °

Scan 40040.00 Kin.

. J.180Scan 13219

0.00 Min.

j ( 57 71 L.j / -^- 85 FI i j 72 ^ 97 111 126 128 140 168 1701v.'i1.... ..'i'.... .-1'i'rT.. .-i1! .....<.....?".. .rTifrr.. .rrT........... rrrrrr.. f.i I • ft »| i i* i | i i it | r i i <i i i » • I * » » • i « r • i | r* i i i * i i * * * i l i f t » • i i i I II I II I i i i * i i | l I '40 60 80 100 120 140 160 180

Unknown #,5rea » 129554.0 Tentative Concentration is

1. Decane, 5-propyl- (SCI)2. Nonane, 2-methy1-5-propyl- (8CI)3. 1-Undecene, 4-methyl- (9CI)4. Nonane, 5-butyl- (8CI9CI)5. Nonane, 3-methyl-5-propyl- (SCI)6. Hexadecane (8CI9CI)7. Decane, 2,3,6-tl- imethyl- (9CI)

12.00

184 C13H28184 C13H28168 C12H24184 C13H28184 C13H28226 C16H34184 C13H28

Sample file: >C0792 Spectrum *: 1013earch speed: 1 Tilt ing option: N No. of ion ranges searched: 42

Prob. CAS # CON * ROOT

1.2.3.4.5.6.7.

86*6362*49*464436

1731262831081171746303901731263931081182544763

62238124

40034004

1321913257615961466165


93716356656870

18323657405238

K DK *FLG TILT

212222

A R | 3 O O I 5 3

CON C_I R_I«J

0000000

95938880959595

10172633212528

59302520171714

72304133171513

. . 1*Bpk-

>C0792Qh 6633

01216 UESTONSUB ROD

032393DVC

Scan14.03

1022Min.

^ 43 .

: lOBpk

' lebpk

j,,li ,40

>BIGDBfib 9999

43 5

1 'oi,!,>BIGDB

Fib 9999

71

60 8'd

85/

Und«c*n«,

V. 7170 I"""

ij ( A60 80

85

1

Und«cane,

97/

- i'i-100

111 127/ "' i£b

3,8-diM*thyl-

99/iob

1131270< *"*120

2,3-di*ethyl-

137 140•- —.,,.... .,.1

<8CI)

•i1411*"

140<8CI9CI>

155 jj 3

•"iko"1"178/ ,ISO

Scan0

155 156,„,,,,,,„,

.00

180Scan0.00

6154Min.

£to

6156Min.

43 57

1 leu,.k

JU,Vo ">BI60B

flb 9999

> 71

60 80

85

' 'Codec ana

99

l6b' '

HI 125

' 120

140

••'•••i40"'

, 4-mathyl- <8CI9CI>

169. „£„ ..... L

180Scan0.00

3765Min.

57 7170 I-"" 85

60

99 112127. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .80 100 ISO 140 160 180

Unknown #,6rea « 136079.0 Ten ta t ive Concen t r a t i on

1. Undecane, 3 ,8-d ime thy 1- ( S C I )2. Undecane, 2 ,3-dimethy 1- (8CI9CI)3. Dodecane, 4-methyl- ( 8 C I 9 C I )4. Decane, 6-ethy 1-2-methy 1- (9CI)5. Dodecane, 2-methy 1-6-propy 1- (9CI)6. Undecane, 4,6-dimethy 1- (SCI)7. Dodecane (8CI9CI)

is 12.00

184 C13H28184 C13H28184 C13H28184 C13H28226 C16H34184 C13H28170 C12H26



4.5.6.7.

Prob.

494342*413736*36

CAS # CON #

17301303173127756117971621082185504508417312822112403

6154615637656163624439576229

ROOT

"BIGDB"BIGDB11BI GOB"BIGDB"BIGDB"BIGDB"BIGDB

K

73644980854773

DK #FLG TILT CON C_I R_IU

35485719345128

0011202

AR I 00 I 51*

0000000

647061100717876

42383842375144

17171414141012

52322939245527

il« >C0792 fll216 WESTON3pk flb 11355 SUB flDO

032393DVC

Scan 106014.43 ttin.

43

j,4*0 '

55

' 01« >BIGDB P«

71^ 81

80

85

C 97

fr100111 126 139 140 158

' 120 ' 140 160ntan«, 3-«thyl-2,4-di»«thyl- <8CI9CI>

3pk flb 9999

167 182 C

180Scan 59180.00 Hin.

43

i40

f57

.„,(,60

le >BIQDB-.jk flb 9999

« 83

80

9599

£66Undecane, g,4-di«

113 128

' 120 ' 140 ' 160»ethyl- <8CI9CI)

fiso

Scan 61570.00 «in.

43

.140

57

.1.60

le >BI6DB

71•X 83T' "*

80

85rDodecana

.rk flb 9999

99

100

113 i" 135 141 155/ ^ / I120 140 160

, 5-»athyl- C8CI9C!)

169*rl180

Scan 61080.00 Bin.

43

i40

\ 57

•|l60

71• 83

1 x.

80

85

•f98

100

113 126

120 140 160

169H

fo180

Unknown #,7rea « 179256.0 Tentative Concentration is 16.00

1. Pentane, 3-ethyl-2,4-dimethy1- (8CI9CI)2. Undecane, 2,4-dimethy1- <8CI9Cn3. Dodecane, 5-methyl- (8CI9CI)4. Hexane, 2,3,5-trimethy1- (8CI9CI)5. Heptane, 2,4-dimethy1- (8CI9CI)6. Pentane, 2,3,3,4-tetramethyl- C8CI9CI)7. Nonane, 5-methyl- (8CI9CI)

128 C9H20184 C13H28184 C13H28128 C9H20128 C9H20128 C9H20142 C10H22

Sample file: >C0792 Spectrum #: 1060~earch speed: 1 Tilting option: N No. of ion ranges searched: 43

Prob. CAS # CON #

1.2.3.4.5.6.7.

48*46*4030252120

10688771731280017453939106953022132321674738915869859

5918615761025919592059676176


57696359405444

26393732522845

ROOT K DK #FLG TILT \ CON C_I R_I

0311102

0000000

967492861007656

54383550505652

16171610755

73352326143214

A R I O O I 5 5

I ll«Bpkg

V

1 ImBpk

>C0792H 11893A^Vj

J

43

01216 UESTON 032393sue ROD DVC Scan.14.50

/ 57 71

41d"""1

/ ^

60]

>BI6DB

^ 9/3^••s'b'"1"Dod«c*n«

flb 9999

j

43

100

111 121

'"ifeo""140 149 167

,nh, „(,,„,,>140 160

, 4-M«thyl- <8CI9CI)

180 184, , rm . /, , ,1 iibScan0.00

1067Min._

:0

3765Min.

/ 57 71

,, ,„"40

i lebpk

(.:60

>BIGDB

185^ 97

,,..,-..A,,Tr80

Undecane.flb 9999

43

99

l6b'

112 127S1 f

' 120 '8,8-dimethyl-

1« 155

140 ' 160

<8CI)

_, / 57 71

"4*6 " '

) le >BI6DBflb 9999

43.11 ;_»« —

40

' v.

6*6 " '1

8^ 86.......irrr;,••8'6 •••Pan tana, 2,

r"60]

85- 86

••s'o'11"1

99.<<*'iob

113 125

' "120 '3,3-triaathyl-

99

i6o

113 114,. JT.,.

141 155

' iio "'"lib"<8CI9CO

140 ' 160

169 184

' 180 '

Scan0.00

169 184-*•"* /' 180 '

Scan0.00

180

-0

6153Min.

i.5990Min.

f.

Unknown #,8rea *= 173386.0 Tentative Concentration is

1. Dodecane, 4-methyl- (8CI9CI)2. Undecane, 2,8-dimethyl- (SCI)3. Pentane, 2,3,3-trimethy1- (8CI9CI)4. Nonane, 3-methy1-5-propy1- (8CI)5. Decanes, 2,3,4-trimethyl- (9CI)6. Decane, 5-propyl- (SCI)7. Hexane, 3,3,4-trimethy1- (8CI9CI)

16.00

184184114184184184128

C13H28C13H28C8H18C13H28C13H28C13H28C9H20



Prob. CAS * CON * ROOT

4.5.6.7.

87*5445403736*35

611797117301256 .560214

31081182622381571731262816747312

3765615359906159400540033926


90695670404753

16353235526426

K DK #FLG TILT % CON C_I R_IU

ARIOOI56

0000000

707410056475649

12223032303246

55221916141211

89262323141931

1*1* >C0792 R1216 UESTONBpk fib 13945 , SUB fiOD DVC

<"*

" .1*40

/ 57""} 71 85

•j 72 f

'""•' •••'•"'so'11"1 1* >BI60B Und«can«, 2Bpk fib 9999

43 57

99 113 i

' 'i6b' " ' " 120 ',10-di*«thyl-

032393

27 141 154' **? "' ' " '140 " ' '

<8CI9CI>

Scan 107314.57 Min.

\ 163 169 184 :

160 "'" 180 "'Scan 159220.00 Bin.

99 H3 127 141J ,/

169 184A"4'd" ' 60 ''""d6" ''"'i6o ' 120 "'"'iVo'"'" 160 ' ' 180 "'

le >BI60Bbpk fib 9999

43 _-Dodecane, 2-methyl- <8CI9C1>

r

Scan 61490.00 Min.

1U 99 113 127 141f I f f 168 1842llU 11 | i 11 i [ in i ti i n - f i i ii| n-m in m in |i i ii in i

40 60 80 100 120

1 le >B!8DB Dec ana, 3,8-dinethyl-Lrk fib 9999

57: 43 '?! 35I ( > 72 --* 99 113 i

Vo'"'" 60'" "so' '' "'160 "'"l20

. 1 .... 1 .... 1 ..iL4Q

<8CI9CI>

27 141l56

''"'iVo'"'1

160 ' "180 'Scan

0.00

156 170rfiT...rfi ' . . . . . .160 180

i "

11149• in.

rto

reaUnknown #,9168025.0 Tentative Concentration is

,10-dimethyl- (8CI9CI)-methyl- (8CI9CI)-dimethyl- (8CI9CI)-dimethyl- (8CI9CI),5-dimethyl- (SCI)^6-dimethyl- (SCI)-methyl- (8CI9CI)

15.00

1.2.3.4.5.6.7.

Undecane, 2Dodecane, 2'Decane, 3,8Decane, 2,4Undecane, 3Undecane, 4Undecane, 3

184 C13H28184 C13H28170 C12H26170 C12H26184 C13H28184 C13H28170 C12H26

Sample file: >C0792 Spectrum #: 1073earch speed: 1 Tilting option: N No. of ion ranges searched: 42

1.2.3.4.5.6.7.

Prob.

95*76705852*52*52

CAS # CON #

17301278156097017312559280184517312811173128221002433

159226149

111496054875439576148

ROOT

"BIGDB"BIGDB"BIGDB"BIGDB"BIGDB"BIGDB11BIGDB

K

83665261403048

DK #FLG TILT CON C_I R_I

2635402658684

0222222

0000000

100157

668865100767676

581020192017

72454225202020

95231721161416

ila >C0792Dk^^ 39016^ ^ ^ !

fll£16 WESTON\7

SUB ODD DVC032393 Scan 1086

14.70 Min.•. 43 / 71

1 .f

4'0 '!• >BI6DB

3k flb 999943 '.u ," 40 '

le >BI8DBjk flb 9999

{ 85I ^

60 80Oc tan*

57

1 1 85

i.-J..... .60 80

97 107 "-3

"^ 7 r r^ i6o ' 120

126 141 155 165

140 160

, 2,3,7-triwethyl- <9CI)

97 H3"N . f* *

' i6o ' 120

Tridecane i 7-*ethyl-

i?6140 ' 160 '

<8CI9CI>

183198 E

180

Scan 39620.00 Min.

f180 '

Scan 108580.00 Min.

57. 43

otjl..,...»40

le >BI6DBik flb 9999

43

( 71

(1 irnflH iiiil?n. 1 .... 1 .... 1 ....60 80

Nonana

99 111 f~

' 100 120

127 140 154 169

140 ' 160

, 2,6-di»«thyl- <8CI9CI)

183198 f

180 'Scan 39560.00 Min.

1 f ' " I":o:J,,,,,,40

1 85l| 1 1 I ifl 1 1 1 jTt1! 160 80

97 111 H3"••X. *^.r^"100 120

127 141 156r,n .„<..., ..r., ...,,..140 160

to180 '

reaUnknown #,10506510.0 Tentative Concentration is 46.00

1. Octane, 2,3,7-trimethy1- (9CI)2. Tridecane, 7-methyl- (8CI9CI)3. Nonane, 2,6-dimethy1- (8CI9CI)4. Octane, 2,3,6-trimethy1- (9CI)5. Octane, 3,6-dimethyl- C8CI9CI)6. Nonane, 3,7-dimethy1- (8CI9CI)7. Heptane, 5-ethyl-2-methy1- (8CI9CI)

156 C11H24198 C14H30156 C11H24156 C11H24142 C10H22156 C11H24142 C10H22

Sample file: >C0792 Spectrum #:"earch speed: 1 Tilting option: N


Prob. CAS # CON # ROOT K DK #FLG TILT CON C_I R_IU

4.5.6.7.

8381*76*707066*60

62016346267301431730228262016335158699401730232813475780

396210858395639611104361003954

"BIGDB" B I GOB"BIGDB"BIGDB"BIGDB"BIGDB"BIGDB

636446555156.61

30474537383040

1222122

100158

0000000

878510391958273

41010671612

57534542423130

29432619194217

lit)pk >C0792fib 7473

A1216 UESTONSUB ODD

032393DVC

Scan15.05

1119Min.

55 %

1«3pk

I , „40

>BI8DBfib 9999

f

K , r6'd"""

1 I

s'o 'Cycloh«x*n«,

98 112 121r / 100 •iso"1"

140 151 168••(•••MMMirrrv140 160

l-browo-4-Mthyl- <8CI9CI)

1771ft

•••iSo"'Scan0.00

8214• in .

9755 -

le*pk

. k

j" . ,.>BI6DB

fib 9999!

40 '>BI8DB

Rb 9999

( r60 '

81<80

Cyclohexane,

55

i r1H-1

S

..f.a'd '

J? 1

100 '

19 122

120 '

135s*i4b ' 160

l-ethyl-l-»ethyl- <8CI9CI>7~ >1 98 3

rT r100,2,4-Triazola,

.11 126

120 '

1-athyl-

r-^

140 ' 160

(8CI9CI)

176 179

"iso"1Scan0.00

180.Scan0.00

8248• in.

f.8219• in.

5B *i_1 « f f

.,L,, „.„!,40 60

82i.lf.ni80

i rp100 ' 120 " ' "iVo"""ito"""iso111fo

Unknown #,11rea - 124497.0 Tentative Concentration is 11.00

1. Cyclohexane, l-bromo-4-methyl- (8CI9CI)2. Cyclohexane, 1-ethy1-1-methy1- (8CI9CI)3. lH-l,2,4-Triazole, 1-ethyl- C8CI9CI)4. 5-Nonen-4-one (8CI9CI)5. Furan, 2,5-dihydro-2,2,4-trimethy1- (8CI9CI)6. Cyclohexane, l-bromo-2-methy1- (8CI9CI)7. Oxazole, 4,5-dimethy1- (8CI9CI)

176 C7H13Br126 C9H1897 C4H7N3140 C9H160112 C7H120176 C7H13Br97 C5H7NO

Sample file: >C0792 Spectrum #search speed: 1 Tilting option: N


1.2.3.4.5.6.7.

Prob.

3836*36*33*31*3130*

CAS * CON *

62944024926903167787043206477023230797629439920662833

8214824882198278822482138222

ROOT


K

44393140355028

DK *FLG TILT CON C_I R_IU

38526538524181

0232223

0 1000 730 1000 1000 940 850 100

40332640403633

14121410101012

25191319171713

A R I O O I 5 9

1 ile >C0792Bpk Jit 55881^LA 43 '

4*0I U >BIGDBBpk fib 9999

, 43 '

UJ40

! le >BISDBbpk fib 9999

43 «,u.,.*40

! le >BISDBtr.k fib 9999

R1216 UESTON 032393SUB fiOD DVC

57

' "5. „1 --^98 99 112 127 141 155163

ri in i ' ( l i i 1 1 1 ri 1 1 iTirTm i i r iTni i u 1 1 in/nn 'f A 1 1 1 160 80 100 120 140 160

Dacane, 5-propyl- < 8 C I >

7 71""S 85

^97 99 J^LS 126 140 155

60 80 ' 100 ' 120 ' 140 ' 160

Tridecane < 8 C I 9 C I >57

7^ 851 ^j 98 99 113 127 141 155169

, A I1, *>"~" ^ / / / ^60 80 100 120 140 160

Dacana, 6-ethyl-2-»«thyl- <9CI)

Scan 112715.13 m i n .

177 184 E..(,.rrr;..ro180

Scan 40030.00 M i n .

184 [. . rr^- 'M'H?180

Scan 62500.00 M i n .

184 185 :

180 'Scan 61630.00 M i n .

85 98 99 113 126 141 155

40 ""6'0"' '"ft"" 160 •"iao11" 140 ' 160

rea

1.2.3.4.5.6.

Unknown637549. 0 Tentative Concentration is

Decane, 5-propyl- (SCI)Tridecane (8CI9CI)Decane, 6-ethy 1-2-methy 1- (9CI)Dodecane (8CI9CI)Decane, 2,3 ,5-t r imethy 1- (9CI)Tetradecane, 1-iodo- (8CI9CI)

58.00

7. Undecane, 4,6-dimethyl- (SCI)

184184184170184324184

C13H28C13H28C13H28C12H26C13H28C14H29IC13H28

Sample file: >C0792 Spectrum f=:©arch speed: 1 Tilting option: N


5.6.7.

Prob.

87*85*8381767474*

CAS # CON #

17312628629505

62108218112403

622381131921894117312822

4003625061636229616461993957

ROOT


K

65726385689165

DK #FLG TILT CON C_I R_IU

46413616353733

2021212

0000000

665810067777076

5395781113

63375753453939

44892249234944

flRIOOISO

•U* >CQ7923pk flb 4929

!• >BI6DBBpk flb 9999

7

B1216 UESTON 032393SUB flDO DVC

Sc*n 114215.29 *in.

85 112 1S6 137 HO 151 16565 182 fr01|M...,.MI|I.,M

40 60. J .ugJ , -I1; f

100 "isb '• "lib"1'1/

"iib"" ii o180

Ethanona, l-<3-«thylcyclobutyl>- < 9 C I >

' 55| °° •»*.l f 1

1 .)! .197 111 186 127

83 85 97 113126

Scan 39810.00 nin.

4'0 " 60le >BI8DBk flb 9999

.43 /1 /

40 ' 60

le >BI8DBk flb 9999

80Decane

"*x 8583 f

' ' e'o 'Octane, 2

160 i20 ' i40 iebi 5-propyl- <8CI)

99

100

112 126 12

' 'iab ' '8 140

140 '

155

"'iib",3,7-triaathyl- <9CI>

'"•'ieb10

Scan 40030.00 »in.

f.' 180

Scan 39620.00 Kin.

1-fH)80 100 120 140 160 180

Unknown #,13rea « 142459.0 Tentative Concentration is

1. Ethanone, 1-(3-ethyIcyclobutyl)- (9CI)2. Decane, 5-propyl- (SCI)3. Octane, 2,3,7-trimethy1- (9CI)4. Ether, 1-hexadecenyl methyl (SCI)5. 4H-l,2,4-Triazole, 4-ethyl- (9CI)6. Nonane, 2-methyl-5-propy1- (SCI)7. 2-Pyrazoline, 1,4,5-trimethy1- (SCI)

13.00

126184156254

97184112

C8H140C13H28C11H24C17H340C4H7N3C13H28C6H12N2

Sample f i l e : >C0792 Spectrum #:"earch speed: 1 T i l t i n g o p t i o n : N


Prob. CAS * CON * ROOT K DK *FLG TILT CON C_I R_IU

1.2.3.4.5.6.7.

21*20171515*1513*

5633571817312628620163461551914943183557310811717423112

3981400339623939822640048274

"BIGDB"BIGDB"BIGDB"BIGDB" B I GDB"BIGDB"BIGDB

54656961285535

51462463534844

2202120

0000000

77838266508840

58516558605665

5543333

31145312151236

A R I O O I 6 I

hilaBpk^

I laBpk

• lebpk

1 le. <k

>C0792flfc 13019

aVl 43^ •3 /

li,40>BI8DB

flb 9999

O'A ,40

>BIGDBflb 9999

it40>B!6DB

flb 9999

1 43H /

° 4*0 ' '

57

JU6057/

60

57

JU6057

J

A1216 MESTON 032393SUB ROD OVC

71{ *5 98 112 127 140 154 155

80 ' l6o ' 120 ' 140 ' 160

Tridacana, 6-Mathyl- <8CI9CI)

/ ?5 98 111126 140 154 155

80 ' l6o ' 'l20' ' '140' ' '160

Nonane, 3,7-dimethyl- <8CI9CI>

71/ 851 / 97 113 127 141 156

' 8!0 ' 'l6o . ' 'l20 ' 140 ' 160

Undacana, 3,6-dimathyl- <8CI>

71/ 35 98 113 12 141 154 155

8*0 ' ibo ' 120 ' 140 ' 160

Scan 115115.39 min.

[-169 182 198 1<r, . < , . \ h180 200

Scan 86330.00 min.

169 183 [^.,,. .. •*? , ,--,.,— JL.Q

180 200

Scan 61000.00 Min.

.,..,f.180 200Scan 39550.00 Min.

169 184 C

' 180 ' 200

rea

1.2.J.4.5.6.

Unknown177296.0 Tentative Concentration is

Tridecane, 6-methyl- (8CI9CI)Nonane, J ,7-d imethy 1- (8CI9CI)Undecane, J f6~d imethy 1- (SCI)Undecane, 3 ,5-d imethy 1- (SCI)Dodecane, 6-methyl- (8CI9CI)Undecane, 2-methyl- (8CI9CI)

7. Octane, 2,7-dimethy 1- (8CI9CI)

16.00

198156184184184170142

C14H30C11H24C13H28C15H28C13H28C12H26C10H22

Sample File:earch speed:

>C0792 Spectrum #:1 Ti11 ing opt ion: N


123!4.5.6.

Prob.

7669*60606058*52*

CAS * CON * ROOT K DK *FLG TILT % CON C_I R_IU

13287213173023281730128917312811604471970457181072168

8633610039558754861160958726

"BIGDB"BIGDB"BIGDB" B I GDB"BIGDB"BIGDB"BIGDB

68555451494741

37314347484754

2022223

0000000

925610010010088122

A R I O O I 6 2

6351111151719

45263030302520

21661513122613

<.laJpk >C0792fib 9047

iOOOO-j 43

M1*

Jpk

1*spk

lar k

40 '>BI8DB

fib 9999

! 41

40"">BI8DB

fib 9999

JC40

>BI6DBfib 9999

-j 41

JL40

01216 UESTON57/

1 ?1

M „.....,(.

83

(,

SUB ROD DVC032393

98 in las 139 149 15S

160 ' 120Cycloh«x*n«, p«ntyl-

55

60 "

83

140 160<8CI9CI>

j 97 111 126131 1B* 1551 t t i .^r ^^^ ^* .

's'o "" f\ i M I 11100 120

Cyclohexane, octyl-

55

J ".•I'I'MM.I.'I...60

83

(1-Butana,

55

67

60

83

JL80

• ••. n. ii K!.i 77140 160

<9CI>

97 112 125139/ f / ^~160 ' 120 ' 140"'" 160

2,3,3-tri«ethyl- <8CI9CI)

^8 100

' 100 " ' " 120 " ' '140 " ' " i'4o

Scan15

168 1?2

180

.86

198

200

Scan0

156

" '180 '

.00

200Scan0

168

" ' 180 " '

.uu

196

200Scan0.00

" ' " 180 200

1196win .

f,5646nin.

f5581Min.

1 ' ' '

I

5587Min.

1,

Unknown #,15rea - 146626.0 Tent at ive Concen t ra t ion is 57.00

1. Cyclohexane, pentyl- (8CI9CI)2. Cyclohexane, octyl- (9CI)J. 1-Butene, 2,3,3-trimethyl- (8CI9CI)4. l-AzabicycloC3.1.Olhexane (8CI9CI)5. 2-Hexene, 4,4,5-trimethyl- C9CI)6. 2-Hepten-4-one, 2-methyl- (8CI9CI)7. 2-Octen-4-one, 2-methyl- (8CI9CI)

154 C11H22196 C14H2898 C7H1483 C5H9N126 C9H18126 C8H140140 C9H160

Sample file: >C0792 Spectrum #: 1196earch speeds 1 Tilting option: N No. of ion ranges searched: 43

Prob.

1.2.3.4.5.6.7.

333126»25*21*21*20

CAS # CON * ROOT

42929261795159594569285767

21* 557026192231924019860710

K DK *FLG TILT CON C_I R_IU

5646558155875336556956265598


58644525363533

37444554475252

2103001

000Q000

787077121756278

38415644595652

101278555

19225313393612

A R I O O I 6 3

Bpk!

'

I 1*Bpk

i leUwk

1 leL rk

>C07920 17760

•i 43 '

0liJ f" 40 '

>BIGDBflb 9999

!-i 43

JL40

7 71a60

R1216 WESTONSUB flOD OVC

®5 97 113 12?| / / /

s'o 'Dod«c«n*

;7 71, j. "60 ' 80 ' '

>BI6DB Dodecane,flb 9999

.43 / 71

1 f f 8!oU^ _ (-40

>BI6DBfib 9999

60 ' 80 '

Nonans ,

100

, 2,

99/

'i'oo2,6

99,/100

120

032393

141 155169/ / "-W

140

7,10-tri«»«thyl-

113 127 141..L / /

120' ' 140

,11-trimethyl-

113 127 141./ / /120 140

3-wethyl-5-propyl-

' 160 '

<9CI)

155169

' r!60" '

<8CI9CI>

155169/ NS

' '160 '

<8CI)

Sc»n16.23

183 197 20

180 ' 200 '

Scan0.00

183 197

'l80' ' '260' '

Scan0.00

182197 20

180 ' 200

Scan0.00

1231Min.

3988Min.

3984Min.

•M)

6159• in.

57

1 / I 85J I ' 99 112 121.,lJ, , .[.I., , .[!. , , .[, , ,.( , ,/, , ,/,40 60 80 100 120

127 141 IBS 184

140 160 180 200

Unknown147411.0 T e n t a t i v e Concen t r a t ion isrea

1.2.3.4.5.6.7. Dodecane, 4,6-dimethy1- ( 9 C I )

Dodecane, 2,7,10-trimethy1- <9CI)Dodecane, 2,6,11-trimethy1- (8CI9CI)Nonane, 3-methy1-5-propy1- (8CI)Decane, 5-ethy1-5-methy1- (SCI)Octane, 2,3,7-trimethy1- (9CI)Heptane, 3-ethy1-5-methy1- (9CI)

57.00

212212184184156142198

C15H32C15H32C13H28C13H28C11H24C10H22C14H30

Sample files >C0792 Spectrum #:"earch speed! 1 Tilting option: N


Prob. CAS * CON # ROOT K DK #FLG TILT CON C_I R_IU

4.

6.7.

89897878747170

74645980312955643108118217312742620163465289690961141728

398839846159

11185396239583960

"BIGDB"BIGDB"BIGDB" B I GDB"BIGDB11 B I GDB"BIGDB

97936760676469

12133856263041

1122012

0000000

951007388827178

0010

13146

66665555393842

69631912483017

A R I O O I 6 1 *

*la >C07923pk flb 26825

R1216 MESTON 032393SUB flOD DVC

Scan 126416.58 win.

- 43 57

U40

' < 71LU60

1« >BI6DB

35 «„/ 99 113

80 ' l6b' 'Nonacosan*

126 127 141

120 ' 140 '

(8CI9CO

155 169

160 ' 3

3pk flb 9999

189 198t

80 ' 200Scan 89050.00 win.

43 57-\ < f ?1A,, l /40 ' 6'0 '

Itt >BI6DB

85f 99 113

Jn,. ,,, .80 100

127 139 141

120 ' 140 '

155 169,-" /160 ' J

Hexatriacontane <8CI9CI>opk flb 9999

183 197 E/ / rn

.80 200Scan 61930.00 *in.

43 57

4'0

f f 71

. , 1, .1le >BI@OB

85/ 97 113', ft >

80 100

Tridccane

127 139 141

120 ' 140

<8CI9CI>

155 169

160 ' ]

, k flb 9999

183 197 E/ / To

L80 200

Scan 62500.00 nin.

43 57

1 f f ?Ij. J J40•"" 6'0 '"•

85f 99 113.,J..,.;>M..7r?.

80 160

127 128 141

120 ' i4o '15S 169^ /iio ' a

184 186 f

L80 ' 260

Unknown #,18rea - 289341.0 Tentative Concentration i»

1. Nonacosane (8CI9CI)2. Hexatriacontane (8CI9CI)3. Tridecane (8CI9CI)4. Hexadecane (8CI9CI)5. Tetradecane, 1-iodo- (8CI9CI)6. Decane, 2,3,5-trimethyl- (9CI)7. Dodecane (8CI9CI)

110.00

408 C29H60506 C36H74184 C13H28226 C16H34324 C14H29I184 C13H28170 C12H26

Sample file: >C0792 Spectrum #: 1264"aarch speed: 1 Tilting option: N No. of ion ranges searched: 43

1.2.J.4.5.6.7.

Prob,

78787878767676

CAS * CON #

630035630068629505544763

1921894162238113112403

8905619362506146619961646229

ROOT


DK *FLG TILT CON C_I R_IU

62626361877468

831005059412933

2222222

0000000

84758082738178

A R I O O I 6 5

555510810

55555555454545

13131312252724

l-ila >C079£Bp k Ajk. 75520

%•40

, !• >B1SDBBpk flb 9999

3394 /0 ' i'i . .1140

1 le >B16DBbpk fib 9999

J?40

, la >BI6DBur.k fib 9999

•I *aao"40

01216 WESTON 032393SUB flDD DVC

1

51 63 76 Q9 log us 128 139 ,f ^ (• ' f - lY * rl'

60 S'Q l6o' ik'6 140l,l'-Biph«nyl <9CI>

1

51 63 76 8? 102 ±15 126 13g

60 ' 80 ' i6o" '' 120 ''"lib"'

Naphthalene, 2-ethenyl- <9CI)1

51 63 7S 37 102 115 128 139

60 80 100 120 140

Acanaphthene <8CI>1.

51 63 76 87 98 115 126 139 j^ H \\' f f / { ' I'l

60 80 100 120 140

Scan 127116.65 Min.

54

!166 176 194 E/ / ->h0

160 180Scan 179350.00 Min.

54

156 L

160 " ' " 180

Scan 179440.00 nin.

04

1*~^~' 0160 180

Scan 179330.00 Min.

54

157 f'I"""* 0160 180

Unknown #,19rea « 502819.0 Tentative Concentration 190.00

1. l,l'-Biphenyl (9CI)2. Naphthalene, 2-ethenyl- (9CI)3. Acenaphthene (SCI)4. 1,4-Ethenonaphthalene, 1,4-dihydro- (8CI9CI)5. Benzene, (2,4-cyclopentadien-l-ylidenemethyl)- (9CI)

154 C12H10154 C12H10154 C12H10154 C12H10154 C12H10


Prob. CAS # CON # ROOT K DK *FLG TILT CON C_I R_IU

1.2.• Bfc4 l5 1P

82*79*35*

1 35*20*

9252482754383329

73224767338503

1793517944179331795617817

" B I GDB"BIGDB"BIGDB"BIGDB"BIGDB

7357504930

3244404359

02112

00000

5884364042

489475054

404811115

9234393515

ARI 00 I 66

il« >C07923pk fib 113894

j 39

- fcH

01216 WESTON 032393SUB ODD DVC

170141 * -.

51 77** 65 J- 94

' e'o' ' 'so' ' 'i6c

•s IXi? 128 ]. 155 1

i ^ |L 'r> 120 140 160

Scan 130517.01 Min.

J1 195 209.

180* ' '260'la >BI8DB

3pk fib 9999B«nz*n«, l,l'-oxybis- < 9 C I >

1I

170

Sc*n 202960.00 w i n .

*o 51 7739 ^ 65 ^ 94

1411 172

le40 60

>BI80Bs'o 'till

'l6o' ' i20" ' 140' ' '

'-Biphenyl 3-3-ol <9CI>k flb 9999

lek

j39 51 63

40 ' ' 60 '>BI6DB

fib 9999

3oJ

39 51 63S" f>* fi*"40 60

85/

TT102 3

100"^ /120

141

^Cl,l'-Biphanyl3-4-ol

85/

80

102 a"v .

100

•i? 127| <-120

141"

I ' l ' L ' l ' L ^ ™ »160 180 200

Scan 202980.00 Min.

170

152J .1

o" ' '<9CI>

^ 179

160 180 ' 260 ' "Scan 202940.00 Min.

170

152/

' 1401 '—

J1 184 186r^ .^' ~

•

llo' 'l8o' ' '260' ' "

Unknown #,20rea - 1856535. Ten ta t ive Concen t r a t ion is 710.00

Benzene, I7l'-oxybis- (9CI)Cl,l'-Biphenyn-3-ol (9CI)Cl,l'-Biphenyl]-4-ol (9CI)QuinaIdonitri le , 3-hydroxy- (8CI)1,4-Methanonaphthalene, 1,4-dihydro- (8CI9CI)[l,l'-BiphenyU-2-ol (9CI)

170 C12H100170 C12H100170 C12H100170 C10H6N20142 C11H10170 C12H100170 C12H100

Sample file: >C0792 Spectrum #: 1305~earch speed: 1 Tilting option: N No. of ion ranges searched: 40

Prob. CAS # CON * ROOT K DK #FLG TILT X CON C_I R_IU

1.2.3.4.5.6.7.

71*25*25*24*11*11*11*

10184858051892693

15462438445390.190437203849

20296202982029420312160982029315988


60222422342624

46687190536584

2223223

0000000

9691100100403961

13504943656165

38778222

37131412171412

A R I O O I 6 7

DEC-15-1992 00:13 FROM TO 4614916 P.02


PRIORITY POLLUTANT PLUS MOLYBDEHW

ANALYSIS HOt A 1217

CLIENT IB: S-?-A

METALS

AMTIMONY

ARSENIC

BERYLLIUM

CADMIUM

COPPER

LEAD

MERCURY

MOLYBDENUM

NICKEL

5E1EHIUM

SILVER

THALLIUM

ZINC

MDL (ma/Kz)

5.00

0.50

1.00

1.00

1,00

1,00

5.00

0.25

1.25

5.00

0,50

1.00

1.00

1.00

RESULTS (ttg

••Vtf.D.

19.9

N.H,

$3.5

11.7

74.2

269

Kt.D.

14.1

9.07

0.67

1.28

N.D.

2440

21 STOEfflXIftY ENVIRONMENTAL • N4D6PS CERTIFICATION «08031

A R I 0 0 1 G 8 TOTAL P.02

21ST CENTURY EnvironmentalSENIUOLATILE ANALYSIS DATA

JOB NUMBERSAMPLE NUMBER A1217 HESTONCLIENT ID S-2ADATA FILE >C0793

COMPOUND

N-NitrosodiMthylaiinePhenolbis(-2-Chloroethyl)Ether2-Cholorophenol1,3-Dichlorobenzene1 ,4-Dich lorobenzeneBenzyl Alcohol1,2-Dichlorobenzene2-Hethylphenolbis(2-chloroisopropyl)Ether4-MethyIphenoIN-Ni t roso-Di-n-Propy laiineHexach loroethaneNitrobenzeneIsophorone2-Nitrophenol2,4-DiMthylphenolBenzo ic Acidbis(-2-Chloroethoxy)Methane2,4-Dichlorophenol1 ,2 ,4-Tr ich lorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4-Chloro-3-Methylphenol2-Methy Inaphtha leneHexach loroeyc lopentadiene2,4,6-Trichlorophanol2,4.5-Trichlorophenol2-Chloronaphthalane2-NitroanilinaDiMthyl PhthalateAcenaphthylene3-Nit roan i line

MATRIX SoilDILUTION FACTOR 1.00OA BATCHDATE ANALYZED 03/24/93

••«•••••••••UG/KG

ND570NDNDND100 JND

1300NDNDNDNDNDNDNDNDNDNDNDNDND190 JNDNDND56 JNDNDNDNDNDNDNDND

MOL

3303303303303303303303303303303303303303303303303301600330330330330330330330330330330160033016003303301600

COMPOUND

Acenaphthene2,4-Oinitrophenol4-NitrophenolDibenzofuran2, 4-Dinitro toluene2,6-DinitrotolueneDiethylphthalate4-Chlorophenyl-phenlyetharFluorene4-Nitroaniline4,6-Oinitro-2-MethylphenolN-Nitrosodiphenylamne4-Browphenyl-phenyletherHexach lorobenzenePentachlorophenolPhenanthreneAnthraceneDi-n-ButylphthalateFluoranthenePyreneButylbenzylphthalate3,3'-DichlorobenzidineBenzo (a) AnthraceneBis(2-Ethylhexyl)PhthalateChryseneDi-n-Octyl PhthalateBenzo (b )FluoranthaneBenzo (k)FluorantheneBenzo(a)PyrenaIndeno ( 1 ,2 ,3-cd )PyreneDibenzo(a,h)AnthraceneBenzo(g,h,i)PeryleneBenzidinePyridine

UG/KG

190 JNDND110 JNDNDNDND180 JNDNDNDNDNDND940230 JND

1000850NDND54059 JB550ND390360410230 JND220 JNDND

MDL

33016001600330330330330330330160016003303303301600330330330330330330660330330

. 330330330330330330330330660•330


(J) Indicates detected below MDL(B) Indicates also present in blank(NO) Indicates compound not detected

ARIOOI69

"El «»emi-VOLATILE ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS

EPA SAMPLE NUMBER


Sample wt/vol: 30 Cg/mL) GM

Leve 1: LQLJ

% Moisture: 100


GPC < Y or N ): N

Column: D8-5

Number TICs Found 4

I II LJESTON II_________I


Lab File ID: >C0793

Date Received: NA


Date Extracted NA

Dilution Factor: 1

CONCENTRATION UhtfTS(ug/L or ug/Kg/UG/KG

CAS NUMBER

1 7934523 925244 101848

COMPOUND NAME

Ethane, 1 ,1 ,2 ,2-tet rach loro- (8CI9CI)UNKNOWNl,l'-Biphenyl <9CI>Benzene, l,l'-oxybi»- (9CI)

RT

8.3215.1116.6316.96

EST CONC

770600

23007300

A R I O O I 7 0

QUANT REPORT

Operator ID: JEFFOutput File: 'SC0793::EDData File: >C0793::D4Name: A1217 UESTONMisc: 032393

ID File: ID0323:: D5Title: hSL BNA STDLast Calibration: 930324 12:17

Compound

Quant Rev: 6 Quant Time:In jected at

Dilution Factor:

930324 13:56930324 00:40

1.00000

BTL*13


1)4)5)6)10)12)18)19)28)32)33)38)43)46)51)53)56)60)61)63)64)65)67)70)71)72)73)75)76)77)78)80)

*d4-l,4-Dichlorobenzene2— Fluoropheno 1Phenol-d5Phenol1,4-Dichlorobenzene1,2-Dichlorobenzene

*d8-NaphthaleneNitrobenzene-d5Naphtha lene2-Methylnaphthalene

*dlO-Acenaphthene2-FluorobiphenylAcenaphtheneDibenzof uranFluorene

*dlO-Phenan throne2,4,6-Tr ibromopheno 1PhenanthreneAnthraceneFluoranthene*d!2-ChrysenePyreneTerpheny l-d!4Benzo (a ) AnthraceneBis(2-Ethylhexyl )PhthalateChrysene*d!2-PeryleneBenzo(b)fluorantheneBenzo (k)FluorantheneBenzo (a )PyreneIndenoCl, 2, 3-cd) PyreneBenzo(g,h,i)Perylene

10.7.9.9.10.10.13.11.13.15.18.16.18.18.19.21.20.21.22.25.28.25.26.28.28.28.32.31.31.32.34.35.

3840798243885892633911431959488717930300705703658777142931006839

667382611614672715974815979

11471407124614151453153817671605177317832067242121222166241624372427274926682670273629913059

16167209832956269821242144583735714045619212312136538677399732894023289185435269286537236381476318664206537940854

76131252555184667524628802376

40.96.103.16.3.37.40.42.5.1.40.53.5.3.5.40.107.28.6.30.40.25.52.16.1.16.40.11.10.12.6.6.

0016289803760010606700867230270024229148006087247857006277349673

UG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/L IUG/L \UG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/L

959085768996878096•969484919896989893999789947995969289957873

* Compound is ISTD

TOTAL ION CHROMflTOGRflMU >C0793 35.0-500.0 an»u. H1217 UESTON 032393

spp t lOfto iBoo , 20,00 aspo 3^00

ata F i l e : >C0793::D4Name: A1217 WESTONMisc: 032393

Id F i l e : ID0323::D5T i t l e : hSL BNA STDLast C a l i b r a t i o n : 930324 12:17

Opera tor ID: JEFFQuant T ime: 930324 13:56I n j e c t e d at: 930324 00:40

Quant Outpu t F i le : ^00793 ::D3

BTL*13

REFERENCE STANDARD SPECTRUMFil« HNTST 40 N6 INTERNAL STDS Sc*n 353Bpk fib 100 SUB CLP NRM 8.12 Min.

150100-

•

Q-

/

« r/6 ?\? /7 » ^^ ?6. { i l.i fT . . ll 1 , ' A f

40 60 80 100 120 140

r

1 4.

-100

•

-o


-

5QQOJ 38

J /°v*

A1217 UESTONSUB

52 66 75 78 87j' / \ 1 /

60 ' 80 '

032393 Scan 66710.38 Min.

150/

115101 >«•?

100 120 140

-100•

»4K>

SflMPLE SPECTRUM (UNALTERED)Fil* >C0793 01217 UESTON 032393 Scan 667Bpk Ab 8144 10.38 Min.

150

8000

fr

52 56 75

,l.,,,(,4m,.^,40 60

J

78 87 "« 1±?x- x 101 ^ 3-"

t il,80 100 120 140

-100

)

Data Fi le : >C0793::D4Name: A1217 UESTONMi»c : 032393Quant Time: 930324 13:56I n j e c t e d at : 930324 00:40

Quant Ou tpu t F i le : ^C0793::D3




REFERENCE STflNDBRD SPECTRUM! k* >SXOSO HP^•flb 100

100-

0-

39/

" "46" '

BNfl Standard 50

50

"Z., . . . un . .

64

57

i l l r " i ,-H-Hr j r i ! I 'M60

50 ng'uLNRM

73i i i l i f i j70

81

1 " s'o

Mixed Base Neut

9283 j

••' "ft"1

95/'"iW

Scan 2848.75 M i n .

112t

I ."lib"1

-100

-0

SBMPLE SPECTRUM <BflCK8ROUND SUBTRPCTED)Fi le >C0793 R1217 UESTON 032393Bpk flb 9955

10000-

•

oJ

SUB

64

Scan 3827.40 M i n .

112

f « / " ,( « \ ? r ?l ^ J f l V » ^ M l | l l l i | l i

40 50l i | I I H | H I U I . l l | . n l f ^ l / n . i M t i l f f . i n i t . . .60 70 80 90 100

f

L.'"lib"

-100*

L

SflMPLE SPECTRUM <UNflLTERED)Fil* >C0793 R1217 UESTONBpk flb 9955

10000-•

a-

64

39 50 57 1

40 50 60 70

032393 Scan 3827.40 Min.

112

81 83 92 95

XrT '. /-100•

±j-O80 90 100 110

ata File: >C0793::D4Name: A1217 UESTONMisc: 032393Quant Time: 930324 13:56Injected at: 930324 00:40





REFERENCE STflNOflRD SPECTRUMFil* >SX050 HP BNfl' Standard 50 50 ng/uL Mixed Base N«ut Scan 427Bpk flb 100 NRM 11.66 Min.

99100-.;

o-J43 44 54 A* „_, r1' / 52 _> \ 6* 76 82 94

^ I ' 1 1 1 ! ' i f i ! • ' ;* 1 1 7-1 ' / f ' i (

f

\Vo ' B'O ' 60 ' 70 ' 80 ' 90 ' i6t

-100.•

0

SflMPLE SPECTRUM <BflCK6ROUND SUBTROCTED)File >C0793Bpk fib 14681

\10000-• 42 ** /

V-'l}!\}f40 '

01217 UESTONSUB

4 5£ 54 64 fig

/ ' \ ^r i-n'i II 1 Jf II /i i i li i | II 1

50 60

032393

71/ 76

l|l..l/..,.A..70 80

Scan 6119.79 Min .

99' -100

94

90 100

SflMPLE SPECTRUM <UNflLTERED>Fil« >C0793Bpk fib 14681

10000;

Q!

42

fl40

01217 UESTON

44 52 34 64 69

.',<."<. ',ih/f i l f i . .;/)|li50 60

71/

70

032393

76

/„„?„80

Scan 6119.79 Min.

99

94/ , i ,

-100•

-o........ i,.. 1 j-, -90 100

Data File: >C0793::04Name: A1217 UESTONMisc: 032393Quant Time: 930324 13:56Injected at: 930324 00:40

Compound No: 5Compound Name: Phenol-d5Scan Number: 611Retention Time: 9.79 min.Quant Ion: 99.0Area: 29562Concentration: 103.28 UG/Lq-value: 85

Quant Output File: '"C0793: : D3



REFERENCE STftNDflRD SPECTRUM

*

! >SX090 HP BNflflb 100

100-1

•

<H

39

It i

50

» f * l * l * * ' l

40

Standard

66

55 |)/ 1 II

.1 tllllll

' ' 's'o' ' '

60

67/

50 ng'uL nixed B**«NRH

94

75/

i-i'i i i i i i i i1 . . . . . . .

'

991 i

80 100

Neut Scan 43811.76 Kin.

123\

i • i i i i i i if -

-100•

t-o120

SftMPLE SPECTRUM <BRCK6ROUND SUBTRflCTED)File >COBpk Rb 3

sooojiT-

793635

39 50

..i l l ih. .,\40

fl!217

6655 "^

fiV

UESTON 03SUB

c

71 75

•I'iC -^-

2393

>4f

99/ 100

..,1 -s'o ' 166

Scan9.82

120

614Kin.

-100

-0

SflMPLE SPECTRUM <UNflLTERED>Fil« >C0793Bpk Rb 3635

4QQOq

SOQQ^"™

oJ

39/ 50if i "*****•* M H'[ M ** j1! '40

R1217 UESTON 038393

94

6655 S 71 75/ 11 f^ y/

l l l l . l l . I l l l f f f ) I 1| 4 l f t , . « ,.

r

99f 100\^f^ffff0fî..iir^

60 80 ' l66 '

Scan 6149.82 win .

' ifeo ' ' '

hlOO

.L-0


Compound No: 6Compound Name: PhenolScan Number: 614Retention Time: 9.82 min.Quant Ion: 94.0Area:. 6982Concentration: 16.98 UG/Lq-value: 76

Quant Output File: •*>C0793::D3



ARI00176

REFERENCE STRNDflRD SPECTRUMFilBpk• "BIQDBflb 100

100-"

J4'0

B*nz«n«, 1,4-dichloro- Scan 106467CLP FLT NRH NOH 0.00 Min.

146

J9 ?

6'6 ' so ' ibb

/111I,

150•

' iab ' 140 ' ieb '

-100

-0

SAMPLE SPECTRUM <BfiCKGROUND SUBTRACTED)Fil*Bpk

>CQ793flb 536

m

400-

0.43

40

01217

" ?N/360 ' e'd

UESTON 032393 Scan 672

84

4-frrr

SUB 10.43 M i n .146

111

F Ni6b ' ifeb ' iib ' ieb '

1-100•

-0

SRMPLE SPECTRUM <UNflLTERED>Fil« >C0793Bpk flb 536

m

400- 40

»' 'A,.'40

fll£17 UESTON

50 ?! ^5 84

rf, \\\i\ /^60 ' s'o ' i6c

038393

1

111

,k....,....,

Sc*n 67210.43 Min.

46' -100

150ir xv :w, ,,,,,>*iP..iib...,

Data File: >C0793:: D4Name: A1217 WESTONMisc: 032393Quant Time: 930324 13:56I n j e c t e d at : 930324 00:40

Quant Ou tpu t F i l e : 'SC0793::D3



Compound No: 10Compound Name: 1,4-DichlorobenzeneScan Number: 672Retention Time: 10.43 min.Quant Ion: 146.0Area: 1242Concentration: 3.03 UG/Lq-value: 89

ARIOOI77

REFERENCE STANDARD SPECTRUMJflte "BI3DB^•Ab 100

100-B

•

40

B«nz«n« .FLT

75r60 ' 80

1.2-dichloro-NRM NOM

111" 113

166 ' i2b

Scan 955010.00 nin.

146x -100

.

-0•""iW '

SAMPLE SPECTRUM <BACKSROUND SUBTRACTED)File >C0793Bpk Ab 7195

8QOO;""

4000

o_37

.(,.Vo '

A1317 UESTOH 038393 Scan 715

y 6i 7« ..ill .. ./!. jM'l'f

60 80

SUB 10.88 Min.146'

11184 "S 113/ 9? | J^

f*I' \^ 'T'1'l'l 'I r

KLQO1

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SAMPLE SPECTRUM (UNALTERED)Fil« >C0793 fll£17 WESTON 033393 Scan 715Bpk Ab 7195 10.88 »in.

14680u<:4000;

&•/ /° 61 7^J^ /* 97 ^j 113

.11... , ..iii ., ,{,. ,.,i|L .1,. .f M-iMi •• r ri i i i i i | i i i i j i i i i j i i . . | . i i i | i i i i i i i i i i i i i i i i i i i i i i i i ] i i i40 60 80 100 ISO 140

1y-100

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ata File: >C0793::D4Name! A1217 WESTONMisc: 032393Quant Time: 930324 13:56Injected at: 930324 00:40





flfilOOI78

REFERENCE STflNDflRD SPECTRUMFil«Bpk

t >DEH03flb 100

100-

0-42

1 | |'i i40

60 N6 STANDARD Scan 538

_, 685* \

.illnni'Hi60

SUB

78 80

1 1 1 I'|1-/TI I80

CLP NRM 11.20 Min.136

100 lOS1!! _.X f \ /

Tl I i t'i l'/'l'| 11 i i i'i i'li |'|-/'i . , . . . - , , , ,-..,.

t

140

100 120 140 160

-100

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SflHPLE SPECTRUM <BflCK6ROUND SUBTRflCTED)Fil« >C0793Bpk fib 17504

10000;: 42

fv rrf'i ....40

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54 *,? 76 *2 *>

60 80 10<

032393

1

108113 130

3 120

Scan 97413.58 »in.

36-100

163 iX'*

140 160

SftMPLE SPECTRUM CUNflLTERED)Film >C0793Bpk fib 17504

:10000

o142

40

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.4 68 82r ^ ?/'I'l'j-t'.j-! rl'i'l'fi . f pj-vi.60 80

/' "iob

032393 Scan 97413.58 Min.

136

108111 130

AS x--i

f

163

.\120 140 160

-100

-0


Compound No: 18 (ISTD)Compound Name: d8-NaphthaleneScan Number: 974Retention Time: 13.58 min.Quant Ion: 136.0Area: 37357Concentration: 40.00 UG/Lq-value: 87




ARIOOI79

REFERENCE STflNDflRD SPECTRUM

F >SX050 HP BNflflb 100

100-

:0-

42 50. i.iTi.. .. . I

40

Standard

54

[ 66

•M60

50 50 ns/'uL »ix«d Base N«ut Scan 547NRM 14.10 M i n .82

"*"*'•

70(., , i , , , .

ic

y 9*7 i" fi . .i. ' . i..-100ruu

•t-o

80 100 120

SAMPLE SPECTRUM <BflCK8ROUND SUBTRACTED)File >COBpk flb £

4000-

0-

793 B1217 UESTON057 SUB

82•*-*

54« 50 f 66 70i. .. i.l.... .r —40 60 80

032393 Sea11.92

? v r' 106 ' iô

n

2/

1

815• in.

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SAMPLE SPECTRUM <UNALTERED>Fil« >C0793Bpk fib 6057

-4000- 42 50

' 'Vo'

01217

54( 66

' '60'

UESTON 032393 Scan 81511.92 win.

82'Kv'

7012;

83 00 99 {/ 9^ y 112,< \S . f I,

-100

-o80 XvO d*cO

ata File: >C0793::D4Name: A1217 UIESTONMisc: 032393Quant Time: 930324 13:56Injected at: 930324 00:40





ARIOQ-180

REFERENCE STflNDflRD SPECTRUMFilmBpk

"BI6DB Naphthal«n« Scan 91203fib 100 FLT NR« N0« 0.00 Kin.

128100-

•

0-

102

...... . ...... ———————————————— I ————————— !

i

129r — "~"

-100•-0

40 ' 60 80 ' i6b 120 140 160

SfiHPLE SPECTRUM <BflCK8ROUND SUBTRACTED)File >C0793Bpk Pb 2825

™

2000-

x7 **W r""

01217 UESTON 032393 Scan 979SUB 13.63 Min.

128

10263 75 87 \

r

168

•100"

•-n

60 ' 80 ' i6b ' 120 ' 140 ' iebSflMPLE SPECTRUM (UNflLTERED)FiU >C0793Bpk Rb 2825

-2000-

1 40IV rfhfc

Vo'*1 '

01217 UESTON

51 64 75 53 1

,' f ' /60 80

032392

1

02V 108^ , , {. ,,,,., ,^l100 120

1

28

136

H J^

Scan 97913.63 Min.

|-100•

168 ;N.

160

Data Fi le : >C0793::D4Name: A1217 WESTONMisc: 032393Quant Time: 930324 13:56Injected at: 930324 00:40

Compound No: 28Compound Name: NaphthaleneScan Number: 979Retention Time: 13.63 min.Quant Ion: 128.0Area: 6192Concentration: 5.60 UG/Lq-value: 96

Quant Output File: /"C0793::D3



A R I O O I 8 I

REFERENCE STANDARD SPECTRUMK-BI6DBb 100

.00-j

.

40

Naphthalene.FLT NRM

60 80 ' 16b

2-Mthyl-NOM

1

115

""" '1...,...ifeb...,...

Scan 915760.00 Min.

42-100

143 '

CTiT,,,,,,,, 0 160

SftMPLE SPECTRUM <BflCK6ROUND SUBTRflCTED)File >COBpk fib A

400-

0-

79388

•

43

j ID i ,il|40

R1217 UESTON 032393SUB

57 1r71 9e 118 1

lvV""rf . " *\r ? \60 80 100 120 14

Scan15.39

42f

152 1t71 ii * i

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1147kin.

[-100

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SRMPLE SPECTRUM <UNRLTERED>Film >C0793 fi!217Bpk fib 807

57

fr

43

1 ,.\-[. .. .1,111 ri ' ' I"1 • i • • • • i •40 60

71**•

80

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r 9/ '\,\ . ,n,.i.,...i6b...

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Lll3J5 *?«<-' t -rI . I I . , . .

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154 *¥tlLt.\' iAo"

-100

^>

ata Files >C0793::D4Name: A1217 UESTONMisc: 032393Quant Time: 930324 13:56Injected at: 930324 00:40




Compound No: 32Compound Name: 2-MethyInaphthaleneScan Number: 1147Retention Time: 15.39 min.Quant Ion: 142.0Area: 1231Concentration: 1.67 UG/Lq-value: 88

AR 100182

REFERENCE STflNDflRO SPECTRUMFile >DEM03 80 N6 STflNDflRO Sc*n 799Bpk fib 100 SUB NRM 15.60 Min.

164100-1

•

0-

8042 54 j 10Q 108 122 132 V 1

1 |'f . . f ! \fl i , 1 ft 1 \ .'1 I'l'l'll'l I'j 1 i . . f. 1 lY, , . . n n . . i Wft | i . i'. , . M'l'l' -^1

f

\,40 60 80 100 120 140 160

-100•

-0

SflMPLE SPECTRUM <BflCK8ROUND SUBTRflCTED)Fil« >C0793Bpk flb 9574

10000-

' 42oV,,,

01217 UESTONSUB

54 66 81 82 «; /; / *t\ H'TrT* i

' 6*0 80 100

032393

136108 122 132 ,,i .'.,.. i^MrfriCiieo 140

Scan 140718.11 Min .

162-100

156 ;

-TT^Wjll^160

SflffPLE SPECTRUM <UNfl!_TERED>Fil« >C0793Bpk flb 9574

10000-

• 420-|r|.p|..j

40

(U217

8054 66 V/ / ],

n-6 'o"-'- in8

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82 x4 108-" / Jr°•n i \\ i .'ii 1 1 1 ii'i i

100

032393

122 132j S

I I *i 1'!***^*

120 140

Sc»n 140718.11 Min .

162100

156

. .^ 'HllllH-O160

Data File: >C0793::D4Name: A1217 UESTONMisc: 032393Quant Time! 930324 13:56Injected at: 930324 00:40

Compound No: 33 CISTD)Compound Name: dlQ-AcenaphtheneScan Number: 1407Retention Time: 18.11 min.Quant Ion: 164.0Area: 21365Concentration: 40.00 UG/Lq-value: 95




AH/00183

REFERENCE STANDARD SPECTRUM

F >sxfib 1

100-•

0-

050 HP BNA00

39 51./. /....,.

Standard

63 75/ /11 'i i'l'fwn'r

) 80

50

85/

1 1

50 ng'uL mix*NRfl

9<

"B

107? /0

180/1'ifivri1

120

d Basa N«ut19

. . 152133 146 /,.,(,r,.|,|/-^"

140ii i i ii i in

160

Sea.79172

J,

n

1,

827nin .

-100•

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SAMPLE SPECTRUM (BACKGROUND SUBTRACTED)File >C0793Bpk fib 19528

20000-

- 39 B

»;„/./40

fl!217 UESTONSUB

1 8563 75 y 99

. . . / .. ,.,. . . (. , tt60 80 3.00

032393

*°7 120 133 /.r T/, ,,,.,< .. r r120 140

Scan 184616.43 Min.172"" -100

ZLj^160

SAMPLE SPECTRUM <UNALTERED)Fila >C0793Bpk Ab 19588

20000-_

0-

OQ

4,40

51 ..y ba

60

A1217

75

8*0

UESTON

85 j.Q7/ " s

f fil|'>'ii'l'i'(yi'pri'|'<'i'i100

032393r

Scan 124616.43 Min.172

-1120 133 \ ;/ / X/120 140

1I'fl'i. , . . . . 1 . .

160

-100•

-0

ata Fi le : >C0793::D4Name: A1217 WESTONMisc: 032393Quant Time: 930324 13:56I n j e c t e d at: 930324 00:40

Compound No: 38Compound Name: 2-FluorobiphenylScan Number: 1246Retention Time: 16.43 min.Quant Ion: 172.0Area: 38677Concentration! 53.86 UG/Lq-vaiue: 96 . .,

Quant Output File: """C0793: :D3



REFERENCE STftNDflRD SPECTRUMFile "BI8DBBpk flb 100

100-

0-*'o '

fic«naphthyl«m«. 1.2-dihydro- Scan Q3329FLT NKn NOn 0.00 Min.

154

76

60 ' 80

,

155r"' l66 ' 120 ' 140 ' 160

-100

-SPMPLE SPECTRUM <BflCK8ROUND SUBTRACTED)File >C0793Bpk flb 1654

;

1000

0

39

<< ;1 1 1 1 1 1 140

01217 UESTONSUB

/ *3 7,6 87 98

60 80 10C

113N

032393 Scan 141518.19 Min.153

126

,< i'

f

167, N

-100

_n120 140 160

SflMPLE SPECTRUM <UNflLTERED>Fil*Bpk

1

>C0793flb 1654

OOO:

fr

40

40

fl!217 UESTON

J1 63

4 f60

'? 87 98

80 ' i66

113

N1

032393 Scan 141618.19 Min.153

162f\ .,(.,.

120 140 160

-100

0

Data F i le : >C0793::D4Name: A1217 UESTONM i a c : 032393Quant Time: 930324 13:56I n j e c t e d at: 930324 00:40

Compound No: 43Compound Name: AcenaphtheneScan Number : 1415Reten t i on Time: 18.19 m i n .Quant Ion: 153.0Area: 3997Concen t ra t ion : 5.72 UG/Lq-value: 94

Quant O u t p u t F i le : "C0793::D3



A R I O O I 8 5

f

REFERENCE STflNOflRD SPECTRUM'jbi "BIQDB Dibanzofuran•bb 100 FLT NRM NOM^ ^

100-

040 ' 60 ' 80 ' 100 ' 120

Scan 1326490.00 Min.168*""

139

....',....,....,..1 .140 160

-100

oSflMPLE SPECTRUM <BflCK8ROUND SUBTRflCTED)File >COBpk flb 1

lOOfr•

793 R1217 UESTON 032393178 SUB

39 ,„ 84 113 139s 55 63 74 y N^^ ^

40 60 80 ' ibb ' 120 ' 140

Scan18.69168•

"•i60'

1453• in.

-100

SflMPLE SPECTRUM <UNfiLTERCD>Fil* >C0793 fl!217 UESTON 032393Bpk fib 1178

1000

-r ? " ? / l" T40 60 80 100 120 140

Scan 146318.69 Bin.168

-100

-0

160


Compound No: 46Compound Name! OibenzofuranScan Number: 1453Retention Time: 18.59 min.Quant Ion: 168.0Area: 3289Concentration: 3.30 UG/Lq-value: 84


. BTL*13Quant ID File: ID0323::D5


flRIOOI86

REFERENCE STANDARD SPECTRUMFilm "BI6DBBpiO fib 100

100-

*63

4'd ' e'd '

9H-Fluor«n«FLT NRM

s'd ' i6b ' 12C

Scan 867370.00 atin.

166^ -100

139' r i i i k . ', ^M ' "0

\ ' 140 ' 160

SAMPLE SPECTRUM <BRCK6ROUND SUBTRACTED)File >C0793Bpk flb 1666

•

• 39

40

^ fl!21? UESTONSUB

69 so51 62 / 3

60 80 ' 16b

032393

111 115

\/••'•'igo11'1

Scan 153819.48 Mirt.166""* -100

139 149,,',(,,,/. „,,#«!<140 160

SAMPLE SPECTRUM (UNALTERED)Fil« >C0793Bpk Ab 1666

:lOOfr

o^*° 51

•&••••••••

A1217 UESTON

63 59 82 111

s'o ' 80 ' i&b '

032393

115

/L -120

Scan 153819.48 *in.

166>s

139 149

.( t ,111,

-100

-o140 ' 160

Data File: >C0793::D4Names A1217 WESTONMisc: 032393 •Quant Time: 930324 13:56Injected at: 930324 00:40

Compound No: 51Compound Name: FluoreneScan Number: 1538Retent ion-Time: 19.48 min.Quant Ion: 166.0Area: 4023Concentration: 5.27 UG/Lq-value: 91

Quant Output File: "C0793::D3



AR 1001 87

REFERENCE STRNDftRD SPECTRUM»>DEM03b 100

lOO-•

0^

fiS42 54 f

\\ f i i ' i ' | i1H| i i ! - | in40 60

80

80

•!•!••'so "

NG STANDARDSUB CLP NRM

y4 108 118m n l i ' i / f | l l ' l l ' i f f i

100 120

132 146 1/60

. , ( lT . ,»£l . . t fo . l140 160

Sc*n 101619.27 w i n .

188"*"•

168

^...rrkvi180

-100•

LQ

SAMPLE SPECTRUM <BACK6ROUNO SUBTRACTED)FileBok

>C0793Ab 11033

10000-

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A1217

52 66 8Q

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100 ' 1BO

032393

132 146. Y ,

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160 170

160 18

.87 nin.188/

1,

-100

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SAMPLE 8PECTRUH (UNALTERED)Fil*Bpk

>C0793Ab 11033

10000-

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. i ....

52 66X /HT

A1217

80

80

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94 102

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118/120

132• jfii. ,....,

146

140

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188

lf° 170Af,,tn.,,tv\WT .

/

!,

-100

-Q160 180

ta File: >C0793::D4Name: A1217 WESTONMisc: 032393Quant Time: 930324 13:56Injected at: 930324 00:40

Compound No: 53 (ISTD)Compound Name: dlO-PhenanthreneScan Number: 1767Retention Time: 21.87 min.Quant Ion: 188.0Area: . 28918Concentration: 40.00 UG/Lq-value: 98




A R I O O I

REFERENCE STANDARD SPECTRUMFile >SXQ5Q HP BNfl Standard §0 50 ng/uL *ix«d Bas« N«ut ScanBpk flb 100 NRM 24.28

330100-

1048Kin.

-100

37 62/ f_/_f t fVTTfr . ,To-V+V

40 80

91 111 141

SAMPLE SPECTRUM <BACK6ROUND SUBTRACTED)Fil« >C0793Bpk Ab 2211

2000-

i&40

01217 UESTONSUB

J? 141

90 ^11 j 170

80 ' 120 160 '

032393

197 S/3 25°,/ i . . . | | t . . . fc, .200 240

Scan 160520.17 w i n .

330irMI :.....Z.ilô280 320


2000-

iIm'j40

A1217

62

90 111

80 1 ' 120

UESTON

1411 170

n'Hjii.197/200

032393

223 £CO

A 4lP'iU* '"280

Scan 160620.17 Min.330jj

T I•'"320

-100

-Data F i le : >C0793::D4Name: A1217 UESTQNMisc: 032393Quant Time: 930324 13:56In jec t ed at: 930324 00:40

Quant Ou tpu t Fi le : /XC0793: : D3

Quant ID F i l e :Last C a l i b r a t i o n !

BTL*13ID0323::D5930324 12:17

Compound No: 56Compound Name: 2,4,6-Tribromopheno1Scan Number: 1605Retention Time: 20.17 min.Quant Ion: 330.0Area: 5435Concentration: 107.24 UG/Lq-value: 96

ARIOOI89

REFERENCE STflNDflRD SPECTRUMJgj "BI8DB•))b 100^ P

100-*

0-

63 75

40 ' 60

Ph«n*nthr«n« Scan 85018FLT NRtt NOM 0.00 Min.

178

> 89f 151 176

**~

18*6 ' 100 ' 120 ' 140 ' 160 ' ISO'

-100'

-0

SAMPLE SPECTRUM (BACK8ROUND SUBTRACTED)File >C0793Bpk fib 11073

10000;

• 50

o- • 40

01317

63 75 76

"S f rl6*0 ' 8'6

UESTON 032393SUB

89 in igfi 128 15>f r \ ^\./ . .' 100 ' 120 ' 140

Scan 177321.93 Min.178

152 i7gX A?L.......,J,.... .

-100•

L —— _«160 180

SftMPLE SPECTRUM <UNflLTEREO>Fil«Bpk

>C0793fib 11073

10000-.

J40

i(/r40

63.,;>60

fl!217 UESTON

75 ?6 89 ii!

-lvp>Ci"'"i--^n--^r---80 100

126\

Wr+*l120

032393

128 151

'''f... '"!••140

152

V-160

Scan 177321.93 Min.178

176

1L_ . .t.180

-100•

-0


Compound No: 60Compound Name: PhenanthreneScan Number: 1773Retention Time: 21.93 min.Quant Ion: 178.0Area: 26928Concentration: 28.22 U6/Lq-value: 98

Quant Output File: 'NC0793::D3



4R/OOI90

REFERENCE STflNDflRD SPECTRUMFil« "BIBpk Rb 1

100-•

^

8DB00

76^

.„.,.,,... i....,.,1!,.,,40 60 80

ftnthracan* SeaFLT NRM NOtl 0

89 151 175

f* il 11 160 ' 120' ' iVo ' ieo

Ji 12.00177

x-"

1180

3127kin.

-100•

-Q

SAMPLE SPECTRUM <BflCK6ROUND SUBTRRCTED>File >C0793Bpk flb 2227

2000-- 39 51

0-- I'M m I'M mi40 , 6C

01217 UESTONSUB

63 76 8* 100

> ' 80 ' 100 '

032393

114 126 150 1

.. ife.rf !.,..„ W>.YI..

Scan 178322.03 Min.178X -100

si 174 ;,,nM>,H,M,K>160 180

SOMPLE SPECTRUM <UNflLTERED)Fil« >C0793Bpk Rb 2265

2000-

- 40

Jd1"1'

R1217 UESTON

__ 63 ?6 89 10

? / -f^ X /• • ,.„• ' • i • ""•!•• ™i • • • ' Ji; • • •60 80 100

032393

0 114 126 180

. |'i <•.,.. .fi !....!•.. f\120 140

Scan 178322.03 Min.178x 100

151 174

160 ' 180

Data File: >C0793::D4Name: A1217 WESTONdisc: 032393Quant Time: 930324 13:56Injected at: 930324 00:40

Compound No: 61Compound Name: AnthraceneScan Number: 1783Retention Time: 22.03 min.Quant Ion: 178.0Area: 6537Concentration: 6.91 UG/Lq-value: 98




A R I O O I 9 I

REFERENCE STANDARD SPECTRUMJ^^^ "BI6D6 ' Fluor an thane• b 100 FLT NRM NQM

100-"

0-4

1011

10 ' 60 ' 8*0 ' l6o ' 120 ' 140 ' l4o '

Sc*n 2064400.00 *in.SOS"

' • I ' I1|180 200

-100"

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SAMPLE SPECTRUM (BACKGROUND SUBTRACTED)Fil« >C0793Bpk Ab 8512

SQOtf

:50

\40

A1217 UESTON

..- -. 88 101Ow f f

6*0 ' 80 ' 100

SUB

110 122/ X180 '

032393

149 150\/

140 r 160

174

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Sc*n 206725.00 Min.202*"*

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-100•

-o1 'eoo "SAMPLE SPECTRUM (UNALTERED)Fil* >COBpk Ab 8

5000:

4

793 A1217 UESTON 032393 Sc*n512 25.00

202

40 A 00 IQI 111 122 149 150 174s 59 74 88 y* . ,. . * v I

2067nin.

-100

.n'i'tf| i — * — |""'"T r l"!***! — i"f i T|" i ' f'"V ' | — *— "r — t 'f1 » — j111! — | "!' 1 — i — i' • nf* »(0 60 80 100 120 140 160 180 200

ata F i l e : >C0795::D4Name: A1217 WESTONMisc: 032393Quant T ime : 930324 13:56I n j e c t e d at : 930324 00:40

Compound No: 63Compound Name: FluorantheneScan Number: 2067Retention Time: 25.00 min.Quant Ion: 202.0Area: 23638Concentration: 30.48 US/Lq-value: 93




A R I O O I 9 2

REFERENCE STRNDflRD SPECTRUMFil« >ISTDBpfc Rb 100

100-

- 62 66 9£ l°t01.. . ,'. .*, ... >.,. pM40* ' ' ' ' ' 'so' ' ' ' '

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Scan 136725.95 sin.240""] -100

208 212 ;

266 ' 240SflMPLE SPECTRUM <BflCK8ROUND SUBTRACTED)File >C0793Bpk flb 6241

4000-'. 54

40' '

01217 UESTON 032393SUB

i nf. 120 156 16066 78 i:i? / 132 N. ~/ 180i-l -I'r'n"; 'H-i'fV 1*1" ['i I'l'i ft i"f i i i r1'

80 120 160

Scan 242128.70 Min.240j -100

208 212 [\S -J--i-t V i'! I'Tlpf"' 0

200 240SftMPLE SPECTRUM <UNflLTERED>Filtt >C0793 A1217 UESTONBpk flb 6241

.

4000-44 '7 78 l?t "°i»

40 80 120

032393

> "s ° 180

' 160

Scan 242128.70 win.240*>

208 212

...V-r*

[-100•

-a260 ' 240

Data F i l e : >C0793::D4Name: A1217 UESTONMisc: 032393Quant Time: 930324 13:56In jec t ed at: 930324 00:40

Compound No: 64 CISTD)Compound Name: d!2-ChryseneScan Number: 2421R e t e n t i o n Time: 28.70 m i n .Quant Ion: 240.0Area: 14763Concen t ra t ion : 40.00 UG/Lq-value: 99




A R J O O I 9 3

REFERENCE STflNDflRO SPECTRUMJflte "Bi^•nb i^^

100-

.<H

t

SDB00

4i/

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SflMPLE SPECTRUH (BACKGROUND SUBTRflCT£D>File >C0793Bpk fib 6371

_4000-^x

40

81217

63 75 88•-• -i •- .' ^ - J

' 8*0

UESTONSUB

101^ 123 136

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032393

150 "i-i" i r'i i •

160

Scan 212225.57 Min.

202" -100

189 218 '

,.^,A^'+200

SfiMPLE SPECTRUH <UNOLTERED>Fil« >C0793Bpk flb 6371

-

4000: 40

0:fri y,,,

R1217 WESTON 032393

y7 75 88 301 123 135 150 1?^t »' .4 «* *.. ft f

' 80 120 ' 160

Scan 212S25.57 »in.

202"""I -100

189 218 i

v>. .4. ^200

L__.ta File: >C0793::D4

Name: A1217 WESTONMisc: 032393Quant Time: 930324 13:56Injected at: 930324 00:40

Compound No: 65Compound Name: PyreneScan Number: 2122Retention Time: 25.57 min.Quant Ion: 202.0Area: 18664Concentration: 25.60 UG/Lq-value: 97

Quant Output File: /SC0793: :D3



AR I 00 I 91*

REFERENCE STRNDfiRO SPECTRWFila >8X060 HPBpk Rb 100

100-

! 54• ^k

0- i«, ,iV !•

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« .0 "« 1££ 136 "

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SRHPLE 8PECTRUH (BRCK6ROUND CUBTRRCTEO>C0793

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plOOtie

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SAMPLE SPECTRUM <UNRLTEKED>rtU >C0793Bpk Rb 6793

;

600QJ 4Q

*£*

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66 00 *\ 14f 136/ / > ;J /' "«Vm ilo ''

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fc«n £166£6.03 ftln.£44^ -100

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Data File: >C0793::O4Name I A1217 UIESTONMi»c: 032393Quant Time: 930324 13:96Injected at: 930324 00:40

Compound No: 67Compound Name: Terphenyl-dl4Scan Number! 2166Retention Time: 26.03 min.Quant Ion: 244.0Area: 20693Concentration! 92.67 UG/Lq-value: 89

Quant Output Filet AC0793siD3

BTL*13Quant ID Files IDQ323:iD?

Last Calibration: 930324 12U7

AR100195

REFERENCE STftNDfiRD 8PECTHUH" l "BI

flb 1

100-

8DB00

4V '

B«nzCalanthrac«n«FLT NRH NOn

114

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;

6853•in.-100

•260 ' £40

80HPLE SPECTRUM <BflCK8ROUNO SUBTRACTED)Filt >C0793Bpk fib 2613

.8000-

- 39fr < j ..„40

R1217 UESTONSUB

88 101 114 123/ T.TS.-_/..j _/ 1 .

80 120

032393

17B f1601*3 x 200"/ J { .f S1*0 200

Scan 241628. SB Bin.C28* -1001

>07 ;^4

240SIMPLE SPECTRUM <UNflLT£RED>FiSa >C0793 P1217 MCSTON 032393 Scan 241*Bpk ftb 2613 28. £6 Bin.

228

2000-0-

*4 69 *<f 101 "-4"3 1B0163 y 800 5?7JiJ. .y. . .....i.- * -..J1|I1'7 .. . / / C .. .L r. . _J40 80 120 1*0 260 24

-100••jj0

ata File: >C0793::04Name: A1217 UESTONttisd 032393Quant Time: 930324 13:96Injected at: 930324 00:40

Quant Output File: "CO?93:tD3

BTL#13Quant ID File: I00323MD5

Last Calibration: 930324 12U7

Compound No: 70Compound Name: Benzo(a)AnthraceneScan Number! 2416Retention Time: 28.65 min.Quant Ioni 226.0Area: 7940Concentrat iont 16.24 UG/Lq-values 94

A R I O O I 9 6

REFERENCE STflHDflRD SPECTBUHFiUBpk

"BI60Bflb 100

100" 57•x

*»'-•

1 , fi-B«nz«n«d i c ar boxy 1 i eFLT NRtt

149

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SflMPLE SPECTRUM <BflCK6ROUNO SUiTRftCTCD)FileBpk

>C0793Ab 330

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43

A fl 1

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71 83 104/ f /

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183

1

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"7 £03 2581 / .A

-100•4

1 lio ' 266 ' £40 'SfUIPLC SPECTRUM <UNALTERED)File >C0793Dpk Ab 431

4440O-

>lu440

A1217 UESTON

149

? ** 104 "3 f Y 7

I|MJ|, . )tjC. .i.u , . , ,(. , J, ,80 ISO 1*0

038393 Bean 843728.87 »in.

£07 £28 £^f

200 ' 840 '

-100

-Data File: >CO793::D4Name: A1217 WESTONMisc: 032393Quant Tims: 930324 13:96Injected at: 930324 00>40

Quant Output F i l a i AC0793:iD3

BTL#13Quant ID Filai 100323::D5


Compound No: 71Compound Nama: Bis(2-EthyIhexyl)PhthalateScan Number: 2437Retention Time: 28.87 min.Quant Ion: 149.0Area: 854Concentration: 1.78 UG/Lq-value: 79 .

ARIOOI97

REFERENCE STflNOPRD SPECTRUMF "BISOB Chry$«n«fib 100 FLT NRM NOM

100-

tr r

t'o ' 80 ' 120 ' 160 '

Scan 2180190.00 Min.228

1-100

-0260 ' 240

SAMPLE SPECTRUM <BflCK6RQUND SUBTRACTED)File >C0793Bpk fib 2571

..

2000-

Ji£,

R1217 UESTON 032393

88 101 11363 V / /

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134 151 *x/ f

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200Wrv,200

Scan 242728.77 Min.228"' -100•

217 •

- YJP r-i"-f "0

SRMPLE SPECTRUM CUNfiLTERED)Fil* >C0793 81217 UESTON 032393Bpk fib 2606

m

2000-

i

44 69 88 . 01 113 189/ \ \. ? / 13* 151 \

Jj ^ T i ...Ji •,_,!.. f f . ^tO ' 80 120 ' 160

200

200

Scan 242728.77 Min.228|1

"jl

f-100•

-o240

at a File: >C0793::D4Name: A1217 WESTONMisc: 032393Quant Time: 930324 13:56Injected at: 930324 00:40

Compound No: 72Compound Name: ChryseneScan Number: 2427Retention Times 28.77 min.Quant Ion: 228.0Area: . 7613Concentration: 16.57 UG/Lq-value: 95




flRIOOI98

REFERENCE STANDARD SPECTRUMFil« >DEM035pk Ob 100

100-"

! 52

40

80 N6 STANDARDSUB CLP NR«

13864 88 102 "Tl 1t8 163 180 204.'..,. S{ .JL. ..Jl.. JI....N .. .'. .' ..-/.

80 120 160 200

Scan 168629.8? stir,.264""] -100

I '288 232 ;

246SAMPLE SPECTRUM <BF»CK8ROUND SUBTRACTED)File >C0793Bpk Ab 3901

4000-"

" 45O-T^W40

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66 *? 108•frr rM A-I..ir^r.i.li

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800

Scan 874938.14 nin.864j -100I

232

4..4T..840SAMPLE SPECTRUM <UNALTERED>Fil« >C0793Bpk Ab 3901

4000-

- 44

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A1817 UESTON

7 81 108 "A )37 «?

' 80 180 ' 3.46

038393

807 888180 < v

' ' ' ' 206 ' ' ' '

Scan 874938.14 Bin.864^ -100

838 ;i*»i. .*4 -°840

Data File: >C0793::D4Name: A1217 UESTONMisc: 032393Quant Time: 930324 13:56Injected at: 930324 00:40

Compound No: 73 <ISTD)Compound Name: d!2-PeryleneScan Number: 2749Retention Time: 32.14 min.Quant Ion: 264.0Area: 12525Concentration! 40.00 UG/Lq-value: 96




ARIOOI99

REFERENCE STflNDRRP 3PECTRUHMfe "BI6DB•|Rb 100

W^100-

-

o-40 ' ' ' '

B*nzC«3accph«nanthrylentt Scan 205992FLT NRM NOfl 0.00 Min.

126

. . . . . . . . . . . J .80 120

252

|

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£53

-100

•

-o160 ' 266 ' 240 ' 280 '

SflMPLE SPECTRUM <BflCK6ROUND SUBTRACTED)File >C0793Bpk flb 1729

;

1000:"0;

57 ?1-N. */•

LI 1 L 4rO ' 8

01217 UESTON 032393SUB

85 126 149/ **--* 141X 179 S08224M 'i'i*.*fl »/'*'' i ' ii'fn-i'i'X'i fî ' i i

120 160 200 240

Scan 266831.29 Min.

252

4

t

269, /

-100.•

-ft

SflMPLE SPECTRUH <UNflLTERED>>C0793

Bpk flb 1729

1000-

81217 UESTON 032393

252

Scan 26681.29 »in.

-100

150 191v v £07 224'< iC0793::D4Name: A1217 UESTONMisc: 032393Quant Time: 930324 13:56Injected at: 930324 00:40

Quant Output File: AC0793:sD3



Compound No: 75Compound Name: Benzo(b)fluorantheneScan Number: 2668Retention Time: 31.29 min.Quant Ion: 252.0Area: 5518Concentration: 11.62 UG/Lq-value! 92

A R I 0 0 2 0 0

REFERENCE STflNDfiRD SPECTRUMFil« "BISDBBpk Pb 100

100-

4*0 '

BvnzotkJf luoranth«n«

126

80 ' 120

FLT NRM NOM

' 160 ' 200 '

Scan 2070890.00 Min.

252/

253r*-100

-O240 ' 280 '

SAMPLE SPECTRUM (BACKGROUND SUBTRACTED)Fil« >C0793Bpk Ab 1841

2000:

: 43

°¥

A1217

83 126

.i;/,,,80 120

UESTONSUB

1E7 150X X•"•'ieo1

032393

y° 207224

£00 ' ' ' £40

Scan 267031.31 win.

252-100

I", "8 ^r,,.. ..,


2000-

^

0

44/

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A1217 UESTON 032393 Scan £67031.31 win.

252

69 y5 ^ 135 y* */* 207 224

f

268 3°L f \

80 120 160 200 240 280

-100

.

-0

Data F i le : >C0793::D4Name: A1217 WESTONMisc: 032393Quant Time: 930324 13:56I n j e c t e d at : 930324 00:40

Quant Ou tpu t F i l e : /SC0793: :D3



Compound No: 76Compound Name: Benzo(k)FluorantheneScan Number: 2670Retention Time: 31.31 min.Quant Ion: 252.0Area:. 4667Concentration: 10.77 UG/Lq-value: 89

ARI0020I

REFERENCE STANDARD SPECTRUMjj^ "BI80B^•flb 100^^

100-

.

40

B«nzoCa]pyren«FLT NRM NOM

1/13/26

80 120 160 ' 200

Scan 503280.00 Bin.

252( -100

}* mfl

240 280SAMPLE SPECTRUM (BACKGROUND SUBTRACTED)File >C0793Bpk Ab 1655

loofr 42

40• \ !

80

A1217 WESTONSUB

5 "3l/26 150 *>6:

120 ' ' ' 160 '

032393

ljs£200

Scan 273632.00 ttin.

252( -100

) 224 281 I

/ 4 x'*240 280

SAMPLE SPECTRUM <UNALTERED>Fil« >C0793Bpk Ab 1655

"

.__ : 441000- fil40

59/ 8S

1 s'o

A1217 WESTON

!/ V i/49 /120 ' 160

032393

11 191 207

' 200

Sc»n 273632.00 Kin.

252( j-100I .

224 281 ;

240 ' 280

Data File: >C0793::D4Name: A1217 WESTONMisc: 032393Quant Times 930324 13:56Injected at: 930324 00:40

Compound No: 77Compound Name: Benzo(a)PyreneScan Number: 2736Retention Time: 32.00 min.Quant Ion: 252.0Area: 5246Concentration: 12.34 UG/Lq-value: 95




AR I 0020-2

REFERENCE STflNDflRD SPECTRUMFile "BI6DBBpk Rb 100

100-•

0-40' ' ' ' '

Ind«noClFLT

138

j' 'e'o' ' ' ' ' ' 120' '

,£ ,3-cd3pyr«n«NRM NOM

' ' ' 160 ' '200

Scan 1933950.00 Min.

276

i

f -100•

-o240 280

SAMPLE SPECTRUM <BflCK6ROUND SUBTRACTED)File >C0793Bpk flb 613

-400-: 4440 '

01217 UESTONSUB

1377? 5 II3 ""1 146\/.{ ,./.+ Lf80 120 160

032393

191 207

" g o o 1 "

Scmn 299134.68 Min.

276{ -100

;

• M,"?..*-"240 280

SPMPLE SPECTRUM <UNflLTERED>Fil.Bpk

>C0793 01217 UESTONRb 795

44.

50O1

0:t

tf

81 138

73/ 113 S. , Ul . I.U.U. ! * .../I. i Ul

*Q ' s'o ' iko146

T f •1 'ifeo'

032393

207191 (t L200

Scan 299134

253

' 246 ' ' '

.68 Min.

271

i*28

t-100.

-00

Data F i l e : >C0793::D4Names A1217 UESTONMisc: 032393Quant Time: 930324 13:56I n j e c t e d at: 930324 00:40

Quant O u t p u t F i l e s ^00793::D3

BTL+13Quant ID File: ID0323::D5


Compound No: 78Compound Name: IndenoCl,2,3-cd)PyreneScan Number: 2991Retention Time: 34.68 min.Quant Ion: 276.0Area: 2880Concentration: 6.96 UG/Lq-value: 78

ARI00203

REFERENCE STRNDRRD SPECTRUMj fe "BI6DB•fib 100

^^^m100-

.

T-n-rr-40

B«nzoCghi ]p«ryl«n«FLT NRM NOM

138

J80 ' 120 160 ' 200

Scan 1912420.00 min.

276i -100:f -Q

240 280

SfiMPLE SPECTRUM <BfiCK6ROUND SUBTRRCTED)File >C0793Bpk fib 486

400-

- 44

40

01217 WESTONSUB

13878 83 *-s 156 i

80 120 160

032393

189 209

' ' ' ' ' 266 ' ' ' '

Scan 305935.39 Min.

276

i' -100

^240 ' 280SfiMPLE SPECTRUM <UNfiLTERED>Fil* >C0793Bpk fib 746

44

J f500-

4*0

69 *,|yfo' l lV'i

80

01217 UESTON

1 1?*i 156 177/ 1 \ ^

120 160

032393

207191 I\ / L

200

Scan 305935.39 M i n .

27JS-1QO/ |

253 1 ;

240 280

ata File: >C0793::04Name: A1217 UESTONMisc: 032393Quant Time: 930324 13:56Injected at: 930324 00:40




Compound No: 80Compound Name: Benzo(g,h,i)PeryleneScan Number: 3059Retention Time: 35.39 min.Quant Ion: 276.0Area: 2376Concentration: 6.73 UG/Lq-value: 73

ARI00201*

FiU >C0793 01217Bpk flb 4880

UESTON 032393 Scan 470SUB ADD OVC 8.32 Min.

831 .

1 37 47 61 70

40 60 80

1 95 99 130 131 16*

' l6b ' 120 ' 140 ' 160 '

1 .!• >BI6DB Ethane, 1,1,2,2-tetrachloro- (8CI9CO Scan 6228Bpk Rb 9999 0.00 Min.

83

1? f40 ' 60 ' 80

I 95 99 130 131 164

100 ' 120 140 ' 160

I le >BI8DB Ethane, 1,2,2-trichloro-l.l-dif luoro- <8CI9CI> Scan 5975Bpk fib 9999 0.00 Min.

83

j 44 47 67 69

4'd 60 ' 80

1 138149 153 16fJ- ' -" r,To100 120 140 160


1. Ethane, 1,1,2,2-tetrachloro- (8CI9CI)2. Ethane, 1,2,2-trich loro-l,l-dif luoro- (8CI9CI)

166 C2H2C14168 C2HC13F2

Sample file: >C0793 Spectrum *:Search speed! 1 Tilting option: N


1.2.

Prob.

95*58*

CAS * CON # ROOT

79345354212

62285975

"BIGDB"BIGDB

K DK #FLS TILT S CON C_I R_IM

9051

1351

02

00

9869

1518

6425

9625

A R I 0 0 2 0 5

f i l * >C0793«6124C

440

) .1* >BI8DBBpk fib 9999

4Cu40

I le >BIGDBBpk flb 9999

4C

F)1217 UESTONSUB PD

» 57

"""1 83 J^5 98. i . - i V i i i i i i - l i i i T M i l l i i i i i M i . !

60 80 100

Tridtcan*

> 577i 85

I 83 •"-" 99

60 80 100

Oodecane3 57

032393D DVC

112 127 141

120 140

<8CI9CI>

113127 131 141/i """"i 'x """

120 ' 140

<8CI9C1>

Scan 112015.11 Min.

155 163 184 C

160 ' 180

Scan 62500.00 »in.

155 169 ley

160 ' 180

Scan 62290.00 »in.

71 85

ftl

M.J,..:.!40 60

le >B!6DBjk Ob 9999

43 «,

1 83 98', *|S r -,-v

80 100

Undecane

112 127. . t r. . . . .Tii. |

120<8CX9CI>

141 155 l^°172f

140 ' 160 180

Scan 62020.00 *in.

71,y , j,, •"•"I 83 3.|...y6l..

" 98

l6o

113 127

120 "lib"156 157

•"•'lib'"1"™i180

rea

1.2.3.4.5.6.

Unknown41548.00 Tentative Concentration is

Tridecane (8CI9CI)Dodecane C8CI9CI)Undecane (8CI9CI)Decane, 6-ethy 1-2-methyl- (9CI)Undecane, 4,6-dimethy 1- (SCI)Undecane, 3,5-d imethy I- (SCI)

18.00

7. Decane, 2,3 ,5-t r imethyl- (9CI)

184170156184184184184

C13H28C12H26C11H24C13H28C13H28C13H28C13H28

Sample f i l e s >C0793 Spectrum #:earch speed: 1 Tilting option: N


4.5.6.7.

Prob. CAS # CON * ROOT K DK *FLG TILT

88*76767671*71*67

6295051124031120214

62108218173128221731281162238113

6250622962026163395787546164

"BIGD8"BIGDB"BIGDB"BIGDB"BIGDB"BIGDB"BIGDB

78747063595568

35272736394335

02222

00000

ARI00206

5079961007510073

CON C_I R_IU

39781011

13

4745454538

14 38

932725223632

34 23

File >C0793Bpk flb 27797

.1-4'o'

1 -1« >BI6DBBpk flb 9999

j 39O'l'i • • •40

! le >BI6DBbpk flb 9999

J40

40

f le >BI6DBLKk flb 9999

3 39

40

fl!217 HESTON 032393SUB flOO DVC

51 63 65 rs 871 e'o ' s'o '

98 102 115 128 129

l6o 120l,l'-Biph«nyl <9CI>

63. 63 £» 76 Q-p/ %^ / /' 60 ' 80

98 102 115 126129{ f"" -X {-^l6o' ' ' ' '126'

Naphthalene, 2-ethenyl- <9CI>

51 63^ 65 76 Q7

60 80 >

101 102 115 128 129

100 ' 120 '

flcanaphthane <8CI>

51 63 73 ^6 87

60 80

98 102 115 126129

100 120

Scan 126616.63 Min.154

139 , f• fTiMi'll'rO140

Scan 179350.00 Min.154

139 t•*x' ill iFni4o" ' '

Scan 179440.00 Min.154

.™,.)L140

Scan 179330.00 Min.154

i-39 1 c•** i< I 'fo140

rea

1.2.

Unknown #,10160809.0 Tentative Concentration is 70.00

Ijl'-Biphenyl (9CI)Naphthalene, 2-ethenyl- (9CI)

J. Acenaphthene (SCI)4. 1,4-Ethenonaphthaiene, 1,4-dihydro- (8CI9CI)5. Benzene, (2,4-cyclopentadien-l-y 1 idenemethyl )-

154 C12H10154 C12H10154 C12H10154 C12H10

(9CI) 154 C12H10

Sample file: >C0793 Spectrum #:jearch speed: 1 Tilting option: N


Prob. CAS # CON # ROOT K DK *FLG TILT CON C_I R_IU

1.2.J.4.5.

82*74*53*24*20*

9252482754383329

73224767338503

1793517944179331795617817

"BIGDB"BIGDB" B I GDB"BIGDB"BIGDB

7366554535

3235354754

02112

00000

5574403340

5011385353

40391975

9245442717

ARI00207

: x im

3pk .

1

1 _laBpk

i labpk

la

i

>C0793M^51830

^n -so 51

.'" / •"4*0 ' e'd

A1217 MESTON 032393SUB flOD DVC

7? ln">. 85 94 102 "r . ' ' ( ' {

80 100

>BI8DB B«nz«n«, l,l'-oxybis-fib 9999

iU ? 65•j f J . x

40 ' " ' ' 60 ' ' '

>BISDBflb 9999

J 39 51 63ftfi i ** *^

40 ' ' 6*0 " '

>8I8D8flb 9999

j 39 51 63

40 ' 60

»

Unknown #res " 500038.0

77^ 85 94 102 "

| / / / ," 'so ' ' '' ' 'ioo " ''Cl ,1 '-Biphsny n-3-ol

76 85 89 102 ^.***S. .' ^^^ f '.

e'd ' i6b 'Cl ,1 '-8iphanyl 3-4-ol

.. *^ 142a* If

120 ' 140

<9CI)

141 1425 129 -^.^

*N If,iab"'1 "'iio'

<9CI>

L5 122 141 142***"* .t^***

iab ' iio 'C9CI)

76 85 89 102 115 131 14^ 143

80 ' l6o 120 140

T e n t a t i v e Concen t r a t i on is

Scan 129716.96 M i n .

170

155 f/ I , h 0160

Scan 202960.00 n in .

170/ ,r

154 L(.jif . ..,..,! ltL0

160Scan 80298

0.00 Hin.170

153 I

^•i6oll'|l|f'0Scan 202940.00 nin.

170

193 EiTTll II !•!• MK>

160

220.00

1. Benzene, l,l'-oxybis- (9CI)2. Cl,l'-Biphenyl]-3-ol (9CI)3. [l,l'-Biphenyl3-4-ol (9CI)4. Cl,l'-Biphenyl]-2-ol (9CI)5. 1,4-Methanonaphthalene, 1,4-dihydro- (8CI9CI)6. !H,3H-NaphthoEl,8-cd]pyran C8CI9CI)

170 C12H100170 C12H100170 C12H100170 C12H100142 C11H10170 C12H100

Sample file: >C0793 Spectrum *:Search speeds 1 Tilting option: N


Prob. CAS # CON * ROOT K DK #FLG TILT CON C_I

1.2^?fl45.6.

74*. 26*1 26*" 20*

18*15*

1018485805189269390437

4453901203849

202962029820294202931609815988

"BIGDB"BIGDB"BIGDB"BIGDB" 8 I GDB"BIGDB

652724264424

416371654384

222223

000000

9398100383857

154241545858

3988543

441414142312

flRI002Q8



ANALYSIS NO: A 1218

CLIENT ID: W-l

METALS MDL («g/L) RESULT (»R/L)

ANTIMONY

ARSENIC

BERYLLIUM

CADMIUM

CHROMIUM

COPPER

LEAD

MERCURY

MOLYBDENUM

NICKEL

SELENIUM

SILVER

THALLIUM

ZINC

0.05

0.005

0.01

0.01

0.01

0.01

0.005

0.0005

0.013

0.05

0.005

0.01

0.01

0.01

N.D.

N.D.

N.D.

N.D.

N.D.

0.01 4|

0.009

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

0.39

21ST CENTURY ENVIRONMENTAL • NJDEPE CERTIFICATION #08031 ——H R I Q02 0 9


21ST CENTURY EnvironmentalSEHiyOLATILE ANALYSIS DATA

A1218 UESTONU-l

>C079fl


Uatar1.

03/23/93

COMPOUND UG/L MDL COMPOUND UG/L

N-NitrosodiMthylaiinePhenolbi5(-2-Chloroethyl)Ether2-Cholorophenol1.3-Dichlorobenzene1.4-DichlorobenzeneBenzyl Alcohol1,2-Dichlorobenzene2-Methylphenolb is(2-chloroisopropy1)Ether4-MethylphenolN-Nitroso-Di-n-PropylaiineHexachloroethaneNitrobenzeneIsophorone2-Nitrophenol2,4-DiMthylphenolBenzole Acidbis(-2-Chloroethoxy)Hethane2,4-Dichlorophenol1,2,4-TrichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4-Chloro-3-Hethylpheno12-HethylnaphthaleneHexachlorocyclopentadiene2,4,6-Trichlorophenol2,4.5-Trichlorophenol2-Chloronaphthalene2-NitroanilineDiMthyl PhthalateAcenaphthylene3-Nitroaniline

NDNDNDNDNDNDND4.6 JNDNDNDNDNDNDNDNDNDNDNDNDNDND2.1 JNDNDNDNDNDNDNDNDNDNDND

10101010101010101010101010101010109010101010101010101010901090101090

mmmummmmmmmmmmmm**mmmmmmmmmnMmmmmmmmmm

Acenaphthene ND2,4-Dinitrophenol ND4-Nitrophenol NDDibenzofuran ND2,4-Dinitrotoluene ND2,6-Dinitrotoluene NDDiethylphthalate ND4-Chlorophenyl-phenlyether NDFluorene ND4-Nitroaniline ND4,6-Oinitro-2-Hethylphenol NDN-Nitrosodiphenylaiine ND4-BroMphenyl-phenylether NDHexachlorobenzene NDPentachlorophenol NDPhenanthrene NDAnthracene NDDi-n-Butylphthalate NDFluoranthene NDPyrene NDButylbenzyiphthalate ND3,3'-Dichlorobenzidine NDBenzo(a)Anthracene NDBis(2-Ethylhexyl)Phthalate NDChrysene NDDi-n-Octyl Phthalate NDBenzo(b)Fluoranthene NDBenzo(k)Fluoranthene NDBenzo(a)Pyrene NDIndeno(l,2,3-cd)Pyrene NDDibenzo(a,h)Anthracene NDBenzo(g,h,i)Perylene NDBenzidine NDPyridine ND

(J) Indicates detected below HOL(B) Indicates also present in blank(ND) Indicates compound not detected

MDL••••*•••

10

90101010101010909010101090101010101010201010

. 101010101010101020.10

A R I Q 0 2 I O

Elsemi-VOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDS

EPA SAMPLE NUMBER

I


Sample wt/Vol: 1000 <g/mL) ML

Leve1: LOW

\ Moisture: 100


GPC < Y or N ): N

Column: DB-5

Number TICs Found 4CONCENTRATION(ug/L or ug/KgO UG/L

II WESTON II_________I


Lab File ID: >C0790

Date Received: NA


Date Extracted NA

Dilution Factor: 1

CAS

1234

NUMBER

827543101848

COMPOUND

UNKNOUNUNKNOWNNaphthaleneBenzene, 1,

NAME

, 2-ethenyl- (9CI)I'-oxybis- (9CI)

1 1RT 1 EST

1

1 13.4818.32116.63116.941

1

CONC

42211

A R I 0 0 2 I i

QUANT REPORT

r ID: JEFFoutput File: /XC0790:Data File: >C0790:ame: A1218 WESTONisc: 032393

Quant Rev: 6:D3;D4

Quant Time:In jected at :

Dilution Factor:

930324 13:24930323 22:24

1.00000

BTL*10

'D File: ID0323::D5itle: hSL BNA STD

Last Calibration: 930324

Compound

12:17

R.T. Scan# Area Cone Units

145121 899338356'47/3

)))))))))))^

™

*d4-l,4-Dichlorobenzene2-FluorophenolPhenol-d51,2-Dichlorobenzene

*d8-NaphthaleneNitrobenzene-d54-Chloroaniline

*dlO-Acenaphthene2-Fluorobiphenyl

*dlO-Phenanthrene2,4,6-Tr ibromopheno 1

^12-Chrysene^Berpheny l-dl4«J12-Pery lene

10.7.9.10.13.11.13.18.16.21.20.28.26.32.

3740788857919610428617690214

667382610716974815

10111408124717691607242421682754

1508010398979516563268011015732

175722688521396337510085144017977

40513644037240454090.405340

.00

.09

.69

.64

.00

.74

.10

.00

.52

.00

.01

.00

.96

.00

UG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/L

9188899089809494959794988994

* Compound is ISTD

TOTflL ION CHROMOT08RRMFil« >C0790 35.0-500.0

. 8P° i

60000-

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50000-.

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10000-

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I

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J .-.,.-. ... J — l i**— —4 ' k ' a!a i ' i'e ' a'o ' a1* ' as ' s'a ' 36

Data File: >C0790::D4Name: A1218 UESTONhisc: 032393




BTL*10

ARI002I3

REFERENCE STBNDRRP SPECTRUM^to >IN•flb 1

100-"

0-

TST 40 N6 INTERNAL STDS00 SUB CLP NRM

5£ _,in / °7 ft>

/ ( / ^1.... . .i.i.nr , ..... . ..ii.40 60

78 87 "v,,c,£ ......s'o ' i6b '

Scan8.18150/

117 126

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353ain.

-100•

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SflMPLE SPECTRUM <BflCK8ROUND SUBTRflCTED>File >C0790Bpk flb 6962

-

4000:; 40<>^rr^

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52 ?6 78 87r, /* -^r / fi-H-l-i'l 1-fllni'l'M'l-n-i'i't in /| ii60 80 100

032393

115<> 117i- • -V" ieo'"1"'

Scan 66710.37 Min.

150-100

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SOMPLE SPECTRUH <UNfiLTERED>Fil* >C0790Bpk flb 6962

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52 7fi 78 87/ 63 7t^ S- j

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032393 Scan 66710.37 Kin.

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11599 ^ ™f .... 1,1.

-100•

liLî6b' ' ' 120 ' 140 '

a ta F i l e : >C079Q: :D4Name: A1218 WESTONMisc : 032393Quant Time: 930324 13:24I n j e c t e d at: 930323 22:24

Quant O u t p u t F i l e : /SC0790: :D3




ARI002IU

REFERENCE STBNDflRD SPECTRUMFil* >SX050 HP BNft Standard 50 50 ng/uL Mixed Base N«ut Scan 264Bpk fib 100 NRfl 8.75 Min.

112100-|

.

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64/

<** 50 57/ 4H / { \

.Illi,,../. . i 1 i .1 . i 1 1 . . i t I,TM£.,.,,..y ...,,,,T T1

73 \ f / **, . /. . . y"> . | , 1 , f

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SfiMPLE SPECTRUM <BflCK8ROUND SUBTRACTED)Fil« >C0790Bpk fib 5056

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59 6745 y /'''"BO' '' e'o

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64

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73

70

81

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032393

83 92 95

9*6 160

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112/ kioo

iioSflMPLE SPECTRUM <UNRLTERED>FilBpk

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.

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64

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7.40 Min.112

?3 81 83 *e 96

t

i70 80 90 100 110

hlOO•

-0

Data File! >C0790:: D4Name: A1218 WESTONMisc: 032393Quant Time: 930324 13:24Injected at: 930323 22:24


Quant Ou tpu t Fi le : /NC0790::D3



ARI002I5

REFERENCE STflNOflRD SPECTRUM^M^t >SX050 HP BNfl^•flb 100•

100-•"

0-

42 52/ X

I, i i h ] ,\r4Q ' ' ' ' ' ' '

Standard

54s 66

V; . , nVj£0

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fl' 82f i i i i I i i

80

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99"

. I . ' / . . ' . . . . . , . . . . , . . . . ,

100

'100 120

-100•"

LO

SflMPLE SPECTRUM <BflCK6ROUND SUBTRfiCTED)File >C0790Bpk fib 4682

-44000-

- 42 5l/ \

o-uujLl l |i, i, i,

01218 MESTONSUB

2 54 /1. ^/ 66 i 82 87

e'o ' so

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99"<~>-

100/100 '

Scan 6109.78 M i n .

j-100•

127 "i t i f --rri'-Q

120

SfiHPLE SPECTRUM <UNftLTERED>fila >C0790Bpk fib 4682

4000-- 42 52

nl.llfl, V40 '

01218 UESTON 0322

99"**"

54 71

X 66 i 82 87.j f'.lll. , , ../ f ,. . 1 . , . . 1 . . . , 1 . , . . f . . , ,

60 80 1

193

100/

00 " ' ' '

Scan 6109.78 Min.

-100•127 ;

• ieo " ' '

a ta F i l e : >C0790: :D4Name: A1218 WESTONMisc: 032393Quant T ime : 930324 13:24I n j e c t e d at : 930323 22:24

Compound No: 5Compound Name: Phenol-d5Scan Number : 610R e t e n t i o n Time: 9.78 m i n .Quant Ion: 99.0Area: 9795Concen t r a t ion : 36.69 UG/Lq-value: 89

Quant Ou tpu t F i l e : •*'C0790::D3



flRI002!6

REFERENCE STflNDflRD SPECTRUMFil« "BI6DB B«nz«n«, 1 ,2-dichloro- Scan 95501Bpk flb 100 FLT NRM NOM 0.00 Min.

146100-.

0-

75 X^r ir3/

40 60 80 100 120 140

-100.

-o

SflMPLE SPECTRUM <B8CK6ROUND SUBTRACTED)Fil« >C0790Bpk flb 732

I500-•

:

81218 UESTON 032393 Scan 716SUB 10.88 Min.

146/

11137 so 63 74 _L? 8B __ ^, 113

'40 ' ' '' , N "Til f f \\*

-100•"

-.n" "60" 's'o " ' ' ' ' ibb' " ' " isb' " ' ' " i40J

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"m60O- ._: *o 50

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R1218 UESTON

63 74 J? 85

\ ^T\\r e'o ' " s'o " ' ' '

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111

r V"ibb ' iab '

Scan 71610.88 Min.

146( I"100•

•

'lib'

Data F i le : >C0790: :D4Name: A1218 WESTONMiac : 032393Quant Time: 930324 13:24I n j e c t e d at: 930323 22:24

Quant Output F i le : ~C0790::D3

Quant ID Fi le :Last C a l i b r a t i o n :

BTL*10ID0323::D5930324 12:17


ARI002I7

REFERENCE STHNDRRD SPECTRUM•h* >nCHO:5•flb 100

î 100-

0-42

1 i i l'i '40

30 N6 STANDARDSUB CLP

54 56 68

i i i i i i i I'/'i'f l i ' '60

82

80 ' '

NRM

90

'"

100 "8/ /

M i l i i f i T i100

121\120

Scan 53811.20 min.

136

124

/

'i i | /'( i i

-100

-0


1QQQO;

OJ

5442 Fila >C0790 A1218 WESTONBpk Ab 15032

.

10000:

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"" •'t ' ' • • 1 ' • ' ' 1 ' • • • 1 • ' • ''I ' ' • ' 1 ' '40 60 80

032393

3 100 "8/ (

' 100 '

Scan 97413.57 win.

136

118 13X°/ \ , ,1.

-100

._n. . . . , .

at a File: >C0790::D4Name: A1218 WESTONMisc: 032393Quant Time: 930324 13:24Injected at: 930323 22:24

Compound No: 18 USTD)Compound Name: d8-NaphthaleneScan Number: 974Retention Time: 13.57 min.Quant Ion: 136.0Area: . 32680Concentration: 40.00 UG/Lq-value: 89




ARI002I&

REFERENCE STftNDBRD SPECTRUMFil«Bpk

"BI8DBfib 100

100-

;Q!

40

B*nzan«Min*, 4-chloro-FLT NRM NOM

65 921 f

60 80 i66

Scmn 1064780.00 Min.

127f [-100r! o

120

SAMPLE SPECTRUM <BflCK8ROUND SUBTRACTED)

SRMPLE SPECTRUM <UNflLTERED>

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200-". 39

Mil,'.'. ..40

01218 UESTONSUB

6552 '

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032393

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Sctn 101113.96 Min.

127' 1-100

120

Fil« >C0790Bpk fib 846

•J 40800-

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01218 UESTON

66

7 1f • • 'i60 80

038393

92 99...r,^,,,,,

Sctn 101113.96 Min.

127j-100

•• .,. -itto180

Data File: >C0790:sD4Name: A1218 UESTONMisc: 032393Quant Time: 930324 13:24In jec ted at: 930323 22:24

Compound No: 29Compound Name: 4-Chloroani1ineScan Number : 1011R e t e n t i o n Time: 13.96 min .Quant Ion: 127.0Area: 732Concentration: 2.10 UG/Lq-value: 94

Quant Ou tpu t F i le : ^00790::D3



AHI002I9

REFERENCE STfiNDflRD SPECTRUM•Le >SXQBO HP BNR Standard

^Bgfc 100

W^ 100-

:CH

54

66

! I '40 ' 60

50 CO ng/ul_ mixed Bas« N*ut Scan B47NRM 14.10 »in.82

"**"• '

70

1" 1 tTl

1C

83 98 99

S ^/ "280 ' l66 ' 120 '

t-100

:t-o

SfiMPLE SPECTRUM <BflCK6ROUND SUBTRflCTEO>File >C0790Bpk flb 4872

.4000-

•

0-

01218 WESTON 032393 Scan 815SUB 11.91 Min.82K,

5442 50\ A.l.

'40'

66 70\ {

12" 98 99 f/ >X ^ 1.

•l t\ 1 I'M' '1 1 1 1 | r^^r, ...,..-..,.. , , f-r-r-n-,60 80 100 120

(-1,00•

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SflMPLE SPECTRUM <UNflLTERED>File >C0790 A1218 UESTON 032393 Scan 815Bpk flb 4872 11.91 Min.

82.

4000-

0-

54/

40 50 66 70?, \ \ r .. i 'JTi f . |r|M. ,• j i ITP •• 1 I i | I40 60 80

12^3 ^ 99 ±2 1

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hlOO1

-0

ata File: >C0790::D4Name: A1218 WESTONMisc: 032393Quant Time: 930324 13*24Injected at: 930323 22:24

Compound No: 19Compound Name: Nitrobenzene-d5Scan Number: 815Retention Time: 11.91 min.Quant Ion: 82.0Area: 11015Concentration: 37.74 U6/Lq-value: 80


BTL410Quant ID File: ID0323::D5

Last Calibration: 930324 12sl7

flRI00220

REFERENCE STflNDRRD SPECTRUHFil«Bpk

» >DEM03flb 100

100-j-

0-42

1 I'i'i i i40

80 N6 STANDARD

84 66

,1'Ljll'ill

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80" 82 100r' \I'l i'ft'1 n i'| i f 1 1 ji i

80 100

108

n-

122

"120

132 134

,.)wC.140

Scan 79915.60 Min.164v.

r.4Si

•••••&••-100•

-0

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;

5000:: 42

fru'Hii40

01218 UESTONSUB

54 66 8^ 2 100 ±

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032393

122 132? s \120

Scan 140618.10 Min.

162-100

134 146 I

140 ' 160SflMPLE SPECTRUM <UNflLTERED>Fil«i >C0790 81218 UESTON 032393 Scan 1408Bpk flb 7750 18.10 Min.

162

5000

f\m

42 54 ?*^/ 10° 108 "2132 134146 ...!.(.. . 1 J. n . ., 1.1 ... 1. H ll ...... 1.. . , f . 1 . _ l.l J r . ll III!1,40 60 80 100 120 140 160

-100

m

-0

Data Files >C0790::D4Name: A1218 UIESTONMisc: 032393Quant Time: 930324 13:24Injected at: 930323 22:24

Compound No: 33 (ISTD)Compound Name: dlQ-AcenaphtheneScan Number: 1408Retention Time: 18.10 min.Quant Ion: 164.0Area: 17572Concentration: 40.00 UG/Lq-value: 94




ARI0022I

REFERENCE STflNDBRD SPECTRUM^fe >SX05Q^•flb 100^^

100-

39

0-VrTTi40

HP BNfl Standard 50

51 63 75 85{ / 6 i

60 80

50 nNRM

94/'l6b'

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^°7 120 133 146^

120n-r-i i ii nrrr

140

Scan 82719.79 B in .

172*"*

51

^J,-1.

-100

_n160

SfiMPLE SPECTRUM <BflCK8ROUND SUBTRflCTED)File >C0790Bpk fib 12553

10000-

39

40

fli2is

51 63 75/ / /

60 ' 80

WESTON

85

•W

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94 1•/ /100

032393 Scan 124716.42 Min.178^

?7 120 133 146 jj £

klOO•

120 140 160

SflMPLE SPECTRUM <UNflLTERED>Fi l lBpk

i >C0790fib 12553

10000-

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40

01218

51 63 75/ / f'"'s'o "'""so

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10-^

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120/iTi JTI'l'i

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Scan 124716.42 M i n .

172

1 -133 146 «8 J

X'-wl' l i b

/ s».-[Vi ,n , , , , ,4iio '

-1UU

.

-0


Compound No: 38Compound Name: 2-Fluorobipheny1Scan Number1. 1247Retention Times 16.42 min.Quant Ion: 172.0Area: 26885Concentration: 45.52 UG/Lq-value: 95

Quant O u t p u t F i l e : ^0790::03



flRI00222

REFERENCE STflHDflRD SPECTRUHFil« >DEM03Bpk fib 100

100-

I 42

O^HHVrr

6654 y

•|i ' ili i i l i ' l i n60

80 m STANDARDSUB CLP NRM

80 94/ y 108 118 132 146

I ' f r Inu l ' f ! i i | l r i» | i f l l ' i f f n | n T ' i | » r i | i i80 100 120 140

Scan 101619.27 M i n .

188""* -100

160 I*8 •

160 ' 180 '

SRMPL.E SPECTRUM <BflCK8ROUND SUBTRACTED)Fil« >C0790Bpk Ab 8475

5000: gg

JZ,c0"' 6'0

A1218 UESTONSUB

66 80 94 1?2 11ft/ i t y * J.1O

90 100 ' 120

032393

132 146

140 '

Scan 176921.86 Min.

188' -100

160 170 :160 ' 180

SflMPLE SPECTRUM <UNflLTERED>FilBpk

• >C0790Ab 8475

3000-

0-

40/401"'

A1218 UESTON

52 66

A f i i r p l v i i60

f80

94 10£

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132 146/

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160•444JL

160

Scan 176921.86 Min .

188

h' 180 f

•100

-0

Data File: >C0790::D4Name: A1218 UESTONMisc: 032395Quant Time: 930324 13:24Injected at: 930323 22:24

Compound No: 53 (ISTD)Compound Name: dlO-PhenanthreneScan Number: 1769Retention Time: 21.86 min.Quant Ion: 188.0Area: 21396Concentration: 40.00 UG/Lq-value: 97

Quant Output Files "" 0790! :D3



ARI00223

REFERENCE STfiNDflRD SPECTRUM

F HP BNfl Standard 50 50flb 100 NRH

100-

' 37 e 91 111 141Y r / /" r " Ô-1^ n''i fi f. "fT t-i iTTf \ IT. ft r. t t'fi i • i f40 80 120 160 2

197

20(7

mixed

222 250

N«ut Sc»n 104824.28 M i n .

330-100

240 280

SfiMPLE SPECTRUM <BflCK8ROUND SUBTRflCTEOFile >C0790Bpk flb 1347

621000^ i*""jgL

40 ' * 80

R1218 WESTONSUB

141

J>1 111 f 170

ieo 160

032393

197 f «0/ ih ,k

200 240 ' 280

Scan 160720.17 M i n .

330""j -100

/ ill '"•326

SflMPLE SPECTRUM <UNflLTERED>Fila >C0790Bpk flb 1347

lOOfr37a

40

fll218 UESTON 032393 Sc*n 160720.17 M i n .

62r, 91,cf

111

îf.'.120

141

1

170 19? 222 250

4o 260 240 ' 2

330

3,01 Ii •< • r- |*11320

-100

•0

ata F i l e : >C0790::04Name: A1218 WESTONMisc: 032393Quant T ime : 930324 13:24I n j e c t e d at: 930323 22:24

Quant O u t p u t F i l e : ^00790::D3

8TL*10Quant ID File: ID0323::D5


Compound No: 56Compound Name: 2,4,6-Tribromopheno1Scan Number: 1607Retention Time: 20.17 min.Quant Ion: 330.0Area: 3375Concentration: 90.01 UG/Lq-value: 94

REFERENCE STflHDRRD SPECTRUMFill5p!o

i >ISTDat 100100-

52

°-T -r-

SUB CLP

? ? "5 1"80 ISO

NRK

156V 168N f160

208184 \f. . >»' ' ' 260

Scan 136725.95 Min.240^

212

2<

-100

-00

SflMPLE SPECTRUM <BRCK8ROUND SUBTRACTED)File >C0790Bpk fib 3341

«

2000- 42: /4V ' '

64 78- , < , ,4 ,1 ' ' 'e'o

01218 UESTONSUB

120^ _ v 132

' ' le<j ' ' ' '

032393 Scan 242428.69 Min.240"**

L56 ,,man e08 212v 170180 x. /;s.. . / /. . ?l-r -Jj160 200 2<

-100•

-A

0SfiMPLE SPECTRUM <UNflLTEREO>Fil« >C0790Bpk fib 3341

_

2000

t

44

i'o

R1218 UESTON

64 78 1°6 12^ 13g/ / ^^ tl /, »fw . »• 1 .« U . .4*11 ;

' 80 120 ' '

032393

156N. 170180

' ' i60i • •

208

260

Scan 242428.69 Min.240••••s.

212

-100

i-O0


Compound No: 64 (ISTD)Compound Name: d!2-ChryseneScan Number: 2424Retention Time: 28.69 min.Quant Ion: 240.0Area: 10085Concentration: 40.00 UG/Lq-value: 98


BTL*10Quant ID File: ID0323:sD5


ARI00225

REFERENCE STflNDRRD SPECTRUMMfce >SX050 HP^Mflb 100

100-

54

^>v,

BNfl Standard

66 80 10^. i .^ r. ,. .

50 50 ng/uL MixedNRM

«a 136 16^ 2 in,.l/,, jt v'T'i '."f"i'T'i ri120 160

Basa N«ut Scan 140831.59 Min.344^ -100

£12 226?4 \ \ ..:r"i ^F V"i*V ("f i -"i<*p i»uO

200 240SfiMPLE SPECTRUM (BflCKSROUND SUBTRACTED)File >C0790Bpk Ab 5734

-4000-

• 54

t N

nisis

66 80 "v6

.•/.4»-.MV,

UESTONSUB

122, 136. .J f130 '

032393

160 163 313\^s 184 V

160 300

Scan 216836.02 win.344^ -100

•

336 1

' 340

SflMPLE SPECTRUM <UNflLTERED>Fil« >C0790Bpk Ab 6734

-4000-

40

A1318

10666 80 v

, . . .£ . . ,f

UESTON

12o 160^ 2 136 X

' 130 ' ' ' ' ' il

032393

T "4>d

Scan 316836.03 Min.344^

313 336

.. \ \

1-100

. ov\ i'im | ' i" i i pr -300 340

ata F i l e : >C0790::04Name: A1218 UESTONMisc : 032393Quant Time: 930324 13:24I n j e c t e d at: 930323 22:24

Compound No: 67Compound Name: Terphenyl-d!4Scan Number: 2168Retention Time: 26.02 min.Quant Ion: 244.0Area: 14401Concentration: 53.96 UG/Lq-value: 89




ARI00226

REFERENCE STANDARD SPECTRUMFil« >DEH03Bpk fib 100

100-

j " V>r "' ' ' i ' '40

80 N8 STANDARDSUB CLP NRH

130 13288 102 if* 163

80 120 160

Scan 1626£9.57 Kin.264

J" -00

200 240

SAMPLE SPECTRUM <BACK8ROUND SUBTRACTED)Fil« >C0790Bpk Ab 2C43

.2000-

0-44

4*0

RlEie UESTONSUB

130 132y 88 104 <["

fa ,.,.., ,4, ,,, if 101 i4 i . .80 ISO

156

160

032393

208 £09

V200

Scan 276432.14 Min.264""*-

23£

/ 4

-100

£40

SAMPLE SPECTRUM (UNALTERED)Fil« >C0790Bpk flb 2543

2000-- 44- /

4V ' '

A1218 WESTON

_ 130 132y 88 104 " i| 166/ , / / jj J /^ 'i t 'j- r*r i- 1". i 1*1 ii'i ! .• ii [ i

80 120 160

032393

207 209vr~'"T~""r"»TJo -"-T-'-'

Scan 276432.14 Min.264"""I -100

232 :240 '

Data F i le : >C0790: :D4Name: A1218 UESTONMisc: 032393Quant T ime: 930324 13:24I n j e c t e d at: 930323 22:24

Compound No: 73 ( ISTD)Compound Name: d!2-PeryleneScan Number: 2754R e t e n t i o n Time: 32.14 m i n .Quant Ion: 264.0Area: 7977Concen t ra t ion : 40.00 UG/Lq-value: 94 ._

Quant Output F i le : ^00790::D3



ARI00227

la >CO?90k fib 806

.In40

R1218 UESTON 032393SUB ftDD DVC

69^'

55 7H 7344 53 / 65 f 84

50 60 70 80

Scan 63.48 nin.

c^90 100

'reaUnknown #,15503.00 Tentative Concentration is 4.00

Sample file: >C0790 Spectrum #:

o data base entries were retrieved.

AR100228

3pV

-

k >C0790 fll218 UESTOKfib 870 SUB fl

43j / 73j 45 55 67 """

01 1 i *-"' ( >s-40 i s'6 so ' V6

03239300 DVC

79 84 98

80 90 £60

Scan 4708.32 ttin.

115 :

iib


Sample file: >C0790 Spectrum 470

Ho data base entries were retrieved.

ARI00229

ile >CQ79Q R1218 WESTOM 032393SUB POD DVC

Sc*n 126716.63 Min.154

Tj 42 51 63 74 76 89 102 115

/ , , , , , , , , , . 1 140 60 80 140

3pk fib 9999Naphthal«n«, 2-«thenyl- <9CI> Sc«n 17944

0.00 Min.154

51 63 74• •

87 101 102 115 128 129

40 60 80 ISO 140ile >BIGDB

»pk fib 9999

39 51 63 74

Acenaphthene <8CI>

87 98 102 115 126129

Scan 179330.00 Min.154

60 80 100 120 140ile >B!GDBpk fib 9999

l.l'-Biphenyl <9CI> Scan 179350.00 Min .

154

39 51 63 74-" x { "^

87 98 102 115 126129 139

40 60 80 160 120 140

Unknown #,113734.00 Ten t a t i ve Concen t r a t i on is 2.00

1. Naphthalene, 2-ethenyl- C9CI)2. Acenaphthene (SCI)3. l,l'-Biphenyl C9CI)4. 1,4-Ethenonaphthalene, 1,4-dihydro- (8CI9CI)

154 C12H10154 C12H10154 C12H10154 C12H10

Sample file: >C0790 Spectrum #: 1267search speed: 1 Tilting option: N No. of ion ranges searched: 42

Prob. CAS # CON * ROOT K DK *FLG TILT CON C_I R_I<J

1.2.3.4. a

70*32*26*

. 25*

8275438332992524

7322476

17944179331793517956

"BIGDB"BIGDB"BIGDB"BIGDB

49373731

52536861

3223

0000

87476343

8364550

421087

14181413

ARI00230

il*Bpk

~

il«tspk

ilewp k

ile3k

>C0790Ob 2280

^

o1r940

>BIGDBflb 9999

|»40

>BIGDBOb 9999

j"40

>BI6DBOb 9999

] 39

40

P.1218

51 77/ 65 "v»

60 'SO

I4ESTONSUB ODD DVC

85 94 102

•••'••'ioo"1

032393

115i120 '

B«nz«n«, l,l'-oxybi*- <9CI>

51 77/ 65 -v,

„,!„.,.,, ,./,,-J.M60 80

85 94 102/,,,f,,,f,,,,

100

118 129

'l20 '"'tl,l'-Biphenyn-4-ol <9CI>

51 63 76,<• n- , uY

60 ' 80

85 89 102

l6o

115 1P7/ j"'"I" "I120

Cl,l'-Biphanyl 3-3-01 <9CI)

51 63 76

60 8*0

85 89 1021 160

115 iaa120

Scan 129716.94 Min.170

141 t-

.140 ' 160

Scan 202960.00 Min.170

141139 154 I140 160

Scan 202940.00 Min.170•>%.

139 HI 152..., [£..... ....,1140 160

Scan 202980.00 Min.170

139 141 162 1140 160

Unknown <=,12irea « 21067.00 Tentative Concentration

1. Benzene, l,l'-oxybis- (9CI)2. [l,l'-Biphenyl3-4-ol (9CI)3. [l,l'-Biphenyl]-3-ol (9CI)4. lH,3H-Naphtho[l,8-cdJpyran (8CI9CI)

is 11.00

170 C12H100170 C12H10Q170 C12H100170 C12H100

Sample file: >C0790 Spectrum *: 1297Search speed: 1 Tilting option: N No. of ion ranges searched: 41

Prob. CAS * CON # ROOT K DK #FLG TILT CON C_I R_IU

1.2.3.4.

87*26*25*11*

10184892693580518203849

20296202942029815988


72302830

34656278

0213

0000

921008760

13454662

55872

89141513

ARI0023I



ANALYSIS NO: A 1219

CLIENT ID: W-1A

METALS MDL (mg/L) RESULT (ng/L)

ANTIMONY

ARSENIC

BERYLLIUM

CADMIUM

CHROMIUM

COPPER

LEAD

MERCURY

MOLYBDENUM

NICKEL

SELENIUM

SILVER

THALLIUM

ZINC

0.05

0.005

0.01

0.01

0.01

0.01

0.05

0.0005

0.013

0.05

0.005

0.01

0.01

0.01

1.05

N.D.

0.16

N.D.

N.D.

0.01

N.D.

N.D.

0.013

N.D.

N.D.

N.D.

N.D.

1.35

21ST CENTURY ENVIRONMENTAL • NJDEPE CERTIFICATION VOJpft \ Q Q 0 O O

21ST CENTURY EnvironmentalSQ1IUOLATILE ANALYSIS DATA

JOB NUMBERSAMPLENUMBER .CLIENT IDDATA FILE

A1219 UESTONU-1A

>C0791


Uater1.00

03/23/93

COMPOUND UG/L HDL COMPOUND US/L

N-Nitrosodiwthyla»inePhono1bis(-2-Chloroethyl)Ether2-ChoIorophenol1.3-Oichlorobenzene1.4-DichlorobenzeneBenzyl Alcohol1,2-Dichlorobenzene2-Methylphenolbis(2-chloroisopro4-HethylphenolN-NitPoso-Di-n-ProHexachloroethaneNitrobenzeneIsophorone2-Nitrophenol2,4-DiBBthylphenolBenzoic Acidbis(-2-Chloroethox2,4-Dichlorophenol1,2,4-TrichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4-Chloro-3~Hethylphenol2-HethylnaphthaleneHexachlorocyciopent2,4,6-Trichlorophenol2,4.5-TrichlorophenoI2-Chloronaphthaltne2-NitroanilineDiMthyl RithalateAcenaphthylene3-Nitroaniline

•ine . NDND

)Ether NDND

e NDe ND

NDe 11

NDpyDEther ND

NDpylaiine ND

NDNDNDNDNDND

y)Hethane NDND

zene NDND13

e NDhenol NDe NDtadiene NDnol NDnot NDle ND

ND: ND

NDND

10101010101010101010101018101010105010101010101010101010901050101090

•••••••••••••••••••••••••••••I

Acenaphthene2,4-Dinitrophenol4-NitrophenolDibenzofuran2,4-Dinitrotoluene2,6-DinitrotolueneDiethylphthalate4-Chlorophenyl-phenIyetherFluorene4-Nitroaniline4,6-Dinitro-2-HethylphenolN-Nitrosodiphenylatine4-BroBophenyl-phenyletherHexachlorobenzenePentachlorophenolPhenanthreneAnthraceneDi-n-ButylphthalateFluoranthenePyreneButylbenzylphthalate3,3'-DichlorobenzidineBenzo(a)AnthraceneBis(2-Ethylhexyl)PhthalateChrysaneDi-n-Octyl PhthalateBenzo(b)FluorantheneBenzo(k)FluorantheneBenzo(a)PyreneIndeno(1,2,3-cd)PyreneDibenzo(a,h)AnthraceneBenzo(g,h,i)PeryleneBenzidinePyridine

(J) Indicates detected below IDL(B) Indicates also present in blank(ND) Indicates compound not detected

HDL

NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND

105050101010101010505018101050101010101010201010

. 101010101010101820

•10

ARI00233

Elsemi-UOLATILE ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS

ERA SAMPLE NUMBER


Sample wt/vol: 1000 Cg/mL) ML

Level: LOW

X Moisture: 100


GPC < Y or N >: N

Column: DB-5

Number TICs Found 2

II UESTONI_______


Lab File ID: >C0791

Date Received: NA


Date Extracted NA

Dilution Factor: 1

CONCENTRATION UtflTS(ug/L or ug/K/> UG/L

CAS NUMBER

1 9199482 101848

COMPOUND NAME.

Butane, 2-ethoxy-2-methy 1- (9CI)Benzene, l,l'-oxybis- (9CI)

RT

3.4916.94

EST CONC

340

fiRI0023U

QUANT REPORT

Jpe ra to r ID: JEFFJu tpu t F i le : /SC0791::D3Data F i l e : >C0791::D4lame: A1219 WESTONl isc: 032393

*D File: ID0323::D5"itle: hSL BNA STDLast Calibration: 930324 12:17

Compound

Quant Revs 6 Quant Time:Injected at:

Di lut ion Factor:

930324 13:41930323 23:09

1.00000

BTL*11

* Compound is ISTD


1)4)5)12)1.8).9)^9)33)•8)•3)56)'.4).7)73)

*d4-l,4-Dichlorobenzene2-FluorophenolPhenol-d51 ,2-Dich lorobenzene

*d8-NaphthaleneNit robenzene-d54-Chloroani 1 ine

*dlO-Acenaphthene2-Fluorobiphenyl

*dlO-Phenanthrene2,4,6-Tribromophenol

*d!2-ChryseneTerphenyl-dl4*d!2-Perylene

10.7.9.10.13.11.13.18.16.21.20.28.26.32.

3841788858929610428617710314

674389617722981822

10171414125317751613243121752760

16811955394104436383721050155132407929611345694246177912075913886

40.42.31.11.40.30.13.40.36.40.70.40.44.40.

0010621400644700590008000900

UG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/L 'UG/LUG/LUG/LUG/LUG/LUG/L

9889848789798892949793979196

ARI00235

TOTfiL ION CHROMflTOeRPWl^ê >C0791 35.0-500.0 a«u. P1219 MESTON 032393^^^Îk T X C^V 1 5?° 1 10|0° 1 15|°° 1 £°|00 1 28I°° L .3.°,Q.°.

j 70000-

65000-

60000-

55000-

50000-•

45000-

40000-

35000-

30000--

£5000-"

soooo-15000-

10000-

5000-

'

i | f !|||jfc 5^ J

\ ® 'T"

1

:.

i•

i 5. U

I* w>, „Lfeeli

L^-,,

1 ;

iji

. i C0791::D4Name: A1219 UESTONMisc: 032393




BTL*11

ARI00236

REFERENCE STfiNDRRO SPECTRUMFil« MNTSTBpk fib 100

100-

- 400-4-H-r

40

40

S£ 56 75

• -I- rl-r • 'IT • r60

N8 INTERNflL STOSSUB CLP NRM

78 87 1:Î.L.< .r. ,.80 l66

Scan 3538.12 M i n .

150

117 1S6^ /

All i i i n ' i i i | i i i i ' , . -

' -100

1L120 140

SflMPLE SPECTRUM <BflCK6ROUND SUBTRACTED)FileBpk

>C0791flb 8018

-5000

nl

38

Vo"

01219

52 56 75

f / S,ti.«ir.,, ,-.-n

UESTON

78

80

SUB

8799{

'166'

032393

115

J1 1 1 1 i117

h1 i I * i • •120

Scan 67410.38 Min.

150/

'"iti"'i4-v

-100

_ft

SflMPLE SPECTRUM <UNflLTERED>Fil* >C0791Bpk flb 8018

0:

!40

. j.f , .....Vo '

fl!219 UESTON 032393 Scan 67410.38 Min.

150

52 56 75 78 37 * 11?

/ \ { / " 1 " (1,60 80 100 120 140

-100

H)

Data F i le : >C0791::D4Name: A1219 UESTONflisc: 032393Quant Time: 930324 13:41I n j e c t e d at: 930323 23:09

Quant Output F i le : ""C0791: :D3




ARI00237

REFERENCE STflNDflRD SPECTRUMp HP BNR St*nd*rd 50 50 ngxuL Mixedfib 100 NRM

N«ut

100-

OA

64

39 4550 5?

40

81 83/ f I 7 \f.•flifi'Ji'iill! iiiii|iiiiiiiif|'/;t'if|iiii|i3 60 70 80 9G

1 > < i6o" | i r i t

Sc«n £848.75 M i n .

112-100

TT+rM-Q110

SflMPLE SPECTRUM (BACKGROUND SUBTRACTED)File >C0791 01219 WESTON 032393 Scan 389Bpk fib 4568 SUB 7.41 Min.

118

4000-

0-

64/

as 50 57-ifn, ,7 i m I n

4*0 ' "50 '( 60

73 8-J 83 f 9S

*

170 so ' 9*6 } 160 ' iio

-100

-0

SRHPLE SPECTRUM <UNflLTEREO>FiU >C079i R1219 UESTON 032393 Scan 389Bpk fib 4568

4000-

0-

7.41 Min.112

64

" / ? r•lilliiiiii...'.'!!!..'.'!.',-.!!40 50 60

81 63 92 95\ { \ S

liviiji./!!...!,-!;];,!... pi.'. ',.... ,..., p...). i?0 80 90 100 110

-100

-0

ata F i le : >C0791::D4Name: A1219 WESTONMisc : 032393Quant Time: 930324 13:41I n j e c t e d at: 930323 23:09

Compound No: 4Compound Name: 2-Fluoropheno1Scan Number: 389Retention Time: 7.41 min.Quant Ion: 112.0Area: . 9553Concentration: 42.10 UG/Lq-value: 89

Quant Ou tpu t F i l e : /XC0791: :D3



ARI00238

REFERENCE STflNDHRD SPECTRUMFil« >SX060 HPBpk fib 100

100--

0-

42/

• i ' / h f40

BNfl Standard 50

44/i-rrvrW

60

54 £.A

*Y \J [|. ,|.JT,.,,;,:)60

50 ngxuLNRM

71o y |

"' 70 "

nix*d B»s« N*ut Scan 42711.66 Kin .

99

76 82 94! 1 1 n 1 1 i i 1 1 1 1 1 1 1 1 1 fl | n i , ,

t

80 90 10C

-100.

^01SftMPLE SPECTRUM <BBCK8ROUND SUBTRACTED*Filt >C0791Bpk flb 5019

.4000-

n.

42

40

44

^

fl!219

54?y^4^

UESTON 032393SUB

6\ 6^,f ? f 760 70 ' s'o ' 9*0

Scan 6179.78 Min.

99'

94i 'I1 ib'c

[-100

-0

SAMPLE SPECTRUM <UNflLTERED>Fil« >C0791Bpk fib 5019

.4000-

• 42

g-LjJJJjVo

fi!219

44 52 54

V I i ' ! 1 1 i ! }•'•••s'o '

UESTON 032393

" 69^ / 76 8£

H.^^lJjI/.l/l.,!/..,60 70 80

Scan 6179.78 Hin.

99' -100.

87 94,f. .,...r,..-ilj£o90 100

Data F i le : >C0791:: D4Name: A1219 WESTQNMisc: 032393Quant Time: 930324 13:41In jec ted at: 930323 23:09

Compound No: 5Compound Name: Phenol-d5Scan Number : 617R e t e n t i o n Time: 9.78 m i n .Quant Ion: 99.0Area: 9410Concent ra t ion : 31.62 UG/Lq-value: 84




ARI00239

REFERENCE STANDARD SPECTRUM^•fct "BISDB^•gb 100^^

100-u

-40

B«nz«n« .FLT

75r60 80

1.2-dichloro-NRM NOtl

111I i13

ioo ifib

Scan 955010.00 »in.

146' -100

,

•1 1 1 1 1 ' ' --I"0140

SAMPLE SPECTRUM <BACK6ROUND SUBTRACTED)Fil« >CG791 fll£19 MESTON 032393Bpk Ab 2153

200O-.

0-

37 50 55 ?3 75

•<n -/ fir ^lC40 60 80

SUB

.. Ill84 -x,, 1 1 ox 97 ^ "3

I'l'i | . i / i i i . i i-VlC i ii i i i| i100 120

Scan 7S210.88 Min.

146/

1 1

-100*

-n140

SAMPLE SPECTRUM <UNALTERED>Film >COBpk Ab 2

2000-

-

0-

791 A1219 UESTON 032393 Sc^153 10. 8(

1

40 "*' j 73 ®? 97 " 113>!].!. . ..II f[ j.j. jljlj .llj.,.. , / j .ll,l

40 60 80 100 120 140

kna46

1

722Min.

-100

.

-0


Quant Output File: "C0791::D3




ARI002t*0

REFERENCE STflNDflRD SPECTRUMFil« >DEM03Bpk fib 100

100-

• 420- < {

40 ' '

54^ 56

i 1 1 i i 1 i I 1 •60

80 N6 STflNDflRDSUB CLP NRM

-n 82 90 in68 79 , y J_QQ 10i.f • {.,,{.,. ,,£,., { ..[.

80 ' 160

Scan 53811.20 Min.

136-100

8 121 124 !

..i-frT^Jt,.. !— j/t/t,t f.£o...^6...,...;

SflMPLE SPECTRUH <BflCK8ROUND SUBTRACTED)File >C0791Bpk fib 17672

10000: ,.: 4a i

40 ' ' '

R1219 WESTONSUB

'6 68 76 fl'i-l 1 l-l'f i i i H'| \-i'\ -l'i60 80

032393

*? 100 «8

100

Scan 98113.58 Min.

136-100

ne "^ i...-{-,. | /'I V- -0120

SAMPLE SPECTRUM <UNfiLTERED>Fil« >C0791Bpk fib 17672

-

lOOOC^ _.- 42 5Âjt **

fl!219 UESTON

/ ? ?S 7rr, ii 'i'i| . i A'| !'>-n60 80

032393

90 108/ 100 xy°r . .-C .. .1.' ' 100 ' '

Scan 98113.58 nin.

136' -100

118 "vj :

..r....>)M120


Compound No: 18 (ISTD)Compound Name: d8-NaphthaleneScan Number: 981Retention Time: 13.58 min.Quant Ion: 136.0Area: 38372Concentration: 40.00 UG/Lq-value: 89




REFERENCE STflNDflRD SPECTRUHi^fe >SX050 HP BNfl^•Pb 100^^

100-•

0-42 50

i I'i 'rvi i | 140

S tandard

54

1 66

•i i 1 1 I'M60

50

70/

50 ng/uL mix«d BaseNRH82

**""

83 98 99

S .-V80 ' l66

N«ut14

112

120

Scan 547.10 M i n .

127

j-100•

-0

SflttPLE SPECTRUM <BRCK8ROUND SUBTRACTED)File >COBpk fib 4

4000-'

0-

791 fl!219 WESTOH646 SUB

82

5442 50 66 70

1 l'| M 1 1 1' •*!'! 1 | 1 M 1 /'I > 1 f\40 60 80

032393 Set11.92

183 98 99

s 100 120

m

2^

822• in.

-100•

-0

SflHPLE SPECTRUH <UNflLTERED>Fil* >C0791Bpk fib 4646

•<4000-

- 42

fr^jX40

5450 f

,\ll

01219 UESTON

82'XN>

66 70

Vo' ' ; ' f" ' ' o

033393

83 98 99/ -v100

Scan 82211.92 Min .

b-10012 1

-r-U120

ata File: >C0791::04Name: A1219 yESTONMisc: 032395Quant Time: 930324 13:41Injected at: 930323 23:09


Quant O u t p u t F i l e : /SC0791: :D3



ARI002i*2

<L

REFERENCE STflNDflRD SPECTRUMFiU "BI60BBpk Pb 100

100-•

-Vo " " "

B«nz«n*ain« . 4-chloro-FLT NRH NOM

65 92

..,./..,....,...., IT,....60 80 100

Scan 1064780.00 Min.127/

ll

-100•

-o120 '

SflMPLE SPECTRUM <BflCK6ROUND SUBTRflCTED)File >C0791Bpk flb 2017

2000-

' 39

0-i|'|'i |i40

01219 UESTONSUB

46 54 « 73 ?6

60 ' 80

032393

91 92 100>r -rr• • ' • ' • • iiJ •

Scan 101713.96 min.

127' -100

»

110 , '{ J'i-tf

120SflMPLE SPECTRUM <UNfiUTERED>Fila >C0791Bpk flb 2017

2000-

- 40 «

O-'iljfpr'. .'pj40

P1219 HESTON

/* r /3x6r. . VI'H'I'I ! i^î • i .60 80

032393

\ J2 3?° 110"'''''"loo"'1"'

Scan 101713.96 min.

127' -100

, , , , , )--\-Q120

Data Fi le : >C0791::D4Name: A1219 WESTONMisc: 032393Quant Time: 930324 13:41I n j e c t e d at: 930323 23:09

Compound No: 29Compound Name: 4-Chloroani1ineScan Number: 1017Retention Time: 13.96 min.Quant Ion: 127.0Area: 5513Concentration: 13.47 UG/Lq-value: 88

Quant Outpu t F i l e : /SC0791::D3

BTLfllQuant ID File: ID0323::D5


ARI002U3

REFERENCE STANDARD SPECTRUM>DEM03

ICC80 N6 STANDARD

SUB

100-30

Sc*n 79915. 60 Sin.

164-100

42 54

<H|'f'..f,M>ft

100\40 60 80

122 13£

f 11 11 I'M 111 f f'2C120

134 146

C,<,,,4\140 160

0

SAMPLE SPECTRUM (BACKGROUND SUBTRACTED)File >C0791Bpk fib 10147

10000-

0-42

4</

01219 UESTON 032393

80 8i54 66 ^ /

if, III' " O 80

SUB

: 100 122 132V 108 \ N.1 1 1 • i| 1 1 1-/ - 1 il ri-

100 120

136

iib

Sc»n 141418.10 win.164•v

146

•»

1' 160

-100

-0

SflHPLE SPECTRUM <UNftLTERED>Fil* >C0791Bpk flb 10147

10000-

; 40o^^W^

40

01219 UESTON

54 66 **^™ "\,'\<\'Fi, |T|T|l|,V. < ' / 7 > U l | t f . l | » l -

60 80 100

032393

,„„ 122 132 136T \ \/!•.'• 11 1 1 . i i • ifhi'i 1 1 .ISO 140

Sc*n 141418.10 nin.

164v " -loo

146 :4n*MU<

160

ata Fi le: >C0791:: D4Name: A1219 WESTONMisc : 032393Quant T ime: 930324 13:41I n j e c t e d at: 930323 23:09

Compound No: 33 ( ISTD)Compound Name: dlO-AcenaphtheneScan Number : 1414R e t e n t i o n Time: 18.10 m i n .Quant Ion: 164.0Area: 24079Concen t ra t ion : 40 .00 UG/Lq-value: 92

Quant Output F i le : /SC0791::D3

Quant ID F i l e :Last C a l i b r a t i o n !

BTL411ID0323::D5930324 12:17

A R I 0 0 2 H

REFERENCE STflNDRRO SPECTRUMFillBpk

e >SX050fib 100

100--

0-

39

HP BNB

51

Standard

/ / 63 75

40 60 80

50 50 ng'ui.NRM

35 107

il'i'i fi'iwiwri'iv

Mix«d Bas* N*ut

120n/Wrr120

133 146/ /

'l40

19

152

C.iio

Scan 827.79 M i n .172

***

4"T'1'P •

-100•

-0

SflMPLE SPECTRUM OfiCKSROUND SUBTRACTED)File >C0791Bpk fib 13366

10000-

o339/ 51/ /4*0 '"

P1219

63 75•flft l'| I'l'lf t'l'SO 80

UESTONSUB

/ 99•il'i'i I'l'IVfl lit

100

032393 Scan 125316.42 min.178*s>>

*/7 120 133 146 s

''"""i'fe""1""n'li'l-i-il'l'.140

•- 1.ft 1 1 1 1 1'f'i i160

[-100•.

-0

SflMPLE SPECTRUM <UMflLTERED)Fila >C0791Bpk fib 13366

P1219 UESTON 032393 Scan 125316.42 min.178

•10000-

<>39

40

8551 63 75 / 99

60 8*0 ' 100/ 7 v20,r,T,v,j(«.,.

133^L

140 ' 160I-100•

-Q

Data Fi le : >C0791::D4Name: A1219 UESTONMisc: 032393Quant Time: 930324 13:41I n j e c t e d at: 930323 23:09

Compound Nos 38Compound Name: 2-FluorobiphenylScan Number : 1253R e t e n t i o n ' T i m e : 16.42 m i n .Quant Ion: 172.0Area: 29611Concen t r a t ion : 36.59 UG/Lq-value: 94

Quant Ou tpu t Fi le : ^C0791::D3



REFERENCE STANDRRD SPECTRUMijflte >DEH03^•pb 100

100-

• 42 54• / /

O i | I ' u ' i ' i i l l f | i40 6C

80 N6 STANDARDSUB CLP NRM

66 80 94/ t ( 108 118

) 80 100 ' 120

132 146

140

Scan 101619.27 »in.

188V -100

160 I** :i-f/'i'i i f h i i i . r i ' l V i i f - o160 180

SAMPLE SPECTRUM BACKGROUND SUBTRACTED)Fil« >C0791Bpk Rb 13284

10000-

^42.{.40

52/

6*0

A1S19 UESTON 032393SUB

66 80 94 102 132 144

' 80 f 100 ' 120 ' 140 '

Scan 177521.86 Bin.

188/

. ...

' ' "9 ^,

1-100'

-O160 ' 180 '

SAMPLE SPECTRUM <UNALTERED>Fil* >C0791Bpk flb 13284

-10000-

•oJ

40/40 "'

A1219

52 66 8Q

y/ / /

60 80

UESTON

94 "2

}\} . m.,i

032393

118

120

132/

146 If* l, , i .J.hL

lib ' 160

Scan 177521.86 win.

188

70( i-!-!1

'

1,'"iio '

hlOO••L-0


Compound No: 53 (ISTD)Compound Name: dlO-PhenanthreneScan Number: 1775Retention Time: 21.86 min.Quant Ion: 188.0Area: 34569Concentration: 40.00 UG/Lq-value: 97

Quant Output File: T0791::D3



REFERENCE STflNDflRD SPECTRUM>SX050 HP BNfl St*nd*rd

Bpk fib 10050 50 ng/uL

NRM

100-

N«ut Sc*n 104824.28 M i n .

330-100

37/

S2 91 111 141

40 80

111 141 222 ounx' ,x 172 197 *?* 2°°

120 160 ' ' ' 2 Q Q 1 ' '240 '

SflMPLE SPECTRUM <BflCK6ROUNO SUBTRflCTEO)File >C0791Bpk flb 1747

:loooi 37

Q,4*0

**

\01219

62**•

90

K-f m |*<80

111

120

UESTON

141

LK

SUB

170 197

200

032393

222 250

240 '

Scan 161320.17 Min.330L

7 \100

280 ' 320SflMPLE SPECTRUM <UNfll_TEREO>Fil* >C0791Bpk flb 1747

1000H 37

4^0

B1219

6e

1 90 111

i 'ftH-foK !?{**.'.80 120

UESTON

141t ! 7 0

, 4197JL200

032393

2y22 250

f /

*240 '' ' 280

Sc*n 161320.17 Min.

330

303 ill/ K/'» • 1 1 1'^320

-100

-0


Quant Output File: 'SC0791::D3



Compound No: 56Compound Name: 2,4,6-TribromophenolScan Number: 1613Retention Time: 20.17 min.Quant Ion: 330.0Area: 4246Concentration: 70.08 UG/Lq-value: 93

REFERENCE STflNDQRD SPECTRUHJHte >ISTDj^^Wb 100^^f

100-

; 5^ 66 78

40 ' e'o

SUB CLP NRft

106 120 156^ x.. 132 V 168 1

„. .,.,!.. .Ji / ..\ / i120 160

Scan 136725.95 M i n .

240**" -100

208 212*4 \. / "

200 240

SPMPLE SPECTRUM (BflCKSROUND SUBTRflCTED)File >C0791Bpk flb 6309

-

««»: 42

4!0

P1219 UESTONSUB

,, 7ft 106 1201 ' . "S

' ' "SO ' ' 180 ' ' '

038393

1\f 170180, />! , ,' ' 160 f ' '

Scan 843128.71 nin.240"%Sl

208 212

260 ' 24

-100•

0

SflMPLE SPECTRUM <UNALTERED>Fil« >C0791Bpk fib 6309

_40OO-

'. 44

40

01219 UESTON

66 79 12 ?? 132

8*0 ' 120 '

032393

156•v 170180

i i P \ i i ^ p'i i160

Scan 243128.71 Min.840"""1 -100

"

808 212\ / •.,.

.. ,. M,, ,M -0200 2< 0


Compound No: 64 (ISTD)Compound Name: d!2-ChryseneScan Number: 2431Retention Time: 28.71 min.Quant Ion: 240.0Area: 17791Concentration: 40.00 UG/Lq-value: 97




AR I 002.U8

REFERENCE STflNDRRD SPECTRUMFileBpk

>SX050 HPflb 100

100-

*,...,

54X

BNR Standard

66 80•'A"i"fTt'80

106X

50

122

120

50 ng/uLNRM

136 158

fr+416

Mixed

160/ *6

Basa N«ut Scan 140831.59 Min.244"V..

212 22684 V \f n..-..r Ji ..,..ii

200

-100

iÔ240

SOMPLE SPECTRUM <BfiCK6ROUND SUBTRACTED)File >C0791 R1219 WESTON 032393Bpk Rb 8065 SUB

5000

^54 106 122 1S@ ^ 312<C 66 80 \ \ 136 x S 184 S>

4*0 ' so ' 120 ' 160 ' 260

Scan 217526.03 Min.244"

226\

-100.

. -o240

SflMPLE SPECTRUM CUNflLTERED)Fil« >C0791Bpk Rb 8065

5000-

j54

40

R1219 UESTON

106 i?266 80 v 1(:r 136

' 'so' ' ' 120 ' ' '

032393

158 160\s *r"•rto"""1"1212

V*200

Scan 217626.03 »in.244***

226

f i">. •torH'-240

-100•

-0

Data File: >C0791:;D4Name: A1219 WESTONMisc: 032393Quant Time: 930324 13:41Injected at: 930323 23:09

Compound No: 67Compound Name: Terphenyl-d!4Scan Number: 2175Retention Time: 26.03 min.Quant Ion: 244.0Area: 20759Concentration: 44.09 UG/Lq-values 91

Quant Output File: 0791: :D3



REFERENCE STANDARD SPECTRUM>DEM03

iCC

100-

64

80

88 102

NS STANDARDSUB CLP NRft

Sc*n 1626£9.87 m i n .

264-100

130 132163 180

40 K204 220 232\ \ /

120 160 200SAMPLE SPECTRUM <BACK8ROUNO SUBTRACTED)File >C0791Bpk Ab 4464

4000-•

0-44 64/ . /

40 i

01219

88 102Hi ff •

UESTONSUB

130 132r*"" 156

120 ' 160

032393

208180 X?

' ' ' ' 266 '

Scan £76032.14 min.

264*"*

232

rr+6r~4 -

-100••

240

SAMPLE SPECTRUM (UNALTERED)FiU >C0791Bpk Ab 4464

4000-

: 4/ 640- [I. ,'T, . If* j

40 £

A1219 UESTON

130 13288 102 """if" 1B6/ f 1 1 u 1 /•r rm-i i"r'i"Ti w, , . u v • •

50 120 160

032393

,„ 207180 v

"'""Uo""11

Scan 276032.14 nin.264*** -100

232

/, . ,4fr240

ata F i le : >C0791:: 04Name: A1219 WESTONMisc: 032393Quant Time: 930324 13:41In jec ted at: 930323 23:09

Compound No: 73 ( ISTD)Compound Name: d!2-PeryleneScan Number : 2760R e t e n t i o n Time: 32.14 m i n .Quant Ion: 264.0Area: 13886Concentration: 40.00 LJG/Lq-value: 96


BTL#11Quant ID F i l e : ID0323::D5


I 00250

la >C0791 (41219 WESTON 032393.^k fib 735 SUB flDD DVC

593 43 ' 73J 39 / 49 55^ 70 , 8fi

Q ' l . M ' J H i i i H i i i i / i n | i i i . | i i i ^ f i l i | i i i i | i n 7 T i i40 CO 60 70 80

la >BI8DB Butana, 2-ethoxy-2-»ethyl- OCX)>k fib 9999

59

1 « ? " ?^ ?ol.Tri . l . i . . . . . . . . . | , . . | . . . . . . . . . , | . | . . . . . . . . . . . . .

40 50 60 70 80

le >BI6DB Pentanal, oxinte < 9 C I >k fib 9999

59d 41 43 f

: 5L T 1 ? ™ ™40 ' 50 60 ' 70 ' 80

" le >BI8DB Butanamida <9CI).k fib 9999

44 59

3 "^ 51 55^ 66 71 J? 86

40 50 60 70 80

Unknown #,1

Scan 133.49 win .

" \' i l l . M l | l . . . i f O90 100

Scan 66490.00 M i n .

101 t

9'd ' 100Scan 16040.00 »in.

101 E, , , , , , , , , , , TTfo

90 100

Scan 16020.00 min.

87 88 frfriTrr.,..,,.ro90 100

^rea ™ 4886.00 Tenta t ive Concent ra t ion is 3 .00

.1. Butane, 2-ethoxy-2-methyl- ( 9 C I )2. Pen tana l , oxime (9CI )3. Bu tanamide (9CI)4. Acetamide C 8 C I 9 C I )

Sample f i l e : >C0791 Spectrum #:Search speed: 1 T i l t i n g o p t i o n : N

Prob. CAS * CON # ROOT K

1. 42 919948 6649 "BIGDB 592. 25* 628795 1604 "BIGDB 243. 24* 541355 1602 "BIGDB 244. 20* 60355 1577 "BIGDB 22

116 C7H160101 C5H11NO

87 C4H9NO59 C2H5NO

13No. of ion ranges searched:

DK #FLG TILT X CON C_I

37 2 0 56 27 1470 3 0 88 50 770 3 0 100 44 853 3 0 77 54 5

40

A R I 0 0 2 5 I

19121212

, xle >C0791

^ A^ j 39

40

il« >BI6DBBpk flb 9999

J 39

40

.le >BI6DBOpk flb 9999

3 39

40le >BIGDB

..k flb 9999

3 39

40

fl!219 UESTON 032393SUB flDO DVC

/ 65 85 94 102 ",1 -.' , , 1 ' ' / (

60 80 100B«nz«n«, l,l'-oxybis-

•5 128 139 I:

Scan 130316.94 win.170

141 ""*• H** 155 p

/ I.P.,iso ' 140 ' i£b<9CI)

51 77/ 65 •v. 35 94 102 1)8 129 139 .-

.,!,... . - / , . ! '-({ ' ^ ^160 80 100

Cl,l'-Biphenyl3-3-ol

51 63 76 85 89 102 13/ / f_ 1 r*~ / ?

'""so"' so ' i6b "'"Cl ,1 '-Biphanyl 3-4-ol

Scan 202960.00 Min.170

141 ^FJ"" 154 t. ../ ,,L

120 ' "iib" ''"'ilb'"<9CI>

.5 128 139 ^

Scan 202980.00 Min.170

3« 152 E•^ .**• ..I.F1 II 1 1 1 | 1 1 1 I')' • I • | • I I I I 1 I • • | • v

120 140 160

<9CI> Scan 202940.00 Min.170'V.L

51 63 76 85 89 102 11B 187 139 J 41 152 f1 e'o ' so * i6b ' 120 14B'"" ifib '

reaUnknown 4,10102670.0 Tentative Concentration is

1. Benzene, l,l'-oxybis- (9CI)2. Cl,l'-Biphenyl]-3-ol (9CI)3. Cl,lf-Biphenyl]-4-ol (9CI)4. !H,3H-Naphtho[l,8-cd]pyran (8CI9CI)

40.00

170 C12H100170 C12H100170 C12H100170 C12H100


Prob. CAS * CON # ROOT K DK #FLG TILT X CON C_I R_I

1.2.3.4. fev

76*28*26*11*

10184858051892693203849

20296202982029415988


71322430

35587178

2223

0000

879710055

14434462

40882

52161413

ARI00252

Q C RESULTS

f lR I00253

QUALITY CONTROL DATA

ANALYSIS NO:

BATCH NO:

MATRIX:

METAL

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

bCADMIUM

CHROMIUM

COBALT

COPPER

IRON

LEAD

MANGANESE

MERCURY

NICKEL

SELENIUM

SILVER

THALLIUM

VANADIUMZINC

MOLYBDENUM

•

A 1218

M 029

Aqueous

AMOUNT OF SPIKE (ug)

2000

50040200050502005002501000205001.0500

10.050!50500500500

91 RT OFNTI IHV FNVinnNMFNTfl

% SPIKE RECOVERY

100102

799610013610099102

9612998911041009689100102109

1 . N.IDFPF OFRTIFIOATIC

Z SPIKE DDP RECOVERY

991027697

10013499101101958697991049210188100102111

>N «O8O31 ———— uK 1 UUc.w'T ———


BATCH NO:

MATRIX:

METAL

ALUMINUMANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUMCALCIUMCHROMIUM

COBALT

COPPER

IRON

LEADMAGNESIUMMANGANESEMERCURY

NICKEL

SELENIUM

SILVER

SODIUMTHALLIUM

VANADIUM

ZINC

MOLYBDENUM

M 029

Aqueous

METHOD B]

N.D.N.D.

N.D.N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.N.D.N.D.N.D.N.D.

—— 2isrr:Fi

AMOUNT OF SPIKE (ug/L) Z SPIKE RECOVERY

62512310514145.2131904054063512456013723801504.9314912511915600111166187139

1109794999793989699100104951009510310395921079996102107

¥

•21ST CENTURY ENVIRONMENTAL • NJDEPE CERTIFICATION A R I Q Q 2


ANALYSIS NO: A 1217

BATCH NO: M 031

MATRIX: Soil

METAL AMOUNT OF SPIKE (ug) % SPIKE RECOVERY % SPIKE PUP RECOVERY

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUMCADMIUM

CHROMIUM

^ COBALT

^ COPPER

IRONLEAD

MANGANESE

MERCURY

NICKEL

SELENIUM

SILVER

THALLIUM

VANADIUM

ZINC

MOLYBDENUM

4000

1000

80

400010010040010005002000100010002.0100020.0100100100010002000

1081020

09787909695081879596

01057796097

0

10000959988949408187819801097295098

21ST CENTURY ENVIRONMENTAL • NJDEPE CERTIFICATION #08031 fl R ( QQ256

BATCH NO:

MATRIX:

METAL

ALUMINUMANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALTCOPPER

IRON

LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

SELENIUM

SILVER

THALLIUM

VANADIUMZINC

MOLYBDENUM

M 031

Soil

METHOD BLANK

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

N.D.

—— 21STOFNTURY


(ng/L) AMOUNT OF SPIKE (ug/L)

511021.334.297.458.1

70.3233018212092.7862044.5153014513.713733.164.414040.178.245.0

FNIVIHDNIMFNTAI • N.IDFPF r.FRTIFICATinN ±

Z SPIKE RECOVERY

9916386122

103112112

901061077811510797112

1079212010786119128

mflnafl.D 1 D O O £7

4

21ST CENTURY ENVIRONMENTAL, INC.SOIL semi-VOLATILE SURROGATE RECOVERY

SAMPLE SI S2 S3 S4 S5 56 TOTNO. (NBZ)# (FBP)# (TPH)* (PHD* (FPH)* (TBP)* OUT

SOIL BLNK 88 123* 114 68 71 61 1A1216 77 89 88 92 81 91 0A1217 84 108 106 103 96 107 0A1263MS 94 105 86 99 88 102 0A1263MSD 94 108 114 99 94 110 0

PC LIMITS

51 (NBZ) - Nitrobenzene-d5 (23-120)52 (FBP) - 2-Fluorobiphenyl (30-115)53 (TPH) - Terphenyl-dl4 (18-137)54 (PHD = Phenol-d5 (24-113)55 (FPH) - 2-Fluorophenol (25-121)56 (TBP) - 2,4,6-Tribromophenol (19-122)

# Column used to flag surrogate recovery values

flRI00258

21ST CENTURY ENVIRONMENTAL INC.WATER semi-VOLATILE SURROGATE RECOVERY

SAMPLENO.

AQ BLANKA1218A1219A0889MSA0889MSD

SI(NBZ)#6375617278

S2(FBP)*6291736168

S3(TPH)*73108887881

S4(PHD*6737324850

S5(FPH)*6951425357

S6(TBP)*5490704243

TOTOUT00000

** Values out due to matrix interference

QC LIMITS

51 (NBZ) - Nitrobenzene-d5 (35-114)52 (FBP) - 2-Fluorobiphenyl (43-116)53 (TPH) - Terphenyl-dl4 (33-141)54 (PHD - Phenol-d5 (10-94 )55 (FPH) - 2-Fluorophenol (21-100)56 (TBP) - 2,4,6-Tribromophenol (10-123)

If Column used to flag surrogate recovery values

10035-9

AccuQual Laboratories, Inc.

Matrix Spike/Matrix Spike Duplicate (MS/MSD! Percent Recover; detenination for BIPHEIY and PHEITL ETHER

D1TE: 3/26/93LAB ID*: 08193-1IISTRUMEIT: GC2

COMPOUIDS

biphenjlphenyl ether

OBS. OBS. DBS.SPIKE BKGD MS USD MS:MSD MS MSD AVGLEVEL COIC. COIC. COIC. R1IGE IUC. tUC. ttEC. EPD

0.25 0.077 0.35 0.36 0.010 109 113 111 3.60.25 0.36 0.60 0.61 0.010 96 100 98 4.1

LE6EID:OBS.: OBSERVEDAVG.: AVERAGE*REC.: PERCEIT RECOVERYCOIC.: COICEiTRATIOIBKGD.: BACKGROUID

RPD: RELATIVE PERCEITDIFFEREICE

I/A: DATA IOT .AVAILABLEERR: 10 DATA COMPUTEDRAIGE: ABSOLUTE DIFFEREICE

ROTES:1. ALL RESULTS SHOBI ABOVE ARE II UIITS OF uG

flRI00260

Areas, times, and heights stored in: D:BEC2B27.ATBData File = DsBGC2B27.PTS Printed on 03-26-1993 at 20:58:15Start time: O.OO min,, Stop time: 35.00 min. Offset!Full Range: 150 millivolts

10 mv

I!it

1 t 1 1 LI 1 I _.!___1_

rt I ! t

A R I 0 0 2 6 !

Areas, times., and .heights stored ins D :BGC2B28. ATEData File = D; BBC2B2S „ PTS Printed on 03-26-1993 at 21:; 39s 50Start time: 0.00 min. Stop times 35.00 min. Offset:Full Range: 150 millivolts . •

10 mv,

ARI00262

3DSOIL SEMIVOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

SAS No.:Lab Name: 21st Century EnvironmentalLab Code: Case No:MATRIX SPIKE- EPA SAMPLE NO.:A1263

Contract No.:SDG No.:

1 COMPOUND NAME11

I Phenol12-Chlorophenol1 1,-4-Dichlorobenzene1 N-Ni t roso-di-n-prop . (1)11,2,4-Trichlorobenzenel4-Chloro-3-methylphenollAcenapthene1 4-Ni t rophenol12 ,4-Dini t roto lueneIPentachloropheno 1IPyrene1

SPIKEADDEDUG/KG

100100505050100501005010050

MSCONCUG/KG

71.777.239.328.239.880.441.874.136.091.742.9

SAMPCONCUG/KG

NDNDNDNDNDNDNDNDNDNDND

MSXREC#

7277795680808474729286

QC LIMITSRECOVERY

26-9025-10228-10441-12638-10726-10331-13711-11428-8917-10935-142

1 COMPOUND NAME11| ..........................1 Phenol12-Chol rophenol1 1,-4-Dichlorobenzene1 n-Ni t roso-d i-n-prop .11,2,4-Trichlorobenzene!4-Chloro-3-Methyl phenolI Acenaphthene1 4-Nit rophenol12, 4-Dinitro toluene1 Pentach lo rophenolIPyrene

SPIKEADDEDUG/KG

100100505050100501005010050

MSDCONCUG/KG

70.276.138.928.037.678.841.069.936.793.244.4

MSD\

REC.

7076785675798270739389

%RPD

211

<162262

<13

QC LIMITS

RPD 1 RECOU

3550273823331950474736

26-9025-10228-10441-12638-10726-10331-13711-11428-8917-10932-142

1

(1) N-Nitroso-di-n-propylamine

# Column to be used to flag recovery and RPD values* Values outside of qc limits

RPD: out ofSpike Recovery:

COMMENTS: ___

outside limitsout of outside limits

FORM III SV-2 1/87 REV

A R 1 0 0 2 6 3

QUANT REPORT

Dperator ID: JEFF?-tput File: -SC0788::ED: ta File: >C0788::D4same: A1263MS1isc: 032393

C File: ID0323::D5Fitle: hSL BNA STDst Calibration: 930324 12:17

Compound

Quant Rev: 6 Quant Time:Injected at:

Dilut ion Factor:

930324 13:10930323 20:53

1.00000

BTL* 8


) *d4-l ,4-Dich lorobenzene-r) 2-Fluoropheno 15) Phenol-d5) Phenol) 2-Chlorophenol

.0) 1 ,4-Dich lorobenzeneL ' ) N-Ni t roso-Di-n-propylamineL ) *d8-Naphthalene.y) Ni t robenzene-d5J7) 1 j2 ,4-Tr ichlorobenzene«Chloro-3-methylphenol

0-AcenaphtheneFluorobiphenyl

i ) Acenaphthene• ) 4-Ni t ropheno 1£7) 2 ,4-Din i t roto luene?"*) *dlO-Phenanthrenei ) 2,4,6-Tr ibromophenol>>) Pentachloropheno 1i4) *d!2-Chrysene) Pyrene) Terphenyl-dl4

'3) *d!2-Perylene

10.377.399.799.829.9610.4111.6313.5711.9213.4915.2118.1016.4218.1818.6918.8521.8620.1621.5828.6925.5626.0232.13

6733886186216346777949808229721137141412531422147114861775161217482429212921732758

15240180702659727774247041517962342940112362134361736316481289692256649936502235814196590613982296222001711675

40.0087.8598.5871.6777 . 1739.2928.2140.0047.0839.7880.4240.0052.2941.8374.1136.0440.00101.5391.7040.0042.8954.1040.00

UG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/L

9091887896

# 9489

*"' 88879889919595989399979497998795

Compound is ISTD

ARI0026U

JOTflL ION CHROHflTOeRRtt032393

r . . . ???. . . t . . .1.°i°.? i .1.Si°.° i .a.°iQ.Q. . . r . . .2.5i°°

File >C0788 35.0-500.0 urn. H1263HSTIC

80000-

70000-

60000-

50000-

40000-

30000-

£0000-

10000-

3000

Data File: >C0788::D4Name: A1265MSMisc: 032393


Operator ID: OEFFQuant Time: 930324 13:10Injected at: 930323 20:53

Quant Output File: 00788::ED

BTL* 8

3RI00265

QUANT REPORT

perator ID: JEFFutput File: ^C0789::EDi :a File: >C0789::D4o.ne: A1263MSDisc: 032393

i File: ID0323::D5it le: hSL BNA STDnt Calibration: 930324

Compound

Quant Rev: 6 Quant TimeIn jected at

Dilution Factor

930324 13:15930323 21:39

1.00000

BTL* 9

12:17


j *d4-l ,4-Dich lorobenzene<.; 2-Fluoropheno 15) Phenol-d5i > Phenol$ i 2-Ch loropheno 10) 1 ,4-Dich lorobenzeneM N-Nitroso-Di-n-propylamine! i *d8-NaphthaleneVJ Ni t robenzene-d57) 1 ,2, 4-Trich lorobenzene>^B|rChloro-3-methy Ipheno 1

! i^^Mo-Acenaphthene8 ) ^^Fluorob ipheny 17 1 Acenaphthene1 ) 4-Ni t ropheno 1» 2,4-Dinitrotoluene31 *d!0-Phenanthrene Terphenyl-dl43) *d!2-Perylene

10.377.409.809.839.9610.4111.6313.5711.9213.4815.2118.1016.4218.1818.6918.8521.8620.1621.5728.6925.5626.0232.13

673388618621634677794980822971

1137141412531422147114861775161217472429212921732759

18428233153230832912294641815174873592115125155242079719261350422582355007735263515103670614191311422146612259

40.0093.7499.0370.2376.1238.8628.0240.0047.1537.6278.8440.0054.1340.9669.8536.6940.00110.5093.1740.0044.4357.1640.00

UG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/L

9689897697929289859189929495959399969697988793

Compound is ISTD

TOTflL ION CHROHflTQ6Rflf1______"File >CO?8935.0-500.0 aau. R1263MSD

TIC032393

100000-

90000-

80000-

70000

eoooo:

50000^

40000^

30000^

aoooo^

lOOOfr

0:

5pQ , 1000 1500 2000 2500 3000

' 2T8" ' ' iz se

Data File: >C0789::D4Name: A1263MSDMisc: 032393



Quant Output File: /NC0789: : ED

BTU* 9

3CWATER SEMIUOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

ab Name: 21st Century EnvironmentalLab Code: Case No:MATRIX SPIKE- EPA SAMPLE NO.: A0889

SAS No.:Contract No.:

SOG No.:

COMPOUND NAME

3heno 1' Cholrophenol-4-Dichlorobenzene

^-Nitroso-di-n-prop. CD! 2,4-Trichlorobenzene'• Chloro-3-methylphenol^cenapthene$-Ni t rophenoli 4-Dini t roto luene; ..ntachloropheno 1'yrene

SPIKEADDEDUG/L

100100505050100501005010050

MSCONCUG/L

35.054.526.623. 024.062.530.020.023.039.336.0

SAMPCONCUG/L

NDNDNDNDNDNONDNDNDNDND

MSXREC*

3554534648626020463972

QC LIMITSRECOUERY

12-8927-12336-9741-11639-9823-9746-11810-8024-969-10326-127

3CWATER SEMIUOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOUERY

Name: 21st Century EnvironmentalLab Code: Case No:MATRIX SPIKE- EPA SAMPLE NO.:A0889

SAS No.:Contract No.:

SDG No.:

COMPOUND NAME

>henol! Cholrophenol, -4-Dichlorobenzenei-Nitroso-di-n-prop.2,4-TrichlorobenzeneChloro-3-Methylphenol

icenaphthene-Nitrophenol4-Dini trot o luene

entachlorophenolyrene

SPIKEADDEDUG/L

100100505050100501005010050

MSDCONCUG/L

38.660.829.425.925.867.532.623.925.439.736.9

MSD96

REC.

3961595252686524514074

96RPD

10111012788181012

QC LIMITS

RPD 1 RECOU

42 1 21-8940 1 27-123283828423150385051

36-19741-11639-9823-9746-11810-8024-969-10326-127

) N-Nitroso-di-n-propylamine

3lu,mn to be used to flag recovery and RPD valuesoutside of qc limits

out of 11 outside limitsRecovery: 0 out of 22 outside limits

DMMENTS: -JHH00268FORM III SU-2 1/87 RED

QUANT REPORT

srator ID:^jut File:a File:

JEFF~C0691::E4>C0691: :D4


Dilution Factor:ne: A0889MS

031293

930312 14:30930312 13:49

1.00000

BTL* 2

File: ID0312::D2tie: hSL BNA STDt Calibration: 930312 11:31

Compound R.T. Scan* Area Cone Units

Compound is ISTD

*d4-l,4-Dichlorobenzene2-Fluoropheno 1Phenol-d5Phenol2-Ch loropheno 11,4-DichlorobenzeneN-Ni t roso-Di-n-p ropy lamina*d8-Naphtha leneNitrobenzene-d51 ,2,4-Tr ich lorobenzene4-Chloro-3-methylpheno 1

i *dlO-Acenaphthenei 2-Fluorobipheny 1

Acenaphthene» 4-Nitropheno 1I 2,4-Dinitrotoluene*dlO-Phenan throne2,4,6-Tribromophenol

> Pentachlorophenol' *d!2-Chrysene

Pyrene> Terphenyl-dl41 *d!2-Perylene

11.418.5210.7810.8011.0011.4512.5914.5312.9014.4316.0818.9817.3019.0619.4919.6922.6921.0022.4029.4726.3726.8032.97

3401983093103203423984934134885697116297157367468938108791225107310941396

20905168822016920148234221293584914706715080113442455228447292712784127527582374463901463118733311842049015365

40.0053.4248.0734.9554.5126.6123.0140.0035.8623.9562.4940.0030.5429.6619.9422.5540.0041.9839.3440.0036.0338.9840.00

UG/LUG/LUGXLUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/L

9788837599938886879497989488758599979996939593

N CHROriflTOSRflfl0691 35.0-500.0 **U. flQ389hS

TIC400

——031293 ————

890 . . . . . 1500 . . . . 1600

110000J

100000

90QQOJ

70000

50000-

3QQQQ

10000

a'o '

Data File: >C0691::D4Name: A0889MSMi»c: 031293



Quant Output File: /*C0691::E4

BTL* 2

QUANT REPORT

»rator ID: JEFF3Ut File: "C0692:: E4

..a File: >C0692::D4ne: A0889MSD=: 031293

File: IDQ312::D2Me: hSL SNA STDt Calibration: 930312 11:31

Compound


Dilution Factor:

930312 15:17930312 14:37

1.00000

BTL* 3


*d4-l,4-Dichlorobenzene2-FluorophenolPhenol-d5Phenol2-Chlorophenol1,4-DichlorobenzeneN-Ni troso-Di-n-p ropy lam ine

»d8-Naphtha leneNi trobenzene-d51,2,4-Tr ichlorobenzene4-Chloro-3-methylpheno 1*dlQ-Acenaphthene2-FluorobiphenylAcenaphthene4-Nitrophenol2,4-D in itro toluene*dlO-Phenan throne2,4,6-TribromophenolPentachlorophenol*d!2-ChrysenePyreneTerphenyl-dl4*d!2-Perylene

11.428.5210.7910.8111.0111.4612.6014.5412.9114.4416.0918.9817.2919.0619.4919.6822.7021.0022.3929.4826.3726.7832.97

3391973083093193413974924124875687106277147357448928098771224107210921395

19147165061921720374239101308187504424615474114692492426359302682837130607908366703890457719207327662175116086

40.0057.0250.0138.5860.7529.3825.8940.0039.1425.7667.4940.0034.0832.6123.9225.3940.0042.7539.7140.0036.9240.3540.00

UG/LUG/LUG/LUG/LUG/LUG/L "UG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/L

8897947898918588909792979593829399949592949196

Compound is ISTD

/JRI0027I

i *

Data File: >C0692::D4Name: A0889MSDMisc: 031293

Id File: ID0312::02Title: hSL BNA STDLast Calibration: 930312 11:31


Quant Output File: /NC0692: :E4

BTL* 3

21ST CENTURY ENVIRONMENTAL INC.

GC/MS STANDARD DKAFLUKWTRIWCNYLPHOSPHINE(DFTPP) TUNECRITERIA FOR SEMIVOLATILES 50ng

DATE AND TIME OF INJECTION: 3/23/93 14:04INSTRUMENT ID: 5970 _

DATA RELEASE AUTHORIZED BY

Ion Abundancern/z Criteria

51 30-60* of MSS 19868 Less than 2X of MSS 6969 (reference only)70 Less than 2X of MSS 69127 40-60* of MSS 198197 Less than IX of MSS 198198 Base peak, 100X relative abundance199 5-9* of MSS 19827? 10-30* of MSS 19836? Greater than IX of MSS 198441 0-100* of MSS 443442 Greater than 40X of MSS 198443 17-23* of MSS 442

THIS PERFORMANCE AFFECTS ALL SAMPLESSTANDARDS AND BLANKS LISTED BELOW

X Relative AirBase AppPeak

37.060.0049.460.0042.530.00

100.007.0920.952.206.8944.369.73

tibdanceFBpriatePeak

37.060.0049.460.0042.530.00

100.007.0920.95'2.2070.8344.3621.93

Status

OkOkOkOkOkOkOkOkOkOkOkOkOk

(SAMPLE ID 11 1!>CQ779::D4I!>C0780::D4I!>C0781::D4II>C0782::D4I!>C0783::D4I!>C0784::D4II>C0785::D4II>C0786::D4II>C07B7::D4II>C0788::D4I!>C0789::D4II>C0790::D4I!>C0791::D4II>C0792::D4I!>C0793::D4I!>C0795::D4I1 1

ILAB ID1150 N9DFTPP!50 PPM BNA STD120 PPM BNA STD180 PPM BNA STDI120PPM BNA STDI160PPH BNA STDIAO 9LAHKK 3/11IA1259MSIA1259MSDIA1263MSIA1263MSOIA1218 UESTONIA1219 UESTONIA1216 UESTONIA1217 UESTONIA1098 KRAJACK 1:101

DATE TIME 11

3/23/93 14:0413/23/93 14:3013/23/93 15:2913/23/93 16:15!3/23/93 17:0113/23/93 17:5113/23/93 18:3713/23/93 19:2213/23/93 20:0813/23/93 20:5313/23/93 21:3913/23/93 22:24!3/23/93 23:09!3/23/93 23:5513/24/93 0:4013/24/93 2:101

1

ARI00273

"ri B;0779 35.0-500

25000:

20000;

isoooilOOOOi

500OJ

O-T--

't-,° i 4i°.0 amu. 50cN8 DFTPP

60 f 80 ( 100032393

120 140 160 180

. 1 16.0 &.& 6.4 6.6 6.8 7.0

Fil« >C0779 50 NG OFTPP°pk fib 2960

3000-

2000-

1000-

M

51

/I

"

50'"

69X 127' \

j-. iL

198

186

,«t 1 .<!.. ,1 <l 1.1

100 150 2

^

255\.

l.Llil L

:ioo:soLeo40

•£0

7 8 ' 71.4 7 '.6 ' 7 '.8 ' e'.O032393 Sc*n 176

7.81 win.

442\

275/i2?6 334 365

' . . f f.)0 ' 250 ' 360 " ' " 350 " ' " 400 '

-100

-80

-60

-40

-20

-0

>C0779176

50 NG DFTPPNRfl

File: >C0779 Scan #:

032393

176 Retn. time: 7.81ARI0027/4

m/z Int. m/z Int. m/z Int . m/z Int. m/z Int .

37.9539.0539.9544. 0550.0051. 0052.0055. 1055.30Ko

o0

63.0565.0569.0574.0575.05

.7774.7976.8587.60110.13537.0611.892.642.642

1. 1492.196.845

2.1621.25049.4594.2576.858

91.9592.3592.9595.8598.0599.15100.95103.45107.00108.10110. 00111.00115.90117.00117.90122.85123.95

•

5.•

3.2.1.

*

12.1.

24.4.•

8..

1.•

811811000574074635554372027993088020912277811284608

135.80136.30141.00141.90146.40147.95148.85152.95154.95155.95157.95159.85161.00164.90166.00167.00167.80

.574

.6762.669.507.372

2.568.811.541.7432.264.507.912

1.115.811.811

4.2911.588

184.95185.15186.05187.05188.90192.00192.90196.00198.00199.00203.95205.05206.05206.95209.95211.15216.90

1.1.14.4.•

1.1.3.

100.7.3.6.27.2.•

a

6.

385655358730946182081277000095142993331838574743081

242.95244.00245.90249.10255.00256.00257.95264.95273.00274.00275. 00276.00276.90296.05314.95323.05334.10

.5749.5272.432.473

51.3858.2092.8381.1151.7574.25720.9462.5341.9265.2361.0811.3181.351

78.1079. 0080.0081.0083.1087.10

3.2432.8382.2643.649.709.541

127.95128.95129.95131.05134.00135.10

3.48019.7971.791.405.541

1.959

J.O 7 .

174.175.179.180.180.

U U

1005050595

.9121.9933.4462.7701.284

221.80222.90224.00225.10227.00

7 . O Ut)1.0471.65513.7843.4466.216

3 / JL422423441442443

. 77

.00

. 00

.00

.00

.00

. o/ a

.5072.4666.89244.3589.730

Initial Calibration DataHSL Compounds

No:

Contractor: 21st Century Envir

Contract No:

Minium RF for SPCC is 0.050

InstruMnt ID: 597QC

Calibration Date: 03/24/93

HaxinuM X RSO for CCC is 30X

Laboratory ID: >C0781 >C0780RF RF

Compound 20.00 50.00

Pyridinen-Ni t rosod inethy laaine2-FluorophenolPhenol -d5Phenolbis (-2-Ch loroethy 1 )Ether2-Chlorophenol1 ,3-Dich lorobenzene1,4-DichlorobenzeneBenzyl Alcohol1,2-Dichlorobenzene«hylphenol

-ChloroisopropyDetherhylphenol

N-Ni t roso-Di-n-propy lamineHexachloroethaneNitrobenzene-d5NitrobenzeneIsophorone2-Nitrophenol2,4-DiaethylphenolBenzoic Acidb is (-2-Ch loroethoxy )Het hane2,4-Dichlorophenol1 ,2 ,4-Tr ich lorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4-Chloro-3-nethylphenol2-Met hy Inaph tha lene

.39789

.55613

.63081

.828341.07965.92494.911011.049051.11240.254951.02548.762871.19259 11.49453 1.66600.47196.37425.44921.85840.21311.31136.12272.46874.34764.496961.25626 1.39404.28052.28547.83060

.62599

.56759

.52924

.70064

.92513

.85194

.80065

.98620

.97675

.32456

.93387

.72036

.22089

.38617

.60402

.44683

.35787

.46370

.80678

.23014

.30546

.21460

.46457

.38072

.48028

.21119

.44706

.28486

.30325

.80010

RF - Response Factor (Subscript is amount

RRT - Average Relative Retention Tine (RT

>C0782 >C0783RF RF80.00 120.00

.79857

.61476

.61998

.78967

.98928 1

.90239

.852561.048521.05001.35307.95940.719231.24637 11.43759 1.55439.45728.37213.46279.82010.24783.32183.23488.47708.39637.488261.25989 1.45064.27983.30130.81267

in ug/1)

.75295

.58620

.59797

.77175

.07445

.88875

.83874

.97355

.98309

.40206

.91928

.74188

.17803

.47069

.52383

.42972

.35311

.42308

.80901

.23198

.29075

.19547

.43864

.37016

.42488

.11844

.44663

.23801

.29915

.75168

>C0784RF

160.00

.68351

.54437

.32150

.450421.01740.84132.79799.93688.94763.32353.89862.699271.490111.39301.55180.42411.32865.39411.77456.21914.28009.26994.42402.35593.407291.07881.39512.22618.27953.76062

RRT

11111111

11111

.385

.397

.713

.945

.947

.962

.960

.990

.004

.052

.048

.085

.085

.123

.123

.115

.878

.881

.922

.939

.952

.983

.970

.981

.993

.004

.027

.036

.120

.133

RF

.65178

.57381

.53990

.708171.01718.88187.84019.998841.01398.33163.94733.728721.265601.43640.58001.44598.35721.43858.81377.22844.30190.20752.45461.37017.459531.18492.42670.26188.29374.79113

% RSD CCC SPCC

2442321635461653103945635526458661034

.005

.811

.767

.371

.302 *

.954

.491

.911

.566 *

.108

.170

.338

.132

.295

.669 "

.408

.135

.791

.707

.844 «

.491

.428

.912

.246 •

.830

.944

.881

.531 «

.600 *

.281

Std/RT Istd)

CCC

- Average Response Factor

- Percent Relative Standard Deviation

- Calibration Check Compounds (*) SPCC - System Performance Check Compounds (**)

Fort UI Page 1 of 3

(Cone-100.0,100.0,100.0,1(Cone-100.0,100.0,100.0,1

(Conc-5fl.0,50.0,50.0,50.0

flRIQ0276


Case No: Instrument ID: 5970C

Contractor: 2ist Century Envir Calibration Date: 03/24/93

Contract No:

Minimm R? for SPCC is 0.050 HaxiBtm % RSO for CCC is 30*

Laboratory ID: >C0781 >C0780 >C0782 >C0783 >C0784DC BC DC DC DC

Compound 20.08 50.00 80.00 120.00 160.00 RRT R? X RSO CCC SPCC

Hexachiorocyclopentadiene .29677 .37439 .46543 .40055 .34843 .880 .37711 16.579 «*2,4,6-TrichIorophenol .44355 .46265 .45479 .41167 .38558 .897 .43165 7.471 »2,4,5-Trichlorophenol .45232 .49981 .48836 .47546 .40909 .901 .46501 7.7192-Chloronaphthalene 1.43395 1.43527 1.49074 1.32952 1.26955 .919 1.39181 6.4542-Fluorobiphenyl 1.39590 1.33866 1.45324 1.33367 1.20095 .907 1.34448 6.988 (Cone-50.0,50.0,50.0,50.02-Hitroaniline .32934 .39466 .40597 .43460 .41626 .946 .39617 10.132Diwithyl Phthalate 1.56273 1.54647 1.52186 1.49039 1.51560 .976 1.52741 1.838Acenaphthylene 1.99431 1.99721 2.07141 1.88111 1.82745 .978 1.95430 5.0273-NitroaniIin« .23872 .26953 .26742 .29278 .28241 1.006 .27017 7.536Acenaphthene 1.35932 1.32089 1.36730 1.25529 1.24349 1.005 1.30926 4.396 •2,4-DinitrophenoI .06220 .12414 .12615 .16504 .16834 1.821 .12917 33.164 *«4-HitrophenoI .09229 .18528 .17067 .18459 .18477 1.033 .16352 24.641 «Dibenzofuran 1.87940 1.91401 1.91602 1.82185 1.79498 1.027 1.86525 2.9342,4-DinitrotoIuene .36595 .44976 .43531 .46100 .47724 1.042 .43785 9.8272,6-DinitrotoIuene .30115 .34600 .35198 .36663 .37284 .988 .34772 8.107DiethylphthalBte 1.53548 1.58078 1.50895 1.37053 1.48523 1.075 1.49620 5.2604-Chlorophenyl-phenylether .73155 .75123 .72063 .68890 .69092 1.078 .71665 3.735Fluorene 1.49651 1.49850 1.45438 1.34260 1.34841 1.076 1.42808 5.4234-Hitroaniline .20235 .26523 .24453 .28954 .29714 1.095 .25976 14.7134,6-Dinitro-2-»thyIphenol .09887 .15060 .15508 .16465 .15300 .908 .14444 18.019N-Nitrosodiphenyla*ine .58653 .59309 .61599 .56766 .52353 .910 .57736 6.810 *2,4,6-Tribroiophenol .08549 .08286 .07211 .06141 .04870 .923 .07010 21.818 (Cone-100,0,100.0,100.0,14-BrowiphenyI-phenylether .24500 .26096 .26598 .24370 .21559 .949 .24625 8.003Hexachlorobenzene .27206 .27468 .27730 .23967 .23145 .964 .25903 8.380 *Pentachlorophenol .08412 .13937 .11572 .10859 .09846 .987 .10925 18.855 »*Phenanthrene 1.35822 1.35752 1.40035 1.27333 1.21042 1.003 1.31997 5.808Anthracene 1.32457 1.34884 1.34782 1.27742 1.24384 1.008 1.30850 3.539Di-n-Butylphthalate 1.76506 1.67098 1.68341 1.49164 1.43961 1.078 1.61014 8.572Fluoranthene 1.07029 1.25434 1.09874 1.00835 .93144 1.143 1.07263 11,204 «Pyrene 2.25274 1.84279 2.07974 1.85934 1.84417 .891 1.97576 9.335

RF - Response Factor (Subscript is anunt in ug/1)

RRT - Average Relative Retention Tine (RT Std/RT Istd)

RF - Average Response Factor

*RS0 - Percent Relative Standard Deviation

CCC - Calibration Check Compounds (*) SPCC - Syste» Performance Check Compounds (**)

Fon UI Page 2 of 3 ARI00277

Initial Calibration DataHSL Coipounds

No: Instrument 10: 5970C

Contractor: 21st Century Envir Calibration Date: 03/24/93

Contract No:

Hinimum RF for SPEC is 0.050 Haximum * RSO for CCC is 30%

laboratory

Compound

) ID: >C0781RF20.00

>C0780 >C0782 >C0783 >C0784PP PP PP PP

50.00 80.00 120.00 160.00 RRT RF XRSO CCC SPCC

Benzidine .06716 .11751 .21015 .19517 .13821 .889 .14564 40.068Terphenyl-dl4 1.23299 .99595 1.11197 .98146 .97024 .907 1.05852 10.662 (Cone-50.0,50.0,50.0,50.0Butylbenzylphthalate .93738 .93455 1.01421 .91390 .92266 .955 .94454 4.2423,3'-Dichlorobenzidine .16988 .24363 .23892 .23960 .19010 .968 .21643 15.741Benzo(a)Anthracene 1.33655 1.36432 1.39118 1.27300 1.25683 .998 1.32438 4.372Bis(2-Ethylhexyl)Phthalate 1.21339 1.31110 1.39281 1.29993 1.28951 1.006 1.30135 4.911Chrysene 1.24291 1.29894 1.29351 1.19360 1.19541 1.002 1.24487 4.090Di-n-octyl phthalate 2.20925 2.49110 2.75486 2.52733 2.62510 .944 2.52153 8.022 *Benzo(b)fluoranthene 1.31993 1.69341 1.66512 1.42020 1.48403 .973 1.51654 10.548Benzo(k)Fluoranthene 1.31890 1.29614 1.45472 1.42003 1.42892 .975 1.38374 5.145Benzo(a)Pyrene 1.26556 1.35063 1.44309 1.34690 1.38428 .996 1.35809 4.751 *

:no(l,2,3-cd)Pyrene 1.24468 1.37045 1.36088 1.28392 1.35071 1.079 1.32213 4.162hzo(a,h)Anthracene 1.03131 1.14083 1.14254 1.08745 1.11688 1.080 1.10380 4.192o(g,h,i)Perylene 1.06198 1.15568 1.17237 1.10394 1.14386 1.101 1.12756 3.947

RF - Response Factor (Subscript is amount in ug/1)

RRT - Average Relative Retention Ti*e CRT Std/RT Istd)

- Average Response Factor

- Percent Relative Standard Deviation

CCC - Calibration Check Compounds (*) SPCC - System Performance Check Compounds (*»)

Form VI Page 3 of 3 A R 1 0 0 2 7 8

— TOTBL ION CHROMfiTQGRflM>C0781 35.0-500.0 *J»u. 20 PPM BNfl STD

TIC032393

5pO f 10(00 ( 1500

48000-

44000-

40000-

36000-

32000-

28000-

24000-

£0000-

16000-

12000-

8000-

4000-

0-

20(00 2500 3000

JU' 8 ao

Data File: >C0781::D4Name: 20 PPM BNA STDMisc: 032593

Id F i l e : ID0318::D4Title: hSL BNA STDLast C a l i b r a t i o n : 930322 12:58

Operator ID: JEFFQuant Time: 930323 16:09I n j e c t e d at: 930323 15:29

Quant O u t p u t F i le : ^00781::D3

BTL* 1

/ I R I 0 0 2 7 9

3L ION CHROMPTQeRflflle >CO?80 35.0-500.0 amu. 50 PPM BNfl STD

TIC500 1000 1500

032393

8000 £500 3000

Data File: >C0780::D4Name: 50 PPM SNA STDMisc: 032393




BTL* 2

ARI00280

— TOTRL ION CHROMflTOSRflflfilm >CQ783 35.0-500.0 **u. 80 PPtt BNfl STD

TIC

100000-

90000-

8QGQQ-

70000

60000;50000

40000

30000

10000-



Operator ID: JEFFQuant Time: 930323 16:54Injected at: 930323 16sl5

Quant Output File: /SC0782: :D3

BTL* 2

ARI0028I

IL ION CHROMflTOSRfltt• >C0763 35.0-500.0 amu. 1SQPPH BNR STD

TIC500 1000 1500 8000 2500

Data File: >C0783::D4Name: 120PPM BNA STDMisc: 032393


Operator ID: JEFFQuant.Time: 930323 17:40Injected at: 930323 17:01


BTL* 3

flRI00282

TOTflL ION CHROMPTOSRflMFile >CO?84 35.0-500.0 a»u. 160PPM BNfl STD

TIC

160000-

500 1000 1500 2000 2500 3000

20000-

I " • I'" ' I " ' I " ' I • " < " ' I24 28 32 36

Data Fi le : >C0784:sD4Name: 160PPM BNA STDMisc: 032393

Id F i l e : ID0318::D4T i t l e : hSL BNA STDLast C a l i b r a t i o n : 930322 12:58

Operator ID: JEFFQuant Time: 930323 18:30In j ec t ed at: 930323 17:51

Quant Ou tpu t F i le : "SC0784: : D3

BTL* 4

21ST CENTURY ENVIRONMENTAL INC.

GC/MS STANDARD t£D Ut]ROTRIW£NYLPHOSPHINE(DFTPP) TUNECRITERIA FOR SEMIUOLATILES 50ng

DATE AND TIME OF INJECTION: 3/25/93 15:31INSTRUMENT ID: 5970

DATA RELEASE AUTHORIZED BY

Ion Abundance•/z Criteria

51 30-60X of MSS 19868 Less than 2X of MSS 6969 (reference only)70 Less than 2X of MSS 69127 40-60X of MSS 198197 Less than IX of MSS 198198 Base peak, 100X relative abundance199 5-9X of MSS 198275 10-30X of MSS 198365 Greater than IX of MSS 198441 0-100X of MSS 443442 Greater than 40X of MSS 198443 17-23X of MSS 442

THIS PERFORMANCE AFFECTS ALL SAMPLESSTANDARDS AND BLANKS LISTED BELOU

X Relative AbundanceBase AppropriatePeak Peak

54.320.0061.06.24

46.230.00

100.005.8518.992.037.9451.528.88

(SAMPLE ID 11 1I>C0814::D5II>C0815::D5II>C0816::E3II>CQ817::E3II>C0818::E3II>C0819::E3II>C0820::E3II>C0821::E3II>C0822::E3II>C0823::E3II>C0824::E3II>C0825::E3II>C0826::E3II>C0827::E3II>C0828::E3Il>C0829::E3i1 1

ILAB ID1150 NQDFTPP150 PPM BNA STD120 PPM BNA STDI160PPM BNA STD180 PPM BNA STDI120PPM BNA STDINA BLANK 031593IAQ BLANK 031193IA1254 FT. MDNMDUTHIA1102 CDUIA1103 CDUIA1099 KRAJACK 1:25IA1098 KRAJACK 1:5INA BLANK 031993IA0979IA11091

54.320.0061.06.39

46.230.00

100.005.8518.992.0389.3351.5217.24

Status

OkOkOkOkOkOkOkOkOkOkOkOkOk

DATE TIME I_____I

15:31115:57117:04117:51118:37119:24120:10120:57121:43122:29123:1510:0110:4711:3312:1913:041

I

3/25/933/25/933/25/933/25/933/25/933/25/933/25/933/25/933/25/933/25/933/25/933/26/933/26/933/26/933/26/933/26/93

• >C0814 35.0-50020 ( 40

~.0000-

J•QQQQ-

-20000-

.0 *»u. 50 US DFTPP 032593TIC

60 80 100 120 140 160 180

k0- | . !6.0

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198 P

186

148 N

255

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275

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•100

-80

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150 26b ' 250 ' 360 ' 350 ' 466 '

•C0814169

50 NG DFTPPNRM

032593

i le: >C0814 Scan #:

m/z I n t . m/z

37.0038.0039.1040.1043.1044.1049.0550.0551.0552.0554.8555.1555.9557.0561.0061.9062.1063.0064.90xo nn

52

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93.8098.0098.90

100.10101.00103.15103.95104.95106.95107.95110.05111.05111.95115.90117.00117.90122.00123.00123.90i r>K nn

169 Retn.

In t . m/z

.3923.3363.033

.2911.782

.5181.0111.024

13.6851.870

27.4324.132

.366

.80910.121

.644

.6821.491

.657KQ1

151.90153.00154.00155.00155.95156.95157.95158.95160.05161.05161.85164.25164.95165.95166.95167.95169.10170.90171.90I -5TC n n

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.594

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.607

.6321.466

.253

.2781.4661.0244.9792.401

.556

.227

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7.73

m/z

197.90198.90199.90200.80201.40202.90204.00205.00206.00207.00208.00209.95211.05214.95216.05216.95217.95221.05222.90r\f\ s. n ft

A R I 0 0 2 8 5In t . m/z I n t .

1005

35

232

1

6

61

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.000

.850

.505

.190

.644

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.652

.888

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5.105

128.10128.95129.95131.05132.05134.05135.05135.95136.95141.05142.00143.00143.80144.80146.20147.00147.90148.90150.20151.10

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1.933.644.783.278

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1.0111.478.404.253

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226.00227.00228.00228.90230.90234.00235.95236.85237.05240.75242.05244.05244.85245.95246.95248.85252.90255.00256.00257.00

^

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1.125.164.442.594.278.543

2.034.821.227.253.417.329.480

2.969.543

7.93551.5168.883.746


r—,ase No: Instrument ID: 5970C


Contract Ho:

Minimum RF for SPCC is 0.090 Maximum X RSO for CCC is 3OS

Laboratory ID

Compound

Pyridinei-Nitrosodimethylaminei!-FluorophenolPhenol-d5tianolis(-2-Chloroethyl)Ether

2-Chlorophanol1 ,3-Dichlorobenzene,4-Oich lorobenzene

benzyl Alcohol1 ,2-Dich lorobenzene'-Kethylphenol. is (2-Ch loro isopropyl Jethar4-HethyIphenol!-Nitroso-Di-n-propy laminalexachloroethaneNitrobenzene-d5nitrobenzenesophoronei-Nitrophenol2,4-Dimethylphenollenzoic Acidiis(-2-Chloroethoxy)Nethane2,4-Dichlorophenol'. ,2 ,4-Tr ich lorobenzenelaphthalene4-ChloroanilineHexachlorobutadiene{-Chloro-3-methylphenolXfethylnaphthalene

: >C0816RF20.00

.48709

.53972

.61699

.953131.12570.95338.83356.989181.00559.35368.93683.890851.938601.79288.87741.43814.38983.45467.97016.18622.32674.12486.49428.33325.438421.28745.44913

r .23266.33304.88749

>C0815RF50.00

.55875

.48986

.52633

.864331.01704.87118.78672.86218.88768.43245.84775.842501.283281.70819.87873.39297.35485.41979.95562.21401.30996.18169.47055.34950.404981.12998.42515.22231.37268.84802

>C0818RF80.00

1111

.95879

.65442

.64877

.06137

.37100

.11637

.014911.871791

11121

1

1

.08318

.61160

.07818

.85219

.65083

.25716

.07688

.50520

.40472

.49764

.15055

.24382

.36762

.14568

.55158

.40947

.43422

.23218

.55039

.23007

.43838

.92859

>C0819RF

120.00

.89820

.59761

.607541.072301.358131.06258.98352.94566.94958.66931.966631.833471.608812.21923.86040.44342.39355.463191.09898.24307.34870.28596.52971.38243.386851.10791.49179.20127.38899.80194

>C0817RF

160.00

t

.8617354676

RRT

t

..35153 ..576951.22170.93187

.

.

..88565 .•

•

t

•

•

1.1.•

.

•

•

1.•

•

•

•

•

•

1.•

•

•

•

9287994175598978956691721898679524683927432243537543410030392206532721255194844534877367000562543355191073815177020

.1.1.1.1.1.1.1.1....

377390712948951961961989804055048088086128126116877881923.939...

953990971.982.9931.0041.0281.0351.1231.134

RF

.75291

.56568

.55823

.995621.21871.98692.90087.95952.97354.53320.94340.947251.676041.98598.89454.44239.37934.453881.03954.22155.33605.19868.50610.36468.406281.14675.47000.21548.38290.84725

X RSO CCC SPCC

28.46311.06621.79122.36012.441 »18.14818.7668.0897.621 «25.0528.8799.66215.72712.42411.950 »»9.1196.1976.5697.89010.741 «6.65835.0156.6218.443 *7.5226.31311.0118.533 »9.867 «7.517

(Cone-100.0,100.0,100.0,1(Cone-100.0,100.0,100.0,1

(Cone-50.0,50.0,50.0,50.0

f - Response Factor (Subscript is a*ount in uo/1)

'XT - Average Relative Retention TiM (RT Std/RT Istd)

riF - Average Response Factor

RSO - Percent Relative Standard Deviation

CCC - Calibration Check Compounds (*) SPCC - System Performance Check Compounds (»*)

For. VI Page 1 of 3 AR I 00287


Contractor: 21st Century Envir

Contract No:

Instrument ID: 5970C

Calibration Date: 03/26/93

Minimum RF for SPCC is 0.090

Compound

Maximum X RSO for CCC is 30*

i ID: >C0816RF20.00

11

12

1

1

1

1

111

1

.20339

.32269

.34253

.32059

.33585

.39975

.78589

.07113

.30001

.36484

.02644

.09633

.84333

.43966

.36774

.87433

.76141

.50377

.23294

.04803

.60638

.06467

.26123

.26518

.03678

.24953

.21661

.80842

.93010

.88520

>C0815RF50.00

.22216

.34724

.371921.195491.21959.400031.637071.86201.274841.26043.04872.095891.72701.42445.367911.58214.699021.30283.21909.06580.60904.07223.27618.25926.057031.188551.194241.57957.852201.912711

>C0818RF80.00

11

12

1

1

1

1

11

.26010

.41920

.45530

.39372

.36912

.46459

.74943

.09072

.30566

.41234

.06845

.12496

.93922

.45402

.40318

.64816

.77215

.36398

.24345

.08249

.69471

.07383

.30170

.27963

.06635

.31705

.339441.8084511.03802.92788

>C0819RF

120.00

*

.

,

1.1..

1.1.,1.,

.

286604136346164292424230840070370847161724990244500768211792

1.65804t

.

1..1....m.tt1.1.1.1.1.

3698035111148756143402887205070852557660072812735424880080422318122082623640193869713

>C0817RF

160.00

11

11

1

1

1

1

111

1

.25511

.39001

.42057

.22674

.30235

.38619

.43985

.73800

.23306

.17692

.06383

.10363

.61128

.33674

.33259

.16259

.61182

.06915

.17349

.08079

.63682

.06955

.28878

.26099

.06747

.19821

.20161

.51508

.86031

.71526

RRT

.879

.897

.902

.919

.907

.947

.977

.9781.0071.0051.0211.0351.0271.042.9891.0761.0781.0761.096.909.910.923.949.964.9881.0031.0081.0791.143.891

RF

.24547

.37855

.410391.285791.33000.410251.596621.89560.272691.29181.05685.107751.75577.40493.364511.48320.691751.25372.21481.07247.62471.07062.28029.26277.061611.237031.234541.66703.940001.82763

XRSD CCC SPCC

13.376 »11.142 »12.6806.0925.7247.55011.5649.40211.4927.373 »34.885 «»12.169 «*7.67212.2747.14821.44411.13916.03812.68521.5407.134 »5.2185.5164.258 »26.277 »*4.1314.8308.0829.223 «6.133

Hexachlorocyclopentadiene2,4,6-Trichloropheno12,4,5-Trichlorophenol2-ChloronaphthaleneJ-Fluorobiphenyl2-NitroanilineDimethyl PhthalatefeenaphthyleneJ-NitroanilineAcenaphthene2,4-Oinitrophenol

Wenolranrotoluene

2,6-DinitrotolueneDiethylphthalate4-Chlorophenyl-phenyletherFluorene4-Nitroaniline4,6-Oinitro-2-MthyIphenolN-Nitrosodiphenylamine2,4,6-Tr ibronpheno 14-8roMphenyl-phenyletherHexachlorobenzenePentachloropheno1PhenanthreneAnthraceneDi-n-ButylphthalateFluoranthenePyrene

RF - Response Factor (Subscript is awunt in ug/1)

RRT - Average Relative Retention TIM (RT Std/RT Istd)

: Average Response Factor

Percent Relative Standard Deviation

CCC - Calibration Check Compounds (*) SPCC - System Performance Check Compounds (**)

FormUI Page 2 of 3 SRI 00288

(Cone-50.0,50.0,50.0,50.0

(Cone-100.0,100.0,100.0,1


Case No: Instrument ID: 997QC


Contract No:

Minimum RF for SPCC is 0.050 tlaximum % RSD for CCC is 30*

Laboratory ID: >C0816 >C0819 >C0818 >C0819 >C0817RF RF RF RF RF _ _

Compound 20.00 90.00 80.00 120.00 160.00 RRT RF X RSO CCC SPCC

Benzidine .28117 .27628 .21638 .18037 .12911 .888 .21666 29.821Terphenyl-dl4 1.29343 1.19217 1.13267 1.09132 1.03036 .907 1.13199 8.288 (Cone-50.0,50.0,50.0,50.0Butylbenzylphthaiate 1.07979 1.13399 1.19734 1.09660 1.07411 .999 1.11636 4.9633,3'-DichIorobenzidine .24690 .22791 .28897 .27249 .22823 .988 .29290 10.749Benzo(a)Anthracene 1.22472 1.29686 1.39096 1.28664 1.24824 .998 1.27349 3.820Bis(2-Ethylhexyl)Phthalate 1.60170 1.99406 1.81401 1.99291 1.62827 1.006 1.64611 9.768Chrysene 1.08732 1.09419 1.26340 1.18730 1.17446 1.002 1.16133 6.277Di-n-octyl phthalate 3.17664 3.38831 4.13722 3.39103 3.39637 .944 3.48991 11.678 *Benzo(b)fluoranthene 1.34092 1.38033 1.47648 1.29991 1.41933 .973 1.37499 9.906Benzo(k)Fluoranthene 1.18114 1.16409 1.72191 1.49369 1.38972 .979 1.38929 16.711Benzo(a)Pyrene 1.19093 1.18949 1.44943 1.31709 1.27199 .996 1.28360 8.381 *Indeno(l,2,3-cd)Pyrene .94481 1.14641 1.32187 1.20934 1.19190 1.078 1.07406 28.318Dibenzo(a,h)Anthracene .87812 .86702 1.14099 .96167 .96972 1.079 .96390 11.386Benzo(g,h,i)Perylene .86912 .89903 1.09622 .99997 .97470 1.100 .99101 9.098

RF - Response Factor (Subscript is amount in ug/1)

RRT - Average Relative Retention Time (RT Std/RT Istd)

RF - Average Response Factor

JKRSD - Percent Relative Standard Deviation

CCC - Calibration Check Compounds (») SPCC - System Performance Check Compounds (**)

For.UI Page 3 of 3 AR I 00289

ION CHROttflTQGRflM'C0816 35.0-500.0 a»u. £0 PPM BNfl STD

TICsop 10,00 1800 2000

65000-

60000-

55000-

50000-

45000-

40000-

35000-

30000-

25000-

20000-

15000-

10000-

5000-i o-1

032593

2500 30,00

12 16 20 24 28 32 36

Data F i l e : >C0816::E3Name: 20 PPM SNA STDMisc: 032593

Id F i le : ID0324::D4Ti t l e : hSL BNA STDLast C a l i b r a t i o n : 930325 10:39

Operator ID: JEFFQuant Time: 930325 17:43In jec ted at: 930325 17:04

Quant Output F i le : ysC0816::D5

BTL* 1

ARI00290

TOTflL ION CHRO»fiT00Rflt1rile >C0815 35.0-500.0 anu. 50 P P I l B N f i STO

TIC032693

500 1000 1500 2000 2500 3000




Quant Output File: 00815::ED

BTL* 2

A R J 0 0 2 9 I

C0818 35.0-500.0 ami. 80 PPfl BNfl STDTIC

Data File: >C0818::E3Name: 80 PPM BNA STDMisc: 032593



Quant Output F i le : "CQ818::D5

BTL* 3

^100292

TOTflL ION CHROMOTOeRBtlFile >CO

320000-

280000-

240000-

:200000-

160000-

12QQQQ-

80000-: .

40000-

0-

819 35.

1,14

0-500.0

500 (

I

k ' ' '

a»u. 120PPCI BNR STO 032693TIC

1000 t 1 00 ( 80,00 t 3500 ( 30,00

j

I

1

Via'

||LIi

1

]. 12*0 ' 24 ' ' S*8 ' 3(2 ' 36

t

Data File: >C0819:: E3Name: 120PPM BNA STDMisc: 032593



Quant Output File: "SC0819::D5

BTL* 4

ARI00293

ION CHROMfiTOSRflMC081? 35.0-500.0 aau. 160PR1 BNfl STD

???. ..i. . A0!0.0. i. ..1Si°.Q.

032893

2000 . 2500 3000

Data File: >C0817::E3Name: 160PPM BNA STDMisc: 032593




BTL* 2

ARI002914

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