y .

." UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

'-<, PBO *•" REGION .7 25 FUNSTON ROAD

KANSAS CITY. KANSAS 66115

Date: NOV 7

MEMORANDUM

i s m i t t a l for A c t i v i t y #: ^ J - ^ I C ? C T ^ : i p t i o n : H i d O — f> i^^ M >o^ /u c v\ i <

SUBJECT: Data Transmittal

Site Desciption: H i C O — T\i^-^ M>o^/uCv\ -TCP^ FROM: Andrea J i r k a ^

Chief, Laboratory Branch, ENSV

TO: Robert Morby Chief, Superfund Branch, WSTM

ATTN: J ^ V C- v CA A ATTXS

Attached is the data transmittal for the above referenced

site. This should be considered a Partial or i Complete data transmittal (completes transmittal of

. ) . If you have have any questions or

comments, please contact Dee Simmons at 551-5129. : [•/•

Attachments . . ..-.=1=4 * —.w ^

cc: Data Files .; Othor: . .i rtlSl • KV J.Ls..y-ll

NOTE: Please see Mary Gerken, SPFD-WSTM, if you want an electronic copy of the data.

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ANALYSTS REOUESTED: CONTAINER PRPSPRVA I IVE MCP NAME Cl ASS NONE Sp PESTICIDFS

DAIE I TMF. FROM REE P TEC : 00/20/'? 1 J I : iS:' PAST

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CONTENTS OF SHIPMENT j de^

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SHEET Of

SAMPLE NUMBER

TYPE OF CONTAINERS

CUBITAINER BOHLE BOTTLE VOA SET

(2 VIALS EA)

NUMBERS OF CONTAINERS PER SAMPLE NUMBER

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ENVIRONMENTAL SERVICES ASSISTANCE TEAM - ZONE H

ICF Technology

ManTech Environmental Tecbnology/ Ine.

ESAT Region VII ManTech Env. Tech., Inc. 25 Funston Road Kansas City, KS 66115 (913) 551-5000

TO: THRU:

FROM: THRU:

Barry Evans, Data Review Task Monitor/ENSV Harold Brown, Ph.D., ESAT Contract Manager/ENSV

Rebecca K. Estep, ESAT Data Reviewer/ManTech Ronald Ross, Manager/ESAT/ManTech

^ ^

DATE: October 8, 1991 SUBJECT: Review of organic data for Dico Des Moines.

TID#: ASSIGNMENT/: ICF ACCT#: ManTech S.O./: ESAT Document/:

07-9109-016 006 045-05-016-02 1110-016 ESAT-VII-016-5006

These data were reviewed according to the "Laboratory Data Validation Functional Guidelines for Evaluating Organic Analyses," February 1, 1988 revision and the "Laboratory Data Validation Functional Guidelines for Evaluating Pesticides and PCBs".

The following comments and attached data sheets are a result of ManTech Environmental Technology, Inc.'s review of the above mentioned data from the contract laboratory.

CASE NO.: CONTRACT NO.: SITE: REVIEWER:.

17046 68-D0-0154 Dico Des Moines Rebecca K. Estep

LABORATORY: METHOD NO: EPA ACTIVITY: MATRIX:

IOWA CS0390O CS125 Soil

Samples for Volatile, Semivolatile, and Testicide/PCB Analysis

SMO SAMPLE NQ. EPA SAMPLE NO.

GL401 GL403

CS125001 CS125003

SMO SAMPLE NO. EPA SAMPLE NO.

GL402 CS125002

GENERAL

m Case 17046 contained 3 environmental and 20 QC low level

concentration soil samples for volatile, base/neutral and acid, and pesticide/PCB analyses. This package includes no field blank, no ield duplicate, and no performance evaluation sample. Data review as perfoinned at level 2.

1. TECHNICAL HOLDING TIMES and PRESERVATION

A. No technical holding times or required preservation are specified for soil samples.

2. GC/MS Tuning

A. All volatile and base/neutral and acid GC/MS tunings and mass calibrations were within quality control limit requirements for bromofluorobenzene (BFB) and decafluorotriphenylphosphine (DFTPP), respectively.

3. INITIAL and CONTINUING CALIBRATION

A. All average relative response factors and relative response factors were within quality control limit requirements for the volatile and base/neutral and acid initial and continuing calibrations, respectively.

B. Acetone, 2-butanone, and 2-hexanone were outside quality 'control limit requirements for percent difference (%D) on the volatile continuing calibration. Since these compounds were non­detect in all samples, no data were qualified.

C. All compounds were within quality control limit requirements for percent relative standard deviation (%RSD) on the volatile initial calibration.

D. 2,4-dinitrophenol was outside quality control limit requirements for percent relative standard deviation on the base/neutral and acid initial calibration. Since 2,4-dinitrophenol was non-detect in all samples, no data were qualified due to the initial calibration rules.

E. Several compounds including benzo(k)fluoranthene were outside quality control limit requirements for percent difference (%D) (greater than 25%) on jthe .base/neutral .and .acid,continuing calibration. Benzo(k)fluoranthene in samples CS12500J. CSJ.25003, CS125003S, and CS125003W for base/neutral and acid analyses were "J" coded due to the continuing calibration rules.

F. All samples were within quality control limit requirements for retention time windows and percent relative standard deviation on the pesticide/PCB initial calibration.

G. All samples were within quality control limit requirements for analytical sequence and relative percent difference on the pesticide/PCB continuing calibration.

H. Several compounds in samples CS125001, CS125002, CS125001DL, CS125002DL, CS125001S, and CS125001W were not within quality control limit requirements for percent difference between the concentrations between columns (quantitation column within 25% of confirmation column actual range was 100-660%) for pesticide/PCB analysis. 4,4'-DDD in samples CS125001, CS125002, CS125001S, and CS125001W, alpha-chlordane in samples CS125001 and CS125002, and endrin ketone in samples CS125002, CS125001S, and CS125001W were "J" coded due to the extreme differences between columns.

4. GC/ECD INSTRUMENT PERFORMANCE

A. The pesticide/PCB resolution check mixture was within quality control limit requirements.

B. The pesticide/PCB performance evaluation check was within quality control limit requirements for retention time windows, relative percent difference of the performance evaluation mixtures and individual mixes, and percent breakdown of endrin and 4,4'-DOT individually and combined.

5. INTERNAL STANDARD RESPONSE

•

A. The internal standard response areas were within a factor f 2 when comparing samples and their associated continuing alibration response areas for volatile and base/neutral and acid

analyses.

6. PESTICIDE CLEANUP CHECKS

A. The percent recoveries for the florisil cartridge and GPC calibration check were within quality control limit requirements.

7. BLANKS

A. One method blank was analyzed for volatiles with methylene chloride detected above the instrument detection limit (IDL) but less than the contract required quantitation limit (CRQL). Since methylene chloride was non-detect in all samples, no data were qualified due to the blank .rules.

B. One method blank was analyzed for base/neutral and acids with bis(2-ethylhexyl)phthalate detected above the instrument detection limit (IDL) but less than the contract required quantitation limit (CRQL). Since this compound was non-detect in all samples, no data were qualified due to the blank rules.

C. One method blank and five instrument blanks were analyzed for pesticide/PCBs with methoxychlor and dieldrin detected above the instrument detection limit (IDL) but less than the contract required quantitation limit (CRQL). Since these compounds were non-detect or greater than five times the highest level detected in any blank in )all associated samples, no data were qualified due to the blank rules.

8. SURROGATE RECOVERY

A. All surrogates were within quality control limit requirements for percent recovery for the volatile and base/neutral and acid fractions.

B. All surrogates were within quality control limit requirements for percent recovery for the pesticide/PCB fraction except for tetrachloro-m-xylene which had high recoveries in samples CS125001, CS125001S, and CS125001W, low recoveries in samples CS125002DL and CS125003, and was diluted out in sample CS125001DL on the quantitation column and had low recoveries in samples CS125903M and CS125003 and high recoveries in samples CS125001, CS125001DL, CS125001S, CS125001W, and CS125002DL on the confirmation column. Decachlorobiphenyl was diluted out of samples CS125001, CS125001DL, CS125001S, and CS125001W on the quantitation colvimn and CS125001DL on the confirmation column. Decachlorobiphenyl had high percent recoveries in samples CS125001, CS125001S, and CS125001W on the confirmation column. All positive results in samples CS125001, CS125001S, CS125001W, and CS125002DL for pesticide/PCB analyses were "J" coded due to the surrogate rules.

C. The percent difference in retention times for the surrogates were within quality control limit requirements on the quantitation and confirmation colvimns for the pesticide/PCB fraction.

9. MATRIZ SPIKE/MATRIX SPIKE DUPLICATE

A. A matrix spike/matrix spike duplicate was analyzed for the volatiles with the percent recovery and relative percent difference within quality control limit requirements.

B. A matrix spike/matrix spike duplicate was analyzed for base/neutral and acid analyses with the percent recovery high for pyrene in sample CS125003W. The relative percent difference for pyrene was high. No data were qualified due to the matrix .sp ike/matrix £pike -jduplicate rules.

C. A matrix spike/matrix spike duplicate was analyzed for pesticide/PCBs with the percent recovery zero for gamma-BHC, endrin, and 4,4'-DDT in samples CS125001S and CS125001W, dieldrin zero percent recovery in seunple CS125001S, aldrin high percent recovery in samples CS125001S and CS125001W, and dieldrin high percent recoveiry in sample CS125001W. The relative percent difference was ^igh for aldrin and dieldrin. No data were qualified due to the laatrix spike/matrix spike duplicate rules.

10. PERFORMANCE EVALUATION SAMPLE

A. No performance evaluation audit sample was submitted to the laboratory for analysis with this case and SDG.

I 11, COMPOUND IDENTIFICATION and QUANTITATION

A. In a level 2 review, no calculations from raw data (quantitation reports) are performed.

B. Several compounds in several samples for volatile, base/neutral and acid, and pesticide/PCB analyses were detected above the instrument detection limit (IDL) but below the contract required quantitation limit (CRQL). These results were raised to the CRQL and "U" coded.

C. Pyrene in sample CS125003W for base/neutral and acid analysis was detected above the calibration range with no further dilution analyzed, thus, the concentration reported was "J" coded.

D. Aldrin, dieldrin, alpha-chlordane, and gamma-chlordane in Scimple CS125001 and dieldrin, 4,4'-DDT, alpha-chlordane, and gamma-chlordane in sample CS125002 for pesticide/PCB analyses were detected above the calibration range, thus, the concentrations reported were taken from the diluted samples, CS125001DL and CS125002DL, respectively.

. SUMMARY

A. Benzo(k)fluoranthene in four samples for base/neutral and acid analyses were "J" coded due to the continuing calibration rules. 4,4'-DDD in four seunples, alpha-chlordane in two samples, and endrin ketone in three samples for pesticide/PCB analyses were "J" coded due to the extreme differences between columns. All positive results in four samples for pesticide/PCB analyses were "J" coded due to the surrogate rules. Pyrene in one sample for base/neutral and acid analysis was "J" coded due to the fact that it was detected above the calibration range and not reanalyzed. Aldrin, dieldrin, alpha-chlordane, and gamma-chlordane in one sample and dieldrin, 4,4'-DDT, alpha-chlordane, and gamma-chlordane in one sample for pesticide/PCB analyses were reported from the diluted Scimples.

B. This data package generally meets the requirements for precision, accuracy, and .completeness ,as-described dn .SOW for Organic Ajialysis. diated J braiary 4 SJ[) «ith.Jthe exceptions Jioted above.

x ENVIRONMENTAL SERVICES ASSISTANCE TEAM -- ZONE H

ICF KE

ManTech Environmental Technology Inc.

ESAT Reg ion VI I Mantech Env. T e c h . I n c . 25 F u n s t o n Road Kansas C i t y , KS 66115 (913) 551-5000

TO:

THRU:

FROM:

THRU:

DATE: SUBJECT:

L a r r y M a r c h i n / B a r r y Evans Data Review Task M o n i t o r

H a r o l d Brown, Ph .D . ESAT Deputy P r o j e c t O f f i c e r , EPA

Kevin Ludwikosk i ESAT Data Reviewer

Ronald A. Ross ESAT Team Manager

O c t o b e r 9 , 1991 Review of i n o r g a n i c d a t a f o r Dico-Des Moines

TID# 07-9109-016 ASSIGNMENT/ 008 ICF ACCT# 0 4 5 - 0 5 - 0 1 6 - 0 2 ManTech S.0.# 1110-016 ESAT Document No. ESAT-VII-016-5008

These data were reviewed primarily according to the "Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses," July 1988 revision with changes given in the Region VII Inorganic Data Review Training Manual and EPA memorandums.

The following comments and attached data sheets are a result of the ESAT review, according to EPA policies, of the following data from the contract laboratory.

CASE NO.: 17046 SITE: Dico-Des Moines REVIEWER: Kevin Ludwikoski

LABORATORY: WEYER METHOD NO.: CS0788A EPA ACTIVITY NO.: C8125 MATRIX: SOIL

TOTAL METALS (SOIL)

SMO Sample No. EPA Sample No. MGJ127 CS125001 MGJ128 CS125002 MGJ129 CS125003

GENERAL

This data review assignment covers THREE SOIL samples analyzed for TOTAL METALS for case number 17046. There were no PE samples field blanks or field duplicates included with this assignment. This review was performed at level two.

1. Technical Holding Times / Preservation

Technical holding times are not specified for soils.

2. Initial and Continuing Calibration

All percent recoveries were within control limits.

3. Blanks

Several analytes were detected in the blanks. Corresponding sample results were qualified according to the blank rule using five times the highest blank value. Sample results requiring modification are reported as non-detect on the attached data sheets.

TOTAL METALS (SOIL)

5 X Highest Analvte Blank (ma/kg) Qualified Samples

Al 69 Sb 47 Ba 5.4 Be 2.9 Cd 3.7 Ca 150 Co 3.5 Cu 4.1 Mg 520 Mn 3.4 Ni 23 Se 2.1 Na 170 V 3.4 Zn. 16

ICP Interference Check

None qualified CS125002S None qualified None qualified CS125001, -002L None qualified None qualified None qualified None qualified None qualified CS125001, -003 CS125002S None qualified None qualified None qualified

4. _

Recoveries of solution AB analytes were within control limits for Total Metals. Sb, K, and Na were found but not present in the ICS solution. Absolute values for K and Na were below the CRDL; therefore, no data were qualified by the ICP interference check sample. Absolute values for Sb were above the CRDL; however, the associated data were not coded. Since the values for Sb obtained were negative, and the spike recovery was low (20.1%), the possibility of a negative bias exists.

5. Laboratory Control Standard (LCS^

LCS results were within established control limits for Total Metals.

6. Duplicates

The RPD for Ca and Mg were outside control limits for Total Metals. The samples that had data qualified are listed below.

TOTAL METALS (SOIL)

Analvte %RSD Sample No. Code

Ca 44.4 CS125001, -002, -003, -900C J Mg 51.6 CS125001, -002, -003, -900C J

7. Matrix Spike Sample

Spike recoveries were outside established control limits for Sb and Se. The samples that had data qualified are listed below.

Code

I J J

Analvte

Sb

Se

8. ICP

%Rec

20.1

53.7

TOTAL METALS (SOIL)

Sample No.

CS125001, -002, CS125900C CS125001, -900C

Serial Dilution

The ICP serial dilution results for all analytes were within control limits for Total Metals.

9. Furnace Atomic Absorption

"The analytical scheme was followed forTurnace AA analysis for Totai^etals. WSA -correlation coeTficients were acceptable for all analytes of interest.

1 0 . Hi i in inwrY

Four analytes had samples that were qualified by the blank rule, two by the spike rule, and two analytes had samples that were qualified by duplicate precision .

A

ENVIRONMENTAL SERVICES ASSISTANCE TEAM - ZONE H

ICF Technology

ManTech Environmental Technology, Inc.

ESAT Reg ion VII ManTech Env. T e c h . , I n c . 25 F u n s t o n Road Kansas C i t y , KS 66115 (913) 551-5000

TO:

THRU:

FROM:

THRU:

B a r r y Evans Data Review Task M o n i t o r H a r o l d Brown, P h . D . ESAT Deputy P r o j e c t O f f i c e r ,

David J . H ickey % ^ ESAT Da ta Rev iewer Rona ld A. Ross ESAT Team Manager

EPA

DATE: October 28, 1991 SUBJECT: Review of organic data for Dico - Des Moines

TID/ 07-9109-016 ASSIGNMENT/ 020 ICF ACCT/ 05-016-02 NSI S.O./ 1110-016 ESAT Document No. ESAT-VII-016-502 0

These data were reviewed primarily according to the "Laboratory Data Validation Functional Guidelines for Evaluating Organic Analyses," February 1988 revision with changes given in the Region VII Organic Data Review Training Manual and EPA memorandums.

The following comments and attached data sheets are a result of the ESAT review, according to EPA policies, of the following data from the contract laboratory.

CASE NO.: 6711G SITE: Dico - Des Moines REVIEWER: David J. Hickey

LABORATORY: EAS METHOD NO.: CS0288A EPA ACTIVITY NO.: CS125 MATRIX: WIPE

PESTICIDES (WIPE)

SMO Sample No.

6711G-001

EPA Sample No.

CS125005

GENERAL

This data review assignment covers 1 WIPE sample analyzed for Pesticides for SAS ntimber 6711G. There was one method blank and

one instrument blank included with this assignment, but no field blanks, duplicates, or performance samples. The level of review for this package was 2 .

1. Holding Times and Preservation

All samples were analyzed within the specified holding times.

2. Pesticide ins* '"'*** *'- Performance

Surrogate retention time shifts were all within established control limits. Retention times for all compounds were within control limits. % degradation for DDT and Endrin individually were within control limits, but collectively were outside established control limits due to multiple cleanups and reanalysis of the sample. However, this outlier did not result in the qualification of sample results. Linearity was within established control limits. The standards were within the retention time windows.

3. Initial and Continuing Calibration

All compounds except Alpha-BHC, Gamma-BHC, and Methoxychlor were outside %D control limits. If all positive results for samples CS125005 and CS125005S had not already been qualified as a result of improper extraction technique (see Summary), positive values for those samples would have been J-coded for Heptachlor, Dieldrin, Endrin, 4,4'-DDT, Aldrin, Endrin Ketone, Alpha-Chlordane, and Gamma-Chlordane.

4. Blanks

No compounds of interest were detected in the method blank.

5. Surrogate Recovery

All surrogate compound recoveries were within control limits.

6. Matrix Spike Recovery

The Matrix spike was analyzed by the lab using a portion (the cleaner of the two gauze pads) of the original sample. This was a deviation from the SAS which resulted in the analysis of some undeterminable fraction of the original sample. The percent recoveries for the matrix spike were, therefore, well outside established control limits as-the origi-nal sample "was -not -wholly -represented. In xKidi=tlan, a-Form l '=for-the-Matrix splice was not provided in the package, ^o additional positive resuits ^or compounds present in the original sample could not be ascertained. There was no matrix spike duplicate run on this sample.

7. Compound Identification and Quantitation

The field sheets did not indicate the amount of the area that was wiped for this sample. Therefore it was assumed that the area

was 100 cm , with the data reflecting that ass\imption. Due to the requested review level, results listed on the summary forms were used for the review. These results were not checked against the raw data for accuracy, and calculations were not verified. All positive results found below the CRQL were raised to the CRQL according to Regional policy and coded U.

8 . giimiiiMT^

The laboratory was instructed to analyze the wipe sample for RAS Pesticides according to the SAS. The original sample (2 guaze pads) was split to accomodate the analysis of a matrix spike, with the cleaner of the two pads used for the matrix spike. Since the split of the sample was a deviation from the extraction procedure provided in the SAS, all positive values for the original sample were J-coded due to the analysis of some undeterminable portion of the sample. Likewise with the matrix spike, all positive results for compounds other than the spiked compounds would have been J-coded, had a Form 1 been provided. As it was, only spike results were provided for the matrix spike, and those results were invalidated because the spiked sample was not representative of the original sample. %D outliers in the initial and continuing calibrations would have resulted in the J-coding of most positive results, had the extraction procedure been correctly followed. With the exception of collective % degradation of DDT/Endrin, all instrument performance checks were within established control limits. However, this outlier did not result in the qualification of any sample results. The laboratory blank was free of contamination. All other QC was acceptable.

^H:aE: DICO - DES NOINES ISB: EAS SAMPLE PREP: ANA] REVIEW LEVEL: 2

SAMPLES

ALPHA-BHC BETA-BHC DELTA-BHC GAMMA-BHC (LINDANE) HEPTACHLOR ALDRIN HEPTACHLOR EPOXIDE ENDOSULFAN I DIELDRIN 4,4'-DDE ENDRIN ENDOSULFAN II 4,4'-DDD ENDOSULFAN SULFATE 4,4'-DDT ENDRIN KETONE M|^^YCHLOR al^Hr-CHLORDANE gajBa-CHLORDANE TOXAPHENE F 50 U

ANALYSIS TYPE: PESTICIDES a n d PCBs

TRY: DJH

CS125005

2.0 2.0 2.0 2.0 8.5 6.5 2.0 2.0 23

4.0 4.0 4.0 4.0 4.0 4.0 7.5 20 13 15

U U U U J J U U J U U U U U U J J J J

MATRIX:WIPE METHOD: CS02 88A REVIEWER: y^U DATA FILE : D20

UNITS: NG/CM2 CASE: 6711G DATE: 11/05/91

i, k H U

ANALYSIS REQUEST REPORT

FOR ACTIVITY: CS125

I I /0/,/Hl 16:03: 1 7

VALIDATED DATA

ALL REAL SAMPLES AND FIELD Q.C.

» FINAL REPORT

FY: 91 ACTIVITY: C5125 DESCRIPTION: DICO-DES MOINES TCE 0Vn3 LOCATION: DES MOINES

STATUS: ACTIVE TYPE: SAMPLING - CONTRACT LAB ANALYSIS PROJECT;

LABO DUE DATE IS 11/ 4/91. REPORT DUE DATE IS 11/18/91.

INSPECTION DATE: 9/ 4/91 ALL SAMPLES RECEIVED DATf 09/05/91

ALL DATA APPROVED BY LABO DATE: 11/01/91 FINAL REPORT TRANSMITTED DATE: 11/07/91

EXPECTED LABO TURNAROUND TIME IS 60 DAYS EXPECTED REPORT TURNAROUND TIME IS 75 DAYS

ACTUAL LABO TUKtJAROUtviD TIME IS 57 DAYS AL I UAL KhPUKI "I UKNAROUND TIME IS 64 DAYS

SITE CODE; SITE. UNKUOWN SITE

IOWA

A33

SAMP. NO. OCC M

()0> 002 003 005

npsCRIPTIOM SAMPLE n ST. .TUS

AIRS/ STORET LOC NO

LAY-1 E R

[l|,M-ll^^<< Minir.jcc Tfp_cp_c.;^, ..-/.f_.f.. c - .. |_ v n- •'. j.;..: :,•; •: DICO-DES MOINES icE-SB-47 SAMPLE LOCAL 1 DES MOINES DICO-DES MOINES TCE-SOIL SAMPLE 1 DES MOINES DICO-DES MOINES irt 0U«3-WIPE SAMPLE 1 DES MOINES

BEG. DATE

IOWA IOWA T n*''" i U H M

08/27/91 08/28/91 09/04/91

BEG. TTME

ib 16 10 ) 1

END. DA 11

45 0&/27/&1 24 08/27/91 13 08/28/91 15 09/04/91

END. TIME

IC: 16; 10: 11 :

00 28 19 20

EXPLANATION OF CODES AND INFORMATION ON ANALYSIS REQUEST DETAIL REPORT

SAMPLE INFORMATION:

SAMP. NO.

QCC

SAMPLE IDENTIFICATION NUMBER (A 3-DIGIT NUMBER WHICH IN COMBINATION WITH THE ACTIVITY NUMBER AND QCC, PROVIDES AN UNIQUE NUMBER FOR EACH SAMPLE FOR IDENTIFICATION PURPOSES) QUALITY lOlviTRrii I'.iinF I A riMt--i t - n I-k i riiii- ncn-, -i r. DESlCiJATL S p e c i f i c QC SAIviPLE.:.. i n i v f l t i . L i WILL BF BLANK FOR ALL NON-QC OR ACTUAL SAMPLES): A B C D F G H K

TRUE VALUE FOR CALIBRATION STANDARD LUNLtNlRATlON RESULTING FROM DUPLICATE LAB SPIKE MEASURED VALUE FOR CALIBRATION STANDARD

FOR FILED DUPLICATE FOR FIELD BLANK FOR METHOD STANDARD METHOD STANDARD

RESULTING FROM DUPLICATE FIELD

MEASURED VALUE MEASURED VALUE MEASURED VALUE TRUE VALUE FOR CONCENTRATION

L M N P R S T W Y

SPIKE MEASURED MEASURED MEASURED MEASURED

VALUE FOR LAB DUPLICATE VALUE FOR LAB BLANK VALUE FOR DUPLICATE FIELD SPIKE VALUE FOR PERFORMANCE STANDARD

CONCENTRATION RESULTING FROM LAB SPIKE MEASURED VALUE FOR LAB SPIKE TRUE VALUE OF PERFORMAwrE STANDARD MEASURED VALUE FOR DUf'LiLAiii LAB S P I K L MEASURED VALUE FOR FIELD SPIKE

2 = COrJCENTRATION RESULTING rROIvi FIELD SPikt MEDIA CODE (A ONE-LETTER CODE DESIGNATING THE MEDIA OF THE SAMPLE): A H S T W

AIR OTHER (DOES NOT FIT ANY OTHER CATEGORY) SOLID (SOIL. SEDIMENT. SLUDGE) TTSSIIF (PLAMT %. ANIMAL) WATER (GROLiUD WATER.. '.iiRFAiF WATFH; \Ka\\v WA 11-R- DR.'f-J. INO U'ATFF.':

DESCRIPTION = A SH O R T ' O E S C R I P T I O N OF THE LOCATION WHERE SAMPLE WAS COLLECTED

AIRS/STORET LOC. NO.

DATE/TIME INFORMATION

THE SPECIFIC LOCATION IDENTIFICATION NUMBER rOR EITHER OF THESE IviATIONAL DATABASE SYSTEMS. AS APPROPRIATE = SPECIFIC INFORMATION REGARDING WHEN THE SAMPLE WAS COLLECTED RfC DATE = DATE SAMPL!^.'G WA'-". ST/.P.TFD BEG. -JME = TIME = AMr-. ' li- -:•• • :..: •';: P M H r \ r . \ r - — r f. T r. •"//*"•' '''; ' " ^ . ' ' . ' ~ ' . ' " . ' ; ~ ' ^

E N D Til'Vir = i Mvi'" -.i;l'/ 'f ' M ' - wr,-- l i .|.l.; . L : :_ ; •. NOTE: A GRAB SAMPLF WILL r-MT,MK, .-.|.i. ,

BEG. DATE/TIME A TIMrfj :'OWr-ri', ; I F •i.;-!yi:'LL V;.ii CONTAIN BOTH BEG AND END TO DESIGNATE DURATION OF COLLECTION

ANALYTICAL RESULTS/MEASUREMENTS INFORMATION:

COMPOUND = MGP (MEDIA-GROUP-PARAMETER) CODE AND NAME OF THE MEASURED CONSTITUENT OR CHARACTERISTIC OF EACH SAMPLE

UNITS - SPECIF li-^UNnTS^iM^WHICH RESULTS ARE RETORTED;

CFS = CUBIC'TE'E'T PER''SECOND"'" ' GPM -•= GALLONS PER MINUTE TN =- INCHES I D . = SPECIES IDENTIFICATION KG = KILOGRAM L = LITER LB = POUNDS MG = MILLIGRAMS (1 X 10-3 GRAMS) MGD = MILLION GALLONS PER DAY MPH = MILES PER HOUR MV = MILLIVOLT M/F = MALE/FEMALE M2 - SQUARE METER M3 = CUBIC METER NA = NOT APPLICABLE NG = NANOGRAMS (1 % 10-9 GRAMS) NTU = NEPHELOMETRIC- TURBIDITY UNITS Pr /L ^ r i m ( l X 10 -1? i ' ^ M P R I E - PER LITER Pb = PICOGRAMS (1 X 10-12 GRAMS) P/CM2 = PICOGRAMS PER SQUARE CENiTIMFTFR SCM = STANDARD CUBIC METER (1 ATM, 25 C) SO FT = SQUARE FEET SU = STANDARD UNITS (PH) UG = MICROGRAMS ( I X 10-6 GRAMS) UMHOS = MICROMHOS/CM (CONDUCTIVITY UNITS) U/CC2 = MICROGRAMS PER 100 SQUARE

CENTIMETERS I "'•r.':- - r.'!;;-PC-IP AM:. rfR ?Q;iAPE CEiiTIMCTER iOOOb - I UOO GALLOWS

POSITIVE/NEGATIVE NUMBER

SPECIFIC CODES USFD TM CON.iUMCIiON WITH DATA VALUES TO PROVIDE ADDITIONAL INFORMATION ON THE REPORTED RESULTS. OR USED TO EXPLAIN THE ABSENCE OF A SPCIFIC VALUE:

+ / u

DATA QUALIFIERS

REMARKS OR !-0R FINAL

T l i ^ T Tt-if /\ ^ I n p o 11M n

T REPORTED APPROVED

DATE/TIME SAMPLE

BLANK = IF FIELD IS BLANK. NO OuALTFiFR^ ARF PFPM^lE^l "• •; r-:: i: T i L: Z i -A r . IKil. Mi^AI^:, ,.-u! iil-' H U M P bj-f-"-.! '-'E " i t'Wt IT' \ Z B L A C C E P T A B L E FOR u.SE

.] = DAtA'RFPORTFn'BnT'l-jni \m. \ 'b nv o: f-RO..LL;L;r:L;

K = ACTUAL VALUE OF SAMPLE IS < VALUE REPORTED L = ACTUAL VALUE OF SAMPLE IS > VALUE REPORTED M = DETECTED BUT BELOW THE LEVEL OF REPORTED

VALUE FOR ACCURATE QUANTIFICATION 0 = PARAMETER NOT ANALYZED U = ACTUAL VALUE OF SAMPLE IS < THE

MEASUREMENT DETECTION LIMIT (REPORTED VALUE)

ANALYSIS REQUEST DETAIL REPORT ACTIVITY; 1-CS125

COMPOUND UNITS 001 002 003

VALIDATED DATA

005

SMOl SILVER. TOTAL. BY ICAP

SM02 ALUMINUM. TOTAL. BY ICAP

SM03 ARSENIC. TOTAL. BY ICAP

SM04 BARIUM, TOTAL, BY ICAP

SM05 BERYLLIUM, TOTAL, BY ICAP

SM06 CADMIUM. TOTAL. BY ICAP

SM07 COBALT. TOTAL. BY ICAP

SMOB CHROMIUM. TOTAL, BY ICAP

SM09 COPPER. TOTAL. BY ICAP

SMIO IRON. TOTAL. BY ICAP

SMll MANGANESE, TOTAL BY ICAP

SMI2 MOLYBDENUM TOTAL. BY ICAP

SM13 NICKEL.TOTAL BY ICAP

SMI4 LEAD. TOTAL. BY ICAP

SMI 5 ANTIMONY. TOTAL. BY ICAP

SM16 SELENIUM BY ICAP

SMI 7 TITANIUM. TOTAL BY ICAP

SM18 THALLIUM. TOTAL BY ICAP

SM19 VANADIUM. TOTAL BY ICAP

SN'!20 ." INC. TOTAL BV ICAP

Sr.'21 C A L C I U W . TOTAL. o\ iCAP

SM22 MAuNtSIUM. 101AL. BY ICAP

SM23 SODIUM.TOTAL, BY ICAP

SM24 POTASSIUM. TOTAL BY ICAP

SM34 MERCURY, TOTAL,BY COLD VAPOR AA

SP01 BHC, ALPHA. BY GC/EC

WI, /h i; • V o 11

MG/KGi4S00

MG/KGi5.3

MG/KG:81

MG/KG:1.1

MG/KG:1.9

MG/KG:11

U

U

U

MG/KG:15

MG/KG-21

Mb'KG- 15000

MG/KG-570

MG/KG:N/A

MG/KG!16

0

U

MG/KG;73

M i , / K l , M / 11

MG/KG!2.2

MG/KG:N/A

MG/KG!2.2

MG/KGi25

M C '1 ',• i:i-:-

l.,,;|, / ( 1, • V •-|-_.L"-_.

MG/KC- : ooo

MG/KG:1100

MG/KG:1100

MG/KG!0.11

UG/KG:38

J

0

u

1

u

1.1

u

u

>•> 1 -

7000

6. 1

130

1 . 1

1 . 1

11

U

U

u 21

29

1 -000

560

N/A 0

25

59

1 . 1

N/A

2. 1

T

u

0

u

20

?90C'

1 100

1 100

2 . - : •; !

1 3000

6.4

150

1.2

1 .2

12

U :

U ! •

U ':

19

18 :

23000

330

N/A

16

0 :

U :

25 :

M / A

1 .2

N/A

2.4

T

U ':

0 ':

U :

34

J 6200

U

U

0. 10

2.9 u

1200

'.1

J [

U :

1400

0. 12

2. 1

U ':

U :

COMPOUND

ANALYSIS REQUEST DETAIL REPORT

UNITS 001

ACTIVITY; 1-CS125

r,t:; ' l y

002 003

VALIDATED DATA

005

SP02 DHC. BETA. BV bC/Ei.

SP03 BHC. DELTA

SP04 GAMMA-BHCa INDANE)

SP05 ALDRIN, BY GC/EC

SP06 DIELDRIN, BY GC/EC

SP07 ENDOSULFAN I, BY GC/EC

SP08 ENDOSULFAN 11. BY GC/EC

SP09 ENDOSULFAN SULFATE, BY GC/EC

SP10 ENDRIN. BY GC/EC

Spn ENDRIN ALDEHYDE. BV GC/EC

SP13 4,4'-DDE

SP14 4.4'-DDD

SP15 4,4'-DDT

SP16 TOXAPHENE, BV GC/EC

SP17 PCB-ARACIILCR 1C1C

SP18 PCB-ARACHLOR 1221

SP19 PCB-ARACHLOR 1232

SP20 PCB-ARACHLOR 1242

SP21 PCB-ARACHLOR 1248

SP22 PCB-ARACHLOR 125-i

SP20 PCB-AKACHuOK 1250

SP24 CHLORDANE. TECHNICAL. BY GC/EC

SP25 HEPTACHLOR.BY GC/EC

SP26 HEPTACHLOR EPOXIDE.BY GC/EC

SP36 CHLORDANE,GAMMA

SP37 PCB-1016 WIPE

I I I ; / ^ i :

UG/K.G

UG/Kb

UG/KG

UG/KG

UG/KG

UG/KG

UG/KG

UG/KG

UG/KG

UG/KG

UG/KG

UG/KG

UG/KG

i i l l / r . i .

UG/KG

UG/KG

UG/KG

UG/KG

•.•;.. • • :•.

1 11 - / I. : .

UG/KG

UG/KC

UG/KG

UG/KG

PGCM2

U i .

38

38

"

U

u 540

5800

38

73

73

73

73

u u u u II

73 1.1

95

73

3800

T.-sfi

1500

730

730

730

W/A

70

38

J

u u 11

u

u u u

fl (~)

2.9

2.9

V

u u

19

230

2.9

5.6

5.6

5.6

5 6

5.6

31

72

290

110

56

56

56

: 1

0

J

u 1200

N/''>

13

J

u u u u u u J

J

u 11

u

u u u

u

Cl

23

160 J

o 1

2. 1

2. 1

2. 1

4.0

2. 1

4.0

4 0

4.0

'1.0

4.0

4.0

4.0

210

10

81

40

40

40

• ' • • ' -

f-J -• A

2. 1

2 1

2. 1

U

U

u •

U :

U

U

U

U

u u u u u

u u u u c

0

u u u

— • - - -

50Q00 U

ANALYSIS REQUEST DETAIL REPORT ACTIVITY: 1-CS125 VALIDATED DATA

COMPOUND UNITS 001 002 003 005

SP3& PCD-1221 A'IPE

SP39 PCB-1232 WIPE

SP40 PCB-1242 WIPE

SP41 PCB-1248 WIPE

SP42 PCB-1254 WIPE

SP43 PCB-1260 WIPE

SP60 METHOXYCHLOR. BY GC/EC

SP61 ENDRIN KETONE, BY GC/EC

SQ29 ALPHA-CHLORDANE

SS01 PHENOL. BY GC/MS

SS02 CARBAZOLE

SS03 ETHER, BIS(2-CHL0R0ETHYL), BY GC/MS

SS04 2-CHLOROPHENOL

SS05 1,3-DICHLOROBENZENE

5506 1 ,-1-DICHLOROBCNZENC

5507 BENZYL ALCOHOL

5S08 1.2-DICHLOROBFNZENE

SS09 2-METHYLPHENOL (O-CRESOL)

SS10 WTHER, BIS(2-CHL0R0IS0rR0rYL). BV GC/MS

SSI 1 4~METHVLPHEtOOL • •''-•: P.r'Oi. •

S S 1 2 I'J I'VJI Ti\C'SO~G I r RLIP 1 L iVi 1 i-.it . rS <• i.ii • ivi.--

SS14 NITROBENZENE. BY GC/MS

SSI 5 ISOPHORONE, BY GC/MS

SS16 2-NITROPHENOL

SSI 7 2,4-OIMETHyLPHENOL

PGCM2

PGi.;M2

PGCM2

PGCM2

PGCM2

UG/KG

UG/KG

UG/KG

Ub/f-li

UG/KG

UG/KG

UG/KG

UG/KG

ilt--> / K 1-1

UG/KG

UG/KG

UG/KG

UG/KG

ur.-,/KC,

UO/t,G

UG/KG

UG/KG

UG/KG

380

260

830

350

350

350

350

350

N/A

350

350

3. )0

350

350

350

350

350

U

J

J

I.l

U

u u u

0

u u u

1 ••

1.1

u

u u u

29

25

100

?70

370

370

370

370

N/A

370

370

370

'J. -7 r\

370

370

370

370

370

U

J

J

U

u u u u

0

u u u

u

ll

u

u u u

21

4 0

2. 1

U

U

U

-100 . I!

400

400

400

400

N/A

400

400

400

•iOC-

'100

400

400

400

400

U

U

u u 11

0

u Ll

U

50000 U

50000 U

50000 U

50000 U

5Q000 U

u

u

U

U

u u u

COMPOUND

ANALYSIS REQUEST DETAIL REPORT

UNITS 001

ACTIVITY: 1-CS125

002 003

VALIDATED DATA

005

SSIS BENZOIC ACiO. BV bi.'MS

SS19 METHANE. Bl S( 2-i.:HL0R0ETHY0XY ) . BY GC/MS

5:.20 2. 4-D 1 CHLOROPHENOL

SS21 1,2,4-TRICHLOROBENZENE

SS22 NAPHTHALENE,BY GC/MS

SS23 4-CHLOROANILINE

SS24 HEXACHLOROBUTADIENE,BY GC/MS

SS25 4-CHL0R0-3-METHYLPHEN0L

SS26 2-METHYLNAPHTHALENE

SS27 HEXACHLOROCVCLOPENTADJENE .BY GL.'MS

SS28 2,4,6-TRICHLOROPHENOL

SS29 2,4.5-TRICHLOROPHENOL

SS30 2-CHLORONAPHTHALENE

SS31 2-NITROANILINE

SS32 PHTHALATE. DIMETHYL. BV GC/MS

SS33 ACENAPHTHYLENE, BY G L / M S

SS34 3-NITROANILINE

SS35 ACENAPHTHENE. BY GC/MS

SS36 2,4-DINITROPHENOL

f , . ^ p^Tpp..^..^,-.,.-..,.

SS40 2,6-DINITROTOLUENE

SS41 PHTHALATE, DIETHYL. BY GC/MS

SS42 4-CHLOROPHENYL PHENYL ETHER

SS43 FLUORENE,GC/MS

n f; 1 v . W

UG/KG

uc;,/Kb

UG/KG

UG/KG

UG/KG

UG/KG

UG/KG

UG/KG

Ub/H b

UG/Kb

UG/KG

UG/KG

UG/KG

1 i\\ /Ml

UG/KG

UG/KG

UG/KG

UG/KG

: . • 1

IK.i/KO

UG/KC

UG/KG

UG/KG

UG/KG

M / A

350

350

350

350

350

350

350

350

350

350

860

350

860

.A'--.0

350

860

350

S60

350

350

350

350

350

U

u u u u u u u I.l

u u u u II

u u u u

Ll

u

u u u

111 / ^

370

370

370

370

370

370

370

370

7.70

370

900

370

900

-J-/.71

370

900

370

900

^x:.r.

d'.'Q

570

370

370

370

r-,

U

U

u u u u u u U

u u u u 11

u u u u 1.:

u

Ll

u

U

u u

400

400

400

400

400

400

400

400

'100

400

960

400

960

••^r'^0

400

960

400

950

-.,-..-.

•500

400

400

400

400

400

u u u u u u u u u u u u u u u u u u u u

u

u

u u u

ANALYSIS REQUEST DETAIL REPORT ACTIVITY; 1-CS125

COMPOUND UNITS 001 002 003

VALIDATED DATA

005

SS-T--1 4-NI TROANI LINF

SS45 4.6-DINITRO-2-METHYLPHENOL

SS'lD N-NITROSODIPHENVLAMINL .BY GC/MS

SS47 4-BROMOPHENYL PHENYL ETHER

SS48 HEXACHLOROBENZENE.BY GC/MS

SS49 PENTACHLOROPHENOL. BY GC/MS

SS50 PHENANTHRENE, BY GC/MS

SS51 ANTHRACENE, BY GC/MS

SS52 PHTHALATE. DI-N-BUTYL-. BY GC/MS

SS53 FLUORANTHENE.BY GC/MS

SS54 PYRENE. BY GC/MS

SS55 PHTHALATE, BUTYL BENZYL

SS56 3,3'-DICHL0R0BENZIDINE

SS57 ANTRACENE, BENZO(A). BV GC/MS

SS58 PHTHALATE, BIS(2 CTHVLHCXVL i. BV CC/MS

S559 CHRYSENE, BV GC/MS

SS60 PHTHALATE. DI-N-OLTYL-. BY GC/MS

SS61 FLUORANTHENE. BENZO(B), BY GC/MS

SS62 FLUORANTHENE, SENZO(KJ, BV GC/MS

S .e3 PYRFMF PEN".'. .1 •• r,'.- ...i/-.

5504 IiJOENO-' '< . 2 . 5-CO iP i P.FkF

5505 ANiHkAbLNt. UlbtNZuiA.Hi. BY bf./MS

SS66 PERYLENE. BENZOcG.H.I;. BV GC/MS

SV03 CHLOROMETHANE. BY GC/MS

SV04 BROMOMETHANE, BY GC/MS

SV05 VINYL CHLORIDE,BY GC/MS

HI; /K i; • ui^r\

UG/KGi860

UG/Kb:350

UG/KG:350

UG/KG:350

UG/KGi860

u !

u !

u !

u !

u !

UG/KG!790

UG/KG:350

UG/KG!350

u u

UG/Kb-2000

UG/KG!1700

UG/KG-350

UG/KG!350

u u

UG/KG!1200

iiCi/Mi • ^50 "

UG/KG!1200

UG/KG!350 u U G / K G ! 8 7 0

UG/KG!1400

•• , 1. • -! ^ y i

UG/KG:350

UC/KG.720

UG/KG!11

UG/KG!11

UG/KG!1 1

11

u u' u

r.t~\r-\

900

370

370

370

900

370

370

370

u •

u u •

U

U

u u u

4C0

370

370

370

370

370

370

370

370

' . j - ! r ^

370

570

1 1

1 1

11

u u u u u u u u u

u

u

u

u u u

l ^ f l - \ _ • - ^ ^

960

400

400

400

960

u

u

u u u u

440

400

400

u u

1300

1 100

400

400

u u

600

/inn u 650

400

400

860

400

100

400

12

12

! 12

u u J

u

u

. u

u u u

..-.:

ANALYSIS REQUEST DETAIL REPORT ACTIVITY: 1-CS125

COMPOUND UNITS 001 002 003

VALIDATED DATA

005

SV06 CHLOROETHANE. BV bC/lviS

SV07 METHYLENE CHLORIDE(DICHLOROMETHANE )

SV08 1,1-DICHLOROETHVLLNh

SV09 1,1-DICHLOROETHANE

SV10 TRANS-1,2-DICHLOROETHYLENE

SV11 CHLOROFORM, BY GC/MS

SV12 1.2-DICHLOROETHANE

SV13 1,1.1-TRICHLOROETHANE

SV14 CARBON TETRACHLORIDE. BY GC/MS

SV15 BROMODICHLOROMETHANE. BV GC/MS

SV16 1,2-DICHLOROPROPANE

SV17 BENZENE, BY GC/MS

SV18 TRANS-1,3-DICHLOROPROPENE

SV19 TRICHLORGETHVLENE, BY GC/MS

SV20 DICHLOROPROPENE. CIS-1.3-. BV GC/MS

SV21 DIBROMOCHLOROMETHANE. BY GC/MS

SV22 1.1.2-TRICHLOROETHANE

SV24 BROMOFORM. BY GC/MS

SV25 1,1.2.2-TETRACHLOROETHENE

SV26 TOLUENE. BV CC/MS

SV27 1 . 1 . 2 . 2-TLTRACnLOP.OETnMliiF

SV29 ETHYL BENZENE,BY GC/MS

SV30 ACETONE, BY GC/MS

SV31 CARBON DISULFIDE. BY GC/MS

SV32 2-BUTANONE

111; / k r; • i i

UG/KG!11

Ub/Kb-11

UG/KG!11

UG/KG!N/A

UG/KG!11

UG/KG!11

UG/KG!n

UG/KG!11

I.Kj.'Kb! 1 1

UG/KG!11

UG/KG!n

UG/KG!11

UG/KG!11

1111 / K 11 i 1

UG/KG:11

UG/KG!11

UG/KG!11

UG/KG!11

1 1 1 . - > ' • ' '

UG/KG:11

UG/KG:11

UG/KG!11

UG/KG!11

UG/KG!11

-

u u u 0

u u u. u II

u u u u II

u

u u u

I.l

u

u Ll

u

1 1

n 11

11

N/A

11

11

11

11

11

11

11

11

11

11

11

11

11

11

11

11

11

11

• " " M

u u u 0

u u u u !l

. . U

u u u

u u u I.l

11

u

u u u

^ r-i

12

12

12

N/A

12

12

12

12

1?

12

12

12

12

12

12

12

12

• 1

12

12

12

12

.12

._ . _.

u !

u !

u !

0 !

u ! u !

u !

u !

u -

u !

u •

u !

u !

u !

u !

u !

u !

L' !

u •

u !

u !

U :

u !

COMPOUND

ANALYSIS REQUEST DETAIL REPORT ACTIVITY: 1-CS125

UNITS 001 002 003

VALIDATED DATA

005

SV33 VINVL ACETATE.BV GC/MS

SV34 2-HEXANONE

SV35 4-METHVL-2-PENTAN0Nh

SV36 STYRENE, BY GC/MS

SV37 XYLENES, TOTALBY GC/MS

ZZOl SAMPLE NUMBER

ZZ02 ACTIVITY CODE

HI; /I- (;

UG/KG

Ub/K(.i

UG/KG

UG/KG

NA

NA

M / A

1 1

1 1

1 1

11

,-,

u u u u

001

CS125

M / A

1 1

1 1

11

1 1

r-l.

u u u u

002

CS125

:;.',-.

12

12

12

12

c u u u u

003

CS125

005

CS125

ACTIVITY CS125 DICO-DES MOINES TCE 0U#3

THE PROJECT LEADER SHOULD CIRCLE ONE - STORET. AIRS. OR ARCHIVE.

CIRCLE ONE: STORET AIRS ARCHIVE

DATA APPROVED BY LABO FOR TRANSMISSION TO PROJECT LEADER ON 11/06/91 15:07:47 BV ^