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07/05/2015 RabicycleWikipedia,thefreeencyclopedia
http://en.wikipedia.org/wiki/Rabi_cycle 1/4
RabicycleFromWikipedia,thefreeencyclopedia
Agreatvarietyofphysicalprocessesbelongingtotheareasofquantumcomputing,condensedmatter,atomicandmolecularphysics,andnuclearandparticlephysicscanbeconvenientlystudiedintermsoftwolevelquantummechanicalsystems.Inthiscase,oneoftheeffectsisrepresentedbytheoscillationsbetweenthetwoenergylevels,asforexample,electronneutrinoemuonneutrinoflavourneutrinooscillations.Inphysics,theRabicycleisthecyclicbehaviourofatwostatequantumsysteminthepresenceofanoscillatorydrivingfield.Atwostatesystemhastwopossiblestates,andiftheyarenotdegenerate(i.e.equalenergy),thesystemcanbecome"excited"whenitabsorbsaquantumofenergy.
Theeffectisimportantinquantumoptics,nuclearmagneticresonanceandquantumcomputing.ThetermisnamedinhonourofIsidorIsaacRabi.
Whenanatom(orsomeothertwolevelsystem)isilluminatedbyacoherentbeamofphotons,itwillcyclicallyabsorbphotonsandreemitthembystimulatedemission.OnesuchcycleiscalledaRabicycleandtheinverseofitsdurationtheRabifrequencyofthephotonbeam.
Thismechanismisfundamentaltoquantumoptics.ItcanbemodeledusingtheJaynesCummingsmodelandtheBlochvectorformalism.
Forexample,foratwostateatom(anatominwhichanelectroncaneitherbeintheexcitedorgroundstate)inanelectromagneticfieldwithfrequencytunedtotheexcitationenergy,theprobabilityoffindingtheatomintheexcitedstateisfoundfromtheBlochequationstobe:
,
where istheRabifrequency.
Moregenerally,onecanconsiderasystemwherethetwolevelsunderconsiderationarenotenergyeigenstates.Thereforeifthesystemisinitializedinoneoftheselevels,timeevolutionwillmakethepopulationofeachofthelevelsoscillatewithsomecharacteristicfrequency,whoseangularfrequency[1]isalsoknownastheRabifrequency.ThestateofatwostatequantumsystemcanberepresentedasvectorsofatwodimensionalcomplexHilbertspace,whichmeanseverystatevector isrepresentedbytwocomplexcoordinates.
where and arethecoordinates.[2]
Ifthevectorsarenormalized, and arerelatedby .Thebasisvectorswillberepresentedas and
Allobservablephysicalquantitiesassociatedwiththissystemsare2 2Hermitianmatrices,whichmeanstheHamiltonianofthesystemisalsoasimilarmatrix.
Contents
1Howtoprepareanoscillationexperimentinaquantumsystem2DerivationofRabiFormulainanNonperturbativeProcedurebymeansofthePaulimatrices3RabioscillationinQuantumcomputing4RabioscillationinAmmoniamaser5Seealso6References7Externallinks
Howtoprepareanoscillationexperimentinaquantumsystem
Onecanconstructanoscillationexperimentconsistingoffollowingsteps:[3]
(1)Preparethesysteminafixedstatesay
(2)Letthestateevolvefreely,underaHamiltonianHfortimet
(3)FindtheprobabilityP(t),thatthestateisin
If wasaneigenstateofH,P(t)=1andtherearenooscillations.Alsoiftwostatesaredegenerate,everystateincluding isaneigenstateofH.Asaresulttherearenooscillations.SoifHhasnodegenerateeigenstates,neitherofwhichis ,thentherewillbeoscillations.TheseprobabilitiesofoscillationsaregivenbyRabiFormula.OscillationsbetweentwolevelsarecalledRabioscillation.ThemostgeneralformoftheHamiltonianofatwostatesystemisgiven
here, and arerealnumbers.Thismatrixcanbedecomposedas,
Thematrix isthe2 2identitymatrixandthematrices arethePaulimatrices.Thisdecompositionsimplifiestheanalysisofthesystemespeciallyinthetimeindependentcasewherethevaluesof and areconstants.Considerthecaseofaspin1/2particleinamagneticfield .TheinteractionHamiltonianforthissystemis
.Where
07/05/2015 RabicycleWikipedia,thefreeencyclopedia
http://en.wikipedia.org/wiki/Rabi_cycle 2/4
where isthemagnitudeoftheparticle'smagneticmoment, isGyromagneticratioand isthevectorofPaulimatrices.HereeigenstatesofHamiltonianareeigenstatesof thatis and .Theprobabilitythatasysteminthestate willbefoundtobeinthearbitrarystate isgivenby .Letsystem
initially isinstate thatiseigenstateof , .Thatis .HereHamiltonianistimeindependent.
SobysolvingtimeindependentSchrdingerequation,wegetstateaftertimetisgivenby ,whereEisthetotalenergyofsystem.Sothestate
aftertimetisgivenby .Nowsupposespinismeasuredinthexdirectionattimet,theprobabilityoffindingspinupis
givenby where isacharacteristicangularfrequencygivenby
whereithasbeenassumedthat .[4]SointhiscaseprobabilityoffindingspinupstateinXdirectionisoscillatoryintimetwhen
systemisinitiallyinZdirection.SimilarlyifwemeasurespininZdirectionthenprobabilityoffinding ofthesystemis .Inthecase ,thatiswhenthe
Hamiltonianisdegeneratethereisnooscillation.SowecanconcludethatiftheeigenstateofanabovegivenHamiltonianrepresentsthestateofasystem,thenprobabilityofthesystembeingthatstateisnotoscillatory,butifwefindprobabilityoffindingthesysteminotherstate,itisoscillatory.Thisistrueforeventime
dependentHamiltonian.Forexample ,theprobabilitythatameasurementofsysteminYdirectionattimetresultsin is
,whereinitialstateisin .[5]
ExampleofRabiOscillationbetweentwostatesinionizedhydrogenmolecule.Ionizedhydrogenmoleculeiscomposedoftwoproton and andoneelectron.Thetwoprotonsbecauseoftheirlargemassescanbeconsideredtobefixed.LetuscallRbethedistancebetweenthemand and thestateswheretheelectronislocalisedaround or
.Assume,atacertaintime,theelectronislocalisedaboutproton .AccordingtotheresultsofprevioussectionweknowitwilloscillatebetweenthetwoprotonswithafrequencyequaltotheBohrfrequencyassociatedwithtwostationarystate and ofmolecule.
Thisoscillationoftheelectronbetweenthetwostatescorrespondstoanoscillationofthemeanvalueoftheelectricdipolemomentofthemolecule.Thuswhenthemoleculeisnotinastationarystate,anoscillatingelectricdipolemomentcanappear.Suchanoscillatingdipolemomentcanexchangeenergywithanelectromagneticwaveofsamefrequency.Consequently,thisfrequencymustappearintheabsorptionandemissionspectrumofIonizedhydrogenmolecule.
DerivationofRabiFormulainanNonperturbativeProcedurebymeansofthePaulimatrices
LetusconsideraHamiltonianintheform .
Theeigenvaluesofthismatrixaregivenby and
.Where and .sowecantake
.
Noweigenvectorfor canbefoundfromequation: .
So .
Usingnormalisationconditionofeigenvector,
.So .
Let and .so .
Soweget .Thatis .Takingarbitraryphaseangle ,wecanwrite .Similarly
.
Soeigenvectorfor eigenvalueisgivenby .
Asoverallphaseisimmaterialsowecanwrite .
Similarlywecanfindeigenvectorfor valueandweget .
Fromthesetwoequations,wecanwrite and .
07/05/2015 RabicycleWikipedia,thefreeencyclopedia
http://en.wikipedia.org/wiki/Rabi_cycle 3/4
Letattimet=0,systembein ThatIs .
Stateofsystemaftertimetisgivenby .
Nowasystemisinoneoftheeigenstates or ,itwillremainthesamestate,howeverinageneralstateasshownabovethetimeevolutionisnontrivial.
Theprobabilityamplitudeoffindingthesystemattimetinthestate isgivenby .
Nowtheprobabilitythatasysteminthestate willbefoundtobeinthearbitrarystate isgivenby
Bysimplifying .........(1).
Thisshowsthatthereisafiniteprobabilityoffindingthesysteminstate whenthesystemisoriginallyinthestate .Theprobabilityisoscillatorywithangular
frequency ,whichissimplyuniqueBohrfrequencyofthesystemandalsocalledRabifrequency.Theformula(1)isknownas
Rabiformula.Nowaftertimettheprobabilitythatthesysteminstate isgivenby ,whichisalso
oscillatory.ThistypeofoscillationsbetweentwolevelsarecalledRabioscillationandseeninmanyproblemssuchasNeutrinooscillation,ionizedHydrogenmolecule,Quantumcomputing,Ammoniamaseretc.
RabioscillationinQuantumcomputing
Anytwostatesystemiscalledqubit.LetaSpinhalfsystembeplacedinaclassicalmagneticfieldwithperiodiccomponentsuchas.TheHamiltonianofsystem(proton)ofmagneticmoment infield isgiven
,where andb , isgyromagneticratioofproton.Onecanfind
eigenvalueandeigenvectoroftheHamiltonianbyabovementionedprocedure.Letattimet=0thequbitisinthestate ,attimetitwillhaveaprobability
ofbeingfoundinstate givenby where .ThisisthephenomenonofRabioscillation.Theoscilltion
betweenthelevels and hasmaximumamplitudefor thatisatresonance.So .Togofromstate tostate itissufficientto
adjustthetimetduringwhichtherotatingfieldactssuchas or .Thisiscalleda pulse.Ifatimeintermediatebetween0and ischosen,we
obtainasuperpositionof and .Inparticular ,wehavea pulse: .Thisoperationhascrucialimportanceinquantumcomputing.
Theequationsareessentiallyidenticalinthecaseofatwolevelatominthefieldofalaserwhenthegenerallywellsatisfiedrotatingwaveapproximationismade.Thenistheenergydifferencebetweenthetwoatomiclevels, isthefrequencyoflaserwaveandRabifrequency isproportionaltotheproductofthetransition
electricdipolemomentofatom andelectricfield ofthelaserwavethatis .Insummary,Rabioscillationsarethebasicprocessusedtomanipulate
qubits.Theseoscillationsareobtainedbyexposingqubitstoperiodicelectricormagneticfieldsduringsuitablyadjustedtimeintervals.[6]
RabioscillationinAmmoniamaser
Inmolecularphysics,awellknownexampleofatwostatesystemisanitrogenatominthedoublewellpotentialofanammoniamolecule.ThetunnelsplittingoftheammoniaNH3moleculefindsapplicationintheammoniaMASER,anacronymforMicrowaveAmplificationofStimulatedEmissionofRadiation,similarlyasLASERisanacronymforLightAmplification.WhilemagneticinteractionsoftheNH3moleculesarenegligible,themoleculesdipolemomentsareverysensitivetoexternalelectricfields.Aprominentcauseforthesplittingofenergylevelsisthetunneleffect.AsanexampleweregardtheammoniamoleculeNH3.Ifwesqueezethenitrogenatomalongthezaxisthroughtheequilateraltriangleformedbythehydrogenatoms,thentheNatomseesadoublewellpotentialV(z).TheNatomcanbeoneithersideoftheplaneoftheHatoms.HencetheNH3moleculeformsatwostatesystemwithtwobasisstatesorspatialeigenstates and withthenitrogenatomononesideortheotheroftheplaneofhydrogenatoms,anditsenergygroundandfirstexcitedstates and arethesymmetricandantisymmetricquantumsuperpositionsofthespatialeigenstates(ignoringrotationalandvibrationalstates).ThesystemcanchangefromLtoRandbackbecausethereisacertainprobabilityamplitudeAthatthenitrogenatomtunnelsthroughthecentralpotentialbarriertotheotherwell.Theammoniamaserisbaseduponthetransitionbetweentheenergyeigenstates,whichmayalsobedescribedastheRabioscillationbetweenthespatialeigenstates.However,theinversiontransitionisseenonlyatlowgaspressure.Asthegaspressureisincreased,thetransitionbroadens,shiftstolowerfrequencyandthenquenches(thefrequencygoestozero).Theammoniamoleculeappearstoundergospatiallocalisationasaresultofinteractionwiththeenvironment.Thiswouldbeofimmensetheoreticalinterest.Inchemistryandintheclassicalworldgenerally,enantiomorphicmoleculeswithdistinguishablespatialeigenstates and arealwaysfoundintheirspatialeigenstates(classicalbehaviour)ratherthantheirenergygroundstates(quantumbehaviour).Whilstammoniaisnotenantiomorphic,itdoesappeartoshowbothbehaviours,quantumatlowpressureandclassicalathighpressure,ifthequenchingisconsideredtobeadirectobservationoflocalisationorcollapseofthewavefunctionintoaspatialeigenstate.Withinthecontextofthedecoherenceprogramme,ithasbeentreatedquantitativelyinthatway.Thebroadening,shiftandquenchingoftheRabioscillationaresimplyconsequencesofimpactsandmaybedescribedwithintheframeworkofanoscillatorsubjecttowhitenoisefromtheenvironment.Thereisnoevidenceforlocalisationontospatialeigenstates.[7]
SeealsoAtomiccoherenceBlochsphereLaserpumpingOpticalpumpingRabiproblemVacuumRabioscillationNeutralparticleoscillation
References
07/05/2015 RabicycleWikipedia,thefreeencyclopedia
http://en.wikipedia.org/wiki/Rabi_cycle 4/4
1. EncyclopediaofLaserPhysicsandTechnologyRabioscillations,Rabifrequency,stimulatedemission(http://www.rpphotonics.com/rabi_oscillations.html)2. Griffiths,David(2005).IntroductiontoQuantumMechanics(2nded.).p.353.3. SourenduGupta(27August2013)."Thephysicsof2statesystems"(http://theory.tifr.res.in/~sgupta/courses/qm2013/hand5.pdf)(PDF).TataInstituteofFundamentalResearch.4. Griffiths,David(2012).IntroductiontoQuantumMechanics(2nded.)p.191.5. Griffiths,David(2012).IntroductiontoQuantumMechanics(2nded.)p.196ISBN97881775823076. AShortIntroductiontoQuantumInformationandQuantumComputationbyMichelLeBellac,ISBN97805218605677. "au:Herbauts_Iin:quantphSciRateSearch"(https://scirate.com/search?q=au:Herbauts_I+in:quantph).SciRate.
QuantumMechanicsVolume1byC.CohenTannoudji,BernardDiu,FrankLaloe,ISBN9780471164333AShortIntroductiontoQuantumInformationandQuantumComputationbyMichelLeBellac,ISBN9780521860567TheFeynmanLecturesonPhysicsVol3byRichardP.Feynman&R.B.Leighton,ISBN9788185015842ModernApproachToQuantumMechanicsbyJohnSTownsend,ISBN9788130913148
Externallinks
AJavaappletthatvisualizesRabiCyclesoftwostatesystems(laserdriven)(http://www.itp.tuberlin.de/menue/lehre/owl/quantenmechanik/zweiniveau/parameter/en/)extendedversionoftheapplet.Includeselectronphononinteraction(http://www.itp.tuberlin.de/menue/lehre/owl/quantenmechanik/elektronphononwechselwirkung/parameter/en/)
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Categories: Quantumoptics Atomicphysics
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