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T he Lif ec y c le of Viny l: Past, Pres ent an d Fu t ure H arm W hat is Vinyl ? Vin yl, als o known as “PVC” or “Polyviny l chloride,” is one of t he mos t widely us ed s ynthet ic mat erials due to it s dur abilit y and ve rs at ilit y. Comm on uses inc lude piping , vin yl s iding , vin yl f looring , electrical ins ulat ion, wind ows , t oy s , med ical equipment, cloth and paper coati ng , packag ing , and cou ntles s other pl as t ic produ cts . Manufacturing PVC The problem with PVC can be summed up in two words:TOXIC LIFECYCLE.Throughout its lifecycle, P VC can ca us e ha r m. PVC r equ ir es h a za r dous che mica ls in it s product ion a nd very ha za rdous che mica ls, su ch a s dioxi n a nd P CBs , a re byproduct s of t ha t s a me product ion. P VC lea che s or r elea se s ha r mful chemica ls in s ome consumer products, a nd t oxi c byproduct s , including d iox ins, ar e crea t ed when it i s b urned.The ala r ming news is that vinyl pr oducti on is on the ri se , des pit e the fa ct t ha t s a fer, fea s ible alter na t ives curr ently exist for a lmost all vinyl products.The manufacture of PVC can put worker health and fence-line communities a t r isk t hro ug h exposure t o haz a r dous che micals t ha t ca n ca us e a numbe r of sev ere hea lt h probl ems including ca ncer, endomet r iosis, neurolog ical da ma ge, immune sys t em damag e, r es pir a t or y problems , li ve r and kidney da ma g e, a nd b ir t h de fects. Fabricating PVC The ba s ic buil ding block of P VC is vinyl chlor ide, a s imple chem ical ma de of chlor ine, ca r bon and h ydrog en. Once t his b a sic b uildi ng block i s ma nufa ctur ed,it is sent t o count less fa br icati ng fac il it ies wher e v inyl consume r pr oduct s a re m a de. P VC is us eles s wit hout t he a ddit ion of a nu mber of da ngerous ch emica l stabilizers, su ch a s lea d and ca dmium, a nd phtha - lates.The fabricators’ job includes mixing in the additives and then working the machines t ha t ma ke t he pipe, s iding, sh ower cur t a ins, fa br ics, toys a nd other vinyl cons ume r pr od- ucts. P hthala t es ma ke P VC flexible, whil e le a d a nd c a dmium perfor m ot her functions related to specific uses. Consumer use Most vinyl pr oduct s are be li ev ed to be ba s ically ha rmless when properl y us ed. Howeve r, some of t he a dditives a nd s oftene r s lea ch out of cert a in vinyl pr oducts.Al t houg h soft P VC t oys ha ve be en ma de for ba bies for ye a r s , s t udies find t ha t t hes e a ddit ives lea ch out of s oft t oys int o t he m out hs of t he chil dren che wi ng on t hem.Vinyl IV bag s us ed in neo-natal i nt ens ive ca re unit s ha ve a lso been s hown t o l ea ch DE HP , a ph t ha late a ddit ive. In E urope, phtha late a dditi ve s in P VC t oys f or children under t he a g e of t hree ha ve be en ba nned a nd in t he US A, most compa nies ha ve v ol unta r ily stopped ma nufa cturing P VC t oys for t his a g e g roup or ha ve e li mina t ed the phthalates . However, a lt ernati ve s oft ene r s ha ve not bee n a dequ a t ely tes t ed to det ermine whether t he y a re sa fe. Ot her vinyl products like b r a nd ne w sh ower cur tains , car int erior s ,a nd floor ing , to na me a fe w, init ia lly r eleas e che mical g as es int o t he a ir. S ome s t udies indicate that t his off ga ss ing ma y cont r ibut e to hea lt h complica t ions, but t he infor ma t ion on t his is s pa r s e a nd nee ds fu r t her study . 3

PVC the Lifecycle of Vinyl

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The Lifecycle of Vinyl: Past, Present and Future Harm

W hat is Vinyl?Vinyl, also known as “PVC” or “Polyvinyl chloride,” is one of the most widely used synthetic materials due to its durability and versatility. Common uses include piping, vinyl siding, vinyl flooring, electrical insulation, windows,

toys, medical equipment, cloth and paper coating, packaging, and countless other plastic products.

Manufacturing PVCThe problem with PVC can be summed up in two words:TOXIC LIFECYCLE.Throughout its

lifecycle,PVC can cause harm. PVC requires hazardous chemicals in its production and veryhazardous chemicals,such as dioxin and PCBs, are byproducts of that same production.PVCleaches or releases harmful chemicals in some consumer products,and toxic byproducts,including dioxins,are created when it is burned.The alarming news is that vinyl productionis on the rise, despite the fact that safer, feasible alternatives currently exist for almost allvinyl products.The manufacture of PVC can put worker health and fence-line communities

at risk through exposure to hazardous chemicals that can cause a number of severe healthproblems including cancer,endometriosis,neurological damage, immune system damage,

respirator y problems, liver and kidney damage, and bir th defects.

Fabricating PVCThe basic building block of PVC is vinyl chlor ide, a simple chemical made of chlor ine,

carbon and hydrogen.Once this basic building block is manufactured,it is sent to countlessfabricating facilit ies where vinyl consumer products are made. PVC is useless without the

addition of a number of dangerous chemical stabilizers,such as lead and cadmium,and phtha-

lates.The fabricators’ job includes mixing in the additives and then working the machinesthat make the pipe, siding,shower curtains,fabrics,toys and other vinyl consumer prod-ucts. Phthalates make PVC flexible, while lead and cadmium perform other functions

related to specific uses.

Consumer useMost vinyl products are believed to be basically harmless when properly used.However, some of the

additives and softeners leach out of certain vinyl products.Although soft PVC toys have been madefor babies for years, studies find that these additives leach out of soft toys into the mouths of thechildren chewing on them.Vinyl IV bags used in neo-natal intensive care units have also beenshown to leach DEHP,a phthalate additive.In Europe, phthalate additives in PVC toys for children

under the age of three have been banned and in the USA, most companies have voluntarily stoppedmanufacturing PVC toys for this age group or have eliminated the phthalates. However, alternativesofteners have not been adequately tested to determine whether they are safe.Other vinyl

products like brand new shower curtains, car interiors, and flooring, to name a few, initiallyrelease chemical gases into the air. Some studies indicate that this off gassing may contribute to

health complications,but the information on this is sparse and needs further study.

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Disposal - Landfill and RecyclingPVC is difficult to recycle for several reasons.First, the high chlorine content in PVC makes recyclingcomplicated and expensive because it cannot be mixed with other plastics.When PVC is heated,the chlor ine is released as hydrogen chloride, which turns to hydrochloric acid. If even a small

amount of PVC mistakenly finds its way into a non-chlor ine based plastic recycling process,thehydrogen chlor ide can contaminate the entire batch of recyclables,damage the equipment,andmake it unfit for recycling.Therefore,PVC has to be separated from the other non-chlorinebased plastics.Second,because there are countless varieties of additives in different vinylproducts, the recycler is faced with the headache of mixing too many unknown chemicals

together and not being able to control the final content of the recycled product. Becauseof the variety of PVC ingredients in different products,PVC - when recycled - ends up beingused to make cheap,low quality products.Given the enormous challenge and narrow profitsassociated with recycling PVC, most of it ends up either in landfills,municipal incinerators,orsimply burned in open pits or backyard burn barrels.The latest landfills designs take into account

the variety of fluids that leach out from the waste,but even the latest landfill t echnologycannot be expected to contain these leachates far into the future. Many of the older landfills

have been leaching toxic fluids for decades.These fluids can seep through porous spaces in earth androck until they reach groundwater where they can travel far from the landfill.

Disposal - Incineration and open burningDioxin is formed when PVC is manufactured and when it is burned, either in an incineratoror an open fire. Dioxin is a known human carcinogen and among the most toxic chemicals

known.Dioxin released from incinerator stacks travels on air currents, sometimes for verylong distances, before eventually falling to the earth to be consumed by animals such as fish,chicken, pigs and cows. Enormous quantities of toxic ash are also created at incineratorsand must be treated as hazardous waste.It is estimated that approximately 200,000 tons of PVCis incinerated annually in the USA, leaving behind ash laced with dioxin and toxic additives.There is controversy over how that hazardous ash is handled and what the ramifications

will be years from now.And then there is the sobering fact t hat for many, the cheapest andmost convenient way to handle waste is to burn it - without pollution controls - in open pits

or backyard burn barrels.This dioxin forming activity occurs throughout the USA and perhapsmore frequently in newly industrializing countries around the globe.

BioaccumulationOnce dioxin enters the environment, it can be carried long distances by the wind. From

there, the dioxin molecules are deposited on surface waters,soils and plants where itmoves up the food chain, accumulating at higher and higher concentrations in fish,animalsand eventually in people.Concentrations of dioxin build up in the fatty tissue of the animals,which are then consumed by people.The evidence bears out since whales,which are high on

the food chain, often have high levels of dioxin and other chlorinated chemicals in theirbodies. People who consume large amounts of fatty meat, dair y and fish probably get thelargest doses of dioxin, but dioxin is also found at lower levels in grains, fruits and vegetables.

TransmissionDioxin has many sources in addition to the manufacture and incineration of PVC. But when PVC plastic is

burned, it directly contr ibutes to the dioxin releases to the environment, which eventually trespass intoour food supply.According to the U.S. Environmental Protection Agency, the average American has abody burden of dioxin that is at or near the level where health effects are known to occur. Unbornchildren are exposed to dioxin in their mother’s womb, while breastfeeding infants receive dioxinfrom their mothers’ breast milk.The benefits of breast-feeding outweigh the hazards from dioxin.In fact, breast-feeding is a bonding and nutritional activity without parallel. More extensive studiesabout the relationship between dioxin exposure and infant health are underway. However,there is

no question that the dioxin levels in mothers’ breast milk must be greatly reduced.This means thatdioxin sources must be eliminated.

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