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LOWER WILLAMETTE GROUP
PROJECT UPDATE PORTLAND HARBOR RI/FS
PRESENTATIONS
Do Note Quote or Cite: Preliminary Data and Draft Interpretation. All Content Subject to Change
August 16, 2005
9:00 - 9:05
9:05-9:15
9:15-9:25
9:25 - 9:40 9:40-10:15
10:15-10:30
10:30 -10:50 10:50-11:00
11:00-12:00
12:00-1:30
1:30-2:40
2:40 - 3:00
3:00 - 3:40
3:40 - 3:50
3:50 - 5:00
AGENDA Project Update
Portland Harbor RI/FS August 16, 2005
I. Workshop Goals
II. Summary of Presentation
III. Project Timeline
IV. RI Data Presentation a. Sediment Stability b. Surface & Subsurface Sediment
BREAK
c. Surface Water d. Fish and Invertebrate Tissue
V. Preliminary Human Health Risks
LUNCH
VI. Preliminary Ecological Risks
BREAK
VII. Initial Feasibility Impressions
VIII. Process for Identifying Additional Data Needs
IX. Panel Responses to Submitted Questions/ OPEN DISCUSSION
Lower Willamette Group
Project Update Portland Harbor RI/FS
August 16, 2005
LWG frftoiKnfta:
Summary of Today's Presentation
• Project Timeline • Rl Data Presentation • Human Health Risk Presentation • Ecological Risk Presentation • Initial Feasibility Impressions • Process for Identifying Additional Data
Needs • Panel responses to submitted questions &
open discussion
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Summary of Rl Data Presentation
• Physical System/Sediment Stability Overview • Sediment Chemistry Update
• Data Sources (LWG and Non-LWG)
• LWG Data Collection (Rounds 1 and 2)
• Nature and Extent of Selected Analytes
• Surface Water Update (Nov '04 and March '05)
• Round 1 Tissue Data Overview
LWG_
Summary of Human Health Presentation
• Receptors and exposure pathways that will be quantitatively evaluated in the baseline HHRA
• Preliminary risk evaluations: • Beach sediment (direct contact) • In-water sediment (direct contact) • Surface water (direct contact) • Fish and shellfish
• Species and chemicals contributing to risks from fish and shellfish consumption
Summary of Ecological Risk Presentation
• Time-line and current status of ERA deliverables
• Preliminary Risk Evaluation (PRE) - Objectives - Lines of evidence evaluated in PRE - Initial list of COPCs for aquatic organisms,
birds, and mammals - Representative chemicals displayed on maps
• Future deliverables and ERA process
LWG
Summary of Ecological Risk Presentation
• Benthic Interpretive Approach - Objectives - Data preparation for SQG evaluation
Hit/no-hit classification of bioassay data Chemistry data evaluation
- Evaluation of existing SQGs - Initiating Site-Specific Predictive Model - Future tasks and final deliverable
LWG L.m>MuuM»w DOXtfONMarOMr Arbl«m tuo £V«t Jtoamfkafe AH tm<m V
2
Summary of Initial Feasibility Presentation
• Review of Work Plan FS approach • Review of Work Plan remedial technologies • Preliminary chemical data integration
• Methods • Uncertainties • Maps presentation
* Future definition of Sediment Management Areas (SMAs)
• Process forward to the FS
Summary of Process for Identifying Additional Data Needs
• Review remaining Primary Project Elements • Review process to ID additional data needs • Review LWG submittals that will ID data
needs • Rl • Baseline Risk Assessments
• FS
• Review Comprehensive Round 2 Report
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Project Timeline Portland Harbor RI/FS
August 16, 2005
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1
2
Portland Harbor Remedial Investigation Update
Gene Revelas/Laura Jones, Integral Consulting August 16, 2005
OVG _ .
Rl Data Presentation Outline
• Physical System/Sediment Stability Overview • Sediment Chemistry Update
• Data Sources (LWG and Non-LWG)
• LWG Data Collection (Rounds 1 and 2)
• Nature and Extent of Selected Analytes
• Preliminary Areas of High Concentrations
• Surface Water Data (Nov '04 and March '05) • Round 1 Tissue Data Overview
LWG •» (*>»>.-ilk: rnL-vxrt r*ilijM£»M»ra07-i4jrfc* VlCucira V^H.-taCKaif
Portland Harbor RI/FS Study Area
1
J
Physically-altered Riverbed
Physical System/Sediment Stability
• STA Survey (2000) • SPI Survey (2001) • Precision Bathymetry Time Series
(2002-2004) • Hydrodynamic/Sediment Transport
Modeling (2005-2006)
V- M-l wriZim. frfbatmwt —d rr*} * 1-7 feTyrv: I>*rt*
Sediment Trend Analysis (STA)® - Sept 2000 (GeoSea Consulting, Ltd, Brentwood Bay, B.C.)
SPI Benthic Regimes and Cross-sectional Areas
3
Sediment Transport Working Conceptual Model
Sediment Stability Summary
• "Short-term" (Rl time frame) surface sediment dynamics measured directly and used for Round 2 Effort (20-30 cm surface interval)
• Hydrodynamic/Sediment Transport Modeling is designed to address "long-term" sediment stability question: • Where are sediments eroded/deposited during
high flow events?
Sediment Chemistry Update Data Sources
"Historical" or Non LWG-Generated Data • 71 Sediment Surveys from 1990 through 2004
throughout Portland Harbor; historical Data mapped in Work Plan
• USACE DMMP Sampling (2005 - results pending)
LWG-Generated Data
• Round 1 - Shoreline (Beach) and Surface Sediments and Tissue Data
• Round 2A - Shoreline, Surface and Subsurface Riverbed Sediments
Sample Numbers and Types Coverage Time
Frame Surface ! Samples
Subsurface Samples
Norv-LWG RM 1-12 1990-2004 849 729
USACE DMMP RM 2-12 2005 86 72
LWG Data
Round 1 RM 2-10 2002 74 0 Round 2A
Q-30cm
30-200cm 200-400cm
400+cm
RM 2-11 2004 555
333 247 29
Total Samples 1564 1410
IMS try tewMn
1
1
2
LWG Surface Sample Collection
Round 1 • hand cores .0-15 cm) - shoreline surface (20 locations) • van Veen or power grab (0-15 cm) - riverbed surface (37 locations) A
Round 2A • hand cores (0-15 cm) - shoreline surface (25 locations) ^ L • power grab iO-30 cm) - riverbed w surface (523 locations including 6 : upstream areas) W *
LWG _
LWG Subsurface Sample Collection
Round 2A Vibracore Samples
• 213 cores collected at 200 locations
160- 14 ft cores 53 - 20 ft cores
• avg. recovery = 30%
• Cores sectioned and analyzed based on: • lithoiogy • field lab screens (FID/PID) • visual observations
Three Sediment Depth Intervals (l-IV) Mapped
Subsurface Core Segments B. C II = 30 to 200 cm (1-6.5 ft)
Deep Subsurface Core Segments D. E. F III = 200 to 574 cm (6.5-19 ft)
200-400 cm (n = 247) 400-574 cm (n = 29)
Surface Grabs and 4 A" Core Seg 1 = 0 to 30 cm (0-1 ft)
Analytes Mapped for Preliminary Nature and Extent Discussion
Selection Criteria Organics
• widely detected in • Total PCBs historical/LWG data • Total DDTs
• concentrations/spatial • Total PAHs distributions range widely • Bis2(ethylhexyl)phthalate
• metals and organics • Dioxin TEQ • bioaccumulative and non-
bioaccumulative compounds • likely focus in risk assessments Metals
• many other chemicals will • Mercury
be evaluated in the RI/FS • Arsenic (not mapped)
• for illustrative purposes today
tWG _ I".. ' "•
Preliminary Nature and Extent Disclaimer-"This is not a risked-based evaluation"
• Point out locations of "elevated" concentrations of 6 selected analytes that may become the focus of the risk assessments
• "Elevated" concentrations are defined as highest mapped range (red symbols) for 5 of 6 of the selected chemicals. For total DDTs, the two highest mapped ranges (red & orange symbols) define elevated
• Spatial trends based on the relative concentrations only, not risk-based levels
• Adjacent/nearby property place names are used as geographic reference points - not intended to imply sources
tWjG_ J v
Preliminary Nature and Extent Summary
• 30 Nearshore locations with elevated concentrations of one or more of the 6 selected chemicals • 19 along west bank (RM 11.5 to 3.3); all chemicals • 11 along east bank (RM 9.2 to RM 2); 5 of 6 chemicals (no
DDT)
" 3 Channel locations • RM 10.6 (Hg) • RM 6.2-6.3 (PAHs, BEHP) • RM 5.3-5.7 (PAHs)
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Preliminary Nature and Extent Summary (cont.)
• Upstream and downstream ends of sampled area (including stations in Multnomah Channel) show generally low concentrations of the mapped analytes
• Subsurface high concentrations in some areas consistent with depositional patterns • Linnton Plywood (PAHs, dioxin)
• Kinder-Morgan (PAHs)
• PGE-Harbrton (PAHs)
Sediment Data - Rounds 1 & 2
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5
i
••V . X ,v.-^ ;u,, •-• w,.
Sediment Data - Rounds 1 & 2
700 Total OOT (ugikg)
700 Frequency Detects
l — Frequency Undetects DETECTED RESULTS (MUM AWO »E(*CE«TIL£II 600 N % OETECTS Arith. Utao G« litln 2Sk SOW. 7Sik 95m
500 • uii n 2se uj n 71 12 ui
400
l \ 1 300 \ 200 • I _ _ 200 • \ 100 AI
0 • i
0 •
0 2
0
40
60
80
100
120
14
0
16
0
18
0
200
220
24
0
26 J
280
30
0
32
0
34
0
36
0
38
0
400
420
440
460
480
500
Concentration
6
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Sediment Data - Rounds 1 & 2
Total PAHs (ug/kg)
—Frequency Detects —Frequency Undetects oetecteo results (hears aro percertaesi
n % OETECT5 Arith. Ucan Geo Mean rsm SOU 7SHi 9
Concentration
Sediment Data - Rounds 1 & 2 Bis(2-ethythexyl)phthalate (ug/kg)
Concentration
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Sediment Data - Rounds 1 & 2
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Sediment Data - Rounds 1 & 2
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Sediment Data - Rounds 1 & 2
450 ARSENIC (mg/kg)
450 DETECTED RESULTS (MEANS ANO PERCENTILES)
400 X N % DETECTS Arith. Mean G«oUtin 2»h 50th 75th 95th
350 J\ U*L _ 1J01L _ _ ij? _ J H . JTL <W_ L"_
300
250
200
J \ —Frequtncy Detects | 300
250
200 r l\ 1
150 1 \ 100 / \ 50 / 0
c 1 2 3 4 5 6 7 8 9 10
11
12
13
14
15
16
17
18
19
20 D
Concentration 2
LWG
13
Round 2A Surface Water Sampling Results
Laura Jones, Integral Consulting August 16, 2005
Overview
• Sample Collection Methods • Summary of Results for Selected Analytes
• Total PCBs
• Total DDT
• Total PAHs
• Dioxin/Furan TEQ
• Arsenic
• Transect Comparisons
LWG „
Surface Water Sampling Design
• Data Needs • Site Characterization • Ecological Risk Assessment • Human Health Risk Assessment • Food Web Modeling • Feasibility Study
• Sample Types • Single-Point Near Bottom Samples • Cross-Sectional River Transect • Single-Point Water-Column Samples
LWG •M.Kr—i (>»•»*fifc A.lMnltamrfttfteirMKK'UUM
2
Surface Water Sampling Design
• Sampling Techniques • Peristaltic Pump Method • High-Volume/XAD-2 resin columns
LWG
3
Sample Stations and Schedule
Stations • 23 stations • Peristaltic Pump Method at all stations • High-Volume/XAD-2 at 7 stations
Schedule • 3 events (early rainy season, late
winter/amphibian egg release, summer low-flow)
Current Status
Three sampling events completed Summer event completed July 2005 November 2004 and March 2005 data included in this presentation
Willamette River Flows During Round 2A Surface Water Sampling
November 2004 & March 2005 Surface Water Sampling Results
Total PCB Atodoti (ngl) PaMWfaC Nov 04 Mat 06
11% 25 U 27 U 59 J 154 W0I4 6% 25 U 26 U 136 J 136 J W004
Total PCB Corganars ,ngt) XAC Nc-t 04 Mat OS
I00S NA NA 023 J 33 J VTO13-1 100% NA NA 012 120 W013
Total DOT ;ng t! »«i»6c Nov 04 Mat 06
0 042 U 053 U NA NA NA 5% 0 43 U 051 U 12 12 W319
Total DOT (ngt) WO Nov TM Mat 06
10C% NA NA 004 J S3 J W015 100% NA NA 004 3 3 W015
Total PAH* jng Vi Pa-italbe Nov. "04 Mat 06
76% 2 4 U IS U 3 7 J 1340 J W012 56% 7 4 U 16 U 26 J 373 J WOO«
DwaoTEQipgl) XAC Nov tM Mat 05
100% NA NA 004 J 057 J W015 100% NA NA 003 J 051 J W015
Big a<»|<NB|illpttlhatatt '"gi-l Pan«alte Nov. "94 Mat 05
0% 220 1300 NA NA NA 0% 270 300 NA NA NA
&*i2a»>y»>a:gr$»»ia>a» IngA) XAC Nov 04 14% 4 3 3 6 33 0 J 330 J W015 0% 49 36 NA NA NA
Total Araanc (vgL) Nov '04 Mat 05
100% NA NA 033 0 67 W322 10C% NA NA 036 0 56 W302-2
taakfee Nov "04
LWC Uoo»iMrni>« DO Oun at I Vti ntcmiur.r, r>ci'Jld X>1»•*»,«
Total PCB Congeners - Transect Samples
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6
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Total Dioxin/Furan TEQ - Transect Samples
LWC L«1W iHt \ae »f t itm- f**itnvmDaa 0»? tBrffrtolV*, AH Ce*St& .faWr.f -C < 'n'ft
Round 2A Surface Water Reporting
Late August 2005 • Validated PCB Congener Data for Nov '04 Sampling
Event • All Validated Data for Mar '05 Sampling Event September 2005 • Data Report for Nov '04 and Mar '05 Sampling
Events • Field Sampling Report for July '04 Event January 2006 • Round 2A Surface Water Site Characterization
Report
LWG
Round 1 Tissue Data Overview
Gene Revelas, Integral Consulting August 16, 2005
LWG i*Abt£hc*.» ttr'M» Ot& tmr?matcm Mll«
Fish Tissue Sampling Period Subyearling Chinook Remaining species
Site Characterization Report
June 24 - 27, 2002 July 22 - November 10, 2002
October 12,2004
LWG
1
2
Crayfish and Sculpm Whole-body Tissue Total PCB and DDT Concentrations by River Mile.
Crayfish and Sculpm Whole-body Tissue HPAH and LPAH Concentralions by River Mile. Undetected are indicated in yellow.
Crayfish and Sculpin Whole-body Tissue Bis(2-Ethylhexyl) Phthalate and 2378-Dioxin TEQ Concentrations by River Mile. Undetected are yellow.
4
5
1
6
1
Preliminary Data Interpretation: Human Health
Laura Kennedy Kennedy/Jenks Consultants
August 16, 2005
Overview
• Human Health CSM • Receptors for Evaluation • Pathways for Evaluation • Process to Select Chemicals of Potential Concern • Preliminary Risk Evaluations
• Beach Sediment (Direct Contact) • ln-water Sediment (Direct Contact)
• Surface Water (Direct Contact) • Fish and Shellfish
• Conclusions (so far)
l
Receptors for Evaluation
• Dockside Workers • Recreational Beach Users • Transients • Fishers/Fish Consumers
• Recreational • Non-tribal • Native American
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Process to Select COPCs
• Compare maximum detected concentrations with screening values
• Beach Sediment: • Residential soil Region 9 PRGs for
recreational/transient beaches • Industrial soil Region 9 PRGs for dockside
worker beaches • In-water Sediment:
• Industrial soil Region 9 PRGs
LWG Cnm DtX' ! > - Oft Mw OUn uuf Pr̂ i Imrifnnjwt. «fl CrrltH I«f*.1 /» HM|»
Process to Select COPCs (cont'd)
• Surface Water: • Tap water Region 9 PRGs
• Groundwater Seeps: • Tap water Region 9 PRGs
• Fish and Shellfish: • All detected chemicals
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Preliminary Risk Evaluations: Beach Sediment (Direct Contact)
• Dockside Worker Beach COPCs
Preliminary Risk Evaluations: Beach Sediment (Direct Contact)
• Recreational/Transient Beach COPCs
Preliminary Risk Evaluations: Beach Sediment (Direct Contact)
Risk Calculation Assumptions (RME): • Default soil exposure factors for industrial or residential
scenarios • Dockside Worker: 50 days per year for 25 years • Recreational Beach User (adult): 94 days per year for 30
years • Recreational Beach User (child): 94 days per year for 6
years • Transient 365 days per year for 2 years • Recreational Fisher 156 days per year for 30 years • Non-tribal Fisher: 104 days per year for 30 years • Native American Fisher: 260 days per year for 70 years • Assumptions apply to individual beaches
Preliminary Risk Evaluations: Beach Sediment (Direct Contact)
Preliminary RME risks
Preliminary Risk Evaluations: In-water Sediment (Direct Contact)
In-water COPCs
Preliminary Risk Evaluations: Surface Water (Direct Contact)
• Surface Water COPCs (to date)
Preliminary Risk Evaluations: Fish and Shellfish
• Species for HHRA: • Resident fish: Black crappie, brown bullhead,
carp, smallmouth bass • Shellfish: Crayfish • Large home range fish: Salmon, sturgeon,
lamprey (Native American consumers only)
LWG_ _
Preliminary Risk Evaluations: Fish and Shellfish
• Ranges of Risk: • Average and maximum/95 percent UCL tissue
concentrations • Whole body and fillet samples for fish species • Single species (non-tribal consumers only) and
multiple species diet • High, medium, and low fish ingestion rates for
adult non-tribal consumers
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Preliminary Risk Evaluations: Fish and Shellfish
• Risk Calculation Assumptions: • Ingestion rates: 175 g/day (23 meals per month), 142
g/day (19 meals per month), 73 g/day (10 meals per month). 17.5 g/day (2 Y2 meals per month)
• Fish consumption at specified ingestion rate every day for 30 years (non-tribal) or 70 years (tribal)
• All fish consumed are from Portland Harbor • Tissue concentrations do not change over time or due to
preparation methods • For single species diet, only one type of fish, either fillet or
whole body, is consumed
Preliminary Risk Evaluations: Fish and Shellfish
Preliminary ranges of risks:
Preliminary Risk Evaluations: Fish and Shellfish
Preliminary Risk Evaluations: Fish and Shellfish
Preliminary Risk Evaluations: Fish and Shellfish
Chemicals that may result in Risk > 10 6 or HQ > 1 under any scenario:
1
Preliminary Risk Evaluations: Fish and Shellfish
* For Non-tribal Multiple-Species Rsh Consumption die! using whole body tissue data
Preliminary Risk Evaluations: Fish and Shellfish
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* For Non-tribal Multiple-Species Fish Consumption diet ussig whole body tissue data
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8
Conclusions (so far)
• Fish consumption likely to drive human health risks
• In-water sediment and surface water EPCs required for 10 5 risks or HQ of 1 for direct contact scenarios:
Conclusions (cont'd)
Approximately 90 percent of risk for Tribal multiple species diet due to resident fish species Approximately 95 percent of noncancer hazards due to PCBs Approximately 95 percent of cancer risk due to PCBs and dioxins Further discussion needed on presenting risks from fish consumption given the assumptions and uncertainties
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Preliminary Ecological Risks
Lisa Saban, Windward Environmental August 16, 2005
Completed Major Ecological Risk Assessment (ERA) Deliverables
Portland Harbor Programmatic Work Plan: Ecorisk Approach in Appendix B
Preliminary Risk Evaluation (PRE) Approach Technical Memorandum
Toxicity Reference Value Selection Technical Memorandum
Benthic Interpretation Approach TM
Initial Food Web Model Approach TM
Technical Memoranda under Development
Revised Comprehensive ERA TM - under review/discussion with EPA GW pathway approach - under discussion with EPA (currently in GW SAP) FSP for benthic invertebrate tissue sampling - under discussion with EPA Water screening values - currently under review by EPA
Scfttrv iV~^ yrvUj Us ZPPr ltJ ^ Syf
Upcoming Major ERA Deliverables
• Preliminary Risk Evalua Hon
• Benthic Interpretative Report
• Food Web Model Reports
• Round 2 Comprehensive Risk
Assessment
• Baseline Ecological Risk Assessment
Round 1 Data Collected for ERA
• 110 whole body fish, clam, and crayfish tissue samples
• 35 fish stomach contents for prey identification (qualitative)
• 58 surface sediment sampling locations
• 12 multiplate stations for community analysis
Round 2 Data Collected for ERA
• 555 surface sediment chemistry locations
• 233 sediment toxicity locations • 25 shorebird beach sediment chemistry
locations
• 25 surface water chemistry locations • 4 composite whole-body tissue and 4 stomach
content samples of juvenile Chinook salmon • 20 juvenile Chinook stomach contents for prey
identification
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Future Data Collection for ERA
• 10 multiplate stations for invertebrate tissue and community analysis (currently in progress)
• Additional invertebrate tissue
• Transition zone water sampling
.*« (Jrnm or OK Mimh Gmj Jwifmatsi.« Owe M ffo*
Preliminary Risk Evaluation
• PRE is first major deliverable in the ecological risk assessment process
• Available Round 1 and Round 2 data are used for initial risk calculations
• Initial risk calculations in the PRE are based on conservative assumptions
• Results of PRE risk calculations will provide initial list of ecological COPCs to focus future ERA iterations
Preliminary Risk Evaluation
• PRE will not evaluate risk to all receptor groups (invertebrates, aquatic plants, and amphibians/reptiles) due to availability of data
• PRE will not evaluate risk from all exposure pathways (direct toxicity to benthic invertebrates, surface water, transition zone water)
• Representative invertebrate tissue is a primary data gap identified in the PRE
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Lines of Evidence Evaluated in PRE
• Tissue-residue approach - Comparison of tissue concentrations of Round 1 clam, crayfish, and fish receptors to tissue-residue toxicity reference values (TRVs)
• Dietary approach - Comparison of estimated dietary concentrations to dietary TRVs*
• Modeled egg approach - Comparison of estimated bird egg tissue concentrations to egg based TRVs
"Die! was based on available Round 1 tissue and BSAF/BAF modeled tissue
Hazard Quotient Approach
• Hazard quotients (HQs) derived from Round 1 tissue and sediment data:
HQ = EPC/TRV
• Conservative exposure point concentrations (EPCs) based on maximum tissue (or modeled tissue) and maximum sediment concentrations
• Toxicity reference values (TRVs) still under review by EPA and are subject to change
4
Initial COPCs for Aquatic Tissue
Chemical HQ >1-10 HQ >10-50 HQ >50-100 HQ > 100 Total PCBs X chromium X copper X lead X mercury X zinc X 4,4'-DDD X 4.4'-DDT X total DD I X
Fttmacn D*Ua4l*cfi toorrtosM. .U
Initial COPCs for Aquatic Tissue (cont'd)
Chemical HQ >1-10 HQ >10-50 HQ >50-100 HQ > 100
alpha-HCH X*
beta-HCH X*
delta-HCH X*
endrin X*
hexachloro-butadiene X*
BEHP X 'HQ based on HL NOTE; HQs < 1 for aU other chanicala
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Initial COPCs for Fish Diet
Chemical HQ >1 -10 HQ >10-50 HQ >50-100 HQ > 100
Total PCBs X copper X
mercury X
zinc X
TBT X
total PAHs X
total DDT X
total PAHs X NOTE: HQs < 1 for ail cxher cfcemicaJs
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5
BEHP HQs in Round 1 sculpin tissue by location
Total dioxin TEQ HQs in Round 1 sculpin tissue by location
Total DDT HQs in Round 1 sculpin tissue by location
Total PCB Aroclor HQs in Round 1 sculpin tissue by location
LWG
BEHP HQs in Round 1 crayfish tissue by location
LWG
1
Total DDT HQs in Round 1 crayfish tissue by location
, 5
7
i
Total PCB Aroclor HQs in Round 1 crayfish tissue by location
8
Initial COPCs for Bird Eggs
Shorebird TEQ HQ: Measured vs. Modeled
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Shorebird lead HQ: Measured vs. Modeled
Shorebird mercury HQ: Measured vs. Modeled
Shorebird total DDTs HQ: Measured vs. Modeled
Shorebird total PAHs HQ: Measured vs. Modeled
Shorebird total PCB Aroclors HQ: Measured vs. Modeled
Deliverables Following the PRE
• Results and Interpretation of the Benthic Toxicity Assessment Report will evaluate the benthic toxicity line of evidence
• Round 2 Comprehensive Report will evaluate ecological exposure of aquatic plants, invertebrates, fish and amphibians/reptiles to surface water based on Round 2 data
<*• MOM MS <>•*» AH C.-W-W r**|»
11
Deliverables Following the PRE
• Round 2 Comprehensive Report also will refine the risk calculations presented in the PRE
• Food Web Model Reports will present predicted tissue concentrations in receptors
• The Baseline Ecological Risk Assessment Report
tlVG,
Benthic Interpretive Approach
Mike Johns, Windward Environmental August 16, 2005
LWG
Benthic Interpretive Approach
• Characterizes the relationship between sediment chemistry and benthic invertebrate toxicity
• Evaluate the predictive relationship between sediment chemistry and toxicity by.
- comparison to existing SQGs - development of a site-specific predictive model
• Identify areas within the Study Area where chemical concentrations in sediment may pose risks to benthic organisms
Data Used:
• 233 co-located sediment chemistry and toxicity test samples
• 215 locations in the Study Area and 6 upstream locations (3 samples per upstream location)
• 10-day Chironomus tentans and 28-day Hyalella azteca sediment toxicity test
• Other existing data sets from Willamette River • Regional or nation wide data sets
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Bioassay Data Preparation for Evaluation to Existing SQGs
• Hit/No-Hit Identifications - used existing freshwater criteria: - Statistical Difference-Only - Sediment Quality Standard (SQS) - Clean-up Screening Level (CSL) - Defined new Substantial Effects Level (SEL) using CSL as template and changing the threshold levels
• Defined four individual bioassay endpoints and pooled endpoints
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Portland Harbor Round 2 Sedqual toxicity test results, RM 2-11
Portland Harbor Round 2 Sedqual toxicity test results, RM 2-4
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Portland Harbor Round 2 Sedqual toxicity test results, RM 4-6
Portland Harbor Round 2 Sedqual toxicity test results, RM 6-8
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Definition of Pooled Endpoints
• Minor Effects Level defined as any one of the four endpoints exceeding its individual SQS
• Moderate Effects Level defined as any one of the four endpoints exceeding the CSL level or two or more endpoints exceeding the SQS
• Substantial Effects Level defined as any one of the four endpoints exceeding the high effects level or two or more endpoints exceeding the CSL
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Summary of Individual Endpoint Classification
Hit OamtfkaUua Chironomus Mortality
Chironomus (•rowth
Hyalella Mortality
Hyalella <.rowth
No KfTects Level
No Significant Difference
92 I48J 106
" Minor KfTects Level
Significant Difference
141 79 127 227
Minor KfTects Level SQS K7 45 61 K8
Moderate KfTects Level
CSL 42 21 34
" Substantial KfTects Level
SEL 15 4 14 °
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Portland Harbor
Round 2 preliminary toxicity test
results: data pooled
RM 2-6
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Portland Harbor
Round 2 preliminary toxicity test
results: data pooled
RM 6-11
Portland Harbor
Round 2 preliminary toxicity test
results: data pooled
RM 2-11
Evaluation of Existing SQGs by Reliability Analysis
• None of the existing SQG sets performs well at any level of effect
• No one SQG set performs better than the others, and their level of conservatism varies greatly among endpoints and effects levels
• Need to develop site-specific predictive model
LWG
Next Steps:
• Further evaluation of chemistry data to focus analyte list on chemicals related to observed toxicity
• Development of Site-Specific Predictive Model
• Results and Interpretation of the Benthic Toxicity Assessment Report to be submitted November 1, 2005
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Feasibility Study Impressions
Carl Stivers, Anchor Environmental ; August 16, 2005
LWG
Work Plan FS Approach
• Complete Baseline Risk Assessments • Refine Remedial Action Objectives • Identify Areas (Sediment Management
Areas) and Volumes of Sediment • Refine Remedial Technologies • Assemble Remedial Alternatives • Screen Remedial Alternatives • Evaluate Remedial Alternatives
4MB
Remedial Technologies (Work Plan) •Institutional Controls •Removal and Disposal •Natural Recovery • Confined Aquatic
• Unenhanced Disposal • Enhanced • Nearshore Confined
•In-situ Containment Disposal •In-situ Containment • New Upland Disposal • Thin Layer Capping Facility • Capping • Existing Upland Disposal • Nearshore berms/fills Facility
•In-situ Treatment •Removal and Treatment • Biological • Physical • Chemical • Chemical • Stabilization • Biological • Others • Stabilization
• Others
Preliminary Chemical Data Integration -Methods
• Preliminary qualitative analysis - primarily not risk-based
• Combined highest concentration category for all reviewed chemicals
• Used highest relative concentration only (with two exceptions below)
• Overlay bioassay substantial effects results • Overlay preliminary sculpin and crayfish tissue risk
info. • Consider potential risk driver bioaccumulative
compounds • PCBs (used top two relative highest categories) • DDTs(same)
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Preliminary Chemical Data Integration -Uncertainty
( am pit It Uncertainty
Substantial ( ncertainty
Some Uncertainty
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Other Inputs to Define Future Sediment Management Areas (SMAs)
• Complete risk assessments and refine areas with unacceptable risks
• Detailed analysis of sediment depths and related volumes
• Overlay physical environment • Overlay habitat types and restoration opportunities • Overlay nver and shoreline uses and potential future
uses • Source differences (e.g., groundwater vs. overwater
source)
LWC
Process Forward to the FS
• Define spatial or volumetric data gaps for FS level determinations
• Further define recontamination/source sampling and evaluation methods
• Physical/chemical process information • Engineering properties • Fate and transport processes
• Conduct Round 3 sampling (for the above) • Work Plan FS Approach
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Work Plan FS Approach
• Complete Baseline Risk Assessments • Refine Remedial Action Objectives • Identify Areas (Sediment Management
Areas) and Volumes of Sediment • Refine Remedial Technologies • Assemble Remedial Alternatives • Screen Remedial Alternatives • Evaluate Remedial Alternatives
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Process for Identifying Additional Data Needs
Keith Pine, Integral Consulting August 16, 2005
LWC |UW|lMroni>
Remaining Primary Project Elements
1. Complete Round 2: collect data to complete Rl and BLRA (late 2005)
2. Comprehensive Round 2 Report and Data Gaps Analysis (April 2006)
3. Round 3: collect data for FS and RI/BLRA data gaps (2006)
4. Draft Rl & BLRA Reports (summer2007)
5. Draft FS Deliverables (winter 2007)
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Process for Identifying Additional Data Needs
1. Identify data gaps and data needs in remaining Round 2 deliverables
2. Develop FSPs to address data needs as they are identified
3. Identify all data gaps and remaining data needs in Round 2 Comprehensive Report
4. Develop FSP(s) to address remaining data needs identified in Round 2 Comprehensive Report
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Data Gaps/Data Needs Evaluations -RI&BLRA
• Revised Phase 1 Hydrodynamic/ Sediment Transport Model Report (submitted 7/5/05)
• Ecological Preliminary Risk Evaluation (9/9/05)
» Benthic Interpretation Report (11/1/05) • Initial Food Web Model (11/4/05) • Round 3 Surface Water FSP (Fall 2005) • Round 2 Comprehensive Report
(Spring 2006)
Data Gaps/Data Needs Evaluations -Feasibility Study
• Step 2 Monitored Natural Recovery Report (11/3/05)
• Facility Siting Final Ranking Report (2006?) • Recontamination Studies (part of R3 SW FSP
development - fall 2005) • Sediment Management Area Data Needs
(part of Comprehensive Round 2 Report) • Background Data Needs (Approach TM
10/31/05)
Comprehensive Round 2 Site Characterization and Data Gaps Analysis
Report
• Summarize LWG and non-LWG sample data • Refine the conceptual site model « Present preliminary human health and
ecological risk evaluations • Identify chemicals and media that may pose
unacceptable risks * Identify preliminary SMAs • Identify potential historical and ongoing
sources of contamination
LWG
Project Update Portland Harbor RI/FS
May 24, 2006 Portland, OR
LOWER WILLAMETTE GROUP