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1 Centre for Process Integration © 2017 Process Integration in Petroleum Refineries - A Perspective and Future Trends Robin Smith University of Manchester

Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

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Page 1: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

1 Centre for Process Integration © 2017

Process Integration in Petroleum Refineries- A Perspective and Future Trends

Robin SmithUniversity of Manchester

Page 2: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

2 Centre for Process Integration © 2017

Outline1. Background

2. Heat Recovery in Crude Oil Distillation Systems

3. Case Study

4. Utility System Optimization

5. Case Study

6. Concluding Remarks

Page 3: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

3 Centre for Process Integration © 2017

Outline1. Background

2. Heat Recovery in Crude Oil Distillation Systems

3. Case Study

4. Utility System Optimization

5. Case Study

6. Concluding Remarks

Page 4: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

4 Centre for Process Integration © 2017

Crude oil refining

Page 5: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

5 Centre for Process Integration © 2017

Refinery CO2 emissions breakdown by process

Off sitesOff sites

Sulphur recovery

Sulphur recovery

Hydrotreating

Hydrotreating

Alkyl/Isom

Alkyl/IsomCat. Reformer

Cat. Reformer

FCC

VDU

ADUADU

150,000 bbl/d Hydroskimming refinery

0.6 Mt/a CO2

150,000 bbl/d Conversion refinery

1.4 Mt/a CO2

Hydrogen

CONCAWE Refinery Management Group, The potential for application of CO2 capture and storage in EU oil refineries, (2011) 65. www.concawe.org.

Page 6: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

6 Centre for Process Integration © 2017

Energy Consumption within refineries

FuelSteam

Electricity

Page 7: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

7 Centre for Process Integration © 2017

Heat Integration using Pinch Analysis

Well established methodology- many successful applications around the world

Page 8: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

8 Centre for Process Integration © 2017

Pinch Analysis - Summary

• An approach to the design of heat recovery systems based on thermodynamic rules

• Applies well to the design of new systems• Fundamentally not suited to retrofit Tries to turn the existing design into a grassroot

design in a single step Often leads to complex and uneconomic retrofits

• Fundamentally not suited to operational optimization

Page 9: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

9 Centre for Process Integration © 2017

• It is a useful tool used in the right way on the right problems

• Can be used to set target performance for new processes

• Can be used to set the ultimate performance of an existing process, but this will not necessarily be economic

BUT

Pinch Analysis - Summary

• It is one of a number of tools that canbe used to improve the performanceof processes

Page 10: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

10 Centre for Process Integration © 2017

Optimize

Final Design

ST

1

2

180 OC

130 OC

100 OC

120 OC 60 OC

60 OC

70 OC

80 OC

4

3

• Difficult mathematical optimization problem - due to nonlinear nature of the problem

• Difficult to get practical solutions reliably for large complex problems

Initial Design(Superstructure)

ST

180 OC

130 OC

100 OC

120 OC

2

1

60 OC

60 OC

70 OC

80 OC

3

4

Superstructure Optimization

• Designer is removed from decision making

Page 11: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

11 Centre for Process Integration © 2017

• Superstructure approach now well developed

• More powerful optimization engines will increasethe application of the approach and the qualityof the solutions

BUT.....

Most users still demand the insights that automated techniques do not provide

Page 12: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

12 Centre for Process Integration © 2017

Graphical Approaches

Trial & Error

NLP

MINLP

Number of Design Configurations

Com

plex

ity

MILP

Optimisation Methods

Stochastic Search Methods

Page 13: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

13 Centre for Process Integration © 2017

Outline1. Background

2. Heat Recovery in Crude Oil Distillation Systems

3. Case Study

4. Utility System Optimization

5. Case Study

6. Concluding Remarks

Page 14: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

14 Centre for Process Integration © 2017

Energy use in crude oil distillation

Medium size refinery

6 million tonnes of crude per year (110,000 bbl/day)

70 MW furnace duty (ADU+VDU)

~ 15 million Euros per year in furnace operating costs

Page 15: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

15 Centre for Process Integration © 2017

Strategies to reduce energy consumption

CDU HEN

Retrofit

Operational Optimisation

• Capital investment required• Benefits increase with

higher capital investment• Downtime required for

implementation

• No capital investment required

• Limited benefits due to fixed configuration

• Changes can be readily implemented

CDU and HEN should be optimised together

Page 16: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

16 Centre for Process Integration © 2017

Challenges to optimising heat-integrated distillation systems

Product quality

Column hydraulics

Installed heat transfer area, capacity of

pumps, bypasses, plant

layout, etc.

CAPEX

• Complex configuration• Subject to many practical

constraints

Page 17: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

17 Centre for Process Integration © 2017

Approach to optimising heat-integrated distillation systems

Optimisation

HEN modelling

CDU modellingStatistical

orFirst-

principle

CDU HEN

• Surrogate models using ANN have been particularly effective

Page 18: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

18 Centre for Process Integration © 2017

Contents1. Background

2. Heat Recovery in Crude Oil Distillation Systems

3. Case Study

4. Utility System Optimization

5. Case Study

6. Concluding Remarks

Page 19: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

19 Centre for Process Integration © 2017

CASE STUDYCarried out by Process Integration Ltd

Page 20: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

20 Centre for Process Integration © 2017

Project background• Complex Chinese refinery, processing 6

millions tonne/y of opportunity crudes

Project Objectives• 5-year energy management contract

(EMC)• Improve system energy efficiency by HEN

retrofit

Constraints• Very tight product quality specifications • Limited condenser duty• Fuel gas with varying composition• Complex existing HEN: 47 exchangers

Industrial Case Study

Implementation completed in January 2016

PF-A ADU-A

VDU

PF-B ADU-B

Page 21: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

21 Centre for Process Integration © 2017

Industrial Case Study

• Historical data for 2 years were analysed to identify representative crude oils from the variety processed in that period

• Main challenge was the complexity of the existing system: five distillation columns

Five distillation columns

Complex HEN

Opportunity crudes

EMC project

Page 22: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

22 Centre for Process Integration © 2017

Industrial Case Study – Procedure Data collection

Develop rigorous simulations

Analyses using rigorous simulations

HEN design developed

Verification of results

E.g. feed and product properties, main operating cases, HE geometry data

Implementation strategy, data collection and savings calculations

Revamping options proposed with various levels of investment

E.g. sensitivity analysis to propose CDU operational changes, pinch analysis

Based on collected data and validated with process engineers

Implementation and validation

Results revised and verified with process engineers

Page 23: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

23 Centre for Process Integration © 2017

Industrial Case Study – Predicted results

Number of heat exchangers

+ 48 °C+ 21 °C

+ 14 °C+ 4 °C

+ 25 °C- 8 °C

3

3

2

2

2

1

Train A

Train B

4

33

2

1

1

6

6

8

Change from base case

Page 24: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

24 Centre for Process Integration © 2017

Industrial Case Study – Predicted results

Number of heat exchangers

3

3

2

2

2

1

Train A

Train B

4

33

2

1

1

6

6

8

Fuel savings

22 % 4.3 MM €/y

Additional heat transfer area

7,230 m2

Page 25: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

25 Centre for Process Integration © 2017

Industrial Case Study – Retrofit modifications

Description Value

Total additional area (m2) 7,230

New heat exchangers 6

Exchangers with additional area 9

Relocated exchangers 8

Page 26: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

26 Centre for Process Integration © 2017

Track record on CDU studies

Project name Client Year Project Description / Economic benefits

Operational Optimisation and

Retrofit Optimisation Study of

Crude Oil Distillation Unit

European

Refinery, Spain2016

Savings from operational and yield optimisation = 4.5 MM€/yr (verified)

for current scenario and 6.4 MM€/yr (estimated) for future scenario

Crude Distillation Unit Preheat

RevampingSinopec, China 2016

EMC: Implemented. Capacity: 3.0 mt/y; CIT increase = 48.2°C;

13.5 MW reduction in furnace duty; additional area: 4,000 m2

Crude Distillation Unit Preheat

RevampingSinopec, China 2016

EMC: Detailed Engineering. Capacity: 3.0 mt/y; CIT increase = 67 °C;

18.5 MW reduction in furnace duty; additional area: 10,300 m2

Crude Distillation Unit Preheat

RevampingSinopec, China 2015

EMC: Implemented. Capacity: 5.2 mt/y; CIT increase = 43 / 22 °C;

10 MW reduction in furnace duty; additional area: 7,805 m2

Benchmark Studies On Crude

Unit Optimisation

European

Refinery, Spain2014

Savings from operational optimisation = 0.85 MM€/yr;

Savings from medium size revamping = 2.62 MM€/year

Overall Refinery Simulation and

Optimisation

PetroChina,

China2013

Average CIT increase by 10°C after implementation,

Operating cost reduced by 1.64 MM$/year

EMC: Energy Management Contract

Implemented retrofit and new design 15 projects since 2009 considering energy efficiency improvement and yield optimisation. Summary of the latest projects:

Page 27: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

27 Centre for Process Integration © 2017

Outline1. Background

2. Heat Recovery in Crude Oil Distillation Systems

3. Case Study

4. Utility System Optimization

5. Case Study

6. Concluding Remarks

Page 28: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

28 Centre for Process Integration © 2017

Utility system – the scopeDet går inte att visa bilden för tillfället.

Page 29: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

29 Centre for Process Integration © 2017

Process integration in utility system• Utility system accounts for 20% to 30% of total energy

consumption in oil refineries

Technically, utility system is the most energy consuming process in a refinery

How can process integration technologies come to help?

Page 30: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

30 Centre for Process Integration © 2017

Page 31: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

31 Centre for Process Integration © 2017

Page 32: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

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Det går inte att visa bilden för tillfället.

Comprehensive utility system modeling and optimization

● Pipeline model with existing modeling and optimization technologies:

A large mixer

Page 33: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

33 Centre for Process Integration © 2017

• In practice, the pipeline is a complex network. It has issues such as flow direction, pressure drop and heat loses etc.

Comprehensive utility system modeling and optimization

Page 34: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

34 Centre for Process Integration © 2017

Outline1. Background

2. Heat Recovery in Crude Oil Distillation Systems

3. Case Study

4. Utility System Optimization

5. Case Study

6. Concluding Remarks

Page 35: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

35 Centre for Process Integration © 2017

CASE STUDYCarried out by Process Integration Ltd

Page 36: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

36 Centre for Process Integration © 2017

Case study – Project background

• A Sinopec refinery that processes 5,000,000 tons of crude oil per year

• Site power demand is about 50MW• Site MP consumption: 210-240t/h• Site LP consumption: 170-210t/h

Page 37: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

37 Centre for Process Integration © 2017

Case study – Analysis & Diagnosis• Mathematical data reconciliation verified site level steam

balance• Flowrate for some streams without flow measurement

instruments estimated based on data reconciliation• Reconciled letdown flowrate proven to be greater than

previous estimates. Still scope to reduce the letdown

Page 38: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

38 Centre for Process Integration © 2017

System modelling using i-Steam

Page 39: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

39 Centre for Process Integration © 2017

Case study – Operational optimisation• Overall, 3.1% of total operating cost can be saved with

operational optimisation– Optimisation operational strategies provided for the CHP, saving 1.7%

of total operating cost– Optimising MP system pressure could save 0.4% of total operating

cost– Optimising LP system pressure could save 1.0% of total operating cost

Page 40: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

40 Centre for Process Integration © 2017

Case study – Retrofit optimisation• Additional 3.8% of total operating cost can be saved with

small scale retrofit– Easy to fit pipe retrofit with in the sulphur recovery and FCC processes

(0.8% saving)– Fixing a unit in a FCC WHB (1.3% saving)– Very small retrofit to the existing low temperature heat recovery system

(1.7%)

Page 41: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

41 Centre for Process Integration © 2017

Track record on Utility studiesYear Project Saving (US M$/yr) Saving in % Pay back

months2008 Operational optimisation for site utility system 13.7 7% -

2008 Operational optimisation for site utility system 2.4 5% -

2008 Operational optimisation for site utility system 4.6 3% -

2009 Operational optimisation for site utility system 2 2% -

2009 Operational optimisation for site utility system 7.5 5% -

2009 Operational optimisation for site utility system 0.65 -

2010 Operational and retrofit study for site utility system 4 8% 14

2011 Operational optimisation for site utility system 0.67 7% -

2012-2013 Driver configuration design - New refinery 6.8-13.7 1.5-3%

2013-2015Operational optimisation for site utility system 1.85 3% -

Retrofit designs 2.27 4% 6

2015-2016 Total site utility project 2.1 5%

2015-2016 Online operational optimisation - ongoing

Page 42: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

42 Centre for Process Integration © 2017

Outline1. Background

2. Heat Recovery in Crude Oil Distillation Systems

3. Case Study

4. Utility System Optimization

5. Case Study

6. Concluding Remarks

Page 43: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

43 Centre for Process Integration © 2017

Where do we stand?• Significant progress has been made in

developing and applying new methodologies for process integration in petroleum refining. heat recovery in crude oil distillation

systems utility systems

• BUT, retrofit remains a significant problem.

• Obtaining cost effective retrofits is still our biggest challenge in heat recovery. Not just new equipment, but minimize piping

modifications and civil engineering

Page 44: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

44 Centre for Process Integration © 2017

Layout and Retrofit

First floor

Ground floor

Reallocated

Additional areaNew exchangers

Removed exchangers

• Need to find more effective ways to include layout constraints in the retrofit decision making.

Page 45: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

45 Centre for Process Integration © 2017

Additional Area and Retrofit• Retrofit often requires additional area around the network

including places other than where the network structure is to be modified.– can be expensive (especially pipework and civil engineering)

• Need to find cost effective ways to achieve this.Heat Transfer Enhancement

Page 46: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

46 Centre for Process Integration © 2017

Crude oil fouling

• Need to be able to model the fouling– Laboratory measurements not relevant– Every crude oil (and crude mix) is different

• Include fouling models in design, retrofit and operational optimization.

Page 47: Process Integration in Petroleum Refineries - iea-industry.org · Process Integration in Petroleum Refineries - A Perspective and Future Trends

47 Centre for Process Integration © 2017

Thank you!