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    REVERSE OSMOSIS TECHNOLOGYREVERSE OSMOSIS TECHNOLOGY

    FOR WATER TREATMENTFOR WATER TREATMENTAND WASTEWATER RECYCLINGAND WASTEWATER RECYCLING

    RANJEET CHOWDHARYRANJEET CHOWDHARYFontus Water Ltd.Fontus Water Ltd.

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    WHY TREAT WATER.WHY TREAT WATER.

    Water scarcityWater scarcityIncreased level of contaminantsIncreased level of contaminantsDepletion of natural sourceDepletion of natural sourceIncreasing cost of Water Increasing cost of Water Availability of refined technologiesAvailability of refined technologiesCost reduction in different areasCost reduction in different areas

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    OverviewOverview

    The Membrane Filtration SpectrumThe Membrane Filtration SpectrumMembrane products and configurationsMembrane products and configurationsRORO -- Basics, Equations, TerminologiesBasics, Equations, TerminologiesRO System DesignRO System DesignEquipment and InstallationsEquipment and Installations

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    M icrofiltrationM icrofiltration

    Separation mechanism based on pore size of Separation mechanism based on pore size of 00..11 toto 11 micronmicronPressure requirements independent of osmoticPressure requirements independent of osmotic

    pressure of solutionpressure of solutionUsually fullUsually full- -flow rather than crossflowflow rather than crossflow

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    Feed

    Macromolecules

    Ions

    Suspended Particles

    Concentrate

    Product

    Water Flow

    M icrofiltrationM icrofiltration

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    U ltrafiltrationU ltrafiltration

    Separation mechanism based on pore sizeSeparation mechanism based on pore sizeof up toof up to 0 0..11 micronmicronPressure requirement independent of Pressure requirement independent of

    osmotic pressureosmotic pressureCrossflow filtration to provide sweeping flowCrossflow filtration to provide sweeping flowat membrane surfaceat membrane surface

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    U ltrafiltrationU ltrafiltration

    Feed

    MacromoleculesIons

    Concentrate

    Product

    Water Flow

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    N anofiltrationN anofiltration

    Minimum size rejected on order of oneMinimum size rejected on order of onenanometer nanometer Between RO and UFBetween RO and UF

    Operates at ultralow pressureOperates at ultralow pressureSelective permeation of ionic salts and smallSelective permeation of ionic salts and smallsolutessolutes

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    Feed

    Macromolecules

    Monovalent Ions

    Concentrate

    Product

    Water Flow

    Polyvalent Ions

    N anofiltrationN anofiltration

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    Membrane ProcessMembrane ProcessCharacteristicsCharacteristics

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    R everse OsmosisR everse Osmosis

    Fundamentals of M

    embranes andR

    everse OsmosisFundamentals of M

    embranes andR

    everse Osmosis

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    R everse OsmosisR everse Osmosis

    Application of pressure greater than osmoticApplication of pressure greater than osmoticpressure of solutionpressure of solutionDiffusion of water but not salt through aDiffusion of water but not salt through a

    semipermeable membrane in directionsemipermeable membrane in directionopposite of natural flowopposite of natural flowCrossflow filtration to sweep awayCrossflow filtration to sweep awayconcentrated saltsconcentrated salts

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    M ajor DesalinationM ajor DesalinationProcessesProcesses

    Raw Water Salt Concentration (mg/l)Raw Water Salt Concentration (mg/l)

    Ion Exchange

    Electrodialysis

    Distillation

    TAP WATER Elements

    BRACKISH WATER Elements

    SEA WATER Elements

    SW HR

    600

    10,000

    1,00050Reverse Osmosis

    300

    50

    50 10,000

    40,000

    50,000

    20,000

    10,000

    2,000

    50,000

    100100,,0000001010

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    R everse OsmosisR everse Osmosis

    Feed

    Ions

    Concentrate

    Product

    Water Flow

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    REVERSE OSMOSIS REVERSE OSMOSIS

    What is reverse osmosisWhat is reverse osmosisWhat quality of water can be obtainedWhat quality of water can be obtainedMaintenance and operating costMaintenance and operating costOther advantagesOther advantagesDisadvantageDisadvantage

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    WHAT IS REVERSE OSMOSIS WHAT IS REVERSE OSMOSIS

    Reverse OsmosisReverse Osmosis is a modern processis a modern processtechnology by which water of high solutetechnology by which water of high soluteconcentration is forced to flow through aconcentration is forced to flow through asemisemi- -permeable membrane to the side of lowpermeable membrane to the side of lowsolute concentration.solute concentration.

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    What is semiWhat is semi- -permeable?permeable?

    SemiSemi- -permeable refers to a membranepermeable refers to a membranethat selectively allows certain speciesthat selectively allows certain species

    to pass through it while retainingto pass through it while retainingothers.others.

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    Reverse OsmosisReverse Osmosis PrinciplePrinciple

    Conc

    Dilute Conc

    Dilute

    OsmosisOsmosis ReverseReverseOsmosisOsmosis

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    MEMBRANE PROCESSMEMBRANE PROCESS

    FEEDFEED PERMEATEPERMEATE

    CONCENTRATECONCENTRATE

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    RO Membrane SeparationRO Membrane SeparationMechanismMechanism

    Concentrated

    Salts

    FEED

    FLOWH2OH2O

    H2O

    H2O Mg

    Cl

    Fe++

    HCO 3 Ca

    SO 4Na+

    ++

    ++

    Membrane

    Pressure

    H2O H2OH2O

    H2O H2OH2O

    Permeate

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    RO Spiral Wound ElementRO Spiral Wound ElementSchematicSchematic

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    M embranes Products andM embranes Products andConfigurationsConfigurations

    M embranes Products andM embranes Products and ConfigurationsConfigurations

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    M embrane M aterialsM embrane M aterials

    Cellulose Acetate (CA)Cellulose Acetate (CA)

    Polyamide (PA)Polyamide (PA)

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    Typical MembraneTypical MembranePropertiesProperties

    ol te MembraneP Membrane

    oi m 8 99 9 99

    lori e 8 99 9 99

    alci m 9 99+ 98 99+

    Ma nesi m 9 99+ 98 99+

    lpate 9 99+ 98 99+

    arbonate 9 99+ 98 99+

    on cti it 8 99 97 99ilica 8 9 98+

    ases

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    Reverse OsmosisReverse Osmosis

    ParameterParameter ValueValue

    PHPH 33 1010TemperatureTemperature < < 4545 CC

    TurbidityTurbidity < < 11..00 NTUNTU

    Silt density indexSilt density index < < 44..00

    Oil & greaseOil & grease NilNil

    Free chlorineFree chlorine < < 00..0101 mg/lmg/l

    Fe, MnFe, Mn

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    TREATMENT SCHEMEFOR REVERSE OSMOSIS

    Dosingtank

    RawWater Tank

    Water

    Cart-ridgefilter

    MG

    F

    RO

    Reje

    ct

    DosingTank

    Treatedwater

    N aOH

    RWP

    SBS,SH M P,

    HCl

    HPP

    ACF

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    Impurities in Water Impurities in Water

    IonicIonicNon IonicNon IonicParticulateParticulate

    MicrobiologicalMicrobiologicalGasesGases

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    R O R emovesR O R emoves

    IonicIonicNon ionicNon ionicParticulateParticulateMicrobiologicalMicrobiological

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    R everse Osmosis:R everse Osmosis:What It Can DoWhat It Can Do

    Remove purified water from a feedRemove purified water from a feedstream (permeate)stream (permeate)Concentrate chemicals in a feedConcentrate chemicals in a feedstream (reject)stream (reject)Selectively separates small ionsSelectively separates small ionsand moleculesand molecules

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    Reverse Osmosis:Reverse Osmosis:What It Cannot DoWhat It Cannot Do

    Cannot concentrate toCannot concentrate to 100 100%%Cannot separate toCannot separate to 100 100%%

    Cannot reject gasesCannot reject gasesAnd isAnd isNot always the most cost effectiveNot always the most cost effective

    methodmethod

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    Factors Which AffectFactors Which AffectPerformance of M embranesPerformance of M embranes

    Feedwater PressureFeedwater PressureFeedwater TemperatureFeedwater TemperatureFeedwater ConcentrationFeedwater ConcentrationIncreased RecoveryIncreased Recovery

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    Comparative PropertiesComparative Properties

    Property CA Membrane PA Membrane

    Advantages Forgiving High RejectionLower Energy

    DisAdvantagesHigher Pressure Low Cl2 Tolerance

    Higher Energy High FoulingpH Sensitive

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    R ule of ThumbR ule of Thumb

    100100 ppm TDS ~ppm TDS ~ 1 1 psi osmotic pressurepsi osmotic pressure11,,000000 ppm TDS ~ppm TDS ~1010 psi osmotic pressurepsi osmotic pressure

    3535,,000000 ppm TDS ~ppm TDS ~350350 psi osmotic pressurepsi osmotic pressure

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    Pressure Driven M embranePressure Driven M embraneProcessesProcesses - - PressuresPressures

    MembraneMembrane Typical OperatingTypical OperatingProcessProcess Pressure RangePressure Range

    (PSI)(PSI)Reverse OsmosisReverse Osmosis

    seawater seawater 0000 -- 12001200brackish water brackish water 100 100 -- 600600

    NanofiltrationNanofiltration 50 50 -- 225225UltrafiltrationUltrafiltration 30 30 -- 100100MicrofiltrationMicrofiltration 2 2-- 4545

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    M embrane ConfigurationsM embrane Configurations

    M embrane ConfigurationsM embrane Configurations

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    Spiral Wound R everse OsmosisSpiral Wound R everse Osmosis

    Brine Channel Spacer

    ProductWater

    MembranesPermeat e

    Channel Spacer

    Water Flow

    Feed

    Brine

    Brine

    ProductWater

    Brine Seal

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    System DesignSystem Design

    System DesignSystem Design

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    OverviewOverview

    Goal of System DesignGoal of System DesignSimplified Overview of SystemSimplified Overview of SystemDifferent Types of ConfigurationsDifferent Types of ConfigurationsElement SelectionElement SelectionOther Factors to be Aware Of Other Factors to be Aware Of Finding Out Customers NeedsFinding Out Customers NeedsFactors Affecting RO PerformanceFactors Affecting RO PerformanceMembrane Company ProjectionsMembrane Company Projections

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    R O Pretreatment OptionsR O Pretreatment Options

    Suspended Solids RemovalSuspended Solids RemovalClarificationClarificationFiltrationFiltration

    Primary Membrane UF/MF/EDRPrimary Membrane UF/MF/EDRControl of biological activityControl of biological activity

    Chlorination/dechlorinationChlorination/dechlorinationChloraminesChloramines

    Non Oxidising BiocidesNon Oxidising BiocidesUltraviolet LightUltraviolet Light

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    R O Pretreatment OptionsR O Pretreatment Options

    Scale control & pH adjustmentScale control & pH adjustmentAntiscalant AdditionAntiscalant Addition

    Acid AdditionAcid AdditionIon ExchangeIon Exchange

    PretreatmentPretreatment

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    R O Systems DesignR O Systems Design

    Module (Element): Contains MembraneModule (Element): Contains MembraneTube:Tube: Modules in Series (Modules in Series (1 1 -- ))Stage:Stage: Set of Tubes in ParallelSet of Tubes in ParallelArray:Array: No. of Stages, Tubes/StageNo. of Stages, Tubes/StageTrain:Train: Set of all of the AboveSet of all of the Above

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    System DesignSystem DesignIntroductory R emarksIntroductory R emarks ..

    System supplier System supplier

    GoalGoal : : Minimize feedMinimize feedpressure and membrane costspressure and membrane costswhile maximizing salt rejectionwhile maximizing salt rejectionand recoveryand recovery

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    ConfigurationConfigurationTypes/TerminologyTypes/Terminology

    Array / StageArray / StageAn Array is a series of parallel vessels withAn Array is a series of parallel vessels withcommon feed, product and reject linescommon feed, product and reject lines

    PumpPump

    RecycleRecyclePermeatePermeate

    ConcentrateConcentrate

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    ConfigurationConfigurationTypes/TerminologyTypes/Terminology

    DoubleDouble- -pass = Permeate Stagedpass = Permeate StagedRefers to configuration where permeate fromRefers to configuration where permeate fromfirst array passes as feed to another arrayfirst array passes as feed to another array

    PumpPump

    FeedFeedWater Water

    ConcentrateConcentrate(drain)(drain)

    ConcentrateConcentrate(sidestream)(sidestream)

    PermeatePermeatePassPass 1 1 PassPass 2 2

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    SingleSingle Module SystemModule System

    Use if flow rate is lowUse if flow rate is lowUse for low recoveryUse for low recovery

    PumpPumpConcentrateConcentrate

    PermeatePermeate

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    SingleSingle- -Array with ParallelArray with ParallelConfigurationConfiguration

    Flow rate can be higher than inFlow rate can be higher than insinglesingle- -modulemoduleUse for low recoveryUse for low recovery

    PumpPump

    ConcentrateConcentrate

    PermeatePermeate

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    M ultiM ulti--Array Array

    7 57 5% recovery% recoveryUse for higher recoveryUse for higher recoveryUse as way to increase recoveryUse as way to increase recovery

    PumpPump

    ConcentrateConcentrate

    PermeatePermeate

    ConcentrateConcentrate

    ((22 Array)Array)

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    M ultiM ulti--Array Array

    ~~ 55% recovery% recoveryReject from first array feeds intoReject from first array feeds into

    second arraysecond array

    PumpPump

    PermeatePermeate

    ConcentrateConcentrate((33 Array)Array)

    l d ll d l

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    R ecirculation and R ecycleR ecirculation and R ecycle

    Way to increase recovery byWay to increase recovery byrecirculating reject to increase feedrecirculating reject to increase feedflowflow

    PumpPump

    RecycleRecyclePermeatePermeate

    ConcentrateConcentrate

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    Double Pass andDouble Pass andPermeate StagedPermeate Staged

    Permeate from first array goes intoPermeate from first array goes intoanother arrayanother arrayUse when standard permeate quality isUse when standard permeate quality is

    not sufficientnot sufficient

    PumpPump

    FeedFeedWater Water

    ConcentrateConcentrate(drain)(drain)

    ConcentrateConcentrate(sidestream)(sidestream)

    PermeatePermeatePassPass 1 1 PassPass 2 2

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    E lement SelectionE lement Selection

    Element Grade vs. Feed TDSElement Grade vs. Feed TDS

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    E lement SelectionE lement Selection

    Element Grade vs. Salt RejectionElement Grade vs. Salt Rejection>> 00% TW% TW>> 55% BW% BW>> % SW% SW>> % SW/HR% SW/HR

    Dow Filmtec Information

    E l S l iE l S l i

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    E lement SelectionE lement Selection

    Element Grade vs. Feed PressureElement Grade vs. Feed Pressure300300 psipsi TWTW600600 psipsi BWBW

    11,,000000 psipsi SW, SW/HRSW, SW/HRDow Filmtec Information

    E l S l iE l S l i

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    E lement SelectionE lement Selection

    LengthLengthNeeded recoveryNeeded recoveryAvailable spaceAvailable space

    Diameter Diameter

    Required permeate flowRequired permeate flow Element Diameter Element Diameter

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    Pressure Drop by VesselPressure Drop by Vessel

    Total Pressure Drop = 20 psi

    3-5 psi Pressure Drop per element

    400

    psi

    30

    psi

    3 5psi

    3 5psi

    3 0psi

    Oth F t t b A fOth F t t b A f

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    Other Factors to be Aware of..Other Factors to be Aware of..

    One to seven elements per pressureOne to seven elements per pressurevesselvesselMaximum feed flowMaximum feed flow physical limitationsphysical limitations

    Minimum brine flow or maximum ratio of Minimum brine flow or maximum ratio of permeate flow to feed flowpermeate flow to feed flow concentrationconcentrationpolarizationpolarizationRecoveryRecovery

    Oth F t t b A fOth F t t b A f

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    Other Factors to be Aware of..Other Factors to be Aware of..System Design GuidelinesSystem Design Guidelines

    Fouling and/or scaling tendency of feedFouling and/or scaling tendency of feedmost influences system designmost influences system designTendency for fouling increases withTendency for fouling increases with

    increasing permeate flux and increasingincreasing permeate flux and increasing

    element recoveryelement recoveryOnly experience can set limits onOnly experience can set limits onpermeate flux and element recovery for permeate flux and element recovery for specific feedspecific feed

    Use system design guidelines whenUse system design guidelines whenprevious experience is not availableprevious experience is not available

    Oth F t t b A fOth F t t b A f

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    Other Factors to be Aware of Other Factors to be Aware of Specification Flow Rate vs.Specification Flow Rate vs.Actual Flow Rate of ElementActual Flow Rate of Element

    Specification performance vs. actualSpecification performance vs. actualperformanceperformanceActual performance depends onActual performance depends on

    operation condition such asoperation condition such astemperature changes, water chemistry,temperature changes, water chemistry,and system designand system design

    Oth F t t b AOth F t t b A

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    Other Factors to be AwareOther Factors to be Awareof..of..

    Fouling factor conceptFouling factor conceptBWBW 11..00 initial to .initial to . 5 5 inin 33 yearsyearsSWSW 11..00 initial to .initial to . in in 33 yearsyears

    Factors Which AffectFactors Which Affect

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    Factors Which AffectFactors Which AffectPerformance of MembranesPerformance of Membranes

    PretreatmentPretreatmentFeedwater TemperatureFeedwater TemperatureFeedwater Concentration andFeedwater Concentration and

    analysisanalysisRecoveryRecovery

    What FO N TU S Offers ?What FO N TU S Offers ?

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    What FO N TU S Offers ?What FO N TU S Offers ?

    Total Water ManagementTotal Water ManagementSingle source responsibilitySingle source responsibilityConsistent QualityConsistent QualityAssured PerformanceAssured PerformanceMinimized RiskMinimized RiskReturn on InvestmentReturn on InvestmentValue added ServicesValue added ServicesUtility management (O&M)Utility management (O&M)

    Objectives & ConsiderationsObjectives & Considerations

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    Objectives & ConsiderationsObjectives & Considerations

    Consistent complianceConsistent complianceMinimizing operating costsMinimizing operating costsMinimizing wasteMinimizing wasteMinimizing energyMinimizing energyLower maintenanceLower maintenance

    Bottle N ecksBottle N ecks

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    Bottle N ecksBottle N ecks

    Physical impuritiesPhysical impurities Colour, Odour Colour, Odour

    High BOD & COD.High BOD & COD.

    High dissolved solids.High dissolved solids.

    Bacterial contamination.Bacterial contamination.

    SolutionSolution

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    Solution...Solution...

    FO N TU S offers Cutting E dge TechnologyFO N TU S offers Cutting E dge Technologyto overcome these bottle necks using:to overcome these bottle necks using:

    M icrofiltrationM icrofiltrationU ltrafiltrationU ltrafiltrationN anofiltrationN anofiltrationR everse OsmosisR everse OsmosisIon Ex changeIon Ex changeprocessprocess

    PackagePackage

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    PackagePackage

    Sewage Treatment PlantSewage Treatment Plant

    Simplicity of designSimplicity of designValue for moneyValue for moneyEasy to installEasy to install

    Proven performance andProven performance andReliabilityReliabilityBest suited for small industrialBest suited for small industrial

    units and small communityunits and small community

    sewagesewage

    STP Performance DataSTP Performance Data

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    S.No.

    Characteristics Influent TreatedSewage

    1 pH 6.5 7.5 6.5 7.5

    2 Biological o x ygendemand (BOD)

    350 400 mg/l 20 30mg/l

    3 Chemical o x ygendemand (COD)

    500 600 mg/l 1 50 200mg/l

    4 Suspended Solids(SS)

    250 mg/l 20 50mg/l

    STP Performance DataSTP Performance Data

    TREATMENT SCHEME

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    TREATMENT SCHEMEFOR RECYCLE

    Effluenttreatment

    plant

    Effluent

    UF RO feedtank

    Cart-ridgefilter

    ACF

    RO

    Reject

    DGBlower

    Recycledwater

    N aOH

    By passflow RO reject

    For irrigationTDS < 2100 ppm

    By passflow

    SBS,

    SH M P,HCl

    HPP

    Reject to ETP

    FO N TU S WAT ER LIMI TE DFO N TU S WAT ER LIMI TE D

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    FO N TU S WAT ER LIMI TE DFO N TU S WAT ER LIMI TE D

    OrganizationOrganization

    Established inEstablished in 20012001Market leaders in the field of water andMarket leaders in the field of water and

    waste water treatmentwaste water treatment

    Established new trend of packaged water Established new trend of packaged water and waste water plants.and waste water plants.Supplied more thanSupplied more than 3500 3500 systems.systems.Client base of more thanClient base of more than 2500 2500ISOISO 001001::20002000 CompanyCompany

    ProductsProducts SystemsSystems

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    ProductsProducts SystemsSystems

    Treatment Plants for:Treatment Plants for:Drinking water Drinking water Municipal WasteMunicipal Waste

    Water Water

    Industrial WasteIndustrial WasteWater Water MembraneMembrane

    DesalinationDesalination

    Recycling of WasteRecycling of WasteWater Water

    ServicesServices

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    ServicesServices

    Process knowProcess know- -howhowDesign & detail EngineeringDesign & detail EngineeringSupply, Construction & InstallationSupply, Construction & Installation

    Personnel TrainingPersonnel TrainingTurnTurn- -key Plantskey PlantsAfter Sales serviceAfter Sales serviceOperation & MaintenanceOperation & Maintenance

    Waste Water TreatmentWaste Water Treatment

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    Waste Water TreatmentWaste Water Treatment

    E ffluent Treatment Plantfor the following sectors:

    Sugar Te x tiles

    Tannery Paper Distillery OthersSewage Treatment Plants

    How to reachHow to reach

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    How to reachHow to reachFO N TU S WAT ER ?FO N TU S WAT ER ?

    FONTUS WATER LTDFONTUS WATER LTD1010TH FLOOR, BLOCKTH FLOOR, BLOCK- -BB5050, CHOWRINGHEE ROAD, CHOWRINGHEE ROAD

    KOLKATAKOLKATA 7 00 7 17 00 7 1Voice:Voice: 00 100 1 ((3333)) 400343 7 400343 7 MOBILE:MOBILE: 0 33 2 310 33 2 31

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    Q UE ST ION S T IMEQ UE ST ION S T IME

    Q UE ST ION S T IMEQ UE ST ION S T IME