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1. Signs of a chemical reaction2. Chemical vs. Physical reaction3. Symbols used in chemical reactions4. Synthesis5. Decomposition6. Single diplacement7. Double displacement8. Combustion
Journal Entry
• How were these rocks formed?
Signs of a chemical reaction
• Production of….
• Heat
• Light
• Gas
• Precipitate (solid formed from two liquids)
• Color change
The 55 Types of Reactions
We classify reactions into 5 categories so that we may more
easily predict the products.
NEXT
Synthesis DefinitionSynthesis reaction – 2 substances are
combined to form a single product
• Combination reactions may also be called composition or synthesis reactions.
A + B AB
+ MENU
Synthesis Examples
2Mg + O2 2MgOMagnesium and oxygen combine to form
magnesium oxide.
2H2 + O2 2H2OHydrogen and oxygen combine to form
dihydrogen monoxide (water)
MENU
Synthesis Demonstration
Zinc + Sulfur Zinc Sulfide
Zn + S ZnS
Observations:
Decomposition Definition
Decomposition reaction – A single compound is broken down into 2 or more products.
AB A + B
+MENU
Decomposition Examples
2NaCl(s) 2Na(s) + Cl2(g)
Sodium chloride (table salt) decomposes into sodium and chlorine gas.
CaCO3 CaO + CO2
Limestone (CaCO3 ) decomposes into lime (CaO) and carbon dioxide.
MENU
Decomposition
2 H2O 2H2 + O2
Water decomposing into hydrogen gas and
oxygen gas.
Decomposition of H2O2MENU
Decomposition Demonstration
C12H22O11 + H2SO4 → C + H2O + SO2
(balance this!)
Sugar + Sulfuric acid Pure carbon + Water + Sulfur dioxide
Observations:
Decomposition Demonstration
• 2 NaHCO3 --> Na2CO3 + H2O + CO2
Observations:
Massinitial
Massfinal
Combustion Definition
Combustion reaction – Hydrogen or a hydrocarbon (H and C) burn in oxygen to produce water and carbon dioxide. Heat is given off as energy.
CxHx + O2 XH2O + XCO2
MENU
Combustion Examples
CH4 + 2O2 2H2O + CO2
Methane burns in oxygen to produce water and carbon dioxide.
C12H22O11 + 12O2 11H2O + 12CO2
A sugar molecule burns in oxygen to produce water and carbon dioxide.
MENU
Combustion demonstration
• Ethanol + Oxygen yields Water + Carbon dioxide
C6H12O6 + O2 H2O + CO2
Single Replacement Definition
Single Replacement reaction – A single element takes the place of an element in a compound.
A + BC B + AC
MENU
+ +
Single Replacement Examples
Mg + BeO Be + MgO
Magnesium replaces beryllium in beryllium oxide to form magnesium oxide and beryllium.
2Na + 2HCl H2 + 2NaCl
Sodium replaces hydrogen in hydrochloric acid to yield hydrogen and sodium chloride.
MENU
Single Replacement Demo.
A single replacement of Zinc metal for hydrogen in hydrochloric acid.
Zn + 2HCl H2 + ZnCl2
Double Replacement Definition
Double Replacement reaction – Elements in 2 compounds switch places to form 2 new compounds.
AB + CD AD + CB
MENU
+ +
Double Replacement Examples
MgO + BeS MgS + BeO
Oxygen and sulfur switch places to form magnesium sulfide and beryllium oxide.
Na2S + Zn(NO3)2 2Na(NO3) + ZnS
Sulfur and nitrate switch places to form sodium nitrate and zinc sulfide.
Make a Venn diagram comparing….
• Synthesis vs. Decomposition
• Single replacement vs. double replacement
What type of reaction?
• 2 H2 + O2 -- 2H20
What type of reaction?
• A + BX AX + B
What type of reaction?
AgNO3 + CuSO4 AgSO4 + CuNO3
What type of reaction is this?
• 2 HCl (aq) + Zn (s) --> ZnCl2 (aq) + H2 (g)
What type of reaction?
Counting atoms
• How many Carbons are in each of the following compounds:– CO2
– C2H6
– Na(CO3)2
– Mg(C2O)4
Warm-up
• Around the room there are _7__ pictures representing types of reactions. YOUR pictures.
• Make a list in your notebook, 1- _7__. Try to determine what type of reaction is being represented by the drawing.
Definitions
• Co-efficient: The number before an element/compound (allowed to change when balancing)– Ex: 2 H2
• Subscript: The small number after an element/compound (NEVER allowed to change when balancing– Ex: 2 H2
Sacrificial Gummy Bear
• Demonstrates:– Two types of chemical reactions– HIGHLY Exothermic energy change– Chemical energy converted into thermal,
radiant and sound energy
Chemicals used
• KClO3 - Potassium chlorate
• C12H22O11 - Sucrose
First reaction
KClO3 (s) KCl (l) + O2
What type of reaction is this?
First reaction
KClO3 (s) KCl (l) + O2
Is this reaction balanced? (Make an RT table)
First reaction
KClO3 (s) KCl (l) + O2
Balance it!
First reaction
2 KClO3 (s) 2 KCl (l) + 3 O2 (g)
First reaction
2 KClO3 (s) 2 KCl (l) + 3 O2 (g)
Second reaction
C12H22O11 + O2 (g) C (s) + CO2 (g) + H2O (g)
What type of reaction is this?
Second reaction
C12H22O11 + O2 (g) C (s) + CO2 (g) + H2O (g)
Is it balanced? (Make an R/P table)
If not, balance it! (1 min. early release if done correctly!)
Second reaction
C12H22O11 + 3 O2 9 C + 3 CO2 + 11 H2O
Balanced equation
Exothermic
• Reactions which release energy∆H = 5635 kJ
How to balance equations
• 1.) Create a “R/P” table– (Reactants vs. Products)
• 2.) Add coefficients to create equal numbers
• 3.) update the R/P table
• 4.) Change co-efficients until R = P
Pre-lab/practice
• Purpose: To generate hydrogen gas– To set norms of behavior when dealing with
acid
Norms:
Locations
• Ring stands are on top of fume hood
• Clamps are in 4A
• All other materials are on counter by sink 1
Materials
• Ring stand/clamp
• Test tube
• 1-2 pea-size chunks of Zn
• 1 bottle of HCl
Procedure
• Set up your apparatus as demonstrated
• Add the Zinc to the test tube
• Add approximately 2-4 cm of HCl to the test tube
• Cover with a small piece of aluminum foil
• Look for signs of a chemical reaction
• Allow to react for 3-4 minutes
Test
• Raise your hand when time has elapsed
• Use the flame test to look for signs of H2 gas
Clean up
• All test tubes must be cleaned out with Alconox
• Make sure that all acid is flushed with a large amount of water
• Sinks are to be totally clean
Homework reminder
• Read and take notes on pages 256-264
• Answer questions 1 and 2
• Due next class