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PLATINUM PALLADIUM PRINTING Mixing and coating emulsions: The chemicals used to make your Platinum/Palladium print come premixed. You will use a combination of 4 solutions to make your emulsion: Sensitizer #1 (1), Sensitizer #2(2), Platinum #3(Pt), and Palladium #4(Pd). These solutions are measured in drops using a specific TOTAL number of drops for a given print size with a slightly higher number of drops of metals (Pt and Pd) than sensitizers (1and 2). For certain papers 1 drop of End Run will be added to the mixture. Contrast can be controlled by adjusting the ratio of 1 and 2 within the overall total number of drops: more 1 and less 2 DECREASES contrast and more 2 and less 1 INCREASES contrast. Be aware that increasing the ratio of 2 will result in a “slower” emulsion (longer exposure time) AND using too much 2 in your emulsion can result in a “grainy” appearance. When mixing your emulsion, use a combination of platinum and palladium to take advantage of palladium’s “speed” and platinum’s “depth.” Your metal ratio should be a MAJORITY of palladium with a touch of platinum. PLEASE CONSERVE PLATINUM. Excessive use of platinum is wasteful and increasing its amount in your emulsion will result in a “slower” emulsion (longer exposure time). Please refer to the Drop Chart below for suggested emulsion mixtures. Pour you emulsion mixture onto your paper and quickly spread the liquid around with a hake brush, synthetic sable brush, or puddle pusher. Let your coated paper air dry or dry it with a hair dryer, put in a contact printer with your negative and expose. Development, clearing, and washing prints: There are a variety of developers and clearing agents that can be used for making Platinum/Palladium prints. We will be using Ammonium Citrate as our developer and EDTA as our clearing bath. Developer is premixed and is used straight. Clearing bath is 1 TBS of EDTA per quart of water. After coating and exposure your “print” is very vulnerable. Any water or other substance that comes into contact with your emulsion will dissolve that area, resulting in a blotchy print.

Platinum Palladium Printing Technical Supplement

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Page 1: Platinum Palladium Printing Technical Supplement

PLATINUM  PALLADIUM  PRINTING    Mixing  and  coating  emulsions:  The  chemicals  used  to  make  your  Platinum/Palladium  print  come  pre-­‐mixed.    You  will  use  a  combination  of  4  solutions  to  make  your  emulsion:  Sensitizer  #1  (1),  Sensitizer  #2(2),  Platinum  #3(Pt),  and  Palladium  #4(Pd).    These  solutions  are  measured  in  drops  using  a  specific  TOTAL  number  of  drops  for  a  given  print  size  with  a  slightly  higher  number  of  drops  of  metals  (Pt  and  Pd)  than  sensitizers  (1and  2).  For  certain  papers  1  drop  of  End  Run  will  be  added  to  the  mixture.    Contrast  can  be  controlled  by  adjusting  the  ratio  of  1  and  2  within  the  overall  total  number  of  drops:  more  1  and  less  2  DECREASES  contrast  and  more  2  and  less  1  INCREASES  contrast.    Be  aware  that  increasing  the  ratio  of  2  will  result  in  a  “slower”  emulsion  (longer  exposure  time)  AND  using  too  much  2  in  your  emulsion  can  result  in  a  “grainy”  appearance.    When  mixing  your  emulsion,  use  a  combination  of  platinum  and  palladium  to  take  advantage  of  palladium’s  “speed”  and  platinum’s  “depth.”    Your  metal  ratio  should  be  a  MAJORITY  of  palladium  with  a  touch  of  platinum.    PLEASE  CONSERVE  PLATINUM.    Excessive  use  of  platinum  is  wasteful  and  increasing  its  amount  in  your  emulsion  will  result  in  a  “slower”  emulsion  (longer  exposure  time).    Please  refer  to  the  Drop  Chart  below  for  suggested  emulsion  mixtures.    Pour  you  emulsion  mixture  onto  your  paper  and  quickly  spread  the  liquid  around  with  a  hake  brush,  synthetic  sable  brush,  or  puddle  pusher.    Let  your  coated  paper  air  dry  or  dry  it  with  a  hair  dryer,  put  in  a  contact  printer  with  your  negative  and  expose.    Development,  clearing,  and  washing  prints:    There  are  a  variety  of  developers  and  clearing  agents  that  can  be  used  for  making  Platinum/Palladium  prints.    We  will  be  using  Ammonium  Citrate  as  our  developer  and  EDTA  as  our  clearing  bath.        Developer  is  pre-­‐mixed  and  is  used  straight.      Clearing  bath  is  1  TBS  of  EDTA  per  quart  of  water.    After  coating  and  exposure  your  “print”  is  very  vulnerable.    Any  water  or  other  substance  that  comes  into  contact  with  your  emulsion  will  dissolve  that  area,  resulting  in  a  blotchy  print.    

Page 2: Platinum Palladium Printing Technical Supplement

1. Place  exposed  “print”  in  clean,  dry  tray.    Quickly  and  evenly  pour  developer  over  print  –  development  is  complete  after  20  seconds  or  so.  After  development,  carefully  pour  developer  back  into  its  pitcher  

 2. Prints  are  to  be  cleared  by  pouring  clearing  bath  into  the  tray  over  the  print.  

Prints  are  to  be  cleared  in  3  successive  baths  of  clearing  agent  –  5  minutes  each.    

3. Wash  prints  for  15  minutes  and  lay  on  screen  to  dry.  **      **  If  you  are  using  Canson  Vidalon  Vellum  or  Bienfang  360  you  should  set  up  your  own  wash  tray  and  monitor  the  print  as  it  washes.  These  papers  are  very  delicate  and  can  get  crumple,  ripped,  or  creased  in  the  wash  if  left  unattended.  Also,  these  papers  tend  to  curl  when  they  dry.  If  they  don’t  want  to  flatten  out  properly,  gently  steam  them  until  they  soften  slightly  and  place  them  between  two  books,  taking  care  not  to  mar  the  print  surface.    FYI:  the  kits  used  in  the  class  come  from  Bostick  and  Sullivan  (bostick-­‐sullivan.com).  They  include  the  2  sensitizing  liquids  (1  and  2),  the  two  metals  (Pt  3  and  Pd  4),  developer,  and  clearing  agent.  Currently,  they  cost  $209  and  should  make  roughly  35  8x10  prints.                                                              

Page 3: Platinum Palladium Printing Technical Supplement

Platinum  Palladium  Printing    Drop  Chart    You  may  use  the  following  chart  to  determine  your  emulsion  mixtures  for  making  platinum  palladium  prints.  Keep  in  mind  that  these  are  suggested  starting  points  and  that  your  actual  mixtures  may  vary.  Standard  sizes  are  listed  first  (followed  by  square  inches  for  that  size  –  different  print  dimensions  may  cover  a  similar  area  and  can  help  determine  mixtures),  followed  by  other  somewhat  common  sizes.  You  are  encouraged  to  add  your  own  mixes  and  sizes.  Adding  one  drop  of  End  Run  to  your  emulsion  mixture  will  help  it  spread  more  evenly  on  heavier  papers  (Bergger  COT  320,  Lana  Aquarelle,  Arches  Platine).  If  you  want  to  use  Rives  BFK  add  1  drop  of  End  Run  and  a  couple  of  drops  of  distilled  water  (roughly  15%  of  the  total  emulsion  –  about  3  drops  for  a  5x7).           Hake  Brush                  Synthetic  Brush/Puddle  Pusher    

     

Print  size  (sq.  inches)  

         1            2          3(Pt)    4  (Pd)    :    Total  

         1            2          3(Pt)    4  (Pd)    :    Total  

 4x5  (20)  

         7              0                2                  6              :          15  

         6              0                2                  5              :          13  

 5x7  (35)  

         12            0              3              11              :          26  

         10            0              3                  9              :          22  

 8x10  (80)  

         20            0              4              18              :          42  

         18            0              4              16              :          38  

   

   

 4x6  (24)  

           8              0                2                  7              :          17  

           7              0                2                  6              :          15  

 5.5x8  (44)  

       15              0                3                13          :          31  

       13              0                3                  11          :          27  

 6x9  (54)  

       16              0                3                15          :          34  

       14              0                3                  13          :          30