1
766 C. Chemical Oceanography OLR (1982) 29 (12) Surface sediment samples from the Angola, Cape Verde and Brazil basins and Vema Channel were examined to evaluate the relationship among car- bonate dissolution, abyssal hydrography and water column carbonate chemistry. At each location lysocline position was determined, carbonate satu- ration was calculated, and major deep-water mass boundaries were identified. In the Vema Channel and the Brazil Basin (western Atlantic), there is a first order correlation among lysocline position, benthic thermocline (AABW/NADW boundary), and the transition from saturation to undersatura- tion with respect to carbonate. In the eastern Atlantic, there is no noticeable benthic thermocline and the lysocline occurs significantly deeper than the saturation/undersaturation transition. Dept. of Geol., Univ. of South Carolina, Columbia, S.C. 29208, USA. 82:6018 Ullman, W.J. and R.C. Aller, 1982. Diffusion coefficients in nearshore marine sediments. Limnol. Oceanogr., 27(3):552-556. The formation resistivity factor F, necessary to calculate bulk sediment diffusion coefficients of interstitial solutes from free solution diffusion coefficients, can be estimated from ~, the sediment porosity. Empirical relationships between F and indicate that F ~ ~ 2 for unlithified marine sands or muds when ~ ~< 0.7 and that F ~ ~2.5 to ff 3 for high porosity muds when ~ ~ 0.7. Dept. of Geophys. Sci., Univ. of Chicago, 5734 S. Ellis Ave., Chicago, Ill. 60637, USA. 82:6019 Yeats, P.A. and J.M. Bewers, 1982. Discharge of metals from the St. Lawrence River. Can. J. Earth ScL, 19(5):982-992. A 2-year study found dissolved-metal concentrations 'unrelated to changes in water flow or suspended load [but] particulate A1, Fe, Mn and Zn concen- trations related to water flow.' The St. Lawrence's annual dissolved, non-detrital, and total particulate metal discharges were used 'to estimate global annual river discharges of metals to the ocean.' Non-detrital particulate fluxes were emphasized. Bedford Inst. of Oceanogr., Dartmouth, N.S. B2Y 4A2, Canada. (isz) C210. Pollution (see also E300-Effects of pollution, and F250-Waste disposal) 82:6020 Balkas, T.I., 1. Salihoglu, A.F. Gaines, M. Sunay and J. Matthews, 1982. Characterization of floating and sinking tar balls in the marine environment. Mar. Pollut. Bull, 13(6):202-205. Tar balls, according to their densities, the prevailing temperature and their degree of weathering float, sink or are washed ashore. Samples were analyzed by IR, H-nmr, GC and GC/MS; densities and hexane, benzene and methanol solubilities were measured. Weathering was investigated in terms of the losses of n-paraffinic/aromatic hydrocarbons. Middle East Tech. Univ., Mar. Sci. Dept., P.K. 28, Erdemli, Icel, Turkey. 82:6021 Barbaro, Alvise, Antonia Francescon and Bruno Polo, 1981. Fluoride distribution along chlorinity gradients in Baltic Sea waters. Finn. mar. Res., 248:129-136. Fluoride concentration was determined in coastal and inland waters of Finland and Sweden, focusing on the relationship between fluoride concentration and chlorinity; a positive linear regression between the two parameters was established. The F/C1 ratio (xl05) changed from 3000 in the lakes to 7.70 in the brackish water areas with the highest chlorinity. The fluoride levels and the F/C1 ratios were similar or slightly lower than those reported in the literature; F/CI ratios recorded in the Pojoviken were among the highest ever found in brackish water. Inst. di Biol. de Mare, Consiglio Naz. delle Ricerche, Riva 7 Martiri, 1364 A, 30122 Venezia, Italy. 82:6022 Fogelqvist, Elisabet, SOren Lagerkvist and Peter Lindroth, 1982. Petroleum hydrocarbons in the Arctic Ocean surface water. Mar. Pollut. Bull., 13(6):211-213. Concentration of petroleum hydrocarbons under the ice north of Svalbard ranges, with Kuwait crude oil as a reference, 0.1--0.6 /tg/L crude oil equivalents with respect to LMW components and 0.054).2/~g/L HMW components. Dept. of Analyt. and Mar. Chem., Univ. of Goteborg, S-412 96 Goteborg, Sweden. 82:6023 Hashimoto, Akio, Hajime Sakino, Tsutomu Kojima, Etsuko Yamagami, Saiko Tateishi and Takashi Akiyama, 1982. Sources and behavioar of dinitro- toluene isomers in seawater. War. Res., 16(6): 891-897. Isomers of dinitrotoluene (DNT) were identified in an industrial effluent discharged into Dokai Bay, Japan. From sampling along a transect, it was found that some isomers are more stable than others and that a decrease in DNT concentration cannot be

Petroleum hydrocarbons in the Arctic Ocean surface water

  • Upload
    lenga

  • View
    214

  • Download
    0

Embed Size (px)

Citation preview

Page 1: Petroleum hydrocarbons in the Arctic Ocean surface water

766 C. Chemical Oceanography OLR (1982) 29 (12)

Surface sediment samples from the Angola, Cape Verde and Brazil basins and Vema Channel were examined to evaluate the relationship among car- bonate dissolution, abyssal hydrography and water column carbonate chemistry. At each location lysocline position was determined, carbonate satu- ration was calculated, and major deep-water mass boundaries were identified. In the Vema Channel and the Brazil Basin (western Atlantic), there is a first order correlation among lysocline position, benthic thermocline ( A A B W / N A D W boundary), and the transition from saturation to undersatura- tion with respect to carbonate. In the eastern Atlantic, there is no noticeable benthic thermocline and the lysocline occurs significantly deeper than the saturation/undersaturation transition. Dept. of Geol., Univ. of South Carolina, Columbia, S.C. 29208, USA.

82:6018 Ullman, W.J. and R.C. Aller, 1982. Diffusion

coefficients in nearshore marine sediments. Limnol. Oceanogr., 27(3):552-556.

The formation resistivity factor F, necessary to calculate bulk sediment diffusion coefficients of interstitial solutes from free solution diffusion coefficients, can be estimated from ~, the sediment porosity. Empirical relationships between F and indicate that F ~ ~ 2 for unlithified marine sands or muds when ~ ~< 0.7 and that F ~ ~2.5 to ff 3 for high porosity muds when ~ ~ 0.7. Dept. of Geophys. Sci., Univ. of Chicago, 5734 S. Ellis Ave., Chicago, Ill. 60637, USA.

82:6019 Yeats, P.A. and J.M. Bewers, 1982. Discharge of

metals from the St. Lawrence River. Can. J. Earth ScL, 19(5):982-992.

A 2-year study found dissolved-metal concentrations 'unrelated to changes in water flow or suspended load [but] particulate A1, Fe, Mn and Zn concen- trations related to water flow.' The St. Lawrence's annual dissolved, non-detrital, and total particulate metal discharges were used 'to estimate global annual river discharges of metals to the ocean.' Non-detrital particulate fluxes were emphasized. Bedford Inst. of Oceanogr., Dartmouth, N.S. B2Y 4A2, Canada. (isz)

C210. Pollution (see also E300-Effec ts of pol lu t ion, and F 2 5 0 - W a s t e disposal)

82:6020 Balkas, T.I., 1. Salihoglu, A.F. Gaines, M. Sunay and

J. Matthews, 1982. Characterization of floating

and sinking tar balls in the marine environment. Mar. Pollut. Bull, 13(6):202-205.

Tar balls, according to their densities, the prevailing temperature and their degree of weathering float, sink or are washed ashore. Samples were analyzed by IR, H-nmr, GC and GC/MS; densities and hexane, benzene and methanol solubilities were measured. Weathering was investigated in terms of the losses of n-paraffinic/aromatic hydrocarbons. Middle East Tech. Univ., Mar. Sci. Dept., P.K. 28, Erdemli, Icel, Turkey.

82:6021 Barbaro, Alvise, Antonia Francescon and Bruno

Polo, 1981. Fluoride distribution along chlorinity gradients in Baltic Sea waters. Finn. mar. Res., 248:129-136.

Fluoride concentration was determined in coastal and inland waters of Finland and Sweden, focusing on the relationship between fluoride concentration and chlorinity; a positive linear regression between the two parameters was established. The F/C1 ratio (xl05) changed from 3000 in the lakes to 7.70 in the brackish water areas with the highest chlorinity. The fluoride levels and the F/C1 ratios were similar or slightly lower than those reported in the literature; F/CI ratios recorded in the Pojoviken were among the highest ever found in brackish water. Inst. di Biol. de Mare, Consiglio Naz. delle Ricerche, Riva 7 Martiri, 1364 A, 30122 Venezia, Italy.

82:6022 Fogelqvist, Elisabet, SOren Lagerkvist and Peter

Lindroth, 1982. Petroleum hydrocarbons in the Arctic Ocean surface water. Mar. Pollut. Bull., 13(6):211-213.

Concentration of petroleum hydrocarbons under the ice north of Svalbard ranges, with Kuwait crude oil as a reference, 0.1--0.6 /tg/L crude oil equivalents with respect to LMW components and 0.054).2/~g/L HMW components. Dept. of Analyt. and Mar. Chem., Univ. of Goteborg, S-412 96 Goteborg, Sweden.

82:6023 Hashimoto, Akio, Hajime Sakino, Tsutomu Kojima,

Etsuko Yamagami, Saiko Tateishi and Takashi Akiyama, 1982. Sources and behavioar of dinitro- toluene isomers in seawater. War. Res., 16(6): 891-897.

Isomers of dinitrotoluene (DNT) were identified in an industrial effluent discharged into Dokai Bay, Japan. From sampling along a transect, it was found that some isomers are more stable than others and that a decrease in DNT concentration cannot be