Pest control across the supply chain

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    Digital Re-print -May | June 2013

    Pest control across the supply chain

    www.gfmt.co.uk

    Grain & Feed Milling Technology is published six times a year by Perendale Publishers Ltd of the United Kingdom.All data is published in good faith, based on information received, and while every care is taken to prevent inaccuracies,the publishers accept no liability for any errors or omissions or for the consequences of action taken on the basis ofinformation published.Copyright 2013 Perendale Publishers Ltd. All rights reserved. No part of this publication may be reproduced in any formor by any means without prior permission of the copyright owner. Printed by Perendale Publishers Ltd. ISSN: 1466-3872

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    Protecting grain and silos from insect

    infection is an important factor to

    be aware of. Clearly millers want

    high quality, consistent grain, says Martin

    Savage, trade policy manager, National

    Association for British and Irish Millers

    (nabim), United Kingdom, but this is not

    always acknowledged by farmers.

    There are some perceptions amongst

    farmers that millers carry out a degree of

    physical cleaning of the grain after it leaves the

    farm. We do process it, by removing dust and

    foreign bodies, but the grain itself is basically

    in the same condition as when it arrives,

    says Savage. Ken Black, national account man-

    ager for rural hygiene, Bayer, United Kingdom,

    advocates a pro-active, preventative approach

    when protecting grain. This is nothing new

    and should be the case every year, however

    the need is emphasised this year given the

    lateness of the agricultural calendar this spring.

    Predictions are that 70-80 percent of

    farmers still wont have done their fabric of

    the building treatment by June, says Black.

    For this reason, we are actively promoting

    the benefits of ensuring treatments are made

    up to two months prior to harvest, ahead

    of what could be another challenging year.

    Good grain store practicesWith this in mind, Savage says that pro-

    moting good grain store practices amongst

    suppliers is very important; a factor that

    offers pay back on a number of levels.

    Primarily theres the management of the

    Pestontrolacross the supply chain

    Pest controlin storageFollowing last years poor

    harvest experiencein the United

    Kingdom, theresa clear recognition

    that every graincounts. A planned

    approach is

    proving key inmaximising outputfrom the supply

    chain1

    Gri&fd milliG tcholoG32 | may - June 2013

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    store to keep moisture and temperature

    levels down; they themselves can damage

    the grain, but they can also lead to otherproblems such as moulds and secondary

    insect infestation.

    The process for controlling this starts at

    a very early stage and begins with thorough

    store cleaning and ensuring that any residues

    of grain from the previous year are removed

    and treatments are applied where necessary.

    Black echoes Savages comments, noting

    that in a late cereals season when there are

    many other farm work pressures, there is a

    risk that good store hygiene will slip down

    the priority list, yet it must not be forgotten.

    An early application of a grain treatment

    product to the fabric of the building will

    ensure that the store is protected against

    any previous insect infestations or re-

    infestations later on in the season, says

    Black. It offers the peace of mind that

    everything is being done to protect their

    valuable stored crops.

    Savage explains that working closely withfarmers to strongly advocate the cleaning of

    the store and the measures carried out to rid

    them of any insects, prior to the grain being

    introduced at harvest is key. The penalties

    at stake are really too high not to prioritise

    these measures because our customers are

    very sensitive about pesticide residues, so we

    really encourage thorough store preparation

    in the first instance.

    He appreciates that in order to fully

    protect the grain, a treatment will need to be

    applied to the product once its in store and

    hes aware of customer concerns surround-

    ing this. That said, Savage acknowledges

    that if insecticide treatments are carried

    out properly and in accordance with the

    labels then its a reasonable and necessary

    approach.

    Thoroughly moderntreatments

    Black explains that the Maximum

    Residue Level (MRL) for deltameth-

    rin - the active contained in Bayers

    grain store treatment, K-Obiol is

    2 mg/kg. A significant advantage

    of K-Obiol is that when either of

    its formulations are applied at their

    recommended rate, the residue

    level is only 0.25 mg/kg - 8 times

    lower than the MRL.

    This is something were keen

    to communicate to millers, because

    we understand the legitimate con-

    cerns they and their customers

    have regarding pesticide residues,

    which is why, K-Obiol has been

    formulated to have such a low

    MRL, says Black.

    K-Obiol is formulated to con-

    trol a wide range of stored crop

    insects, including grain weevils, flour

    beetles, grain borers, saw-toothedgrain beetles, and flying insects too.

    Its available in two modern pyre-

    throid formulations, both containing

    the active ingredient, deltamethrin.

    K-Obiol EC25 has been formu-

    lated to treat the fabric of grain

    silos and storage facilities prior to

    the introduction of grain. K-Obiol

    EC25 can also be used as an admix-

    ture, post-harvest and will offer up

    to 12 months protection. The sec-

    ond formulation, K-Obiol ULV6,

    is also designed to be used as an

    admixture, post-harvest.

    Black explains that this treat-

    ment offers a number of key ben-

    efits. As well as having an incredibly

    low MRL, K-Obiol also offers no

    with-holding period. Other similar

    treatments commonly have a with-

    holding period of at least 90 days,

    meaning that the grain cant be

    processed until three months after

    the application. Grain treated by

    K-Obiol can be processed straight away.

    K-Obiols other key advantage lies

    within its active ingredient deltamethrin.Competitor products often contain actives

    from the organophospate chemical family,

    says Black. This is old chemistry now and

    has been heavily used over the past years.

    Some strains of beetles and weevils are now

    resistant to this and require a further applica-

    tion of a pyrethroid insecticide or fumiga-

    tion to achieve full control, heightening the

    amount of chemical applied to the grain and

    therefore increasing the residue risk.

    Peter Crowden is a specialist pest con-

    troller at Rutland Pest Control and sits

    on the NPTA (National Pest Technicians

    Association) board. Peter specialises in pest

    control on arable farms and explains that

    K-Obiol is his product of choice.

    Were confident in using both K-Obiol

    EC25 as a treatment to the fabric of the

    ImagecourtesyofAlpha

    FumigationServicesLtd

    Gri&fd milliG tcholoG34 | may - June 2013

    FEATURE

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    building and K-Obiol ULV6 as a grain

    ad-mixture, says Crowden. Deltamethrin

    does not significantly penetrate the grain,

    therefore providing confidence that the MRL

    will not be exceeded.

    Financial implicationsWhile flour millers do hold some weight

    when advising on methods of best practice,

    Crowden believes that the biggest incentive

    for growers to protect their grain is the

    financial implications associated with having

    their wheat rejected due to insect infesta-

    tions. The mere presence of insects at

    mills is unacceptable because they will make

    it through the cleaning and sieving proc-

    esses and can turn up in the final products.

    Generally speaking, the presence of any

    insect leads to rejection.

    Savage says that in the event of insects

    being present, the grain is likely to be

    returned to the farmer. Not only will he not

    get paid for that delivery, hell also have to

    cover the haulage cost. Failing that, it mightget used for animal feed and therefore

    attract a far lower price. Savage adds that

    understandably, farmers are aware of this,

    and mills do make it very clear.

    nabim and MAGB represent proces-

    sors on the boards of Red Tractor and the

    Scottish Quality Crops (SQC) so we can

    ensure that the standards focus on good

    store management and pest control. On

    a practical level, mills receiving grain with

    insect infestations would report the rejection

    to either of those assurance schemes and

    they would either carry out an immediate

    audit or it would be flagged up for the next

    annual audit.

    New infestationsCrowden highlights another financial

    implication related to insect infestation. In

    the event of new insect infestations occur-

    ring in the stored grain, it will be necessary

    to consider the use of ad-mixed insecticide

    such as, K-Obiol EC25, or K-Obiol

    ULV6. Another approach is aluminium phos-

    phide fumigation, but use of this method

    is reliant on whether or not it is permitted

    by the end markets. Fumigation is a very

    expensive option, it can often cost anything

    up to 5 per tonne. In contrast, treatment

    with K-Obiol EC25 is around 62-65 p per

    tonne and will provide up to 12 months

    protection when used as an ad-mixture,

    he says.From a pest controllers point of view,

    Crowden is in agreement with Black and

    Savage. He warns that growers need to deal

    with any pest issues before the 2013 crop

    is harvested, or face severe impairment to

    grain quality. This will result in the loss of

    grain, lost quality premiums and the pos-

    sibility of a load being rejected due to insect

    infestation.

    Supply chain strategyWith this in mind, it would appear that

    the key for success in these challenging

    times is strategy. It begins with an early,

    proactive response to preparing the grain

    store, well in advance of the harvest. It

    then continues into how farmers treat the

    grain once its in the store. The strategy

    then extends into how the growers decide

    to market their product.

    In the United Kingdom, such a strate-

    gic marketing approach is advocated by

    the cereals and oilseed rape levy board,

    the HGCA. They encourage farmers

    to market their cereal proactively and

    according to a plan, says Savage. This

    may involve selling some of the grain early

    in the season, a further quantity mid-way

    through the year and some at the end of

    the season. Essent ially this means produc-

    ers will be able to spread their price risk

    where they have the confidence that grain

    is protected for the full 12-month cycle.

    This is a win-win situation as, from a millingpoint of view, it helps to ensure a continu-

    ous supply of high-quality, insect free grain

    throughout the season.

    More inforMation:

    Website: www.pestcontrol-expert.com

    Gri&fd milliG tcholoG may - June 2013 | 35

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    We have around 100 years of

    experience in fumigating

    to disinfest ships and their

    cargoes. These days the use of phosphine

    gas in bulk grain shipments, or consign-

    ments, is not unusual, and is often seen

    as an efficient use of the ship and time,

    arranging the fumigation to take place

    during a cargos voyage, using the vessel

    itself as a mobile, floating fumigation

    chamber. However, as with on-land bulk

    grain fumigations, certain safety precautions

    must be observed to maintain a satisfacto-

    ry level of safety for all involved - the pest

    control contractor (fumigator), the ships

    crew during the voyage, and the staff

    involved in discharging the fumigated cargo

    at the final destination port. The legal and

    safety requirements are detailed in several

    official documents, which are available to

    everyone involved in this process:

    FumigationHealth and safety guidance for employ-

    ers and technicians carrying out fumigation

    operations, HSEs document ISBN 978 0

    7176 2999 2 - HSG251

    Recommendations on the safeuse of pesticides in ships

    The United Nations International

    Maritime Organisation (IMO) Safety of Life

    at Sea (SOLAS) Convention places an obli-

    gation on all governments to ensure all ship-

    ping activities are carried out safely. The use

    of pesticides includes the fumigation of cargo

    spaces and of cargo, in port, or in-transit, and

    any part of the ship so affected by their use, as

    contained in the IMOs Recommendations on

    the Safe Use of Pesticides in Ships, Applicable

    to the Fumigation of Cargo Holds

    What are the risks withphosphine fumigation?

    These two documents together are

    extensive and comprehensive. Everyone

    involved in the fumigation of bulk grain and

    other cargoes, from the loading of the vessel

    to be fumigated, to the handling of the grain/

    commodity being discharged from the vessel

    after in-transit fumigation, should be aware

    of their responsibilities to ensure it is as safe

    an activity as possible. Responsibilities vary

    with the activity during the fumigation pro-

    cedure, but everyone must take the subject

    and their part in it seriously. Perhaps because

    phosphine has been in use for several

    decades, and in general is a less equipment-

    heavy application method, many peopleinvolved tend to take it for granted and

    assume that safety is built-in to the activity.

    It is worth reminding everyone involved in

    phosphine fumigation, of the lethal potential

    of these easy-to-use little tablets and the

    other formulations:

    Phosphine gas (PH3) is never kept under

    pressure in cylinders, as methyl bromide

    used to be, because it will explode. It is gen-

    erated on-site by water vapour reacting with

    the solid metal phosphides. So you will see

    tablets similar in size to Alka Selzer. This is

    the only similarity to the effervescent antacid,

    which we all know because PH3 is a deadly

    poisonous gas.

    This is a major problem. When methyl

    bromide was in use, everyone knew it

    was a deadly gas, with lots of stories of

    workers being off work with foot or chest

    problems when the gas seeped into boots

    and wellingtons, or it was breathed in,

    undetected, damaging and sometimes lethal

    lung problems.

    With methyl bromide, we were never

    allowed to sail a vessel under gas. The

    fumigation was completed at the quayside,

    with all but a few vital crew, on-shore in

    local hotels. But times have changed (not

    necessarily for the better). I suspect it is due

    to considerable pressure from all ends of

    the grain trade, but we now regularly see

    grain cargoes travelling the oceans under

    phosphine fumigation. This situation would

    be OK if everyone involved understood

    and followed all the safety rules. But this is

    clearly not the case, as several mistakes and

    accidents have shown in recent months.

    Government safey servicesOver recent years the Health & Safety

    Executive (HSE) has greatly reduced its

    interest in and involvement with inland fumi-

    gations. During the annual BPCA Fumigation

    Diploma Course, HSE always explained the

    standards and expectations in fumigation.

    This has gradually ceased coinciding with the

    phasing out of methyl bromide. The normal

    grain trade has not seen any problems

    in fumigating grain stocks in silos and flat

    storages across the land, but we no longer

    see an HSE overview, or any HSE presence

    at all, realising finally last year that HSE no

    longer has a single specialist to advise on

    fumigations issues. They have, in association

    with the BPCA, produced and revised their

    Guidance Notes, and this is now available as

    a downloadable free publication (ISBN 978 0

    by Mike Kelly, Acheta,United Kingdom

    Image 2: Hatch cover resting where it landed

    Pest controlin transitGrains on the move are

    not immune frompest problems.

    Transportation timecan be effectivelyused to solve this

    issue, but doescome with its own

    set of challenges

    Gri&fd milliG tcholoG36 | may - June 2013

    FEATURE

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    7176 2999 2 - HSG251), very useful, but the

    physical staff are no longer there retired

    and not replaced.

    The recent accident in Northern

    Ireland, involving the vessel Arklow

    Meadow, occurred when some phosphine

    sleeves were mishandled, by being left

    on the wet deck still generating phos-

    phine gas that resulted in a large-scale

    hospitalisation of those who inhaled the

    phosphine. The investigation and brief

    report, was by the Marine Accident

    Investigation Branch of Southampton (see

    the acc ident overview).

    A few years ago HSE would have been

    the major safety service to be involved in

    situations of this nature, but in recent years

    they have lost their fumigation specialists

    through retirements. But what is the rel-

    evance of these changes? Is fumigation at sea

    any different in 2013 to what was the case

    in 2005? The answer unfortunately is yes, less

    safe, and why is as follows:

    Changes in perceptionWith the phasing out of methy l bro-

    mide, there is also a reduced level of

    understanding of the risks and hazards of

    cargo fumigations. The relevant legislation

    is still in place, and the strongly-worded

    advisory documents covering the activi-

    ties involving fumigation at sea remain ,

    but somehow grain handlers, silo opera-

    tors, shippers and exporters/importersand other traders seem to have forgotten

    the main issues. Fumigation is the use of

    a potentially deadly gas, which is usually

    significantly more dangerous to humans

    than to insects.

    Let me explain this last statement so

    there is no confusion;

    Methyl bromide would kill insects and

    humans easily, within a space of a few hours;

    the legal human safe limit was always 5 parts

    per million (ppm) for an exposure of a normalworking day, and exceptionally 15 ppm for up

    to 15 minutes. This was for a gas everyone

    knew and understood to be dangerous, and

    which was to be treated with great care and

    caution. Cargoes to be fumigated with methyl

    bromide were done either on land before

    loading, or in a ship with the crew taken off to

    a nearby hotel. No questions and no objec-

    tions, and safety was paramount, with the

    Image 1: Bulk grain loading

    Gri&fd milliG tcholoG may - June 2013 | 37

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    9/11

    HSE, IMO and Coastguard Agency all working

    to the same standard and expectation.

    Methyl bromide requires about 24 hours

    to work, occasionally up to 48 hours, then

    the cargo can be ventilated and off-loaded

    or otherwise handled.

    Phosphine is a much slower-acting fumi-

    gant, not just in its generation from solid

    metal phosphides, but also in its action on

    the target pests, particularly insects and

    mites. Despite the much higher concentra-

    tions in most cargo fumigations, insects

    and mites take days to succumb. To work

    effectively the fumigation usually extends at

    least 5-10 days. This is not just to make life

    more difficult for the grain trade, but it is a

    biological fact of insect life. Insects can often

    survive more than a week at concentrations

    which would kill humans in minutes.

    So methyl bromide works quickly,

    destroys the ozone layer, has never had a

    problem of resistance, and is safe up to 5

    ppm, and was done in-port.

    Phosphine takes days, sometimes weeks

    depending on species and temperature, has

    quite a range of species showing serious

    resistance, and is safe only up to 0.1 ppm

    (or 0.2 ppm for 15 minutes) and is usually

    done at-sea.

    Remember: Methyl bromide should

    never be used for fumigation in-transit (IMO

    Recommendations, Annex 1D).

    Weighing up the dangersIt is very easy to look at this and say that

    here is money talking. It is far too costly to

    hold a vessel in port whilst the fumigation is

    conducted and completed, over maybe 15

    days with all crew safe on shore, than to

    allow the ship to sail with a much more

    hazardous gas in use, but utilizing the

    voyage time as an important component

    to get the best fumigation done at the

    same time.

    Through most of the world, we have

    almost or actually, lost methyl bromide

    for sound environmental reasons, but

    the simple tablet or sachet or plate

    generating phosphine gas is generating

    a gas more lethal to humans than many

    people realise. Not quite completed

    fumigation sleeves left on a wet deck

    could easily kill people. Working in a

    hold before all gas has been vented and

    a genuine clearance certificate issued by

    a technically knowledgeable fumigator,

    could be the last work a person does.

    Phosphine really is a more danger-

    ous gas than

    methyl bromide

    was, though

    all fumigantsare hazardous

    to man. The

    human safe

    limit of 0.1 ppm

    compared to 5

    ppm tells it all,

    and is not just

    a silly over-reac-

    tion. It is agreed

    throughout the

    western world,

    and the United

    States that this

    very low level

    is the only safe

    level to work to.

    My concern

    is to see work-

    ers not taking the

    tablets , sachets

    and sleeves and

    plates seriously,

    just because they

    look innocuous.

    We dont need a

    lot of scientific detail,

    about the differencesbetween these formulations - they all pro-

    duce Phosphine - sometimes quicker, some-

    times slower, but it is always a toxic hazard

    to man, and correct actions are needed to

    keep everyone involved safe.

    Gas detecting and measuring equipment

    must be available on board, and those who

    need to use it must have received suitable

    training. Gas testing must take place during

    the voyage to ensure that areas where crew

    members will work or sleep are free from

    dangerous levels of the gas. The ventilation

    system and procedures must provide a safe

    to handle cargo at the port of discharge,

    and usually this is managed by the profes-

    sional fumigator contracted to service the

    fumigated cargo.

    Just before I close, please also remem-

    ber that phosphine gas can self-ignite athigher concentrations, another reason to

    handle it with care and technical under-

    standing. A cargo of bulk wheat loaded

    in the south of France for Iran, when the

    cargo was very warm and the ambient

    humidity was high, blew the 20-tonne

    hatch covers off by exploding and break-

    ing the cleats. Only the derricks stopped

    the hatch fall ing into the sea, which was

    fortunately calm so no more damage was

    incurred and the vessel could return to a

    port for repairs (Images 2, 3, 4).

    Accident overview

    Release of phosphine gasalongside Warrenpoint,Northern Ireland

    On December 5, 2012, the general cargo

    vessel Arklow Meadow was discharging

    her cargo of maize alongside the timberberth at Warrenpoint, Northern Ireland.

    Fumigation retainers (socks) had been

    placed on top of her cargo before the

    vessel had sailed from Nikatera, Ukraine.

    Although the vessel had been certified to

    commence cargo operations by a shore-

    side tank inspector after he had tested

    the atmosphere in the upper parts of the

    holds, the fumigant retainers were not

    removed from the holds when discharge

    operations commenced.

    As a result, some of the fumigant retainers

    were removed by the crew and some

    were shipped into the shore hoppers. The

    retainers removed by the crew startedto smoke profusely, and a retainer burst,

    spilling its contents when it was removed

    from the hopper. The smoking retainers

    triggered a major emergency response

    situation within the port and nine people

    were taken to hospital for treatment for

    the exposure to poison.

    Provided by MAIB March2013

    More Information:

    Website : www.acheta.co.uk

    Image 4: Lightly toasted wheat! afterexplosion and surface flame in the hold

    Image 3: Testing forgas, after the event

    Fumigation specialist on vesselArklow Meadow during theemergency

    Gri&fd milliG tcholoG38 | may - June 2013

    FEATURE

  • 7/28/2019 Pest control across the supply chain

    10/11Gri&fd milliG tcholoG may - June 2013 | 39

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    www.gfmt.co.uk

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    A subscription magazine for the global flour & feed milling industries - first published in 1891INCORPORATING PORTS, DISTRIBUTION AND FORMULATION

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    May-June2013

    Kill stepvalidation oflow-moistureextrusion

    Adding value tofeed millingwith profit-oriented feed

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    Pest controlacross the supply

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