Penguard HSP ZP Com E

8/10/2019 Penguard HSP ZP Com E

http://slidepdf.com/reader/full/penguard-hsp-zp-com-e 1/6



Penguard HSP ZP E Comp A

R67 STOT SE 3, H336

See Section 16 for

the full text of the R-

phrases declared

above.

See Section 16 for

the full text of the H

statements

declared above.

Occupational exposure limits, if available, are listed in Section 8.

Type

[1] Substance classified with a health or environmental hazard

[2] Substance with a workplace exposure limit[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII[5] Substance of equivalent concern

If swallowed, seek medical advice immediately and show the container or label.Keep person warm and at rest. Do NOT induce vomiting.

Skin contact

Check for and remove any contact lenses. Immediately flush eyes with runningwater for at least 15 minutes, keeping eyelids open. Seek immediate medicalattention.

Remove contaminated clothing and shoes. Wash skin thoroughly with soap andwater or use recognised skin cleanser. Do NOT use solvents or thinners.

4.

First-aid measures

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is

irregular or if respiratory arrest occurs, provide artificial respiration or oxygen bytrained personnel.

Ingestion

Inhalation

Eye contact

:

:

:

:

First-aid measures

General In all cases of doubt, or when symptoms persist, seek medical attention. Never giveanything by mouth to an unconscious person. If unconscious, place in recoveryposition and seek medical advice.

:

Fire-fighting measures5.

Recommended: alcohol-resistant foam, CO₂, powders, water spray.Extinguishing media :

Recommendations : Fire will produce dense black smoke. Exposure to decomposition products maycause a health hazard. Appropriate breathing apparatus may be required.Cool closed containers exposed to fire with water. Do not release runoff from fire todrains or watercourses.

Extinguishing media not to

be used

: Do not use water jet.

Personal precautions Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist.Refer to protective measures listed in sections 7 and 8.

6. Accidental release measures

:

:Spill Contain and collect spillage with non-combustible, absorbent material e.g. sand,

earth, vermiculite or diatomaceous earth and place in container for disposalaccording to local regulations (see Section 13). Preferably clean with a detergent.

Avoid using solvents.

Note: see section 8 for personal protective equipment and section 13 for waste disposal.

Handling

Handling and storage7.

Prevent the creation of flammable or explosive concentrations of vapours in air andavoid vapour concentrations higher than the occupational exposure limits.In addition, the product should only be used in areas from which all naked lights andother sources of ignition have been excluded. Electrical equipment should beprotected to the appropriate standard.Mixture may charge electrostatically: always use earthing leads when transferring

from one container to another.Operators should wear antistatic footwear and clothing and floors should be of theconducting type.Keep away from heat, sparks and flame. No sparking tools should be used.

Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray ormist arising from the application of this mixture. Avoid inhalation of dust from

:

Date of issue : Page: 2/6 14.04.2014.




Storage

sanding.Eating, drinking and smoking should be prohibited in areas where this material ishandled, stored and processed.Put on appropriate personal protective equipment (see Section 8).Never use pressure to empty. Container is not a pressure vessel.

Always keep in containers made from the same material as the original one.Comply with the health and safety at work laws.Do not allow to enter drains or watercourses.Information on fire and explosion protection

Vapours are heavier than air and may spread along floors. Vapours may formexplosive mixtures with air.

When operators, whether spraying or not, have to work inside the spray booth,ventilation is unlikely to be sufficient to control particulates and solvent vapour in allcases. In such circumstances they should wear a compressed air-fed respiratorduring the spraying process and until such time as the particulates and solventvapour concentration has fallen below the exposure limits.

Store in accordance with local regulations.Notes on joint storage

Keep away from: oxidising agents, strong alkalis, strong acids.Additional information on storage conditions

Observe label precautions. Store in a dry, cool and well-ventilated area. Keep awayfrom heat and direct sunlight. Keep away from sources of ignition. No smoking.Prevent unauthorised access. Containers that have been opened must be carefullyresealed and kept upright to prevent leakage.

:

Engineering measures Provide adequate ventilation. Where reasonably practicable, this should beachieved by the use of local exhaust ventilation and good general extraction. Ifthese are not sufficient to maintain concentrations of particulates and solventvapours below the OEL, suitable respiratory protection must be worn.

8. Exposure controls/personal protection

Skin and body

Personal protective equipment

If workers are exposed to concentrations above the exposure limit, they must useappropriate, certified respirators. Use respiratory mask with charcoal and dust filterwhen spraying this product.(as filter combination A2-P2). In confined spaces, usecompressed-air or fresh-air respiratory equipment. When use of roller or brush,consider use of charcoalfilter.

Personnel should wear antistatic clothing made of natural fibres or of high-temperature-resistant synthetic fibres.

Respiratory system

:

:

:

:

Occupational exposure limits

1-methoxy-2-propanol EU OEL (Europe, 12/2009). Absorbed through skin. Notes: list

of indicative occupational exposure limit values

STEL: 568 mg/m³ 15 minutes. STEL: 150 ppm 15 minutes. TWA: 375 mg/m³ 8 hours. TWA: 100 ppm 8 hours.

There is no one glove material or combination of materials that will give unlimitedresistance to any individual or combination of chemicals.The breakthrough time must be greater than the end use time of the product.The instructions and information provided by the glove manufacturer on use,storage, maintenance and replacement must be followed.Gloves should be replaced regularly and if there is any sign of damage to the glovematerial.

Always ensure that gloves are free from defects and that they are stored and usedcorrectly.The performance or effectiveness of the glove may be reduced by physical/chemical

damage and poor maintenance.Barrier creams may help to protect the exposed areas of the skin but should not beapplied once exposure has occurred.

Hands

For right choice of glove materials, with focus on chemical resistance and time ofpenetration, seek advice by the supplier of chemical resistant gloves.

Ingredient name





Use safety eyewear designed to protect against splash of liquids.Eyes :

The user must check that the final choice of type of glove selected for handling thisproduct is the most appropriate and takes into account the particular conditions ofuse, as included in the user's risk assessment.

Physical and chemical properties9.

Physical state

Solubility

Liquid.

Insoluble in the following materials: cold water and hot water.

Characteristic.Odour

Various colours.Colour

Flash point Closed cup: 23°C (73,4°F)

:

:

:

:

:

Density : 1.8 g/cm³

Explosion limits : 1.2 - 13.1%

Stability and reactivity

Stable under recommended storage and handling conditions (see Section 7).

Hazardous decomposition products: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen.

Keep away from the following materials to prevent strong exothermic reactions: oxidising agents, strong alkalis, strongacids.

10.

Toxicological information11.

There are no data available on the mixture itself. The mixture has been assessed following the conventional method ofthe Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. See Sections 2and 15 for details.

Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result inadverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys,liver and central nervous system. Solvents may cause some of the above effects by absorption through the skin.Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases,

loss of consciousness. Repeated or prolonged contact with the mixture may cause removal of natural fat from the skin,resulting in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid maycause irritation and reversible damage. Swallowing may cause nausea, diarrhoea, vomiting, gastro-intestinal irritationand chemical pneumonia.

Based on the properties of the epoxy constituent(s) and considering toxicological data on similar mixtures, this mixturemay be a skin sensitiser and an irritant. It contains low molecular weight epoxy constituents which are irritating to eyes,mucous membrane and skin. Repeated skin contact may lead to irritation and to sensitisation, possibly with cross-sensitisation to other epoxies. Skin contact with the mixture and exposure to spray mist and vapour should be avoided.

Contains epoxy resin (MW ≤ 700), hydrocarbons, c9-unsatd., polymd.. May produce an allergic reaction.

Ecological information12.

There are no data available on the mixture itself.Do not allow to enter drains or watercourses.

The preparation has been assessed following the conventional method of the Dangerous Preparations Directive1999/45/EC and is classified for eco-toxicological properties accordingly. See Sections 2 and 3 for details.

Ecological information

Product/ingredient name Aquatic half-life Photolysis Biodegradability

Aquatic ecotoxicity

epoxy resin (MW ≤ 700) - Acute EC50 1,4 mg/l Daphnia 48 hours- Acute LC50 3,1 mg/l Fish -

fatheadminnow

96 hours

trizinc bis(orthophosphate) - Acute LC50 0,14 mg/l Fish -

Oncorhynchusmykiss

96 hours

Product/ingredient name Test SpeciesResult Exposure

Biodegradability





LogKow BCF Potential

Bioaccumulative potential

Product/ingredient name

epoxy resin (MW ≤ 700) >3 - low

n-butyl acetate 1,78 - low2-methylpropan-1-ol 0,76 - lowtrizinc bis(orthophosphate) - 60960 high

1-methoxy-2-propanol <1 - low

epoxy resin (MW ≤ 700) - - Not readilytrizinc bis(orthophosphate) - - Not readily

Disposal considerations13.

Do not allow to enter drains or watercourses. Material and/or container must be disposed of as hazardous waste.

08 01 11* Waste paint and varnish containing organic solvents or other dangeroussubstances. If this product is mixed with other wastes, this code may no longer apply.If mixed with other wastes, the appropriate code should be assigned. For furtherinformation, contact your local waste authority.

European waste catalogue

(EWC)

:

14.

International transport regulations

Paint.Proper shipping name

Packing group III

Label

:

:

:

Transport information

1263UN Number :

Class 3:

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that

persons transporting the product know what to do in the event of an accident or spillage.

Additional information

ADR / RID : Tunnel restriction code: (D/E)Hazard identification number: 30Special provisions: 640E

Emergency schedules (EmS): F-E, S-EMarine pollutant: Yes.

:IMDG

Transport in accordance with ADR/RID, IMDG/IMO and ICAO/IATA and national regulation.

Marine pollutant

substances

Solvent naphtha (petroleum), light aromatic , trizinc bis(orthophosphate):

Marking : The environmental hazardous / marine pollutant mark is only applicable forpackages containing more than 5 litres for liquids and 5 kg for solids.

Regulatory information

Irritant Dangerous for theenvironment

15.

Safety phrases S23- Do not breathe vapour / spray.S24- Avoid contact with skin.S37- Wear suitable gloves.S51- Use only in well-ventilated areas.

R10- Flammable.R36/38- Irritating to eyes and skin.

R43- May cause sensitisation by skin contact.R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environment.

Hazard symbol or symbols

Risk phrases

EU regulations

:

:

:

: The product is classified and labelled for supply in accordance with the Directive1999/45/EC as follows:





:

Additional warning

phrases

: Contains epoxy constituents. May produce an allergic reaction.

epoxy resin (MW ≤ 700)2-methylpropan-1-ol

Contains

Industrial use : The information contained in this safety data sheet does not constitute the user’sown assessment of workplace risks, as required by other health and safetylegislation. The provisions of the national health and safety at work regulations applyto the use of this product at work.

R10- Flammable.R41- Risk of serious damage to eyes.R36/38- Irritating to eyes and skin.R37/38- Irritating to respiratory system and skin.R43- May cause sensitisation by skin contact.R66- Repeated exposure may cause skin dryness or cracking.R67- Vapours may cause drowsiness and dizziness.R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in

the aquatic environment.R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environment.R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in theaquatic environment.

Full text of abbreviated R

phrases

:

Full text of abbreviated H

statements

: H226 Flammable liquid and vapour.H315 Causes skin irritation.H317 May cause an allergic skin reaction.H318 Causes serious eye damage.H319 Causes serious eye irritation.H335andH336

May cause respiratory irritation. May cause drowsiness or dizziness.

H336 May cause drowsiness or dizziness.H400 Very toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.H411 Toxic to aquatic life with long lasting effects.H412 Harmful to aquatic life with long lasting effects.

16. Other informationCEPE Classification : 1

Date of issue 14.04.2014.

Version 2

:

This Safety Data Sheet is prepared in accordance with Annex II to Regulation (EC) No 1907/2006.

:

Notice to reader

The information in this SDS is based on the present state of our knowledge and on current laws. The product

is not to be used for purposes other than those specified under section 1 without first obtaining writtenhandling instructions. It is always the responsibility of the user to take all necessary steps to fulfil thedemands set out in the local rules and legislation. The information in this SDS is meant to be a description ofthe safety requirements for our product. It is not to be considered a guarantee of the product's properties.

D t f i : Page: 6/614 04 2014

Documents

Penguard HSP ZP Com E