Page : 1 MATERIAL SAFETY DATA SHEET OCTAVEgadotagro.com/_Uploads/dbsAttachedFiles/OCTAVE_MSDS_20-2-2013… · Page : 1 MATERIAL SAFETY DATA SHEET Version : 1 Date : 20/2/2013 OCTAVE

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MATERIAL SAFETY DATA SHEET Version : 1Date : 20/2/2013

OCTAVE Supersedes : 0/0/0

Product code : 7081

SECTION 1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier : OCTAVE1.2. Relevant identified uses of the : Fungicidesubstance or mixture and usesadvised against1.3. Details of the supplier of thesafety data sheetName : FMC CHEMICAL SprlAddress : Boulevard de la Plaine, 9/3

1050 BRUXELLESBELGIQUE

Telephone number : 00 32 2 6459584Telefax number : 00 32 2 6459655E-mail : [email protected]. Emergency telephone number : 00 32 14 58 45 45

SECTION 2 HAZARDS IDENTIFICATION

2.1. Classification of the substanceor mixtureMOST IMPORTANT HAZARDSAdverse human health effects : Harmful if swallowedEnvironmental effects : Very toxic to aquatic organisms, may cause long-term adverse effects in the

aquatic environmentPhysical and chemical hazards- Fire or explosion : Not classified as flammable by EC criteriaClassification of the product : According to European regulations (67/548/EEC & 1999/45/EC), this product is

classified as :Xn; R22N; R50/53

2.2. Label elements- Symbols and indications of danger

: - HARMFUL (Xn) - DANGEROUS FOR THE ENVIRONMENT (N)- R phrases : R22 : Harmful if swallowed.

R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects inthe aquatic environment.

- S phrases : S2 : Keep out of the reach of children.S13 : Keep away from food, drink and animal feedingstuffs.S20/21 : When using, do not eat, drink or smoke.S23 : Do not breathe the gas, fumes, vapours, spray.S35 : This material and its container must be disposed of in a safe way.S46 : If swallowed seek medical advice immediately and show this container orlabel.S57 : Use appropriate container to avoid environmental contamination.

- Additional phrases : The following must appear on the label :To avoid risks to man and the environment, comply with the instructions for use

2.3. Other hazards : None, to our knowledge

FMC CHEMICAL SprlBoulevard de la Plaine, 9/3 1050 BRUXELLES BELGIQUE

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Product code : 7081

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

MIXTUREChemical nature : Fungicide based on Prochloraz manganese chlorideHazardous constituents

Substance name Contents CAS No EC No Index No No registration ClassificationProchloraz manganese chloride : 50 - 60 % 75747-77-2 278-301-3 ----- ---- Xn; R22

N; R50-53----------------------------------Acute Tox. 4 (oral) H302Aquatic Acute 1 H400Aquatic Chronic 1 H410

Further information : Full text of R and H phrases : see section 16

SECTION 4 FIRST AID MEASURES

4.1. Description of first aid measuresInhalation : Move the affected person to the fresh air

In the event of coughing and slight breathlessness:Call a doctor

Skin contact : Remove all contaminated clothing and footwearWash with soap and water

Eye contact : Rinse with plenty of water immediatelyIf irritation persists, consult an eye specialist

Ingestion : Rinse mouth out with waterNever attempt to induce vomitingCall a doctor immediately

4.2. Most important symptoms and : Irritation to skin and eyeseffects, both acute and delayed Gastro-intestinal ailment4.3. Indication of any immediate : Treat symptomatically and supportively in response to reactions of patientmedical attention and specialtreatment needed

SECTION 5 FIRE-FIGHTING MEASURES

5.1. Extinguishing mediaSuitable extinguishing media : : Foam

Carbon dioxide (CO2)Powders

Not suitable extinguishing media : : Water (the product is dangerous for the environment - do not dilute it)5.2. Special hazards arising from the : Toxic fumes are releasedsubstance or mixture5.3. Advice for fire-fighters : Isolate fire area. Evacuate downwind

Do not dispose of fire-fighting water in the environmentDo not breath fumesDo not attempt to fight the fire without suitable protective equipment :Self-contained breathing apparatusComplete protective clothing

SECTION 6 ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective : For non-emergency personnel :equipment and emergency Avoid contact with skin and eyesprocedures Do not breathe dust

For emergency responders :Do not attempt to intervene without suitable protective equipmentFor further information see section 8


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Product code : 7081

SECTION 6 ACCIDENTAL RELEASE MEASURES (continued)

6.2 Environmental precautions : Do not allow product to spread into the environmentContain the spilled material by bunding (product is hazardous for the environment)

6.3. Methods and material forcontainment and cleaning up- Recovery : Sweep up or vacuum up the product

Collect up the product and place it in a spare container suitably labelled- Disposal : Dispose of contaminated materials in accordance with current regulations6.4 Reference to other sections : For further information see section 13

SECTION 7 HANDLING AND STORAGE

7.1. Precautions for safe handlingTechnical measures : Ensure good ventilation of the work stationPrecautions : Avoid any direct contact with the product

Do not breathe dust.Smoking is forbidden

Safe handling advice : Keep away from sources of ignition.Avoid raising powdered material due to explosion hazard

Hygiene measures : Always wash your hands after handling the productDo not eat, drink or smoke during useSeparate working clothes from town clothes and launder separately

7.2. Conditions for safe storage,including any incompatibilitiesStorage conditions- Recommended : Store :

- in a cool and dry area- in a well-ventilated area- away from direct sunlight- away from food and drinks and animal foodstuffs- out of reach of children

Packaging materials- Recommended : Original packaging7.3. Specific end use(s) : No information available

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1. Control parametersOccupational exposure limits : No specific limit8.2. Exposure controlsEngineering measures : Ensure good ventilation of the work station

Extraction to remove vapours at their sourcePersonal protective equipment- Respiratory protection : In the event of insufficient ventilation :

Filtering respiratory protective device with a pesticide canister- Hand protection : Protective gloves made of PVC

Nitrile-rubber protective gloves- Eye protection : Safety goggles- Skin and body protection : Impermeable clothing


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Product code : 7081

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physicaland chemical propertiesPhysical state : PowderColour : Off-whiteOdour : slightOdour threshold : Not determinedpH : ~ 7.5 (10 g/l - 20 °C)Specific temperatures- Boiling : Not applicable- Melting point : Not applicableDecomposition temperature : Not applicableFlammability characteristics- Flash point : Not applicable- Auto-ignition temperature : Not applicableOxidizing properties : Non oxidizing material according to EC criteriaExplosion properties : Not explosiveVapour pressure : Not applicableVapour density (air = 1) : Not applicableDensity : : 270 kg/m³Solubility- in water : DispersibleOctanol/water partition coefficient : Not applicableKinematic viscosity : Not applicableEvaporation rate : Not applicable9.2 Other information : No additional information available

SECTION 10 STABILITY AND REACTIVITY

10.1. Reactivity : To our knowledge, the product does not present any particular risk10.2. Chemical stability : Stable at ambient temperature and under normal conditions of use10.3. Possibility of hazardous : Divided solid. Dust explosion possible when mixed with air.reactions10.4. Conditions to avoid : High temperature10.5. Incompatible materials : Strong oxidizing agents10.6. Hazardous decomposition : On thermal decomposition (pyrolysis), releases :products Carbon oxides (CO, CO2)

Nitrogen oxidesHydrogen chloride

SECTION 11TOXICOLOGICAL INFORMATION

11.1. Information on toxicologicaleffectsAcute toxicity : Harmful if swallowed

LD 50 oral (rat) : 1500 - 4600 mg/kgLD 50 skin (Rat) : > 2000 mg/kgLC 50 inhalation / 4h (rat) : > 2.66 mg/l(maximum attainable concentration)


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Product code : 7081

SECTION 11TOXICOLOGICAL INFORMATION (continued)

Skin corrosion/irritation : Based on available data, the classification criteria are not met.Serious eye damage/irritation : Slightly irritating to the eyes

Based on available data, the classification criteria are not met.Respiratory or skin sensitization : Does not cause sensitisationRepeated dose toxicity : No information availableCarcinogenicity : Prochloraz manganese chloride : No cancerogenic effects were notedMutagenicity : Prochloraz manganese chloride : No mutagenic effects were notedReproductive toxicity : Prochloraz manganese chloride : Tests on animals showed adverse effects on

fertility and development

SECTION 12 ECOLOGICAL INFORMATION

12.1. Toxicity : Product as is :Very toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environmentLC 50 (Fish) / 96 h : 2.4 mg/lEC 50 (Daphnia) / 48h : 4.3 mg/lProchloraz manganese chloride :EC 50 (Algae) / 72 h : 0.094 mg/l

12.2. Persistence and degradability : Prochloraz manganese chloride :Not easily biodegradableHalf-life (in soil) : 5-37 d

12.3. Bioaccumulative potential : Prochloraz manganese chloride :BCF : 200

12.4. Mobility in soil : Prochloraz manganese chloride : The product is not mobile in soil12.5. Results of PBT and vPvB : No additional information availableassessment12.6. Other adverse effects : No information available

SECTION 13 DISPOSAL CONSIDERATIONS

13.1. Waste treatment methodsWASTE FROM PRODUCTProhibition : : Discharging waste into rivers and drains is prohibitedDestruction/Disposal : Dispose of in accordance with relevant local regulations

Incinerate at a licensed installationCONTAMINATED PACKAGINGDecontamination/cleaning : Clean with waterDestruction/disposal : Dispose of in accordance with relevant local regulations

Do not re-use empty container

SECTION 14 TRANSPORT INFORMATION

14.1. UN number : 307714.2. UN proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Prochloraz

manganese chloride)14.3. Transport hazard class(es) : 914.4. Packing group : III14.5. Environmental hazards : Additional marking : "Environmentally hazardous substance"


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Product code : 7081

SECTION 14 TRANSPORT INFORMATION (continued)

14.6. Special precautions for user : No information available14.7. Transport in bulk according to : No information availableAnnex II of MARPOL73/78 and the IBCCode

SECTION 15 REGULATORY INFORMATION

15.1. Safety, health and : No additional information availableenvironmental regulations/legislationspecific for the substance or mixture15.2. Chemical Safety Assessment : A chemical safety assessment acc. to art. 14 of Regulation (EC) No 1907/2006 is

not required, because art. 15 of the same regulation applies

SECTION 16 OTHER INFORMATION

R phrases text of § 2&3 : R22 : Harmful if swallowed.R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects inthe aquatic environment.

H phrases text of § 2&3 : H302 : Harmful if swallowedH400 : Very toxic to aquatic lifeH410 : Very toxic to aquatic life with long lasting effect

Registered trademarks : : Octave and FMC are trademarks of FMC Corporation or its subsidiaries

This sheet complements the technical sheets but does not replace them. The information given is based on our knowledge of theproduct, at the time of publication. It is given in good faith.Besides, the attention of the user is drawn to the possible risk incurred by using the product for any other use than that for which itwas intended.In no way does this exempt the user from knowing and applying all the regulations controlling his activity. The user alone will takeon the responsibility for taking the precautions involved by the use of the product.The aim of all the mandatory regulations mentioned is just to help the user to fulfill his obligations regarding the use of hazardousproducts.

This information must not be considered exhaustive. It does not exempt the user from ensuring that other obligations than thosementioned could apply, related to the storage and use of the product, this being his sole responsibility.

End of document


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Page : 1 MATERIAL SAFETY DATA SHEET OCTAVEgadotagro.com/_Uploads/dbsAttachedFiles/OCTAVE_MSDS_20-2-2013… · Page : 1 MATERIAL SAFETY DATA SHEET Version : 1 Date : 20/2/2013 OCTAVE