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Precambrian Research 93 (1999) 235–258
P–T–t evolution of the Wilson Terrane metamorphic basementat Oates Coast, Antarctica
Ulrich Schussler a,*, Michael Brocker b, Friedhelm Henjes-Kunst c, Thomas Will aa Mineralogisches Institut, Universitat Wurzburg, Am Hubland, 97074 Wurzburg, Germanyb Institut fur Mineralogie, Universitat Munster, Corrensstraße 24, 48149 Munster, Germany
c Bundesanstalt fur Geowissenschaften und Rohstoffe, Postfach 510153, 30631 Hannover, Germany
Received 19 March 1998; received in revised form 24 August 1998; accepted 24 August 1998
Abstract
Within the basement of the northern Wilson Terrane at Oates Coast, a very-high-grade central zone is distinguishedfrom high-grade zones to the east and west. In the central zone, P–T estimates of 8 kbar and 800°C derive from therelic assemblage: (1) Crd+Bt+Sil+Spl+Pl+Qtz for an earlier medium-pressure granulite-facies metamorphismwhich is also documented by relic assemblages Qtz+Pl+Bt+Opx (±Grt±Cpx). A subsequent low-pressure granulite-facies to upper-amphibolite-facies stage with pervasive migmatization took place at 4–5.5 kbar and minimum 700°C,as derived from mineral reactions and thermodynamic calculations on the assemblages (2) Grt+Crd+Bt+Pl+Qtzand (3) Grt+Bt+Sil+Pl+Qtz±Spl. Decompression at still high temperatures and a clockwise directed P–T–t pathare indicated by reactions Bt+Sil+Qtz=Crd+Grt+Kfs+V and Grt+Sil+Qtz+V=Crd.
The low-pressure granulite-facies to upper-amphibolite-facies stage is dated by six nearly concordant U–Pb monaziteages of 484–494 Ma from three migmatite samples and correlates to the late Pan-African Ross Orogeny in Cambro-Ordovician times. The age of the medium-pressure granulite-facies assemblages is not constrained by geochronologicaldata. Either they form relics of the Precambrian Antarctic Craton, or they represent an early metamorphic stage ofthe Ross Orogeny. Rb–Sr and K–Ar dating on biotites yielded 470, 468, 470 Ma and 473, 469, 470 Ma (±5 Ma each),indicating the time of cooling to 450–300°C. This is confirmed by 40Ar–39Ar plateau ages of 476±2, 472±3 and470±2 Ma for these biotites.
A late tectonic pegmatite yielded a concordant U–Pb monazite age of 489±3 Ma, while slightly discordant U–Pbdata of two zircon fractions are explained by recent minor lead loss of ca 490 Ma old zircons. Cooling to ca 500–350°Cis dated to 472±2 Ma by concordant 40Ar–39Ar plateau ages of two muscovite fractions.
The cooling history of the basement from high-grade conditions to the blocking temperature of Rb–Sr and K–Arin micas took place within ca 15–20 Ma. Cooling rates of 18–25°C Ma−1 can be derived, if continuous coolingis assumed.
U–Pb data points of zircons as well as Sm–Nd whole rock model ages between 1.8 and 1.9 Ga indicate that at leastpart of the migmatites derive from Early Proterozoic crustal protoliths.
Comparing the new P–T–t data from the northern Wilson Terrane with those from the southern Wilson Terrane,a common tectono-metamorphic history becomes evident for a 600 km long sector of the Ross Orogenic belt at thePacific end of the Transantarctic Mountains, at least since the granulite-facies metamorphic event. © 1999 ElsevierScience B.V. All rights reserved.
Keywords: Age determination; Antarctica; Metamorphic evolution; Oates Coast; Ross Orogeny; Wilson Terrane
* Corresponding author. Fax: +49 931 888 4620; e-mail: [email protected]
0301-9268/99/$ – see front matter © 1999 Elsevier Science B.V. All rights reserved.PII S0301-9268 ( 98 ) 00091-6
236 U. Schussler et al. / Precambrian Research 93 (1999) 235–258
1. Introduction performed for the first time during the GermanAntarctic North Victoria Land ExpeditionsGANOVEX V and VII in 1988/89 and 1992/The Oates Coast is located at the Pacific end of
the Transantarctic Mountains (155–160°E and 93, carried out by the Bundesanstalt furGeowissenschaften und Rohstoffe (BGR,69–71°S, Fig. 1). The predominant high-grade to
very high-grade crystalline basement rocks of this Hannover).Based on the regional distribution of criticalarea form the northern part of the Wilson Terrane,
which is the westernmost of three tectonometamor- mineral assemblages, the northern part of theWilson Terrane at the Oates Coast can be sub-phic terranes of the Early Paleozoic Ross Orogen.
Prior to 1988 only a few Soviet, Australian and divided into three metamorphic, high-grade tovery-high-grade units, one of them containingNew Zealand expeditions had touched parts of the
Oates Coast area between 1958 and 1967, resulting relics of granulite-facies mineral assemblages withOpx±Cpx±Grt [Fig. 2; Schussler (1996)].in preliminary petrographic descriptions of some
outcrops ( Klimov and Soloviev, 1958; McLeod Interestingly, high-grade metamorphic rocks withsuch granulite-facies relics occur in a similar geolo-and Gregory, 1967; Sturm and Carryer, 1970).
Large-scale geological mapping and systematic gical and lithological setting in the Terra NovaBay region of the southern Wilson Terranesampling of the crystalline basement rocks were
Fig. 1. Geological sketch map of Oates Coast and North Victoria Land at the Pacific End of the Transantarctic Mountains. ProbablePrecambrian and Cambro-Ordovician lithologies of the three tectonic terranes are undifferentiated except low-grade metasedimentsof McCain Bluff (MC) and Berg Mountains (B). Post-Ordovician lithologies are omitted. Black dots denote occurrences of granulite-facies relics. WE, Western Exiles Thrust; EE, Eastern Exiles Thrust; W, Wilson Thrust.
237U. Schussler et al. / Precambrian Research 93 (1999) 235–258
Fig. 2. Sample locations and regional distribution of critical phases within the metamorphic complex of the northern Wilson Terraneat Oates Coast. All mineral assemblages occur together with quartz, plagioclase, biotite and ±K-feldspar. Thrusts are labelled likein Fig. 2. The hatched area indicates the transition between eastern and central zone. A, Mt. Archer; BM, Berg Mountains; H, HaraldBay; LM, Lazarev Mountains; MC, McCain Bluff; RK, Ringgold Knoll; TP, Thompson Peak.
(Fig. 1). Several questions arise concerning the morphic rocks from the highest-grade core of theOates Coast crystalline basement. In an attempthigh-grade basement rocks of the Oates Coast.
What were the P–T conditions of different meta- to unravel the metamorphic history, we discussthe metamorphic P–T conditions and present newmorphic stages/events? To what extent can geo-
chronological data resolve the metamorphic and geochronological data. Compared with data fromthe southern Wilson Terrane at Terra Nova Bay,cooling history? How do P–T–t data from the
Oates Coast basement match those from other our results suggest a common tectonometamorphicevolution for the high-grade metamorphic coreareas of the Wilson Terrane? In order to clarify
these questions, detailed petrological and geochro- complexes at both ends of the 600 km long NorthVictoria Land/Oates Coast sector of the Rossnological investigations were initiated. In this
paper, we concentrate on the evolution of meta- Orogenic belt.
238 U. Schussler et al. / Precambrian Research 93 (1999) 235–258
2. Geological setting Terrane is well investigated in the Terra Nova Bayarea. Here, amphibolite-facies metamorphismreached maximum temperatures of 750°C at pres-The Ross Orogeny took place at the paleo-
Pacific margin of the Precambrian Antarctic conti- sures of 3.5–5 kbar (cf Schubert and Olesch, 1989;Palmeri et al., 1991; Palmeri, 1997). U–Pb mona-nent in the Early Paleozoic as a result of accretion-
ary processes during an orthogonal plate zite, zircon and titanite ages dating the amphibo-lite-facies stage range from 490 to 480 Ma ( Kleeconvergence (Stump, 1995; Tessensohn, 1997). The
Ross Orogen is roughly traced by the present et al., 1990; Klee, 1995). K–Ar, 40Ar–39Ar andRb–Sr mica data between 480 and 440 Ma indicategeomorphologic heights of the Transantarctic
Mountains. In the area of North Victoria Land cooling of the basement down to the mica blockingtemperatures (Vita-Scaillet et al., 1994; Klee andand Oates Coast, plate convergence with a craton-
ward-directed subduction of oceanic crust led to Henjes-Kunst, in preparation). Opx–Grt-bearingrelic mineral assemblages of an earlier granulite-the accretion of the outboard Bowers and
Robertson Bay Terranes to the westernmost, facies metamorphism with Opx being in partreplaced by Ath during the subsequent amphibo-inboard Wilson Terrane [Fig. 1; Kleinschmidt and
Tessensohn (1987); Kleinschmidt et al. (1992); lite-facies metamorphic stage were found in severaloutcrops along the eastern edge of the Deep FreezeMatzer (1995)]. The Wilson Terrane is interpreted
as an active continental margin of the Antarctic Range (Fig. 1). Rocks from these outcrops containrelic structures diverging from the common RossCraton during the Ross Orogeny. It is dominated
by medium- to high-grade metamorphic rocks Orogenic direction. P–T estimates yielded ca8 kbar and 800°C for the granulite-facies stage.which were intruded by syn- to post-tectonic calc-
alkaline igneous rocks of the Granite Harbour Sm–Nd model ages between 1.8 and 2.2 Ga pointto Precambrian continental crust being involvedsuite of magmatic arc affinity (Gunn and Warren,
1962; Borg et al., 1987; Vetter and Tessensohn, in these high-grade metamorphic basement rocks(cf Talarico and Castelli, 1995). From all this1987; Armienti et al., 1990; Fenn, 1993; Schussler
et al., 1993). information, a multistage tectonometamorphic his-tory involving a Proterozoic granulite-facies eventThe high-grade metamorphic rocks of the whole
Wilson Terrane are subdivided into an eastern, followed by an amphibolite-facies event in EarlyPaleozoic time is deduced for the highest-grademedium- to high-pressure belt and a western, low-
pressure belt (Grew et al., 1984). Low-grade meta- basement rocks of the low-pressure belt in theTerra Nova Bay area (cf Talarico and Castelli,sedimentary rocks accompany the low-pressure
belt along its western margin throughout almost 1995 and references given therein).The Oates Coast area forms the northern partthe whole Wilson Terrane, but sporadically also
occur in a transition between the low-pressure and of the low-pressure belt (Schussler, 1996). Due tocompressive tectonics during Ross Orogenic ter-the medium- to high-pressure belt.
For the eastern, medium- to high-pressure belt, rane accretion, the high-grade basement rocks ofthis area were detached and thrust to the east andwhich extends from the Lanterman Range to the
Dessent Ridge (Fig. 1), upper-amphibolite-facies to the west onto low-grade metasedimentary rocksof the Wilson Terrane [Figs. 1 and 2; Flottmannmetamorphic conditions at 5–10 kbar were
deduced (cf Goodge and Dallmeyer, 1996). In the and Kleinschmidt (1991, 1993); Kleinschmidt(1990)]. Within the high-grade basement, theseLanterman Range, high-pressure metamorphism
is documented by the occurrence of eclogites (Di thrust tectonics also led to the occurrence of zoneswith different metamorphic grades at the sameVincenzo et al., 1997). U–Pb and Sm–Nd ages
between 500 and 492 Ma from eclogites and level of exposure (Schussler, 1996). The WilsonThrust ( W in Figs. 1 and 2) and the westerngneisses of the Lanterman Range were interpreted
to date the time of peak metamorphism (Goodge branch of the Exiles Thrust System ( WE) formthe eastern and western borders of the high-gradeet al., 1995; Di Vincenzo et al., 1997).
The western, low-pressure belt of the Wilson basement rocks, respectively. The eastern branch
239U. Schussler et al. / Precambrian Research 93 (1999) 235–258
of the Exiles Thrust System (EE) separates a In parts of the basement rocks, a retrogressive,but still syntectonic overprint caused far-reachingwestern zone from a central zone. Differences in
metamorphic grade indicate a tectonic contact re-equilibration and transformation of formerhigh-grade gneisses into muscovite–biotite gneissesbetween the central zone and an eastern zone
as well. with only few relics of cordierite and sillimanite(Schussler, 1996).The metamorphic basement consists of extensive
series of psammitic metasediments with local varia- The final stage of the high-grade metamorphicevolution was accompanied by the intrusion oftions to more quartzitic or more pelitic composi-
tions. Differences in lithology and metamorphic late- to posttectonic pegmatites. A garnet–tourma-line pegmatite (sample RK12) having intruded thegrade allow to distinguish the central zone from
the eastern and the western zones [Fig. 2; Schussler metamorphic basement of the central zone atRinggold Knoll (Fig. 2) was dated by the Rb–Sr,(1996)]. The metasediments in the latter two zones
are extremely monotonous, whereas abundant Sm–Nd, K–Ar and 40Ar–39Ar methods. A Rb–Srmineral-whole rock isochron yielded an age ofcalc-silicate interlayers, sometimes associated with
amphibolites, occur in the central zone. 492±8 Ma, interpreted to date the pegmatiteemplacement. Cooling to the blocking temperatureFurthermore, tectonic lenses of ultramafic rocks
within the metasediments are restricted to the of the K–Ar system in muscovite was dated to ca470–475 Ma (Schussler and Henjes-Kunst, 1994).central zone.
All basement rocks were affected by variable Except the critical mineral assemblages and reac-tions observed in the migmatites and except somedegrees of migmatization. In the eastern and west-
ern zones, metatexites with in situ formation of geochronological data of the Ringgold Knoll peg-matite, nothing is known about metamorphic evo-small leucosomes, or migmatites with up to deci-
metre-wide leucosomes and melanosomes are lution and age relations in the Oates Coast partof the Wilson Terrane. To obtain more informa-common. In the central zone, additional diatexites
are widespread and show advanced magmatic tex- tion, three samples of migmatites of the centralzone, in part with granulite-facies relics, weretures with sporadic occurrence of nebulitic restite.
In the eastern and western zones, the prograde chosen for detailed petrological and geochronolog-ical investigations to find out:metamorphic equilibria$ the P–T conditions of the last metamorphic
Ms+Qtz=Sil+Kfs+V event which led to a widespread migmatizationand which is predominantly preserved in theBt+Sil+Qtz=Crd+Kfs+Vlarge majority of the basement rocks;
were recognized in pelitic bulk compositions [min- $ the P–T conditions of an earlier granulite-facieseral abbreviations after Kretz (1983)]. In the event which is evident from some relic mineralcentral zone, the higher-grade reactions assemblages preserved in part of the migmatites;
$ the time of the last metamorphic event; andBt+Sil+Qtz=Crd+Grt+Kfs+V$ the time of cooling subsequent to the last meta-
Bt+Sil+Qtz=Crd+Spl+Kfs+V morphic event.The new data regarding these points allow theare documented. In addition, a relic granulite-reconstruction of at least part of the P–T–t evolu-facies mineral assemblagetion of this basement sector and enable a compari-
Qtz+Pl+Bt+Opx±Grt±Cpx son with other basement segments of the WilsonTerrane. Additionally, new geochronological dataoccurs in migmatites of the central zone. A latefrom the Ringgold Knoll Pegmatite give moredecompression at still high temperatures for theprecise insight into the relations between meta-central zone is indicated by growth of Crd accord-morphism and magmatism of the region.ing to the reactionUnfortunately the relic granulite-facies mineralassemblages in the migmatites are rare and tinyGrt+Sil+Qtz+V=Crd.
240 U. Schussler et al. / Precambrian Research 93 (1999) 235–258
and, in case of the Opx-bearing relics, sometimesheavily altered. Their preparation for isotopeanalysis to date the granulite-facies stage seems tobe impossible therefore.
3. Sample description: petrography and mineralchemistry
US-380 was taken from the eastern ridge ofThompson Peak (69°24∞30◊S, 157°44∞30◊E; Fig. 2)and forms part of monotonous migmatitic gneisses.The major minerals are Grt+Bt+Sil+Kfs+
Fig. 3. Relic granulite-facies mineral assemblage typicallyPl+Qtz, with accessory apatite, monazite and rareoccurring as layers and schlieren in migmatites of the Harald
opaque phases. Biotite shows a weak preferred Bay and Mt. Archer area in the central zone of the Oates Coastorientation as typical for migmatites. Garnet is basement: orthopyroxene (medium grey) and biotite (dark)
together with plagioclase and quartz ( light).sometimes euhedral (up to 2 mm in grain size) butmore frequently is corroded along the edges.Quartz, plagioclase and K-feldspar form gra- Layers or boudins of calc-silicate rocks are interca-
lated. At the northeastern flank of Mt. Archer,noblastic aggregates in interstices between biotite-dominated parts. K-feldspar may have numerous decimetre to metre wide lenses of ultramafic rocks
are present. Opx-bearing granulite-facies relicssmall exsolutions of plagioclase. Rare sillimanitewas found as inclusion in plagioclase or in the have been found in the migmatites (Fig. 3). The
mineral content of US-495 is Grt+Bt+Crd+marginal parts of garnet.Two different types of plagioclase compositions Sil+Spl+Kfs+Pl+Qtz. Leucocratic parts are
dominated by quartz and plagioclase, with subor-can be distinguished: anorthite contents of ca60 mol% were found in rare grains with inclusions dinate biotite and K-feldspar. Myrmekitic
intergrowths of plagioclase and vermicular quartzof sillimanite, whereas plagioclase without silli-manite inclusions has anorthite contents between can be observed. The melanocratic parts are
quartz-poor or even-free and are dominated by38 and 42 mol%. The latter also forms exsolutionlamellae in K-feldspar which is composed by biotite which defines the schistosity of the rock.
The biotite is accompanied by plagioclase±88–91 mol% orthoclase and 12 to 9 mol% albite.Biotite has uniform XMg-values of 0.47–0.48. cordierite. Most garnets (0.5–4.0 mm in size) are
euhedral, some of them show corrosion texturesGarnet is almandine-dominated but contains con-siderable amounts of pyrope and spessartine. A along the edges. Biotite inclusions may be strongly
orientated parallel to the matrix foliation.slight zonation was recognized across three largegarnet grains. Wide cores of 1.2–1.8 mm in size Cordierite, green spinel, plagioclase, quartz and
ilmenite form additional inclusions in garnet.have a composition of 65–67 mol% almandine,21–22 mol% pyrope and 8–9 mol% spessartine. In Green spinel may also be part of the matrix
assemblage, but typically occurs in conspicuouscontrast, spessartine increases to 12–15 mol% andpyrope decreases to 12–18 mol% in the 0.1–0.2 mm patches with the assemblage Crd+Bt+Sil+
Spl+Pl+Qtz (Fig. 4). Sillimanite can also bewide rims, while the almandine content of66–67 mol% is identical to that of the cores. included in plagioclase.
Selected microprobe analyses of the mineralsUS-495 is a dark, gneissic migmatite and wascollected at the southwestern ridge of Mt. Archer which were taken for P–T calculations are given
in Table 1. The anorthite content of plagioclase(69°13∞30◊S, 157°36∞00◊E; Fig. 2). The outcrop isdominated by migmatites with clearly defined leu- varies between 27 and 42 mol%. In contrast to
sample US-380, plagioclases with and withoutcosomes and melanosomes and by diatexites.
241U. Schussler et al. / Precambrian Research 93 (1999) 235–258
tine and 16–20 mol% pyrope. The rims consist of68–72 mol% almandine, 12–16 mol% spessartineand 11–18 mol% pyrope.
US-501 was collected at the southwestern coast-line of Harald Bay, southeast of Mt. Archer(69°13∞20◊S, 157°44∞30◊E; Fig. 2). The outcrop isformed by rather homogeneous garnet-rich diatexi-tic migmatites which in part contain melanosomesand remnants of calc-silicate layers. The matrix ofUS-501 is formed by Grt+Bt+Kfs+Pl+Qtz+Gr. The structure of the medium- to coarse-grainedrock is more or less irregular. In part, biotite isclearly orientated. A weak differentiation into
Fig. 4. Relic granulite-facies mineral assemblage (1), occurring more melanocratic areas and more leucocratic onesin several conspicuous patches of sample US-495 from Mt.is evident from the hand specimen and the thin-Archer in the central zone: spinel (dark), biotite (medium grey)sections. K-feldspar forms large, xenomorphicand sillimanite (fibres) together with cordierite, plagioclase and
quartz ( light). grains within the leucocratic parts, accompaniedby smaller, often platy plagioclase and quartz.Plagioclase and quartz sometimes occur in myr-sillimanite inclusions have similar anorthite
contents. K-feldspar shows a wide compositional mekitic intergrowth. Xenomorphic garnet (up toseveral millimetre in diameter), biotite, plagioclaserange with orthoclase between 61 and 91 mol%
and 1–3 mol% celsiane, the rest being albite. XMg and small amounts of quartz are the main constitu-ents of the more melanocratic parts. Garnet con-values of matrix biotite vary from 0.41 to 0.49.
Distinctly higher XMg values up to 0.65 were tains inclusions of biotite, cordierite, sillimanite,green spinel, ilmenite, plagioclase and quartz.observed in biotites included in garnet, whereas
those included in cordierite have XMg values down Narrow, frayed strips of graphite as a minorcomponent are distributed in the whole matrix,to 0.42. Cordierite gave rather uniform XMg data
between 0.61 and 0.65 which may rise up to 0.68 but do not occur as inclusions in garnet. Accessoryminerals are monazite, zircon and rare apatite.when cordierite is included in garnet.
Green spinel is a hercynite-dominated solid solu- K-feldspar which usually shows thin perthiticexsolution lamellae is composed of 84–92 mol%tion of 68–72 mol% hercynite, 11–15 mol% spinel
and 10–14 mol% gahnite, with 1–3 mol% magne- orthoclase, 7–15 mol% albite and 1–2 mol% celsi-ane. Plagioclase has anorthite contents oftite and ca 1 mol% galaxite as minor endmembers.
Some grains show enhanced gahnite contents up 40–44 mol%. XMg for biotite in the matrix and atthe rims of garnet ranges from 0.54 to 0.57. Valuesto 28 mol% at the expense of hercynite. If included
in garnet, the contents of magnetite and spinel from 0.60 to 0.67 were observed for biotitesincluded in garnet. One green spinel included inmay increase up to 6 and 19 mol%, respectively,
whereas gahnite decreases to 7 mol%. garnet consists of 60 mol% hercynite, 28 mol%spinel, 9 mol% gahnite and 1 mol% magnetite.Garnet is Ca-poor and has an almandine-domi-
nated pyralspite composition. Each of the seven Garnet is a nearly pure solid solution of alman-dine and pyrope with subordinate spessartine andprofiles measured across garnet grains exhibits a
slight chemical zonation, usually with a homogen- andradite. Three profiles across garnet grains showeither a homogeneous composition of 66–67 mol%eous central part and a smaller rim of distinct
chemical composition. The rims are characterized almandine, 26–27 mol% pyrope, 3–5 mol% andra-dite and 2–3 mol% spessartine, or a slight zonationby decreasing pyrope and increasing spessartine
contents. Almandine remains constant or increases with a homogeneous core composition and analmandine increase and pyrope decrease to 70 andparallel to spessartine. Typical core compositions
are 67–69 mol% almandine, 9–12 mol% spessar- 23 mol%, respectively, at the rims.
242 U. Schussler et al. / Precambrian Research 93 (1999) 235–258
Table 1Compositions of phases taken for the calculation of P–T conditions of the assemblage (1) in migmatite US-495
US-495 loc 3 loc 3 loc 3 loc 3 loc 3 loc 3 loc 7 loc 7 loc 7 loc 7 loc 9 loc 9 loc 9 loc 9 loc 9bt 1 bt 2 crd 1 crd 2 pl spl bt crd pl spl bt1 bt2 bt 3 crd spl
Wt%SiO2 34.51 33.84 47.75 48.41 61.22 0.02 35.00 48.40 59.99 0.00 35.65 34.34 33.79 48.33 0.00TiO2 2.82 3.01 0.04 0.00 — 0.00 2.60 0.05 — 0.02 3.26 3.76 3.89 0.00 0.00Al2O3 19.04 19.95 32.76 32.63 24.13 57.91 18.77 32.81 24.82 57.96 21.83 18.60 19.26 32.77 57.80Cr2O3 0.11 0.03 — — — 0.21 0.03 — — 0.17 0.18 0.09 0.24 — 0.17Fe2O3 3.18 3.18 0.48 0.13 0.18 1.83 0.00 0.90 0.06 1.62 2.98 3.22 3.32 0.33 1.95MgO 9.82 9.41 8.00 8.15 0.00 3.52 9.73 8.04 0.00 3.36 7.22 8.90 8.19 7.97 3.17CaO 0.00 0.01 0.03 0.03 5.62 0.04 0.00 0.02 6.66 0.00 0.01 0.00 0.00 0.03 0.00MnO 0.23 0.12 0.53 0.44 0.01 0.47 0.13 0.47 0.02 0.49 0.17 0.19 0.17 0.44 0.46FeO 16.21 16.22 7.41 7.86 — 30.66 19.06 7.29 — 29.62 15.21 16.44 16.91 8.08 30.74ZnO — — — — — 4.83 — — — 6.24 — — — — 5.42Na2O 0.30 0.33 0.36 0.28 8.21 — 0.21 0.35 7.84 — 0.23 0.31 0.29 0.25 —K2O 9.05 8.88 0.00 0.01 0.10 — 8.85 0.04 0.14 — 8.05 9.09 9.13 0.00 —Total 95.27 94.98 97.36 97.94 99.47 99.49 94.38 98.37 99.53 99.48 94.79 94.94 95.19 98.20 99.71
CationsSi 2.62 2.57 4.97 5.01 2.73 0.00 2.68 4.99 2.68 0.00 2.66 2.62 2.58 4.99 0.00Ti 0.16 0.17 0.00 0.00 — 0.00 0.15 0.00 — 0.00 0.18 0.22 0.22 0.00 0.00Al 1.70 1.79 4.02 3.98 1.27 1.95 1.70 3.98 1.31 1.95 1.92 1.67 1.73 3.99 1.94Cr 0.01 0.00 — — — 0.01 0.00 — — 0.00 0.01 0.01 0.01 — 0.00Fe3+ 0.18 0.18 0.04 0.01 0.01 0.04 0.00 0.07 0.00 0.04 0.17 0.19 0.19 0.03 0.04Mg 1.11 1.07 1.24 1.26 0.00 0.15 1.11 1.23 0.00 0.14 0.80 1.01 0.93 1.23 0.14Ca 0.00 0.00 0.00 0.00 0.27 0.00 0.00 0.00 0.32 0.00 0.00 0.00 0.00 0.00 0.00Mn 0.01 0.01 0.05 0.04 0.00 0.01 0.01 0.04 0.00 0.01 0.01 0.01 0.01 0.04 0.01Fe2+ 1.03 1.03 0.64 0.68 — 0.73 1.22 0.63 — 0.71 0.95 1.05 1.08 0.70 0.74Zn — — — — — 0.10 — — — 0.13 — — — — 0.12Na 0.04 0.05 0.07 0.06 0.71 — 0.03 0.07 0.68 — .03 0.05 0.04 0.05 —K 8.88 0.86 0.00 0.00 0.01 — 0.87 0.01 0.01 — 0.77 0.88 0.89 0.00 —Total 7.74 7.73 11.03 11.04 5.00 2.99 7.77 11.02 5.00 2.99 7.50 7.71 7.68 11.03 2.99
The indication of the analyses refers to that used in Table 2 for the individual calculations. Cations are normalized on an oxygennumber of 11 for biotite, 18 for cordierite, 8 for plagioclase and 4 for spinel. H2O contents are not considered.
4. Petrological results carried out on the assemblage (1) Crd+Bt+Sil+Spl+Pl+Qtz which was analysed in threesmall domains of the thin-section, signed as loca-Assuming local equilibria, conditions of forma-
tion were calculated for mineral assemblages of tions 3, 7 and 9 in Table 2. For the locations 3and 9, three calculations involving analyses ofUS-495 and US-501 employing the average P–T
method of Powell and Holland (1994) and using different biotite or cordierite grains were done.Furthermore, assemblage (2) Grt+Crd+Bt+an updated version of the thermodynamic data set
of Holland and Powell (1990). Once the endmemb- Pl+Qtz was analysed and calculated, which typi-cally forms most of the matrix of this sample. Iners of the minerals in an equilibrium assemblage
have been identified, it is possible to balance all US-501, the assemblage (3) Grt+Bt+Sil+Pl+Qtz±Spl was used.the reactions among those endmembers. With the
thermodynamic data available, each reaction can For assemblage (1) it is possible to balance fiveindependent reactions between cordierite, biotite,be used for characterizing the pressure and temper-
ature of formation of the assemblage. sillimanite, spinel, plagioclase, quartz and H2O.The calculated pressures and temperatures areRegarding sample US-495, calculations were
243U. Schussler et al. / Precambrian Research 93 (1999) 235–258
Table 2P–T data with 2s errors and x2 values calculated for assemblage (1) Crd+Bt+Sil+Spl+Pl+Qtz which was found at the domains3, 7 and 9 of sample US-495
Assemblage XH20 P (kbar) 2s (P) T (°C ) 2s (T) x2
Loc 3crd1–bt1–sp1–pl–qtz–sil–fluid 1.0 7.6 1.2 827 124 0.58 (1.54)
0.6 7.1 1.1 779 110 0.49 (1.54)crd1–bt2–spl–pl–qtz–sil–fluid 1.0 7.7 1.3 837 133 0.49 (1.54)
0.6 7.1 1.1 786 117 0.40 (1.54)crd2–bt1–spl–pl–qtz–sil–fluid 1.0 7.8 1.2 833 125 0.63 (1.54)
0.6 7.5 1.1 788 112 0.53 (1.54)
Loc 7crd–bt–spl–pl–qtz–sil–fluid 1.0 7.5 1.0 787 109 0.85 (1.54)
0.6 6.3 0.9 730 93 0.78 (1.54)
Loc 9crd–bt1–spl–pl–qtz–sil–fluid 1.0 8.0 2.0 795 238 0.72 (1.54)
0.6 6.9 1.7 762 220 0.65 (1.54)crd–bt2–spl–pl–qtz–sil–fluid 1.0 7.9 1.4 802 141 0.64 (1.54)
0.6 7.0 1.2 752 124 0.56 (1.54)crd–bt3–spl–pl–qtz–sil–fluid 1.0 7.8 1.5 797 173 0.62 (1.54)
0.6 6.7 1.3 751 153 0.54 (1.54)
The calculations have been performed using an updated version of the internally consistent thermodynamic dataset of Holland andPowell (1990) and an updated version of the program THERMOCALC (Powell and Holland, 1988).
correlated and the best average P–T estimate is XH2O=1 range from 7.5 to 8 kbar and from 790to 840°C, indicating medium-pressure granulite-obtained by least-square techniques, allowing the
s uncertainties to be calculated. Finally, a x2 test facies conditions (Fig. 5). The calculated valuesdecrease by ca 50°C and 1 kbar when a fluidis applied to the average P–T result in order to
test for the reliability of the estimate. In the case composition of XH2O=0.6 is assumed. The P–Tof five independent reactions, as in assemblage(1), the x2 value should be <1.54. In all ourcalculations this value was well below 1.0 (Table 2)indicating the reliability of the results as well assupporting our initial assumption of localequilibrium.
All calculations were performed assuming ideal-mixing-on-sites activities, except for garnet andplagioclase. Garnet was described with the regularmodel of Newton and Haselton (1981), and plagio-clase was modelled as a molecular solution employ-ing the mixing parameters of Newton et al. (1980).For each assemblage, the calculations were carried
Fig. 5. P–T data calculated for the medium-pressure granulite-out for various fluid compositions. The resultsfacies assemblages (1), #, $, and the low-pressure granulite-including the 2s uncertainties are given in Table 2facies to upper-amphibolite-facies assemblages (2), %, &; and
and are shown on the P–T diagrams in Figs. 5 (3),6, +. For one point of each metamorphic stage, the errorand 11. range is given. Filled symbols denote results from calculations
at XH2O=1, open symbols those at XH2O=0.6.For assemblage (1), all P–T estimates at
244 U. Schussler et al. / Precambrian Research 93 (1999) 235–258
Tab
le3
U–P
ban
alyt
ical
resu
lts
for
zirc
ons
ofm
igm
atit
eU
S-50
1,fo
rm
onaz
ites
ofm
igm
atit
esU
S-38
0,U
S-49
5an
dU
S-50
1,an
dfo
rzi
rcon
san
dm
onaz
ite
ofpe
gmat
ite
RK
12
Sam
ple
Size
(mm
)C
once
ntra
tion
s(p
pm)
Mea
sure
dis
otop
era
tios
Cor
rect
edis
otop
era
tiosa
App
aren
tag
e(M
a)
UP
b206P
b208P
b/207P
b/206P
b/206P
b/±
2s207P
b/±
2s207P
b/C
orr.
206P
b/207P
b/207P
b/±
2sto
tal
rad.
206P
b206P
b204P
b238U
235U
206P
bco
eff.
238U
235U
206P
b
Zir
con
US-
501
>12
532
539
.532
.90.
1109
540.
0922
7111
039
0.11
7527
179
1.47
479
225
0.09
101
0.99
771
692
014
47±
1U
S-50
110
0–90
374
43.3
36.6
0.09
8822
0.08
4656
7150
0.11
3984
172
1.29
956
201
0.08
269
0.97
569
684
612
62±
2U
S-50
190
–80
386
43.3
36.8
0.09
3779
0.08
3283
7846
0.11
0909
167
1.24
612
189
0.08
149
0.99
167
882
212
33±
1U
S-50
112
5–10
037
143
.736
.90.
0988
220.
0864
9918
512
0.11
5567
174
1.36
625
206
0.08
574
0.99
870
587
513
32±
1U
S-50
180
–62
395
40.1
34.6
0.08
6616
0.07
7898
1112
40.
1018
8215
41.
0764
016
80.
0766
30.
969
625
742
1111
±3
RK
1250
0–25
063
9546
145
4b0.
0137
460.
0604
4642
450.
0777
5623
50.
6121
519
50.
0571
00.
948
483
485
495
±2
RK
1220
0–16
058
6742
241
4b0.
0163
040.
0614
0532
500.
0773
0323
80.
6076
020
40.
0570
10.
916
480
482
492
±3
Mon
azit
eU
S-50
112
5–10
019
4313
9613
2.8
9.33
3274
0.05
8691
7262
0.07
9579
243
0.62
196
193
0.05
668
0.98
349
449
147
9±
4U
S-50
110
0–80
1973
1420
135.
19.
3348
720.
0589
7573
720.
0796
8820
30.
6262
916
20.
0570
00.
988
494
494
492
±3
US-
495
125–
100
4499
1338
301.
53.
3408
970.
0579
1013
610
0.07
8007
178
0.61
135
141
0.05
684
0.99
048
448
448
5±
2U
S-49
5>
125
5291
1474
359.
83.
0064
960.
0576
7016
128
0.07
9144
178
0.61
947
140
0.05
677
0.99
549
149
048
3±
2U
S-38
0>
8071
4616
1248
1.9
2.26
5368
0.05
7922
1298
00.
0784
8612
10.
6147
197
0.05
680
0.99
348
748
748
4±
1U
S-38
080
–62
6150
1572
415.
22.
6966
690.
0584
2095
830.
0785
9311
90.
6166
295
0.05
690
0.98
948
848
848
8±
2R
K12
125–
8025
757
3118
3106b
0.71
7675
0.05
8633
8177
0.07
8838
237
0.61
890
189
0.05
694
0.98
748
948
948
9±
1
aCor
rect
ion
for
frac
tion
atio
n,sp
ike,
blan
k,in
itia
lco
mm
onle
ad.
bVal
ues
for
tota
lra
diog
enic
Pb.
245U. Schussler et al. / Precambrian Research 93 (1999) 235–258
data vary within a rather limited range of ca ±5°Cand ±0.1 kbar, if analyses of different cordieriteor biotite grains of the same domain are used forthe calculations, as shown for the domains 3 and9 in Tables 1 and 2.
Significantly lower P–T conditions of 640–650°Cand 4–5 kbar at XH2O=1.0 were found for assem-blage (2). If calculated with XH2O=0.6, the valuesdecrease by ca 30°C and 0.5 kbar, respectively.Assemblage (3) in US-501 gave pressures between4.1 and 5.7 kbar, however, in a wide temperaturerange from 720 to 870°C (the P–T range is definedwhen garnet core compositions are taken for thecalculations, but by using rim concentrations, thedata points plot into the same range). If calculated
Fig. 6. Concordia diagram with U–Pb dates between 484 andwith XH2O=0.6, the pressures range from 4.1 to494 Ma for six monazite fractions of the investigated migmat-5.5 kbar is identical to the range given for ite samples.
XH2O=1. Nevertheless XH2O=0.6 seems to be morerealistic as the matrix of US-501 contains graphitewhich indicates lowered H2O activities (Fig. 5). below the closure temperature between 487 and
494 Ma. However, reverse discordance may alsoresult from analytical problems. For the presentstudy, most potential mechanisms [e.g. poor spike5. Isotope datacalibration, incomplete dissolution; Hawkins andBowring (1997) and references herein] can confi-5.1. Metamorphic rocksdently be ruled out, except mass spectrometricproblems which may have occurred for a shortU–Pb isotope analysis was carried out on mona-
zite from US-380, US-495 and US-501. The mona- time. Even in this case, the age range indicated bythe 207Pb/206Pb ages (479–492 Ma) still appears tozites are commonly included in biotite, cordierite
and garnet, that is, the more melanocratic parts remain geologically significant. If the size fractionsnot overlapping with the discordia are excluded,of the rocks, but they also occur as inclusions in
plagioclase and quartz or along grain boundaries the 207Pb/206Pb ages of the remaining fractionsindicate a more restricted time span between 484between these minerals. Two different size fractions
for each sample were analysed (Table 3). Four and 492 Ma.Five zircon size fractions (clear, short prismatic,fractions yielded concordant or nearly concordant
U–Pb ages which range between 484 and 494 Ma without visible inclusions) of sample US-501 werealso analysed by use of the conventional U–Pb(Fig. 6). In all samples, one grain size fraction
plots above the concordia. The highest degree of multigrain method (Fig. 7, Table 3). Three zirconfractions [C, D, E in Fig. 7(a)] define a ‘discordia’reverse discordance is observed for the largest
grain size fractions of samples US-501 and US-495. (MSWD 2.04) with a lower intercept at 469±8 Maand an upper intercept at 1918±31 Ma.The reason for this result is poorly understood.
Reverse discordance as a product of excess 206Pb Cathodoluminescence studies document the pres-ence of inherited cores in zircons in at least threeeffects are found in magmatic monazites mainly
(Parrish, 1990), but can also be expected in mona- fractions [A, B, C in Fig. 7(a); Fig. 7(b)] and fromtheir position in the concordia diagram, at leastzite newly grown during metamorphism. In this
case, the 207Pb/235U dates still provide reliable age fractions A and B appear to have a pre 1.9 Gacomponent.information, suggesting that the studied samples
experienced metamorphic crystallization or cooling Rb–Sr and K–Ar isotope analysis of biotite
246 U. Schussler et al. / Precambrian Research 93 (1999) 235–258
two low-temperature increments. For the mediumto high-temperature increments, plateau ages of476.4±2.3, 472.2±3.3 and 470.1±2.3 Ma wereobtained (order of the data always with increasingsample numbers).
Sm–Nd isotope analysis of whole rock powdersfrom the same samples yielded model ages of 1.93,1.76 and 1.77 Ga (Table 6), calculated usingdepleted mantle parameters (DePaolo, 1981).
5.2. Pegmatite
The geochronological data of the garnet–tour-maline pegmatite RK12 from Ringgold Knoll[Fig. 2; Schussler and Henjes-Kunst (1994)] weresupplemented by U–Pb analyses on one monaziteand two zircon fractions (Table 3; Fig. 10). Ucontents of ca 6000 ppm for zircon and ca26 000 ppm for monazite which are up to 20 timeshigher than those of zircons and monazites fromthe metamorphic rocks support a magmatic originof these minerals in the pegmatite. RK12 zirconsare free of inclusions and of brownish colour.Some of the crystals show a length/width ratio>10 which is also in favour of an igneous zirconcrystallization. The monazite yielded a concordantU–Pb age 489±2 Ma. The zircon fractions plotslightly below the concordia, with U–Pb ages of
(a)
(b)
Fig. 7. (a) Concordia diagram with U–Pb data points of fivezircon fractions of the migmatite US-501. Three fractions (C–E)define a straight line which may be interpreted as a discordiawith a lower intercept at 469±8 Ma and an upper interceptwhich points to a protolith age of ca 1.9 Ga. (b) Fractions A–Cshow inherited cores in the zircons during cathodoluminescenceinvestigations ( left photo, prismatic zircon 180 mm in length;right photo, prismatic zircons ca 200 mm in length).
from all three samples yielded 470, 468, 470 Maand 473, 469 and 470 (each ±5) Ma, respectively(Tables 4 and 5; Fig. 8), providing average ages of469±3 Ma for the Rb–Sr system and 471±3 Mafor the K–Ar system. 40Ar–39Ar total gas dates are474, 471 and 469 (±2) Ma. On all biotites,40Ar–39Ar incremental heating experiments wereperformed in order to verify the geological signifi-
Fig. 8. Comparison of Rb–Sr, K–Ar, 40Ar–39Ar total gas andcance of the conventional K–Ar dates. They 40Ar–39Ar plateau biotite ages of the investigated migmatitesyielded slightly disturbed age spectra (Fig. 9) with and of K–Ar and 40Ar–39Ar muscovite data of pegmatite RK12
found at Ringgold Knoll.step ages of 300–380 and 400–460 Ma for the first
247U. Schussler et al. / Precambrian Research 93 (1999) 235–258
Table 4Rb–Sr analytical results for whole rocks and biotite fractions of samples US-380, US-495 and US-501
Sample Concentration (ppm) Isotope ratios Age (Ma±2s)
Rb Sr 87Rb/86Sr 87Sr/86Sr 2s
US-380Whole rock 255.3 141.9 5.2321 0.759543 24 470±5Biotite 559.0 2.15 1489.2 10.697685 24
US-495Whole rock 180.2 73.7 7.1153 0.775298 19 468±5Biotite 324.5 1.71 855.65 6.431442 11
US-501Whole rock 191.3 253.8 2.1855 0.732308 20 470±5Biotite 642.6 3.61 776.55 5.915233 11
Table 5K–Ar analytical results for biotite fractions of samples US-380, US-495 and US-501
Sample K (wt%) Rad. Ar (nl g−1) Rad. Ar (%) Date (Ma±2s)
US-380 8.05 169.5 99.1 473.3±4.9US-495 7.72 160.5 98.7 468.9±4.8US-501 8.04 167.5 98.5 469.8±4.9
Table 6Sm–Nd analytical data for whole rocks of the investigated migmatite samples from Oates Coast
Sample Nd (ppm) Sm (ppm) 147Sm/144Nd 143Nd/144Nd e(Nd) t(Nd, DM)
pr.d. t
US-380 39.06 7.438 0.1147 0.511829 −15.8 −10.7 1.93US-495 42.94 8.376 0.1175 0.511975 −12.9 −8.0 1.76US-501 26.36 4.517 0.1032 0.511807 −16.2 −16.2 1.77
480–485 Ma. The discordant position of the data 6. Discussionpoints can be explained by recent Pb loss of zirconswhich have crystallized ca 490 Ma ago. 6.1. Metamorphic historyInterestingly to note, the U–Pb data do not provideevidence for inherited zircon components within From our petrological data, two stages in the
metamorphic evolution of the central zone canpegmatite RK12.Schussler and Henjes-Kunst (1994) reported be distinguished. Within the migmatites, an earl-
ier, medium-pressure granulite-facies stage is40Ar–39Ar plateau ages on two muscovite fractionsof the pegmatite of 471.0±4.2 and 471.1±4.2 Ma. clearly documented by the relic assemblage (1):
Crd+Bt+Sil+Spl+Pl+Qtz. This assemblageRecalculation of these data using a more reliablestandard led to slightly higher plateau ages of which only occurs in very small domains within
the rock matrix indicates temperatures of472.0±2.2 and 472.3±2.2 Ma, respectively.
248 U. Schussler et al. / Precambrian Research 93 (1999) 235–258
Fig. 10. Concordia diagram with U–Pb data points of one mon-azite fraction and two zircon fractions of pegmatite RK12.
on the calculations are taken into account (Fig. 5;Table 2). This metamorphic stage is confirmed bythin layers and schlieren showing the relic assem-blage Qtz+Pl+Bt+Opx (±Grt±Cpx). Theserelics occur within the migmatites at several loca-tions of the central zone. In rare cases when garnetor clinopyroxene coexist with orthopyroxene, theorthopyroxene is in part or completely replacedby anthophyllite. Garnet profiles show rather uni-form compositions except some minor composi-tional variations along the rims; this lack ofzonation is interpreted as the result of a youngerre-equilibration of the former granulite-facies gar-nets. Therefore, garnet–orthopyroxene thermome-try on several samples gave variable temperaturesmuch below the lower stability of orthopyroxene,indicating disequilibrium conditions for these Opx-bearing relic assemblages (Schussler, 1996).
The formation of the assemblages (2) withFig. 9. 40Ar–39Ar spectra of biotite fractions from migmatitesUS-380, US-495 and US-501. Grt+Crd+Bt+Pl+Qtz and (3) Grt+Bt+Sil+
Pl+Qtz±Spl in the matrix of samples US-495 andUS-501, respectively, can be related to the wide-790–840°C at nearly 8 kbar. Despite of the relic
nature of assemblage (1), equilibrium conditions spread migmatization and recrystallization of themetamorphic rocks which largely destroyed theare still preserved, as indicated by the narrow
range of P–T data obtained when various mineral former medium-pressure granulite-facies assem-blages. Most of the garnets in the migmatites eitheranalyses from the assemblage at the same location
were used for the calculation. This is supported by grew during this stage or were re-equilibrated. Thisis indicated by euhedral grain forms, by biotitenearly identical results from different domains
(Table 2). The medium-pressure granulite-facies inclusions showing the same orientation as thematrix biotite and by the flat zonation profilesconditions significantly stand out from those of
the later low-pressure granulite-facies to high mentioned above.The strongly varying temperatures calculatedamphibolite-facies stage, even if the uncertainties
249U. Schussler et al. / Precambrian Research 93 (1999) 235–258
reactions in the KASH-system ( Xu et al., 1994).The same minimum temperature is given by thesolidus curve in the system Qtz–Or–An40–H2O[reaction A in Fig. 11; Johannes (1984)]. The highportions of former melt in the migmatite seriesshow that the melting temperature has beenexceeded considerably. The solidus curve andtherewith minimum temperature estimate for theassemblages (2) and (3) shift towards even highervalues if a H2O activity <1 is taken into account(Johannes and Holtz, 1990). Relic inclusions ofsillimanite in cordierite and in garnet provideevidence that reaction (3) Bt+Sil+Qtz=Crd+Grt+Kfs+V took place. Taking intoaccount the melt-in temperature of minimum700°C, pressures between 4 and 5.5 kbar arerequired for the reaction [ Xu et al. (1994)KFMASH-system; see also Holdaway and Lee
Fig. 11. Possible alternatives for the P–T–t evolution of the (1977)]. From all these arguments, a low-pressuremetamorphic basement in the northern Wilson Terrane: if the granulite-facies to upper-amphibolite-facies stagemedium-pressure granulite relics are of Precambrian age, then
of metamorphism at ca 4–5.5 kbar and minimumloop (I ) represents the Precambrian metamorphism and loop700°C, but most probably under significantly(II ) the metamorphic overprint during the early Paleozoic Rosshigher temperature conditions, can be postulatedOrogeny. If the relics are of early Ross age, then loop (I ) marks
the P–T–t evolution during the Ross Orogeny [ loop (II) may for the investigated rocks.be neglected in this case]. (1) Ms+Qtz=Sil+Kfs+V Decompression at still elevated temperatures is(Chatterjee and Johannes, 1974; Xu et al., 1994); (3) evident from reaction (5) Grt+Sil+Qtz+V=Bt+Sil+Qtz=Crd+Grt+Kfs+V ( Xu et al., 1994); (5)
Crd, which led to the formation of a rim ofGrt+Sil+Qtz+V=Crd ( Xu et al., 1994); (A) solidus curve incordierite around some garnets with sillimanitethe system Qtz–Or–An40–H2O (Johannes, 1984); (B) aluminum
silicate triplepoint (Holdaway and Mukhopadhyay, 1993). $, inclusions in samples from the central zone. The& and +, Data points for the medium-pressure granulite-facies reaction indicates minimum pressures of caassemblage (1) and the low-pressure granulite-facies to upper 3–4 kbar, as calculated for the pure Fe endmemb-amphibolite-facies assemblages (2) and (3), taken from Fig. 5. ers in the KFASH-System [Fig. 11; Xu et al.
(1994)]. Introduction of MgO will shift the reac-from the assemblages (2) and (3) may be explained tion to even higher pressures (Holdaway andby different closing temperatures of the different Lee, 1977).chemical systems used for thermometry. However, All the migmatites that occur in the northernthey may also reflect disequilibrium for the mineral Wilson Terrane seem to have resulted from theassemblages used. This is the more likely explana- younger low-pressure granulite-facies to upper-tion, as the influence of a melting phase on the amphibolite-facies metamorphism. But theresystem is not considered in the calculations. On remains one question concerning a possible mig-the other hand, discontinuous mineral reactions matization during the earlier medium-pressureand the solidus for the system require a P–T range granulite-facies event. The position of P–T pointswhich is consistent with the calculated data. A for assemblage (1) at ca 8 kbar/800°C calculatedminimum temperature of 700°C derives from the at XH2O=1 clearly indicates the formation of meltupper stability of muscovite according to reaction (Fig. 11). If XH2O was 0.5, the solidus curve shifts(1) Ms+Qtz=Sil+Kfs+V (Fig. 11). The posi- to ca 770°C at 7 kbar (Johannes and Holtz, 1990)tion of this reaction in the P–T field was experimen- and the calculated P–T values for assemblage (1)tally defined by Chatterjee and Johannes (1974) decrease below 780°C (Fig. 5), this is close to or
even below the solidus temperature. The lack ofand is corroborated by calculation of mineral
250 U. Schussler et al. / Precambrian Research 93 (1999) 235–258
migmatites of this early metamorphic stage in the disturbed later. Lower step ages for the firstincrements of the 40Ar–39Ar spectra demonstratefield may be explained as follows:
$ early migmatites exist, but appear quite similar that the K–Ar systems suffered from slight Ar lossin post-Ordovician time, although K–Ar dates andto the younger ones and can not be distin-
guished from these; 40Ar–39Ar plateau ages for the same samples areconcordant within the given errors. 40Ar–39Ar$ early migmatites have been completely
reworked during the last migmatization, except plateau ages for the biotite fractions suggest thatcooling temperatures were already reacheda few small relics like the Opx or the very tiny
patches with assemblage (1); between 470 and 476 Ma ago. This variation maypoint to some minor regional differences in the$ the medium-pressure granulite-facies metamor-
phism was ‘dry’ and without formation of melt; late cooling history of the whole migmatite com-plex. The 40Ar–39Ar plateau ages of 472 Ma of thein this case, the rehydration of the central zone
during the low-pressure granulite-facies to high- pegmatitic muscovites indicate the common cool-ing history of migmatites and pegmatites.amphibolite-facies event has to be explained.
U–Pb zircon data of the smallest size fractionsC, D and E of sample US-501 define a discordia6.2. Age relationshipswith a lower intercept age of 469±8 Ma, suggest-ing that Pb loss or growth of new rims stopped atEstimates for the closure temperature of thethe same time when the Rb–Sr and K–Ar closingU–Pb system in monazite range between 730 andtemperatures of biotite were reached (nevertheless640°C (Copeland et al., 1988; Parrish, 1988;caution is required by interpreting the discordiaMezger, 1990). A value of 770°C is given by Dahlbecause of inherited cores in at least fraction C).(1997). These temperatures match in part theThis zircon intercept age corresponds well to atemperatures which were found for the low-pres-SHRIMP age of 469±4 Ma on zircon rims of asure granulite-facies to upper-amphibolite-faciesdiatexite from the Daniels Range [Fig. 1; Blackstage of the migmatites. The range in monaziteand Sheraton (1990)] which was interpreted toages between 484 and 494 Ma is therefore interpre-date a late thermal overprint. The upper interceptted to date this metamorphic stage in the centralof the discordia indicates a protolith age ofzone of the Oates Coast basement.1918±31, however, due to a complex history ofThe emplacement of the Ringgold Knoll pegma-the zircons in Ross time, combined with multistagetite is dated to ca 490 Ma by the new U–Pb agePb loss and/or zircon growth, no precise age infor-data of one monazite and two zircon fractions andmation can be inferred from this upper intercept.is further constrained by a Rb–Sr mineral-wholeThe larger size fractions A and B are interpretedrock isochron age of 492±8 Ma (Schussler andto be multiply discordant, and from their data,Henjes-Kunst, 1994). Metamorphism of the coun-even older protolith ages can be deduced. Thetry rocks and the subsequent intrusion of the late->1900 Ma protolith ages point to componentstectonic pegmatite took place within a very shortwithin the migmatites which derived from Earlytime span which cannot be resolved by U–PbProterozoic crustal rocks of probably Eastage dating.Antarctic provenance. This is corroborated by theFor biotite, closure temperatures of the Rb–SrSm–Nd whole rock model ages between 1.8 andand the K–Ar systems range from 350 to 300°C1.9 Ga from all three migmatite samples.(Purdy and Jager, 1976; Dodson, 1979; Harrison
et al., 1985), a temperature of 450°C for the K–Arsystem is given by Villa and Puxeddu (1994). The
7. Interpretationsmineral ages for biotites of US-380, US-495 andUS-501 are summarized in Fig. 8. From this, con-
7.1. P–T–t evolutioncordant Rb–Sr and K–Ar dates of, on average,469 and 471 Ma give a lower age limit for thecooling of the migmatites from regional-metamor- The new petrological and geochronological data
presented here can be used to define a segment ofphic temperatures, if the isotope systems were not
251U. Schussler et al. / Precambrian Research 93 (1999) 235–258
a P–T–t path for the central zone of the Oates Gregory (1967) for several locations along thecoastline west of Oates Coast and by Stuwe andCoast crystalline basement (Fig. 11). The earliest
event documented was a medium-pressure granu- Oliver (1989) for King Georg V Land which isneighbouring Oates Coast at its western side.lite-facies stage at ca 790–840°C/8 kbar. This was
followed by a low-pressure granulite-facies to Given that a Precambrian granulite-facies eventhas to be expected for the precursors of the Wilsonupper-amphibolite-facies stage at minimum 700°C
and 4–5.5 kbar, dated to ca 490 Ma ago. This Terrane rocks. The medium-pressure granulite-facies assemblages observed in the rocks investi-second metamorphic stage clearly took place in
the course of the Early Paleozoic Ross Orogeny. gated could be interpreted as relics of the remobil-ized Precambrian basement. In this case, a P–T–tA decompression at high temperatures as indicated
by reactions (3) and (5) is taken as evidence for a path with at least two separate loops would result(Fig. 11), loop (I ) of Proterozoic age, clockwiseclockwise direction of the Ross Orogenic P–T
evolution. Between ca 490 and 473 Ma, the base- direction not verified, and loop (II ) of EarlyPaleozoic age in clockwise direction. Alternatively,ment cooled down from 730–700°C to 350–300°C
[or from 770 to 450°C, taking into account the a medium-pressure granulite-facies metamorphismcould also have taken place early during the Rossclosing temperatures compiled by Villa (in press)].
Therewith a cooling rate of 18–25°C Ma−1 is Orogeny and may have immediately preceded thelow-pressure granulite-facies to upper-amphibo-indicated if continuous cooling is assumed.
The cooling history between 490 and 473 Ma is lite-facies stage during one single P–T–t loop (I )in clockwise direction. In this case, the centralcorroborated by age dates from a pegmatite
located at Ringgold Knoll (Fig. 2). The intrusion zone can be interpreted as a deeper crustal levelof the Ross metamorphic crystalline complex atinto the hot basement took place ca 490 Ma ago,
as established by new U–Pb data on monazite and Oates Coast, compared to the eastern and westernzones (Schussler, 1996). At the moment, no realzircon and by Rb–Sr and Sm–Nd whole rock–min-
eral isochrons (Schussler and Henjes-Kunst, 1994). evidence for either of these two possibilities wasrecognized.Final cooling to ca 350°C [500°C, Hammerschmidt
and Frank (1991)] was dated at 472±2 Ma bymeans of two 40Ar–39Ar spectra. In addition, these 7.2. Regional aspectsdata demonstrate that intrusive activities tookplace more or less contemporaneously with the 7.2.1. The western low-pressure metamorphic belt
of the Wilson Terranelow-pressure granulite-facies to upper-amphibo-lite-facies event. The low pressure belt extends from the Pacific
end of the Wilson Terrane at the Oates Coast forStill unknown is the age of the earlier medium-pressure granulite-facies event at the Oates Coast. ca 600 km in southeastern direction to the Terra
Nova Bay region (Deep Freeze Range, see Fig. 1)The Wilson Terrane is interpreted as an activecontinental margin of the East Antarctic craton at the Ross Sea. By comparing the geological
situations, striking similarities become obvious. Induring Ross Orogeny (e.g. Kleinschmidt andTessensohn, 1987), and at least parts of the base- both regions, high-grade metamorphic complexes
are in tectonic contact to low-grade metasedimen-ment should therefore derive from Precambriancontinental crust. This is substantiated by U–Pb tary series to the west. At the Oates Coast, these
metasediments are represented by the Berg Groupdata points of zircons from sample US-501, butalso by the whole rock Sm–Nd model ages. Sm–Nd (Skinner et al., 1996), at Terra Nova Bay by the
Priestley Formation (Skinner, 1983, 1989; Faddamodel ages of 1.8 to 2.2 Ga (Talarico et al., 1995)and a U–Pb zircon upper intercept age of et al., 1994). Evidence for a west-southwest
directed thrusting of the high-grade basement2028+30/−38 Ma ( Klee et al., 1990) from theTerra Nova Bay in the southern Wilson Terrane towards the craton over the Berg Group metasedi-
ments along the western branch of the Exilessupport this interpretation. Granulite-facies rocksfrom the craton were described by McLeod and Thrust System at the Oates Coast was found by
252 U. Schussler et al. / Precambrian Research 93 (1999) 235–258
Flottmann and Kleinschmidt (1991, 1993). A sim- 1991; Talarico et al., 1995; Palmeri, 1997). Bothcontain migmatites which were formed during P–Tilar thrusting in the Terra Nova Bay region is
assumed, but has not yet been proved conditions cited above. For the polymetamorphiccomplex, the migmatite stage is part of a decom-( Kleinschmidt and Matzer, 1990). A tectonic con-
tact (Boomerang Thrust) between the high-grade pressional P–T path, whereas the migmatites ofthe metasedimentary sequence represent the high-basement and the Priestley Formation is described
by Skinner (1991), but is not regarded as an est metamorphic stage of a counterclockwise heat-ing path. These contrasting P–T paths areequivalent of the Exiles Thrust at Oates Coast
( Kleinschmidt, 1990). interpreted as P–T trajectories of different crustallevels in the same tectonic setting that developedThe high-grade metamorphic basement at Terra
Nova Bay (Deep Freeze Range) is formed by during the Cambro-Ordovician Ross Orogeny(Palmeri, 1997). Different crustal levels in the samemonotonous metamorphic, in part migmatitic
series which are quite similar in lithology to the tectonic setting were also recognized for the vari-ous zones of the Oates Coast basement (Schussler,Oates Coast metamorphic basement. Also,
different metamorphic zones can be distinguished 1996), with a decompressional P–T evolution forthe rocks of the central zone (P–T–t path I in(Palmeri et al., 1991). In the highest-grade parts,
the basement contains assemblages with Fig. 11). The P–T evolution of the eastern andwestern zones has not yet been investigated inGrt+Crd+Bt+Sil+Spl+Kfs+Qtz (Schubert
and Olesch, 1989) and also granulite-facies relics detail.Monazite, zircon and titanite from several gneisswith Opx–Grt and Opx–Grt–Crd bearing assem-
blages (Talarico et al., 1989, 1995; Talarico, 1990; samples of the Terra Nova Bay basement (withand without granulite-facies relics) yielded concor-Castelli et al., 1991; Talarico and Castelli, 1995).
For garnet and orthopyroxene bearing granulite- dant to nearly concordant U–Pb ages of480–490 Ma. A six point zircon discordia definesfacies relics at Terra Nova Bay, Castelli et al.
(1991) and Talarico and Castelli (1995) estimated a lower intercept age of 488±9 Ma for one sample( Klee et al., 1990; Klee, 1995). These dates closelyP–T conditions of 800–825°C and 7–8 kbar which
correspond well to the P–T data for the medium- resemble our U–Pb ages on monazites from theOates Coast which are interpreted to date the low-pressure granulite-facies stage of the Oates Coast
basement. A second, low-pressure granulite-facies pressure granulite-facies to upper-amphibolite-facies metamorphism of the Ross Orogeny. Similarstage is proved for the Terra Nova Bay basement
at ca 750–875°C and 4–5 kbar (Castelli et al., to the Oates Coast migmatites, the upper interceptage of the zircon discordia for a Terra Nova Bay1991; Talarico and Castelli, 1994). P–T conditions
for a late amphibolite-facies stage in the migmatites migmatite provides evidence for crustal compo-nents of Early Proterozoic age ( Klee et al., 1990).at Terra Nova Bay are estimated by Schubert and
Olesch (1989) to ca 650°C at 5 kbar. Palmeri et al. This is corroborated by Sm–Nd ages of 1.8–2.2 Ga(Talarico et al., 1995). The cooling history appears(1991) and Palmeri (1997) calculated 750°C at
5 kbar as maximum conditions for this stage. to be more complex in the Terra Nova Bay region,as indicated by K–Ar and 40Ar–39Ar mineral data650°C at 3–4 kbar are given by Talarico and
Castelli (1994) for a retrograde stage within the scattering between ca 480 and 440 Ma (Vita-Scaillet et al., 1994; Klee and Henjes-Kunst, ingranulite relics. These data generally match those
for the low-pressure granulite-facies to upper- preparation).From the strong similarities in petrology andamphibolite-facies stage of the Oates Coast
basement. geochronology between Oates Coast and TerraNova Bay it is likely that both regions underwentThe metamorphic basement at Terra Nova Bay
can be subdivided into a polymetamorphic com- a common tectonometamorphic history, at leastsince the medium-pressure granulite-facies event.plex with granulite relics and into a monometamor-
phic metasedimentary sequence (Palmeri et al., This assumption is supported by results from the
253U. Schussler et al. / Precambrian Research 93 (1999) 235–258
Daniels Range which is located in striking direction Monazites and titanites from the Lantermanbetween Oates Coast and Terra Nova Bay (Fig. 1). metamorphic complex yielded U–Pb ages of caUlitzka (1987) estimated P–T conditions of ca 498 Ma, dating the time when metamorphic tem-730°C and 4 kbar for the formation of migmatites peratures were ca 650–700°C (Goodge et al.,in the Daniels Range and reported a steep meta- 1995). Ages of 500±5 and 492±3 Ma derive frommorphic gradient to low-grade metasediments Sm–Nd mineral-whole rock isochrons of the eclog-towards the west. Within the high-grade series, the ite lenses, U–Pb two point discordias (rutile, wholeoccurrence of a granulite-facies assemblage with rock) result in ages of 495±6 and 503±6 Ma forQtz+Pl+Opx+Grt+Crd+Sil+Spl was noted the same samples (Di Vincenzo et al., 1997),by Plummer et al. (1983) from a breccia pipe. interpreted to approximately constrain the time ofMost of the K–Ar muscovite and biotite dates the high-pressure event. Subsequent coolingreported by Kreuzer et al. (1987) from the Daniels to temperatures <400°C is indicated by 40Ar–Range vary between 470 and 475 Ma. These dates 39Ar plateau ages of ca 482 Ma on muscovitesare corroborated by new 40Ar–39Ar plateau ages (Goodge and Dallmeyer, 1996; Henjes-Kunst, inof 475±2 and 476±2 Ma (Henjes-Kunst, unpub- preparation).lished) and thus correspond to the cooling ages The U–Pb monazite and titanite data suggestobtained for the Oates Coast basement. In conclu- that the high-grade metamorphism took place casion, the available data imply that during the Late 10 Ma earlier in the Lanterman Range than in thePrecambrian/Early Paleozoic, a rather homogen- Oates Coast area. 40Ar–39Ar plateau ages clearlyeous style of orogenic evolution has taken place indicate that during the cooling history theover a strike length of at least 600 km along the Lanterman Range reached the muscovite closurePacific margin of the old Antarctic craton.
temperature again ca 10 Ma earlier than the OatesCoast basement, most likely due to an earlieruplift.7.2.2. The eastern medium- to high-pressure
metamorphic belt of the Wilson TerraneOne of the best investigated areas of this belt is
the Lanterman Range in the northwestern WilsonTerrane (Fig. 1). For the metamorphic rocks of
Acknowledgmentthis area, Grew and Sandiford (1984) calculatedP–T conditions of ca 700°C at 8 kbar for an early
The Bundesanstalt fur Geowissenschaften undstage of metamorphism, followed by an intermedi-Rohstoffe in Hannover is thanked for the invitationate overprint at 650–700°C and 5.5–6.4 kbar andof U. Schussler to participate in the GANOVEXa final greenschist-facies stage at 300–370°C andProgram. Many thanks are due to all who contrib-3–5 kbar. Conditions of 700°C and up to 8 kbaruted to the success of the field work with theirare also suggested by Roland et al. (1984) whologistic or professional help. H. Klappert, M. Metz,mention that a subsequent, second metamorphicM. Bockrath and P. Macaj are thanked for labora-stage should have taken place at somewhat lowertory assistance at the BGR. Thanks are due to H.P–T conditions. For metamorphism in the DessentBaier (Munster) for laboratory assistance and S.Formation in the southeastern Wilson Terrane,Rochnowski (Munster) for support on the massKleinschmidt et al. (1984) estimated 600°C atspectrometer. K.-P. Kelber kindly prepared the6–7 kbar. Recently, eclogite lenses were foundfigures, P. Spathe the thin sections. U. Schusslerwithin the Lanterman Range, documenting meta-wants to thank W. Schubert for involving him inmorphic conditions of maximum 850°C at mini-geological research in North Victoria Land and formum 15 kbar for a high-pressure stage, followedhelpful advice and discussion. J.D. Kramers, M.by medium- and low-pressure stages underOkrusch and F. Talarico are thanked for con-amphibolite-facies conditions (Di Vincenzo et al.,
1997). structively reviewing the manuscript. Financial sup-
254 U. Schussler et al. / Precambrian Research 93 (1999) 235–258
port from the Deutsche Forschungsgemeinschaft is US-495 and US-501 was carried out atthe Zentrallaboratorium fur Geochronologie,gratefully acknowledged.Munster. For Rb–Sr analyses, mineral separates(40–50 mg) and whole rock powders (ca 100 mg)were mixed with a 87Rb–84Sr spike in Teflon screw-Appendixtop vials and dissolved in a hot HF–HNO3 (5:1)mixture. Rb and Sr were separated by standard
A1.1. Analytical methods ion-exchange procedures using 2.5 N HCl as elu-tant. Rb was loaded as chloride on a double
A1.1.1. Mineral compositions Ta-filament assembly and analysed on a NBS-typeMineral compositions were determined in pol- Teledyne mass spectrometer with a single Faraday
ished thin-sections using a CAMECA SX50 collector. Sr was loaded with H3PO4 on single Taelectron microprobe with wavelength-dispersive filaments and analysed on a VG Sector 54 multicol-spectrometers at the Mineralogisches Institut, lector mass spectrometer in dynamic mode. DuringUniversitat Wurzburg. The operating conditions the period of this study, the 87Sr/86Sr ratio of thewere: 15 kV accelerating voltage; 15 nA sample NBS-987 standard was 0.71025±0.00003 (2s).current; and 1–2 mm beam size. Element peaks and Based on repeated measurements, the 87Rb/86Srbackgrounds were each measured over 20 s, except ratios were assigned an uncertainty of 1% (2s).for Fe (30 s). Synthetic silicate and oxide minerals For other isotope ratios uncertainties are reportedwere used for reference standards. Matrix correc- at the 2sm level, taking into account the within-tion was calculated by the PAP-program supplied run precision, an estimated uncertainty of 0.1%by CAMECA. An analytical error of 1% relative for the 87Sr/86Sr spike ratio, the error magnificationfor major elements was verified by repeated meas- based on the spike/sample ratio and the blankurements on respective standards. For low concen- correction. Rb–Sr ages were calculated using thetrations, higher errors must be taken into account. least squares regression technique of York (1969).The detection limit is at concentrations of Errors are reported on the 95% confidence level.0.05–0.1 wt% for the operating conditions used. A decay constant of lRb 1.42×10−11 a−1
(Neumann and Huster, 1974) was used for agecalculations. The analytical results and apparentA1.1.2. Isotope analysis
For mineral separation, ca 1.5–2.5 kg of sample ages are given in Table 4.Decomposition of monazite or zircon and chem-material were crushed in a steel mortar and succes-
sively ground in a tungsten carbid mill for a few ical separation of U and Pb largely followed theprocedures suggested by Krogh (1973) for zircon,seconds. After sieving and washing, monazite and
zircon were extracted from the size fraction but using 6 N HCl instead of HF for dissolutionof monazite. A 235U/208Pb mixed spike was used<350 mm by standard magnetic and heavy liquid
techniques. Biotite was enriched from the size for isotope dilution. U and Pb were analysed ona VG Sector 54 multicollector mass spectrometerfraction 250–180 mm with a magnetic separator.
All mineral fractions for U–Pb and Rb–Sr analysis in static and dynamic mode, respectively. Pb wasloaded on rhenium single filaments with silica gelwere carefully handpicked. Biotite for Rb–Sr and
K–Ar analyses was also ground under ethanol to and H3PO4. U was loaded with graphite andH2O on rhenium and analysed using a tripleremove interlayer inclusions. Monazite and zircon
were washed in high purity HCl, H2O and aceton filament configuration. Pb isotope ratios were cor-rected for 0.012% fractionation per atomic massto remove surface contaminations. Mica concen-
trates were washed in ethanol (p.a) in an ultrasonic unit as determined from measured values of NBS981. Total analytical Pb blanks were <0.2 ngbath. For Rb–Sr, K–Ar and 40Ar–39Ar analyses,
dry aliquots of the same biotite separates were during the period of this study. An assumed uncer-tainty in the blank amounts of 50% was used inused.
U–Pb and Rb–Sr isotope analysis of US-380, the error propagation. The calculation of the error
255U. Schussler et al. / Precambrian Research 93 (1999) 235–258
ellipses in Fig. 6 follows Ludwig (1980) and con- the isotope abundances, the mass intensities werecorrected for effects of mass discrimination, step-siders the internal precision (2s) of the mass
spectrometric measurements, an estimated uncer- temperature dependent total-system blank, decayand interfering isotopes produced during irradia-tainty of 0.15% of the U/Pb ratio in the spike,
the error magnification from the spike/sample tion. The error in the 40Ar–39Ar age was calculatedby statistical propagation of in-run uncertainties,ratio and the estimated uncertainty (±1%)
in the isotopic composition of the blank the errors of the correction factors and the blankdeterminations. Total-gas ages were computed byPb (208Pb/204Pb=37.5, 207Pb/204Pb=15.5, 206Pb/
204Pb=17.72). For initial lead correction, isotopic appropriate weighting of the age, percentage 39Arreleased and calculated uncertainty of the indivi-compositions according to the model of Stacey
and Kramers (1975) were employed. Zircons and dual temperature step. A ‘40Ar–39Ar age plateau’is defined by ages recorded by two or more contigu-monazite of the RK12 pegmatite were treated in
a similar way during U–Pb analysis at the ous gas fractions, each representing >5% (andtogether >50%) of the total 39Ar released andBundesanstalt fur Geowissenschaften und
Rohstoffe (BGR). being mutually identical within their calculateduncertainties. Both, the errors of the total-gas andK–Ar and 40Ar–39Ar analyses of biotite sepa-
rates were carried out at the BGR, Hannover. For the plateau ages additionally take into account theuncertainties derived for the flux-calibration factor.conventional K–Ar dating, K was determined by
flame photometry using Li as an internal standard, All ages and element concentrations were calcu-lated using the IUGS recommended constantsAr by total-fusion isotope-dilution static analysis
on a MAT CH4 mass spectrometer (cf Seidel et al., (Steiger and Jager, 1977). All errors quoted arecalculated on the 95% confidence level (2s).1982). Mean intralaboratory uncertainties (2s) in
radiogenic Ar and K are ±0.3 and 1%, respec-tively. Note that our K–Ar date for the standardglauconite GL-O is ca 1% younger than the mean Referencesvalue of the compilation of Odin (1982). For40Ar–39Ar analysis, sample aliquots of ca 15 mg Armienti, P., Ghezzo, C., Innocenti, F., Manetti, P., Rocchi,
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