OSHA Requires That if there are chemicals at your work site… You must be trained in Hazard Communications

OSHA Requires

That if there are chemicals at your work site…

You must be trained in Hazard Communications

Hazard Communication, Labeling, and the MSDS

OSHA Requires

• That when you use a chemical, the MSDS be readily available– Good rule of thumb:

• Within 50 feet indoors• Within 100 feet outdoors

– The custodial department has more MSDS’s than any other department

– Custodial has one book on each floor in each building

OSHA

Hazard Communication Training• Basic Orientation Level• Area-Specific Training• Job-Specific Training

OSHA Standards

CFR 29, Parts 1900-1910• Hazard Communication• Universal Precaution (HIV/Hep B)• Injury and Illness• Emergency Procedures• Hearing Conservation

OSHA Standards

CFR 29, Parts 1900-1910• Respirator• Industrial Truck (Fork Lift)• Confined Space• Fire Extinguisher• Lock Out Protection

OSHA Standards

CFR 29, Parts 1900-1910• Crane• Radiation Safety• There are also rules on:

– Asbestos, Indoor Air Quality (IAQ), Lead, Mercury, and Personal Protective Equipment (PPE)

Government Regulatory Acts

The College is responsible for compliance with many government regulations.

EPA

Environmental Protection Agency• Clean Air• Clean Water• TOSCA• RCRA (Hazardous Waste)• CERCLA (Superfund)• SARA (Title III)• EPCRA (Right to Know)• Endangered Species

EPA

Definition of Hazardous Waste• …any garbage, refuse, sludge from a waste treatment plant, or air

pollution control facility and other discarded material, including solid, liquid, semi-solid, or contained gaseous material resulting from industrial, commercial, mining, and agricultural operations, and from community activities…– Ignitable– Corrosive– Reactive– Toxic

OSHA

Definition of Hazardous Substance

“…a substance or material that presents a physical or health hazard.”

OSHA

Physical Hazards

Bodily harm can result from the physical properties of the substance.

OSHA

Physical Hazards• Compressed gases• Flammable materials• Explosives• Corrosives• Reactives

OSHA

Health Hazards

Exposure can adversely affect an individual’s health.

OSHA

Health Hazards• Irritation• Sensitization• Organ damage• Cancer

OSHA

Toxic Effects of Materials• Acute• Chronic

OSHA

Toxic Effects of Materials• Acute

– Sudden exposure– High concentration of toxic material– Rapid reaction with body tissue

OSHA

Toxic Effects of Materials• Chronic

– Repeated exposure to small concentrations– No immediate reaction to exposure– Effects appear long after exposure

OSHA

Routes of Entry

The four ways toxic materials can enter the body

OSHA

Routes of Entry• Inhalation• Most common route of entry

– Rapidly absorbed in lungs and passed to bloodstream

– Vapors and gases– Particulates– Aerosols and gases

OSHA

Routes of Entry• Absorption through the skin

• Reaction with surface skin• Skin penetrated—sensitization• Multiple skin layers penetrated and toxin enters

bloodstream and causes systemic poisoning

OSHA

Routes of Entry• Ingestion

– Usually not intentional• Keep food away from chemicals• Wash hands before eating, drinking, or smoking

OSHA

Routes of Entry• Injection

– Materials enter through broken skin• Cuts• Sores• Burns• Scratches

OSHA Requires

M aterialS afetyD ataS heet

Training

MATERIAL MSDS No. 259SAFETY Revision No. 006DATA Date: 01/31/98SHEET Page 1 of 2

SECTION I: GENERAL INFORMATION

HILTI, INC.: P.O. Box 21148, Tulsa, OK 74121; Ph: 1 800 879 6000; EmergencyNo.: 1 800-879444

PRODUCT: FS-ONE High Performance Intumescent Firestop Sealant

DESCRIPTION: One-part acrylic-based sealant

For: SALT LAKE COMM COLLEGE/+ P.O. No. P.O. BOX 30808 SALT LAKE CITY, UT 84130-0808

SECTION II: HAZARDOUS INGREDIENTS

INGREDIENTS AND EXPOSURE LIMITS

INGREDIENTS: CAS NUMBER: PEL: TLV: STEL:Vinyl acetate 000108-05-4 NE NE NEAmmonium polyphosphate 007722-76-1 NE NE NEExpandable graphite 012689-13-3 NA NA NAPolyisobutylene 009003-29-6 NE NE NE

PEL = OSHA Permissible Exposure Limit. TVL = ACGIH Threshold Limit Value. These are 8 hour time-weighted averages unless otherwise indicated “C” (Ceiling) or“STEL” (Short Term Exposure Limit). NA = Not Applicable. NE = None Established. ND = Not Determined.

SECTION III: PHYSICAL DATA

APPEARANCE AND ODOR: Red paste. Odorless pH: Not DeterminedBOILING POINT: Approx. 100o C/ 212o F MELTING POINT: Not DetVOC CONTENT: None VAPOR PRESSURE: Not DetEVAPORATION RATE: Not Determined VAPOR DENSITY: 1.5SOLUBILITY IN WATER: Slightly soluble SPECIFIC GRAVITY: Not Det

SECTION IV: FIRE AND EXPLOSION HAZARD DATA

FLASH POINT: Non-Flammable FLAMMABLE LIMITS: Not ApplicableEXTINGUISHING MEDIA: Not applicable. Use extinguishing agent suitable for typeof surrounding fire.SPECIAL FIRE FIGHTING PROCEDURES: A self-contained breathing apparatus

should be worn when fighting fires involving chemicals.UNUSUAL FIRE AND EXPLOSION HAZARDS: None Known

SECTION V: HEALTH HAZARD DATA

KNOW HAZARDS: None Known. CARCINOGENICITY: No ingredients are considered by IARC, NTP, or OSHA PRIMARY ROUTES OF EXPOSURE: DermalSIGNS AND SYMPTOMS OF EXPOSURE: None expectedMEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions

EMERGENCY AND FIRST AID PROCEDURESEYES: Immediately flush with plenty of water while holding eyelids apart. .SKIN: Wipe off material and wash with soap and water. INHALATION: Move victim to fresh air if discomfort develops. INGESTION: Give plenty of water to drink. OTHER: Referral to a physician is recommended

CONTROL MEASURES AND PERSONAL PROTECTIVE EQUIPMENTVENTILATION: General (natural or mechanically induced fresh air movements).EYE PROTECTION: Safety glasses or goggles are recommended SKIN PROTECTION: Gloves are recommended (cotton are sufficient).RESPIRATORY PROTECTION: None normally required.

PRECAUTIONS FOR SAFE HANDLING AND USEHANDLING AND STORING PRECAUTIONS: Avoid contact with the skin. SPILL PROCEDURES: Allow to cure.

SECTION VI: TOXICITY INFORMATION

REGULATORY INFORMATIONHAZARD COMMUNICATION: This MSDS has been prepared in accordance with the

federal OSHA Hazard Communication Standard.HMIS CODES: Health 1, Flammability 0, Reactivity0, PPE BDOT SHIPPING INFO: Non-regulatedTSCA INVENTORY STATUS: Chemical components listed on TSCA inventory.SARA TITLE III, SECTION 313: This product contains 1-4% ethylene glycol (CAS 107-

21-1) which is subject to reporting under Section 313 of SARA Title III (40 CFR Part372).

WASTE DISPOSAL METHODS: Consult with regulatory agencies or corporate personnelfor disposal methods that comply with local, state, and federal health andenvironmental regulations.

HEALTH/SAFETY CONTACTS: Steve Gerrard (x6309), Jerry Metcalf (x6704)

SECTION VII: REACTIVITY DATA

STABILITY: StableHAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition can yield

carbon dioxide an/or carbon monoxide.INCOMPATIBILITY: Strong acids, peroxides and other oxidizing agentsHAZARDOUS POLYMERIZATION: Will not occurCONDITIONS TO AVOID: None Known



HILTI, INC.: P.O. Box 21148, Tulsa, OK 74121; Ph: 1 800 879 6000;Emergency No.: 1 800-879444



For: SALT LAKE COMM COLLEGE/+ P.O. No.P.O. BOX 30808SALT LAKE CITY, UT 84130-0808

Date of Issue







Emergency Telephone #







SECTION II: HAZARDOUS INGREDIENTS

INGREDIENTS AND EXPOSURE LIMITS

INGREDIENTS: CAS NUMBER: PEL: TLV: STEL:

Vinyl acetate 000108-05-4 NE NE NEAmmonium polyphosphate 007722-76-1 NE NE NEExpandable graphite 012689-13-3 NA NA NAPolyisobutylene 009003-29-6 NE NE NE

PEL = OSHA Permissible Exposure Limit. TVL = ACGIH Threshold LimitValue. These are 8 hour time-weighted averages unless otherwiseindicated “C” (Ceiling) or “STEL” (Short Term Exposure Limit). NA = NotApplicable. NE = None Established. ND = Not Determined.

SECTION III: PHYSICAL DATA

APPEARANCE AND ODOR: Red paste. OdorlessBOILING POINT: Approx. 100o C/ 212o FVOC CONTENT: NoneEVAPORATION RATE: Not DeterminedSOLUBILITY IN WATER: Slightly soluble (prior to curing) pH: Not DeterminedMELTING POINT: Not DeterminedVAPOR PRESSURE: Not DeterminedVAPOR DENSITY: 1.5SPECIFIC GRAVITY: Not Determined

VaporDensity

Air = 1.0

SECTION IV: FIRE AND EXPLOSION HAZARD DATA

FLASH POINT: Non-Flammable

FLAMMABLE LIMITS: Not Applicable

EXTINGUISHING MEDIA: Not applicable. Use extinguishing agentsuitable for type of surrounding fire.

SPECIAL FIRE FIGHTING PROCEDURES: A self-contained breathingapparatus should be worn when fighting fires involving chemicals.

UNUSUAL FIRE AND EXPLOSION HAZARDS: None Known

NFPA HAZARD RATING 3 <--Health 1 <--Flammability 0 <--Reactivity <--Special

SECTION VI: TOXICITY INFORMATION

REGULATORY INFORMATION

HAZARD COMMUNICATION: This MSDS has been prepared in accordance withthe federal OSHA Hazard Communication Standard.

HMIS CODES: Health 1, Flammability 0, Reactivity0, PPE B

DOT SHIPPING INFO: Non-regulated

TSCA INVENTORY STATUS: Chemical components listed on TSCA inventory.

SARA TITLE III, SECTION 313: This product contains 1-4% ethylene glycol (CAS107-21-1) which is subject to reporting under Section 313 of SARA Title III (40CFR Part 372).

WASTE DISPOSAL METHODS: Consult with regulatory agencies or corporatepersonnel for disposal methods that comply with local, state, and federal healthand environmental regulations.

HEALTH/SAFETY CONTACTS:Steve Gerrard (x6309), Jerry Metcalf (x6704)

The National Fire Protection Association has a hazardous materials labeling model.

HEALTH HAZARD4–Deadly3–Extreme Danger2–Hazardous1–Slightly Hazardous0–Normal Material

FIRE HAZARDFlash Points4–Below 73o F3–Below 100o F2–Below 200o F1–Above 200o F0–Will not burn

Hazardous MaterialsClassifications







REACTIVITY 4–May detonate 3–Shock and heat may detonate2–Violent chemical change1–Unstable if heated0–Stable



REACTIVITY 4–May detonate 3–Shock and heat may detonate2–Violent chemical change1–Unstable if heated0–Stable

SPECIFICHAZARDOxidizer OXAcid ACIDAlkali ALKCorrosive CORUse NO WATER WRadiation Hazard

• For more information, contact:• Rand Webb

GFSB 126 OfficeMail Stop FCE-mail: [email protected] (office)801-856-6458 (cell)

THANK YOU!For your attention!

Documents

OSHA Requires That if there are chemicals at your work site… You must be trained in Hazard Communications