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1
Technical ReportNREL/TP-560-44256October 2008
Controlled Hydrogen Fleet InfrastructureDemonstration and Validation Project
and
Fall 2008
Composite Data ProductsFinal Version September 24, 2008
Keith Wipke, Sam Sprik, Jennifer Kurtz, and Todd Ramsden
2
Disclaimer and Government License
This work has been authored by Midwest Research Institute (MRI) under Contract No. DE-AC36-99GO10337 with the U.S. Department of Energy (the “DOE”). The United States Government (the “Government”) retains and the publisher, by accepting the work for publication, acknowledges that the Government retains a non-exclusive, paid-up, irrevocable, worldwide license to publish or reproduce the published form of this work, or allow others to do so, for Government purposes.
Neither MRI, the DOE, the Government, nor any other agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe any privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not constitute or imply its endorsement, recommendation, or favoring by the Government or any agency thereof. The views and opinions of the authors and/or presenters expressed herein do not necessarily state or reflect those of MRI, the DOE, the Government, or any agency thereof.
3
Controlled Hydrogen Fleet and Infrastructure Demonstration and
Validation ProjectFall 2008
Composite Data ProductsSeptember 24, 2008 (Final)
Keith Wipke, Sam Sprik, Jennifer Kurtz, Todd Ramsden
4
0200
400600
8001000
1200
14001600
18002000
22002400
2006 Target
2009 Target
Actual Operating Hours Accumulated To-Date Projected Hours to 10% Degradation
Max Hrs Accumulated (1)(2) Avg Hrs Accumulated (1)(3) Projection to 10% Degradation (4)(5)(6)
Tim
e (H
ours
)
DOE Learning Demonstration Fuel Cell Stack Durability:Based on Data Through 2008 Q2
Max ProjectionAvg Projection
Created: Sep-03-08 10:36 AM
(1) Range bars created using one data point for each OEM. Some stacks have accumulated hours beyond 10% voltage degradation.(2) Range (highest and lowest) of the maximum operating hours accumulated to-date of any OEM's individual stack in "real-world" operation.(3) Range (highest and lowest) of the average operating hours accumulated to-date of all stacks in each OEM's fleet.(4) Projection using on-road data -- degradation calculated at high stack current. This criterion is used for assessing progress against DOE targets, may differ from OEM's end-of-life criterion, and does not address "catastrophic" failure modes, such as membrane failure.(5) Using one nominal projection per OEM: "Max Projection" = highest nominal projection, "Avg Projection" = average nominal projection. The shaded green bar represents an engineering judgment of the uncertainty on the "Avg Projection" due to data and methodology limitations. Projections will change as additional data are accumulated.(6) Projection method was modified beginning with 2008 Q2 data.
CDP#1: Hours Accumulated and Projected Hours to 10% Stack Voltage Degradation
5
Dyno Range (2) Window-Sticker Range (3) On-Road Range (4)(5)0
50
100
150
200
250
300
Vehi
cle
Ran
ge (m
iles)
Vehicle Range1
2015 Target2009 Target Gen 1 Gen 2
Created: Sep-22-08 11:51 AM
(1) Range is based on fuel economy and usable hydrogen on-board the vehicle. One data point for each make/model.(2) Fuel economy from unadjusted combined City/Hwy per DRAFT SAE J2572.(3) Fuel economy from EPA Adjusted combined City/Hwy (0.78 x Hwy, 0.9 x City).(4) Excludes trips < 1 mile. One data point for on-road fleet average of each make/model.(5) Fuel economy calculated from on-road fuel cell stack current or mass flow readings.
CDP#2: Vehicle Range
6
Dyno (1) Window-Sticker (2) On-Road (3)(4)0
10
20
30
40
50
60
70
80
Fuel
Eco
nom
y (m
iles/
kg H
2)
Fuel Economy
Gen 1 Gen 2
Created: Sep-22-08 11:51 AM
(1) One data point for each make/model. Combined City/Hwy fuel economy per DRAFT SAE J2572.(2) Adjusted combined City/Hwy fuel economy (0.78 x Hwy, 0.9 x City).(3) Excludes trips < 1 mile. One data point for on-road fleet average of each make/model.(4) Calculated from on-road fuel cell stack current or mass flow readings.
CDP#6: Fuel Economy
7
0
10
20
30
40
50
60
70
All OEMs
Effic
ienc
y (%
)
Fuel Cell System1 Efficiency2 at ~25% Net Power.
DOE Target
Created: Aug-29-06 4:09 PM
1 Gross stack power minus fuel cell system auxiliaries, per DRAFT SAEJ2615.
2 Ratio of DC output energy to the lower heating value of the input fuel (hydrogen).Excludes power electronics and electric drive.
CDP#8: FC System Efficiency
8
CDP#9: Safety Reports – Vehicles
9
350bar 700bar0
1
2
3
4
5
6
7
8
9
Wei
ght P
erce
nt H
ydro
gen
(%)
Weight Percent Hydrogen
2015 DOE MYPP Target1
2010 DOE MYPP Target1
2007 DOE MYPP Target1
Created: Aug-19-08 11:39 AM1Targets are set for advanced materials-based hydrogen storage technologies.
CDP#10: Storage Weight % Hydrogen
10
350bar 700bar0
0.01
0.02
0.03
0.04
0.05
0.06
0.07
0.08
0.09
0.1
Mas
s H
2 pe
r Lite
r (kg
/L)
Mass of Hydrogen Per Liter
2015 DOE MYPP Target1
2010 DOE MYPP Target1
2007 DOE MYPP Target1
Created: Aug-19-08 11:39 AM1Targets are set for advanced materials-based hydrogen storage technologies.
CDP#11: Volumetric Capacity of H2 Storage
11
0
2000
4000
6000
8000
10000
12000
14000
16000
18000
Num
ber o
f cyc
les
Hydrogen Tank Cycle Life1
All OEMs
2015 DOE MYPP Target2
2010 DOE MYPP Target2
2007 DOE MYPP Target2 Gen 1 Gen 2
Created: Sep-17-08 10:29 AM
1Data reported reference NGV2, HGV2, or EIHP standards.2Some near-term targets have been achieved with compressed and liquid tanks. Emphasis is on advanced materials-based technologies.
CDP#12: Vehicle Hydrogen Tank Cycle Life
12
On-Site Natural Gas Reforming On-Site Electrolysis0
10
20
30
40
50
60
70
80
2010 MYPP Target2015 MYPP Target
2012 MYPP Target
2017 MYPP Target
Prod
uctio
n Ef
ficie
ncy
(LH
V %
)
Hydrogen Production Conversion Efficiency1
Average Station EfficiencyQuarterly Efficiency DataHighest Quarterly Efficiency
Created: Sep-24-08 4:17 PM
1Production conversion efficiency is defined as the energy of the hydrogen out of the process (on an LHV basis) divided by the sum of the energy into the productionprocess from the feedstock and all other energy as needed. Conversion efficiency does not include energy used for compression, storage, and dispensing.
CDP#13: On-Site Hydrogen Production Efficiency
13
0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 20
100
200
300
400
500
600
700
800
Avg Fuel Rate (kg/min)
Num
ber o
f Fue
ling
Even
tsHistogram of Fueling Rates
All Light Duty Through 2008Q2
5 minute fill of5 kg at 350 bar
3 minute fill of5 kg at 350 bar
11594 EventsAverage = 0.80 kg/min
25% >1 kg/min
2006 Tech Val Milestone2010 MYPP Adv Storage Materials Target
Created: Sep-02-08 4:10 PM
CDP#18: Refueling Rates
14
0 20 40 60 80 100 120 140 160 180
Non-Event
Near Miss
Incident
Number of Reports
Seve
rity
Total Infrastructure Safety Reports by Severityand Report Type Through 2008 Q2
Alarms OnlyAutomatic System ShutdownElectrical IssueEquipment MalfunctionFalse Alarm/MischiefH2 Release - Minor, NO IgnitionH2 Release - Significant, NO IgnitionManual System ShutdownNon-H2 ReleaseSite Power OutageStructural IssueSystem Trouble, not Alarm
Created: Sep-02-08 5:01 PM
An INCIDENT is an event that results in: - a lost time accident and/or injury to personnel - damage/unplanned downtime for project equipment, facilities or property - impact to the public or environment - any hydrogen release that unintentionally ignites or is sufficient to sustain a flame if ignited - release of any volatile, hydrogen containing compound (other than the hydrocarbons used as common fuels)A NEAR-MISS is: - an event that under slightly different circumstances could have become an incident - unplanned H2 release insufficient to sustain a flame
CDP#20: Safety Reports – Infrastructure
15
0 2 4 6 8 10 12-30
-20
-10
0
10
20
30
40
50
60
0.9 % trips below 0 oC
Max Op = 125.6 oF
Min Op = -1.3 oF
25.1 % trips above 28 oC
Frequency [%]
Tem
pera
ture
[o C]
Average Ambient Trip Temperature: All OEMs
Created: Sep-03-08 10:41 AM
CDP#21: Range of Ambient TemperatureDuring Vehicle Operation
16
CDP#22: Vehicle Operating Hours
17
CDP#23: Vehicles vs. Miles Traveled
18
CDP#24: Cumulative Vehicle Miles Traveled
19
CDP#25: Vehicle H2 Storage Technologies
20
CDP#26: Cumulative H2 Produced or Dispensed
21
Ref. Elec. Del. Ref. Elec. Del. Ref. Elec. Del.99.7
99.75
99.8
99.85
99.9
99.95
100
Cal
cula
ted
H2 In
dex
(%)
H2 Calculated Quality Index by Year and Production Method
On-Site NG Reformer (Data Range)On-Site Electrolysis (Data Range)Delivered (Data Range)SAE J2719 APR2008 GuidelineCalculated Data
Created: Sep-22-08 1:41 PM
Data is from Learning Demonstration and California Fuel Cell Partnership testingYear 1 is 2005Q3-2006Q2, Year 2 is 2006Q3-2007Q2, and Year 3 is 2007Q3-2008Q2
Year 1 Year 2 Year 3
CDP#27: Hydrogen Quality Index
22
0 1 2 3 4 5 6 7 8 9 10
Particulates
μg/L
H2 Impurities
Data Range SAE J2719 APR2008 Guideline Measured Less Than or Equal To (Detection Limited)
0 500 1000 1500 2000 2500 3000
(N2+He+Ar) He
(Ar+N2)
0 5 10 15 20 25 30 35 40
H2O Total HC
O2 CO2 CO
NH3
μmol/mol (ppm)
0 10 20 30 40 50 60 70 80
Total S*
nmol/mol (ppb)Created: Sep-22-08 1:41 PM Data is from Learning Demonstration and California Fuel Cell Partnership testing
*Total S calculated from SO2, COS, H2S, CS2, and Methyl Mercaptan (CH3SH).
CDP #28: Hydrogen Impurities
Ref. Elec. Del. Ref. Elec. Del. Ref. Elec. Del.0
1
2
3
4
5
6
7
8
9
10
11
Part
icul
ate
Con
cent
ratio
n ( µ
g/L)
Particulate Concentration (µg/L)H2 Impurities by Year and Production Method
On-Site NG Reformer (Data Range)On-Site Electrolysis (Data Range)Delivered (Data Range)SAE J2719 APR2008 GuidelineMeasuredLess Than or Equal To (Detection Limited)
Created: Sep-22-08 1:42 PM
Data is from Learning Demonstration and California Fuel Cell Partnership testingYear 1 is 2005Q3-2006Q2, Year 2 is 2006Q3-2007Q2, and Year 3 is 2007Q3-2008Q2
Year 1 Year 2 Year 3
CDP#28 Supplemental: Hydrogen Impurities by Year and Production Method
23
CDP#28 Supplemental: Hydrogen Impurities by Year and Production Method
Ref. Elec. Del. Ref. Elec. Del. Ref. Elec. Del.0
500
1000
1500
2000
2500
3000
Cal
culta
ted
Tota
l Im
purit
ies
( µm
ol/m
ol)(p
pm)
Calcultated Total Impurities (µmol/mol)(ppm)H2 Impurities by Year and Production Method
On-Site NG Reformer (Data Range)On-Site Electrolysis (Data Range)Delivered (Data Range)SAE J2719 APR2008 GuidelineCalculated Data
Created: Sep-22-08 1:41 PM
Data is from Learning Demonstration and California Fuel Cell Partnership testingYear 1 is 2005Q3-2006Q2, Year 2 is 2006Q3-2007Q2, and Year 3 is 2007Q3-2008Q2
Year 1 Year 2 Year 3
Ref. Elec. Del. Ref. Elec. Del. Ref. Elec. Del.0
0.5
1
1.5
2
2.5
3
3.5
4
4.5
5
5.5
H2O
( µm
ol/m
ol)(p
pm)
H2O (µmol/mol)(ppm)H2 Impurities by Year and Production Method
On-Site NG Reformer (Data Range)On-Site Electrolysis (Data Range)Delivered (Data Range)SAE J2719 APR2008 GuidelineMeasuredLess Than or Equal To (Detection Limited)
Created: Sep-22-08 1:41 PM
Data is from Learning Demonstration and California Fuel Cell Partnership testingYear 1 is 2005Q3-2006Q2, Year 2 is 2006Q3-2007Q2, and Year 3 is 2007Q3-2008Q2
Year 1 Year 2 Year 3
CDP#28 Supplemental: Hydrogen Impurities by Year and Production Method
Ref. Elec. Del. Ref. Elec. Del. Ref. Elec. Del.0
0.5
1
1.5
2
Tota
l HC
( µm
ol/m
ol)(p
pm)
Total HC (µmol/mol)(ppm)H2 Impurities by Year and Production Method
On-Site NG Reformer (Data Range)On-Site Electrolysis (Data Range)Delivered (Data Range)SAE J2719 APR2008 GuidelineMeasuredLess Than or Equal To (Detection Limited)
Created: Sep-22-08 1:41 PM
Data is from Learning Demonstration and California Fuel Cell Partnership testingYear 1 is 2005Q3-2006Q2, Year 2 is 2006Q3-2007Q2, and Year 3 is 2007Q3-2008Q2
Year 1 Year 2 Year 3
CDP#28 Supplemental: Hydrogen Impurities by Year and Production Method
Ref. Elec. Del. Ref. Elec. Del. Ref. Elec. Del.0
5
10
15
20
25
30
35
40
O2( µ
mol
/mol
)(ppm
)
O2(µmol/mol)(ppm)H2 Impurities by Year and Production Method
On-Site NG Reformer (Data Range)On-Site Electrolysis (Data Range)Delivered (Data Range)SAE J2719 APR2008 GuidelineMeasuredLess Than or Equal To (Detection Limited)
Created: Sep-22-08 1:41 PM
Data is from Learning Demonstration and California Fuel Cell Partnership testingYear 1 is 2005Q3-2006Q2, Year 2 is 2006Q3-2007Q2, and Year 3 is 2007Q3-2008Q2
Year 1 Year 2 Year 3
CDP#28 Supplemental: Hydrogen Impurities by Year and Production Method
Ref. Elec. Del. Ref. Elec. Del. Ref. Elec. Del.0
50
100
150
200
250
300
He
( µm
ol/m
ol)(p
pm)
He (µmol/mol)(ppm)H2 Impurities by Year and Production Method
On-Site NG Reformer (Data Range)On-Site Electrolysis (Data Range)Delivered (Data Range)SAE J2719 APR2008 GuidelineMeasuredLess Than or Equal To (Detection Limited)
Created: Sep-22-08 1:41 PM
Data is from Learning Demonstration and California Fuel Cell Partnership testingYear 1 is 2005Q3-2006Q2, Year 2 is 2006Q3-2007Q2, and Year 3 is 2007Q3-2008Q2
Year 1 Year 2 Year 3
CDP#28 Supplemental: Hydrogen Impurities by Year and Production Method
Ref. Elec. Del. Ref. Elec. Del. Ref. Elec. Del.0
500
1000
1500
2000
2500
N2 ( µ
mol
/mol
)(ppm
)
N2 (µmol/mol)(ppm)H2 Impurities by Year and Production Method
On-Site NG Reformer (Data Range)On-Site Electrolysis (Data Range)Delivered (Data Range)SAE J2719 APR2008 GuidelineMeasuredLess Than or Equal To (Detection Limited)
Created: Sep-22-08 1:42 PM
Data is from Learning Demonstration and California Fuel Cell Partnership testingYear 1 is 2005Q3-2006Q2, Year 2 is 2006Q3-2007Q2, and Year 3 is 2007Q3-2008Q2
Year 1 Year 2 Year 3
CDP#28 Supplemental: Hydrogen Impurities by Year and Production Method
Ref. Elec. Del. Ref. Elec. Del. Ref. Elec. Del.0
50
100
150
200
Ar (µm
ol/m
ol)(p
pm)
Ar (µmol/mol)(ppm)H2 Impurities by Year and Production Method
On-Site NG Reformer (Data Range)On-Site Electrolysis (Data Range)Delivered (Data Range)SAE J2719 APR2008 GuidelineMeasuredLess Than or Equal To (Detection Limited)
Created: Sep-22-08 1:42 PM
Data is from Learning Demonstration and California Fuel Cell Partnership testingYear 1 is 2005Q3-2006Q2, Year 2 is 2006Q3-2007Q2, and Year 3 is 2007Q3-2008Q2
Year 1 Year 2 Year 3
CDP#28 Supplemental: Hydrogen Impurities by Year and Production Method
Ref. Elec. Del. Ref. Elec. Del. Ref. Elec. Del.0
500
1000
1500
2000
2500
Ar+
N2 ( µ
mol
/mol
)(ppm
)
Ar+N2 (µmol/mol)(ppm)H2 Impurities by Year and Production Method
On-Site NG Reformer (Data Range)On-Site Electrolysis (Data Range)Delivered (Data Range)SAE J2719 APR2008 GuidelineMeasuredLess Than or Equal To (Detection Limited)
Created: Sep-22-08 1:42 PM
Data is from Learning Demonstration and California Fuel Cell Partnership testingYear 1 is 2005Q3-2006Q2, Year 2 is 2006Q3-2007Q2, and Year 3 is 2007Q3-2008Q2
Year 1 Year 2 Year 3
CDP#28 Supplemental: Hydrogen Impurities by Year and Production Method
Ref. Elec. Del. Ref. Elec. Del. Ref. Elec. Del.0
500
1000
1500
2000
2500
3000
N2+H
e+A
r (µm
ol/m
ol)(p
pm)
N2+He+Ar (µmol/mol)(ppm)H2 Impurities by Year and Production Method
On-Site NG Reformer (Data Range)On-Site Electrolysis (Data Range)Delivered (Data Range)SAE J2719 APR2008 GuidelineMeasuredLess Than or Equal To (Detection Limited)
Created: Sep-22-08 1:42 PM
Data is from Learning Demonstration and California Fuel Cell Partnership testingYear 1 is 2005Q3-2006Q2, Year 2 is 2006Q3-2007Q2, and Year 3 is 2007Q3-2008Q2
Year 1 Year 2 Year 3
CDP#28 Supplemental: Hydrogen Impurities by Year and Production Method
Ref. Elec. Del. Ref. Elec. Del. Ref. Elec. Del.0
1
2
3
4
5
6
7
8
9
CO
2 ( µm
ol/m
ol)(p
pm)
CO2 (µmol/mol)(ppm)H2 Impurities by Year and Production Method
On-Site NG Reformer (Data Range)On-Site Electrolysis (Data Range)Delivered (Data Range)SAE J2719 APR2008 GuidelineMeasuredLess Than or Equal To (Detection Limited)
Created: Sep-22-08 1:42 PM
Data is from Learning Demonstration and California Fuel Cell Partnership testingYear 1 is 2005Q3-2006Q2, Year 2 is 2006Q3-2007Q2, and Year 3 is 2007Q3-2008Q2
Year 1 Year 2 Year 3
CDP#28 Supplemental: Hydrogen Impurities by Year and Production Method
Ref. Elec. Del. Ref. Elec. Del. Ref. Elec. Del.0
0.2
0.4
0.6
0.8
1
CO
( µm
ol/m
ol)(p
pm)
CO (µmol/mol)(ppm)H2 Impurities by Year and Production Method
On-Site NG Reformer (Data Range)On-Site Electrolysis (Data Range)Delivered (Data Range)SAE J2719 APR2008 GuidelineMeasuredLess Than or Equal To (Detection Limited)
Created: Sep-22-08 1:42 PM
Data is from Learning Demonstration and California Fuel Cell Partnership testingYear 1 is 2005Q3-2006Q2, Year 2 is 2006Q3-2007Q2, and Year 3 is 2007Q3-2008Q2
Year 1 Year 2 Year 3
CDP#28 Supplemental: Hydrogen Impurities by Year and Production Method
Ref. Elec. Del. Ref. Elec. Del. Ref. Elec. Del.0
10
20
30
40
50
60
70
Tota
l S* (
nmol
/mol
)(ppb
)
Total S* (nmol/mol)(ppb)H2 Impurities by Year and Production Method
On-Site NG Reformer (Data Range)On-Site Electrolysis (Data Range)Delivered (Data Range)SAE J2719 APR2008 GuidelineMeasuredLess Than or Equal To (Detection Limited)
Created: Sep-22-08 1:42 PM
Data is from Learning Demonstration and California Fuel Cell Partnership testingYear 1 is 2005Q3-2006Q2, Year 2 is 2006Q3-2007Q2, and Year 3 is 2007Q3-2008Q2*Total S calculated from SO2, COS, H2S, CS2, and Methyl Mercaptan (CH3SH).
Year 1 Year 2 Year 3
CDP#28 Supplemental: Hydrogen Impurities by Year and Production Method
Ref. Elec. Del. Ref. Elec. Del. Ref. Elec. Del.0
0.02
0.04
0.06
0.08
0.1
Form
alde
hyde
(µm
ol/m
ol)(p
pm)
Formaldehyde (µmol/mol)(ppm)H2 Impurities by Year and Production Method
On-Site NG Reformer (Data Range)On-Site Electrolysis (Data Range)Delivered (Data Range)SAE J2719 APR2008 GuidelineMeasuredLess Than or Equal To (Detection Limited)
Created: Sep-22-08 1:42 PM
Data is from Learning Demonstration and California Fuel Cell Partnership testingYear 1 is 2005Q3-2006Q2, Year 2 is 2006Q3-2007Q2, and Year 3 is 2007Q3-2008Q2
Year 1 Year 2 Year 3
CDP#28 Supplemental: Hydrogen Impurities by Year and Production Method
Ref. Elec. Del. Ref. Elec. Del. Ref. Elec. Del.0
0.05
0.1
0.15
0.2
Form
ic a
cid
( µm
ol/m
ol)(p
pm)
Formic acid (µmol/mol)(ppm)H2 Impurities by Year and Production Method
On-Site NG Reformer (Data Range)On-Site Electrolysis (Data Range)Delivered (Data Range)SAE J2719 APR2008 GuidelineMeasuredLess Than or Equal To (Detection Limited)
Created: Sep-22-08 1:42 PM
Data is from Learning Demonstration and California Fuel Cell Partnership testingYear 1 is 2005Q3-2006Q2, Year 2 is 2006Q3-2007Q2, and Year 3 is 2007Q3-2008Q2
Year 1 Year 2 Year 3
CDP#28 Supplemental: Hydrogen Impurities by Year and Production Method
Ref. Elec. Del. Ref. Elec. Del. Ref. Elec. Del.0
1
2
3
4
5
6
NH
3 ( µ
mol
/mol
)(ppm
)
NH3 (µmol/mol)(ppm)H2 Impurities by Year and Production Method
On-Site NG Reformer (Data Range)On-Site Electrolysis (Data Range)Delivered (Data Range)SAE J2719 APR2008 GuidelineMeasuredLess Than or Equal To (Detection Limited)
Created: Sep-22-08 1:42 PM
Data is from Learning Demonstration and California Fuel Cell Partnership testingYear 1 is 2005Q3-2006Q2, Year 2 is 2006Q3-2007Q2, and Year 3 is 2007Q3-2008Q2
Year 1 Year 2 Year 3
CDP#28 Supplemental: Hydrogen Impurities by Year and Production Method
Ref. Elec. Del. Ref. Elec. Del. Ref. Elec. Del.0
5
10
15
20
25
Tota
l Hal
ogen
ates
(µm
ol/m
ol)(p
pm)
Total Halogenates (µmol/mol)(ppm)H2 Impurities by Year and Production Method
On-Site NG Reformer (Data Range)On-Site Electrolysis (Data Range)Delivered (Data Range)SAE J2719 APR2008 GuidelineMeasuredLess Than or Equal To (Detection Limited)
Created: Sep-22-08 1:42 PM
Data is from Learning Demonstration and California Fuel Cell Partnership testingYear 1 is 2005Q3-2006Q2, Year 2 is 2006Q3-2007Q2, and Year 3 is 2007Q3-2008Q2
Year 1 Year 2 Year 3
CDP#28 Supplemental: Hydrogen Impurities by Year and Production Method
Ref. Elec. Del. Ref. Elec. Del. Ref. Elec. Del.0
5000
10000
15000
20000
25000
30000
Part
icul
ate
Size
(µm
)
Particulate Size (µm)H2 Impurities by Year and Production Method
On-Site NG Reformer (Data Range)On-Site Electrolysis (Data Range)Delivered (Data Range)SAE J2719 APR2008 GuidelineMeasuredLess Than or Equal To (Detection Limited)
Created: Sep-22-08 1:42 PM
Data is from Learning Demonstration and California Fuel Cell Partnership testingYear 1 is 2005Q3-2006Q2, Year 2 is 2006Q3-2007Q2, and Year 3 is 2007Q3-2008Q2
Year 1 Year 2 Year 3
CDP#28 Supplemental: Hydrogen Impurities by Year and Production Method
24
0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 20
100
200
300
400
500
600
700
Avg Fuel Rate (kg/min)
Num
ber o
f Fue
ling
Even
tsHistogram of Fueling Rates
Comm vs Non-Comm Fills - All Light Duty Through 2008Q2
5 minute fill of5 kg at 350 bar
3 minute fill of5 kg at 350 bar
Fill Type Avg (kg/min) %>1 ------------- ------------------ -------Comm 0.94 36%Non-Comm 0.68 17%
CommNon-Comm2006 Tech Val Milestone2010 MYPP Adv Storage Materials Target
Created: Sep-02-08 4:59 PM
CDP#29: Fueling Rates – Communication and Non-Communication Fills
25
0 20 40 60 80 100 120 140 160 180 200
AdjustmentCheck Only
OtherRepair
Replacement
Maintenance: Average Labor Hours Per Station Since InceptionThrough 2008 Q2
ScheduledUn-Scheduled
0 5 10 15 20 25 30 35 40
AdjustmentCheck Only
OtherRepair
Replacement
Maintenance: Average Number of Events Per Station Since Inception
0% 10% 20% 30% 40% 50% 60% 70% 80% 90% 100%
# of EventsHours
Comparison of Scheduled/Un-Scheduled Maintenance
Created: Aug-08-08 4:37 PM
CDP#30: Infrastructure Maintenance
26
CDP#31: Number of Reporting Stations
27
CDP#32: Infrastructure Hydrogen Production Methods
28
0 10 20 30 40 50 60 70 80 90 1000
1
2
3
4
5
6
7
8
9
10
11
12Range Histogram: All OEMs
Percentage of chassis dyno range1 b/w refuelings
Perc
enta
ge o
f Ref
uelin
gs
0 10 20 30 40 50 60 70 80 90 1000
25
50
75
100
Cum
ulat
ive
Perc
enta
ge
Created: Sep-22-08 11:51 AM
Total refuelings2 = 16175
1. Range calculated using the combined City/Hwy fuel economy from dyno testing (not EPAadjusted) and usable fuel on board.2. Some refueling events are not detected/reported due to data noise or incompleteness.
CDP#33: Percentage of Theoretical Range Traveled Between Refuelings
29
0 10 20 30 40 50 60 70 80 90 100
Gen1
Gen2
Vehicle Range Factors
Percentage of chassis dyno range1.
All
OEM
s Win
dow
-Stic
ker
2 W
indo
w-S
ticke
r 2
On-
Roa
d 3
On-
Roa
d 3
Dyn
o 1
Created: Sep-22-08 11:52 AM
1. Calculated using the combined City/Hwy fuel economy from dyno testing (non-adjusted)and usable fuel on board.2. Applying window-sticker correction factors for fuel economy: 0.78 x Hwy and 0.9 x City.3. Using fuel economy from on-road data (excluding trips > 1 mile, consistent with other data products).
CDP#34: Effective Vehicle Range
30
05Q2 05Q3 05Q4 06Q1 06Q2 06Q3 06Q4 07Q1 07Q2 07Q3 07Q4 08Q1 08Q20
2
4
6
8
10
12
14
16
18
Reporting Period
Num
ber o
f Sta
tions
Infrastructure Safety Trend and Online Stations Through 2008 Q2
Number of Online StationsAvg Refuelings Between Safety Reports
Created: Sep-02-08 5:02 PM
0
20
40
60
80
100
120
140
160
180
200
Avg
# o
f Ref
uelin
gs B
etw
een
Safe
ty R
epor
ts
7 11
32 34
88
102
117
47
75
124
100
58
44
CDP#35: Average Refuelings Between Infrastructure Safety Reports
31
05Q2 05Q3 05Q4 06Q1 06Q2 06Q3 06Q4 07Q1 07Q2 07Q3 07Q4 08Q1 08Q20
5
10
15
20
25
30
35
40
Reporting Period
Num
ber o
f Rep
orts
Type of Infrastructure Safety Reports by Quarter Through 2008 Q2
IncidentNear MissNon-EventStations OnlineAvg # Reports/Station
Created: Sep-02-08 5:02 PM
An INCIDENT is an event that results in: - a lost time accident and/or injury to personnel - damage/unplanned downtime for project equipment, facilities or property - impact to the public or environment - any hydrogen release that unintentionally ignites or is sufficient to sustain a flame if ignited - release of any volatile, hydrogen containing compound (other than the hydrocarbons used as common fuels)A NEAR-MISS is: - an event that under slightly different circumstances could have become an incident - unplanned H2 release insufficient to sustain a flame
CDP#36: Type of Infrastructure Safety Report By Quarter
32
0 20 40 60 80 100 120 140 160 180
Non-Event
Near Miss
Incident
Number of Reports
Seve
rity
Primary Factors of Infrastructure Safety ReportsThrough 2008 Q2
Calibration/Settings/ Software ControlsDesign FlawEnvironment (Weather, Power Disruption, Other)False AlarmInadequate Training, Protocol, SOPInadequate/ Non-working EquipmentMaintenance RequiredMischief, Vandalism, SabotageNew Equipment MaterialsNot Yet DeterminedOperator/Personnel Error
Created: Sep-02-08 5:01 PM
An INCIDENT is an event that results in: - a lost time accident and/or injury to personnel - damage/unplanned downtime for project equipment, facilities or property - impact to the public or environment - any hydrogen release that unintentionally ignites or is sufficient to sustain a flame if ignited - release of any volatile, hydrogen containing compound (other than the hydrocarbons used as common fuels)A NEAR-MISS is: - an event that under slightly different circumstances could have become an incident - unplanned H2 release insufficient to sustain a flame
CDP#37: Primary Factors of Infrastructure Safety Reports
33
0 2 4 6 8 10 12 14 16 18 200
200
400
600
800
1000
1200
1400
1600
1800
Time (min)
Num
ber o
f Fue
ling
Even
ts
Histogram of Fueling TimesAll Light Duty Through 2008Q2
Average = 3.23 % <5 = 88
Created: Sep-02-08 4:21 PM
CDP#38: Refueling Times
34
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 50
50
100
150
200
250
300
350
400
450
Amount Fueled (kg)
Num
ber o
f Fue
ling
Even
tsHistogram of Fueling AmountsAll Light Duty Through 2008Q2
Average = 2.24
Created: Sep-02-08 4:21 PM
CDP#39: Refueling Amounts
35
Tank Levels: DOE Fleet
15%
FE
Created: Sep-19-08 10:35 AM
Total refuelings1 = 18060
1. Some refueling events not recorded/detected due to data noise or incompleteness.
Median Tank Level (At Fill) = 39%
2. The outer arc is set at 20% total refuelings.3. If tank level at fill was not available, a complete fill up was assumed.
CDP#40: H2 Tank Level at Refueling
36
FE
Tank Level Medians (At Fill): DOE Fleet, All Vehicles
Created: Sep-19-08 10:35 AM
Total refuelings1 = 18060
1. Some refueling events not recorded/detected due to data noise or incompleteness.2. If tank level at fill was not available, a complete fill up was assumed.
CDP#41: Refueling Tank Levels - Medians
37
Refueling by Time of Day: DOE Fleet
9%
3
12
9
6
Created: Sep-19-08 10:35 AM
Total Fill3 Events = 15158% of fills b/t 6 AM & 6 PM: 90.4%
1. Fills between 6 AM & 6 PM
2. The outer arc is set at 12 % total Fill.
3. Some events not recorded/detected due to data noise or incompleteness.
AM PM
CDP#42: Refueling by Time of Day
38
Sunday Monday Tuesday Wednesday Thursday Friday Saturday0
5
10
15
20
Fills by Day of Week: DOE Fleet
% o
f Fill
s in
a D
ay
DayCreated: Sep-19-08 10:35 AM
CDP#43: Refueling by Day of Week
39
Driving Start Time - Day: DOE Fleet
10%
3
12
9
6
DOE FleetNHTS
Created: Aug-29-08 9:49 AM
Total Driving3 Events = 181174% of driving trips b/t 6 AM & 6 PM: 88.4%
1. Driving trips between 6 AM & 6 PM
2. The outer arc is set at 12 % total Driving.
3. Some events not recorded/detected due to data noise or incompleteness.
AM PM
% of NHTS trips b/t 6 AM & 6 PM: 81.5%
2001 NHTS Data Includes Car, Truck, Van, & SUV day trips ASCII.csv Source: http://nhts.ornl.gov/download.shtml#2001
CDP#44: Driving Start Time – Day
40
Sunday Monday Tuesday Wednesday Thursday Friday Saturday0
2
4
6
8
10
12
14
16
18
20
Driving Trips by Day of Week: DOE Fleet
% o
f Driv
ing
Trip
s in
a D
ay
Day
DOE FleetNHTS
Created: Aug-29-08 9:49 AM
2001 NHTS Data Includes Car, Truck, Van, & SUV day tripsASCII.csv Source: http://nhts.ornl.gov/download.shtml#2001
CDP#45: Driving by Day of Week
41
0
5
10
15
20
25
30
35
40
45
50%Time at Power Levels: DOE Fleet
% T
ime
at P
ower
Lev
el
0-5%
5-10%
10-15
%15
-20%
20-25
%25
-30%
30-35
%35
-40%
40-45
%45
-50%
50-55
%55
-60%
60-65
%65
-70%
70-75
%75
-80%
80-85
%85
-90%
90-95
%95
-100%
>100%
% Fuel Cell Power (Gross) of MaxCreated: Aug-28-08 5:48 PM
18.4%-43.7% of operating time at idle(Vehicle Speed = 0 & F.C. Power > 0)
CDP#46: Fuel Cell System Operating Power
42
0 5 10 15 20 250
5
10
15
20
25
30
35
40
45
Freq
uenc
y (%
)
Trip Length (miles)
Trip Length: DOE Fleet
DOE FleetNHTS
Created: Sep-03-08 11:06 AM2001 NHTS Data Includes Car, Truck, Van, & SUV day tripsASCII.csv Source: http://nhts.ornl.gov/download.shtml#2001
CDP#47: Trip Length
43
CDP#48: Primary Factors Affecting Learning Demo Fleet Fuel Cell Degradation
44
CDP#49: Primary Factors Affecting Learning Demo Team Fuel Cell Degradation
45
Refueling by Time of Night: DOE Fleet
4%
3
12
9
6
Created: Sep-19-08 10:35 AM
Total Fill3 Events = 15158% of fills b/t 6 PM & 6 AM: 9.6%
1. Fills between 6 PM & 6 AM
2. The outer arc is set at 12 % total Fill.
3. Some events not recorded/detected due to data noise or incompleteness.
PM AM
CDP#50: Refueling by Time of Night
46
Driving Start Time - Night: DOE Fleet
3%
3
12
9
6
DOE FleetNHTS
Created: Aug-29-08 9:49 AM
Total Driving3 Events = 181174% of driving trips b/t 6 PM & 6 AM: 11.6%
1. Driving trips between 6 PM & 6 AM
2. The outer arc is set at 12 % total Driving.
3. Some events not recorded/detected due to data noise or incompleteness.
PM AM
% of NHTS trips b/t 6 PM & 6 AM: 18.4%
2001 NHTS Data Includes Car, Truck, Van, & SUV day trips ASCII.csv Source: http://nhts.ornl.gov/download.shtml#2001
CDP#51: Driving Start Time – Night
47
0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 20
50
100
150
200
250
300
350
Avg Fuel Rate (kg/min)
Num
ber o
f Fue
ling
Even
tsHistogram of Fueling Rates
All Light Duty by Year Through 2008Q2
5 minute fill of5 kg at 350 bar
3 minute fill of5 kg at 350 bar
Year Avg (kg/min) %>1 ------- ----------------- -------2005 0.66 16%2006 0.74 21%2007 0.81 26%2008 0.86 28%
20052006200720082006 Tech Val Milestone2010 MYPP Adv Storage Materials Target
Created: Sep-02-08 4:21 PM
CDP#52: Refueling Data by Year
48
0
2
4
6
8
10% Energy by Power levels: DOE Fleet
% E
nerg
y
0-5%
5-10%
10-15
%15
-20%
20-25
%25
-30%
30-35
%35
-40%
40-45
%45
-50%
50-55
%55
-60%
60-65
%65
-70%
70-75
%75
-80%
80-85
%85
-90%
90-95
%95
-100%
>100%
% Fuel Cell Power (Gross) of Max
Cum
ulat
ive
%
0
20
40
60
80
100
Created: Aug-28-08 5:48 PM
CDP#53: Fuel Cell System Energy within Power Levels
49
0-1 hr 1-6 hr 6-12 hr 12-18hr 18-24hr 1-7days 7-30days >30days0
10
20
30
40
50
60
% T
rips
Time
Time between Trips: DOE Fleet
0-10 min 10-20 min 20-30 min 30-40 min 40-50 min 50-60 min0
10
20
30
40
50
% T
rips
Time
0-60 min Breakdown: DOE Fleet
Created: Sep-03-08 11:06 AM
CDP#54: Time Between Trips
50
0-0.5 0.5-1 1-1.5 1.5-2 2-2.5 2.5-3 3-3.5 3.5-4 4-4.5 4.5-5 >50
5
10
15
20
25
30
35
40Trip Energy: DOE Fleet
% T
rips
Energy Consumed [kWh]Created: Aug-28-08 5:48 PM
# of Trips: 208476
CDP#55: Fuel Cell System Energy
51
0 5 10 15 20 25 30 35 400
5
10
15
20
25
Freq
uenc
y (%
)
Daily Distance (miles)
Daily Distance: DOE Fleet
DOE FleetNHTS
Created: Sep-03-08 11:06 AM
Cumulative Frequency@ 20 miles
DOE Fleet: 50.1%NHTS: 27.2%
Cumulative Frequency@ 40 miles
DOE Fleet: 69.1%NHTS: 52.9%
2001 NHTS Data Includes Car, Truck, Van, & SUV day tripsASCII.csv Source: http://nhts.ornl.gov/download.shtml#2001
CDP#56: Daily Driving Distance
52
CDP#57: H2 Storage System Mass and Volume Breakdown
53
0
100
200
300
400
500
600
700
Pow
er D
ensi
ty (W
/L)
FC System Power Density (W/L)
2010 and 2015 DOE MYPP Target1 Gen 1 Gen 2
Created: Sep-17-08 10:29 AM (1) Fuel cell system includes fuel cell stack and BOP but excludes H2 storage, power electronics, and electric drive.
CDP#58: Fuel Cell System Power Density
54
0
100
200
300
400
500
600
700
Spec
ific
Pow
er (W
/kg)
FC System Specific Power (W/kg)
2010 and 2015 DOE MYPP Target1 Gen 1 Gen 2
Created: Sep-17-08 10:30 AM (1) Fuel cell system includes fuel cell stack and BOP but excludes H2 storage, power electronics, and electric drive.
CDP#59: Fuel Cell System Specific Power
55
0 10 20 30 40 50 60 70 80 90 1000
10
20
30
40
50
60
70
80
Production Capacity Utilization1 [%]
Prod
uctio
n C
onve
rsio
n Ef
ficie
ncy
2 [%]
Monthly Production Conversion Efficiency vs Utilization
Electrolysis DataElectrolysis Fit3
Electrolysis Fit ConfidenceNatural Gas DataNatural Gas Fit3
Natural Gas Fit Confidence
Created: Sep-24-08 4:15 PM
1) 100% production utilization assumes operation 24 hrs a day, 7 days a week2) Production conversion efficiency is defined as the energy of the hydrogen out of the process (on a LHV basis) divided by the sum of the energy into the productionprocess from the feedstock and all other energy as needed. Conversion efficiency does not include energy used for compression, storage, and dispensing.3) High correlation with electrolysis data (R2 = 0.81) & low correlation with natural gas data (R2 = 0.058)
CDP#60: On-Site Hydrogen Production Efficiency vs. Capacity Utilization
56
On-Site Compression0
10
20
30
40
50
60
70
80
90
100
2010 MYPP Compression Target
2015 MYPP Compression Target
Com
pres
sion
Effi
cien
cy (%
)
On-Site Hydrogen Compression Efficiency1
Average Station Compression EfficiencyQuarterly Compression Efficiency DataHighest Quarterly Compression Efficiency
Created: Sep-03-08 4:45 PM
1Consistent with the MYPP, compression efficiency is defined as the energy of the hydrogen out of the process (on an LHV basis) divided by the sum of theenergy of the hydrogen output plus all other energy needed for the compression process. Data shown for on-site hydrogen production and storagefacilities only, not delivered hydrogen sites.
CDP#61: Refueling Station Compressor Efficiency
57
0
100
200
300
400
500
600
700
WTW
GH
G E
mis
sion
s (g
CO
2-eq
/mi)
Learning Demonstration Fuel Cycle Well-to-Wheels Greenhouse Gas Emissions1
Baseline Conventional Mid-Size Passenger Car2
Baseline Conventional Mid-Size SUV2
Average WTW GHG Emissions (Learning Demo)
Minimum WTW GHG Emissions (Learning Demo)
WTW GHG Emissions (100% Renewable Electricity)
WTW GHG Probability Based on Learning Demo3
Created: Sep-24-08 4:19 PM
On-Site Natural Gas Reforming On-Site Electrolysis(4)1. Well-to-Wheels greenhouse gas emissions based on DOE's GREET model, version 1.8b. Analysis uses default GREET values except for FCV fuel economy, hydrogenproduction conversion efficiency, and electricity grid mix. Fuel economy values are the Gen 1 and Gen 2 window-sticker fuel economy data for all teams (as used in CDP #6);conversion efficiency values are the production efficiency data used in CDP #13.2. Baseline conventional passenger car and light duty truck GHG emissions are determined by GREET 1.8b, based on the EPA window-sticker fuel economy of a conventionalgasoline mid-size passenger car and mid-size SUV, respectively. The Learning Demonstration fleet includes both passenger cars and SUVs.3. The Well-to-Wheels GHG probability distribution represents the range and likelihood of GHG emissions resulting from the hydrogen FCV fleet based on window-sticker fueleconomy data and monthly conversion efficiency data from the Learning Demonstration.4. On-site electrolysis GHG emissions are based on the average mix of electricity production used by the Learning Demonstration production sites, which includes bothgrid-based electricity and renewable on-site solar electricity. GHG emissions associated with on-site production of hydrogen from electrolysis are highly dependent onelectricity source. GHG emissions from a 100% renewable electricity mix would be zero, as shown. If electricity were supplied from the U.S. average grid mix, average GHGemissions would be 1296 g/mile.
CDP#62: Learning Demonstration Vehicle Greenhouse Gas Emissions
REPORT DOCUMENTATION PAGE Form Approved OMB No. 0704-0188
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October 2008 2. REPORT TYPE
Technical Report 3. DATES COVERED (From - To)
4. TITLE AND SUBTITLE
Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project: Fall 2008
5a. CONTRACT NUMBER DE-AC36-99-GO10337
5b. GRANT NUMBER
5c. PROGRAM ELEMENT NUMBER
6. AUTHOR(S) K. Wipke, S. Sprik, J. Kurtz, and T. Ramsden
5d. PROJECT NUMBER NREL/TP-560-44256
5e. TASK NUMBER H2708100
5f. WORK UNIT NUMBER
7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES)National Renewable Energy Laboratory 1617 Cole Blvd. Golden, CO 80401-3393
8. PERFORMING ORGANIZATIONREPORT NUMBER NREL/TP-560-44256
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11. SPONSORING/MONITORINGAGENCY REPORT NUMBER
12. DISTRIBUTION AVAILABILITY STATEMENT National Technical Information Service U.S. Department of Commerce 5285 Port Royal Road Springfield, VA 22161
13. SUPPLEMENTARY NOTES
14. ABSTRACT (Maximum 200 Words) Graphs of composite data products produced by DOE's Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation project through September 2008.
15. SUBJECT TERMS hydrogen; hydrogen demonstration; hydrogen validation
16. SECURITY CLASSIFICATION OF: 17. LIMITATION OF ABSTRACT
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