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VDI/VDE-IT (DE) / CEA-LITEN (FR) / VTT (FI) / TU Lodz (PL) / University of Catania (IT) / Aristotle University of Thessaloniki (EL) / ENEA (IT) / University of the Algarve (PT) / Universitat Rovira i Virgili (SP) / CNRS- Bordeaux (FR) / Polithnica University of Bucharest (RO) / Warsaw University of Technology (PL) / Institute of Macromolecular Chemistry ASCR (CZ) / University of Patras (EL) / CSEM (CH) / Universitat Autonoma de Barcelona (SP) / Chemnitz University of Technology (DE) Proposal n° 247745 NoE FlexNet - Network of Excellence for building up Knowledge for improved Systems Integration for Flexible Organic and Large Area Electronics (FOLAE) and its exploitation 2010 - 2012

NoE FlexNet - Network of Excellence for building up ... · Proposal n° 247745 NoE FlexNet - Joint Programme of Activities Work Package 2 Research collaboration coordinated by TUL

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VDI/VDE-IT (DE) / CEA-LITEN (FR) / VTT (FI) / TU Lodz (PL) / University

of Catania (IT) / Aristotle University of Thessaloniki (EL) / ENEA (IT) /

University of the Algarve (PT) / Universitat Rovira i Virgili (SP) / CNRS-

Bordeaux (FR) / Polithnica University of Bucharest (RO) / Warsaw University of Technology (PL) /

Institute of Macromolecular Chemistry ASCR (CZ) / University of Patras (EL) / CSEM (CH) / Universitat

Autonoma de Barcelona (SP) / Chemnitz University of Technology (DE)

Proposal n° 247745

NoE FlexNet - Network of Excellence

for building up Knowledge

for improved Systems Integration for

Flexible Organic and Large Area Electronics

(FOLAE) and its exploitation

2010 - 2012

Proposal n° 247745

oe-a members in

Europe 2009:

94 Central /

North / West (DE, GB, FR, AT, NL,

SE, BE, CH, IE, DK, FI)

6 South-East (GR, IT, ES, PL)

Background & Motivation –

Imbalanced OLAE activities in Europe

Proposal n° 247745

FlexNet Consortium

Proposal n° 247745

NoE FlexNet - R&D Organisation

Proposal n° 247745

NoE FlexNet - Joint Programme of Activities

Work Package 2

Research collaboration coordinated by TUL

The aim of WP2 - to target a selected critical issues related to OTFT integration - is realised by six Task Forces:

Task 2.1 Organic Semiconductors for OTFTs

Task 2.2 Dielectrics and Conductors

Task 2.3 Interfaces

Task 2.4 Barrier Materials

Task 2.5 Characterisation of materials

Task 2.6 Processing and Components Integration

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Joint Programme of Activities

www.noe-flexnet.eu ; www.kfm.p.lodz.pl/

7

CRI-s assigned to TFs

www.noe-flexnet.eu ; www.kfm.p.lodz.pl/

1 Patent: “New method of synthesis of n-type semiconductors based on tetraazaanthracene core” P. Gawrys, E. Bartnik, M. Zagorska, T. Marszalek, J. Ulanski; Polish Patent Submission P 395095 [2011]

9 Publications: 1) Adam Pron, Renji R. Reghu, Renata Rybakiewicz, Hubert Cybulski, David Djurado, Juozas V. Grazulevicius, Malgorzata Zagorska, Irena Kulszewicz-Bajer, and Jean-Marie Verilhac, ”Triarylamine Substituted Arylene Bisimides as Solution Processable Organic Semiconductors for Field Effect Transistors. Effect of Substituent Position on Their Spectroscopic, Electrochemical, Structural, and Electrical Transport Properties”, J. Phys. Chem. C, 2011, 115, 1508.

2) Renata Rybakiewicz, David Djurado, Hubert Cybulski, Ewelina Dobrzynska, Irena Kulszewicz-Bajer, Damien Boudinet, Jean-Marie Verilhac, Malgorzata Zagorska, Adam Pron, ”Arylene bisimides with triarylamine N-substituents as new solution processable organic semiconductors: Synthesis, spectroscopic, electrochemical and electronic properties”, Synth. Met. 2011, 161, 1600.

3) P. Gawrys, T. Marszalek,E. Bartnik, M. Kucinska, J. Ulanski,and M. Zagorska, ”Novel, Low-Cost, Highly Soluble n-Type Semiconductors: Tetraazaanthracene Tetraesters” Org. Lett., 2011, 13, 6090-6093

4) Kazim, S.,Ahmad, S.,Pfleger, J.,Pleštil, J.,Joshi, Y.,“Polyaniline-sodium montmorillonite clay nanocomposites: effect of clay concentration on thermal, structural and electrical properties”, J. Mat. Sci. 47, 1, 420-428, 2012.

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WP 2 Public dissemination:

www.noe-flexnet.eu ; www.kfm.p.lodz.pl/

5) Menšík, M.,Pfleger, J.,Rybak, A.,Jung, J.,Ulanski, J.,Halašová, K.,Vohlídal, J., „Photogeneration of free charge carriers in tenuously packed .pi. conjugated polymer chains”,Polym. Adv. Tech., 22, 12, 2075, 2011

6) Pfleger, J.,Kazim, S.,Slunečková, V.,Bondarev, D.,Vohlídal, J.: „Composites of semiconductive polyelectrolytes for optoelectronic applications”. Proceedings of the European Polymer Congress 2011. Granada : European Polymer Federation, 2011. p. 370. ISBN 978-84-694-3124-5. EPF 2011.

7) Kazim, S.,Pfleger, J.,Halašová, K.,Procházka, M.,Bondarev, D.,Vohlídal, J. ”SERS active systems of water soluble polythiophene and plasmonic nanoparticles: preparation and optical properties”, Europ. Phys. J.-Appl. Phys., 2011, 55(2), 23905_1-23905_6.

8) Nicolet, D. H. Deribew, C. Renaud, G. Fleury, C. Brochon, E. Cloutet, L. Vignau, G. Wantz, H. Cramail, M. Geoghegan, G. Hadziioannou, "Optimization of the Bulk heterojunction Composition for Enhanced Photovoltaic Properties: Correlation between Phase Behavior and Performance", J. Phys. Chem. B, 115 (44) (2011), 12717–12727.

9) Chen, Qian; Bory, Benjamin F.; Kiazadeh, Asal; et al.” Opto-electronic characterization of electron traps upon forming polymer oxide memory diodes”, Appl. Physi. Lett., 99 8, 83305-83305 ( 2011).

44 – oral or poster presentations at international conference

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WP 2 Public dissemination:

www.noe-flexnet.eu ; www.kfm.p.lodz.pl/

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The database is continuously updated

TF 2.1: Organic semiconductors

Database of commercially available semiconductors

www.noe-flexnet.eu ; www.kfm.p.lodz.pl/

www.noe-flexnet.eu 11

Substrate:

PEN substrate was chosen as standard

flexible substrate, and is used in TF2.6

and other TFs.

Electrodes:

The first draft of conductive inks

database has been prepared by ENEA

and is transfered into interactive database

(similar as for semiconductors) by WUT

PEDOT latexes, various batches are

available with different particle sizes (50-

200 nm) (CNRS)

TF 2.2: Dielectrics and Conductors

Research Advisory Sercice Instruction for use

the access to the platform is free !

www.noe-flexnet.eu ; www.kfm.p.lodz.pl/

Description of Flexnet partners capabilities (with high level competences in the field of FOLAE) http://www.noe-flexnet.eu/public/about/partners (by partner)

http://www.noe-flexnet.eu/public/knowledge/competences (list of competences)

Description of Flexnet demonstrators http://www.noe-flexnet.eu/public/systems/demo1-fact-sheet.pdf

http://www.noe-flexnet.eu/public/systems/demo2-fact-sheet.pdf

Description of Critical research Issues (to have a better knowledge of “bottleneck” related to FOLAE technologies) http://www.noe-flexnet.eu/public/critical-research-issues

FlexNET Education and Training website (information about research activities in your region and other) http://bpr.mb.tu-chemnitz.de/flexnet-education/?location=homepage

Go beyond the workshop … and visit some or all internet links: ①

the access to the platform is free !

www.noe-flexnet.eu ; www.kfm.p.lodz.pl/

Fill the questionnaire (or a part) (2 pages)… and communicate it to your local platform at:

http://www.kfm.p.lodz.pl/

the access to the platform is free !

Company :

Contact person:

Visiting list of competences, • Are you interested to have details about one or more capabilitie(s) ?

• If yes, which one(s) ? Why? with which Flexnet partner(s) ? Is it in relation with your activity?

Visiting demonstrator description, • Are you interested to have more details about demonstrator?

• If yes, which demonstrator(s)? Why? Is it in relation with your activity?

…we will answer you !!

www.noe-flexnet.eu ; www.kfm.p.lodz.pl/

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On the basis of the actual activity in your company, • Could you imagine to participate to demonstrator activity ?

• If yes, how? (providing material, process, etc,,)

• If not, do you imagine, in the future, your could produce FOLAE or integrate FOLAE or propose a

product/process adapted for FOLAE

what could be the conditions to occur?

what could be the conditions to NOT occur?

In relation with your activity, which advantages you imagine for FOLAE

In relation with your activity, which limitations you imagine for FOLAE

Is it related to Critical Research Issues (if yes, which one?)

Do you have general questions about FOLAE?

Are you interested to contact a Flexnet partner?

the access to the platform is free !

Fill the questionnaire (or a part) (2 pages)… and communicate it to your local platform at:

http://www.kfm.p.lodz.pl/

www.noe-flexnet.eu ; www.kfm.p.lodz.pl/

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Contact:

Constantin von Dewitz

[email protected]

+49 30 31 00 78 – 328

Jacek Ulanski

[email protected]

+49 42 631 32 05

www.noe-flexnet.eu

www.noe-flexnet.eu ; www.kfm.p.lodz.pl