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Noble Pathways to Propylene ProductionNovember 2021
Innovation Applied. Performance Delivered.™
A Snapshot of Lummus Technology
• Founded in 1907• A global leader in developing technology solutions that
make modern life possible and focus on a more sustainable, low carbon future.
• Master licensor of petrochemical, refining, gas processing and energy transition technologies, and a supplier of catalysts, proprietary equipment, digitalization and related lifecycle services to customers worldwide.
• Through 50/50 JV with Chevron (Chevron Lummus Global), Lummus is the market leader in hydroprocessing and residupgrading technology
• Acquired by The Chatterjee Group and Rhône Capital in 2020
Overview
Key End Markets Today:
Technologies130+
Refining Petrochemicals
Licensed Units2,400+
Years of Industry Leadership110+
Key Figures
Patents3,400+
2
Innovation Applied. Performance Delivered.™
A Top Tier Global Player Across the Value Chain
3
Catalyst and spare parts provide
ongoing relationships
Retrofit opportunities aligned with latest innovations and
developments
Differentiated master licensor: one-stop-shop solution
Equipment and modularized solutions
Asset optimization services over the
process facility life cycle
New Plant / Revamp CAPEX
Plant Operating Life OPEX
Leading portfolio of customer solutions available throughout the process facility life cycle
Broadest and most diversified technology portfolio
Lummus Technology
Innovation Applied. Performance Delivered.™
Synergies of Refinery / Petrochemical Integration
• Recent Trend: Greater Integration not just Co-location
• Position Petrochemicals Plants near: Low-cost feedstock Lower Transportation Costs for Feedstocks Fuel Sources Existing Infrastructure Downstream Markets: PE / PP / PET
4
Complimentary Units
Refinery
H2
Naphtha
Py-Oil
Petrochemicals
Coke, FOEB
Heavy Fuel Oil
Crude
ULSFO
Diesel
Gasoline
PX
Propylene
Ethylene
Price
Relative prices supporthigher conversion
• Petrochemicals Provide High Value Outlet for Refiners
Innovation Applied. Performance Delivered.™
Thermal Crude to Chemicals - TC2C™
TC2C™ Initiative:• Joint development agreement formed in 2018 between Saudi
Aramco, Lummus Technology and CLG• Developing, commercializing and marketing innovative crude to
chemical technologies
Platform Includes:• CLG's hydroprocessing technologies• Lummus’ ethylene cracker technology• Aramco's proprietary TC2C™ technology
Unlike any Other Crude-to-Chemicals Technology:• Processes low-value streams such as slurry oil and pyrolysis oils• Can be tailored to maximize olefins, aromatics or any combination
Integration of Processes Allows to:• Achieve maximum output of chemicals from a barrel• Achieve low carbon footprint for petrochemicals production
5
Innovation Applied. Performance Delivered.™
TC2C™ Highest Chemicals Yields at Significantly Lower Costs
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Maximizes high-value chemicals by:• Optimizing hydrogen infusion into
straight run and cracked distillates• Hydrocracking VGO’s to high-quality
distillates and UCO• Utilizing LC-FINING technology to
maximize recovery of suitable distillates and vacuum gas-oil components
• Processing cracker Pyoil and FCC slurry oil
Lowers overall costs with:• Novel TC2C crude oil separation technology with up to 40% capital
cost reduction• Targeted fractionation throughout crude conditioning section• Integration of LC-FINING with combined distillate and VGO
hydroprocessing• Tailored catalyst systems and steam cracking integration
Innovation Applied. Performance Delivered.™
INDMAX FCC Technology – Synergies of Partnership
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Superior HardwareSuperior Hardware
Superior Process/ Performance and Global Licensing of INDMAX FCC Technology
Complimenting Efforts by Lummus Technology and Indian Oil R&D Centre
TOTAL 10 LICENSED UNITS
World’s Largest INDMAX FCC – 85,600 BPSDOperating since December 2015
Innovation Applied. Performance Delivered.™
INDMAX High Propylene FCC
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Ultra Low Sulfur Gasoline
INDMAXFCCUnit
CDAlky
Gasoline HDS
CDHydro / CDHDS
Ether/ Dimer Technologies
OCU/ Reverse OCU
LPR Ethylene Recovery
Ethylene
PRUC3s
Dry gas
Propylene
IsomerizationC4s
Alkylate
C5s
Slurry Oil to Coker Unit
Naphtha HDS+ BTX Extraction Benzene, Toluene, Mixed Xylenes
C4 LPG
C3 LPG
MTBE/ ETBE/ TAME/ Dimers
LCO product
Delayed Coker
ARDS/VRDS
VGO Hydrotreater
CDU/VDU
HT VGO
Virgin VGO / ATB
Naphtha / Gas Oils
Treated AR/ VR
MTBE Back-cracking
High Purity Isobutylene
Butene-1
Innovation Applied. Performance Delivered.™
Olefins Conversion Technology (OCT)
• Olefins Conversion Technology (OCT) is an on-purpose Propylene production process based on the most Selective and Energy Neutral Metathesis Chemistry
9
+nC4= / nC5= / iC5= H2C=CH2 Propylene
Europe 6%Middle East
28%
China31%
Americas 8%
Far East 27%
52 Licensed Units33 Units in Operation
Capacity range : 50-750 kta
Average capacity : 190 kta
Innovation Applied. Performance Delivered.™
OCT Process
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Innovation Applied. Performance Delivered.™
OCT benefits
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• Converts low value C4’s and C5’s to PG Propylene with High selectivity >92%
• Energy neutral reaction – environmental friendly technology, (reduces plant overall “green-house gases”)
• Produces ultra high purity 99.99+% on-purpose propylene – Savings in comonomerconsumption of PP plants
• Feedstock flexible technology to accommodate various quality of C4 and C5 feeds
• No Superfractionation; no compressor; carbon steel metallurgy; mild process conditions –Low Capital Investment
• Technology can be built into a grassroots cracker, bolted onto an existing cracker, built into or added onto an existing refinery – Easily Integrated
• OCT boosts propylene production in a Steam Cracker – P/E ratio greater than 1 is achievable
• Quick Construction, reduces overall project Cost, Duration and quick payback
• Commercially proven for over 35 years
Innovation Applied. Performance Delivered.™
CATOFIN® PDH Technology (PDH)
• CATOFIN ® Propane Dehydrogenation Technology (PDH) is an on-purpose Propylene production process
+Propane Heat Propylene Hydrogen+
Total LicensesC3 feed 40C3+iC4 feed 2iC4 feed 18nC4 feed 21
Total CATOFIN® /CATADIENE® Licenses ‐ 81
>75% Total Number of PDH awards in Last two years
Fundamentally a robust process because the design is based on CATADIENE®, which is a very severe process
First PDH unit of India is Lummus CATOFIN PDH Process
Innovation Applied. Performance Delivered.™
CATOFIN® PDH Process
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PSA
Air in
Reactor Switching
Reactor on Stream
Reactor on Reheat
Low Temp. Section
FreshPropane
Steam
Cooler
ProductCompressor
Cooler Flash Drum
C2-rich product
Air Out
Propane Recycle
Propylene Product
ProductSplitter
Deethanizer
Hydrogen Product
Charge Heater
Fuel gas
Cycle driven by need to add heat of reaction not by need to regenerate the catalyst
Innovation Applied. Performance Delivered.™
Key Advantages of CATOFIN® Technology
14
• Ability to meet and exceed the design capacity• Feed flexibility• Reliable operation• Rapid start-up• Low cost of production• Low investment – simple equipment• Best NPV• Robust catalyst
Innovation Applied. Performance Delivered.™
CATOFIN® PDH – In Summary
15
Strong operability and reliability+ Low capital costs
+ Low operating costs= Superior project economics
• Increasingly preferred way to increase propylene supply• Highest reliability• Best plant economics
Innovation Applied. Performance Delivered.™
Novolen Polypropylene Technology
16
• Licensed production capacity - >20 million tons per year
• 50 licenses awarded worldwide
• Gas phase polymerization: highest product capabilities (MFR range, and C2 + C4incorporation)
• Helical agitator to keep particles in motion and move product between reactor cooling zones (top + bottom)
• Most compact and efficient reactor system:Dense bed (non-fluidized), no de-entrainment zoneFull condensing mode cooling Low gas flow
• Agitator operational benefits: Robust operation, quick restart after power
failure (powder remains in reactor) Low sensitivity to fines No fouling, low sensitivity to electrostatic charge Low power consumption
• Ongoing improvements to the process, catalysts, products, and services
Innovation Applied. Performance Delivered.™
Novolen Poly Propylene Technology – Key Highlights
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• Lowest CAPEX >10% lower cost than nearest competitor
• Low OPEX
• High operability
• Lowest environmental impact
• Leading Global Scale Capacity
• Low CAPEX / OPEX Superior Plant Economics
Novolen technology offers 50 to 200 Million US$ NPV advantage Over Competition(Ref. 1000 kta Plant)
Competition Novolen
Innovation Applied. Performance Delivered.™
Novolen Poly Propylene Technology – Key Highlights
18
Full product capability as produced in a gas-phase system with single, cascade or parallel reactor
Novolen Extended Support Services
w w w . L u m m u s Te c h n o l o g y . c o m
Innovation Applied. Performance Delivered.™