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y = 0.0057x 1.0882 R² = 0.4228 0 0.5 1 1.5 2 2.5 0 100 200 300 400 500 600 Ferrous Iron A+er the Nails (mg/L) Hardness in the Groundwater (mg/L) y = 0.4358x + 64.893 R² = 0.0076 0 50 100 150 200 250 300 350 400 450 0 10 20 30 40 50 60 70 80 90 100 Filter Arsenic (μg/L) Groundwater Chloride (mg/L) y = 37.155x + 91.234 R² = 0.085 0 50 100 150 200 250 300 350 400 450 0 0.5 1 1.5 2 2.5 Filter Arsenic (μg/L) Ferrous Iron a+er the Nails (mg/L) y = 0.3662x 18.268 R² = 0.1869 0 50 100 150 200 250 300 350 400 450 0 50 100 150 200 250 300 350 400 450 500 Filter Arsenic (μg/L) Groundwater Arsenic (μg/L) 0 50 100 150 200 250 300 350 400 450 500 1 11 21 31 41 51 61 71 81 91 101 Arsenic Concentra?on (μg/L) Filter Referance Number Ground water Filter Outlet Kanchan TM Arsenic Filter Nawalparasi, Nepal Project Description: The Kanchan Arsenic Filter TM (KAF) was developed by the Department of Civil and Environmental Engineering at MIT in collaboration with the Environmental and Public Health Organization (ENPHO, Nepal) for the low-cost removal of arsenic from drinking water in Nepal. Groundwater arsenic contamination is a recognized problem in many areas of South Asia. However, the uncertain performance of the KAF under various water quality conditions has limited the distribution of the KAF outside of Nepal. Our study focused on assessing the effect of various groundwater chemical parameters on the arsenic removal performance of the KAF. Tested Parameters: Findings: The KAF will not perform well in groundwater conditions that do not promote iron corrosion. Poor Performance Indicators: • GW As > 200 ug/L • Nail Fe(II) < 1.1 mg/L • GW Chloride < 7 mg/L Next Steps: Incorporating local components into the KAF system to increase iron corrosion (i.e. rock salt - NaCl) so that it can be promoted in areas with various groundwater conditions. Providing safe & affordable water to rural communities Claudia M Espinoza & Maclyn ODonnell • pH • Dissolved Oxygen • Chloride • Electrical Conductivity • Manganese • Arsenic • Ferrous Iron • Phosphate • Silica/Silicate • Hardness (CaCO 3 ) • Flow Rate • Filter Age • Location • User Survey • low GW Hardness • high GW pH Test Results: • Tested 101 filtered water and 77 groundwater samples in 15 different villages. Phosphate, Silica, Dissolved Oxygen, Manganese, Conductivity, Flow, Age, and Location did not affect KAF Performance Figure 2: As in the GW vs. FW. Error: +/-20% (As 100 μg/L) and +/-50 μg/L (As >100 μg/L). Figure 1: Overview of measured As. Error: +/-20% (As 100 μg/L) and +/- 50 μg/L (As >100 μg/L). Figure 3: Fe(II) after nails vs. As in FW. Error: +/-20% (As 100 μg/L), +/-50 μg/L (As >100 μg/L), +/-0.03 mg/L (Fe 1 mg/L), and +/-20% (Fe >1mg/L). Figure 4: GW Cl vs. As in FW. Error: +/-20% (As 100 μg/L), +/-50 μg/L (As >100 μg/L), and +/-10% (Cl). Figure 5: GW hardness vs. Fe(II) after nails. Error: +/-0.03 mg/ L (Fe 1 mg/L), +/-20% (Fe >1mg/L) and +/-10% (hardness). red solid line - Nepali arsenic drinking water standard (50 μg/L) green dotted line - Shift from mostly well performing KAFs to both well and poor performing KAFs GW = groundwater Kathmand u Valley Sampling Methodology: Arsenic Overview:

Nepal Final Project/Thesis Poster

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Poster made for the Legatum Seed Grant final presentation of my Nepal thesis and project work.

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Page 1: Nepal Final Project/Thesis Poster

y  =  0.0057x  -­‐  1.0882  R²  =  0.4228  

0  

0.5  

1  

1.5  

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0   100   200   300   400   500   600  

Ferrou

s  Iron  A+

er  th

e  Nails  (m

g/L)  

Hardness  in  the  Groundwater  (mg/L)  

y  =  -­‐0.4358x  +  64.893  R²  =  0.0076  

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r  Arsen

ic  (μ

g/L)  

Groundwater  Chloride  (mg/L)  

y  =  -­‐37.155x  +  91.234  R²  =  0.085  

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r  Arsen

ic  (μ

g/L)  

Ferrous  Iron  a+er  the  Nails  (mg/L)  

y  =  0.3662x  -­‐  18.268  R²  =  0.1869  

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r  Arsen

ic  (μ

g/L)  

Groundwater  Arsenic  (μg/L)  

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1   11   21   31   41   51   61   71   81   91   101  

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on  (μ

g/L)  

Filter  Referance  Number  Ground  water   Filter  Outlet  

KanchanTM Arsenic Filter Nawalparasi, Nepal

Project Description: The Kanchan Arsenic FilterTM (KAF) was developed by the Department of Civil and Environmental Engineering at MIT in collaboration with the Environmental and Public Health Organization (ENPHO, Nepal) for the low-cost removal of arsenic from drinking water in Nepal. Groundwater arsenic contamination is a recognized problem in many areas of South Asia. However, the uncertain performance of the KAF under various water quality conditions has limited the distribution of the KAF outside of Nepal. Our study focused on assessing the effect of various groundwater chemical parameters on the arsenic removal performance of the KAF.

Tested Parameters: Findings: The KAF will not perform well in groundwater conditions that do not promote iron corrosion.

Poor Performance Indicators: •  GW As > 200 ug/L •  Nail Fe(II) < 1.1 mg/L •  GW Chloride < 7 mg/L

Next Steps: Incorporating local components into the KAF system to increase iron corrosion (i.e. rock salt - NaCl) so that it can be promoted in areas with various groundwater conditions.

Providing safe & affordable water to rural communities

Claudia M Espinoza & Maclyn O’Donnell

•  pH •  Dissolved Oxygen •  Chloride •  Electrical Conductivity •  Manganese

•  Arsenic •  Ferrous Iron •  Phosphate •  Silica/Silicate •  Hardness (CaCO3)

•  Flow Rate •  Filter Age •  Location •  User Survey

•  low GW Hardness •  high GW pH

Test Results:

•  Tested 101 filtered water and 77 groundwater samples in 15 different villages.

•  Phosphate, Silica, Dissolved Oxygen, Manganese, Conductivity, Flow, Age, and Location did not affect KAF Performance

Figure 2: As in the GW vs. FW. Error: +/-20% (As ≤100 µg/L) and +/-50 µg/L (As >100 µg/L).

Figure 1: Overview of measured As. Error: +/-20% (As ≤100 µg/L) and +/- 50 µg/L (As >100 µg/L).

Figure 3: Fe(II) after nails vs. As in FW. Error: +/-20% (As ≤100 µg/L), +/-50 µg/L (As >100 µg/L), +/-0.03 mg/L (Fe ≤1 mg/L), and +/-20% (Fe >1mg/L).

Figure 4: GW Cl vs. As in FW. Error: +/-20% (As ≤100 µg/L), +/-50 µg/L (As >100 µg/L), and +/-10% (Cl). Figure 5: GW hardness vs. Fe(II) after nails. Error: +/-0.03 mg/

L (Fe ≤1 mg/L), +/-20% (Fe >1mg/L) and +/-10% (hardness).

red solid line - Nepali arsenic drinking water standard (50 µg/L)

green dotted line - Shift from mostly well performing KAFs to both well and poor performing KAFs

GW = groundwater

FW = filtered water

Kathmandu Valley

Sampling Methodology: Arsenic Overview: