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The Global Market for Graphene, 2D Materials and Carbon Nanotubes © Future Markets, Inc. All rights reserved. TABLE OF CONTENTS 1 RESEARCH METHODOLOGY........................................................................................................ 52 2 EXECUTIVE SUMMARY................................................................................................................... 59 2.1 CARBON NANOTUBES................................................................................................................ 59 o 2.1.1 Exceptional properties.......................................................................................................... 61 o 2.1.2 Products and applications.................................................................................................... 62 o 2.1.3 Competition from graphene................................................................................................. 68 o 2.1.4 Production............................................................................................. ................................. 69 2.1.4.1 Multi-walled nanotube (MWNT) production............................................................. 69 2.1.4.2 Single-walled nanotube (SWNT) production........................................................... 70 o 2.1.5 Global demand for carbon nanotubes............................................................................... 72 2.1.5.1 Current products.................................................................................................. ........ 74 2.1.5.2 Future products.................................................................................................. .......... 75 2.1.5.3 The market in 2018...................................................................................................... 75 o 2.1.6 Market drivers and trends.................................................................................................... 75 2.1.6.1 Electronics............................................................................ ......................................... 75 2.1.6.2 Electric vehicles and lithium-ion batteries................................................................ 76 o 2.1.7 Market and production challenges..................................................................................... 77 2.2 2D MATERIALS................................................................................................................... ........... 80 2.3 GRAPHENE.......................................................................................................... .......................... 80 o 2.3.1 The market in 2017............................................................................................................... 81

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Page 1: Nanotechnology Market Research - TABLE OF …...The Global Market for Graphene, 2D Materials and Carbon Nanotubes © Future Markets, Inc. All rights reserved. TABLE OF CONTENTS 1 RESEARCH

The Global Market for Graphene, 2D Materials and Carbon Nanotubes

© Future Markets, Inc. All rights reserved.

TABLE OF CONTENTS 1 RESEARCH METHODOLOGY........................................................................................................ 52 2 EXECUTIVE SUMMARY................................................................................................................... 59

• 2.1 CARBON NANOTUBES................................................................................................................ 59

o 2.1.1 Exceptional properties.......................................................................................................... 61

o 2.1.2 Products and applications.................................................................................................... 62

o 2.1.3 Competition from graphene................................................................................................. 68

o 2.1.4 Production.............................................................................................................................. 69

▪ 2.1.4.1 Multi-walled nanotube (MWNT) production............................................................. 69

▪ 2.1.4.2 Single-walled nanotube (SWNT) production........................................................... 70

o 2.1.5 Global demand for carbon nanotubes............................................................................... 72

▪ 2.1.5.1 Current products.......................................................................................................... 74

▪ 2.1.5.2 Future products............................................................................................................ 75

▪ 2.1.5.3 The market in 2018...................................................................................................... 75

o 2.1.6 Market drivers and trends.................................................................................................... 75

▪ 2.1.6.1 Electronics..................................................................................................................... 75

▪ 2.1.6.2 Electric vehicles and lithium-ion batteries................................................................ 76

o 2.1.7 Market and production challenges..................................................................................... 77

• 2.2 2D MATERIALS.............................................................................................................................. 80

• 2.3 GRAPHENE.................................................................................................................................... 80

o 2.3.1 The market in 2017............................................................................................................... 81

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The Global Market for Graphene, 2D Materials and Carbon Nanotubes

© Future Markets, Inc. All rights reserved.

o 2.3.2 The market in 2018............................................................................................................... 82

o 2.3.3 Production.............................................................................................................................. 82

o 2.3.4 Products.................................................................................................................................. 84

o 2.3.5 Graphene investments 2016-2018..................................................................................... 86

o 2.3.6 Market outlook for 2018....................................................................................................... 87

o 2.3.7 Global funding and initiatives.............................................................................................. 93

o 2.3.8 Products and applications.................................................................................................... 94

o 2.3.9 Production.............................................................................................................................. 96

▪ 2.3.9.1 Production capacities by producer............................................................................ 96

▪ 2.3.9.2 Graphite producers...................................................................................................... 97

o 2.3.10 Market drivers and trends............................................................................................... 98

o 2.3.11 Market and technical challenges................................................................................. 102

o 2.3.12 Key players globally....................................................................................................... 104

▪ 2.3.12.1 Asia-Pacific................................................................................................................. 104

▪ 2.3.12.2 North America............................................................................................................ 107

▪ 2.3.12.3 Europe......................................................................................................................... 107

3 MATERIALS OVERVIEW............................................................................................................... 109

• 3.1 Properties of nanomaterials........................................................................................................ 109

• 3.2 Categorization............................................................................................................................... 110

• 3.3 CARBON NANOTUBES.............................................................................................................. 111

o 3.3.1 Properties............................................................................................................................. 111

o 3.3.2 Multi-walled nanotubes (MWNT)...................................................................................... 113

▪ 3.3.2.1 Properties.................................................................................................................... 113

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The Global Market for Graphene, 2D Materials and Carbon Nanotubes

© Future Markets, Inc. All rights reserved.

▪ 3.3.2.2 Applications................................................................................................................ 113

o 3.3.3 Single-wall carbon nanotubes (SWNT)........................................................................... 114

▪ 3.3.3.1 Properties.................................................................................................................... 115

▪ 3.3.3.2 Applications................................................................................................................ 115

▪ 3.3.3.3 Single-chirality............................................................................................................ 118

o 3.3.4 Comparison between MWNTs and SWNTs................................................................... 119

o 3.3.5 Double-walled carbon nanotubes (DWNTs)................................................................... 119

▪ 3.3.5.1 Properties.................................................................................................................... 119

▪ 3.3.5.2 Applications................................................................................................................ 120

o 3.3.6 Few-walled carbon nanotubes (FWNTs)......................................................................... 120

▪ 3.3.6.1 Properties.................................................................................................................... 120

▪ 3.3.6.2 Applications................................................................................................................ 120

o 3.3.7 Carbon Nanohorns (CNHs)............................................................................................... 121

▪ 3.3.7.1 Properties.................................................................................................................... 121

▪ 3.3.7.2 Applications................................................................................................................ 121

o 3.3.8 Carbon Onions.................................................................................................................... 122

▪ 3.3.8.1 Properties.................................................................................................................... 122

▪ 3.3.8.2 Applications................................................................................................................ 123

o 3.3.9 Fullerenes............................................................................................................................. 123

▪ 3.3.9.1 Properties.................................................................................................................... 123

▪ 3.3.9.2 Applications................................................................................................................ 124

o 3.3.10 Boron Nitride nanotubes (BNNTs)............................................................................... 125

▪ 3.3.10.1 Properties.................................................................................................................... 125

▪ 3.3.10.2 Applications................................................................................................................ 126

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The Global Market for Graphene, 2D Materials and Carbon Nanotubes

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• 3.4 Applications of carbon nanotubes............................................................................................. 126

• 3.5 GRAPHENE.................................................................................................................................. 127

o 3.5.1 History................................................................................................................................... 127

o 3.5.2 Forms of graphene............................................................................................................. 128

o 3.5.3 Properties............................................................................................................................. 129

o 3.5.4 3D Graphene....................................................................................................................... 131

o 3.5.5 Graphene Quantum Dots................................................................................................... 131

▪ 3.5.5.1 Synthesis..................................................................................................................... 133

▪ 3.5.5.2 Applications................................................................................................................ 133

▪ 3.5.5.3 Producers.................................................................................................................... 135

• 3.6 OTHER 2-D MATERIALS........................................................................................................... 136

o 3.6.1 Beyond moore’s law........................................................................................................... 136

o 3.6.2 Batteries................................................................................................................................ 137

• 3.6.3 PHOSPHORENE................................................................................................................ 137

o 3.6.3.1 Properties.................................................................................................................... 137

o 3.6.3.2 Fabrication methods.................................................................................................. 139

o 3.6.3.3 Challenges for the use of phosphorene in devices.............................................. 139

o 3.6.4.1 Applications.......................................................................................................................... 140

o 3.6.5 Market opportunity assessment........................................................................................ 142

• 3.7 GRAPHITIC CARBON NITRIDE (g-C3N4).............................................................................. 143

o 3.7.1 Properties............................................................................................................................. 143

o 3.7.2 Synthesis.............................................................................................................................. 144

o 3.7.3 C2N........................................................................................................................................ 144

o 3.7.4 Applications.......................................................................................................................... 145

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▪ 3.7.4.1 Electronics.................................................................................................................. 145

▪ 3.7.4.2 Filtration membranes................................................................................................ 145

▪ 3.7.4.3 Photocatalysts............................................................................................................ 145

▪ 3.7.4.4 Batteries (LIBs).......................................................................................................... 145

▪ 3.7.4.5 Sensors....................................................................................................................... 146

o 3.7.5 Market opportunity assessment........................................................................................ 146

• 3.8 GERMANENE............................................................................................................................... 146

o 3.8.1 Properties............................................................................................................................. 147

o 3.8.2 Applications.......................................................................................................................... 147

▪ 3.8.2.1 Electronics.................................................................................................................. 147

▪ 3.8.2.2 Batteries...................................................................................................................... 148

o 3.8.3 Market opportunity assessment........................................................................................ 148

• 3.9 GRAPHDIYNE.............................................................................................................................. 148

o 3.9.1 Properties............................................................................................................................. 149

o 3.9.2 Applications.......................................................................................................................... 149

▪ 3.9.2.1 Electronics.................................................................................................................. 149

▪ 3.9.2.2 Batteries...................................................................................................................... 150

▪ 3.9.2.3 Separation membranes............................................................................................ 150

▪ 3.9.2.4 Water filtration............................................................................................................ 150

▪ 3.9.2.5 Photocatalysts............................................................................................................ 150

▪ 3.9.2.6 Photovoltaics.............................................................................................................. 150

o 3.9.3 Market opportunity assessment........................................................................................ 151

• 3.10 GRAPHANE............................................................................................................................. 151

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o 3.10.1 Properties........................................................................................................................ 152

o 3.10.2 Applications..................................................................................................................... 152

▪ 3.10.2.1 Electronics.................................................................................................................. 152

▪ 3.10.2.2 Hydrogen storage...................................................................................................... 152

o 3.10.3 Market opportunity assessment................................................................................... 153

• 3.11 HEXAGONAL BORON-NITRIDE.......................................................................................... 153

o 3.11.1 Properties........................................................................................................................ 154

o 3.11.2 Applications..................................................................................................................... 155

▪ 3.11.2.1 Electronics.................................................................................................................. 155

▪ 3.11.2.2 Fuel cells..................................................................................................................... 155

▪ 3.11.2.3 Adsorbents.................................................................................................................. 155

▪ 3.11.2.4 Photodetectors........................................................................................................... 155

▪ 3.11.2.5 Biomedical.................................................................................................................. 156

o 3.11.3 Market opportunity assessment................................................................................... 156

• 3.12 MOLYBDENUM DISULFIDE (MoS2).................................................................................... 157

o 3.12.1 Properties........................................................................................................................ 157

o 3.12.2 Applications..................................................................................................................... 158

▪ 3.12.2.1 Electronics.................................................................................................................. 158

▪ 3.12.2.2 Photovoltaics.............................................................................................................. 159

▪ 3.12.2.3 Piezoelectrics............................................................................................................. 159

▪ 3.12.2.4 Sensors....................................................................................................................... 160

▪ 3.12.2.5 Filtration....................................................................................................................... 160

▪ 3.12.2.6 Batteries...................................................................................................................... 160

▪ 3.12.2.7 Fiber lasers................................................................................................................. 160

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o 3.12.3 Market opportunity assessment................................................................................... 160

• 3.13 RHENIUM DISULFIDE (ReS2) AND DISELENIDE (ReSe2)........................................... 161

o 3.13.1 Properties........................................................................................................................ 162

o 3.13.2 Applications..................................................................................................................... 162

▪ 3.13.2.1 Electronics.................................................................................................................. 162

o 3.13.3 Market opportunity assessment................................................................................... 162

• 3.14 SILICENE.................................................................................................................................. 163

o 3.14.1 Properties........................................................................................................................ 164

o 3.14.2 Applications..................................................................................................................... 164

▪ 3.14.2.1 Electronics.................................................................................................................. 164

▪ 3.14.2.2 Photovoltaics.............................................................................................................. 165

▪ 3.14.2.3 Thermoelectrics......................................................................................................... 165

▪ 3.14.2.4 Batteries...................................................................................................................... 165

▪ 3.14.2.5 Sensors....................................................................................................................... 166

o 3.14.3 Market opportunity assessment................................................................................... 166

• 3.15 STANENE/TINENE................................................................................................................. 166

o 3.15.1 Properties........................................................................................................................ 167

o 3.15.2 Applications..................................................................................................................... 168

o 3.15.3 Market opportunity assessment................................................................................... 168

• 3.16 TUNGSTEN DISELENIDE..................................................................................................... 169

o 3.16.1 Properties........................................................................................................................ 170

o 3.16.2 Applications..................................................................................................................... 170

▪ 3.16.2.1 Electronics.................................................................................................................. 170

o 3.16.3 Market opportunity assessment................................................................................... 170

• 3.17 ANTIMONENE......................................................................................................................... 171

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o 3.17.1 Properties........................................................................................................................ 171

o 3.17.2 Applications..................................................................................................................... 171

• 3.18 DIAMENE.................................................................................................................................. 172

o 3.18.1 Properties........................................................................................................................ 172

o 3.18.2 Applications..................................................................................................................... 172

• 3.19 INDIUM SELENIDE................................................................................................................. 172

o 3.19.1 Properties........................................................................................................................ 172

o 3.19.2 Applications..................................................................................................................... 173

• 3.20 COMPARATIVE ANALYSIS OF GRAPHENE AND OTHER 2D MATERIALS............. 174

4 COMPARATIVE ANALYSIS GRAPHENE AND CARBON NANOTUBES............................ 176

• 4.1 Comparative properties............................................................................................................... 177

• 4.2 Cost and production..................................................................................................................... 178

• 4.3 Carbon nanotube-graphene hybrids......................................................................................... 179

5 CARBON NANOTUBE SYNTHESIS............................................................................................ 180

• 5.1 Arc discharge synthesis.............................................................................................................. 181

• 5.2 Chemical Vapor Deposition (CVD)............................................................................................ 182

• 5.3 Plasma enhanced chemical vapor deposition (PECVD)........................................................ 183

• 5.4 High-pressure carbon monoxide synthesis.............................................................................. 184

• 5.5 Flame synthesis............................................................................................................................ 185

• 5.6 Laser ablation synthesis.............................................................................................................. 186

• 5.7 Silane solution method................................................................................................................ 187

6 GRAPHENE SYNTHESIS............................................................................................................... 188

• 6.1 Large area graphene films.......................................................................................................... 188

• 6.2 Graphene oxide flakes and graphene nanoplatelets.............................................................. 189

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• 6.3 Production methods..................................................................................................................... 190

o 6.3.1 Production directly from natural graphite ore................................................................. 192

o 6.3.2 Alternative starting materials............................................................................................. 192

o 6.3.3 Quality................................................................................................................................... 192

• 6.4 Synthesis and production by types of graphene..................................................................... 193

o 6.4.1 Graphene nanoplatelets (GNPs)...................................................................................... 194

o 6.4.2 Graphene nanoribbons...................................................................................................... 194

o 6.4.3 Large-area graphene films................................................................................................ 195

o 6.4.4 Graphene oxide (GO)......................................................................................................... 197

• 6.5 Pros and cons of graphene production methods.................................................................... 198

o 6.5.1 Chemical Vapor Deposition (CVD)................................................................................... 199

o 6.5.2 Exfoliation method.............................................................................................................. 199

o 6.5.3 Epitaxial growth method..................................................................................................... 200

o 6.5.4 Wet chemistry method (liquid phase exfoliation)........................................................... 200

o 6.5.5 Micromechanical cleavage method.................................................................................. 201

o 6.5.6 Green reduction of graphene oxide................................................................................. 202

o 6.5.7 Plasma.................................................................................................................................. 202

• 6.6 Recent synthesis methods.......................................................................................................... 203

• 6.7 Synthesis methods by company................................................................................................ 208

7 REGULATIONS AND STANDARDS............................................................................................ 210

• 7.1 Standards...................................................................................................................................... 210

• 7.2 Europe............................................................................................................................................ 211

• 7.3 United States................................................................................................................................. 214

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• 7.4 Asia................................................................................................................................................. 216

o 7.4.1 Japan.................................................................................................................................... 216

o 7.4.2 South Korea......................................................................................................................... 216

o 7.4.3 Taiwan.................................................................................................................................. 216

o 7.4.4 Australia................................................................................................................................ 216

• 7.5 Workplace exposure.................................................................................................................... 217

8 CARBON NANOTUBES PATENTS.............................................................................................. 218 9 GRAPHENE PATENTS................................................................................................................... 221 10 CARBON NANOTUBES TECHNOLOGY READINESS LEVEL.............................................. 225 11 GRAPHENE TECHNOLOGY READINESS LEVEL................................................................... 227 12 CARBON NANOTUBES MARKET STRUCTURE..................................................................... 229 13 GRAPHENE MARKET STRUCTURE........................................................................................... 231 14 CARBON NANOTUBES PRODUCTION ANALYSIS................................................................ 235

• 14.1 Production volumes in metric tons, 2010-2027.................................................................. 235

• 14.2 Carbon nanotube producer production capacities............................................................. 240

• 14.3 Regional demand for carbon nanotubes............................................................................. 242

o 14.3.1 Japan................................................................................................................................ 243

o 14.3.2 China................................................................................................................................ 244

• 14.4 Main carbon nanotubes producers....................................................................................... 245

o 14.4.1 SWNT production........................................................................................................... 245

▪ 14.4.1.1 OCSiAl......................................................................................................................... 245

▪ 14.4.1.2 FGV Cambridge Nanosystems................................................................................ 245

▪ 14.4.1.3 Zeon Corporation....................................................................................................... 246

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• 14.5 Price of carbon nanotubes-MWNTs, SWNTs and FWNTs............................................... 246

o 14.5.1 MWNTs............................................................................................................................ 247

o 14.5.2 SWNTs............................................................................................................................. 247

• 14.6 APPLICATIONS....................................................................................................................... 248

15 GRAPHENE PRODUCTION AND PRICING ANALYSIS..................................................................................... 251

• 15.1 Graphene production volumes 2010-2027.......................................................................... 251

• 15.2 Graphene pricing..................................................................................................................... 253

o 15.2.1 Pristine Graphene Flakes pricing................................................................................ 254

o 15.2.2 Few-Layer Graphene pricing........................................................................................ 255

o 15.2.3 Graphene Nanoplatelets pricing.................................................................................. 256

o 15.2.4 Reduced Graphene Oxide pricing............................................................................... 257

o 15.2.5 Graphene Quantum Dots pricing................................................................................. 257

o 15.2.6 Graphene Oxide Nanosheets pricing.......................................................................... 258

o 15.2.7 Multilayer Graphene (MLG) pricing............................................................................. 259

o 15.2.8 Mass production of lower grade graphene materials............................................... 260

o 15.2.9 High grade graphene difficult to mass produce......................................................... 260

o 15.2.10 Bulk supply...................................................................................................................... 260

o 15.2.11 Commoditisation............................................................................................................. 261

• 15.3 Graphene producers and production capacities................................................................ 261

16 CARBON NANOTUBES INDUSTRY NEWS 2013-2018-INVESTMENTS, PRODUCTS AND PRODUCTION............................................................................................................................................ 263 17 GRAPHENE INDUSTRY DEVELOPMENTS 2013-2018-INVESTMENTS, PRODUCTS AND PRODUCTION............................................................................................................................................ 280 18 END USER MARKET ANALYSIS FOR CARBON NANOMATERIALS................................. 335

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• 18.1 3D PRINTING........................................................................................................................... 335

o 18.1.1 MARKET DRIVERS AND TRENDS............................................................................ 335

o 18.1.2 APPLICATIONS............................................................................................................. 336

o 18.1.3 MARKET SIZE AND OPPORTUNITY........................................................................ 338

o 18.1.4 MARKET CHALLENGES.............................................................................................. 339

o 18.1.5 PRODUCT DEVELOPERS........................................................................................... 340

• 18.2 ADHESIVES............................................................................................................................. 342

o 18.2.1 MARKET DRIVERS AND TRENDS............................................................................ 342

o 18.2.2 APPLICATIONS............................................................................................................. 343

o 18.2.3 MARKET SIZE AND OPPORTUNITY........................................................................ 344

o 18.2.4 MARKET CHALLENGES.............................................................................................. 347

o 18.2.5 PRODUCT DEVELOPERS........................................................................................... 348

• 18.3 AEROSPACE AND AVIATION.............................................................................................. 349

o 18.3.1 MARKET DRIVERS AND TRENDS............................................................................ 349

o 18.3.2 APPLICATIONS............................................................................................................. 351

▪ 18.3.2.1 Composites................................................................................................................. 353

▪ 18.3.2.2 Coatings...................................................................................................................... 356

o 18.3.3 MARKET SIZE AND OPPORTUNITY........................................................................ 360

o 18.3.4 MARKET CHALLENGES.............................................................................................. 364

o 18.3.5 PRODUCT DEVELOPERS........................................................................................... 365

• 18.4 AUTOMOTIVE......................................................................................................................... 368

o 18.4.1 MARKET DRIVER AND TRENDS............................................................................... 369

o 18.4.2 APPLICATIONS............................................................................................................. 370

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▪ 18.4.2.1 Composites................................................................................................................. 371

▪ 18.4.2.2 Thermally conductive additives............................................................................... 372

▪ 18.4.2.3 Tires............................................................................................................................. 373

o 18.4.2.4 Heat dissipation in electric vehicles........................................................................ 373

o 18.4.3 MARKET SIZE AND OPPORTUNITY........................................................................ 375

o 18.4.4 MARKET CHALLENGES.............................................................................................. 378

o 18.4.5 PRODUCT DEVELOPERS........................................................................................... 379

• 18.5 COATINGS............................................................................................................................... 382

o 18.5.1 MARKET DRIVERS AND TRENDS............................................................................ 383

o 18.5.2 APPLICATIONS............................................................................................................. 387

o 18.5.3 MARKET SIZE AND OPPORTUNITY........................................................................ 398

o 18.5.4 MARKET CHALLENGES.............................................................................................. 404

o 18.5.5 PRODUCT DEVELOPERS........................................................................................... 405

• 18.6 COMPOSITES......................................................................................................................... 408

o 18.6.1 MARKET DRIVERS AND TRENDS............................................................................ 409

o 18.6.2 APPLICATIONS............................................................................................................. 411

▪ 18.6.2.1 Polymer composites.................................................................................................. 411

▪ 18.6.2.2 Barrier packaging...................................................................................................... 415

▪ 18.6.2.3 Electrostatic discharge (ESD) and electromagnetic interference (EMI) shielding 415

▪ 18.6.2.4 Wind turbines............................................................................................................. 415

▪ 18.6.2.5 Ballistic protection...................................................................................................... 416

o 18.6.3 MARKET SIZE AND OPPORTUNITY........................................................................ 417

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o 18.6.4 MARKET CHALLENGES.............................................................................................. 420

o 18.6.5 PRODUCT DEVELOPERS........................................................................................... 421

• 18.7 ELECTRONICS....................................................................................................................... 426

o 18.7.1 FLEXIBLE ELECTRONICS, CONDUCTIVE FILMS AND DISPLAYS................... 427

▪ 18.7.1.1 MARKET DRIVERS AND TRENDS....................................................................... 427

▪ 18.7.1.2 APPLICATIONS......................................................................................................... 429

▪ 18.7.1.3 MARKET SIZE AND OPPORTUNITY.................................................................... 450

▪ 18.7.1.4 MARKET CHALLENGES......................................................................................... 456

▪ 18.7.1.6 PRODUCT DEVELOPERS...................................................................................... 461

o 18.7.2 CONDUCTIVE INKS...................................................................................................... 465

▪ 18.7.2.1 MARKET DRIVERS AND TRENDS....................................................................... 465

▪ 18.7.2.2 APPLICATIONS......................................................................................................... 467

▪ 18.7.2.3 MARKET SIZE AND OPPORTUNITY.................................................................... 475

▪ 18.7.2.4 MARKET CHALLENGES......................................................................................... 478

▪ 18.7.2.5 PRODUCT DEVELOPERS...................................................................................... 479

o 18.7.3 TRANSISTORS, INTEGRATED CIRCUITS AND OTHER COMPONENTS........ 481

▪ 18.7.3.1 APPLICATIONS......................................................................................................... 482

▪ 18.7.3.2 MARKET SIZE AND OPPORTUNITY.................................................................... 490

▪ 18.7.3.3 MARKET CHALLENGES......................................................................................... 494

▪ 18.7.3.4 PRODUCT DEVELOPERS...................................................................................... 497

o 18.7.4 MEMORY DEVICES...................................................................................................... 499

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▪ 18.7.4.1 MARKET DRIVERS AND TRENDS....................................................................... 499

▪ 18.7.4.2 APPLICATIONS......................................................................................................... 501

▪ 18.7.4.3 MARKET SIZE AND OPPORTUNITY.................................................................... 504

▪ 18.7.4.4 MARKET CHALLENGES......................................................................................... 505

▪ 18.7.4.5 PRODUCT DEVELOPERS...................................................................................... 506

o 18.7.5 PHOTONICS................................................................................................................... 510

▪ 18.7.5.1 MARKET DRIVERS.................................................................................................. 510

▪ 18.7.5.2 APPLICATIONS......................................................................................................... 511

▪ 18.7.5.3 MARKET SIZE AND OPPORTUNITY.................................................................... 516

▪ 18.7.5.4 MARKET CHALLENGES......................................................................................... 517

▪ 18.7.6 PRODUCT DEVELOPERS........................................................................................... 517

• 18.8 ENERGY STORAGE AND CONVERSION......................................................................... 518

o 18.8.1 BATTERIES.................................................................................................................... 519

▪ 18.8.1.1 MARKET DRIVERS AND TRENDS....................................................................... 519

▪ 18.8.1.2 APPLICATIONS......................................................................................................... 523

▪ 18.8.1.3 MARKET SIZE AND OPPORTUNITY.................................................................... 528

▪ 18.8.1.4 MARKET CHALLENGES......................................................................................... 532

o 18.8.2 SUPERCAPACITORS................................................................................................... 534

▪ 18.8.2.1 MARKET DRIVERS AND TRENDS....................................................................... 534

▪ 18.8.2.2 APPLICATIONS......................................................................................................... 535

▪ 18.8.2.3 MARKET SIZE AND OPPORTUNITY.................................................................... 541

▪ 18.8.2.4 MARKET CHALLENGES......................................................................................... 544

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o 18.8.3 PHOTOVOLTAICS......................................................................................................... 546

▪ 18.8.3.1 MARKET DRIVERS AND TRENDS....................................................................... 546

▪ 18.8.3.2 APPLICATIONS......................................................................................................... 547

▪ 18.8.3.3 MARKET SIZE AND OPPORTUNITY.................................................................... 553

▪ 18.8.3.4 MARKET CHALLENGES......................................................................................... 555

o 18.8.4 FUEL CELLS AND HYDROGEN STORAGE............................................................ 557

▪ 18.8.4.1 MARKET DRIVERS.................................................................................................. 557

▪ 18.8.4.2 APPLICATIONS......................................................................................................... 559

▪ 18.8.4.3 MARKET SIZE AND OPPORTUNITY.................................................................... 560

▪ 18.8.4.4 MARKET CHALLENGES......................................................................................... 562

▪ 18.8.4.5 PRODUCT DEVELOPERS...................................................................................... 562

• 18.9 LED LIGHTING AND UVC..................................................................................................... 570

o 18.9.1 MARKET DRIVERS AND TRENDS............................................................................ 570

o 18.9.2 PROPERTIES AND APPLICATIONS......................................................................... 571

▪ 18.9.2.1 Flexible OLED lighting.............................................................................................. 571

o 18.9.3 GLOBAL MARKET SIZE AND OPPORTUNITY....................................................... 573

o 18.9.4 MARKET CHALLENGES.............................................................................................. 574

o 18.9.5 PRODUCT DEVELOPERS........................................................................................... 575

• 18.10 FILTRATION AND SEPARATION........................................................................................ 575

o 18.10.1 MARKET DRIVERS AND TRENDS............................................................................ 575

o 18.10.2 APPLICATIONS............................................................................................................. 577

▪ 18.10.3 Water filtration................................................................................................................. 581

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▪ 18.10.4 Gas separation............................................................................................................... 582

▪ 18.10.5 Photocatalytic absorbents............................................................................................. 582

▪ 18.10.6 Air filtration....................................................................................................................... 583

o 18.10.7 MARKET SIZE AND OPPORTUNITY........................................................................ 584

o 18.10.8 MARKET CHALLENGES.............................................................................................. 586

o 18.10.9 PRODUCT DEVELOPERS........................................................................................... 588

• 18.11 LIFE SCIENCES AND MEDICAL......................................................................................... 590

o 18.11.1 MARKET DRIVERS AND TRENDS............................................................................ 591

o 18.11.2 APPLICATIONS............................................................................................................. 592

▪ 18.11.2.1 Cancer therapy...................................................................................................... 596

▪ 18.11.2.2 Medical implants and devices............................................................................. 598

▪ 18.11.2.3 Wound dressings.................................................................................................. 598

▪ 18.11.2.4 Biosensors.............................................................................................................. 599

▪ 18.11.2.5 Medical imaging.................................................................................................... 600

▪ 18.11.2.6 Tissue engineering............................................................................................... 600

▪ 18.11.2.7 Dental...................................................................................................................... 601

▪ 18.11.2.8 Electrophysiology.................................................................................................. 601

▪ 18.11.2.9 Wearable and mobile health monitoring............................................................ 601

o 18.11.3 MARKET SIZE AND OPPORTUNITY........................................................................ 612

▪ 18.11.3.1 Wearable healthcare............................................................................................ 614

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o 18.11.4 MARKET CHALLENGES.............................................................................................. 618

o 18.11.5 PRODUCT DEVELOPERS........................................................................................... 620

• 18.12 LUBRICANTS........................................................................................................................... 624

o 18.12.1 MARKET DRIVERS AND TRENDS............................................................................ 624

o 18.12.2 APPLICATIONS............................................................................................................. 625

o 18.12.3 MARKET SIZE AND OPPORTUNITY........................................................................ 627

o 18.12.4 MARKET CHALLENGES.............................................................................................. 629

o 18.12.5 PRODUCT DEVELOPERS........................................................................................... 629

• 18.13 OIL AND GAS.......................................................................................................................... 630

o 18.13.1 MARKET DRIVERS AND TRENDS............................................................................ 631

o 18.13.2 APPLICATIONS............................................................................................................. 632

▪ 18.13.2.1 Sensing and reservoir management.................................................................. 632

▪ 18.13.2.2 Coatings.................................................................................................................. 633

▪ 18.13.2.3 Drilling fluids........................................................................................................... 634

▪ 18.13.2.4 Sorbent materials.................................................................................................. 635

▪ 18.13.2.5 Catalysts................................................................................................................. 635

▪ 18.13.2.6 Separation.............................................................................................................. 635

o 18.13.3 MARKET SIZE AND OPPORTUNITY........................................................................ 636

o 18.13.4 MARKET CHALLENGES.............................................................................................. 639

o 18.13.5 PRODUCT DEVELOPERS........................................................................................... 640

• 18.14 RUBBER AND TIRES............................................................................................................. 641

o 18.14.1 APPLICATIONS............................................................................................................. 641

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o 18.14.2 GLOBAL MARKET SIZE AND OPPORTUNITY....................................................... 641

o 18.14.3 MARKET CHALLENGES.............................................................................................. 643

o 18.14.4 PRODUCT DEVELOPERS........................................................................................... 643

• 18.15 SENSORS................................................................................................................................ 644

o 18.15.1 MARKET DRIVERS AND TRENDS............................................................................ 644

o 18.15.2 APPLICATIONS............................................................................................................. 645

▪ 18.15.2.1 Infrared (IR) sensors............................................................................................. 650

▪ 18.15.2.2 Electrochemical and gas sensors....................................................................... 650

▪ 18.15.2.3 Pressure sensors.................................................................................................. 651

▪ 18.15.2.4 Biosensors.............................................................................................................. 651

▪ 18.15.2.5 Optical sensors...................................................................................................... 653

▪ 18.15.2.6 Humidity sensors................................................................................................... 654

▪ 18.15.2.7 Strain sensors........................................................................................................ 654

▪ 18.15.2.8 Acoustic sensors................................................................................................... 654

▪ 18.15.2.9 Wireless sensors................................................................................................... 654

▪ 18.15.2.10 Surface enhanced Raman scattering................................................................ 654

o 18.15.3 MARKET SIZE AND OPPORTUNITY........................................................................ 655

o 18.15.4 MARKET CHALLENGES.............................................................................................. 657

o 18.15.5 PRODUCT DEVELOPERS........................................................................................... 659

• 18.16 SMART TEXTILES AND APPAREL..................................................................................... 662

o 18.16.1 MARKET DRIVERS AND TRENDS............................................................................ 662

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o 18.16.2 APPLICATIONS............................................................................................................. 666

▪ 18.16.3 Conductive coatings....................................................................................................... 669

▪ 18.16.4 Conductive yarns............................................................................................................ 670

o 18.16.5 MARKET SIZE AND OPPORTUNITY........................................................................ 671

o 18.16.6 MARKET CHALLENGES.............................................................................................. 676

o 18.16.7 PRODUCT DEVELOPERS........................................................................................... 678

19 CARBON NANOTUBES PRODUCERS AND PRODUCT DEVELOPERS............................ 680

• 220 Company profiles 20 GRAPHENE PRODUCERS............................................................................................................ 807

• 20.1 TYPES OF GRAPHENE PRODUCED, BY PRODUCER................................................. 807

• 119 Company profiles (pages 811-991) 21 GRAPHENE PRODUCT AND APPLICATION DEVELOPERS............................................... 892

• 21.1 Industrial collaborations and licence agreements.............................................................. 892

• 21.2 Markets targeted, by product developers and end users.................................................. 896

• 110 Company profiles (pages 897-962) 22 REFERENCES.................................................................................................................................. 963 TABLES

• Table 1: Market summary for carbon nanotubes-Selling grade particle diameter, usage, advantages, average price/ton, high volume applications, low volume applications and novel applications............................................................................................................................................. 59

• Table 2: Properties of CNTs and comparable materials........................................................................ 61

• Table 3: Market opportunity assessment for CNTs in order of opportunity from high to low........... 63

• Table 4: Annual production capacity of MWNT producers 2017.......................................................... 69

• Table 5: SWNT producers production capacities 2017.......................................................................... 71

• Table 6: Production volumes of MWNTs (tons), 2010-2027................................................................. 73

• Table 7: Competitive analysis of Carbon nanotubes and graphene by application area and potential impact by

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2027....................................................................................................................................... 79

• Table 8: Demand for graphene (tons), 2010-2027................................................................................. 83

• Table 9: Consumer products incorporating graphene............................................................................ 85

• Table 10: Graphene investments and financial agreements 2017....................................................... 86

• Table 11: Market opportunity assessment matrix for graphene applications..................................... 89

• Table 12: Graphene target markets-Applications and potential addressable market size............... 95

• Table 13: Main graphene producers by country and annual production capacities.......................... 96

• Table 14: Categorization of nanomaterials............................................................................................ 110

• Table 15: Properties of carbon nanotubes............................................................................................. 111

• Table 16: Applications of multi-walled carbon nanotubes................................................................... 114

• Table 17: Markets, benefits and applications of Single-Walled Carbon Nanotubes....................... 116

• Table 18: Comparison between single-walled carbon nanotubes and multi-walled carbon nanotubes............................................................................................................................................. 119

• Table 19: Markets, benefits and applications of fullerenes................................................................. 124

• Table 20: Applications of carbon nanotubes......................................................................................... 126

• Table 21: Properties of graphene............................................................................................................ 130

• Table 22: Comparison of graphene QDs and semiconductor QDs................................................... 132

• Table 23: Graphene quantum dot producers........................................................................................ 135

• Table 24: Electronic and mechanical properties of monolayer phosphorene, graphene and MoS2................................................................................................................................................................. 139

• Table 25: Market opportunity assessment for phosphorene applications........................................ 143

• Table 26: Market opportunity assessment for graphitic carbon nitride applications....................... 146

• Table 27: Market opportunity assessment for germanene applications........................................... 148

• Table 28: Market opportunity assessment for graphdiyne applications............................................ 151

• Table 29: Market opportunity assessment for graphane applications............................................... 153

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• Table 30: Market opportunity assessment for hexagonal boron nitride applications...................... 156

• Table 31: Market opportunity assessment for molybdenum disulfide applications......................... 160

• Table 32: Market opportunity assessment for Rhenium disulfide (ReS2) and diselenide (ReSe2) applications........................................................................................................................................... 162

• Table 33: Market opportunity assessment for silicene applications.................................................. 166

• Table 34: Market opportunity assessment for stanine/tinene applications....................................... 168

• Table 35: Market opportunity assessment for tungsten diselenide applications............................. 170

• Table 36: Comparative analysis of graphene and other 2-D nanomaterials.................................... 174

• Table 37: Comparative properties of carbon materials........................................................................ 177

• Table 38: Comparative properties of graphene with nanoclays and carbon nanotubes................ 179

• Table 39: SWNT synthesis methods....................................................................................................... 181

• Table 40: Large area graphene films-Markets, applications and current global market................ 188

• Table 41: Graphene oxide flakes/graphene nanoplatelets-Markets, applications and current global market.................................................................................................................................................... 189

• Table 42: Main production methods for graphene................................................................................ 190

• Table 43: Large area graphene films-Markets, applications and current global market................ 196

• Table 44: Graphene synthesis methods, by company......................................................................... 208

• Table 45: National nanomaterials registries in Europe........................................................................ 212

• Table 46: Nanomaterials regulatory bodies in Australia...................................................................... 217

• Table 47: Top ten countries based on number of nanotechnology patents in USPTO 2014-2015. 219

• Table 48: Published patent publications for graphene, 2004-2016................................................... 222

• Table 49: Leading graphene patentees.................................................................................................. 223

• Table 50: Industrial graphene patents.................................................................................................... 223

• Table 51: Carbon nanotubes market structure...................................................................................... 229

• Table 52: Graphene market structure..................................................................................................... 231

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• Table 53: Production volumes of carbon nanotubes (tons), 2010-2027........................................... 236

• Table 54: Annual production capacity of MWNT producers................................................................ 241

• Table 55: SWNT producer’s production capacities 2016.................................................................... 242

• Table 56: Example carbon nanotubes prices........................................................................................ 247

• Table 57: Markets, benefits and applications of Carbon Nanotubes................................................. 248

• Table 58: Global production of graphene, 2010-2027 in tons/year. Base year for projections is 2015................................................................................................................................................................. 251

• Table 59: Types of graphene and prices................................................................................................ 253

• Table 60: Pristine graphene flakes pricing by producer...................................................................... 255

• Table 61: Few-layer graphene pricing by producer.............................................................................. 255

• Table 62: Graphene nanoplatelets pricing by producer....................................................................... 256

• Table 63: Reduced graphene oxide pricing, by producer................................................................... 257

• Table 64: Graphene quantum dots pricing by producer...................................................................... 258

• Table 65: Graphene oxide nanosheets pricing by producer............................................................... 258

• Table 66: Multi-layer graphene pricing by producer............................................................................. 259

• Table 67: Production capacities of graphene producers, current and planned, metric tons......... 261

• Table 68: Market drivers for use of carbon nanomaterials in 3D printing......................................... 335

• Table 69: Graphene properties relevant to application in 3D printing............................................... 336

• Table 70: Applications and benefits of carbon nanomaterials in 3D printing................................... 337

• Table 71: Market size for carbon nanomaterials in 3D printing.......................................................... 338

• Table 72: Market opportunity assessment for CNTs in 3D printing................................................... 338

• Table 73: Market opportunity assessment for graphene in 3D printing............................................ 338

• Table 74: Market challenges for carbon nanomaterials in 3D printing.............................................. 339

• Table 75: Market challenges rating for carbon nanomaterials in the 3D printing market............... 340

• Table 76: Carbon nanotubes product and application developers in the 3D printing industry...... 340

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• Table 77: Graphene product and application developers in the 3D printing industry..................... 341

• Table 78: Market drivers for use of carbon nanomaterials in adhesives.......................................... 342

• Table 79: Graphene properties relevant to application in adhesives................................................ 343

• Table 80: Applications and benefits of carbon nanomaterials in adhesives..................................... 344

• Table 81: Market size for carbon nanomaterials in adhesives........................................................... 345

• Table 82: Market opportunity assessment for CNTs in adhesives.................................................... 345

• Table 83: Market opportunity assessment for graphene in adhesives.............................................. 346

• Table 84: Market challenges rating for carbon nanomaterials in the adhesives market................ 347

• Table 85: Carbon nanotubes product and application developers in the adhesives industry....... 348

• Table 86: Graphene product and application developers in the adhesives industry..................... 348

• Table 87: Market drivers for use of carbon nanomaterials in aerospace.......................................... 349

• Table 88: Applications and benefits of CNTs in aerospace................................................................ 351

• Table 89: Applications in aerospace composites, by nanomaterials type and benefits thereof.... 355

• Table 90: Types of nanocoatings utilized in aerospace and application........................................... 357

• Table 91: Market size for carbon nanomaterials in aerospace........................................................... 361

• Table 92: Market opportunity assessment for CNTs in aerospace.................................................... 362

• Table 93: Market opportunity assessment for graphene in aerospace............................................. 362

• Table 94: Market challenges rating for carbon nanomaterials in the aerospace market............... 364

• Table 95: Carbon nanotubes product and application developers in the aerospace industry...... 365

• Table 96: Graphene product and application developers in the aerospace industry...................... 367

• Table 97: Market drivers for use of carbon nanomaterials in automotive......................................... 369

• Table 98: Applications and benefits of carbon nanomaterials in automotive................................... 374

• Table 99: Market size for carbon nanomaterials in automotive.......................................................... 375

• Table 100: Market opportunity assessment for CNTs in automotive................................................. 376

• Table 101: Market opportunity assessment for graphene in the automotive industry.................... 377

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• Table 102: Applications and commercialization challenges for carbon nanomaterials in the automotive market............................................................................................................................... 378

• Table 103: Market challenges rating for CNTs in the automotive market......................................... 379

• Table 104: Carbon nanotubes product and application developers in the automotive market..... 379

• Table 105: Graphene product and application developers in the automotive market.................... 381

• Table 106: Properties of nanocoatings................................................................................................... 382

• Table 107: Graphene properties relevant to application in coatings................................................. 388

• Table 108: Markets for nanocoatings..................................................................................................... 399

• Table 109: Market opportunity assessment for carbon nanomaterials in the coatings market..... 404

• Table 110: Market challenges rating for carbon nanomaterials in the coatings market................. 405

• Table 111: Carbon nanotubes product and application developers in the coatings industry........ 405

• Table 112: Graphene product and application developers in the coatings industry....................... 406

• Table 113: Market drivers for use of carbon nanomaterials in composites...................................... 409

• Table 114: Comparative properties of polymer composites reinforcing materials.......................... 411

• Table 115: Applications and benefits of carbon nanomaterials in composites................................ 412

• Table 116: Market size for carbon nanomaterials in composites....................................................... 417

• Table 117: Market opportunity assessment for CNTs in composites................................................ 418

• Table 118: Market opportunity assessment for graphene in composites......................................... 419

• Table 119: Applications and commercialization challenges for carbon nanomaterials in composites................................................................................................................................................................. 420

• Table 120: Market challenges rating for carbon nanomaterials in the composites market............ 421

• Table 121: Carbon nanotubes product and application developers in the composites market.... 421

• Table 122: Graphene product and application developers in the composites market.................... 424

• Table 123: Market drivers for use of carbon nanomaterials in flexible electronics and conductive films........................................................................................................................................................ 427

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• Table 124: Applications and benefits of carbon nanomaterials in flexible electronics and conductive films........................................................................................................................................................ 432

• Table 125: Comparison of ITO replacements....................................................................................... 435

• Table 126: Wearable electronics devices and stage of development............................................... 440

• Table 127: Graphene properties relevant to application in sensors.................................................. 446

• Table 128: Market size for carbon nanomaterials in flexible electronics and conductive films..... 450

• Table 129: Market opportunity assessment for CNTs in flexible electronics, wearables, conductive films and displays................................................................................................................................ 452

• Table 130: Market opportunity assessment for graphene in flexible electronics, wearables, conductive films and displays............................................................................................................ 453

• Table 131: Global market for wearable electronics, 2015-2027, by application, billions $............ 454

• Table 132: Applications and commercialization challenges for CNTs in flexible electronics and conductive films................................................................................................................................... 459

• Table 133: Market challenges rating for carbon nanomaterials in the flexible electronics and conductive films market...................................................................................................................... 461

• Table 134: Carbon nanotubes product and application developers in transparent conductive films and displays......................................................................................................................................... 461

• Table 135: Graphene product and application developers in transparent conductive films.......... 464

• Table 136: Market drivers for use of carbon nanomaterials in conductive inks............................... 465

• Table 137: Comparative properties of conductive inks........................................................................ 468

• Table 138: Opportunities for advanced materials in printed electronics........................................... 471

• Table 139: Applications in flexible and stretchable batteries, by nanomaterials type and benefits thereof................................................................................................................................................... 473

• Table 140: Market opportunity assessment for graphene in conductive inks.................................. 475

• Table 141: Market opportunity assessment for CNTs in conductive inks......................................... 476

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• Table 142: Conductive inks in the flexible and stretchable electronics market 2017-2027 revenue forecast (million $), by ink types........................................................................................................ 478

• Table 143: Market challenges for carbon nanomaterials in conductive inks.................................... 478

• Table 144: Market challenges rating for carbon nanomaterials in the conductive inks market.... 479

• Table 145: Carbon nanotubes product and application developers in conductive inks................. 479

• Table 146: Graphene product and application developers in conductive inks................................ 479

• Table 147: Market drivers for carbon nanomaterials in transistors, integrated circuits and other components.......................................................................................................................................... 481

• Table 148: Applications and benefits of CNTs in transistors, integrated circuits and other components.......................................................................................................................................... 485

• Table 149: Comparative properties of silicon and graphene transistors........................................... 487

• Table 150: Applications and benefits of graphene in transistors, integrated circuits and other components.......................................................................................................................................... 489

• Table 151: Market size for carbon nanomaterials in transistors, integrated circuits and other components.......................................................................................................................................... 491

• Table 152: Market opportunity assessment for CNTs in transistors, integrated circuits and other components.......................................................................................................................................... 492

• Table 153: Market opportunity assessment for graphene in transistors, integrated circuits and other components.......................................................................................................................................... 493

• Table 154: Market challenges rating for graphene in the transistors and integrated circuits market................................................................................................................................................................. 495

• Table 155: Applications and commercialization challenges for CNTs in the transistors, integrated circuits and other components market............................................................................................. 495

• Table 156: Market challenges rating for CNTs in the transistors, integrated circuits and other components market............................................................................................................................. 496

• Table 157: Carbon nanotubes product and application developers in transistors, integrated circuits and other

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components........................................................................................................................ 497

• Table 158: Graphene product and application developers in transistors and integrated circuits. 498

• Table 159: Market drivers for use of carbon nanomaterials in memory devices............................. 500

• Table 160: Applications and benefits of CNTs in memory devices.................................................... 502

• Table 161: Market size for carbon nanomaterials in memory devices.............................................. 504

• Table 162: Market opportunity assessment for CNTs in memory devices....................................... 505

• Table 163: Market challenges rating for carbon nanomaterials in the memory devices market... 505

• Table 164: Carbon nanotubes product and application developers in memory devices................ 509

• Table 165: Graphene product and application developers in memory devices............................... 509

• Table 166: Market drivers for use of carbon nanomaterials in photonics......................................... 510

• Table 167: Applications and benefits of CNTs in photonics................................................................ 511

• Table 168: Graphene properties relevant to application in optical modulators................................ 512

• Table 169: Applications and benefits of graphene in photonics......................................................... 515

• Table 170: Market size for carbon nanomaterials in photonics.......................................................... 516

• Table 171: Market challenges rating for carbon nanomaterials in the photonics market............... 517

• Table 172: Graphene product and application developers in photonics........................................... 517

• Table 173: Market drivers for use of carbon nanomaterials in batteries........................................... 520

• Table 174: Applications and benefits of CNTs in batteries................................................................. 523

• Table 175: Applications in flexible and stretchable batteries, by materials type and benefits thereof................................................................................................................................................................. 527

• Table 176: Market size for carbon nanomaterials in batteries............................................................ 529

• Table 177: Potential addressable market for thin film, flexible and printed batteries..................... 530

• Table 178: Market opportunity assessment for graphene in batteries.............................................. 532

• Table 179: Market challenges in CNT batteries.................................................................................... 532

• Table 180: Market challenges rating for CNTs in the batteries market............................................. 533

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• Table 181: Market challenges rating for graphene in the batteries market...................................... 534

• Table 182: Market drivers for use of carbon nanomaterials in supercapacitors.............................. 534

• Table 183: Applications and benefits of CNTs in supercapacitors.................................................... 536

• Table 184: Comparative properties of graphene supercapacitors and lithium-ion batteries......... 537

• Table 185: Applications and benefits of graphene in supercapacitors.............................................. 538

• Table 186: Properties of carbon materials in high-performance supercapacitors........................... 539

• Table 187: Applications in flexible and stretchable supercapacitors, by nanomaterials type and benefits thereof.................................................................................................................................... 541

• Table 188: Market size for carbon nanomaterials in supercapacitors............................................... 542

• Table 189: Market opportunity assessment for CNTs in supercapacitors........................................ 543

• Table 190: Market opportunity assessment for graphene in supercapacitors................................. 543

• Table 191: Market challenges in supercapacitors................................................................................ 544

• Table 192: Market challenges rating for CNTs in the supercapacitors market................................ 545

• Table 193: Market challenges rating for graphene in the supercapacitors market......................... 546

• Table 194: Market drivers for use of carbon nanomaterials in photovoltaics................................... 546

• Table 195: Applications and benefits of CNTs in photovoltaics......................................................... 548

• Table 196: Market size for carbon nanomaterials in photovoltaics.................................................... 553

• Table 197: Market size for CNTs in photovoltaics................................................................................ 554

• Table 198: Market size for graphene in photovoltaics......................................................................... 554

• Table 199: Potential addressable market for CNTs in photovoltaics................................................. 555

• Table 200: Market challenges for CNTs in solar................................................................................... 556

• Table 201: Market challenges rating for CNTs in the solar market.................................................... 556

• Table 202: Market challenges rating for graphene in the solar market............................................. 557

• Table 203: Market drivers for use of carbon nanomaterials in fuel cells and hydrogen storage.. 557

• Table 204: Electrical conductivity of different catalyst supports compared to carbon nanotubes. 560

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• Table 205: Market size for carbon nanomaterials in fuel cells and hydrogen storage................... 561

• Table 206: Market opportunity assessment for carbon nanomaterials in fuel cells and hydrogen storage.................................................................................................................................................. 561

• Table 207: Market challenges rating for carbon nanomaterials in the fuel cells and hydrogen storage market..................................................................................................................................... 562

• Table 208: Carbon nanotubes product and application developers in the energy storage, conversion and exploration industries.................................................................................................................. 562

• Table 209: Graphene product and application developers in the energy storage and conversion industry.................................................................................................................................................. 566

• Table 210: Market drivers for use of carbon nanomaterials in LED lighting and UVC................... 570

• Table 211: Applications of carbon nanomaterials in lighting............................................................... 571

• Table 212: Market size for carbon nanomaterials in LED lighting and UVC.................................... 573

• Table 213: Investment opportunity assessment for carbon nanomaterials in the lighting market. 574

• Table 214: Market impediments for carbon nanomaterials in lighting............................................... 574

• Table 215: Carbon nanomaterials product and application developers in the LED and UVC lighting market.................................................................................................................................................... 575

• Table 216: Market drivers for use of carbon nanomaterials in filtration............................................ 575

• Table 217: Comparison of CNT membranes with other membrane technologies.......................... 579

• Table 218: Applications and benefits of CNTs in filtration and separation....................................... 580

• Table 219: Applications and benefits of graphene in filtration and separation................................ 581

• Table 220: Market size for carbon nanomaterials in filtration............................................................. 584

• Table 221: Market opportunity assessment for CNTs in filtration...................................................... 585

• Table 222: Market opportunity assessment for graphene in the filtration and separation market. 586

• Table 223: Market challenges for carbon nanomaterials in filtration................................................. 587

• Table 224: Market challenges rating for carbon nanomaterials in the filtration market.................. 587

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• Table 225: Carbon nanotubes product and application developers in the filtration industry......... 588

• Table 226: Graphene product and application developers in the filtration industry........................ 589

• Table 227: Market drivers for use of carbon nanomaterials in the life sciences and medical market................................................................................................................................................................. 591

• Table 228: CNTs in life sciences and biomedicine............................................................................... 593

• Table 229: Graphene properties relevant to application in biomedicine and healthcare............... 593

• Table 230: Applications and benefits of carbon nanomaterials in life sciences and medical........ 594

• Table 231: Applications in flexible and stretchable health monitors, by advanced materials type and benefits thereof.................................................................................................................................... 604

• Table 232: Market size for carbon nanomaterials in life sciences and medical............................... 612

• Table 233: Potential addressable market for smart textiles and wearables in medical and healthcare............................................................................................................................................. 613

• Table 234: Market opportunity assessment for graphene in biomedical & healthcare markets... 616

• Table 235: Market opportunity assessment for CNTs in life sciences and medical........................ 618

• Table 236: Applications and commercialization challenges for carbon nanomaterials in life sciences and medical.......................................................................................................................................... 618

• Table 237: Market challenges rating for carbon nanomaterials in the life sciences and medical. 620

• Table 238: Carbon nanotubes product and application developers in the medical and healthcare industry.................................................................................................................................................. 620

• Table 239: Graphene product and application developers in the biomedical and healthcare industry................................................................................................................................................................. 622

• Table 240: Market drivers for use of carbon nanomaterials in lubricants......................................... 624

• Table 241: Applications of graphene in the lubricants market............................................................ 625

• Table 242: Applications of carbon nanotubes in lubricants................................................................. 626

• Table 243: Applications in lubricants, by nanomaterials type and benefits thereof........................ 626

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• Table 244: Market size for carbon nanomaterials in lubricants.......................................................... 627

• Table 245: Market opportunity assessment for CNTs in lubricants................................................... 627

• Table 246: Market opportunity assessment for graphene in lubricants............................................ 628

• Table 247: Market challenges rating for carbon nanomaterials in the lubricants market............... 629

• Table 248: Carbon nanotubes product and application developers in the lubricants industry...... 629

• Table 249: Graphene product and application developers in the lubricants industry.................... 630

• Table 250: Market drivers for carbon nanomaterials in oil and gas................................................... 631

• Table 251: Applications of graphene in the oil and gas market......................................................... 632

• Table 252: Market summary and revenues for carbon nanomaterials in the oil and gas market. 637

• Table 253: Investment opportunity assessment for CNTs in the oil and gas market..................... 638

• Table 254: Investment opportunity assessment for graphene in the oil and gas market............... 638

• Table 255: Market challenges rating for carbon nanomaterials in the oil and gas exploration market................................................................................................................................................................. 640

• Table 256: Carbon nanomaterial product and application developers in the oil and gas market. 640

• Table 257: Applications of carbon nanomaterials in rubber and tires............................................... 641

• Table 258: Market summary and revenues for carbon nanomaterials in the rubber and tires market................................................................................................................................................................. 641

• Table 259: Investment opportunity assessment for carbon nanomaterials in the rubber and tires market.................................................................................................................................................... 642

• Table 260: Market challenges for carbon nanomaterials in rubber and tires................................... 643

• Table 261: Companies developing graphene-based products in rubber and tires......................... 643

• Table 262: Market drivers for use of carbon nanomaterials in sensors............................................ 644

• Table 263: Applications and benefits of CNTs in sensors................................................................... 646

• Table 264: Applications and benefits of graphene in sensors............................................................ 647

• Table 265: Graphene properties relevant to application in sensors.................................................. 649

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• Table 266: Comparison of ELISA (enzyme-linked immunosorbent assay) and graphene biosensor................................................................................................................................................................. 653

• Table 267: Market size for carbon nanomaterials in sensors............................................................. 655

• Table 268: Market opportunity assessment for CNTs in sensors...................................................... 656

• Table 269: Market opportunity assessment for graphene in the sensors market........................... 657

• Table 270: Market challenges rating for graphene in the sensors market....................................... 658

• Table 271: Market challenges for CNTs in sensors............................................................................. 658

• Table 272: Market challenges rating for CNTs in the sensors market.............................................. 659

• Table 273: Carbon nanotubes product and application developers in the sensors industry......... 659

• Table 274: Graphene product and application developers in the sensors industry........................ 660

• Table 275: Types of smart textiles.......................................................................................................... 663

• Table 276: Smart textile products............................................................................................................ 663

• Table 277: Market drivers for use of carbon nanomaterials in smart textiles and apparel............ 664

• Table 278: Desirable functional properties for the textiles industry afforded by the use of nanomaterials....................................................................................................................................... 666

• Table 279: Applications and benefits of CNTs in textiles and apparel.............................................. 668

• Table 280: Applications and benefits of graphene in textiles and apparel....................................... 670

• Table 281: Global smart clothing, interactive fabrics and apparel market........................................ 672

• Table 282: Market opportunity assessment for CNTs in smart textiles and apparel...................... 675

• Table 283: Market opportunity assessment for graphene in smart textiles and apparel................ 676

• Table 284: Applications and commercialization challenges for carbon nanomaterials in smart textiles and apparel............................................................................................................................. 676

• Table 285: Market challenges rating for CNTs in the smart textiles and apparel market.............. 677

• Table 286: Carbon nanotubes product and application developers in the textiles industry.......... 678

• Table 287: Graphene product and application developers in the textiles industry........................ 678

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• Table 288: CNT producers and companies they supply/licence to................................................... 680

• Table 289: Graphene producers and types produced......................................................................... 807

• Table 290: Graphene producers target market matrix......................................................................... 812

• Table 291: Graphene industrial collaborations, licence agreements and target markets.............. 892

• Table 292: Graphene product developers and end users target market matrix.............................. 896

FIGURES • Figure 1: Molecular structures of SWNT and

MWNT............................................................................. 61 • Figure 2: The SGCNT synthesis

method................................................................................................. 71 • Figure 3: Production capacities for SWNTs in kilograms, 2005-

2017................................................. 72 • Figure 4: Global demand for MWNTs (tons), 2010-

2027...................................................................... 74 • Figure 5: Graphene production capacity, current and

planned............................................................ 83 • Figure 6: Demand for graphene, 2010-

2027........................................................................................... 84 • Figure 7: Vittoria bike tires incorporating

graphene................................................................................ 85 • Figure 8: Demand for graphene, by market,

2027.................................................................................. 88 • Figure 9: Global government funding for graphene in millions USD to

2017..................................... 94 • Figure 10: Global consumption of graphene 2016, by

region............................................................. 101 • Figure 11: 15-inch single-layer graphene sheet being prepared in the Chongqing

Institute of Green and Intelligent Technology, Chinese Academy of Sciences........................................................ 105

• Figure 12: Schematic of single-walled carbon nanotube..................................................................... 115

• Figure 13: TIM sheet developed by Zeon Corporation........................................................................ 116

• Figure 14: Double-walled carbon nanotube bundle cross-section micrograph and model............ 120

• Figure 15: Schematic representation of carbon nanohorns................................................................ 121

• Figure 16: TEM image of carbon onion.................................................................................................. 122

• Figure 17: Fullerene schematic............................................................................................................... 124

• Figure 18: Schematic of Boron Nitride nanotubes (BNNTs). Alternating B and N atoms are shown in blue and red......................................................................................................................................... 125

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• Figure 19: Graphene layer structure schematic.................................................................................... 127

• Figure 20: Graphite and graphene.......................................................................................................... 128

• Figure 21: Graphene and its descendants: top right: graphene; top left: graphite = stacked graphene; bottom right: nanotube=rolled graphene; bottom left: fullerene=wrapped graphene. ................................................................................................................................................................ 129

• Figure 22: Schematic of (a) CQDs and (c) GQDs. HRTEM images of (b) C-dots and (d) GQDs showing combination of zigzag and armchair edges (positions marked as 1–4)..................... 132

• Figure 23: Green-fluorescing graphene quantum dots........................................................................ 134

• Figure 24: Graphene quantum dots........................................................................................................ 135

• Figure 25: Black phosphorus structure................................................................................................... 137

• Figure 26: Black Phosphorus crystal...................................................................................................... 138

• Figure 27: Bottom gated flexible few-layer phosphorene transistors with the hydrophobic dielectric encapsulation....................................................................................................................................... 141

• Figure 28: Graphitic carbon nitride.......................................................................................................... 144

• Figure 29: Structural difference between graphene and C2N-h2D crystal: (a) graphene; (b) C2N-h2D crystal. Credit: Ulsan National Institute of Science and Technology.................................. 145

• Figure 30: Schematic of germanene....................................................................................................... 147

• Figure 31: Graphdiyne structure.............................................................................................................. 149

• Figure 32: Schematic of Graphane crystal............................................................................................. 152

• Figure 33: Structure of hexagonal boron nitride.................................................................................... 154

• Figure 34: BN nanosheet textiles application........................................................................................ 156

• Figure 35: Structure of 2D molybdenum disulfide................................................................................ 157

• Figure 36: SEM image of MoS2............................................................................................................... 158

• Figure 37: Atomic force microscopy image of a representative MoS2 thin-film transistor............. 159

• Figure 38: Schematic of the molybdenum disulfide (MoS2) thin-film sensor with the deposited molecules that create additional charge.......................................................................................... 160

• Figure 39: Schematic of a monolayer of rhenium disulfide................................................................. 161

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• Figure 40: Silicene structure..................................................................................................................... 163

• Figure 41: Monolayer silicene on a silver (111) substrate................................................................... 164

• Figure 42: Silicene transistor.................................................................................................................... 165

• Figure 43: Crystal structure for stanene................................................................................................. 167

• Figure 44: Atomic structure model for the 2D stanene on Bi2Te3(111)........................................... 167

• Figure 45: Schematic of tungsten diselenide........................................................................................ 170

• Figure 46: Schematic of Indium Selenide (InSe).................................................................................. 173

• Figure 47: Graphene can be rolled up into a carbon nanotube, wrapped into a fullerene, and stacked into graphite........................................................................................................................... 176

• Figure 48: Schematic representation of methods used for carbon nanotube synthesis (a) Arc discharge (b) Chemical vapor deposition (c) Laser ablation (d) hydrocarbon flames.............. 180

• Figure 49: Arc discharge process for CNTs........................................................................................... 182

• Figure 50: Schematic of thermal-CVD method..................................................................................... 183

• Figure 51: Schematic of plasma-CVD method...................................................................................... 184

• Figure 52: CoMoCAT® process............................................................................................................... 185

• Figure 53: Schematic for flame synthesis of carbon nanotubes (a) premixed flame (b) counter-flow diffusion flame (c) co-flow diffusion flame (d) inverse diffusion flame........................................ 186

• Figure 54: Schematic of laser ablation synthesis................................................................................. 187

• Figure 55: Graphene synthesis methods............................................................................................... 191

• Figure 56: TEM micrographs of: A) HR-CNFs; B) GANF® HR-CNF, it can be observed its high graphitic structure; C) Unraveled ribbon from the HR-CNF; D) Detail of the ribbon; E) Scheme of the structure of the HR-CNFs; F) Large single graphene oxide sheets derived from GANF.. 192

• Figure 57: Graphene nanoribbons grown on germanium................................................................... 195

• Figure 58: Methods of synthesizing high-quality graphene................................................................. 198

• Figure 59: Roll-to-roll graphene production process............................................................................ 203

• Figure 60: Schematic of roll-to-roll manufacturing process................................................................. 204

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• Figure 61: Microwave irradiation of graphite to produce single-layer graphene.............................. 206

• Figure 62: Nanotechnology patent applications, 1991-2015.............................................................. 219

• Figure 63: Share of nanotechnology related patent applications since 1972, by country.............. 219

• Figure 64: CNT patents filed 2000-2016................................................................................................ 220

• Figure 65: Published patent publications for graphene, 2004-2016.................................................. 223

• Figure 66: Technology Readiness Level (TRL) for Carbon Nanotubes............................................ 226

• Figure 67: Technology Readiness Level (TRL) for graphene............................................................. 228

• Figure 68: Schematic of typical commercialization route for graphene producer........................... 231

• Figure 69: Global demand for carbon nanotubes (tons), 2010-2027................................................ 237

• Figure 70: Demand for carbon nanotubes, by market in 2017, total................................................. 238

• Figure 71: Demand for single-walled carbon nanotubes, by market, 2017...................................... 239

• Figure 72: Demand for single-walled carbon nanotubes, by market, 2027...................................... 240

• Figure 73: Production volumes of Carbon Nanotubes 2017, by region............................................ 243

• Figure 74: Global market for graphene 2010-2027 in tons/year........................................................ 252

• Figure 79: 3D Printed tweezers incorporating Carbon Nanotube Filament...................................... 337

• Figure 80: Graphene Adhesives.............................................................................................................. 343

• Figure 81: Carbon nanotube Composite Overwrap Pressure Vessel (COPV) developed by NASA................................................................................................................................................................. 353

• Figure 82: Veelo carbon fiber nanotube sheet...................................................................................... 354

• Figure 83: HeatCoat CNT anti-icing coatings........................................................................................ 359

• Figure 84: Potential addressable market for carbon nanomaterials in aerospace.......................... 363

• Figure 85: Graphene-based automotive components.......................................................................... 372

• Figure 86: Antistatic graphene tire.......................................................................................................... 373

• Figure 87: Schematic of CNTs as heat-dissipation sheets................................................................. 374

• Figure 88: Heat transfer coating developed at MIT.............................................................................. 388

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• Figure 89: Water permeation through a brick without (left) and with (right) “graphene paint” coating................................................................................................................................................................. 394

• Figure 90: Four layers of graphene oxide coatings on polycarbonate.............................................. 397

• Figure 91: Global Paints and Coatings Market, share by end user market...................................... 398

• Figure 92: Potential addressable market for carbon nanomaterials in the coatings market.......... 403

• Figure 93: CNT anti-icing coating for wind turbines............................................................................. 416

• Figure 94: Potential addressable market for carbon nanomaterials in composites........................ 419

• Figure 95: Carbon nanotube thin-film transistors and integrated circuits on a flexible and transparent substrate.......................................................................................................................... 430

• Figure 96: Moxi flexible film developed for smartphone application.................................................. 430

• Figure 97: Flexible graphene touch screen........................................................................................... 431

• Figure 98: Galapad Settler smartphone................................................................................................. 432

• Figure 99: 3D printed carbon nanotube sensor.................................................................................... 434

• Figure 100: Flexible organic light emitting diode (OLED) using graphene electrode..................... 435

• Figure 101: Graphene electrochromic devices. Top left: Exploded-view illustration of the graphene electrochromic device. The device is formed by attaching two graphene-coated PVC substrates face-to-face and filling the gap with a liquid ionic electrolyte....................................................... 437

• Figure 102: Flexible mobile phones with graphene transparent conductive film............................. 438

• Figure 103: Carbon nanotube-based color active matrix electrophoretic display (EPD) e-paper. 438

• Figure 104: Foldable graphene E-paper................................................................................................ 439

• Figure 105: Covestro wearables.............................................................................................................. 441

• Figure 106: Softceptor sensor.................................................................................................................. 444

• Figure 107: BeBop Media Arm Controller.............................................................................................. 444

• Figure 108: LG Innotek flexible textile pressure sensor...................................................................... 445

• Figure 109: C2Sense flexible sensor...................................................................................................... 446

• Figure 110: Wearable gas sensor........................................................................................................... 448

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• Figure 111: BeBop Sensors Marcel Modular Data Gloves................................................................. 448

• Figure 112: BeBop Sensors Smart Helmet Sensor System............................................................... 449

• Figure 113: Torso and Extremities Protection (TEP) system.............................................................. 450

• Figure 114: Potential addressable market for CNTs in flexible electronics, conductive films and displays................................................................................................................................................. 454

• Figure 115: Global market for wearable electronics, 2015-2027, by application, billions $........... 454

• Figure 116: Global transparent conductive electrodes market forecast by materials type, 2012-2027, millions $.................................................................................................................................... 456

• Figure 117: Schematic of the wet roll-to-roll graphene transfer from copper foils to polymeric substrates............................................................................................................................................. 458

• Figure 118: The transmittance of glass/ITO, glass/ITO/four organic layers, and glass/ITO/four organic layers/4-layer graphene....................................................................................................... 459

• Figure 119: Nanotube inks........................................................................................................................ 467

• Figure 120: BGT Materials graphene ink product................................................................................. 469

• Figure 121: Flexible RFID tag.................................................................................................................. 470

• Figure 122: Enfucell Printed Battery....................................................................................................... 474

• Figure 123: Graphene printed antenna.................................................................................................. 474

• Figure 124: Conductive inks in the flexible and stretchable electronics market 2017-2027 revenue forecast (million $), by ink types........................................................................................................ 477

• Figure 125: Graphene IC in wafer tester................................................................................................ 483

• Figure 126: A monolayer WS2-based flexible transistor array........................................................... 483

• Figure 127: Emerging logic devices........................................................................................................ 484

• Figure 128: Thin film transistor incorporating CNTs............................................................................. 485

• Figure 129: Schematic cross-section of a graphene based transistor (GBT, left) and a graphene field-effect transistor (GFET, right)................................................................................................... 488

• Figure 130: Potential addressable market for carbon nanomaterials in transistors and integrated circuits................................................................................................................................................... 493

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• Figure 131: Carbon nanotubes NRAM chip........................................................................................... 501

• Figure 132: Stretchable SWCNT memory and logic devices for wearable electronics.................. 502

• Figure 133: Carbon nanotubes NRAM chip........................................................................................... 503

• Figure 134: Schematic of NRAM cell...................................................................................................... 508

• Figure 135: Hybrid graphene phototransistors...................................................................................... 513

• Figure 136: Wearable health monitor incorporating graphene photodetectors............................... 514

• Figure 137: Flexible PEN coated with graphene and a QD thin film (20nm) is highly visibly transparent and photosensitive......................................................................................................... 514

• Figure 138: The SkelStart Engine Start Module 2.0 based on the graphene-based SkelCap ultracapacitors...................................................................................................................................... 519

• Figure 139: Energy densities and specific energy of rechargeable batteries.................................. 522

• Figure 140: Nano Lithium X Battery........................................................................................................ 525

• Figure 141: H600 concept car.................................................................................................................. 528

• Figure 142: Anion concept car................................................................................................................. 529

• Figure 143: Skeleton Technologies ultracapacitor............................................................................... 537

• Figure 144: Zapgo supercapacitor phone charger............................................................................... 539

• Figure 145: Stretchable graphene supercapacitor............................................................................... 540

• Figure 146: Suntech/TCNT nanotube frame module........................................................................... 548

• Figure 147: Solar cell with nanowires and graphene electrode......................................................... 551

• Figure 148: Schematic illustration of the fabrication concept for textile-based dye-sensitized solar cells (DSSCs) made by sewing textile electrodes onto cloth or paper....................................... 552

• Figure 149: LG OLED flexible lighting panel......................................................................................... 572

• Figure 150: Flexible OLED incorporated into automotive headlight.................................................. 572

• Figure 151: Degradation of organic dye molecules by graphene hybrid composite photocatalysts................................................................................................................................................................. 583

• Figure 152: Graphene anti-smog mask.................................................................................................. 583

• Figure 153: Graphene Frontiers’ Six™ chemical sensors consists of a field effect transistor (FET) with a graphene channel. Receptor molecules, such as DNA, are

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attached directly to the graphene channel................................................................................................................................ 599

• Figure 154: Graphene-Oxide based chip prototypes for biopsy-free early cancer diagnosis....... 600

• Figure 155: Connected human body...................................................................................................... 602

• Figure 156: Flexible, lightweight temperature sensor.......................................................................... 602

• Figure 157: Graphene-based E-skin patch............................................................................................ 604

• Figure 158: Smart e-skin system comprising health-monitoring sensors, displays, and ultra flexible PLEDs................................................................................................................................................... 606

• Figure 159: Graphene medical patch..................................................................................................... 607

• Figure 160: TempTraQ wearable wireless thermometer..................................................................... 608

• Figure 161: Mimo baby monitor............................................................................................................... 608

• Figure 162: Nanowire skin hydration patch........................................................................................... 609

• Figure 163: Wearable sweat sensor....................................................................................................... 610

• Figure 164: GraphWear wearable sweat sensor.................................................................................. 611

• Figure 165: Global medical and healthcare smart textiles and wearables market, 2015-2027, billions $.............................................................................................................................................................. 615

• Figure 166: Global medical and healthcare smart textiles and wearables market, 2015-2027, billions $.............................................................................................................................................................. 616

• Figure 167: Schematic of boron doped graphene for application in gas sensors........................... 633

• Figure 168: Directa Plus Grafysorber..................................................................................................... 635

• Figure 169: Nanometer-scale pores in single-layer freestanding graphene membrane can effectively filter NaCl salt from water................................................................................................................... 636

• Figure 170: GFET sensors....................................................................................................................... 651

• Figure 171: First generation point of care diagnostics......................................................................... 652

• Figure 172: Graphene Field Effect Transistor Schematic................................................................... 653

• Figure 173: Conductive yarns.................................................................................................................. 671

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• Figure 174: Global smart clothing, interactive fabrics and apparel market 2013-2027 revenue forecast (million $)............................................................................................................................... 672

• Figure 175 Global smart clothing, interactive fabrics and apparel sales by market segment, 2016................................................................................................................................................................. 673

• Figure 176: Global market revenues for nanotech-enabled smart clothing and apparel 2014-2021, in US$, conservative estimate........................................................................................................... 674

• Figure 177: Global market revenues for nanotech-enabled smart clothing and apparel 2014-2021, in US$, optimistic estimate................................................................................................................. 674