49
Yeshaiahu (Shaya) Fainman Department of ECE, Jacobs School of Engineering University of California, San Diego La Jolla, California 92093-0407 Tel: (858) 534-8909; Fax: (858) 534-1225; E-mail: [email protected] http://emerald.ucsd.edu Nanophotonics Technology and Applications Lyncean Group, September 6, 2013

Nanophotonics Technology and Applicationsth order efficiency 0.2 0.4 0.6 0.8 1.0 RCWA Transparency Theory Near-field coupling Plasmonics Applications: Optical interconnects for chip

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  • Yeshaiahu (Shaya) Fainman Department of ECE, Jacobs School of Engineering

    University of California, San Diego La Jolla, California 92093-0407

    Tel: (858) 534-8909; Fax: (858) 534-1225; E-mail: [email protected]

    http://emerald.ucsd.edu

    Nanophotonics Technology and Applications

    Lyncean Group, September 6, 2013

    mailto:[email protected]://emerald.ucsd.edu/

  • Outline/Contents

    • Introduction: Technology Drive

    • Nanophotonics Process

    • Monolithic SOI Integration Platform

    • Heterogeneous Integration with SOI

    • Optofluidic nano-plasmonics

    • Testing for Manufacturability

    • Conclusions

    FUNDAMENTALS

    CHIP-SCALE SYSTEM TECHNOLOGY

  • Introduction: Technology Drive • Optical Interconnects for on-chip Multi-Core Computing

    • Optics in Data Centers

    Challanges: • Difficult to scale • Energy inefficient • Expensive • Cabeling complexity

    CENTER FOR INTEGRATED ACCESS NETWORKS

    • Nanostructured composites compatible with Si CMOS technology enables miniaturization and integration of information systems on a chip • Nanophotonics advances scalable and energy efficient computing platforms for stationary and mobile applications • Nanophotonics is being developed in collaboration with industry (SUN/Oracle)

  • Optofluidic information systems: “Making sense of sensing”

    Future information systems will integrate electrical, optical, fluidic, magnetic, mechanical, acoustic, chemical, and biological signals and processes on a chip

    VCSEL+Near-field polarizer: polarization control, mode stabilization, and heat management

    Composite nonlinear, E-O, and artificial dielectric materials control and enhance near-field coupling

    Near-field coupling between pixels in Form-birefringent CGH (FBCGH) FBCGH provides dual-

    functionality for focusing and beam steering

    Wavelength ( µ m) 1.3 1.5 1.7 1.9 2.1 2.3 2.5

    Ref

    lect

    ivity

    0.0

    0.2

    0.4

    0.6

    0.8

    1.0 TE TM

    Information I/O through surface wave, guided wave,and optical fiber from near-field edge and surface coupling

    Near-field E-O modulator controls optical properties and near-field micro-cavity enhances the effect

    +V -V

    Angle (degree) 20 30 40

    TM E

    ffici

    ency

    0.0

    0.2

    0.4

    0.6

    0.8

    1.0

    Near-field E-O Modulator + micro-cavity

    FBCGH VCSEL

    Near-field E-O coupler

    Micro polarizer

    Fiber tip Grating coupler

    Thickness ( µ m) 0.60 0.65 0.70 0.75 0.80

    TM 0

    th o

    rder

    effi

    cien

    cy

    0.2

    0.4

    0.6

    0.8

    1.0

    RCWA Transparency Theory

    Near-field coupling

    Plasmonics

    Applications: Optical interconnects for chip communications, optical feedback + gain for signal processing , biomedical sensing OPTOFLUIDICS

  • What are the opportunities for nanophotonics?

    • We can use lithography to “write” optical functional materials and devices, and exploit near field optical phenomena

    • Subwavelength features act as a metamaterial with optical properties controlled by the density and geometry of the constituent materials

    The ultimate challenge Field localization on nanoscale: Create nanophotonic systems to increase field interaction (cross-section) with confined material • Silicon Photonics • Nanoresonators/Nanolasers • Plasmonics

  • Goals: –Investigate near-field optical and quantum phenomena in nanostructures and resonators –Develop modeling and simulation tools for resonant and nonlinear interactions in QE

    materials –Optimize design of multifunctional, integrated nanophotonic devices and sub-systems

    utilizing near-field effects –Develop near-field manipulation and characterization tools and tools for manipulation, control

    and validation (amplitude, phase, time, etc.) of near-field devices and their interference –Fabricate and characterize example devices and integrated sub-systems for proof-of-concept

    and validation of modeling/optimization, fabrication and characterization tools

    Establishing Nanophotonics Process

    Near-field Optical Systems Science

    Fabrication Characterization

    Design and simulation

    Feedback from characterization of fabricated systems enable improvement of design/fabrication process

    Performance analysis enables improvement of system design and verification of modeling simulation tools

    Reliable modeling tools permit easy system design optimization

    • Monolithic Si photonics – CMOS • Heterogeneous III-V on SOI

    • Nanophotonic probe station • Near field system testing

    • Multidomain Optimization • Optical Spice

  • Design and Modeling Tools: UCSD-RCWA, R-SOFT, COMSOL

    Polarization-selective resonant ring cavity time delay

    TE modes: Resonant & delayed by ring cavity

    TM modes: Not resonant with ring cavity

    Multicavity resonant delay line

    Pol-selective mirror TM-Transmitted

    TE-Reflected

    Resonant phase modulator

    Index Modulation (∆n)

    -0.0010 -0.0005 0.0000 0.0005 0.0010

    Pha

    se C

    hang

    e (R

    ad)

    -4

    -3

    -2

    -1

    0

    1

    2

    3

    4

    3-layer front mirror5-layer front mirror7-layer front mirror9-layer front mirror11-layer front mirror

    Form-birefringent modes

    I. Richter, P.-C. Sun, F. Xu and Y. Fainman “Design of form birefringent microstructures,” Appl. Opt. 34, 2421–2429 (1995).

    SiO2

    Substrate

  • Fabrication of Nanophotonic Devices

    ∆WS = 50 nm WS = 500 nm

    H = 250 nm

    DBR single mode high-Q resonators

    H.-C. Kim, K. Ikeda, and Y. Fainman, JLT and Opt. Lett., 2007

    Microring resonator Photonic crystal device

    High resolution lithography enables construction of various nanophotonic components and devices

    140nm

    1µm (320nm mod.)

    Si

    Si

    Rib waveguide for larger size

    cavity

  • New Calit2 Photonics Nanofabrication and Chip-scale Testing Facilities

    Calit2 Building: Opened Nov 2005

    New Nanofabrication Facility Nano3

    State of the Art E-beam from December 2012

  • ( , ) cos( ( ) ), ) ,(R R S RS SI I x yI I I x xt yy φ φω= + + ∆ −+

    Heterodyne NSOM

    Performance: • Telecom wavelength • Amplitude and phase • Linear & nonlinear effects • Measures: modal content, group delay, losses, index • Time resolution: ~1 fsec • Coherent detection with heterodyne gain Er/Es ~ 104

    Near-field amplitude Near-field phase Output amplitude x

    y

    Topography

    Simultaneously generated images of an SOI waveguide:

  • Outline/Contents

    • Introduction: Technology Drive

    • Nanophotonics Process

    • Monolithic SOI Integration Platform

    • Heterogeneous Integration with SOI

    • Optofluidic nano-plasmonics

    • Testing for Manufacturability

    • Conclusions

  • Λ

  • Resonant Photonic Structutes

    In Out

    Horizontal grating on top

    Vertical grating on sidewalls

    Two step process (waveguide grating) or (grating waveguide)

    Motivation: Simple Fabrication of Si-Photonic Wires

    One step process (all structures in one step)

    SiO2

    Si SiO2

    Si substrate

    Kim, Ikeda, and Fainman, JLT and Opt. Lett., 2007

  • Resonant Filter with Vertical Gratings

    0

    0.2

    0.4

    0.6

    0.8

    1

    1530 1540 1550 1560 1570

    26nm

    140nm

    1µm (320nm mod.)

    Si Si

    Rib waveguide for larger size

    cavity

    250nm

    500nm (50nm modulation)

    Channel waveguide for smaller size

    Si

    SiO2

    cavity

    Q=2600

    Transmittance

    19nm

    Modulated optically by 514nm laser with thermal nonlinearity

    0mW 3.3mW 6.6mW 10mW

    1554.8nm

    λ=1554.8nm

    Modulated output

    High quality resonator is obtained without any other structure than the waveguide (small footprint), with one step lithographic process (easy fabrication).

    Silicon-based functional optical devices, such as modulator, filter and detector, are desirable for on-chip photonic interconnections. The vertical grating structure enables configuring functional devices with small dimensions and CMOS compatible fabrication. Kim, Ikeda, and Fainman, JLT and Opt. Lett., 2007

  • Top View Bragg conditions

    Backward coupling in WG1 (Port1 input)

    Backward coupling in WG2 (Port2 input)

    Cross coupling between WG1 and WG2

    Design: (1) Satisfy 3 Bragg conditions for desired wavelengths changing (W1, W2, Λ) (2) Determine coupling coefficients for desired bandwidths by changing (∆W1, ∆W2, G) (3) Determine length (L) of the structure to obtain the necessary extinction ratios

    Λ

    ∆W1 W1

    L

    ∆W2 W2

    β1

    β2

    1

    2

    3

    4

    G

    1 122 ( ) πβ λ =Λ1 1 1 1

    ( ) ( )β λ β β λΛ− = −

    2 222 ( ) πβ λ =Λ

    1 22( ) ( )c cπβ λ β λ+ =Λ

    2 2 2 2( ) ( )β λ β β λΛ− = −

    1 2( ) ( )c cβ λ β β λΛ− = −

    Wavelength Selective Coupler with Resonant Photonic Wires on Silicon Chip

  • Photonic wire: add-drop filter for WDM

    Port3 Port4

    WG1

    WG2

    550nm

    430nm 250nm

    SEM micrograph

    Port2

    Port1

    Port4 80µm

    Port3

    K. Ikeda, M. Nezhad and Y. Fainman, "Wavelength Selective Coupler with Vertical Gratings on Silicon Chip," APPLIED PHYSICS LETTERS Volume: 92 Issue: 20 Article Number: 201111: MAY 19 2008

    Microscope image

    Si Substrate

    H

    W2

    Si

    W1

    Si SiO2

  • 1 by 4 Wavelength Division Multiplexer Design and Characterization

    z = L/2z

    z = -L/2

    ΔW2ΔW1

    G2

    W1

    W2

    ΛB {

    Port 4 Port 5

    W4

    W3

    W5

    G3

    G4 G5

    Transmission Port

    1550 1560 1570 1580 1590 1600

    -25

    -20

    -15

    -10

    -5

    0

    Wavelength (nm)

    Tran

    smis

    sion

    (dB

    )

    TransmissionPortPort 5Port 4Port 3Port 2

    D. T. H. Tan, K. Ikeda, S. Zamek, A. Mizrahi, M.P. Nezhad, A.V. Krishnamoorthy, K. Raj, J.E. Cunningham, X. Zheng, I. Shubin, Y. Luo and Y. Fainman, "Wide bandwidth, low loss 1 by 4 wavelength division multiplexer on silicon for optical interconnects," Opt. Express. 19, 2401-2409 (2011).

    Zoom in Port #4

    • 3dB bandwidth of 3nm per channel • 6 nm channel separation • < 0.8dB ripple in the passband of each channel • Insertion loss of 1dB • 16dB inter-channel crosstalk suppression

    Measured performance:

  • Importance of Pulse Compression • Localization in time domain will benefit applications such as imaging,

    spectroscopy and communicationsOTDM • Compression is often used as alternative to mode locking to derive the

    necessary short pulses • High compression factors and CMOS compatibility are important

    H. C. H. Mulvad, M. Galili, L. K. Oxenløwe, H. Hu, A. T. Clausen, J. B. Jensen, C. Peucheret, and P. Jeppesen, “Demonstration of 5.1 Tbit/s data capacity on a single-wavelength channel,” Opt. Express 18, 1438–1443 (2010).

    Pulse Compression Approaches:

    Nonlinear, dispersive medium

    Solitonic compression Compression with Dispersive Element

    Self Phase Modulation L. F. Mollenauer, R. H. Stolen, and J. P. Gordon, “Experimental observation of picosecond pulse narrowing and solitons in optical fibers,” Phys. Rev. Lett. 45, 1095 (1980).

    W. J. Tomlinson, R. H. Stolen, and C. V. Shank, “Compression of optical pulses chirped by self-phase modulation in fibers”, J. Opt. Soc. Am. B 1 , 139 (1984)

  • Input, spectrally narrow,

    temporally wide

    Spectrally and temporally

    wide

    Output, spectrally wide and

    temporally narrow

    Dispersive Grating

    a

    Input, spectrally narrow,

    temporally wide

    Spectrally and temporally

    wide

    Output, spectrally wide and

    temporally narrow

    Dispersive Grating

    a

    b

    c

    b

    c

    Nanophotonic circuit: Ultrafast Compression of Optical Pulses on a Silicon Chip

    Scanning electron micrograph of dispersive grating before deposition of SiO2 overcladding

    • Input pulses are spectrally broadened due to self phase modulation (via the Kerr nonlinearity in the highly confined silicon nanowire waveguide) • The pulse is compressed by the dispersive grating leading to spectrally wide and temporally narrow output pulses.

    c

    c

    Calculated quasi-TE mode profile for silicon nanowire waveguide used for self phase modulation

    -10-5

    05

    10

    0 48121620

    0

    0.5

    1

    P k P (W)

    Time (ps)

    Aut

    ocor

    rela

    tion

    Input Peak Power (W)

    -10-5

    05

    10

    0 48121620

    0

    0.5

    1

    P k P (W)

    Time (ps)

    Aut

    ocor

    rela

    tion

    Input Peak Power (W)

    D.T.H. Tan , P. C. Sun and Y. Fainman, Monolithic nonlinear pulse compressor on a silicon chip, Nature Communications, 1, 1113, 2010

  • Outline/Contents

    • Introduction: Technology Drive

    • Nanophotonics Process

    • Monolithic SOI Integration Platform

    • Heterogeneous Integration with SOI

    • Optofluidic nano-plasmonics

    • Testing for Manufacturability

    • Conclusions

  • Detector

    Electrical I/O Block B

    λ3

    Detector

    Detector

    λ2

    Electrical I/O

    Modulator

    Modulator

    Modulator

    λ2 λ3

    Block A

    Source λ3

    Source λ1

    Source λ2

    Optical interconnects and networking on a Si chip

    Fast Modulators

    Liu, Nature, 2004

    Xu, Nature, 2005

    Add/Drop Filters

    Lee, Opt. Lett. 2006

    Ikeda, APL 2008

    Nezhad, Nat. Phot. 2010 Hill, Nature Photon. 2009

    Miniature Optical Sources

    Huang, Nature Photon. 2007

    Waveguides

    Integrated networking on a chip

    Small, No EM Interference, Efficient

    Passive (Si)

    Active (Si, III-V)

  • Challenge: create a low-loss metal coated resonator enabling lasing (threshold gain < 200 cm-1) with the following features:

    • (1) room temperature operation • (2) subwavelength size in all 3-D and • (3) isolation from near field interactions

  • Optimal condition does not correspond to Rgain=Rout

    •A. Mizrahi, V. Lomakin, B. A. Slutsky, M. P. Nezhad, L. Feng, and Y. Fainman, "Low Threshold Gain Metal Coated Laser Nanoresonators", Opt. Lett., vol. 33, no. 11, pp. 1261-1263, June 2008 •Our later designs replace the substrate side with air, but gain threshold requirement does not change significantly

    Our Approach: Use Dielectric Shield

  • Fabrication results

    Array of etched nanolasers

    After RIE and BOE After PECVD of SiO2

    After Al sputtering After HCl etch (Note: different size laser is

    shown here)

    Nanolaser aperture

    M. P. Nezhad, A. Simic, O. Bondarenko, B. A. Slutsky, A. Mizrahi, L. Feng, V. Lomakin, and Y. Fainman, Nature Photonics, (2010).

  • Lasing conditions: Pump at 1064nm pulsed PW=12ns, Rep rate 300KHz

    Room-Temperature Lasing

    Lasing Wavelength:1430nm Lasing Threshold: 700µW/µm2 Linewidth: 0.9nm

    M. P. Nezhad, A. Simic, O. Bondarenko, B. A. Slutsky, A. Mizrahi, L. Feng, V. Lomakin, and Y. Fainman, Nature Photonics (2010).

    Core size: 420nm/490nm Diameter=0.75 λ Height=0.9 λ

  • Challenge - create a laser that operates without threshold • efficient conversion of emited light into lasing mode • subwavelength size in all 3-D • isolation from near field interactions • thresholdless operation

    Nanoscale coaxial lasers

    M. Khajavikhan, A. Simic, M. Kats, J. H. Lee, B. Slutsky, A. Mizrahi, V. Lomakin, and Y. Fainman, “Thresholdless Nanoscale Coaxial Lasers” Nature, 10840, February 2012

    TEM-like scalable mode of coaxial resonator alleviates the threshold constrain

  • Electromagnetic Analysis

    Structure A Rcore=225 nm

    Δ=75 nm h1= 20 nm h2= 210 nm h3= 30 nm

    Structure B Rcore=200 nm

    Δ=100 nm h1= 20 nm h2= 210 nm h3= 30 nm

    - nanoscale structure results in discrete sparse sets of mode in the spectral domain - spectral location of modes can be determined by tailoring the size, inner-outer radius- height of the plugs and gain region, etc. - the gain acts as a spectral filter for the modes - ultimately we can design a cavity that has only one confined mode in the gain bandwidth

  • Thresholdless Laser For the single mode nanoscale coaxial cavity β→1:

    Spontaneous emission coupling into the continuous spectrum of the free space radiation modes is minimized in nanoscale coaxial cavities because: 1- the metallic cover protects the emitters in the gain region from coupling to radiation modes 2- the ultra-small aperture of nanocoax cavity blocks most of the radiation modes from penetrating into the cavity

    spontaneous emission into the lasing mode

    spontaneous emission into the continuous spectrum of the free space radiation modes → 0

    spontaneous emission other cavity modes

    spontaneous emission into the lasing mode

    β=

    →1

  • Light-light Measurement: Structure A T = 4 K Room-temperature

    Spectrum Evolution

    -At low pump power multimode nature of the cavity is reflected into the modified PL.

    -Blue shift of the spectrum with power

    Light-light curve

    -The laser shows three regions of operation: PL-ASE-Lasing -Rate equation model predicts that almost 20 percent of the spontaneous emission couples to the lasing mode (β≈0.2)

    -Because of higher temperature, the non radiative surface recombination dominates at lower pump levels and Auger non-radiative recombination dominates at higher pump levels

    PL

    Lasing

    ASE

    rate equation model

    - Below threshold the linewidth is proportional to the inverse of power as predicted by Schawlow-Townes formula

    - Above threshold the linewidth depends on many parameters including the gain-index coupling (α) and spontaneous emission coupling factor (β)

    Linewidth

    Schawlow-Townes

  • Light-light Measurement: Structure A T = 4 K T= 4.5 K

    Spectrum Evolution

    -At low pump power multimode nature of the cavity is reflected into the modified PL

    -Blue shift of the spectrum with power

    Light-light curve

    -The laser shows three regions of operation: PL-ASE-Lasing -Rate equation model predicts that almost 20 percent of the spontaneous emission couples to the lasing mode (β≈0.2)

    PL

    Lasing

    ASE

    rate equation model

    - Below threshold the linewidth is proportional to the inverse of power as predicted by Schawlow-Townes formula

    - Above threshold the linewidth depends on many parameters including the gain-index coupling (α) and spontaneous emission coupling factor (β)

    Linewidth Schawlow-Townes

  • Light-light Measurement: Structure B T = 4 K T = 4.5 K

    Spectrum Evolution

    - Single narrow Lorentzian emission is obtained over the entire five-orders-of-magnitude range of pump power - the linewidth at lowest pump powers agrees with the calculated Q of the TEM-like mode

    -Blue shift of the spectrum with power

    Light-light curve

    - No distinguishable ASE kink - Rate equation model predicts that more than 95 percent of the spontaneous emission couples to the lasing mode (β≥0.95)

    rate equation model

    - No sub-threshold narrowing of linewidth with inverse power (Schawlow-Townes formula)

    Linewidth

  • Outline/Contents

    • Introduction: Technology Drive

    • Nanophotonics Process

    • Monolithic SOI Integration Platform

    • Heterogeneous Integration with SOI

    • Optofluidic nano-plasmonics

    • Testing for Manufacturability

    • Conclusions

  • Optofluidics (DARPA’s Opto Center)

    Center for Optofluidic Integration

    Main Challenges: - Create novel devices that are uniquely enabled by fluids - Dynamic adaptation of optical properties - Integration of optical and biochemical functionality 500 nm 50 µm 5 mm

    E F G

    Vision: Combine Optics and Microfluidics

  • Main Challenges: • Create novel devices uniquely enabled by fluids integrated with optics • Use microfluidics delivery of biomolecules, viruses and cells for optical interrogation • Create optical field localization devices to increase interaction cross-section by co-localizing it with biomolecules for sensing and imaging

    - Plasmonic localization

    Optofluidic Nanoplasmonics: Combine Nanoplasmonics and Microfluidics

  • Overview of activities

    • SPP over a nanohole array – integration with microfluidics – universal biosensing

    experiments • Plasmonic Focusing and Field

    Localization – Diffractive Focusing of SPP – Plasmonic Photonic Crystal – Resonant Nano-Focusing-

    Antenna (RNFA)

    Al

    Si

    SPP

    Incidence

    Al Si

    aD

    h

    xy

    z

    x

    yz

    SiAu

    H-NSOM

    SiO2Au

    Si

    SiO2

    TEz

    Si

    T. W. Ebbesen, et. al. Nature 391, 667 (1998)

  • 3-D Metallodielectric Nanostructure for Enhanced SPR Sensing

    0

    0.2

    0.4

    0.6

    0.8

    1

    Norm

    aliz

    ed In

    tens

    ity

    400 nm hole diame250 nm hole diame

    0

    0.2

    0.4

    0.6

    0.8

    1

    Norm

    aliz

    ed In

    tens

    ity

    400 nm hole diame250 nm hole diame

    0 50 100 150 200 250 300 350 400 4501537.2

    1537.4

    1537.6

    1537.8

    1538

    1538.2

    1538.4

    1538.6

    1538.8

    1539

    Time (min)

    wav

    elen

    gth

    (nm

    )

    PBS@11

    sample100308-3 1ug/ml (16nM) Strept 0.54nm

    PBS

    1ug/ml Strep@42

    Fresh Strept@68

    PBS@125

    5ug/ml Strep@215

    PBS@291

    0 50 100 150 200 250 3001545

    1545.2

    1545.4

    1545.6

    1545.8

    1546

    1546.2

    1546.4

    1546.6

    1546.8

    154710-3-08sample4-Streptavidin of 8nM shift of 0.5nm

    50 ug/mlBSA-Biotin

    Wav

    elen

    gth

    (nm

    )

    PBS

    PBS@20min

    0.5ug/ml Strepa@80min

    PBS@168min

    1ug/ml Strepta@203min

    PBS@289min

    Substrate__SiO2

    ARC

    Polymer Polymer

    Au Au

    Control signal shows linear attachment of streptavidin from 0.6nm for 16nM to 0.3nm for 8nM

    • Resonant coupling to enhance localized SPP field • Enhanced sensitivity bio-sensing • Monitoring of surface hydrophilicity • Calibration and monitoring of binding affinity e.g. Biotinated-BSA and Streptavidin 2-D composite nanoresonant design and fabricated device

    Narrowed linewidth of farfield intensity

    0 20 40 60 80 100 1201532

    1534

    1536

    1538

    1540

    1542

    1544

    Res

    onan

    t Wav

    elen

    gth

    nm)

    Time (min)

    0

    2

    4

    6

    8

    10

    12

    Adso

    rptio

    n Th

    ickn

    ess

    (nm

    )

    Air

    After Methanol RinseAfter

    Methanol Rinse

    Air(1 day later)

    After Water Rinse

    0 20 40 60 80 100 1201532

    1534

    1536

    1538

    1540

    1542

    1544

    Res

    onan

    t Wav

    elen

    gth

    nm)

    Time (min)

    0

    2

    4

    6

    8

    10

    12

    Adso

    rptio

    n Th

    ickn

    ess

    (nm

    )

    Air

    After Methanol RinseAfter

    Methanol Rinse

    Air(1 day later)

    After Water Rinse

    Air

    After Methanol RinseAfter

    Methanol Rinse

    Air(1 day later)

    After Water Rinse

    Monitoring of surface monolayer

    Initial states: Signal channel immobilized BSA-biotin Control channel: Clear Au surface

    Lead to 400pM detection limit with 30pm spectral resolution

    Immobilization: 50ug/ml BSA-biotin Binding events: Streptavidin of 16nM, 8nM and 0.8nM (1, 0.5 and 0.05 ug/ml)

    0 50 100 150 200

    0

    0.1

    0.2

    0.3

    0.4

    0.5

    Time(min)

    Wav

    eleng

    th sh

    ift(nm

    )10-0908-2-BioBSA-BSA--strept(0.05--0.5ug/ml

    PBS

    PBS

    Strep- 0.05ug/ml

    Strep- 0.5ug/ml

    PBS

    Signal channel: BSA-biotin Control channel: BSA Control signal allows to acount for environmental effects and nonspecific binding

    Non-specific binding subtraction shows 0.8nM streptavidin detection

    16nM

    8nM

    8nM

    0.8nM

    Chen,Pang, Kher, Fainman, APL 94, 073117, 2009

  • Nanopillar

    Initial RIE etch to create nanopillar

  • Large Rim Opening

    260-nm rim diameter nanocrescent (using standard sputtering setup)

  • Smaller Rim Opening

    140-nm rim diameter nanotorch (using new sputtering setup)

  • Even Smaller Rim Opening

    50-nm rim diameter nanocrescent (using new sputtering setup)

  • • Used Renishaw inVia Raman system with StreamlineTM Raman Imaging

    • Measurement Process 1) SERS substrate is immersed in benzenethiol for

    3 hours 2) Rinsed with ethanol 3) Raman imaging of sample to locate nanotorch 4) Maximize Raman signal by incrementally moving

    substrate so laser beam is focused onto single nanotorch and perform point-measurement

    SERS Measurements

  • SERS Measurement of Nanotorch

    x5

    ~1.5 x 106 for the 260-nm opening for 1573 cm-1 mode ~8.2 x 106 for the 140-nm opening—6X times

    neat BT

    260-nm

    140-nm

    H. M. Chen et al (submitted)

  • Measurements of Reproducibility

    Peak [cm-1] Mode Std. Dev.

    1000 ν (C-C-C) 20.0%

    1023 ν (C-H) 12.3%

    1074 ν(C-C-C) and ν (C-S) 12.6%

    1573 ν (C-C-C) 16.5%

    < 20% deviation H. M. Chen et al (submitted)

  • ACKNOWLEDGEMENTS • Colleagues and postdocs: Vitaliy Lomakin (UCSD), Harry

    Wieder (UCSD), C. Tu (UCSD), A. Krishnamoorthy (Sun/Oracle), Boris Slutsky (UCSD), M. Nezhad (UCSD), L. Pang (UCSD), U. Levy (HUJI), H. C. Kim, K. Ikeda, A. Mizrahi (UCSD), M. Khajavikhan (UCSD), J. H. Lee (UCSD)

    • Students:D. Tan, L. Feng, O. Bondarenko, M. Abashin, A. Simak, M. Ayache, S. Zamek, K. Tetz, M. Chen

    • Funding : NSF, DARPA, SPAWAR, ARO, Cymer Inc., and Oracle

    • Bill Mitchell at the UCSB nanofabrication facility

    • UCSD Nano3 Facility

  • Conclusions/Summary Material design flexibility (Choice of materials, composition, and geometry) Novel Functionality (Near-field phenomena, Field localization, Enhanced nonlinearities) Miniaturization, Integration and Packaging (Compatible with CMOS process) Multifunctionality and Dynamic Adaptation (Integrating polarization and spectral

    dispersion, modulation, filtering, manipulation, detection, and generation of light) (1) Monolithic Si-photonic chip-scale integration: pulse compressor • Demonstration of self-phase modulation in Si • Demonstration of multiport dispersion compensation devices • Integration of discrete elements into a Si-photonic sub-system on a chip using

    CMOS compatible SOI platform (2) Heterogeneous Integration • Demonstration of optimal composite 3D metal-dielectric-semiconductor

    nanolasers with threshold gain allowing room temperature operation. • Demonstration of electrically pumped III-V nanolasers integrable with SOI • Demonstrated Thresholdless nanolasers (3) Optofluidic Plasmonics • Integration of microfluidics with Plasmonics • Plasmonic field localization for biosensing • Demo integrated biosensors (4) Near field testing for manufacturability: H-NSOM and CSTF • Demo H-NSOM operating with liquid cladding for testing photonic lightwave circuits

    Nanophotonics technology for on-chip systems integration provides:

    Slide Number 1Outline/ContentsIntroduction: Technology DriveOptofluidic information systems: “Making sense of sensing”Slide Number 5Establishing Nanophotonics ProcessSlide Number 7Slide Number 8New Calit2 Photonics Nanofabrication and Chip-scale Testing FacilitiesHeterodyne NSOMOutline/ContentsSlide Number 12Slide Number 13Slide Number 14Slide Number 15Dielectric Metamaterials: Form BirefringenceSlide Number 17Resonant Filter with Vertical GratingsSlide Number 19Photonic wire: add-drop filter for WDMSlide Number 21Importance of Pulse CompressionNanophotonic circuit: Ultrafast Compression of�Optical Pulses on a Silicon Chip� Outline/ContentsOptical interconnects and networking on a Si chipSlide Number 26Our Approach: Use Dielectric ShieldFabrication resultsRoom-Temperature LasingNanoscale coaxial lasers Electromagnetic AnalysisThresholdless LaserLight-light Measurement: Structure A�T = 4 KLight-light Measurement: Structure A�T = 4 KLight-light Measurement: Structure B�T = 4 KOutline/ContentsOptofluidics (DARPA’s Opto Center) Optofluidic Nanoplasmonics: Combine Nanoplasmonics and MicrofluidicsOverview of activitiesSlide Number 40NanopillarLarge Rim OpeningSmaller Rim OpeningEven Smaller Rim OpeningSERS MeasurementsSERS Measurement of NanotorchMeasurements of ReproducibilityACKNOWLEDGEMENTSConclusions/Summary