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MATERIAL SAFETY DATA· Sc0gin® HV Alginate
SHEET
MSDS
Ref.
N0.:
2203800
EY °“ʻ°""'“°`§S&mʻZSf$£fE°3This documen
t has been prepare
d to meet the requirement
s ofthe U.S. OSHA Hazard Communicatio
nStandard,
29 CFR 1910.1200;
the Canadak
Workplace Hazardous
Materials Information System (WHMIS)and, the EC Directive, 2001/58/EC.
1. PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAME: Scogin® HV Alginate
CHEMICAL FAMILY: Polysaccharide
.
MOLECULAR
FORMULA:
(C¤H»O:)nSYNONYMS: Algin (INCI name)
, alginic acid, sodium salt
GENERAL USE: Industrial - Paper
EMERGENCY 'I`ELEPHONE NUMBERS(800) 424-9300 (CHEMTREC - U.S.) I-(202) 483-7616 (CHEMTREC - All Other Countries)(303) 595-904
8 (Medical - U.S. - Call Collect)
+47 I 32 30 3500 (Plamt- Drammen, Nc>rway)
2. HAZARDS IDENTIFICATIONEMERGENCY OVERVIEW:
v§lIovEsli odorless, free—fl0wing
powder.Powder become
s slippery when wet.
Accumulation of overhead
settled dust may form explosive
concentrations
in air when distidispersed.
irbed and
POTENTIAL HEALTH EFFECTS: No signiiicant
health
effects
expected.
)
Y 1
T
Scogin® HV Alginate (2203800)
Date: 06/23/2004
`
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical
Name
CAS#
Wt.% EC No. EC Classsodi
um alginate
9005-ss-s
Net
classified
as
hazardous
4. FIRST AID MEASURESEYES: Flush with plenty of water. Get medical attention if irritation occurs and persists.
SKIN: Wash with plenty of soap and water.
INGESTION: Drink 1 or 2 glasses
of water. Never give anything by mouth to an unconsciousperson. If any discomfort persists, obtain medical attention.
INHALATIONZ Remove to fresh air. If breathing
difficulty or discomfort occurs and persists, obtainmedical attention.
NOTES TO MEDICAL DOCTOR: that product
hee
low ora] and inhalation
toiticity.
rt isnot a skin sensitizer and is non-irritating to the skin and eyes. It is expected to have low dermal toxicity.Aspiration or inhalation of this product could caus
e chemical pneumonitis
. Treatment is symptomatic and
supportive.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water. foam. dry chemical,
CO;
FIRE / EXPLOSION As with most
organic
materials.
excessive
accumulatioof dust on overhea
d structures
may produce
explosive concentrations
when disturbed
and dispersed
by asmall explosion that shakes down accumulated dust and causes, momentarily, an ignitable concentration.Product will bum when in contact with a tlame, but self-extinguishes when ignition source is removed.
I']
FIRE FIGHTING PROCEDURES: None. Treat as "Class A" tire. Once ignited, theproduct tends to smolder.
FL LE LHVHTS2 Not applicable
i! Aʻ
I
F 1
Scogin®
uv Argtttete
(zzossoo)
Date:
06/23/2004
6. ACCIDENTAL RELEASE MEASURESRELEASE NOTES: Powd
er becomes
slippery
when
wet.
Maintain
good
housekeepingto minimize accumulatio
n of settled dust, especiall
y on overhea
d surfaces.
Sweep
up the spilled nand dispose of in accordance with the waste disposal method outlined in Section 13, "DisposalConsiderations".
practicesiaterial
7. HANDLING AND STORAGETIANDLTNG AND STORAGE: Use local exhaus
t or genera
l dilution ventilation to control
exposure
to dust. Always use safe lifting techniques
when manually moving containers,
especially whenhandling containers weighing more than 50 pounds (22.7 kg). To protect quality, store in a tight containerin a cool, dry place. Avoid exposur
e to excessiv
e heat.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: Use
local exhaust,
which
is sufficient
enough
to removeairbome dust.
PERSONAL PROTECTIVE EQUIPMENTEYES AND FACE: Whenev
er airbome
dust concentrations
are high, appropriateprotectiv
e eyewear,
such as m0n0·g0ggles,
should be wom to prevent eye contact
RRRPID A'I"f lI}V• un.....,..,... ,1...... :.. tn- .......r..,.r.. t......tr..:..- -....t. »........»• 1... .·..··-•··.·.ll¤A nthhauteur uu-x 1 un 1 ; wnenever oust in me workers oreatnmg
zone cannot oe comroneo
wrmventilation or other engineering means, workers should wear respirators or dust masks approved byNIOSH/MSHA, EU CEN or comparabl
e certification organizatio
n to protect them against airborn
edust.
PROTECTIVE CLOTHING: No special clothing is required.
GLOVES: No special gloves are required.
COMMENTS:EXPOSURE
LIMITS:
Particulates Not Otherwise Classitied (PNOC):ACGH-Ifl WA10 mg/mi (inhalable particulate)3 mg/ms (respirable particulate)
Page
3 0f8
1
. — EScogin® HV Alginate (2203800) Date: 06/23/2004
9. PHYSICAL AND CHEMICAL PROPERTIESODQR;
Almost
0d0l'I¢SSAPPEARANCE: Yellowish to light-brown, free-flowing powder
AUTOIGNITION TEMPERATURE: > 200 °C (> 392 °F)
BOILING POINT: None volatile
EVAPORATION RATE: (Butvl acetate
= 1) Not annlicableFLASH POINT: Not applicabl
eMELTING POINT: Not availablePERCENT VOLATILE: Not availablepH: 6.5 - 8.5 (1% aqueous solution)
SOLUBILITY IN WATER: Slowly soluble, forming a viscous. colloidal solutionVAPOR DENSITY: Not available
VAPOR PRESSURE: Not available
~
10. STABILITYgANDg_REACTIVITY ( t t .CONDITIONS TO AVOID: Stron
g oxidizing agents
, high temperature
s and
high humidity levels.
STABILITY: StablePOLYM ERIZATION: Will not occur
HAZARDOUS DECOMPOSITION PRODUCTS: None known
ll. TOXICOLOGICAL INFORMATIONEYE EFFECTS: Non-
irritating (tehmt)
SKIN EFFECTS: Nee-ttttteuhg
(rabbit)
DERMAL LD50: No data available
for the product.
ORAL LD50: > 5,000 mg/kg (rat) ` (
INHALATION LC50: 4.72 mg/1
(1 hy (rat)
Page4of8
' tA l
Scogin® HV Alginate (2203800) Date: 06/23/2004
SENSITIZATION: (Skin) Non-sensitizing (guinea pig) ʻ
ACUTE EFFECTS FROM OVEREXPOSURE: This product
has low oral andinhalation toxicity. It is not a skin sensitize
r and is non-
irritating to the skin and eyes. It is expecte
d to have
low dermal toxicity. Large quantities of this product may cause
intestinal obstruction. Aspiration orinhalation could cause chemical pneumonltis.
CIIRONIC EFFECTS FROM OVEREXPOSURE: Sodium alginate
showed
noadverse effects in chronic studies when administered inthe diet (5 - 15%). NoThe Joint WHO/FAO Expert Committee on Food Additives (JECFA) has granIntake (ADI) of "not specilied“ (no upper limit), the best possible classilicatior39th session of 23/12 February 1992).
nitttietiiea
ere
eveuehre.ted an Acceptable Daily
x for food additives (IECFA,
CARCINOGENICITY:NTP: Not listedIARC: Not listed
OSHA: Not listedOTHER: ACGIH: Not listed
\
12. ECOLOGICAL INFORMATIONENVIRONMENTAL DA'IʻA:gseai
¤me1gteete is htetregteee
hre, eee is mt expeeteti
te havesignihcant environment
al effects. `
ECOTOXICOLOGICAL INFORMATION: No data
available
for the product;however, no significant effects on aquatic organism
s are expected
.
I3. DISPOSAL CONSIDERATIONSDISPOSAL METHOD: No speei
si titspessi
methods
are suggested.
it is the user's
tespettsutintyto comply with all applicabl
e local, Slate
. and federal laws, rules, regulation
s and standards
.NOTE: Handle as a non-hazardous
material
BOD(5) : approximately 400 mg 02/g
COD : approximately
650 mg O2/g
Page 5 of 8
tl
lI
A ·
seegiho r-rv Argtttate
(2202800) Date: 06/23/2004
14. TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION (DOT)
MARINE POLLUTANT: None
ADDITIONAL INFORMATION: Not listed in Title 49 of the U.S. Code ofFederal Regulations as a hazardousmaterial.Stabilizer} emulsiiier; water soluble, dry
INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG)
ADDITIONAL INFORMATION: Not regulated
ADR - EUROPEAN AGREEMENT CONCERNING THEINTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD
ADDITIONAL INFORMATION: Not regulated
INTERNATIONAL CIVIL AVIATION ORGANIZATION (ICAO) /INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA)
ADDITIONAL INFORMATION: Not regulated
OTHER INFORMATION:Canada (TDG) : Not applicable
15. REGULATORY INFORMATIONUNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) - ·-SECTION 302 EXTREMELY HAZARDOUS SUBSTAN CES (40 CFR 355, APPENDDI A):
Not listed
Page 6 of 8
ii
' t e1 ʼ
Scogin®
nv Argattete
(2203800)
D¤¢¤=
06/23/2004
SECTION 311 HAZARD CATEGORIES (40 CFR 370):Not applicabl
eSECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR 370):
The Threshold Planning Quantity (TPQ) for this product, if treated as a mixture, is 10,000 lbs;however, this product contains the following ingredients with a TPQ of less than 10,000 lbs.:None
SECTION 313 REPORTABLE INGREDIENTS (40 CFR 372):This product docs not contain any toxic chemical
s subject to the reporting requirement
s of
Section 313, Title III of the SARA (Superfund Amendments and Reauthorization Act) of1986.
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION ANDLIABILITY ACT)
CERCLA DESIGNATION & REPORTABLE QUANTITIES (RQ) (40 CFR 302.4):Not listed
TSCA (TOXIC SUBSTANCE CONTROL ACT)TSCA INVENTORY STATUS (40 CFR 710):
Listed ~
CANADAWHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM):
TO I T `ADIH€$fI€S\IbSI5IIIEIEISEʻ”ʻ” EE1:is1vr¤·`E· E"—-—~ M A RM A A
E NUMBERS:E 40l(s0dium alginatc)
INTERNATIONAL LISTINGSAustralia (AICS): ListedChina: ListedJapan (ENCS): (8)-237Korea: KE-0049
2Philippines
(PICCS): Liswd
ADDITIONAL REGULATORY INFORMATION:U.S.A.: This product is permitted for use in food unde
r Title 21 of the Code of Federa
lRegulations.
Refer to Regulations
for speciiic information on use in foods. I
EU: This product is permitted for use in food under the Miscellaneous
Additives Directive. Referto Directive for specific information on use in foods. I
Page
7 ot`8
- ` `
0
I_.!·'
III
II
IK
II!
ʻ¤.»4 _
Scogin® HV Alginate (2203800) Date: 06/23/2004
16. OTHER INFORMATION
NFPA
I}Z!I 2r-mmmbaii
j-Reaetivit
n N<>
¤¤No special requirementsNFPA = National Fire Protection Associatio
nDegree
of Hazard Code:4 = Extreme3 = High2 = Moderat
eI = Slight0 = Insigniiicant
REVISION SUMMARY:This MSDS replaces Revision #1, dated January 21,Changes in information are as follows:New Format, as well as:Section 12 (Ecological Information)Section 15 (Regulatory Information)Section 16 (Other Infomation)
2003. `
Scogin and FMC BioPolymer Logo - FMC Trademarks
© 2004 FMC Corporation.
All Rights Reserved.
Page
8 of8