MS June 2010 6CH01 6CH02 6CH07 6CH04 6CH05 6CH08

Mark Scheme (Results)

June 2010

GCE

GCE Chemistry (6CH01/01)

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6CH01_01 1006

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Section A (multiple choice) Question Number

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1 (a) B 1 Question Number

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1 (b) D 1 Question Number

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2 D 1 Question Number

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3 A 1 Question Number

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4(b) D 1 Question Number

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4 (c) C 1 Question Number

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4 (d) A 1 Question Number

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5 B 1 Question Number

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7 C 1 Question Number

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9 C 1

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14 (b) A 1 Question Number

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14 (c) C 1

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Section B Question Number

Acceptable Answers Reject Mark

15 (a)(i)

electrons (1) charge (1) square brackets not essential Mark independently Ignore (labelling of) nucleus unless incorrect

2

Question Number


15 (a)(ii)

1s22s22p63s23p6

Allow electron number as sub script Allow orbitals as capital letters Allow TE from (a) (i) if Ca atom or Ca+ ion

1

Question Number


15 (a)(iii)

Smaller Because it has one less (sub) shell of electrons / orbital / energy level / less shielding (1) And the ratio of protons : electrons has increased / more protons than electrons / greater net force on remaining electrons (so remainder of electrons held more closely) / greater effective nuclear charge (1)

bigger scores zero greater nuclear charge /positive charge

2

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Question Number


15 (a)(iv)

Any two from: Strong (electrostatic) forces / attractions / bonds (between ions) (1) (ions) held in giant lattice / many (ionic) attractions / forces / bonds (1) So large amount of energy needed (to break apart ions) (1)

Any mention of covalent or metallic bonds or atoms or molecules scores zero High temperature

2

Question Number


15 (b)(i)

Because the ions are free to move (when a potential difference is applied)

Electrons / particles are free to move

1

Question Number


15 (b)(ii)

The cations / barium and calcium (ions) are different sizes Ignore any discussion of reasons (could select either the calcium ion because it has more water molecules associated with it OR the barium ion because it has more shells of electrons and so larger)

Atoms are different sizes

1

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Question Number


15 (b)(iii)

Mass of calcium ions in 1 kg = 0.100 x 40 (= 4.0) (g) (1) If mass quoted must be correct to score first mark Hence 4.0 g per 1000 g of solution So ppm = (4.0/1000) x 1000000 = 4000 (ppm) (1) OR Mass of calcium ions in 1 kg = 0.100 x 40.1 (= 4.01) (g) (1) Hence 4.01 g per 1000 g of solution So ppm = (4.01/1000) x 1000000 = 4010 (ppm) (1) Correct answer alone = 2 marks Allow TE for second mark from incorrect mass

2

Question Number


15 (c)

(Sulfur / nitrogen oxides) form when (fossil) fuels are burnt / when petrol or diesel burn in vehicle engines / emissions from vehicle (engines) / volcanoes / lightning (1) They (react with water to) form sulfuric / sulfurous acid /nitric acid /acid rain / gases are acidic (1) Which reacts with limestone (to form soluble compounds) / limestone and acid take part in neutralisation / dissolves building / corrodes building (1) Allow correct equation for third mark but Ignore equations if mark already awarded. Ignore comments regarding erosion

from factories alone

3

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15 (d)

Either Yes, as the values match closely (so little deviation from ionic model) Or no, as the values are (slightly) different so a degree of covalency / not fully ionic

100% ionic covalent

1

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Question Number


16 (a)

Atoms (of an element) with the same number of protons (1) But with different number of neutrons (1) Same atomic number but different mass number only = (1) Element(s) with same number of protons but different number of neutrons = (1) max Ignore comments on electrons unless incorrect in which case award max 1

2

Question Number


16 (b)(i)

(Electric field) accelerates ions

1

Question Number


16 (b) (ii)

(Magnetic field) deflects / changes direction of / bends the beam of ions if the term ‘ions’ is missing or an incorrect term is used e.g. ‘atoms’, penalise only once in parts b (i) and b (ii)

just bends ions

1

Question Number


16 (c)

% abundance = (135 x 9.01 + 136 x 10.81 + 137 x 12.32 + 138 x 67.86) /100 (1) = 137.4 (1) ignore units Allow TE for one slip in transfer of data from question Correct answer scores (2)

Just 137 as final answer 137.39 137.3903 137.390

2

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Question Number


16 (d)

three peaks (caused by Br2

+ ions) (1) because ions (79Br-79Br)(+) and (81Br-79Br)(+) / (79Br-81Br)(+) and (81Br-81Br)(+) (1) Mark independently

2

Question Number


16 (e)

Any one analysis of material from space / drug testing in sport / identify breakdown products from drugs in body / quality control in pharmaceutical industry / identify molecules from sample with potential biological activity / radioactive dating with context e.g determine age of fossils / human remains The uses above must have a context / determining Mr of a molecule / evidence for structure from fragmentation pattern

1

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Question Number


17 (a)

(1) for around carbon and its hydrogens (1) for around oxygen and its hydrogen Allow all dots or all crosses Ignore circles around atoms

2

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17 (b)(i)

C(s) / (graphite) + 2H2(g) + 2O2(g) Correct species (1) Allow oxygen above arrows rather than in box Balancing and state symbols (1) Second mark dependent on correct species except as below with either hydrogen or oxygen or both as atoms e.g C(s) / (graphite) + 4H(g) + 4O(g) Scores second mark

2

Question Number


17 (b)(ii)

Enthalpy / energy / heat(energy) change when one mole of a substance (1) Is formed from its elements (in their most stable / standard states) (1)

Under standard conditions of 298K/ 25 ºC / any stated temperature AND 1 atm pressure / 101 kPa / 100 kPa (1) Definitions based on lattice enthalpies may score third mark only

heat required / heat given out / heat taken in

3

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Question Number


17 (b)(iii)

∆HƟc = -∆H1Ɵ + ∆H2Ɵ (1) = (2 x −285.8 + −393.5) − (−239.1) = −726 (1) Ignore units Correct answer alone = 2 marks +726 = 1 -440.2 = 1 if omit multiply by 2

2

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17 (c)(i)

20.7 x 200 x 4.18 = 17305(.2) (J) ignore sf except 1 sf i.e. 20000 OR 20.7 x 200 x 0.00418 = 17.305(2) kJ ignore sf except 1 sf i.e. 20 ignore signs ignore mol−1

1

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17 (c) (ii)

0.848/32 = 0.0265 (mol) ignore sf except 1 sf i.e. 0.03

1

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Question Number


17 (c)(iii)

17305.2/0.0265 = −653000 (J mol−1 ) (3sf) OR −653 (kJ mol−1) (3sf) Ignore missing units but penalise incorrect units Allow TE from (c)(i) & (ii)

1

Question Number


17 (c)(iv)

Any two from As heat/energy absorbed by apparatus / heat/energy ‘lost’ to surroundings (1) methanol not completely burnt / incomplete combustion (1) methanol ‘lost’ by evaporation (1) cannot ensure all products are at standard conditions at end of reaction / water is produced as a gas / reaction not carried out in the standard conditions (1)

just heat/energy loss just incomplete reaction

2

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Question Number


18 (a)(i)

Crude oil / petroleum / coal

Oil on its own / Natural gas / fossil fuels / any named fraction of crude oil

1

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18 (a)(ii)

use of high temperatures / heat (in the absence of air) / thermal decomposition / catalysts (1) Either to break large molecules / to form smaller molecules / to break bonds in large molecules / to break carbon-carbon bonds (1) OR producing alkenes / producing carbon-carbon double bonds (1)

2

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Question Number


18 (a)(iii)

Risks (2) Amendments (2)

Risk Amendment exposure to harmful / toxic fumes

Set up in fume cupboard

Escape of flammable / harmful / toxic reactants or products from ill fitting bung

Correct fitting of bung

Escape of flammable / harmful /toxic reactants or products from poorly positioned delivery tube

Placement of delivery tube below mouth of test tube / use a longer delivery tube

suck back Attach Bunsen valve / remove delivery tube from water before stopping heating etc

Mark all 4 points independently If escaping gases linked to 2 amendments but no risk mentioned then allow 1 for risk

Dangerous collect in syringe

4

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18 (b)(i)

Reagent – Hydrogen/H2 (1) Catalyst – Nickel/Ni/palladium/Pd/platinum/Pt (1) Mark independently

2

Question Number


18 (b)(ii)

1,2 – dibromoethane (1) ignore punctuation

H

H H

C C H

BrBr (1)

Mark independently Allow CH2BrCH2Br

1,2 - bromoethane dibromoethane Skeletal formula C2H4Br2

2

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Question Number


18 (b)(iii)

From purple / pink → colourless

clear

1

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18 (c)(i)

arrow from bromide ion can start from any part of the bromide ion and can go towards the C or the + sign on the intermediate bromide ion must show negative charge allow 2 max for addition of Br2 and any other electrophilic additions half headed arrows used throughout penalise only once

∂- on bromide ion for third mark

3

Question Number


18 (c)(ii)

Bromine / bromide / hydrogen could add to either carbon (in the double bond) / bromide / bromine could add to either primary or secondary carbocation / (propene is unsymmetrical) so could form 1-bromopropane and / or 2-bromopropane. Allow correct structural or displayed formulae.

bromine could add to any of the three carbons

1

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Question Number


18 (d)

C C C

H

H H

C

H H

C6H5 H C6H5

position of hydrogen atoms and phenyl groups (1) Allow phenyl groups on 2nd and 3rd carbon OR 1st and 4th OR 1st and 3rd

carbon carbon single bonds and continuation bonds (1) second mark not awarded for incorrect monomer

(1) max with or without square brackets and n or numbers Do not penalise H from phenyl groups attaching to carbon chains Ignore extra square brackets, numbers and ‘n’ provided 2 monomer units shown

2

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Question Number


18 (e)(i)

Any two (raw material for) paper cup requires cutting down trees (1) polystyrene cup uses less energy (280 kWh rather than 980 kWh) to produce so less CO2 released / less fossil fuels (1) polystyrene cup releases less sulfur based compounds into air so less chance of forming acid rain / less chance of damaging buildings / acidifying lakes (produces 3.5 kg rather than 11 kg) (1) polystyrene cup releases no chlorine compounds which damages ozone layer / poisonous (produce 0 kg rather than 0.4 kg) (1) 2 pieces of data chosen with no explanation allow 1 mark Ignore comments regarding water

2

Question Number


18 (e)(ii)

2 additional factors e.g ease of recyclability whether cup is easy to reuse space taken up in landfill type and amount of gases formed if incinerated useful heat obtained if incinerated biodegradeability / how long they take to decompose management of gases produced during decomposition durability / how long the cup lasts method of disposal Ignore comments regarding atom economy Ignore comments regarding acid rain / ozone layer / greenhouse gases unless linked to gases produced during disposal

2

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Further copies of this publication are available from Edexcel Publications, Adamsway, Mansfield, Notts, NG18 4FN Telephone 01623 467467 Fax 01623 450481 Email [email protected] Code US023629 Summer 2010 For more information on Edexcel qualifications, please visit www.edexcel.com/quals Edexcel Limited. Registered in England and Wales no.4496750 Registered Office: One90 High Holborn, London, WC1V 7BH

6CH01_01 1006

mailto:[email protected]


June 2010

GCE







Summer 2010



6CH02_01 1006



Correct Answer

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1(a) D 1 Question Number

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1(b) A 1 Question Number

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1(c) B 1 Question Number

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11 A 1

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18 B 1

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19 (a)

Mark independently From: colourless (1) To: pink / (pale) red (1) If colour change wrong way round max (1)

From: clear To: magenta / purple / cerise

2

Question Number


19 (b)

(Titres 2, 3 and 4) are concordant / within 0.2 (cm3) / within 0.1 (cm3) / consistent OR Titre 1 is rough / trial / a rangefinder / too far out / overshot ALLOW Titre 1 is an outlier / is anomalous

Just “very similar” / within 0.05 / within 0.5 Titre 1 “very different” Just “not accurate” “Titration 1 is a control experiment”

1

Question Number


19 (c)

28.00 (cm3) / 28.0 (cm3) / 28 (cm3)

28.14 (cm3) / 28.1 (cm3) / 28.13 (cm3)

1

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IN (d)(i) to (d)(v), IGNORE UNITS EVEN IF INCORRECT AND ALLOW ANSWER IN EACH CASE WHETHER BY TE OR MARK SCHEME ANSWER, REGARDLESS OF

ANY WORKING SHOWNQuestion Number


19 (d)(i)

0.100 x 28.00 = 0.0028 / 2.8 x 10 (mol) -3

1000 ALLOW TE from (c) IGNORE sf except one sf

1

Question Number


19 (d)(ii)

0.0028 / 2.8 x 10-3 (mol) OR Same answer to (d)(i) if TE applied IGNORE sf except one sf

1

Question Number


19 (d)(iii)

0.0028 = 0.112 (mol dm-3) 0.025 OR Answer to (d)(ii) if TE applied from (d)(ii) 0.025 IGNORE sf except one sf

1

Question Number


19 (d)(iv)

10 x 0.112 = 1.12 (mol dm-3) OR Answer to (d)(iii) x 10 if TE applied from (d)(iii) IGNORE sf except one sf

1

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Question Number


19 (d)(v)

1.12 x 60 = 67.2 (g dm-3) OR Answer to (d)(iv) x 60 if TE applied from (d)(iv) IGNORE sf except one sf

67.1

1

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Question Number


19 (e)

NOTE: answer must refer to making up the diluted solution and not the titration NOTE: the Reason mark must be correctly linked to the Improvement Improvement: Use a pipette / burette to measure acid (solution) (1) Reason: Pipette / burette more accurate (than a measuring cylinder) (1) ALLOW “more precise” OR Improvement: Shake / invert the volumetric flask (thoroughly) (1) Reason: To ensure a uniform concentration (1) OR Improvement: Rinse out measuring cylinder (and transfer washings to the volumetric flask) (1) Reason: To ensure all the acid is transferred (to the volumetric flask) (1) OR Improvement: Use a (teat) pipette to make up to the mark (in volumetric flask) (1) Reason: To ensure volume of solution accurately measured (1)

Use of volumetric flask for initial measurement of volume of vinegar solution “more reliable” swirl (the flask) to ensure “fully dissolved” just “rinse out apparatus” Any suggested improvements relating to the titration part of this experiment

2

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Question Number


19 (f)(i)

Z / between 27.85 and 28.05 (cm3) ALLOW 27.95 ±0.10 (cm3)

1

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19 (f)(ii)

Any one of the following / a statement equivalent to:

• overshoots/misses end-point • water left in burette / pipette • air lock below tap in burette / air in

pipette • burette not vertical • alkali not at stated concentration • leaking tap • not reading meniscus at eye-level • funnel left in top of burette • not reading level against a white

background • not reading meniscus correctly • washing pipette between titres • washing the flask with the solution that

will go in it • not swirling flask / mixture

IGNORE “errors in calculation”

“water left in conical flask” just “measurements may be inaccurate” “there could be uncertainty with other equipment” “contamination of the vinegar”

1

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Question Number

Acceptable Answers Mark

20 (a)(i)

H C

H3C

C H

H

H

Br

H C

H3C

C H

H

H

Br(:)

H

H3C

C H

H

H

C

Br

(1) for both arrows

(1) for carbocation(1) for arrow

1st mark:

• top arrow must start from the double bond / close to the double bond and not from either of the C atoms of the C=C bond

• top arrow can end on, or close to, the H in HBr • lower arrow must start from the bond and not the H

atom in HBr REJECT full charges on the HBr 2nd mark: the carbocation must have a full + and not ∂+ 3rd mark:

• the bromide ion must have a full — and not ∂— • the lone pair need not be shown on the Br—

• arrow from bromide ion can start anywhere on the Br–— or from the minus sign or the lone pair (if shown) on Br— and can go to the C or the + sign on the intermediate

3rd mark available even if an incorrect intermediate has been drawn

3

Question Number


20(a)(ii)

H C

H3C

C H

H

H OR CH3 CH2 CH2

+

1

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Question Number


20(b)(i)

B /CH3CH2CH(OH)CH3 /butan-2-ol (1) Because the C atom bearing the OH is attached to two other C atoms / C with OH group attached to one H (atom) (1) ALLOW Because the C atom bearing the OH is attached to two alkyl groups These marks are stand alone

Just “OH is on the second C atom” / “OH is in the chain, not on the end” OR “OH attached to two methyl / two CH3 groups” OH- (instead of –OH)

2

Question Number


20(b)(ii)

C /(CH3)3COH /(2-)methylpropan-2-ol (1) Because it is a tertiary (alcohol)/no C-H bonds to break (1) ACCEPT a description of a tertiary alcohol These marks are stand alone

“tertiary structure” / “tertiary carbon” / “tertiary carbocation”

2

Question Number


20(b)(iii)

BOTH B / CH3CH2CH(OH)CH3 / butan-2-ol AND

H

H H O H

H

HHH

C C C C

BOTH required for the one mark

Structural / skeletal formula

1

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Question Number


20(b)(iv)

A / CH3CH2CH2CH2OH / butan-1-ol and D / CH3CH(CH3)CH2OH / (2-)methylpropan-1-ol BOTH needed for one mark

1

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20(b)(v)

Steamy fumes / misty fumes / white mist

White smoke

1

Question Number


20(b)(vi)

(C4H9OH + PCl5 ) C4H9Cl + POCl3 + HCl (1) for HCl (1) for rest of the equation correct NOTE: Equation must be completely correct for the second mark. ACCEPT “PCl3O” instead of POCl3

2

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21(a)(i)

Mark the two points independently, subject to the constraint in Reject column Effect: (Equilibrium) shifts to the right (1) ALLOW: “favours forward reaction” / “increase the amount of product” / “increase the yield (of product)” Reason: Exothermic (in forward direction) (1) NOTE: Just “(equilibrium) shifts in the exothermic direction” scores (1)

“Equilibrium shifts to left” will score (0) for (a)(i)

2

Question Number


21(a)(ii)

First mark: Activation energy for the reaction is too high / (if cooled) molecules would not have enough energy to react / few(er) molecules have the required Ea/more molecules have energy ≥ Ea

at higher temperatures OR not (technologically) feasible to cool the gases before they enter the converter/costly to cool the gases

(1) Second mark: (cooling the gases would make) the rate (too) slow /rate is faster if the temperature is high (so the gases are not cooled)

(1)

Cooling the gases decreases the yield (of products) /an incorrect Le Chatelier argument

2

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Question Number


21(a)(iii)

Mark the two points independently, subject to the constraint in Reject column Effect: (Equilibrium) shifts to the right ALLOW: “favours forward reaction” / “increase the amount of product” / “increase the yield of product”

(1) Reason: Shifts / moves in the direction of fewer (moles of gas) molecules ALLOW “shifts in direction of fewer moles (of gas molecules)”

(1) IGNORE effect on the rate

“Equilibrium shifts to left” will score (0) for (a)(iii) “.... fewer atoms”

2

Question Number


21(b)(i)

(In NO): +2 / 2+ (1) (In NO3

–): +5 / 5+ (1) NOTE: (In NO): Just “2” AND (In NO3

–): Just “5” scores (1)

2

Question Number


21(b)(ii)

NO3— + 4H+ + 3e— → NO + 2H2O

ACCEPT multiples

1

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Question Number


21(b)(iii)

Ag → Ag+ + e(—) / Ag – e(—) → Ag+

ACCEPT multiples IGNORE state symbols, even if incorrect

“Ag + e— Ag+”

1

Question Number


21(b)(iv)

3Ag + NO3

— + 4H+ 3Ag+ + NO + 2H2O (2)

(1) for multiplication of the silver half-equation by three or cq multiple from (b)(ii) (1) for rest of equation correct NOTE: Equation must be completely correct for the second mark. IGNORE state symbols, even if incorrect

if any e— are left in the final equation, second mark cannot be scored

2

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SECTION C Question Number


22(a)(i)

2-bromo-2-chloro-1,1,1-trifluoroethane ALLOW 1-bromo-1-chloro-2,2,2-trifluoroethane IGNORE incorrect punctuation and incorrect order of the halogen atoms

“1-bromo-1-chloro-2-trifluoroethane”

1

Question Number


22(a)(ii)

London (forces) / instantaneous dipole / induced dipole / dispersion / van der Waals’ (forces) (1) permanent dipole (-permanent dipole) (forces) / dipole-dipole (forces) / dipole (forces) (1) IGNORE any references to hydrogen bonding

2

Question Number


22(a)(iii)

Any one of the following / a statement equivalent to: Ethanol is flammable [Note: if any reference to only the halogenoalkane being flammable scores (0)] OR reference to greater control of heating (e.g. “to control the rate of reaction” / “to prevent the reaction being too vigorous” / “to prevent the reaction getting out of control”) ALLOW “so that the reaction takes place slowly” OR “(reaction) mixture is flammable/it is flammable” OR “Bunsen flame too hot / too vigorous” OR “(Bunsen flame) would cause too much evaporation to occur” OR “(allows) constant heating”/ “even heating”

Compound X is flammable Just “to prevent an explosion” Just “to minimise the risk”

1

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22(a)(iv)

Solvent (for both reactants) OR To dissolve (the reactants) OR To mix the reactants ALLOW “To enable the mixture to dissolve”

Just “mixing” “to acidify the silver nitrate”

1

Question Number


22(a)(v)

Cream / off-white / pale-yellow precipitate ALLOW Cream / off-white / pale-yellow solid IGNORE incorrect identification of this precipitate NOTE: both colour and state (of the AgBr) needed

Just “Yellow” (precipitate/ solid) OR “white precipitate” OR “white-yellow precipitate” (0) if contradictory observation given, eg “cream precipitate and fizzing”

1

Question Number


22(a)(vi)

Ag+(aq) + Br— (aq) → AgBr(s) Must include state symbols ACCEPT multiples

If NO3

— left on either side

1

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Question Number


22(b)(i)

Mark independently Name: ethanol (1) ALLOW “ethan-1-ol” Structural formula: CH3CH2OH or C2H5OH (1) Allow displayed formula ALLOW brackets around the OH

C2H6O

2

Question Number


22(b)(ii)

Mark independently 1st mark: Energy of products, labelled, below that of reactants, labelled (1) Note if the words ‘reactants’ and ‘products’ are written, ignore any formulae Note if the words ‘reactants’ and ‘products’ are not written, both formulae of the reactants and both formulae of the products must be given. (Na+ ions can be omitted.) 2nd mark: Shape of profile with one ‘hump’ (1) 3rd mark: Activation energy / “Ea” correctly shown with a single-headed arrow to the peak (or close to it) (1)

Maxwell-Boltzmann curve scores (0) for (b)(ii) Double-headed arrow showing Ea

3

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22(c)(i)

Chlorofluorocarbon Accept ..flouro… spelling

1

Question Number


22(c)(ii)

Any one of the following / a statement equivalent to: aerosol / propellant / spray cans OR (degreasing) solvent OR fire retardant ALLOW fire extinguishers / putting out fires ALLOW making expanded polystyrene / making plastics / making polymers

pesticides / anaesthetics just “retardant” anti-freeze air-conditioning frying pans detergents

1

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22(c)(iii) QWC

Mark independently 1st mark: O + O3 → 2O2 IGNORE any state symbols (1) 2nd mark: (chlorine free radical acts as a) catalyst (1) Last 3 marks: any three from:

• (the chlorine free radical) persists in the atmosphere / continues to attack / is regenerated / (starts) a chain reaction (1)

NOTE ‘chain reaction’ may be described in terms of a chlorine radical breaking down many / a large number of / a specified number of, eg 10,000, O3 (molecules). NOTE: As written, this response also earns the scoring point relating to ozone depletion.

• less ozone / ozone decreases / causes hole(s) in ozone layer / breakdown of ozone (layer) / damages ozone layer / depletes ozone layer (1)

• UV (reaching Earth’s surface) increases

/ less UV absorbed / (more) UV reaches Earth’s surface (1)

• causes (skin) cancer/mutation / DNA

damage occurs (1) IGNORE any references to “global warming” / “Greenhouse Effect”

If Cl● and / or ClO● left in equation OR 2O3 → 3O2

Just (UV) “harmful”

5

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Question Number


22(d)(i)

The C-F bond is (very) strong OR C-F bond is (much) harder to break than the C-Cl bond OR UV/radiation does not have enough energy /does not have (high) enough frequency

Any mention of electronegativity OR mention of bond polarity scores (0)

1

Question Number


22(d)(ii) QWC

(long wavelength) IR /infrared radiation (1) The molecule is polar OR (the molecule) changes its polarity OR “polar bonds” OR vibrational energy/vibrations of the bonds / stretching or bending increases OR (IR causes) bonds to vibrate

(1)

Marks are stand alone

UV / ultraviolet Just “molecule vibrates” (0)

2

6CH02_01 1006

Further copies of this publication are available from Edexcel Publications, Adamsway, Mansfield, Notts, NG18 4FN Telephone 01623 467467 Fax 01623 450481 Email [email protected]

Order Code US023632 Summer 2010 For more information on Edexcel qualifications, please visit www.edexcel.com/quals Edexcel Limited. Registered in England and Wales no.4496750 Registered Office: One90 High Holborn, London, WC1V 7BH

6CH02_01 1006



June 2010

GCE







Summer 2010



6CH07_01 1006


Qu ties on Acceptable Answers

Re tjec Number

Mark

1 (a)(i

Nichrome wire / platinum wire / ceramic / silica rod (1) Accept recognisable spelling eg platinium, nickrome (Co eacid H / solution (1) Salt (mixed with wire and acid, and) placed in a ho l nsen bur r

Titanium, aluminium, nickel, chromium, cosilicon Salt plBunsen burner OR flaalo it

3 )

nc ntrated /dilute) hydrochloric / Cl/HCl(aq)

t/b ue/roaring/non-luminous/Bunsen/Bune flame (1)

pper,

aced in

me ne OR burn

Question Number

Acceptable Answers Re tjec Mark

1 (a)(ii)

Li+

Accept li+/ Li+ ions/ A is Li+

Ignore (aq), (s), (l), (g)

Li, Li2+ Rb Ca2+, SLit mlith m

1

,Ca, Sr,

r2+, Rb+

hiu / iu ions

Question Number


1 (

Cal u 2 / slaked lime

Accept calcium oxide/CaO / quicklime Ignore (aq) / solution / (s) / solid

Cal u CO2/CaCO3

1

b)(i) ci m hydroxide/Ca(OH) ci m/Ca

6CH07_01 1006

Question Nu e

Acceptable Answers Re tjec mb r

Mark

1 (b)(i

CO /Ignore separated additional cation

Carbon dioxide gas given off (when this carbonate /hydrogencarbonate is heated/decomposed) (1) Second mark depends on a recognisable carbonate/hydrogencarbonate ie CO3, CO3

-, carbonate, hydrogencarbonate Li2CO3, LiHCO3, CaCO3 etc

CO C 3 , car nhyd ognate Li2 3 LiHCO3,

CaCO3 etc

2 i) 3

2- HCO3- (1) 3, O -

bo ate, r encarbo

CO ,

Question Number


1 (c)(i)

Oxide / O2-

Oxygen, O2, O, O-

calcium oxide / CaO

1

Question Number


1 (c)(ii)

Hydroxide / OH-/(OH-)2

(OH)2

- 1

6CH07_01 1006

Qu ties on Acceptable Answers Re tjec Number

Mark

1 (c)(i

Mark with reference to (ii) For correct answer to (ii) Un r er) (1) Tu Accept other appropriate indicators eg (red) litmus (paper) turns blue ORAdd a suitable metal ion solution (1) to e[seOR Wa s (1) Alkalineblu aOR Oth r eg Titrate with hydrochloric acid and suitable ind r If incorrect answer to (ii) but answer as above (1) a If incorrect answer to (ii) with correct test and correct result for that ion (1) max

2 ii)

ive sal indicator (paprns blue/purple/pH12-14 (1)

giv a correct colour of precipitate (1) e User Guide 2 page 17 for some details]

/ heat with ammonium ionrm gas given off/damp red litmus turns

e/ mmonia gas given off (1)

reasonable tests with results e

icator with correct final colou

m x

Question Nu e

Acceptable Answers Re tjec mb r

Mark

1 (d)

Li2CO3 Accept Li2(CO3) OR LiHCO3

Accept correct formula of any red flame coloured s block metal ca n te eg Rb2CO3, CaCO3, SrCO3

LiCO3

1

rbo ate/hydrogencarbona

6CH07_01 1006


Mark

2 (a)(i

Silver((I))iodide (solid / precipitate) / AgI / Ag+I- /AgI(s) OR Silver((I))iodide (solid / precipitate) and AgI / Ag /

Iodide (alone) Iodine Silver ((I)) iodine AgBr and AgI Cl-/Br-/I-

If both name and formula are given and either is wrong eg Silver((I)) Iodine and AgI

1 )

+ -I AgI(s)

Question Number


2 (a)(ii)

C3H n any order) Acformu

Any answer which does not have C3H7I somewhere

1

7I (i

cept additional information like additional lae

Question Number


2 (a)(iii)

H | |H- C C -H | H Accept structural formula CH3CHICH3

Displayed or structural formula for 1-iodopropane

1 H H

| C – – | |

I H

6CH07_01 1006

Question Number


2 (a)(iv)

At first ignore answer to (iii) Propan-2-ol / 2-propanol / CH3CH(OH)CH3 Accept displayed formula (allow slightly displaced bonds C) | HO Accept skeletal formula Allow TE from (a)(iii) eg 1-iodopropane forms propan-1-ol

Propanol prop-1-ol C3H7OH

1

Question Number


2 (b)(i)

Mark colours independently From orange (1) To green/blue (1) Accept shades of green eg dark green, muddy green, green-brown

yellow

2

Question Number


2 (b)(ii)

Propanone Accept propan-2-one Allow propanal/propanoic acid if TE from (a)(iv)

prop((-2-))one

1

Question Number


2 (b)(iii)

Oxidation / redox / oxidation and reduction / oxidation of … (eg alcohol)

Reduction Condensation/substitution/ Addition

1

6CH07_01 1006


Mark

3 (a)(i

(Glass/graduated/volumetric/bulb)pipette (and pipette filler) Accept any recognisable spelling of pipette eg pipet, pipette etc

Burette/ pipette and burette/ measuring cylteat pdro ipip t Pipate/pipotte

1 )

inder/ ipette/

pp ng et e

Question Number

Acceptable Answers Rej cte Mark

3 (a)(ii)

Starch (solution) (1) Accept startch Blue-black/blue/black to colourless (1) Accept purple/blue-black to colourless Second mark depends on first

Other indica Methy/phenthalein Colourblue-black/black

2

tors egl orange olph-

less to

blue/

Question Nu emb r


3 (b)(i

14.5(0), 13.7(0), 13.75 All three needed for the mark

1 )

6CH07_01 1006

Question Number


3 (b)(i

The first result is discarded/ ignored/ not included/a range finder OROnly use last two values ORTh e rd are concordant / first value not within 0.2 cm3

Accept: ThOR Actual correct average calculation to give 13.73/13.725

1 i)

e s cond and thi

is is the average of the second and third runs

Question Number


3 (b)(iii)

13.73 x 0.0200 = 2.746 x 10-4 /0.0002746(mol) 1000 Accept 2.7/2.75 x 10-4 Note that 13.725 gives 2.745 x 10-4 Allow TE from different calculated average titre

1 sf

1

Question Number


3 (c)

1.373 x10-4 /0.0001373(mol) Also 1.35/1.37/1.375 /1.4 x 10-4 Accept answer to (b)(iii) 2

1 sf (unless already penalised anywhere in this question)

1

6CH07_01 1006


Mark

3 (d)

4.58 x 10-5 /0.0000458(mol) 4.57667/4.577 x 10-5 etc Als Ac

o 4.583/4.57/4.6(0) x 10-5

cept answer to (c) 3

1 sf (unless already penalised an h re in this question)

1

yw e

Question Number

Acceptable Answers Re tjec Mark

3 (e)(i)

Vo

(100 cm3) round bottomed flask/ conical flask/ measuring cylinder

1

lumetric/graduated (flask)

Question Number


3 (e)(i

These marks are independent of flask used in (i) Tra f ings (1) Ma u Mix g is must be at the end) (

Make sure it is all transferred

3 i)

ns er solution and rinsings/wash

ke p to the mark (1)

in / inverting / shaking (th1)

Question Number


3 (e (i

4.58 x 10 Also 4.57/4.6 x 10-4 Accept Answer to (d) x 10

1 sf (unlesalready penalised anywhere in this question)

1 ) ii) -4 /0.000458 (mol) s

6CH07_01 1006

Question Number


3 (e)(i

4.58 x 10 x 214 = 0.098 /0.98012 g Also 0.097941/0.0979 etc

Accept answer to (e)(iii) x 214 Ign e

1 sf (unless already penalised anywhere in this question)

1 v) -4

or SF

Question Number


3 (e)(v)

0.098 x 100 0.10 = 98 /98.0/98.01/98.012 % Also 97.941/97.94/97.9 % Accept answer to (e)(iii) x100 0.10 correct answer with no working scores (1) Ignore SF

1 s ualready penalised anywhere in this question)

1 f ( nless

Question Number


3 (f)

Sulfuric acid is corrosive/irritant/irritable/burns (skin)

Sulfuric acid is harmful/ hazardous/ toxic

1

6CH07_01 1006


Mark

4 (a)(i

From the equation 1 mol butan-1-ol gives 1 mol of 1-bromobutane / ratio 1:1 OWTTE (1) As 80% yield, 0.125 mol of butan-1-ol gives 0.125 x 0.8 mol = 0.1 mol of 1-brombutane (1) Accep that they appreciate the proportion calculation and the mole ratio Examples: Number of moles of butan-1-ol = 0.1 x 100

)

t any clear indication

/ 0.1 80 0.8 (= 0.125) OR Nu e butane = 80

mb r of moles of 1-bromo x 0.125

100 (= 0.1) In both these examples ‘butan-1-ol’/ ‘1-bromobutane’ as appropriate, must be present to g The numerical expression alone would gain (1) OR As above examples but additionally using molar masses to calculate masses

2

ain (2)

Question Number


4 (a)(ii)

74 x 0.125 (1) = 9.25 g) 9.

(

25 = 1.4 /11.42/11.420/11.419753 cm (1) 0.81 ie o Accept 11.4 /11.42/11.420/11.419753 cm3 (2) (with no working)

1sf

2

1 3

ign re sf unless only one

6CH07_01 1006

Question Number


4 (a)(iii)

0.125 x 119 = 14.875 /14.87/14.88/14.9/15 (g)

1 s

1

f

Question Number


4 (b)

Flask in beaker of labelled cold water (1) Water need not be drawn in but… Condenser with jacket (1) Need not be labelled, can be at any angle so long as it goes upwards Condenser inlet and outlet with correct water direction (1) This mark can be given if no jacket is present open at top and no leaks(1) This mark is conditional on a condenser Do not penalise accidental closures in drawing or attempts to draw out perimeter of apparatus making the condenser appear closed If distillation set up is drawn the beaker of cold water mark can be awarded

heated beaker (of cold water) stopper in the top/tap funnel in the top of the condenser unless clearly open

4

6CH07_01 1006


Mark

4 (c)(i

Lower layer as more dense Lower layer is 1-bromobutane because it is denser Lower r / butan-1-ol

1

)

layer as denser than wate

Question Number


4 (c)(ii)

To r mhydrochl acid/H2SO4 (1) by a

2 e ove / neutralize / react with remaining

oric acid/HCl/acid/sulfuric

re cting to form carbon dioxide (gas) (1)

Question Number


4 (d

Distillation /fractional dist /distil /d l Accept any recognisable spelling Ignore further description Allow a description which includes the words he n

Dry/filter/an i

1

)(i) illation /redistil isti late

ati g / boiling followed by condensing

or yth ng else

Question Number


4 (d)(ii)

Mecompare with Data Book value (101.7 oC) (Pu ORBoils at boiling temperature of liquid/ 101.7 o small temperature range/ boils at one part OR Collect the product at 101.7 oC/ between 100 and 103 oC

1 asure boiling temperature of liquid {and

re if it agrees)}

C / boils over a very icular temperature

6CH07_01 1006

Further copies of this publication are available from Edexcel Publications, Adamsway, Mansfield, Notts, NG18 4FN Telephone 01623 467467 Fax 01623 450481 Email [email protected] Code US023643 Summer 2010 For more information on Edexcel qualifications, please visit www.edexcel.com/quals Edexcel Limited. Registered in England and Wales no.4496750 Registered Office: One90 High Holborn, London, WC1V 7BH

6CH07_01 1006


June 2010

GCE







Summer 2010

Publications Code UA023636



Correct Answer Mark

1 (a) D 1 Question Number

Correct Answer Mark

1 (b) D 1 Question Number

Correct Answer Mark

1 (c) A 1 Question Number

Correct Answer Mark


Correct Answer Mark


Correct Answer Mark


Correct Answer Mark


Correct Answer Mark


Correct Answer Mark

7 (a) C 1 Question Number

Correct Answer Mark

7 (b) B 1 Question Number

Correct Answer Mark

7 (c) D 1 Question Number

Correct Answer Mark

8 B 1

Question Number

Correct Answer Mark


Correct Answer Mark


Correct Answer Mark


Correct Answer Mark


Correct Answer Mark


Correct Answer Mark


Correct Answer Mark


Correct Answer Mark

16 A 1



17 (a)(i)

5.7 x 10 –5 /5.71 x 10 –5 /5.714x 10 –5 /0.000057 IGNORE SF except 1 (ie don’t accept 6 x 10 –5)

1

Question Number


17 (a)(ii)

C4H9Br: first order / 1 (1) (going from first to second experiment) rate doubles when concentration / number of moles doubles (and [OH—] constant )/ rate and concentration increase in proportion (1) ALLOW ‘time halves’ instead of ‘rate doubles’ OH— : zero order / 0 and (going from second to third expt) as increase in concentration does not affect rate (and [C4H9Br] constant ) (1) ALLOW ‘doubling in concentration of OH—

instead of ‘increase in concentration’ ALLOW time increases by the same factor as increase in hydroxide concentration (5/3) May refer to experiment number rather than concentrations

3

Question Number


17 (a)(iii)

Rate = k[C4H9Br] OR Rate = k[C4H9Br]1[OH—]0

ALLOW k in lower or upper case

Rate equation must be consistent with orders in (a)(ii) If no order is given for hydroxide in (ii) mark cannot be given

1

Question Number


17 (a)(iv)

k= 2.9 x 10-5 0.017 = 1.7 x 10-3 / 1.71 x 10-3 / 1.706 x 10-3 s-1

ALLOW k=1.68 x 10-3

(value obtained from experiment 2 or 3) value of k (1) units (1) stand alone mark ALLOW TE from (a)(iii) IGNORE SF except 1 Rate = k[C4H9Br]2 gives k= 0.10036 dm3 mol-1s-1

Rate = k[C4H9Br][OH-] gives k= 1.42 dm3 mol-1s-1

ALLOW k=1.39 dm3 mol-1s-1

(value obtained from experiment 2 or 3) Rate = k[C4H9Br][OH-]2 gives k= 1184.6 dm6 mol-2s-1

Rate = k[C4H9Br]2[OH-] gives k= 83.62 dm6 mol-2s-1

2

Question Number


17(b)

[OH—] is (in chemical equation but) not in rate equation / not in rate determining step (so is in a step other than rate determining step) OR Only C4H9Br is in rate equation / rate determining step (so OH— is in a step other than rate determining step)

1

Question Number

Acceptable Answers Mark

17 (c)

First mark Choice of bromoalkane must be consistent with rate equation in (a)(iii). If [OH—] is not in rate equation, secondary/tertiary bromoalkane. If [OH—] is in rate equation, primary/secondary bromoalkane. (1) Second and third marks Either SN1 or SN2 mechanism can score 2 marks regardless of choice of bromoalkane.

Lone pairs not required Curly arrow from C-Br bond to Br (making Br—) (1) Curly arrow from anywhere on OH— / HO— to C+ in correct intermediate (making alcohol) (1) OR

Both curly arrows from OH— and from C-Br bond to Br (may both be shown at start) (1) Transition state including minus charge (and product) (1) Do not penalise if C2H5 shown instead of C3H7. Bonds in transition state can be dotted. Do not penalise the missing H atoms in alkyl groups in mechanism.

3

Question Number


17 (d) QWC

(Primary and tertiary) carbocation intermediates have different stabilities (1) as (inductive effects of) alkyl groups stabilise tertiary carbocation (1) OR Steric hindrance differs for attack on primary and tertiary carbon (in the molecule) / less space available for attack by OH— on tertiary carbon / more space for attack by OH— on primary carbon (1) as bulky / three alkyl groups obstruct attack (1)

“Tertiary bromoalkanes react by SN1” without further explanation carbocation intermediates have different reactivity steric hindrance in carbocation

2

Question Number


18 (a)(i)

(Acid) hydrolysis

substitution

1

Question Number


18 (a)(ii)

K2Cr2O7 / Na2Cr2O7 / Cr2O7

2— Potassium dichromate((VI)) / sodium dichromate((VI)) / dichromate((VI)) ions ALLOW manganate((VII)) ions, etc

Just “dichromate” chromates Correct formula with wrong name and vice versa Incorrect oxidation number

1

Question Number


18 (a)(iii)

Lithium tetrahydridoaluminate/ lithium aluminium hydride/ LiAlH4 (in dry ether)

Just [H—]

1

Question Number


18 (a)(iv)

Methyl butanoate (1) CH3CH2CH2COOH + CH3OH → CH3CH2CH2COOCH3 + H2O (1)

ALLOW ⇌ IGNORE state symbols even if wrong

Methyl butoate

2

Question Number


18 (a)(v)

CH3 CH2 CH2 CO

Cl Don’t penalise undisplayed methyl groups as here. COCl must be displayed as above.

C3H7 for CH3CH2CH2

1

Question Number


18 (b)(i)

Nitrogen inert / unreactive / less reactive (than oxygen) OR Oxygen might react with chemicals going through column / sample might oxidise

1

Question Number


18 (b)(ii)

Solubility (in liquid / stationary phase) OR Interaction with liquid / stationary phase OR Interaction between mobile and stationary phase OR Attraction for liquid / stationary phase OR Strength of (named) intermolecular forces OR Adsorption on liquid / stationary phase OR Absorption on liquid / stationary phase

Size of molecule / molar mass Polarity, unless with explanation Boiling point / volatility Viscosity Attraction for carrier gas Just a named intermolecular force Just ‘retention time’ Density

1

Question Number


18 (c)(i)

O

H

CH3

C CH2

O

C O

H

CH3

C CH2

O

C

OR

CH3

H

CH2

O

C O C

H

CH3

CH2 C

O

OC

Ester link including C=O (1) Rest of polymer with oxygens at end correct (1) All H atoms must be shown. PENALISE lack of displayed C=O once only ACCEPT Without brackets around formula but bonds at end should be shown More than two correct units IGNORE n after brackets

2

Question Number


18 (c)(ii)

Hydrolysis OR Splits / breaks ester link OR polymer breaks down to monomers OR equation showing hydrolysis

Just ‘breaks polymer down’

1

Question Number


19 (a)(i)

(Kp =) pCH3CO2H pCH3OH (x) pCO Partial pressure symbol can be shown in various ways, eg pp, pCO, (CO)p, etc ALLOW p in upper or lower case, round brackets IGNORE units

[ ] State symbols given as (l) + in bottom line

1

Question Number


19 (a)(ii)

P CH3OH = 4.9 (atm) (1) P CO = 4.9 (atm) (1) 1 mark for recognition that pressures are equal IGNORE units

2

Question Number


19 (a)(iii)

Kp = ((22.2)/(4.9)2) = 0.925 (1) atm—1 (1) stand alone mark but must match expression used in (a)(iii) OR 9.25 x 104 Pa—1 / 92.5 kPa—1 (2) ALLOW TE from (a)(i) if inverted and/or (a)(ii)

Answers to other than 3 significant figures

2

Question Number


19 (b)(i)

CH3OH: 3.2 CO : 3.2 (1) for both values CH3CO2H: 46.8 (1) ALLOW TE for moles of ethanoic acid based on numbers of methanol and carbon monoxide used, as long as moles of methanol and carbon monoxide are equal and moles ethanoic acid + moles methanol = 50

2

Question Number


19 (b)(ii)

46.8 x 32 = 28.2 / 28.1504 (atm) 53.2 IGNORE sf except 1 Value = 28.16 if mol fraction rounded ALLOW TE from (b)(i)

28.1 46.8 x 32 = 50 29.95 (atm)

1

Question Number


19 (b)(iii)

exothermic as yield / pp of ethanoic acid / conversion of reactants/ Kp is higher at lower temperature / as equilibrium moves (right) at lower temperature ALLOW if partial pressure of ethanoic acid < 22.2 atm in (b)(ii), endothermic as yield / pp of ethanoic acid / conversion of reactants/ Kp is lower at lower temperature

1

Question Number


19 (c)(i)

No effect and other concentrations change to keep Kp constant / Kp is only affected by temperature/ as equilibrium moves (right) to keep Kp constant / change in pressure does not change Kp

As Kp is a constant

1

Question Number


19 (c)(ii)

Yield increased to restore fraction / quotient / partial pressure ratio back to Kp

ALLOW (equilibrium moves) to use up the methanol /answers based on entropy or Le Chatelier Correct prediction in (c)(i) and (c)(ii) with inadequate explanations scores 1 mark in (c)(ii)

Just ‘equilibrium moves to the right’

1

Question Number


19 (d)

Mark independently Reaction can occur at lower temperature / has lower activation energy / requires less energy (1) less fuel needed / fewer emissions (from fuels) / fewer raw materials needed / less natural resources used (1) OR Enables use of an alternative process with higher atom economy (1) fewer raw materials needed / less natural resources used (1)

Answer based on car exhaust emissions

2

Question Number


20 (a)(i)

Correct answer with or without working scores 2 marks [H+] = (1 .00 x 10—14/ 0.250) = 4 x 10—14 (1) pH = (13.39794 =) 13.4 (1) OR pOH = -log 0.250 = 0.602 (1) pH = (13.39794 =)13.4 (1) ALLOW TE in second mark if error in [H+] calculation gives pH more than 7 3 or more sf IGNORE rounding errors e.g. accept 13.39

2

Question Number


20 (a)(ii)

(Ka =) [CH3COO—][H+] (1) [CH3COOH] ALLOW H30+ instead of H+

[A—][H+] if key to symbols given [HA] IGNORE state symbols

[H+]2 [CH3COOH]

1

Question Number


20 (a)(iii)

Correct answer with or without working scores 2 marks 1.7 x 10—5 = [H+]2 (1) 0.125 [H+] = 1.46 x 10—3

pH = 2.84/2.8 (1) no TE from an incorrect [H+]

2

Question Number


20 (a)(iv)

pH = 4.8 / 4.77 (1) pH = pKa / [H+] = Ka (when acid is half neutralized) (1)

H+ = Ka

2

Question Number


20 (a)(v)

Sigmoid curve starting between pH 2 and 4 (2.8), ending between pH 12 and 14 inclusive (1) with steep rise (may be vertical or gently sloping) of between 3 – 7 units between pH 6 and 12. Sloping section should not extend over more than 5cm3. (1) When 12.5 cm3, NaOH added. (1) ALLOW tolerance for grid Reverse curves lose first mark

3

Question Number


20 (a)(vi)

First mark Thymolphthalein more suitable as it changes (from colourless to blue) in steep region of titration (pH 8.3 to 10.6)/ at the equivalence point / at the end point OR thymolphthalein has pH range in steep region of titration (1) Second mark Methyl yellow changes (from red to yellow at pH 2.9 to 4) before equivalence point / before the end point / doesn’t change in steep section OR Methyl yellow has pH range before / outside steep region of titration (1) ALLOW ‘Thymolphthalein more suitable as it changes at the equivalence point but methyl yellow does not.’ This scores 2 marks OR First mark pKin ± 1 must lie within vertical region on titration curve (1) Second mark hence thymolphthalein is suitable and methyl yellow is not (1)

2

Question Number


20 (b)

Sodium ethanoate/ CH3COONa Potassium ethanoate / CH3COOK ALLOW other cations as alternatives to sodium

Use of sodium hydroxide (because it’s in food)

1

Question Number


21 (a)(i)

∆So

system = 109.2 + (6x 69.9) – 343 (1) =(+)185.6(J mol–1 K-1) / (+)186 (J mol–1 K-1) (1) OR (+)0.186 (kJ mol–1 K-1) (2) IGNORE units even if incorrect correct answer with no working scores 2 Value using 1 for H2O = -163.9 scores 1 Use of value for H2O(g) (188.7) gives 898.4 (J mol–1 K-1) (1) correct value with incorrect sign scores 1

185

2

Question Number


21 (a)(ii)

Yes as (solid and) liquid forms (from solid) / number of moles increases OR If ∆So

system in (i) is negative the sign is not as expected as liquid forms from solid / number of moles increases

Disorder increases, with no ref to liquid or number of moles

1

Question Number


21 (a)(iii)

First mark ∆So

surroundings = –88.1 x (1000 ) (1) 298 Second mark = -295.6375 = -295.6 J mol-1 K-1 (1) correct units must be shown but order not important OR -0.2956 kJ mol-1 K-1 (1) correct units must be shown but order not important correct answer with or without working and correct units scores (2) ignore sf except 1 correct value with positive sign scores 1

2

Question Number


21 (a)(iv)

(185.6–295.6) = -110 (J mol-1 K-1 ) OR -0.110 ( kJ mol-1 K-1) could use 186 or 296 etc TE from (a)(i) and (iii) (+)602.8 (J mol-1 K-1 ) if value for 6H2O(g) was used in (a) (i) -459.5 (J mol-1 K-1 ) if value for one H2O was used in (a) (i)

Answers where values in J are added to kJ

1

Question Number


21 (a)(v)

Decomposition (at 298 K) will not occur as ∆So

total is negative / Reactions are only spontaneous if total entropy change is positive / decomposition not thermodynamically feasible / (hydrated cobalt chloride) is thermodynamically stable TE if answer to (a)(iv) is positive showing decomposition (at 298 K) may occur OR Positive total entropy change doesn’t indicate rate of reaction

1

Question Number


21 (b)(i)

First mark Thermometer (1) Second mark (dependent on first) depends on choosing thermometer as temperature change is small / (%) error in balance smaller than for temperature reading (%) error in pipette smaller than for temperature reading (can be shown by calculation) / as scale with greater degree of precision needed / scale with more graduations needed (1) IGNORE any references to ‘accurate thermometer’

2

Question Number


21 (b)(ii)

Use more cobalt chloride / less water (1) To increase temperature rise (1) Mark independently

Just ‘use more reactants’ Use more cobalt chloride and more water repeat expt add a lid or extra insulation to beaker use distilled water

2

Question Number


21 (c)(i) QWC

Radius (of cation) increases (down group) OR any two values of radius: Mg 2+ = 0.072, Ca 2+ = 0.100 / Sr 2+ = 0.113 (nm) data may be shown beside the table (1) Radius Co2+ = 0.065 nm OR Co2+ radius smaller than other ions (1) Data on EITHER Co2+ OR data showing increase in radius down Group II required for BOTH of first two marks Force of attraction between ions decreases (as radius of ions increases) / charge density of ions decreases / negative ion can come closer to nucleus of positive ion (1) ALLOW “weaker ionic bonds” Predict lattice energy –2550 to -2900 (kJ mol-1) (1) IGNORE sign

Atomic radii unless ionic radii also given Radius of cobalt chloride Polarising power decreases

4

Question Number


21 (c)(ii) QWC

First mark Reference to enthalpy of hydration (may be in equation ∆Hsolution = -LE + ∆Hhydration) (1) Second mark Solubility depends on relative size of lattice energy and enthalpy of hydration (1) Third mark EITHER Solubility more likely if ∆Hsolution is negative OR (If ∆Hsolution is positive,) may / will dissolve if ∆Stotal is positive ACCEPT solvation instead of hydration

3

Question Number


21 (d) QWC

First mark Third ionization energy high(er) for Mg / Mg = 7733 kJ mol–1, (third ionization energy for Co = 3232 kJ mol-1) (1) Second mark (Third ionization energy for Mg is high) because the electron is being removed from an inner shell / full shell / 2p level / 2p orbital (1) OR Not compensated by higher lattice energy for Mg3+ (and so ∆Hformation of MgCl3 would be highly endothermic) (1)

2


June 2010

GCE



2 6CH05_01 1006



For further information, please call our GCE line on 0844 576 0025, our GCSE team on 0844 576 0027, or visit our website at www.edexcel.com


Summer 2010



3 6CH05_01 1006

Section A Question Number

Correct Answer

Mark


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Correct Answer

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Correct Answer

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Correct Answer

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Correct Answer

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Correct Answer

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Correct Answer

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12 D 1

4 6CH05_01 1006

Question Number

Correct Answer

Mark


Correct Answer

Mark


Correct Answer

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Correct Answer

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Correct Answer

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Correct Answer

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Correct Answer

Mark

20 D 1

5 6CH05_01 1006



21 (a)(i) Copper: 0 to +2/2+/2+/II/2 (1)

Nitrogen: +5/5+/5+/V/5 to +4/4+/4+/IV/4 (1)

2

Question Number


21(a)(ii) Cu → Cu2+ + 2e(−

) OR

Cu − 2e(−

) → Cu2+ (1) Cu[(H2O)6]

2+ OK if 6 waters shown on l.h.s.

NO3− + 2H+ + e(

−) → NO2 + H2O

OR

2NO3− + 4H+ + 2e(

−) → 2NO2 + 2H2O (1)

OR

2NO3− + 4H+ + 2e(

−) → N2O4 + 2H2O (1)

Ignore the full equation if it is given as well Allow equations written as reverse of above Ignore state symbols even if wrong

Allow ⇌ for →

2

Question Number


21(a)(iii) (electrode potential) values are for standard conditions (1) nitric acid is concentrated / not 1 mol dm-3 / not 1 M (1) Allow temperature not stated for second mark

NO3− are not 1 mol dm-3

Any reference to loss of NO2

2

6 6CH05_01 1006

Question Number


21(b)(i) initially a (pale/light) blue precipitate (1) Allow blue solid Ignore white precipitate (re-dissolves in excess to form) a (deep) blue solution (1) Stand alone mark Accept any shade of blue except greenish-blue

Any colour (other than blue) precipitate in blue solution

2

Question Number


21(b)(ii) Cu2+(aq) + 2OH−(aq) → Cu(OH)2(s) (1)

Zn2+(aq) + 2OH−(aq) → Zn(OH)2(s) (1)

Zn(OH)2(s) + 2OH−(aq) → Zn(OH)42−(aq) (1)

If two previous equations combined correctly

then (1) only : Zn2+ + 4OH− → Zn(OH)42−

Allow

Zn(OH)2(s) + 2OH−(aq) → ZnO22-(aq)+ 2H2O(l)

OR

Zn(OH)2(s) + 4OH−(aq) → Zn(OH)64−(aq)

OR equivalent non-ionic equations, including those with Zn2+ + 2NaOH etc OR Correct balanced equations starting with hexaqua or tetraqua cations ALLOW the hydroxides to be shown as e.g. Zn(OH)2(H2O)4 (s) provided that the whole equation balances. Penalise missing /incorrect state symbols on product once only. Ignore other state symbols

3

7 6CH05_01 1006

Question Number


21(b)(iii) QWC

First 2 marks: zinc hydroxide/oxide amphoteric because it reacts with alkali (to give a solution of a zincate) (1) and reacts with acid (to give a salt) (1) zinc hydroxide is / acts as both an acid and an alkali – scores (1) only Third mark: hexaquazinc or hydrated zinc ions exchanged water for ammonia or other named ligand (1) OR

Zn(H2O)6 2+ + 4NH3 → etc (1)

Allow any number of ammonias from 1 to 6 Allow balanced equations, ionic or full. Ligand exchange reaction must start with a complex ion Note: If zinc mentioned initially but equation refers to a correct compound then credit should be given If equations wrong but words are correct then ignore equations

Reference to zinc ions or zinc metal Do not allow deprotonation

3

8 6CH05_01 1006

Question Number


21(c)(i) I2 + 2S2O32− → 2I− + S4O6

2− Ignore state symbols even if wrong.

Non-ionic equation. 1

Question Number


21(c)(ii) QWC

Amount thiosulphate = 0.0331 dm3 x 0.1 mol dm —3 = 0.00331 mol (1) = amount of copper(II) ions in 25 cm3 portion (1)

∴ ∴ ∴ ∴ amount Cu = 10 x 0.00331= 0.0331 mol in total (1)

∴∴∴∴ mass Cu = 0.0331 mol x 63.5 g mol-1 (1) = 2.102 g

∴∴∴∴ % copper = (2.102 x 100)÷ 3.00 (1) = 70.1% (1) to 3 s.f. only Mark consequentially but if % > 100 then (-1) If equation in (i) is incorrect but used correctly in part (ii) then all marks can be scored unless answer > 100% Correct answer can score 6 marks irrespective of the stoichiometry of the equation in (c)(i) If candidates uses 64 for molar mass of Cu final answer will be 70.6; scores max of 5

70.06 or 70.0

6

Question Number


21(c)(iii) some reagent used to fill the jet (which does not react with the iodine solution) and so the titre is too high (1) and hence the percentage value would be too high (1) Allow only if the titre is said to be high If the titre is thought to be too low then allow percentage value too low for 2nd mark (1)

2

9 6CH05_01 1006

Question Number


22(a)(i) H2SO4 + HNO3 → NO2+ + H2O + HSO4

- OR

H2SO4 + HNO3 → H2NO3+ + HSO4

-

H2NO3+

→ NO2+ + H2O

Both needed OR

(1) Ignore state symbols even if wrong

arrow showing attack on the nitronium ion with arrow going to N atom, or into the C – N gap (1) Arrow must start at or inside ring Ignore position of + charge structure of the intermediate showing reasonable delocalisation (over at least 3 carbon atoms) (1) arrow from the bond showing the loss of H+ from the intermediate. Removal by hydrogen sulphate ion preferable but not essential (1) Kekulé structures score full marks If the electrophile is incorrect then the intermediate structure mark is lost

Delocalisation mustn’t go over C where NO2

+ is attached

4

10 6CH05_01 1006

Question Number


22(a)(ii) QWC

First mark: (lone pair of) electrons on the oxygen atom or on the OH group is delocalised / incorporated into the ring (1) OR the OH group is electron donating (1) Second mark: so the ring in phenol is more negative / has increased electron density / ring is more nucleophilic / hence more susceptible to electrophilic attack (1) OR the OH group activates the ring (1) Second mark stand alone

Reject hydroxide for first mark only Nucleophilic attack on the ring ‘Makes it more reactive’ on its own

2

Question Number


22(a)(iii) tin (1) and concentrated hydrochloric acid (1) Formulae acceptable. If NaOH is added after HCl then ignore; if implication that HCI and NaOH are added together then second mark is lost OR iron (1) and concentrated hydrochloric acid (1) 2nd mark conditional on a metal OR hydrogen (1) and platinum / palladium catalyst (1)

lithium aluminium hydride sodium borohydride Nickel Raney Nickel

2

11 6CH05_01 1006

Question Number


22(a)(iv) ethanoyl chloride OR acetyl chloride OR CH3COCl OR equivalent displayed formula OR ethanoic anhydride OR acetic anhydride OR (CH3CO)2O OR equivalent displayed formula Right name but wrong formula does not score Ignore minor spelling errors if the formula is correct

1

Question Number


22(b) QWC

First mark: steam is passed into the mixture OR water is added and mixture boiled or distilled or heated (1) Second mark: and the 2-nitrophenol / product vapour distilled off with the water (and condensed) (1) Advantage: The 2-nitrophenol / product distils at a lower temperature / prevents decomposition(1) Stand alone

Passed over; anything that implies external heating with a steam bath or water bath any implication of fractional distillation any suggestion that separation based on differing boiling temperature water-soluble

3

Question Number


22(c) Read the whole answer to get the sense The (ring) hydrogen atoms are on carbon atoms which have one / a hydrogen on an adjacent carbon atom, so are doublets (1) All the other hydrogen atoms have no adjacent hydrogen (bearing carbon) atoms, so are singlets (1)

nearby

2

12 6CH05_01 1006

Question Number


23(a)(i) Any TWO of: complex ions / complexes (1) coloured ions / compounds / solutions (1) catalytic properties (1) paramagnetic (1) Allow coloured complexes (2) coloured complex compound (1) If a list appears with 1 or 2 correct properties followed by properties related to the element, then (1) mark only Ignore ‘partially filled d-orbitals’

complex compounds

2

Question Number


23(a)(ii)

OH2

OH2

VOH2

OH2

H2O

H2O

3+

ignore absence of charge clearly octahedral (ignore bonds to the H in H2O) (1) but allow some latitude in the symbols used to show the 3D structure. Wedges do not have to be exact – if used they are enough to show 3D if the axial bonds are lines The word ‘octahedral’ does not salvage a poor drawing dative (covalent) / coordinate (bond) (1) not just shown by an arrow lone pair (of electrons on the oxygen) (1) can be shown on the diagram

3

13 6CH05_01 1006

Question Number


23(b)(i) (+) 0.34 (V) OR (+) 0,34 V sign not needed

1

Question Number


23(b)(ii) QWC

(simultaneous) oxidation and reduction (1) Allow redox of a species / substance / reactant / compound / chemical / element (1)

2

Question Number


23(b)(iii) − 0.66(V) (1) Allow TE from (b)(i) reaction not feasible since the potential is negative (2nd mark is for an answer consistent with sign of Eo ) (1)

2

14 6CH05_01 1006

Section C Question Number


24(a)

Circles that encompass two atoms

1

Question Number


24(b) First mark: Recognition that paracetamol is not chiral / has no enantiomers / does not have optical isomers (1) Second and third marks: Any two of: there is no racemisation so the product will not be a mixture (1) no need to separate (the enantiomers) (1) do not have to discard an unwanted enantiomer / atom economy is higher (1) OR converse arguments starting from (-)-carvone.

Is not optically active

3

15 6CH05_01 1006

Question Number


24(c) (C=C): add bromine (water) (1) decolourises (1) OR KMnO4 (1)

purple → brown / colourless (1) (C=O): add 2,4-dnp / 2,4-dinitrophenylhydrazine/ Brady’s reagent (1) orange or yellow or orange-red or red ppt (1) Ignore a negative Fehling’s / Tollens’ test If a positive Fehling’s / Tollens’ is given in addition to 2,4 DNP then third and fourth marks are lost Observation dependent on test

1,4-dnp

4

16 6CH05_01 1006

Question Number


24(d)(i) amount of carvone = (4.5 ÷ 150) mol = 0.03 mol (1)

amount of hydrogen = (1.44 ÷ 24) mol = 0.06 mol (allow 1st mark for either of the mole calculations) so two double bonds are reduced (1) OR 2 moles H2 : (1 mol carvone) OR 4 mole H : (1 mol carvone) If hydrogen is used it must be clear whether they are atoms or molecules This mark can be salvaged if the structure is correct and both double bonds are reduced

(1) stand alone Accept displayed formula if completely correct

Any structure that shows reduction of the C=O bond

3

17 6CH05_01 1006

Question Number


24(d)(ii) (a ketone/C=O) absorption / peak / trough / within the range 1680 – 1700 (cm-1) (1) Ignore units will be seen in carvone but not in limonene / the reduction product (1) omission of the value for the absorption loses first mark only

1720 - 1740 cm-1 2

Question Number


24(e)(i)

for both double bonds having HBr added (1) ignore added hydrogens for correct orientation in exocyclic double bond (1) stand alone

Any structure retaining C=C bonds

2

18 6CH05_01 1006

Question Number


24(e)(ii) HBr can be eliminated using a hydrogen from the carbon on either side of the bromine (1) which would then give a double bond in a different position from that in carvone (1) this second mark can be answered using a skeletal / structural formula (below)

Reference to substitution

2

19 6CH05_01 1006

Question Number


24(f)(i) QWC

Using an SN1mechanism: selection of a chiral starting material (1) curly arrow from C-X bond to X (1) and intermediate carbocation (1) curly arrow from nucleophile (can come from negative charge) (1) planar intermediate attacked from either side to give a racemic mixture OR intermediate equally attacked from either side to give a racemic mixture (1) Using an SN2 mechanism: selection of a chiral starting material (1) curly arrow from nucleophile (can come from negative charge) (1) curly arrow from C-X bond to X (1) to give correct transition state (1) attack from opposite side to C-X bond gives inverted product can be shown on a diagram (1) Using nucleophilic addition to C= O: Selection of any aldehyde (other than methanal) or any asymmetric ketone (1) Curly arrow from nucleophile (can come from negative charge) to C of C=O and curly arrow from = to O (1) Intermediate (1) Arrow from O– of intermediate to H+ (1) planar molecule attacked from either side to give a racemic mixture OR molecule equally attacked from either side to give a racemic mixture (1)

If H-X used then -1

5

20 6CH05_01 1006

Question Number


24(f)(ii) heterogeneous catalysts can be filtered off OR do not appear in any liquid or gaseous products OR are easy to separate OR are stereospecific OR suited to continuous processes rather than batch processes

greater surface area 1


June 2010

GCE







Summer 2010



6CH08_01 1006 2/14


Question Number

Acceptable Answers

Reject Mark

1 (a) Compound contains a transition metal (ion) / Compound contains chromate((VI)) / CrO4

2―

Allow any yellow salt (name or correct formula) Allow ‘transition element / metal (present)’ Ignore d block Ignore any cation included

Dichromate oxides Cr6+

1

Question Number

Acceptable Answers

Reject Mark

1 (b) Sodium (ions) present / Na+ Na Anion

1

Question Number

Acceptable Answers

Reject Mark

1 (c) dichromate(VI) / dichromate / Cr2O72― /

2CrO42― + 2H+ Cr2O7

2― + H2O Ignore references to the other ions present (Na+, 2H+, SO4

2―) No TE

Cr(VI) Cr6+

1

Question Number

Acceptable Answers

Reject Mark

1 (d) Cr2O72― / dichromate((VI))(allow Cr(VI)) is

reduced (by the ethanol) / the ethanol is oxidized (by Cr2O7

2― (allow Cr(VI))) / the ethanol forms ethanal / ethanoic acid (1) Cr3+ / chromium(III) / Cr(III) formed (1) Allow fully balanced ionic half-equation (2) No TE

Cr6+ 2

Question Number

Acceptable Answers

Reject Mark

1 (e) Precipitate chromium(III) hydroxide / Cr(OH)3 / Cr(OH)3(H2O)3 (1) Solution chromate(III) / tetrahydroxochromate(III) / hexahydroxochromate(III) / Cr(OH)4

― / Cr(OH)6

3― (1) Allow hydrated forms / CrO2

- / CrO33-

Allow chromium hydroxide if Cr3+

Allow Cr(OH)52-

Ignore number of water ligands

Cr2O3

Cr3+

Cr3+(aq)

2

6CH08_01 1006 3/14

Question Number

Acceptable Answers

Reject Mark

1 (f) Pale blue ions Cr2+ / Cr(H2O)n

2+ chromium(II) / Cr(II) (1) Role of zinc Reducing agent / Reduces / Reduction / providing electrons (1)

Cu2+

2

Question Number

Acceptable Answers

Reject Mark

1 (g) Green ions Cr3+/ chromium(III) / Cr(III) (1) Explanation The Cr2+ / chromium(II) / Cr(II) (allow ‘blue species’) is oxidized by (oxygen in) the air (1) Ignore water ligands Allow oxidized by oxygen

2

6CH08_01 1006 4/14

Question Number

Acceptable Answers

Reject Mark

2 (a)(i) OH / hydroxyl group present OR Compound could be an alcohol / OH or a carboxylic acid / COOH

Hydroxide / OH—

alcohol / carboxylic acid alone

1

Question Number

Acceptable Answers

Reject Mark

2 (a)(ii) P is (an alcohol) not a carboxylic acid Allow P is an alcohol if in (a)(i) P is described as “an alcohol or a carboxylic acid” Ignore primary and/or secondary

Alcohol without three carbons

1

Question Number

Acceptable Answers

Reject Mark

2 (a)(iii) P contains the group CH3CH(OH)― / P is a 2-ol Allow P is propan-2-ol / secondary alcohol

P is a methylketone / ethanol / methyl alcohol

1

Question Number

Acceptable Answers

Reject Mark

2 (a)(iv) P is propan-2-ol / CH3CH(OH)CH3

OH

or H3C

C

CH3

HOH

No TE on earlier incorrect answer

Molecular formula only

1

Question Number

Acceptable Answers

Reject Mark

2 (a)(v) Peak is caused by (CH3CHOH )+ / C2H5O+ / CH2CH2OH+ (1) stand alone (molecular ion (of propan-2-ol) will fragment by) loss of one CH3 group / CH3

● / CH3 radical (1) Second mark can be awarded only if ion has relative mass of 45 Allow the molecule fragments (instead of molecular ion) Allow equations with charge not balanced

Formula without positive charge Breaking C-C bond on its own CH3

+

2

6CH08_01 1006 5/14

Question Number

Acceptable Answers

Reject Mark

2 (b)(i) Hydrogen chloride / HCl Allow hydrochloric acid / HCl(aq)

HCl and POCl3 1

Question Number

Acceptable Answers

Reject Mark

2 (b)(ii) Q is a carboxylic acid / COOH /

C

OH

O

Allow CO2H / propanoic acid / carboxylic alone

Carboxylate 1

Question Number

Acceptable Answers

Reject Mark

2 (b)(iii) Q is propanoic acid / CH3CH2COOH / CH3CH2CO2H / C2H5COOH

OH

O

H3C

H2C

C

OH

O

1

6CH08_01 1006 6/14

Question Number

Acceptable Answers

Reject Mark

3 (a) Fe + 2H+ Fe2+ + H2

Fe + 2H3O+ Fe2+ + H2 + H2O Ignore state symbols and correct sulfate formulae

Non ionic equation

1

Question Number

Acceptable Answers

Reject Mark

3 (b) Effervescence / fizzing stopped/no more bubbles of gas given off Allow no more gas given off

All iron dissolved Steamy fumes (for gas)

1

Question Number

Acceptable Answers

Mark

3 (c)(i)

Ignore omission of trailing zeros

Titre / cm3

23.35 23.05 22.70 23.00 22.95 (1)

Titres used ( or

)

(1)

2

Question Number

Acceptable Answers

Reject Mark

3 (c)(ii) ((23.05 + 23.00 + 22.95) ÷ 3) = 23.00 (cm3) Allow 23 / 23.0 TE from (c)(i)

1

6CH08_01 1006 7/14

Question Number

Acceptable Answers

Reject Mark

3 (c)(iii) (A) Moles MnO4– (in titre) = 23.00 x10-3 x .022

= 5.06 x 10-4 (1) (B) Moles Fe2+ in 250 cm3 = 10 x 5 x Answer in

(A) (= 0.0253) (1) (C) Mass of Fe = Answer in B x 55.8 (= 0.0253 x

55.8 =1.41 (g)) (1) (D) % iron =100 x answer in C ÷ 1.48 (= 95.4 %)

(1) Ignore SF except 1 SF Ignore correct intermediate rounding of calculated values Allow 56 for Ar of iron (95.7 %) Allow TE from (c)(i) and (ii) Correct answers with no working score full marks

% > 100 %

4

Question Number

Acceptable Answers

Reject Mark

3 (d) Iron(II) ions: Pipette and sulfuric acid: measuring cylinder (1) both needed for the mark An exact volume of iron(II) ion solution is needed but only an approximate volume of /excess sulfuric acid (1) The second mark may be awarded if a burette and measuring cylinder are given Allow any recognisable spelling of pipette, eg pipet

Just pipette more accurate than measuring cylinder

2

6CH08_01 1006 8/14

Question Number

Acceptable Answers

Reject Mark

3 (e) To ensure that the manganate(VII) ions were fully reduced (to manganese(II)) Or To ensure MnO2 is not precipitated Allow Large number of H+ ions required in (titration) equation 8 moles H+ ions required (per mol Fe2+ in titration) To prevent oxidation of Fe2+ by (oxygen in) air or by water To prevent hydrolysis

To ensure complete reaction

1

Question Number

Acceptable Answers

Reject Mark

3 (f) First permanent pink colour Allow (colourless) solution turns pink

Purple to pink Turns purple

1

Question Number

Acceptable Answers

Reject Mark

3 (g) HCl / Cl− will be oxidized (to chlorine) by the manganate(VII) OR HCl / Cl− will react with manganate(VII) to form chlorine (1) So the reaction of the iron(II) ions with manganate(VII) will not be quantitative/titre will be too high (1) Allow permanganate / manganate (for manganate(VII)) Ignore references to toxicity of chlorine

HCl / Cl−

strong reducing agent / oxidised by Fe2+

Just chlorine formed Titration values inaccurate

2

6CH08_01 1006 9/14

Question Number

Acceptable Answers

Reject Mark

4 (a) Amount of phenylamine = 9/93 / 0.0968 (mol) (1) = amount of ethanoic anhydride Mass ethanoic anhydride =102 x 9/93 = 9.87 (g) (1) Ignore SF except 1 SF Correct answer with no working scores full marks Mr values reversed scores max 1 only if a mole calculation is clearly shown

2

Question Number

Acceptable Answers

Reject Mark

4 (b)(i) To ensure that all the phenylamine reacts So ethanoic anhydride is in excess To ensure complete reaction

1

Question Number

Acceptable Answers

Reject Mark

4 (b)(ii) Reaction is exothermic / produces heat Allow reaction is vigorous so that the temperature does not increase (too much) Ignore references to the reaction being violent, dangerous, explosive etc

1

6CH08_01 1006 10/14

Question Number

Acceptable Answers

Reject Mark

4 (b)(iii) Mistake: The condenser water flow is wrong way round so air may be trapped/jacket will not be full of water (1) Allow cooling not so effective / flammable liquid might escape Correction Reverse the flow of water (1) Mistake: Flammable liquids are being heated with a Bunsen/naked flame (1) Correction so the Bunsen burner should be replaced by a hot plate (allow water bath) (1) OR Mistake: Heating with a Bunsen too strong (so glass may crack) (1) Correction Use micro-burner/gauze (1)

4

6CH08_01 1006 11/14

Question Number

Acceptable Answers

Reject Mark

4 (b)(iv)

Funnel (conical allowed) with grid / line / horizontal filter paper (1) Side-arm conical flask (with valve or connection to a pump) (1) Reduced pressure achieved by: Flow of water through the pump/valve/can be shown in diagram (reduces pressure in the flask) (1) Allow using a (vacuum / suction) pump connected to side-arm (connection may be shown in diagram)(1)

3

Question Number

Acceptable Answers

Reject Mark

4 (c) Mass of N-phenylethanamide if 100% yield = 135 x 9/93 (1) = 13.06 g Yield = 100 x 7.49/13.06 = 57.3 % (1) Alternatively Moles phenylamine =9/93 = 0.0968 Moles N-phenylethanamide = 7.49/135 = 0.0555 (1) Yield = 100 x .0555/.0968 = 57.3 % (1) Correct answer with no working scores (2) Ignore sf except 1 sf Yields greater than 100 % score zero

100 x 7.49/9 = 83.2 % (0)

2

6CH08_01 1006 12/14

Question Number

Acceptable Answers

Reject Mark

4 (d) Some of the N-phenylethanamide will remain on the filter paper/will be deposited on the sides of the glassware/in solution (and will not be recovered by filtration)

1

Question Number

Acceptable Answers

Reject Mark

4 (e) The product was not dry / was damp / water (still) present Ignore reference to impurities present

1

6CH08_01 1006 13/14

Further copies of this publication are available from Edexcel Publications, Adamsway, Mansfield, Notts, NG18 4FN Telephone 01623 467467 Fax 01623 450481 Email [email protected] Code UA023646 Summer 2010 For more information on Edexcel qualifications, please visit www.edexcel.com/quals Edexcel Limited. Registered in England and Wales no.4496750 Registered Office: One90 High Holborn, London, WC1V 7BH

6CH08_01 1006 14/14


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