MORPHISTO GmbH Safety Data Sheet€¦ · according to Regulation (EC) No 1907/2006 Safety Data Sheet MORPHISTO GmbH Kaliumpermanganat-Schwefelsäure Revision date: 13.02.2020 Product

according to Regulation (EC) No 1907/2006

Safety Data SheetMORPHISTO GmbH

Kaliumpermanganat-Schwefelsäure

Revision date: 13.02.2020 Product code: 15436.xxxxx Page 1 of 7

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture

laboratory reagent

none

Uses advised against

1.3. Details of the supplier of the safety data sheet

MORPHISTO GmbHCompany name:

Street: Weismüllerstr. 45

Place: D-60314 Frankfurt am Main

Telephone: Telefax:+49 (0) 69 / 400 3019-60 +49 (0) 69 / 400 3019-64

[email protected]:

http://www.morphisto.deInternet:

Poison Information Center Mainz, Germany, Tel: +49(0)6131/192401.4. Emergency telephone

number:

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Regulation (EC) No. 1272/2008

This mixture is not classified as hazardous in accordance with Regulation (EC) No. 1272/2008.

2.2. Label elements

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Hazardous components

QuantityChemical nameCAS No

EC No Index No REACH No

GHS Classification

1 - < 5 %7664-93-9 sulphuric acid ... %

231-639-5 016-020-00-8

Skin Corr. 1A; H314

Full text of H and EUH statements: see section 16.

Further Information

Product does not contain listed SVHC substances > 0,1 % according to Regulation (EC) No. 1907/2006 Article

59 (REACH)

SECTION 4: First aid measures

4.1. Description of first aid measures

In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data

sheet if possible).

General information

Provide fresh air. In case of respiratory tract irritation, consult a physician.

After inhalation

Print date: 13.02.2020GB - ENRevision No: 1,1

mailto:[email protected]

http://http://www.morphisto.de





After contact with skin, wash immediately with: Water and soap. If skin irritation occurs: Get medical

advice/attention.

After contact with skin

In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding eyelids

apart. Subsequently consult an ophthalmologist.

After contact with eyes

Rinse mouth immediately and drink plenty of water. (200-500 ml)

Do NOT induce vomiting. Call a physician immediately.

After ingestion

4.2. Most important symptoms and effects, both acute and delayed

No information available.

4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Carbon dioxide (CO2). Dry extinguishing powder. alcohol resistant foam. Atomized water.

Suitable extinguishing media

High power water jet.

Unsuitable extinguishing media

5.2. Special hazards arising from the substance or mixture

Can be released in case of fire: Carbon monoxide Carbon dioxide (CO2). Sulphur oxides

In case of fire: Wear self-contained breathing apparatus.

5.3. Advice for firefighters

Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.

Additional information

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Wear personal protection equipment. See protective measures under point 7 and 8.

Do not allow to enter into surface water or drains.

Discharge into the environment must be avoided.

6.2. Environmental precautions

Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).

Suitable material for diluting or neutralizing: caustic soda, diluted.

Treat the recovered material as prescribed in the section on waste disposal .

Clear contaminated areas thoroughly.

6.3. Methods and material for containment and cleaning up

See protective measures under point 7 and 8.

6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Avoid contact with skin, eyes and clothes.

Wear suitable protective clothing. ( See section 8. )

Use extractor hood (laboratory).

Advice on safe handling

The product is not: Combustible.

Advice on protection against fire and explosion






Usual measures for fire prevention.

7.2. Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a cool, well-ventilated place. Suitable material for Container: polyethylene.

Glass.

Unsuitable materials for Container: Aluminium. Zinc.

Requirements for storage rooms and vessels

Do not store together with: Explosives. Oxidizing solids. Oxidizing liquids. Infectious substances. Radioactive

substances.

Hints on joint storage

Store small packages in a suitable, robust cabinet. Keep container tightly closed in a cool, well-ventilated place.

Protect against: UV-radiation/sunlight.

Further information on storage conditions

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limits (EH40)

Categoryfibres/mlmg/m³ppmSubstanceCAS No Origin

TWA (8 h)-Sulphuric acid (mist)7664-93-9 0.05 WEL

8.2. Exposure controls

Provide adequate ventilation as well as local exhaustion at critical locations.

@1001.B010017 Use extractor hood (laboratory).

Appropriate engineering controls

Always close containers tightly after the removal of product.

Protective and hygiene measures

Wear safety glasses; chemical goggles (if splashing is possible).

Eye/face protection

In case of prolonged or frequently repeated skin contact:

Pull-over gloves of rubber. EN ISO 374

Suitable material:

(penetration time (maximum wearing period): >= 8 h)

Butyl rubber. (0,5 mm)

Protective clothing should be selected, depending on concentration and quantity of the hazardous substance.

The chemical resistance of the products should be discussed with suppliers.

Hand protection

No special measures are necessary.

Skin protection

With correct and proper use, and under normal conditions, breathing protection is not required.

Respiratory protection necessary at:

exceeding exposure limit values

Suitable respiratory protective equipment: gas filtering equipment (EN 141). Typ: E

Respiratory protection

No special measures are necessary.

Environmental exposure controls






dark violet

liquidPhysical state:

Colour:

9.1. Information on basic physical and chemical properties

SECTION 9: Physical and chemical properties

stingingOdour:

pH-Value (at 20 °C): not determined

Changes in the physical state

>100 °CFlash point:

none

Explosive properties

Lower explosion limits:

Upper explosion limits:

none

Oxidizing properties

Density (at 20 °C): ~1,03 g/cm³

Water solubility: miscible.

SECTION 10: Stability and reactivity

10.1. Reactivity


10.2. Chemical stability

Stable under normal storage and handling conditions.

10.3. Possibility of hazardous reactions


heat.

10.4. Conditions to avoid

metals in powder form. strong alkalis. Reducing agents, strong.

10.5. Incompatible materials


10.6. Hazardous decomposition products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Toxicocinetics, metabolism and distribution


Acute toxicity

Based on available data, the classification criteria are not met.







Chemical nameCAS No

SourceSpeciesDoseExposure route Method

7664-93-9 sulphuric acid ... %

RatLD50 2140

mg/kgECHA Dossieroral

inhalation (4 h) aerosol LC50 (0,85)

mg/l

Mouse. ECHA Dossier


Irritant effect on the eye: slightly irritant but not relevant for classification.

Irritant effect on the skin: slightly irritant but not relevant for classification.

Irritation and corrosivity

Sensitising effects



Carcinogenic/mutagenic/toxic effects for reproduction



STOT-single exposure




STOT-repeated exposure

Aspiration hazard



Specific effects in experiment on an animal

SECTION 12: Ecological information

12.1. Toxicity


CAS No Chemical name

[h] | [d]Aquatic toxicity Dose SourceSpecies Method

sulphuric acid ... %7664-93-9

Acute fish toxicity 96 h ECHA DossierLC50 16 mg/l Lepomis macrochirus

Acute algae toxicity 72 h ECHA DossierErC50 >100

mg/l

Desmodesmus

subspicatus

Acute crustacea toxicity 48 h ECHA DossierEC50 >100

mg/l

Daphnia magna

12.2. Persistence and degradability

The methods for determining the biological degradability are not applicable to inorganic substances.

12.3. Bioaccumulative potential



12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment


SECTION 13: Disposal considerations






13.1. Waste treatment methods

Disposal recommendations

Contents / container can be disposed of in accordance with national regulations. Product is acid. The product

needs to apply neutralizing agents before draining to wastewater treatment plants.

List of Wastes Code - residues/unused products

160509 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and

discarded chemicals; discarded chemicals other than those mentioned in 16 05 06, 16 05 07 or 16

05 08

List of Wastes Code - used product

WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and

discarded chemicals; discarded chemicals other than those mentioned in 16 05 06, 16 05 07 or 16

05 08

160509

List of Wastes Code - contaminated packaging

WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND

PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED; absorbents, filter materials, wiping

cloths and protective clothing; absorbents, filter materials, wiping cloths and protective clothing other

than those mentioned in 15 02 02

150203

Non-contaminated packages may be recycled.

Contaminated packaging

SECTION 14: Transport information

Land transport (ADR/RID)

14.1. UN number: No dangerous good in sense of these transport regulations.

Inland waterways transport (ADN)


Marine transport (IMDG)


Air transport (ICAO-TI/IATA-DGR)


14.5. Environmental hazards

noENVIRONMENTALLY HAZARDOUS:

14.6. Special precautions for user


14.7. Transport in bulk according to Annex II of Marpol and the IBC Code


SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

EU regulatory information

No information available.2004/42/EC (VOC):

National regulatory information

1 - slightly water contaminatingWater contaminating class (D):

15.2. Chemical safety assessment

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information






Changes

Rev. 1,0 ; 11.07.2013 Initial release

Abbreviations and acronyms

ADR: Accord européen sur le transport des marchandises dangereuses par Route ( European Agreement

concerning the

RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer

(Regulations

Concerning the International Transport of Dangerous Goods by Rail )

IMDG: International Maritime Code for Dangerous Goods

IATA: International Air Transport Association

IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)

ICAO: International Civil Aviation Organization

ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)

GHS: Globally Harmonized System of Classification and Labelling of Chemicals

EINECS: European Inventory of Existing Commercial Chemical Substances

CAS: Chemical Abstracts Service (division of the American Chemical Society)

LC50: Lethal concentration, 50 percent

LD50: Lethal dose, 50 percent

NOAEL: No observed adverse effect level

NOAEC: No observed adverse effect concentration

H314 Causes severe skin burns and eye damage.

Relevant H and EUH statements (number and full text)

The above information describes exclusively the safety requirements of the product and is based on our

present-day knowledge. The information is intended to give you advice about the safe handling of the product

named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be

transferred to other products. In the case of mixing the product with other products or in the case of

processing, the information on this safety data sheet is not necessarily valid for the new made-up material.

Further Information

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety

data sheet.)


Documents

MORPHISTO GmbH Safety Data Sheet€¦ · according to Regulation (EC) No 1907/2006 Safety Data Sheet MORPHISTO GmbH Kaliumpermanganat-Schwefelsäure Revision date: 13.02.2020 Product